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1.
Gokhfeld, D. M.
Highly Porous Superconductors: Synthesis, Research, and Prospects / D. M. Gokhfeld, M. R. Koblischka, A. Koblischka-Veneva> // Phys. Metals Metallogr. - 2020. -
Vol. 121
,
Is. 10
. - P. 936-948,
DOI
10.1134/S0031918X20100051. - Cited References: 146 . - ISSN 0031-918X. - ISSN 1555-6190
РУБ
Metallurgy & Metallurgical Engineering
Рубрики:
HIGH-T-C
CRITICAL-CURRENT DENSITY
HIGH-TEMPERATURE SUPERCONDUCTORS
Кл.слова (ненормированные):
YBCO
--
Bi2223
--
Bi2212
--
MgB2
--
synthesis
--
porosity
--
foam
--
polycrystal
--
fabric
--
sponge
--
pinning
--
critical current
--
percolation
--
magnetization
Аннотация:
This paper presents a review of studies of superconductors with a
porosity
above 50%. The pores in such superconducting materials allow refrigerant penetration and provide efficient heat dissipation and stable operation. Methods for the synthesis of the main groups of porous superconductors are described. The results of studies of the structural, magnetic, and electrical transport properties are presented, and the features of the current flow through porous superconductors of various types are considered. The directions of further development and application of porous superconductors are presented.
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Публикация на русском языке
Гохфельд, Денис Михайлович. Высокопористые сверхпроводники: синтез, исследования и перспективы [Текст] / Д. М. Гохфельд, М. Р. Коблишка, А. Коблишка-Венева // Физ. металлов и металловед. - 2020. - Т. 121 № 10. - С. 1026-1038
Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk Sci Ctr,Siberian Branch, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Shibura Inst Technol, Dept Mat Sci & Engn, Lab Superconducting Mat, Tokyo 1358548, Japan.
Доп.точки доступа:
Koblischka, M. R.; Koblischka-Veneva, A.; Гохфельд, Денис Михайлович
}
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2.
Gokhfeld, D. M.
Magnetic flux trapping in porous high-Tc superconductors / D. Gokhfeld> // Phys. C: Supercond. Appl. - 2024. -
Vol. 619
. - Ст. 1354486,
DOI
10.1016/j.physc.2024.1354486. - Cited References: 39 . - ISSN 0921-4534. - ISSN 1873-2143
Кл.слова (ненормированные):
Trapped magnetic field
--
Pinning
--
Critical current
--
Magnetization
--
YBCO
--
REBCO
--
Porosity
--
Surface barrier
Аннотация:
Porosity
affects the properties of high-Tc superconductors and can improve their performance by enhancing oxygenation, cryocooling, etc. Among other factors, the presence of pores plays a significant role in the process of magnetic flux trapping. Relationships with the
porosity
manifest in the irreversibility field, the full penetration field, and the remnant magnetization of the samples. To account for the effect of
porosity
on the trapped magnetic flux into type-II superconductors, a simple toy model is suggested. Generally, as the
porosity
increases, the trapped flux and related parameters tend to diminish. However, in the case of microscopic samples,
porosity
can enhance magnetic flux trapping.
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Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russia
Доп.точки доступа:
Гохфельд, Денис Михайлович
}
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3.
Magnetic Resonance Imaging
of Water Absorption by Highly Porous Ceramic Materials / E. V. Morozov [et al.]> // Dokl. Chem. - 2019. -
Vol. 484
,
Is. 2
. - P. 44-47,
DOI
10.1134/S0012500819020058. - Cited References: 9. - The studies were performed using equipment of KRTsKP FITs "KNTs SO RAN" in the framework of the program of basic research of the Russian Academy of Sciences (project no. V.44.1.7.) regarding the development of the MRI methodology for studying composite and porous materials, and also supported by the Russian Foundation for Basic Research (project no. 16-29-05334ofi_m "Scientific foundations for creating thin-film coatings with controlled wettability") regarding the development of water-repellent porous materials. . - ISSN 0012-5008
Кл.слова (ненормированные):
magnetic resonance imaging
--
porosity
--
ceramic materials
--
hydrophobic coatings
--
adsorption
--
capillary phenomena
Аннотация:
A nontrivial character of water absorption in highly porous ceramic materials has been demonstrated for the first time by magnetic resonance imaging: a phenomenon of hygroscopic memory has been detected consisting in the concentration of adsorbed water in certain areas inside the sample, repeated during subsequent wetting with water. It has been shown that hydrophobization of the material by applying fluoro paraffin coatings to oxide fibers using the method of dissolution of fluoropolymers in supercritical CO2 has a significant impact on the transport of water into products and can be considered an efficient means of protecting porous materials from moisture. The results demonstrate the capabilities of the MRI method in studying the water absorption and identifying water migration pathways in highly porous materials.
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Публикация на русском языке
Магнитно-резонансная томография водопоглощения высокопористыми керамическими материалами [Текст] / Е. В. Морозов [и др.] // Докл. Акад. наук. - 2019. - Т. 484 № 5. - С. 563-567
Держатели документа:
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
All-Russian Research Institute of Aviation Materials, Moscow, 105005, Russian Federation
Gubkin State University of Oil and Gas, Moscow, 119991, Russian Federation
Доп.точки доступа:
Morozov, E. V.; Морозов, Евгений Владимирович; Buznik, V. M.; Bespalov, A. S.; Grashchenkov, D. V.
}
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4.
Structural, magnetic and
electrochemical characteristics of Ni/C composites fabricated from modified hydrolytic lignin / S. I. Tsyganova, O. Yu. Fetisova, D. A. Velikanov, O. P. Taran> // Mater. Lett. - 2023. -
Vol. 352
. - Ст. 135120,
DOI
10.1016/j.matlet.2023.135120. - Cited References: 11. - The present work was supported by the Russian Foundation for Basic Research , the Government of the Krasnoyarsk Territory and carried out as part of the budget project ( 0287-2021-0017 ) of the Institute of Chemistry and Chemical Technology SB RAS . - ISSN 0167-577X. - ISSN 1873-4979
Перевод заглавия:
Структурные, магнитные и электрохимические характеристики Ni/C-композитов, полученных из модифицированного гидролитического лигнина
Кл.слова (ненормированные):
Hydrolytic lignin
--
Porosity
--
Ni/C composite
--
Carbonization
--
Magnetic properties
--
Specific capacity
Аннотация:
The synthesis of metal–carbon materials based on hydrolytic lignin by its modification with subsequent carbonation is studied. It is shown the modification of hydrolysis lignin with ZnCl2 and NiCl2 leads to a significant increase of specific surface area up to 716 m2/g and the apparent specific capacity up to 350F/g of carbonized composite. It was found out that fabricated Ni/C composites are characterized by a coercive force of 80–105 Oe, a saturation magnetization of 4–11 Gs•cm3/g, and a residual magnetization of 0.28–0.45 Gs•cm3/g. This indicates the prospects of their use as a magnetically soft material.
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Держатели документа:
Institute of Chemistry and Chemical Technology SB RAS, Federal Research Center KSC Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Tsyganova, S. I.; Yu. Fetisova, O.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Taran, O. P.
}
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5.
Synthesis and catalytic
hydrogenation activity of Pd and bimetallic Au–Pd nanoparticles supported on high-
porosity
carbon materials / O. V. Belousov [et al.]> // React. Kinet. Mech. Catal. - 2019. -
Vol. 127
,
Is. 1
. - P. 25–39,
DOI
10.1007/s11144-018-1430-0. - Cited References: 57 . - ISSN 1878-5190
Кл.слова (ненормированные):
MOCVD
--
Hydrothermal synthesis
--
Palladium nanoparticles
--
Mesostructured carbon
--
Bimetallic Pd–Au catalyst
--
Furfural diethyl acetal
--
Hydrogenation
Аннотация:
The processes of palladium deposition on various high-
porosity
carbon matrices (Sibunit, CMK-3) have been studied. Mesostructured carbon material CMK-3 was synthesized using a silicate template of SBA-15 type. Pd nanoparticles were loaded onto carbon matrices by metalorganic chemical vapour deposition (MOCVD) method using palladium(II) acetylacetonate precursor. Bimetal Au–Pd systems were synthesized by autoclave reduction of gold(III) chloride complexes on Pd-containing carbon matrices. Structure of the obtained composite particles was studied by electron microscopy and X-ray diffraction. The average diameter of Pd particles on Sibunit is about 10, and 5–6 nm on CMK-3. The catalytic activity of the synthesized materials was studied in the reaction of furfural diethyl acetal (FDEA) hydrogenation, using gas–liquid chromatographic analysis. There is significant difference in catalytic activity of MOCVD-Pd/C compared to conventional impregnated Pd/C systems: the hydrogenation rate is 3–6 times higher with MOCVD-derived catalysts. Introducing Au into a MOCVD-Pd/C catalyst increases the hydrogenation rate threefold. Considerable difference in the composition of hydrogenation products was observed between these differently prepared catalysts.
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Держатели документа:
Institute of Chemistry and Chemical Technology of the Siberian Branch of the Russian Academy of Sciences - A Separate Division of FSC KSC SB RAS, 50/24, Akademgorodok, Krasnoyarsk, Russian Federation
Boreskov Institute of Catalysis, 5, Lavrentieva, Novosibirsk, Russian Federation
Kirensky Institute of Physics of the Siberian Branch of the Russian Academy of Sciences - A Separate Division of FSC KSC SB RAS, 50/38, Akademgorodok, Krasnoyarsk, Russian Federation
Доп.точки доступа:
Belousov, O. V.; Tarabanko, V. E.; Borisov, R. V.; Simakova, I. L.; Zhyzhaev, A. M.; Tarabanko, N.; Isakova, V. G.; Исакова, Виктория Гавриловна; Parfenov, V. V.; Ponomarenko, I. V.
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