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    Engineering of K3YSi2O7 to Tune Photoluminescence with Selected Activators and Site Occupancy / J. Qiao [et al.] // Chem. Mater. - 2019. - Vol. 31, Is. 18. - P. 7770-7778, DOI 10.1021/acs.chemmater.9b02990. - Cited References: 48. - This work was supported by the National Natural Science Foundation of China (Nos. 51722202, 51972118 and 51572023), Natural Science Foundations of Beijing (2172036), Fundamental Research Funds for the Central Universities (FRF-TP-18-002C1), and Guangdong Provincial Science & Technology Project (2018A050506004). This work was also supported by the National Science Foundation, Ceramics Program (No. 1911372), and the computational resources were provided by the Extreme Science and Engineering Discovery Environment (XSEDE) supported by the National Science Foundation (No. ACI-1548562). . - ISSN 0897-4756
   Перевод заглавия: Производство K3YSi2O7 для настройки фотолюминесценции с выбранными активаторами и заселением позиций
Кл.слова (ненормированные):
Citrus fruits -- Density functional theory -- Doping (additives) -- Energy gap -- Gallium alloys -- III-V semiconductors -- Indium alloys -- Light -- Light emitting diodes -- Metal ions -- Phosphors -- Photoluminescence -- Rare earths -- Rietveld refinement -- Semiconductor alloys
Аннотация: The luminescence of rare earth ions (Eu2+, Ce3+, and Eu3+)-doped inorganic solids is attractive for the screening of phosphors applied in solid-state lighting and displays and significant to probe the occupied crystallographic sites in the lattice also offering new routes to photoluminescence tuning. Here, we report on the discovery of the Eu- and Ce-activated K3YSi2O7 phosphors. K3YSi2O7:Eu is effectively excited by 450 nm InGaN blue light-emitting diodes (LEDs) and displays an orange-red emission originated from characteristic transitions of both Eu2+ and Eu3+, while K3YSi2O7:Ce3+ shows green emission upon 394 nm near-ultraviolet (NUV) light excitation. Rietveld refinement verifies the successful doping of the activators, and density functional theory (DFT) calculations further support that Eu2+ occupies both K1 and Y2 crystallographic sites, while Ce3+ and Eu3+ only occupy the Y2 site; hence, the broad-band red emission of Eu2+ are attributed to a small DFT band gap (3.69 eV) of K3YSi2O7 host and a selective occupancy of Eu2+ in a highly distorted K1 site and a high crystal field splitting around Y2 sites. The white LEDs device utilizing orange-red-emitting K3YSi2O7:Eu and green-emitting K3YSi2O7:Ce3+ exhibits an excellent CRI of 90.1 at a correlated color temperature of 4523 K. Our work aims at bridging multivalent Eu2+/Eu3+ and Ce3+ site occupancy in the same host to realize photoluminescence tuning and especially exposes new ways to explore new phosphors with multicolor emission pumped by blue and NUV light for white LEDs.

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Держатели документа:
School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, 100083, China
Department of Nanoengineering, University of California, San Diego, 9500 Gilman Drive, San Diego, CA 92093, United States
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
National Synchrotron Radiation Research Center, Hsinchu, 300, Taiwan
State Key Laboratory of Luminescent Materials and Devices, Institute of Optical Communication Materials, South China University of Technology, Guangzhou, 510641, China

Доп.точки доступа:
Qiao, J.; Amachraa, M.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Chuang, Y. -C.; Ong, S. P.; Zhang, Q.; Xia, Z.
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    Exploration of structural, thermal, vibrational and spectroscopic properties of new noncentrosymmetric double borate Rb3NdB6O12 / V. V. Atuchin [et al.] // Adv. Powder Technol. - 2017. - Vol. 28, Is. 5. - P. 1309-1315, DOI 10.1016/j.apt.2017.02.019. - Cited References: 42. - We are grateful to Guochun Zhang for the crystal structure data on K3YB6O12, and O. Tsydenova and A. Sarapulova for her consultations. This research was supported by SB RAS Program No.II.2P (No. 0356-2015-0412) and RSF (14-22-0143). The reported study was funded by RFBR according to the research projects 15-02-04950 and 15-52-53080, 16-32-00351, 16-52-48010 and 17-52-53031. Also, the work was supported by Act 211 Government of the Russian Federation, contract 02.A03.21.0011 and by the Ministry of Education and Science of the Russian Federation (4.1346.2017/PP). . - ISSN 0921-8831
   Перевод заглавия: Изучение структурных, тепловых, колебательных и спектроскопических свойств нового нецентросимметричного кристалла двойного бората Rb3NdB6O12
Кл.слова (ненормированные):
Rubidium neodymium borate -- Solid state reaction -- Rietveld refinement -- DSC -- Raman scattering
Аннотация: New noncentrosymmetric rare earth borate Rb3NdB6O12 is found in the ternary system Rb2O–Nd2O3–B2O3. The Rb3NdB6O12 powder was fabricated by solid state synthesis at 1050 K for 72 h and the crystal structure was obtained by the Rietveld method. Rb3NdB6O12 crystallized in space group R32 with unit cell parameters a = 13.5236(4), c = 31.162(1) Å, Z = 3. From DSC measurements, the reversible phase transition (I type) in Rb3NdB6O12 is observed at 852–936 K. The 200 μm thick tablet is transparent over the spectral range of 0.3–6.5 μm and the band gap is found as Eg ∼ 6.29 eV. Nonlinear optical response of Rb3NdB6O12 tested via SHG is estimated to be higher than that of K3YB6O12. Blue shift of Nd luminescent lines is found in comparison with other borates. The vibrational parameters of Rb3NdB6O12 are evaluated by experimental methods.

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Держатели документа:
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, Novosibirsk, Russian Federation
Institute of Chemistry, Tyumen State University, Tyumen, Russian Federation
Laboratory of Single Crystal Growth, South Ural State University, Chelyabinsk, Russian Federation
Laboratory of Oxide Systems, Baikal Institute of Nature Management, SB RAS, Ulan-Ude, Russian Federation
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Laboratory for Nonlinear Optics and Spectroscopy, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Nanodiagnostics and Nanolithography, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Condensed Matter Spectroscopy, Institute of Automation and Electrometry, SB RAS, Novosibirsk, Russian Federation
Laboratory of High Pressure Minerals and Diamond Deposits, Institute of Geology and Mineralogy, SB RAS, Novosibirsk, Russian Federation

Доп.точки доступа:
Atuchin, V. V.; Subanakov, A. K.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Bazarov, B. G.; Bazarova, J. G.; Dorzhieva, S. G.; Gavrilova, T. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Pugachev, A. M.; Tushinova, Y. L.; Yelisseyev, A. P.
}
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    Exploration of structural, vibrational and spectroscopic properties of self-activated orthorhombic double molybdate RbEu(MoO4)2 with isolated MoO4 units / V. V. Atuchin, A. S. Aleksandrovsky, B. G. Bazarov [et al.] // J. Alloy. Compd. - 2019. - Vol. 785. - P. 692-697, DOI 10.1016/j.jallcom.2019.01.013. - Cited References: 42. - The reported study was funded by RFBR according to research projects 16-52-48010, 17-52-53031 and 18-03-00557. Besides, this study was supported by the Ministry of Science and Higher Education of the Russian Federation (project 0339-2016-0007). The work was supported by Act 211 Government of the Russian Federation, contract No 02.A03.21.0011. Additionally, the work was partially supported by the Ministry of Education and Science of the Russian Federation (4.1346.2017/4.6). . - ISSN 0925-8388. - ISSN 1873-4669
   Перевод заглавия: Исследование структурных, колебательных и спектроскопических свойств самоактивированного орторомбического двойного молибдата RbEu(MoO4)2 с изолированными группами MoO4

РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering
Рубрики:
MORPHOLOGY-CONTROLLED SYNTHESIS
LUMINESCENCE PROPERTIES
Кл.слова (ненормированные):
Rubidium europium molybdate -- Solid state reaction -- Rietveld refinement -- DSC -- Raman luminescence
Аннотация: RbEu(MoO4)2 is synthesized by the two-step solid state reaction method. The crystal structure of RbEu(MoO4)2 is defined by Rietveld analysis in space group Pbcn with cell parameters a = 5.13502(5), b = 18.8581(2) and c = 8.12849(7) Å, V = 787.13(1) Å3, Z = 4 (RB = 0.86%). This molybdate possesses its phase transition at 817 K and melts at 1250 K. The Raman spectra were measured with the excitation at λ = 1064 and 514.5 nm. The photoluminescence spectrum is evaluated under the excitation at 514.5 nm. The absolute domination of hypersensitive 5D0→7F2 transition is observed. The ultranarrow 5D0→7F0 transition in RbEu(MoO4)2 is positioned at 580.2 nm being 0.2 nm blue shifted, with respect to that in Eu2(MoO4)3.

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Держатели документа:
SB RAS, Lab Opt Mat & Struct, Inst Semicond Phys, Novosibirsk, Russia.
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia.
South Ural State Univ, Lab Single Crystal Growth, Chelyabinsk 454080, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
SB RAS, Kirensky Inst Phys, Lab Coherent Opt, Fed Res Ctr KSC, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660079, Russia.
SB RAS, Baikal Inst Nat Management, Lab Oxide Syst, Ulan Ude 670047, Russia.
Buryat State Univ, Ulan Ude 670000, Russia.
Ind Univ Tyumen, Dept Gen & Special Chem, Tyumen 625000, Russia.
SB RAS, Inst Semicond Phys, Lab Nanodiagnost & Nanolithog, Novosibirsk 630090, Russia.
SB RAS, Kirensky Inst Phys Fed Res Ctr KSC, Lab Mol Spect, Krasnoyarsk 660036, Russia.
SB RAS, Inst Inorgan Chem, Lab Funct Films & Coatings, Novosibirsk 630090, Russia.
SB RAS, Lab Crystal Phys, Kirensky Inst Phys, Fed Res Ctr KSC, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
Siberian Fed Univ, Krasnoyarsk 660079, Russia.
SB RAS, Inst Automat & Elect, Lab Condensed Matter Spect, Novosibirsk 630090, Russia.

Доп.точки доступа:
Atuchin, V. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Bazarov, B. G.; Bazarova, J. G.; Chimitova, Olga D.; Denisenko, Yuriy G.; Gavrilova, T. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Maximovskiy, Eugene A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Pugachev, Alexey M.; Surovtsev, Nikolay V.; RFBR [16-52-48010, 17-52-53031, 18-03-00557]; Ministry of Science and Higher Education of the Russian Federation [0339-2016-0007]; Act 211 Government of the Russian Federation [02.A03.21.0011]; Ministry of Education and Science of the Russian Federation [4.1346.2017/4.6]
}
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    Guan, M.
    Atomic deciphering of cation exchange mechanism in upconversion nanoparticles / M. Guan, M. S. Molokeev, J. Zhou // J. Lumin. - 2020. - Vol. 224. - Ст. 117289, DOI 10.1016/j.jlumin.2020.117289. - Cited References: 36. - The authors acknowledge the Science and Technology Innovation Committee of Shenzhen (Grant No. KQTD20170810110913065), Australian Research Council (ARC) Discovery Early Career Researcher Award Scheme (J. Z., DE 180100669), and the China Scholarship Council (Ming Guan, No. 201506400025) . - ISSN 0022-2313
   Перевод заглавия: Атомная расшифровка катионообменного механизма в наночастицах с апконверсией
Кл.слова (ненормированные):
Mn2+ -- β-NaYF4 nanoparticles -- Cation exchange -- Rietveld refinement
Аннотация: Transition metal ion doping in upconversion nanoparticles (UCNPs) provides an effective way to enhance the luminescence for their wide array of applications. However, the doping sites of transition metal ions have not been comprehensively explored, and commonly assumed that transition metal ions replace the trivalent lanthanides within the lattice. Here we report that cation exchange of transition metal (Mn2+) in β-NaYF4:Yb3+/Er3+ UCNPs occurs through alkaline metal (Na+) replacement, via 2Na+ ↔ Mn2+ + Vacancy reaction. This process distorts the LnF9 polyhedrons and tailors the surrounding environment around the trivalent lanthanides, thereby improving the upconversion intensity from active lanthanides. Further confirmed by core-shell design and spectroscopic study, we prove that the transition–alkaline metal exchange enables both the emission enhancement and transition probability variation of activators.

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Держатели документа:
UTS-SUStech Joint Research Centre for Biomedical Materials & Devices, Southern University of Science and Technology, Shenzhen, Guangdong 518055, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, 79 Svobodny Ave., Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhou, J.
}
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Investigation of structural, elastic and magnetic properties of Cu2+ ions substituted cobalt nano ferrites / A. Thakur, R. Verma, F. Wan [et al.] // J. Magn. Magn. Mater. - 2023. - Vol. 581. - Ст. 170980, DOI 10.1016/j.jmmm.2023.170980. - Cited References: 47. - This research work was supported by the National Key Research and Development Program of China (2022YFE010707). The author(s) would like to acknowledge the support provided under the DST-FIST Grant No. SR/FST/PS-I/2018/48 of Govt. of India. PT is thankful to DST-SERB TARE fellowship vide Sanction Order No TAR/2022/000414 . - ISSN 0304-8853. - ISSN 1873-4766
Кл.слова (ненормированные):
Nanoferrites -- Structure -- Rietveld Refinement -- Elastic Properties -- Magnetic Porperties
Аннотация: In the present work, we synthesized the Cu-doped CoFe2O4 (Co1-xCuxFe2O4) nanoparticles with x = 0.0, 0.2, 0.4 and 0.6, by employing the citrate precursor method. The X-ray Diffraction (XRD) pattern confirmed the pure cubic structure formation with the Fd-3m space group. To know the structural purity of each sample as well as the distribution of cations, Rietveld refinement was carried out. The crystallite size increases from 39.55 nm to 41.80 nm upto x = 0.2 and with further doping of Cu2+ ions it decreases to 36.27 nm. Similar variation is observed in the lattice parameter where the value of ‘a’ first increases from 8.378 Å to 8.381 Å and then decreases to 8.377 Å. The development of a non-uniform grain is seen using scanning electron microscope (SEM), which reveals the reduction in grain size. Fourier Transform Infrared Spectroscopy (FTIR) showed the two peaks ν1 and ν2 for all the samples around 541 cm−1 and 408 cm−1, respectively, which further decreases to 532.5 cm−1 and 402.5 cm−1 as the dopant ion concentration increases. The Stiffness constant, and Elastic modulus decrease with doping whereas, the Poisson’s ratio and Pugh’s ratio show a constant value of around 0.249 and 1.660, respectively. Vibrating Sample Magnetometer (VSM) analysis shows a decrease in saturation magnetization (σs) value from 76.85 emu/g to 43.62 emu/g. The net magnetic moment (nB) decreases from 3.29 μB to 1.85 μB and the effective anisotropy constant value decreases from 10.672erg/g to 4.461erg/g. Thus, the prepared nanoparticles provide a way forward for their industrial applications.

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Держатели документа:
School of Electronics and Information Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China
NanoLatticeX, Amity University Haryana, Gurugram, Haryana 122413, India
Nanotechnology Wing, Innovative Science Research Society, Shimla 177002, India
Centre for Nanotechnology, Amity University Haryana, Gurugram 122413, India
Department of Physics, Amity University Haryana, Gurugram 122413, India
Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences, 50 Akademgorodok, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Thakur, Atul; Verma, Ritesh; Wan, Fayu; Ravelo, Fayu; Edelman, I. S.; Эдельман, Ирина Самсоновна; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Thakur, Preeti
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    Low-temperature synthesis and structural properties of ferroelectric K 3WO3F3 elpasolite / V. V. Atuchin [et al.] // Chem. Phys. Lett. - 2010. - Vol. 493, Is. 1-3. - P. 83-86, DOI 10.1016/j.cplett.2010.05.023. - Cited References: 37 . - ISSN 0009-2614
Рубрики:
PEROVSKITE-LIKE OXYFLUORIDES
   CORE-LEVEL SPECTROSCOPY
   PHASE-TRANSITIONS
   SOLID-STATE
   ELECTRON-DIFFRACTION
   DIFFUSE-SCATTERING
   RHEED ANALYSIS
   POLAR
   BEHAVIOR
   (NH4)(3)TIOF5
Кл.слова (ненормированные):
Chemical synthesis -- Elpasolite -- Ferroelectric phase transition -- Fluorine atoms -- Low temperature synthesis -- Low temperatures -- Oxyfluorides -- Partial ordering -- Room temperature -- SEM -- Space Groups -- Structure parameter -- XRD -- Chemical properties -- Ferroelectric materials -- Ferroelectricity -- Fluorine -- Oxygen -- Phase transitions -- Rietveld method -- Single crystals -- Synthesis (chemical) -- X ray photoelectron spectroscopy -- X ray powder diffraction -- Scanning electron microscopy
Аннотация: Low-temperature ferroelectric G2 polymorph of K3WO 3F3 has been prepared by chemical synthesis. Structural and chemical properties of the final product have been evaluated with X-ray powder diffraction (XRD), scanning electron microscopy (SEM) and X-ray photoelectron spectroscopy (XPS). Structure parameters of G2-K 3WO3F3 are refined by the Rietveld method from XRD data measured at room temperature (space group Cm, Z = 2, a = 8.7350(3), b = 8.6808(5), c = 6.1581(3), ? = 135.124(3), V = 329.46(3) 3; RB = 2.47%). Partial ordering of oxygen and fluorine atoms has been found over anion positions. Mechanism of ferroelectric phase transition in A2BMO3F3 oxyfluorides is discussed. В© 2010 Elsevier B.V. All rights reserved.

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Держатели документа:
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russian Federation
Laboratory of Nanolithography and Nanodiagnostics, Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russian Federation
Laboratory of Physical Principles for Integrated Microelectronics, Institute of Semiconductor Physics, SB RAS, Novosibirsk 630090, Russian Federation
Laboratory of Crystal Physics, Institute of Physics, SB RAS, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Atuchin, V. V.; Gavrilova, T. A.; Kesler, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Aleksandrov, K. S.; Александров, Кирилл Сергеевич
}
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Molokeev, M. S.
Crystal structures of room- and low-temperature phases in oxyfluoride (NH4)(2)KWO3F3 / M. S. Molokeev, A. D. Vasiliev, A. G. Kocharova // Powder Diffr. - 2007. - Vol. 22, Is. 3. - P. 227-230, DOI 10.1154/1.2759491. - Cited References: 8. - Cover image: Artwork representing main idea of this article . - ISSN 0885-7156

РУБ Materials Science, Characterization & Testing

Кл.слова (ненормированные):
structure determination -- Rietveld analysis -- powder diffraction -- phase transition -- oxyfluoride
Аннотация: Crystal structures of (NH4)2KWO(3)F(3) at 298 K and 113 K were solved from X-ray powder diffraction data and refined by the Rietveld technique. The compound is isostructural with elpasolite K2NaAlF6 at room temperature with space group Fm-3m, a=8.95850(5) angstrom, V=718.961(7) angstrom(3), Z =4, D-x=3.363 g/cm(3), and M-W=364.02. The structure was refined over 18 parameters to R-wp =12.6%, R-p=10.9%, R-exp=5.03%, and R-B=3.27% from 40 independent reflections. (NH4)2KWO(3)F(3) was transformed upon cooling to a ferroelastic monoclinic phase with space group P2(1)/n, a'=6.3072(3) angstrom, b'=6.3028(3) angstrom, c'=8.9882(3) angstrom, beta'=90.242(2)degrees, V=357.30(3) angstrom(3), Z =2, and D-x=3.383 g/cm(3). The low-temperature structure at 113 K was refined over 28 parameters,P to R-wp=20.9%, R-p=21.3%, R-exp= 12.5%, and R-B=6.93% from 453 independent reflections. (C) 2007 International Centre for Diffraction Data.

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Доп.точки доступа:
Vasiliev, A. D.; Васильев, Александр Дмитриевич; Kocharova, A. G.; Кочарова, Алла Георгиевна; Молокеев, Максим Сергеевич
}
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    New insight into the crystal structure of Sr4Ca(PO4)2SiO4 and the photoluminescence tuning of Sr4Ca(PO4)2SiO4:Ce3+,Na+,Eu2+ phosphors / M. Zhang [et al.] // J. Mater. Chem. C. - 2016. - Vol. 4, Is. 38. - P. 9078-9084, DOI 10.1039/c6tc03373c. - Cited References: 31 . - ISSN 2050-7534
   Перевод заглавия: Новый взгляд на кристаллическую структуру Sr4Ca(PO4)2SiO4 и управление люминесценцией в Sr4Ca(PO4)2SiO4:Ce3+,Na+,Eu2+
Кл.слова (ненормированные):
Calcium -- Energy transfer -- Europium -- Light emission -- Light emitting diodes -- Luminescence -- Phosphate minerals -- Phosphors -- Photoluminescence -- Positive ions -- Rietveld refinement -- Tuning -- Chemical compositions -- Energy transfer mechanisms -- Green component -- Hexagonal cells -- Luminescence properties -- Single phase -- Solid state method -- White lightemitting diodes (WLEDs) -- Crystal structure
Аннотация: A new single phase based on the substitution of a Sr cation by a Ca cation in the apatite-type Sr5(PO4)2(SiO4) has been fabricated with the nominal chemical composition of Sr4Ca(PO4)2(SiO4), which appears as a definite compound rather than a solid solution between (Sr,Ca)3(PO4)2 and (Sr,Ca)2SiO4. The crystal structure of Sr4Ca(PO4)2(SiO4) has been firstly analysed by the difference electron map, and further resolved by the Rietveld refinement, and the final composition has been determined as Sr4Ca(PO4)(2+x)(SiO4)(1-x)(OH)x (x = 0.64) with a hexagonal cell (P63/m). The Ce3+/Eu2+ codoped Sr4Ca(PO4)2SiO4 phosphors have been designed and prepared by the solid state method, and the photoluminescence tuning from blue to green upon 365 nm ultraviolet (UV) radiation can be realized, which is ascribed to the energy transfer from Ce3+ to Eu2+ ions. The luminescence properties and the energy transfer mechanism in Ce3+/Eu2+ codoped Sr4Ca(PO4)2SiO4 phosphors have been discussed, which might act as potential candidates for blue-green components in UV-pumped white light emitting diodes (WLEDs). © 2016 The Royal Society of Chemistry.

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Держатели документа:
School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation

Доп.точки доступа:
Zhang, M.; Xia, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Shi, L.; Liu, Q.
}
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    Photoluminescence of monoclinic Li3AlF6 crystals under vacuum ultraviolet and soft X-ray excitations / V. A. Pustovarov [et al.] // Opt. Mater. - 2015. - Vol. 49. - P. 201-207, DOI 10.1016/j.optmat.2015.09.011. - Cited References: 49. - This work was partly supported by the Ministry of Education and Science of the Russian Federation (the basic part of the government mandate); Center of Excellence "Radiation and Nuclear Technologies" (Competitiveness Enhancement Program of Ural Federal University, Russia), HASYLAB DESY (Projects Nos. 20110843, 20080119EC), European Social Fund ("Mobilitas" program, MJD219), Estonian Research Council (Institutional Research Funding IUT02-26) and Baltic Science Link project coordinated by the Swedish Research Council, VR . - ISSN 0925-3467
   Перевод заглавия: Люминесценция моноклинных кристаллов Li3AlF6 под вакуумным ультрафиолетом и мягким рентгеновским излучением

РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
LiBaAlF6 single-crystals
   F-type centers
   LiBaF3 crystals
   Color-centers
   Recombination luminescence
   Rietveld refinement
   VUV spectroscopy
   Trapped excitons
   Energy-transfer
   Pure
Кл.слова (ненормированные):
Li3AlF6 -- Time-resolved luminescence -- VUV spectroscopy -- Defects
Аннотация: Using Bridgman technique we have grown monoclinic β-LiAF crystals suitable for optical studies, performed XRD-identification and Rietveld refinement of the crystal structure and carried out a photoluminescence study upon vacuum ultraviolet (VUV) and extreme ultraviolet (XUV)-excitations, using the low-temperature (T = 7.2 K) time-resolved VUV-spectroscopy technique. The intrinsic PL emission band at 340–350 nm has been identified as due to radiative recombination of self-trapped excitons. The electronic structure parameters were determined: bandgap E g ≈ 12.5 eV, energy threshold for creation of unrelaxed excitons 11.8 eV < E n < 12.5 eV . The PL emission bands at 320–325 and 450 nm were attributed to luminescence caused by lattice defects. We have discovered an efficient excitation of PL emission bands in the energy range of interband transitions ( E ex > 13.5 eV), as well as in the energy range of core transitions at 130 eV. We have revealed UV–VUV PL emission bands at 170 and 208 nm due to defects. A reasonable assumptions about the origin of the UV–VUV bands were discussed.

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Держатели документа:
Ural Federal University, 19, Mira Street, Yekaterinburg, Russian Federation
Institute of Physics, University of Tartu, 14c, Ravila Street, Tartu, Estonia
Kirensky Institute of Physics, SB RAS, Akademgorodok 50, Krasnoyarsk, Russian Federation
Far Eastern State Transport University, 47, Serysheva Street, Khabarovsk, Russian Federation
Institute of Geology and Mineralogy, SB RAS, 43, Russkaya Street, Novosibirsk, Russian Federation
Novosibirsk National Research University, 2, Pirogova Street, Novosibirsk, Russian Federation

Доп.точки доступа:
Pustovarov, V. A.; Пустоваров В. А.; Ogorodnikov, I. N.; Огородников И. Н.; Omelkov, S. I.; Омелков С. И.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Kozlov, A. V.; Козлов А. В.; Isaenko, L. I.; Исаенко Л. И.
}
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10.

    Photoluminescence tuning in a novel Bi3+/Mn4+ co-doped La2ATiO6:(A = Mg, Zn) double perovskite structure: Phase transition and energy transfer / G. Xing [et al.] // J. Mater. Chem. C. - 2018. - Vol. 6, Is. 48. - P. 13136-13147, DOI 10.1039/c8tc05171b. - Cited References: 60. - This work was supported by the National Natural Science Foundation of China (Grant No. 51672259, 51672265, 21521092, 51750110511), the Engineering Research Center of Nano-Geomaterials of Ministry of Education, China University of Geosciences (Wuhan) (No. NGM2016KF002), the Key Research Program of Frontier Sciences, CAS (Grant No. YZDYSSW-JSC018), and the projects for science and technology development plan of Jilin province (20170414003GH), the Program for Jiangmen Innovative Research Team (No. [2017]385), and the major program of basic research and applied research of Guangdong Province (2017KZDXM083). . - ISSN 2050-7534
   Перевод заглавия: Управление люминесценцией в новой структуре двойного перовскита La2ATiO6:(A = Mg, Zn) допированным Bi3+/Mn4+: фазовый переход и перенос энергии
Кл.слова (ненормированные):
Crystal symmetry -- Energy transfer -- Light -- Luminescence -- Perovskite -- Phosphors -- Rietveld refinement
Аннотация: Red-emitting phosphors are indispensable compounds which are used to achieve a warm white light in phosphor-converted white light emitting diodes (pc-WLEDs). However, the luminous efficiency and stability of red phosphors are still big challenges. In this work, we developed red-emitting double perovskite phosphors La2ATiO6:Bi3+,Mn4+ (A = Mg, Zn) (LAT:Bi3+,Mn4+) and discuss the relationship between the double perovskite phosphor structure and the luminescence performance in detail. According to the Rietveld refinement results for the La2Mg(1−w)ZnwTiO6:Bi3+,Mn4+ (0 ≤ w ≤ 1) (LM(1−w)ZwT:Bi3+,Mn4+) solid solution, the proposed mechanism of the spectral adjustment is ascribed to the appearance of the phase transition, which results in a lower local structural symmetry of the [LaO12] polyhedron and the variation of the crystal field environment for Mn4+. Notably, this is the first time that the influence of the local structure variation on the luminescence tuning in double perovskite structure phosphors has been revealed, and this could offer guidance for the development of new phosphor system. By designing Mg2+/Zn2+ cation substitution, the internal quantum efficiency (IQE) is remarkably enhanced beyond 20%. In addition, we succeeded in achieving a Bi3+/Mn4+ co-doped energy transfer in the double perovskite structure phosphors. Owing to the Bi3+ → Mn4+ energy transfer in LAT, the red emission of the Mn4+ ions could be dramatically enhanced. The energy transfer efficiency of LAT:Bi3+,Mn4+ eventually exceeded 90%. The IQE and the thermal stability were all enhanced by around 30% compared to the non-co-doped samples, respectively. These results indicate that the Bi3+ → Mn4+ energy transfer strategy could play a pivotal role in the development of highly efficient red-emitting phosphors. The performance of the fabricated pc-WLEDs devices indicates that LAT:Bi3+,Mn4+ could be a promising red phosphor for near ultraviolet (n-UV) based warm pc-WLEDs.

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Держатели документа:
Engineering Research Center of Nano-Geomaterials, Ministry of Education, Faculty of Materials Science and Chemistry, China University of Geosciences, 388 Lumo Road, Wuhan, 430074, China
State Key Laboratory of Rare Earth Resource Utilization, Changchun Institute of Applied Chemistry, Chinese Academy of Sciences, Changchun, 130022, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, FRC KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
School of Applied Physics and Materials, Wuyi University, Jiangmen, Guangdong, 529020, China

Доп.точки доступа:
Xing, G.; Feng, Y.; Pan, M.; Wei, Y.; Li, G.; Dang, P.; Liang, S.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Cheng, Z.; Lin, J.
}
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11.

    Preparation and structural properties of nonlinear optical borates K 2(1-x)Rb 2xAl 2B 2O 7, 0 ˂ x ˂ 0.75 / V. V. Atuchin [и др.] // J. Alloys Compd. - 2012. - Vol. 515. - P. 119-122, DOI 10.1016/j.jallcom.2011.11.115. - Cited References: 30. - This study was supported by SB RAS (Grant 34) and RFBR Grants 11-02-90706-mob_st and 11-03-00867a. . - ISSN 0925-8388
   Перевод заглавия: Получение и структурные свойства нелинейных оптических боратов K 2(1-x)Rb 2xAl 2B 2O 7, 0 ˂ x ˂ 0.75

РУБ Chemistry, Physical + Materials Science, Multidisciplinary + Metallurgy & Metallurgical Engineering + Aluminum + Crystal structure + Nonlinear optics + Rietveld analysis + Rubidium + Solid solutions + Structural properties + X ray powder diffraction
Рубрики:
UV-light generation
   Frequence-conversion
   K2Al2B2O7 crystal
   Composition ratio
   Mixed-crystals
   Growth
   KRbAl2B2O7
   NLO properties
   Non-linear optical
   Non-linear optical properties
   Rietveld analysis of X-ray powder diffraction data
   Solubility limits
   Space Groups
   Structural parameter
Кл.слова (ненормированные):
KRbAl2B2O7 -- Solid solution -- Crystal structure -- NLO properties
Аннотация: The structures of K 2(1-x)Rb 2xAl 2B 2O 7, x = 0.25, 0.5, 0.75, have been determined in space group P321 through Rietveld analysis of X-ray powder diffraction data. The solubility limit in K 2(1-x)Rb 2xAl 2B 2O 7 crystals has been estimated as x similar to 0.83-0.9. Nonlinear optical properties of KRbAl 2B 2O 7 have been verified by powder Kurtz-Perry method. Mechanisms of structural parameter variation in K 2Al 2B 2O 7 crystal family have been discussed.

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Доп.точки доступа:
Atuchin, V. V.; Bazarov, B. G.; Gavrilova, T. A.; Grossman, V. G.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Bazarova, Zh. G.
}
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12.

    Probing Eu2+ luminescence from different crystallographic sites in Ca10M(PO4)7:Eu2+ (M = Li, Na, and K) with β-Ca3(PO4)2-type structure / M. Chen [et al.] // Chem. Mater. - 2017. - Vol. 29, Is. 17. - P. 7563-7570, DOI 10.1021/acs.chemmater.7b02724. - Cited References: 34. - The present work was supported by the National Natural Science Foundation of China (Grants 51722202, 91622125, and 51572023), Natural Science Foundations of Beijing (2172036), and Fundamental Research Funds for the Central Universities (FRF-TP-16-002A3). C.C.L. and C.C.S. acknowledge the financial support from the Ministry of Science and Technology of Taiwan (Contract No. MOST 104-2113-M-027-007-MY3), and M. Molokeev acknowledges support of the Russian Foundation for Basic Research (17-52-53031). . - ISSN 0897-4756
   Перевод заглавия: Исследование люминесценции Eu2+ в разных кристаллографических положениях в Ca10M(PO4)7:Eu2+ (M = Li, Na and K) со структурой типа beta-Ca3(PO4)2
Кл.слова (ненормированные):
Calcium -- Doping (additives) -- Excited states -- Light emission -- Lithium -- Luminescence -- Phosphors -- Photoluminescence -- Positive ions -- Rietveld refinement -- Single crystals -- Color tuning -- Crystallographic sites -- Different distributions -- Emission bands -- Local environments -- Long wavelength bands -- Luminescent centers -- Power diffraction data -- Europium
Аннотация: Eu2+ local environments in various crystallographic sites enable the different distributions of the emission and excitation energies and then realize the photoluminescence tuning of the Eu2+ doped solid state phosphors. Herein we report the Eu2+-doped Ca10M(PO4)7 (M = Li, Na, and K) phosphors with β-Ca3(PO4)2-type structure, in which there are five cation crystallographic sites, and the phosphors show a color tuning from bluish-violet to blue and yellow with the variation of M ions. The difference in decay rate monitored at selected wavelengths is related to multiple luminescent centers in Ca10M(PO4)7:Eu2+, and the occupied rates of Eu2+ in Ca(1), Ca(2), Ca(3), Na(4), and Ca(5) sites from Rietveld refinements using synchrotron power diffraction data confirm that Eu2+ enters into four cation sites except for Ca(5). Since the average bond lengths d(Ca-O) remain invariable in the Ca10M(PO4)7:Eu2+, the drastic changes of bond lengths d(M-O) and Eu2+ emission depending on the variation from Li to Na and K can provide insight into the distribution of Eu2+ ions. It is found that the emission band at 410 nm is ascribed to the occupation of Eu2+ in the Ca(1), Ca(2), and Ca(3) sites with similar local environments, while the long-wavelength band (466 or 511 nm) is attributed to Eu2+ at the M(4) site (M = Na and K). We show that the crystal-site engineering approach discussed herein can be applied to probe the luminescence of the dopants and provide a new method for photoluminescence tuning.

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Держатели документа:
Beijing Municipal Key Laboratory of New Energy Materials and Technologies, School of Materials Sciences and Engineering, University of Science and Technology Beijing, Beijing, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center, KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Institute of Organic and Polymeric Materials, National Taipei University of Technology, Taipei, Taiwan
National Synchrotron Radiation Research Center, Hsinchu, Taiwan

Доп.точки доступа:
Chen, M.; Xia, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lin, C. C.; Su, C.; Chuang, Y. -C.; Liu, Q.
}
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13.

    Structural and spectroscopic properties of new noncentrosymmetric self-activated borate Rb3EuB6O12 with B5O10 units / V. V. Atuchin [et al.] // Mater. Des. - 2018. - Vol. 140. - P. 488-494, DOI 10.1016/j.matdes.2017.12.004. - Cited References: 53. - We are grateful to Guochun Zhang for the crystal structure materials on K3YB6O12 and O. Tsydenova, A. Sarapulova for the consultations. The work was supported by Projects № 0356-2015-0412 of SB RAS Program № II.2P and № 0339-2016-0007. The reported study was funded by RFBR according to research projects 16-52-48010, 17-02-00920, 17-03-00886 and 17-52-53031 and RSF project 14-22-00143. The work was supported by Act 211 Government of the Russian Federation, contract № 02.A03.21.0011, and by the Ministry of Education and Science of the Russian Federation (5.5523.2017/8.9). This research was supported by Grant no. 8.2.01.2017 of Tomsk State University Academic D.I. Mendeleev Fund Program. . - ISSN 0264-1275
   Перевод заглавия: Структурные и спектроскопические характеристики самоактивированного бората Rb3EuB6O12 со структурными единицами B5O10
Кл.слова (ненормированные):
Rubidium rare earth borate -- Solid state reaction -- Rietveld refinement -- Raman -- Infrared spectroscopy -- Luminescence
Аннотация: New noncentrosymmetric double borate Rb3EuB6O12 was designed and synthesized by the solid state reaction method, and its crystallographic parameters were obtained by Rietveld analysis. This borate crystallizes in the trigonal space group R32 with cell parameters a = 13.4604(2) Å, c = 30.7981(5) Å, Z = 15. Its structure features a three-dimensional framework composed of the [B5O10]5 − groups that are bridged by Eu-O polyhedra. The existence of B5O10 group in the structure was confirmed by vibrational spectroscopy. Rb3EuB6O12 melts incongruently at 1101 K. The second harmonic generation effect of Rb3EuB6O12 is 16 times higher than that of the α-quartz standard. In the luminescence spectrum, the domination of a single prominent narrow line from the hypersensitive 5D0 - 7F2 manifold of Eu3 + ions is observed, while the 5D0 - 7F1 manifold and ultranarrow 5D0 - 7F0 line are of comparable peak intensity. These features are explained by a specific local symmetry of the Eu3+ ion within the crystal structure of Rb3EuB6O12.

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Держатели документа:
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, Tomsk, Russian Federation
Laboratory of Single Crystal Growth, South Ural State University, Chelyabinsk, Russian Federation
Baikal Institute of Nature Management, SB RAS, Ulan-Ude, Russian Federation
Buryat State University, Ulan-Ude, Russian Federation
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Nanodiagnostics and Nanolithography, Institute of Semiconductor Physics, SB RAS, Novosibirsk, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk, Russian Federation
Department of Chemistry, Lomonosov Moscow State University, Moscow, Russian Federation

Доп.точки доступа:
Atuchin, V. V.; Subanakov, A. K.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Bazarov, B. G.; Bazarova, J. G.; Gavrilova, T. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Stefanovich, S. Y.
}
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14.

Structure refinement and magnetic properties of synthetic Co3Ge2O5(OH)4 phyllogermanate / N. A. Belskaya, E. K. Khrapova, A. A. Ivanova [et al.] // J. Magn. Magn. Mater. - 2023. - Vol. 587. - Ст. 171262, DOI 10.1016/j.jmmm.2023.171262. - Cited References: 51. - The authors are grateful to Dr. N.V. Kazak and Dr. A.A. Levin for a lot of fruitful discussions. Magnetisation measurements were carried out in the Common Access Facility Centres of SBRAS (Krasnoyarsk, Russia) X-ray powder diffraction measurements were performed at the Engineering Centre of St. Petersburg State Institute of Technology. - The study was supported by grant No. 23-22-00245 of the Russian Science Foundation, https://rscf.ru/project/23-22-00245/ . - ISSN 0304-8853. - ISSN 1873-4766
Кл.слова (ненормированные):
Layered material -- Lizardite structure -- Hydrothermal synthesis -- Crystal structure -- Rietveld method -- Antiferromagnetism/Ferromagnetism
Аннотация: Co3Ge2O5(OH)4 relates to a specific group of 1:1 layered compounds with an ability to form either platy or tubular particles depending on chemical composition. Despite successful synthesis and perspective application, there is a lack of information on its crystal structure and magnetic properties, granted by Co ions. Co3Ge2O5(OH)4 phyllogermanate nanoparticles have been obtained using a hydrothermal method and characterised using powder X-ray diffraction and magnetisation measurements. Triclinic symmetry with a 1:P1 space group has been established. The unit cell contains three layers perpendicular to the c crystallographic direction, with 7.6 Å spacing and –b/3 shift of the middle layer. At a low magnetic field of 100 Oe the compound undergoes a magnetic transition at TN=5.2 K. The field of 9 T is not sufficient to take the sample to a magnetically saturated state with an asymptotic magnetic moment of 2.43 μB/Co2+. The estimations of the intralayer and interlayer exchange constants give values of J1/kB=2.75 K and J2/kB=0.25 K, respectively.

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Держатели документа:
Ioffe Institute, Polytechnicheskaya street, St.-Petersburg, 26194021, Russian Federation
Kirensky Institute of Physics, Akademgorodok 50, bld. 38, Krasnoyarsk, 660036, Russian Federation
Reshetnev Siberian State University of Science and Technology, 31, Krasnoyarsky Rabochy Av., Krasnoyarsk, 660037, Russian Federation

Доп.точки доступа:
Belskaya, N. A.; Khrapova, E. K.; Ivanova, A. A.; Eremin, E. V.; Еремин, Евгений Владимирович; Pavlov, S. I.; Krasilin, A. A.
}
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15.

Synthesis and luminescent properties of (RE0.95Ln0.05)2O2S (RE = La, Y; Ln = Ho, Tm) / E. I. Sal'nikova, Y. G. Denisenko, I. E. Kolesnikov [et al.] // J. Solid State Chem. - 2021. - Vol. 293. - Ст. 121753, DOI 10.1016/j.jssc.2020.121753. - Cited References: 33 . - ISSN 0022-4596
Кл.слова (ненормированные):
Rare earth oxysulfides -- Synthesis -- Rietveld -- Luminescence -- Lifetime -- Quantum yield
Аннотация: Solid solutions of oxysulfides (RE0.95Ln0.05)2O2S (RE = La, Y; Ln = Ho, Tm) were obtained by hydrogen reduction of the co-precipitated sulfates followed by sulfidation of the reaction products. The crystal chemical characteristics of the obtained compounds were refined by the Rietveld method. Morphological certification of particles in the dynamics of synthesis was performed. Most of the particles produced by chemical reactions have a cut that indicates the formation of a compound with a hexagonal syngony with angles of 60 and 120°. This indicates that the thermal effect of gaseous reagents H2, H2S on sulfates leads to heterogeneous reactions of thermal dissociation and the formation of new phases. Steady state luminescence properties displayed characteristic sharp bands corresponding to 4f-4f transitions. Luminescence decay curves of all studied samples showed monoexponential decay with microsecond and hundreds microsecond lifetimes depending on doping ions. Calculated color coordinates of Ho3+ and Tm3+-doped powders make them promising candidates to be used as phosphors.

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Держатели документа:
Department of Inorganic and Physical Chemistry, Tyumen State University, Tyumen, 625003, Russian Federation
Komissarov Department of General Chemistry, Northen Trans-Ural Agricultural University, Tyumen, 625003, Russian Federation
Department of General and Special Chemistry, Industrial University of Tyumen, Tyumen, 625000, Russian Federation
Center for Optical and Laser Materials Research, St. Petersburg State University, St. Petersburg, 199034, Russian Federation
Department of Physics, Lappeenranta University of Technology LUT, Lappeenranta, 53850, Finland
Laboratory of the Chemistry of Rare Earth Compounds, Institute of Solid State Chemistry, UB RAS, Ekaterinburg, 620137, Russian Federation
Laboratory of Electron and Probe Microscopy, Tyumen State University, Tyumen, 625003, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Sal'nikova, E. I.; Denisenko, Y. G.; Kolesnikov, I. E.; Lahderanta, E.; Andreev, O. V.; Azarapin, N. O.; Basova, S. A.; Gubin, A. A.; Oreshonkov, A. S.; Орешонков, Александр Сергеевич
}
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16.

Synthesis, structural, magnetic, and electronic properties of cubic CsMnMoO3F3 oxyfluoride / V. V. Atuchin [et al.] // J. Phys. Chem. C. - 2012. - Vol. 116, Is. 18. - P. 10162-10170, DOI 10.1021/jp302020f. - Cited References: 64. - We thank Dr. A.M. Ziatdinov for the electron paramagnetic resonance measurements. This study was partly supported by SB RAS (Grant 28). . - ISSN 1932-7447

РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary
Рубрики:
RAY PHOTOELECTRON-SPECTROSCOPY
   PHASE-TRANSITIONS
   CORE LEVELS
   SURFACE CHARACTERIZATION
   CRYSTAL-STRUCTURE
   CLEAVED SURFACE
   MIXED-VALENCE
   OXIDES
   MN
   MOLYBDENUM
   Chemical bondings
   Cubic phase
   Energy differences
   Heat capacity measurements
   Oxyfluorides
   Powder samples
   Solid-state synthesis
   Space Groups
   Temperature range
   Valence electron
   Binding energy
   Chemical bonds
   Electronic structure
   Fluorine compounds
   Magnetic properties
   Metal ions
   Photoelectrons
   Rietveld method
   X ray photoelectron spectroscopy
   Electronic properties
Аннотация: A powder sample of CsMnMoO3F3 oxyfluoride has been prepared by solid state synthesis. The pyrochlore-related crystal structure of CsMnMoO3F3 has been refined by the Rietveld method at T = 298 K (space group Fd-3m, a = 10.59141(4) angstrom, V = 1188.123(8) angstrom(3); R-B = 3.44%). The stability of the cubic phase has been obtained over the temperature range T = 110-293 K by heat capacity measurements. Magnetic properties have been measured over the range of T = 2-300 K. The electronic structure of CsMnMoO3F3 has been evaluated by X-ray photoelectron spectroscopy. Chemical bonding effects have been discussed for all metal ions using binding energy difference parameters and wide comparison with related oxides and fluorides. The competition between O-2(-) and F- ions for metal valence electrons has been found.

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Держатели документа:
Atuchin, Victor V.
Gavrilova, Tatyana A.
Kesler, Valery G.] SB RAS, Inst Semicond Phys, Novosibirsk 630090, Russia
Molokeev, Maxim S.
Yurkin, Gleb Yu.
Flerov, Igor N.
Patrin, Gennadii S.] SB RAS, Inst Phys, Krasnoyarsk 660036, Russia
Laptash, Natalia M.] FEB RAS, Inst Chem, Vladivostok 690022, Russia
Flerov, Igor N.
Patrin, Gennadii S.] Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660074, Russia

Доп.точки доступа:
Atuchin, V. V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Yurkin, G. Yu.; Юркин, Глеб Юрьевич; Gavrilova, T. A.; Kesler, V. G.; Laptash, N. M.; Flerov, I. N.; Флёров, Игорь Николаевич; Patrin, G. S.; Патрин, Геннадий Семёнович
}
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17.

    The electronic and optical properties of a narrow-band red-emitting nanophosphor K2NaGaF6:Mn4+ for warm white light-emitting diodes / C. Jiang [et al.] // J. Mater. Chem. C. - 2018. - Vol. 6, Is. 12. - P. 3016-3025, DOI 10.1039/c7tc05098d. - Cited References: 55. - We acknowledge the financial support received from the Program for Innovative Research Team in University of Ministry of Education of China (Grant No. IRT_17R38), the Key Program of Guangzhou Scientific Research Special Project (Grant No. 201607020009), the National Natural Science Foundation of China (Grant No. 51672085, 51322208, 3160440), and the Fundamental Research Funds for the Central Universities. M. G. Brik acknowledges the supports received from the Recruitment Program of High-end Foreign Experts (Grant No. GDW20145200225), the Programme for the Foreign Experts offered by Chongqing University of Posts and Telecommunications, Ministry of Education and Research of Estonia, (Project PUT430) and European Regional Development Fund (Project TK141), and the Guest Professorship at Kyoto University (Prof. S. Tanabe laboratory). The first-principles calculations were carried out using the resources provided by the Wroclaw centre for Networking and Supercomputing (http://wcss.pl; Grant No. WCSS#10117290). . - ISSN 2050-7534
   Перевод заглавия: Электронные и оптические свойства узкополосного нанолюминофора K2NaGaF6:Mn4+ , излучающего красный свет, для белых светодиодов излучающих теплый белый свет
Кл.слова (ненормированные):
Energy efficiency -- Gallium compounds -- Light emission -- Light emitting diodes -- Manganese -- Manganese compounds -- Optical properties -- Phosphors -- Precipitation (chemical) -- Quenching -- Rietveld refinement -- Sodium compounds
Аннотация: Recently, as a key red component in the development of warm white light-emitting diodes (WLEDs), Recently, as a key red component in the development of warm white light-emitting diodes (WLEDs), Mn4+-doped fluorides with narrow red emission have sparked rapidly growing interest because they improve color rendition and enhance the visual energy efficiency. Herein, a red nanophosphor, K2NaGaF6:Mn4+, with a diameter of 150-250 nm has been synthesized using a simple co-precipitation method. Rietveld refinement reveals that it crystallizes in the space group Fm3m with the cell parameter a = 8.25320(4) Å. The exchange charge model (ECM) has been used to calculate the energy levels of Mn4+ ions in K2NaGaF6, which match well with the experimental spectra. The as-synthesized phosphor exhibits a narrow red emission at around 630 nm (spin-forbidden 2Eg → 4A2 transition of Mn4+ ions) when excited at 365 nm (4A2g → 4T1g) and 467 nm (4A2g → 4T2g), with a quantum efficiency (QE) of 61% and good resistance to thermal quenching. Based on the structure, the formation mechanism of ZPL has been discussed. In addition, the concentration-dependent decay curves of Mn4+ in K2NaGaF6 were fitted using the Inokuti-Hirayama model, suggesting that the dipole-dipole interactions determine the concentration quenching. Finally, encouraged by the good performance, a warm LED with a CRI of 89.4 and CCT of 3779 K was fabricated by employing the title nanophosphor as the red component. Our findings suggest that K2NaGaF6:Mn4+ can be a viable candidate for the red phosphor used in warm WLEDs.

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Держатели документа:
China-Germany Research Center for Photonic Materials and Device, State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Engineering, South China University of Technology, Guangzhou, China
School of Applied Physics and Materials, Wuyi University Jiangmen, Guangdong, China
College of Mathematics and Physics, Chongqing University of Posts and Telecommunications, Chongqing, China
Institute of Physics, University of Tartu, W. Ostwald Str. 1, Tartu, Estonia
Institute of Physics, Jan Dlugosz University, Armii Krajowej 13/15, Cz?stochowa, Poland
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Department of Chemistry, Hong Kong Baptist University, Kowloon Tong, Hong Kong

Доп.точки доступа:
Jiang, C.; Brik, M. G.; Li, L.; Peng, J.; Wu, J.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Wong, K. -L.; Peng, M.
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18.

    Исследования твердых растворов состава Pb1-xBax(NO3)2 / К. Е. Коржнева [и др.] // Фундамент. пробл. совр. материаловед. - 2018. - Т. 15, № 3. - С. 360-365, DOI 10.25712/ASTU.1811-1416.2018.03.008. - Библиогр.: 13. - Работа выполнена в рамках государственного задания, проект № 0330 - 2016 - 0008 и при поддержке Российского фонда фундаментальных исследований (грант № 18-32-00359). . - ISSN 1811-1416
   Перевод заглавия: Studies of solid solutions of the composition Pb1-xBax(NO3)2
Кл.слова (ненормированные):
рост из водных растворов -- твердый раствор состава Pb1-xBax(NO3)2 -- рентгенофазовый анализ -- метод Ритвельда -- Crystal growth from aqueous solution -- solid solution ofPb1-xBax(NO3)2 -- powder X-ray diffraction analysis -- Rietveld method
Аннотация: При исследовании системы Pb(NO3)2–Ba(NO3)2–H2O впервые были получены соединения состава Pb0,75Ba0,25(NO3)2, Pb0,68Ba0,32(NO3)2, Ba0,58Pb0,42(NO3)2, Ba0,73Pb0,27(NO3)2. Кристаллы выращивались из водных растворов с разным соотношением Pb(NO3)2 к Ba(NO3)2. Во всех поставленных экспериментах рост осуществлялся путем медленного охлаждения со скоростью 1°С/сутки в диапазоне температур 75 – 45При исследовании системы Pb(NO3)2–Ba(NO3)2–H2O впервые были получены соединения состава Pb0,75Ba0,25(NO3)2, Pb0,68Ba0,32(NO3)2, Ba0,58Pb0,42(NO3)2, Ba0,73Pb0,27(NO3)2. Кристаллы выращивались из водных растворов с разным соотношением Pb(NO3)2 к Ba(NO3)2. Во всех поставленных экспериментах рост осуществлялся путем медленного охлаждения со скоростью 1При исследовании системы Pb(NO3)2–Ba(NO3)2–H2O впервые были получены соединения состава Pb0,75Ba0,25(NO3)2, Pb0,68Ba0,32(NO3)2, Ba0,58Pb0,42(NO3)2, Ba0,73Pb0,27(NO3)2. Кристаллы выращивались из водных растворов с разным соотношением Pb(NO3)2 к Ba(NO3)2. Во всех поставленных экспериментах рост осуществлялся путем медленного охлаждения со скоростью 1oС/сутки в диапазоне температур 75 – 45оС. С помощью рентгенофазового анализа на базе экспериментальных данных была построена часть фазовой диаграммы системы Pb(NO3)2–Ba(NO3)2–H2O и выделены поля кристаллизации Ba(NO3)2 и непрерывного ряда твердых растворов состава Pb1-xBax(NO3)2. Выращенные кристаллы исследовали с помощью рентгенофазового анализа, и для полученных рентгенограмм делали уточнение методом Ритвельда. Все пики на рентгенограммах были проиндексированы кубической центросимметричной структурой (Pa-3) с параметрами, близкими к Ba(NO3)2. При взаимодействии простых соединений нитрата свинца и бария образуется ряд твердых растворов с постепенным увеличением объема и параметров ячейки от чистого нитрата свинца к чистому нитрату бария. Данная структура также характеризуется одинаковым координационным числом катионов 12, разными ионными радиусами Pb 1.49, Ba 1.61, а также одним видом равностороннего NO3 треугольника с углами 60о и длинами связей от 2,1078 до 2,1597. Кристалл Pb0,68Ba0,32(NO3)2 прозрачен в диапазоне 0,304-3,5 микрон. Была проведена оценка ширины запрещенной зоны, которая составила 3,81 и 3,88 эВ при 300 и 80 К, соответственно.С/сутки в диапазоне температур 75 – 45°С. С помощью рентгенофазового анализа на базе экспериментальных данных была построена часть фазовой диаграммы системы Pb(NO3)2–Ba(NO3)2–H2O и выделены поля кристаллизации Ba(NO3)2 и непрерывного ряда твердых растворов состава Pb1-xBax(NO3)2. Выращенные кристаллы исследовали с помощью рентгенофазового анализа, и для полученных рентгенограмм делали уточнение методом Ритвельда. Все пики на рентгенограммах были проиндексированы кубической центросимметричной структурой (Pa-3) с параметрами, близкими к Ba(NO3)2. При взаимодействии простых соединений нитрата свинца и бария образуется ряд твердых растворов с постепенным увеличением объема и параметров ячейки от чистого нитрата свинца к чистому нитрату бария. Данная структура также характеризуется одинаковым координационным числом катионов 12, разными ионными радиусами Pb 1.49, Ba 1.61, а также одним видом равностороннего NO3 треугольника с углами 60° и длинами связей от 2,1078 до 2,1597. Кристалл Pb0,68Ba0,32(NO3)2 прозрачен в диапазоне 0,304-3,5 микрон. Была проведена оценка ширины запрещенной зоны, которая составила 3,81 и 3,88 эВ при 300 и 80 К, соответственно.С. С помощью рентгенофазового анализа на базе экспериментальных данных была построена часть фазовой диаграммы системы Pb(NO3)2–Ba(NO3)2–H2O и выделены поля кристаллизации Ba(NO3)2 и непрерывного ряда твердых растворов состава Pb1-xBax(NO3)2. Выращенные кристаллы исследовали с помощью рентгенофазового анализа, и для полученных рентгенограмм делали уточнение методом Ритвельда. Все пики на рентгенограммах были проиндексированы кубической центросимметричной структурой (Pa-3) с параметрами, близкими к Ba(NO3)2. При взаимодействии простых соединений нитрата свинца и бария образуется ряд твердых растворов с постепенным увеличением объема и параметров ячейки от чистого нитрата свинца к чистому нитрату бария. Данная структура также характеризуется одинаковым координационным числом катионов 12, разными ионными радиусами Pb 1.49, Ba 1.61, а также одним видом равностороннего NO3 треугольника с углами 60° и длинами связей от 2,1078 до 2,1597. Кристалл Pb0,68Ba0,32(NO3)2 прозрачен в диапазоне 0,304-3,5 микрон. Была проведена оценка ширины запрещенной зоны, которая составила 3,81 и 3,88 эВ при 300 и 80 К, соответственно.
During the present study of Pb(NO3)2-Ba(NO3)2-H2O system Pb0,75Ba0,25(NO3)2, Pb0,68Ba0,32(NO3)2, Ba0,58Pb0,42(NO3)2, Ba0,73Pb0,27(NO3)2 compounds were obtained for the first time. The crystals were grown from aqueous solutions with different ratios of Pb(NO3)2 to Ba(NO3)2. The growth was carried out by slow cooling at a rate of 1°/day in the temperature range of 75-45°C in all experiments. Using x-ray diffraction phase analysis part of Pb(NO3)2-Ba(NO3)2-H2O phase diagram was built and the crystallization fields of Ba(NO3)2 and a continuous series of Pb1-xBax(NO3)2 solid solutions were selected on the basis of the experimental data. The grown crystals were investigated by x-ray phase analysis and the obtained x-ray diffraction patterns were refined by the Rietveld method. All peaks in patterns were indexed by a cubic centrosymmetric structure (Pa-3) with parameters close to Ba(NO3)2. The interaction of simple compounds of lead and barium nitrates produces a number of solid solutions with a gradual increase in the volume and parameters of the unit cell from pure lead nitrate to pure barium nitrate. Their structure is characterized by the same coordination number (12) for cations with different radii: Pb2+ (1.49), Ba2+ (1.61), as well as one kind of equilateral NO3 triangle with angles of 60° and bond lengths from 2.1078 to 2.197 Å. Pb0,68Ba0,32(NO3)2 crystal is transparent in the range of 0,304-3,5 microns. The band gap was estimated as 3.81 and 3.88 eV at 300 and 80 K, respectively.

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Дальневосточный государственный университет путей сообщения
Институт геологии и минералогии им. В. С. Соболева СО РАН
Институт физики им. Л.В. Киренского СО РАН
Новосибирский государственный университет

Доп.точки доступа:
Коржнева, Ксения Евгеньевна; Korzhneva K. E.; Исаенко, Людмила Ивановна; Isaenko L. I.; Елисеев, Александр Павлович; Elisseev A. P.; Голошумова, Алина Александровна; Goloshumova A. A.; Тарасова, Александра Юрьевна; Tarasova A.Yu.; Молокеев, Максим Сергеевич; Molokeev, M. S.
}
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