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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Grishina, Svetlana, Kodera, Peter, Goryainov, Sergey, Oreshonkov A. S., Seryotkin, Yurii, Simko, Frantisek, Polozov, Alexander G.
Заглавие : Application of Raman spectroscopy for identification of rinneite (K3NaFeCl6) in inclusions in minerals
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-05-00682]; European Regional Development FundEuropean Union (EU) [ITMS 26240220086]; Vedecka Grantova Agentura MSVVaS SR a SAV [1/0313/20]
Место публикации : J. Raman Spectrosc. - 2020. - Vol. 51, Is. 12. - P.2505-2516. - ISSN 0377-0486, DOI 10.1002/jrs.6005. - ISSN 1097-4555(eISSN)
Примечания : Cited References: 55. - Russian Foundation for Basic Research, Grant/Award Numbers: 18-05-00682, 18-05-00682; European Regional Development Fund, Grant/Award Number: ITMS 26240220086; Vedecka Grantova Agentura MSVVaS SR a SAV, Grant/Award Number: 1/0313/20
Предметные рубрики: SALT MELT
IRON
DEPOSIT
FLUIDS
TRANSFORMATIONS
FERRIHYDRITE
Аннотация: Solid daughter phases in fluid and salt melt inclusions in minerals provide important clues to characterization of mineral‐forming processes. The analysis of the fluid inclusions often requires the exposure of the daughter minerals. Rinneite (K3NaFeCl6), which is a hygroscopic mineral, decomposes in air and cannot thus be identified by conventional methods. A combined approach has been applied for investigation of synthetic and natural rinneite to acquire its diagnostic Raman spectrum for a nondestructive identification. We used natural rinneite inclusions in halite, suitable for applying a complex of methods, to clear up the reference spectrum. Improved high‐resolution X‐ray diffraction (XRD) data obtained from natural rinneite inclusion are comparable with that of previously published, with similar unit cell dimensions. Polarized Raman spectra of natural inclusions were obtained using different geometries and polarization of the incident and scattered light. Interpretation of experimental Raman spectra was performed within the framework of lattice dynamics simulations and group analysis. Individual spectral bands are interpreted in terms of Raman‐active vibrational modes of K3NaFeCl6 structural units. Raman spectrum of synthetic rinneite with main peaks at 75, 91, 103, 143, 167, 171, 187, and 239 cm−1 agrees well with the spectra of rinneite inclusions in halite from the Nepa potash deposit and rinneite daughter minerals in salt melt inclusions hosted by quartz veinlets from the porphyry gold systems in the Central Slovakia Volcanic Field. This provides a firm basis for any future identification of this mineral worldwide, using nondestructive Raman spectroscopy.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Parshin A. M., Zyryanov V. Ya., Shabanov V. F., Nazarov V. G.
Заглавие : Bipolar-homogeneous structural phase transition in nematic droplets formed in the polymer matrix in a magnetic field
Место публикации : Crystallogr. Rep. - New York: Maik Nauka/Interperiodica/Springer, 2009. - Vol. 54, Is. 7. - С. 1191-1196. - DEC. - ISSN 1063-7745, DOI 10.1134/S1063774509070098
Примечания : Cited Reference Count: 19. - Гранты: This study was supported by the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools ( grant no. NSh-3818.2008.3), the Russian Foundation for Basic Research ( project no. 08-03-01007), the Presidium of the Russian Academy of Sciences ( project no. 27.1), and the Siberian Branch of the Russian Academy of Sciences ( project nos. 110 and 144).Финансирующая организация: President of the Russian Federation [NSh-3818.2008.3]; Russian Foundation for Basic Research [08-03-01007]; Russian Academy of Sciences [27.1, 110, 144]
Предметные рубрики: DISPERSED LIQUID-CRYSTALS
FRANK CONSTANTS
ALIGNMENT
Ключевые слова (''Своб.индексиров.''): bipolar configuration--bipolar structure--cyanobiphenyls--homogeneous structure--mutual transformations--nematic director--nematic droplets--order parameter--poly(vinyl butyral)--structural phase transition--temperature range--thermal fluctuations--crystal structure--drop formation--liquid crystals--magnetic fields--nematic liquid crystals--phase transitions
Аннотация: The phase transition from the bipolar structure to the homogeneous structure in droplets formed from the nematic liquid crystal 4-n-pentyl-4'-cyanobiphenyl in poly(vinyl butyral) in the presence of a magnetic field has been investigated. The phase transition is associated with the expansion of the regions with a tilted orientation of the director in the vicinity of defects (the disappearance of boojums) and with the alignment of the nematic director lines in the bulk of the droplet in the direction of the magnetic field. In the temperature range T = 24-34A degrees C, cyclic mutual transformations between the bipolar configuration of the nematic director and the homogeneous structure, which have a period of similar to 0.5-3.5 s and result from thermal fluctuations of the order parameter, are observed in droplets 3-15 A mu m in size after the forming field is switched off.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sadreev A. F., Berggren K. F.
Заглавие : Current statistics for wave transmission through an open Sinai billiard: Effects of net currents
Место публикации : Phys. Rev. E: AMER PHYSICAL SOC, 2004. - Vol. 70, Is. 2. - Ст.26201. - ISSN 1539-3755, DOI 10.1103/PhysRevE.70.026201
Примечания : Cited References: 27
Предметные рубрики: EIGENVECTOR STATISTICS
OPEN SYSTEMS
EIGENFUNCTIONS
CHAOS
FLUCTUATIONS
CROSSOVER
ELECTRONS
INTENSITY
Ключевые слова (''Своб.индексиров.''): acoustic wave transmission--boundary conditions--computer simulation--continuum mechanics--current density--fermi level--mathematical transformations--microwaves--probability density function--quantum theory--random processes--reverberation--statistical methods--surface waves--waveguides--microwave cavities--poynting vector--sinai billiard--wave functions--cavity resonators
Аннотация: Transport through quantum and microwave cavities is studied by analytic and numerical techniques. In particular, we consider the statistics for a finite net probability current (Poynting vector) j flowing through an open ballistic Sinai billiard to which two opposite leads/wave guides are attached. We show that if the net probability current is small, the scattering wave function inside the billiard is well approximated by a Gaussian random complex field. In this case, the current statistics are universal and obey simple analytic forms. For larger net currents, these forms still apply over several orders of magnitudes. However, small characteristic deviations appear in the tail regions. Although the focus is on electron and microwave billiards, the analysis is relevant also to other classical wave cavities as, for example, open planar acoustic reverberation rooms, elastic membranes, and water surface waves in irregularly shaped vessels.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Avramov P. V., Kuzubov A. A., Fedorov A. S., Sorokin P. B., Tomilin F. N., Maeda Y.
Заглавие : Density-functional theory study of the electronic structure of thin Si/SiO2 quantum nanodots and nanowires
Место публикации : Phys. Rev. B: AMERICAN PHYSICAL SOC, 2007. - Vol. 75, Is. 20. - Ст.205427. - ISSN 1098-0121, DOI 10.1103/PhysRevB.75.205427
Примечания : Cited References: 63
Предметные рубрики: ERBIUM ION LUMINESCENCE
TOTAL-ENERGY CALCULATIONS
WAVE BASIS-SET
POROUS SILICON
OPTICAL-PROPERTIES
OXIDIZED SI
SEMICONDUCTOR NANOWIRES
PHASE-TRANSFORMATIONS
NANOCRYSTALS
CONFINEMENT
Аннотация: The atomic and electronic structures of a set of proposed pentagonal thin (1.6 nm in diameter) silicon/silica quantum nanodots (QDs) and nanowires (NWs) with narrow interface, as well as parent metastable silicon structures (1.2 nm in diameter), were studied using cluster B3LYP/6-31G(*) and periodic boundary condition (PBC) plane-wave (PW) pseudopotential (PP) local-density approximation methods. The total density of states (TDOS) of the smallest quasispherical QD (Si-85) corresponds well to the PBC PW PP LDA TDOS of the crystalline silicon. The elongated SiQDs and SiNWs demonstrate the metallic nature of the electronic structure. The surface oxidized layer opens the band gap in the TDOS of the Si/SiO2 species. The top of the valence band and the bottom of conduction band of the particles are formed by the silicon core derived states. The theoretical band gap width is determined by the length of the Si/SiO2 clusters and describes the size confinement effect in the experimental photoluminescence spectra of the silica embedded nanocrystalline silicon with high accuracy.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : POLSKII A. I., VERSHININ V. V., YAKOVCHUK V. Y.
Заглавие : DIRECT AND REVERSE TRANSFORMATIONS OF THE SURFACE ACOUSTIC-WAVES, USING PERIODIC MAGNETIC-STRUCTURES
Место публикации : Zhurnal Tek. Fiz.: MEZHDUNARODNAYA KNIGA, 1980. - Vol. 50, Is. 10. - P2236-2238. - ISSN 0044-4642
Примечания : Cited References: 4
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6.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sutormin V. S., Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Director transformations within nematic droplets dispersed in polyvinylpirrolydon induced by temperature and moisture
Коллективы : IInternational LC Conference
Место публикации : 22nd International LC Conference: Abstracts. - 2008. - Vol. 1. - P.378
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Udod L. V., Sitnicov M. N., Aplesnin S. S., Molokeev M. S.
Заглавие : Electrical and dielectrical propeties of gas-sensor resistive type Bi2Sn2O7
Коллективы : Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации : Solid State Phenom.: Selected, peer reviewed papers/ ed.: S. G. Ovchinnikov, A. Samardak: Trans Tech Publications, 2014. - Vol. 215: Trends in Magnetism: Nanomagnetism (EASTMAG-2013). - P.503-506. - ISSN 978-303835054-5, DOI 10.4028/www.scientific.net/SSP.215.503. - ISSN 1662-9779
Примечания : Cited References: 14. - This work was supported by the Russian Foundation for Basic Research projects no. 12-02-00125-а
Ключевые слова (''Своб.индексиров.''): crystallographic structure--polymorphic transformations--electrical resistivity--dielectric permeability
Аннотация: Polycrystalline samples of Bi2Sn2O7 have been synthesized by conventional solid-state reaction method. According to the X-ray powder diffraction research, our sample co-existing of two polymorphs phases: cubic and rhombic, concurrently. The real dielectric permeability Re (ε) monotonic grows versus temperature and the imaginary dielectric permeability Im (ε) nonmonotonic is increased at the heating. There are maxima at Т=450 K on both temperature dependences Im (ε) and Re (ε) reveal. Anomalies in the temperature dependence of electrical resistivity at temperatures are found and to be correlated with the α → β structural phase transition temperature.
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8.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Sutormin V. S., Timofeev I. V., Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Electrically controlled transformations of cholesteric structure initiated by the ionic modification of surface anchoring
Коллективы : International Liquid Crystal Conference
Место публикации : Abstracts of 27th International Liquid Crystal Conference (ILCC 2018). - 2018. - Ст.P4-C0-12
Примечания : Cited References: 3
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kostikov D. A., Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Electrically induced structural transformations of a chiral nematic under tangential-conical boundary conditions
Колич.характеристики :10 с
Место публикации : Molecules. - 2023. - Vol. 28, Is. 23. - Ст.7842. - ISSN 14203049 (eISSN), DOI 10.3390/molecules28237842
Примечания : Cited References: 30
Аннотация: In this study, structural transformations induced by an electric field in the chiral nematic under tangential-conical boundary conditions have been considered. The composition influence of the orienting polymer films on the director tilt angles, the formation of orientational structures in the LC layer, as well as the electro-optical response and relaxation processes have been studied. It has been shown that the poly(tert-butyl methacrylate) concentration change in the orienting polymer mixture allows for smoothly controlling the director tilt angle without fixing its azimuthal orientation rigidly.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Prishchepa O. O., Sutormin V. S., Bikbaev R. G., Timofeev I. V., Zyryanov V. Ya.
Заглавие : Electrically induced transformations of defects in cholesteric layer with tangential-conical boundary conditions
Место публикации : Sci. Rep. - 2020. - Vol. 10, Is. 1. - Ст.4907. - ISSN 20452322 (ISSN), DOI 10.1038/s41598-020-61713-9
Примечания : Cited References: 45. - The authors are grateful for the financial support by the Russian Science Foundation (Grant No. 18-72-10036)
Аннотация: Electric-field-induced changes of the orientational structures of cholesteric liquid crystal layer with the tangential-conical boundary conditions have been investigated. The samples with the ratio of the cholesteric layer thickness d to the helix pitch p equalled to 0.57 have been considered. The perpendicularly applied electric field causes a decrease of the azimuthal director angle at the substrate with the conical surface anchoring. In the cells with d = 22 μm, the defect loops having the under-twisted and over-twisted areas are formed. At the defect loop the pair of point peculiarities is observed where the 180° jump of azimuthal angle of the director occurs. Under the action of electric field the loops shrink and disappear. In the cells with d = 13 μm, the over-twisted and under-twisted defect lines are formed. Applied voltage results in the shortening of lines or/and their transformation into a defect of the third type. The director field distribution near defect lines of three types has been investigated by the polarising microscopy techniques. It has been revealed that the length ratio between the over-twisted and third-type defect lines can be controlled by the electric field.
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