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ACOUSTIC PROPERTIES OF TERBIUM FERRITE-GARNET AT LOW-TEMPERATURES / O. P. KVASHNINA [и др.] // Fiz. Tverd. Tela. - 1984. - Vol. 26, Is. 8. - P. 2408-2410. - Cited References: 5 . - ISSN 0367-3294

РУБ Physics, Condensed Matter

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Доп.точки доступа:
KVASHNINA, O. P.; KAPITONOV, A. M.; SMOKOTIN, E. M.; TITOVA, A. G.
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Complex magnetic order in the Nd(Tb)Fe3(BO3)4 multiferroic revealed by single-crystal neutron diffraction / I. V. Golosovsky [et al.] // Phys. Rev. B. - 2019. - Vol. 99, Is. 13. - Ст. 134439, DOI 10.1103/PhysRevB.99.134439. - Cited References: 33. - This work was supported by the Russian Grant No. RFBR 16-02-00058. A.A.M. acknowledges the financial support from the Russian Science Foundation (16-12-10531). . - ISSN 2469-9950
Кл.слова (ненормированные):
Antiferromagnetism -- Binary alloys -- Crystal structure -- Crystallography -- Magnetic structure -- Neodymium compounds -- Neutron diffraction -- Single crystals -- Terbium compounds
Аннотация: Magnetic structure of the substituted multiferroics-ferroborates Nd0.9Tb0.1Fe3(BO3)4 and Nd0.8Tb0.2Fe3(BO3)4 were determined in the framework of a self-consistent refinement of the single crystal neutron diffraction data. The small substitution of Nd for Tb leads to the reorientation of the main antiferromagnetic vector L from the basal plane towards the hexagonal axis. The reorientation takes place via an angular structure for which L does not coincide with the principal crystallographic directions and evolves with temperature due to competing magnetic anisotropies of Fe, Nd, and Tb subsystems. Our refinement at 2 K reveals the existence of distortions in the collinear antiferromagnetic Fe spin arrangement suggested before in other ferroborates. Therefore, besides the main antiferromagnetic vector L, the magnetic structure involves additional fine symmetrized combinations of spin components allowed by symmetry. They coexist with certain L components and could originate from the antisymmetric Dzyaloshinsky-Moriya Fe-Fe exchange interactions. At higher temperatures, the magnetic structure is described by the simple collinear model, where the L vector is deviated from the hexagonal plane. © 2019 American Physical Society.

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Держатели документа:
National Research Center, Kurchatov Institute, B.P. Konstantinov Petersburg Nuclear Physics Institute, Gatchina, 188300, Russian Federation
Prokhorov General Physics Institute, RAS, Moscow, 119991, Russian Federation
Universite Grenoble Alpes, CEA, INAC-MEM, Grenoble, 38000, France
Institucio Catalana de Recerca i Estudis Avancats, Barcelona, E-08010, Spain
Fisika Aplikatua II, Zientzia Eta Teknologia Fakultatea, Universidad Del Pais Vasco, UPV/EHU, Bilbao, 48940, Spain
Kirenskii Institute of Physics, Siberian Division of RAS, Krasnoyarsk, 660038, Russian Federation

Доп.точки доступа:
Golosovsky, I. V.; Vasilev, A. I.; Mukhin, A. A.; Ressouche, E.; Skumryev, V.; Urcelay-Olabarria, I.; Gudim, I. A.; Гудим, Ирина Анатольевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
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High-temperature magnetoelectricity of terbium aluminum borate: The role of excited states of the rare-earth ion / A. M. Kadomtseva [et al.] // Phys. Rev. B. - 2014. - Vol. 89, Is. 1. - Ст. 014418, DOI 10.1103/PhysRevB.89.014418. - Cited References: 25. - We thank Dr. Daniel Sando for useful comments and remarks. This work is supported by the Russian Foundation for Basic Research (Projects No. 13-02-01093, No. 13-02-12443, No. 13-02-01093, No. 12-02-01261, and No. 13-02-12442) and a grant from the Russian Federation President on support of sciences schools no. 4828.2012.2, The Ministry of Education and Science of Russian Federation, Project No. 8365. . - ISSN 1098-0121. - ISSN 1550-235X

РУБ Physics, Condensed Matter
Рубрики:
GROUND-STATE
PRFE3(BO3)4
MULTIFERROICS
Аннотация: Recently discovered magnetoelectricity in the rare-earth aluminum borates RAl3(BO3)4 has attracted attention due to the large values of magnetoinduced electric polarization. We have observed for the first time the magnetoelectric polarization in TbAl3(BO3)4 exhibiting anomalous temperature dependence: an electric polarization induced by in-plane magnetic field (P||a,H⊥c axis) which is small at low temperatures (4K), remarkably increases by almost an order of magnitude at high temperatures (150–300K). The observed nonmonotonic temperature behavior of the field-induced polarization, including a change of sign at ∼65–70K, is attributed to the competition of the ground and excited crystal-field states of Tb3+ ions. Quantum theory analysis, involving the combination of analytical and numerical methods, has enabled us to quantitatively describe the observed magnetic and magnetoelectric properties of TbAl3(BO3)4.
Недавно обнаруженное магнетоэлектричество в редкоземельных алюмоборатах RAl3 (BO3) 4 привлекло к себе внимание из-за больших значений магнитоиндуцированной электрической поляризации. Мы наблюдали в первый раз магнитоэлектрическую поляризацию в TbAl3 (BO3) 4, показывающую аномальную температурную зависимость: электрическая поляризация индуцируется в плоскости магнитного поля (Р | |, Н ⊥ оси с), и является небольшой при низких температурах (4K), Значительно увеличивается, почти на порядок величины, при высоких температурах (150-300 К). Наблюдаемая с изменением температуры немонотонность поляризации от поля, в том числе изменению знака на ~ 65-70 К, может быть отнесена к конкуренции между основном и возбужденном кристаллическим полем состояниями ионов ТЬ3 +. Теория квантового анализа, предполагающей сочетание аналитических и численных методов, позволила нам количественно описать наблюдаемые магнитные и магнитоэлектрические свойства TbAl3 (BO3) 4.

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Держатели документа:
Moscow MV Lomonosov State Univ, MSU, Dept Phys, Moscow 119992, Russia
Russian Acad Sci, Prokhorov Gen Phys Inst, Moscow, Russia
State Univ, Moscow Inst Phys & Technol, Moscow, Russia
Natl Res Univ Elect Technol MIET, Zelenograd, Russia
RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Kadomtseva, A. M.; Popov, Y. F.; Vorob'ev, G. P.; Kostyuchenko, N. V.; Popov, A. I.; Mukhin, A. A.; Ivanov, V. Y.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович; Pyatakov, A. P.; Zvezdin, A. K.; Russian Foundation for Basic Research [13-02-12443, 13-02-01093, 12-02-01261, 13-02-12442]; Russian Federation President on support of sciences schools [4828.2012.2]; Ministry of Education and Science of Russian Federation [8365]
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Incorporating rare-earth terbium(III) ions into Cs2AgInCl6:Bi nanocrystals toward tunable photoluminescence / Y. Liu, X. M. Rong, M. Z. Li [et al.] // Angew. Chem. - 2020. - Vol. 132, Is. 28. - P. 11731-11737, DOI 10.1002/ange.202004562. - Cited References: 43 . - ISSN 1521-3757

РУБ Chemistry, Multidisciplinary
Рубрики:
HALIDE DOUBLE PEROVSKITE
   LEAD-FREE
   LANTHANIDE
   STABILITY
   EMISSION
Кл.слова (ненормированные):
doping -- energy transfer -- perovskite nanocrystals -- photoluminescence -- terbium
Аннотация: The incorporation of impurity ions or doping is a promising method for controlling the electronic and optical properties and the structural stability of halide perovskite nanocrystals (NCs). Herein, we establish relationships between rare‐earth ions doping and intrinsic emission of lead‐free double perovskite Cs2AgInCl6 NCs to impart and tune the optical performances in the visible light region. Tb3+ ions were incorporated into Cs2AgInCl6 NCs and occupied In3+ sites as verified by both crystallographic analyses and first‐principles calculations. Trace amounts of Bi doping endowed the characteristic emission (5D4→7F6‐3) of Tb3+ ions with a new excitation peak at 368 nm rather than the single characteristic excitation at 290 nm of Tb3+. By controlling Tb3+ ions concentration, the emission colors of Bi‐doped Cs2Ag(In1−xTbx)Cl6 NCs could be continuously tuned from green to orange, through the efficient energy‐transfer channel from self‐trapped excitons to Tb3+ ions. Our study provides the salient features of the material design of lead‐free perovskite NCs and to expand their luminescence applications.

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Держатели документа:
Univ Sci, Sch Materials Sciences, Beijing Municipal Key Lab New Energy Materials, Technology Beijing,Technologies,Engn, Beijing, P. R. China.
Shenzhen Univ, Coll Materials Sci, Guangdong Res Ctr Interfacial Engn Functional Mat, Shenzhen Key Lab Special Functional Materials, Shenzhen, P. R. China.
Kirensky Inst Phys, Fed Res Ctr KSC SB RASs, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Engn Phys, Radioelectronics, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
S China Univ Technology, Sch Materials Sci, State Key Lab Luminescent Materials, Guangdong Prov Key Lab Fiber Laser Materials, Guangzhou, P. R. China.

Доп.точки доступа:
Liu, Ying; Rong, Ximing; Li, Mingze; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhao, Jing; Xia, Zhiguo
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    Incorporating rare-earth terbium(III) Ions into Cs2AgInCl6:Bi nanocrystals toward tunable photoluminescence / Y. Liu, X. M. Rong, M. Z. Li [et al.] // Angew. Chem. - Int. Edit. - 2020. - Vol. 59, Is. 28. - P. 11634-11640, DOI 10.1002/anie.202004562. - Cited References: 43. - This work is supported by the National Natural Science Foundation of China (51961145101, 51972118 and 51722202), Fundamental Research Funds for the Central Universities (FRFTP-18-002C1), Guangdong Provincial Science & Technology Project (2018A050506004) and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01X137). This work is also funded by RFBR according to the research project No. 19-52-80003. . - ISSN 1433-7851. - ISSN 1521-3773
   Перевод заглавия: Включение редкоземельного тербия (III) в нанокристаллы Cs2AgInCl6: Bi для перестраиваемой фотолюминесценции

РУБ Chemistry, Multidisciplinary
Рубрики:
HALIDE DOUBLE PEROVSKITE
   LEAD-FREE
   LANTHANIDE
   STABILITY
   EMISSION
Кл.слова (ненормированные):
doping -- energy transfer -- perovskite nanocrystals -- photoluminescence -- terbium
Аннотация: The incorporation of impurity ions or doping is a promising method for controlling the electronic and optical properties and the structural stability of halide perovskite nanocrystals (NCs). Herein, we establish relationships between rare‐earth ions doping and intrinsic emission of lead‐free double perovskite Cs2AgInCl6 NCs to impart and tune the optical performances in the visible light region. Tb3+ ions were incorporated into Cs2AgInCl6 NCs and occupied In3+ sites as verified by both crystallographic analyses and first‐principles calculations. Trace amounts of Bi doping endowed the characteristic emission (5D4→7F6‐3) of Tb3+ ions with a new excitation peak at 368 nm rather than the single characteristic excitation at 290 nm of Tb3+. By controlling Tb3+ ions concentration, the emission colors of Bi‐doped Cs2Ag(In1−x Tbx )Cl6 NCs could be continuously tuned from green to orange, through the efficient energy‐transfer channel from self‐trapped excitons to Tb3+ ions. Our study provides the salient features of the material design of lead‐free perovskite NCs and to expand their luminescence applications.

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Держатели документа:
Univ Sci & Technol Beijing, Beijing Municipal Key Lab New Energy Mat & Techno, Sch Mat Sci & Engn, Beijing 100083, Peoples R China.
Shenzhen Univ, Shenzhen Key Lab Special Funct Mat, Shenzhen Engn Lab Adv Technol Ceram, Guangdong Res Ctr Interfacial Engn Funct Mat,Coll, Shenzhen 518060, Peoples R China.
Fed Res Ctr KSC SB RASs, Lab Crystal Phys, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Engn Phys & Radioelect, Krasnoyarsk 660041, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangdong Prov Key Lab Fiber Laser Mat & Appl Tec, Sch Mat Sci & Technol, Guangzhou 510641, Peoples R China.

Доп.точки доступа:
Liu, Ying; Rong, Ximing; Li, Mingze; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhao, Jing; Xia, Zhiguo
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IR spectroscopy of the low-frequency phonon spectrum of the TbFe3(BO3)(4) single-crystal / V. S. Kurnosov [et al.] // Low Temp. Phys. - 2014. - Vol. 40, Is. 12. - P. 1087-1096, DOI 10.1063/1.4904002. - Cited References:27 . - ISSN 1063. - ISSN 1090-6517. -

РУБ Physics, Applied
Рубрики:
EARTH FERROBORATES RFe3(BO3)4
RAMAN-SCATTERING
TERBIUM FERROBORATE
Аннотация: A study of the IR reflectance spectra of the TbFe3(BO3)4 crystal. We determined the frequencies of the polar lattice phonons in the high-temperature R32, and low- temperature P3121, phases. All 8A 2 ⊕ 11E-modes were found in the high-temperature phase, with nine of them corresponding to lines of the absorption spectrum. In the low-temperature phase, of the 20A 2 ⊕ 35E-modes allowed by the symmetry of the crystal lattice, 20A 2 ⊕ 25E-modes were found.

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Публикация на русском языке ИК спектроскопия низкочастотного фононного спектра монокристалла TbFe3(BO3)4 [Текст] / В. С. Курносов [и др.] // Физ. низких температур : Физико-технический институт низких температур им. Б.И. Веркина НАН Украины, 2014. - Т. 40 Вып. 12. - С. 1397-1408

Держатели документа:
Natl Acad Sci Ukraine, B Verkin Inst Low Temp Phys & Engn, UA-61103 Kharkov, Ukraine.
Russian Acad Sci, Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Kurnosov, V. S.; Tsapenko, V. V.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна
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Magnetic and magnetoelectric properties of terbium aluminum borate / A. M. Kadomtseva [et al.] // Bull. Russ. Acad. Sci. Phys. - 2014. - Vol. 78, Is. 2. - P. 97-99, DOI 10.3103/S1062873814020142. - Cited References: 9. - This work was supported by the Russian Foundation for Basic Research, projects nos. 13-02-01093 and 12-02-01261. . - ISSN 1062-8738. - ISSN 1934-9432
Кл.слова (ненормированные):
Aluminum -- Terbium -- Aluminum borate -- Magnetoelectric properties -- Rare earth ions -- Temperature dependence -- Terbium compounds
Аннотация: The magnetic and magnetoelectric properties of terbium aluminum borate are studied. It is established that temperature dependences of the magnetoelectric effects of terbium aluminum borate are analogous to those of terbium ferroborate, despite the difference in effective magnetic fields acting on rare-earth ions in these compounds. This confirms the general assumption on the decisive role of the rare-earth element in the magnetoelectric properties of borates. © 2014 Allerton Press, Inc.

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Публикация на русском языке Магнитные и магнитоэлектрические свойства алюмобората тербия [Текст] / А. М. Кадомцева [и др.] // Изв. РАН. Сер. физич. - 2014. - Т. 78 № 2. - С. 165-167

Держатели документа:
Faculty of Physics, Moscow State University, Moscow 119992, Russian Federation
Prokhorov General Physics Institute, Russian Academy of Sciences, Moscow 119991, Russian Federation
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, 660036, Russian Federation

Доп.точки доступа:
Kadomtseva, A. M.; Кадомцева А.М.; Popov, Yu. F.; Попов Ю. Ф.; Vorob'ev, G. P.; Воробьев Г. П.; Pyatakov, A. P.; Пятаков А.П.; Zvezdin, A. K.; Звездин А. К.; Mukhin, A. A.; Мухин А. А.; Ivanov, V. Yu.; Иванов В. Ю.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович
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Magnetic anisotropy and magnetoelectric properties of Tb1-x Er (x) Fe-3(BO3)(4) ferroborates / A. K. Zvezdin [et al.] // J. Exp. Theor. Phys. - 2009. - Vol. 109, Is. 1. - P. 68-73, DOI 10.1134/S1063776109070097. - Cited References: 18. - This study was supported by the Russian Foundation for Basic Research (project no. 07-02-00580). . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
GDFE3(BO3)(4)
Кл.слова (ненормированные):
Competing exchange -- Complex compositions -- Critical fields -- Electric polarization -- Er concentrations -- Exchange splitting -- Ferroborates -- G factors -- Magnetoelectric properties -- Nonmonotonic -- Simple model -- Spin-flop transitions -- Composite micromechanics -- Erbium -- Ions -- Magnetic anisotropy -- Magnetostriction -- Magnetostrictive devices -- Phase transitions -- Polarization -- Spin dynamics -- Terbium alloys -- Single crystals
Аннотация: Magnetic and magnetoelectric properties of ferroborate single crystals with complex composition (Tb1 - x Er (x) Fe-3(BO3)(4), x = 0, 0.75) and with competing exchange Tb-Fe and Er-Fe interactions are investigated. Jumps in electric polarization, magnetostriction, and magnetization are observed as a result of spin-flop transitions, as well as a considerable decrease in the critical field upon an increase in the Er concentration, in a field H (c) parallel to the c axis. The observed behavior of phase-transition fields is analyzed and explained using a simple model taking into account anisotropy in g factors and exchange splitting of funda-mental doublets of the easy-axis Tb3+ ion and easy-plane Er3+ ion. It is established that magnetoelectric and magnetostriction anomalies under spin-flop transitions are mainly controlled by the Tb subsystem. The Tb subsystem makes a nonmonotonic contribution Delta P (a) (H (a) , T) to polarization along the a axis: the value of Delta P (a) reverses its sign and increases with temperature due to the contribution from the excited states of the Tb3+ ion.

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Держатели документа:
[Zvezdin, A. K.
Pyatakov, A. P.
Ivanov, V. Yu.
Kuz'menko, A. M.
Mukhin, A. A.] Russian Acad Sci, Prokhorov Inst Gen Phys, Moscow 119991, Russia
[Kadomtseva, A. M.
Popov, Yu. F.
Vorob'ev, G. P.
Pyatakov, A. P.] Moscow MV Lomonosov State Univ, Moscow 119992, Russia
[Bezmaternykh, L. N.
Gudim, I. A.] Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660038, Russia
ИФ СО РАН
Moscow State University, Moscow 119992, Russian Federation
Prokhorov Institute of General Physics, Russian Academy of Sciences, Moscow 119991, Russian Federation
Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk 660038, Russian Federation

Доп.точки доступа:
Zvezdin, A. K.; Kadomtseva, A. M.; Popov, Y. F.; Vorob'ev, G. P.; Pyatakov, A. P.; Ivanov, V. Y.; Kuz'menko, A. M.; Mukhin, A. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Russian Foundation for Basic Research [07-02-00580]
}
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Magnetic structure and magnetic interactions in terbium iron borate TbFe3(BO3)4 / A. M. Vorotynov [et al.] // Workshop INTAS - Sib. Branch of the RAS Sci. Cooperation on the Res. Project “New Layered 3d-Materials for Spintronics” / chairman G. A. Petrakovskii. - 2007. - P. 13
Аннотация: INTAS (The International Association for the Promotion of Cooperation with Scientists from the New Independent States of the Former Soviet Union) — международная ассоциация по содействию сотрудничеству с учёными новых независимых государств бывшего Советского Союза. Некоммерческая организация, финансировалась главным образом из бюджета Европейского Союза. Являлась крупнейшим фондом, поддерживающим научное сотрудничество между учёными стран бывшего СССР и Европейского Союза с 1993 г. Программы INTAS охватывали широкий круг научно-исследовательских проблем. 22 сентября 2006 года было принято решение о прекращении осуществления программы на основании рекомендации Европейской Комиссии. С 1 апреля 2007 года прекратилось распределение новых грантов.

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Доп.точки доступа:
Petrakovskii, G. A. \chairman\; Петраковский, Герман Антонович; Vorotynov, A. M.; Воротынов, Александр Михайлович; Ritter, C.; Petrakovskii, G. A.; Balaev, A. D.; Балаев, Александр Дмитриевич; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; "New Layered 3d-Materials for Spintronics", Workshop INTAS - Siberian Branch of the Russian Academy of Sciences Scientific Cooperation on the Research Project(2007 ; March 20-23 ; Krasnoyarsk)
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10.

Magnetic structure and magnetic interactions in terbium iron borate TbFe3(BO3)4 / A. Vorotynov, C. Ritter [и др.] // Workshop INTAS - Siberian Branch of the Russian Academy of Sciences Scientific Cooperation on the Research Project "New Layered 3d-Materials for Spintronics" : (books of abstrats) : March 20-23, 2007 Krasnoyarsk, Russia. - Красноярск, 2007. - P. 13

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Доп.точки доступа:
Vorotynov, A. M.; Воротынов, Александр, Михайлович; Ritter, C.; Petrakovskii, G. A.; Петраковский, Герман Антонович; Balaev, A. D.; Балаев, Александр Дмитриевич; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина, Анатольевна; "New Layered 3d-Materials for Spintronics", Workshop INTAS - Siberian Branch of the Russian Academy of Sciences Scientific Cooperation on the Research Project(2007 ; Marh ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН; ETH Zurich and Paul Scherrer Institute, Condensed Matter Research with Neutron and Muons Department; Institute of Physics of Polish Academy of Sciences; Институт неорганической химии им. А.В.Николаева СО РАН
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