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Analysis of the structure and magnetic properties of an interface in multilayered (Fe/Si) N nanostructures with the surface-sensitive XMCD method / M. S. Platunov [et al.] // JETP Letters. - 2014. - Vol. 99, Is. 12. - P. 706-711, DOI 10.1134/S002136401412011X. - Cited References: 26. - We are grateful to S.V. Komogortsev for stimulating discussions and to the management of BESSY II, Helmholtz-Zentrum Berlin, for the opportunity of performing experiments at the UE46-PGM1 beamline. This work was supported by the Russian Foundation for Basic Research (project nos. 13-02-01265a and 14-02-31051mol-a), by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (project no. NSh- 2886.2014.2), by the Presidium of the Russian Academy of Sciences (program no. 24.34), and by the Ministry of Education and Science of the Russian Federation (state contract no. 02.G25.31.0043 and state task for research at Siberian Federal University in 2014). . - ISSN 0021-3640. - ISSN 1090-6487

РУБ Physics, Multidisciplinary
Рубрики:
RAY CIRCULAR-DICHROISM
   YIELD
   SPECTRA
   Fe
Аннотация: The structural and magnetic properties of (Fe/Si) N nanostructures obtained by successive deposition on the SiO2/Si(100) surface at a temperature of the substrate of 300 K have been studied. The thicknesses of all Fe and Si layers have been determined by transmission electron microscopy measurements. The magnetic properties have been studied by the X-ray magnetic circular dichroism (XMCD) method near the Fe L 3, 2 absorption edges. The orbital (m l ) and spin (m S ) contributions to the total magnetic moment of iron have been separated. The thicknesses of magnetic and nonmagnetic iron silicide on the Si/Fe and Fe/Si interfaces have been determined with the surface sensitivity of the XMCD method and the model of the interface between the nonmagnetic and weakened magnetic phases.

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Публикация на русском языке Анализ структуры и магнитных свойств интерфейса в многослойных наноструктурах (Fe/Si)N с применением поверхностно-чувствительного метода XMCD [Текст] / М. С. Платунов [и др.] // Письма в Журн. эксперим. и теор. физ. - 2014. - Т. 99 Вып. 11-12. - С. 817-823

Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Helmholtz Zentrum Berlin, BESSY II, D-12489 Berlin, Germany

Доп.точки доступа:
Platunov, M. S.; Платунов, Михаил Сергеевич; Varnakov, S. N.; Варнаков, Сергей Николаевич; Zharkov, S. M.; Жарков, Сергей Михайлович; Bondarenko, G. V.; Бондаренко, Геннадий Васильевич; Weschke, E.; Schierle, E.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Foundation for Basic Research [13-02-01265a, 14-02-31051mol-a]; Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools [NSh- 2886.2014.2]; Presidium of the Russian Academy of Sciences [24.34]; Ministry of Education and Science of the Russian Federation [02.G25.31.0043]
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Competing magnetic states in silicene and germanene 2D ferromagnets / D. V. Averyanov, I. S. Sokolov, M. S. Platunov [et al.] // Nano Res. - 2020. - Vol. 13, Is. 12. - P. 3396-3402, DOI 10.1007/s12274-020-3027-y. - Cited References: 58. - This work was supported by National Research Center (NRC) "Kurchatov Institute" (No. 1359, characterization) and the Russian Science Foundation (No. 19-19-00009 (synthesis) and No. 20-79-10028 (magnetization measurements)). D. V. A. also acknowledges support from the President's scholarship (SP 1398.2019.5). The measurements have been carried out using equipment of the resource centers of electrophysical and electron microscopy techniques in NRC "Kurchatov Institute" . - ISSN 1998-0124. - ISSN 1998-0000

РУБ Chemistry, Physical + Nanoscience & Nanotechnology + Materials Science,
Рубрики:
RAY CIRCULAR-DICHROISM
ABSORPTION
Кл.слова (ненормированные):
silicene -- germanene -- 2D ferromagnetism -- X-ray magnetic circular dichroism (XMCD) -- monolayer
Аннотация: Two-dimension (2D) magnets have recently developed into a class of stoichiometric materials with prospective applications in ultra-compact spintronics and quantum computing. Their functionality is particularly rich when different magnetic orders are competing in the same material. Metalloxenes REX2 (RE = Eu, Gd; X = Si, Ge), silicene or germanene — heavy counterparts of graphene — coupled with a layer of rare-earth metals, evolve from three-dimension (3D) antiferromagnets in multilayer structures to 2D ferromagnets in a few monolayers. This evolution, however, does not lead to fully saturated 2D ferromagnetism, pointing at a possibility of coexisting/competing magnetic states. Here, REX2 magnetism is explored with element-selective X-ray magnetic circular dichroism (XMCD). The measurements are carried out for GdSi2, EuSi2, GdGe2, and EuGe2 of different thicknesses down to 1 monolayer employing K absorption edges of Si and Ge as well as M and L edges of the rare-earths. They access the magnetic state in REX2 and determine the seat of magnetism, orbital, and spin contributions to the magnetic moment. High-field measurements probe remnants of the bulk antiferromagnetism in 2D REX2. The results provide a new platform for studies of complex magnetic structures in 2D materials.

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Держатели документа:
Natl Res Ctr Kurchatov Inst, Kurchatov Sq 1, Moscow 123182, Russia.
ESRF European Synchrotron, CS 40220, F-38043 Grenoble 9, France.
ALBA Synchrotron Light Source, Barcelona 08290, Spain.
LOrme Merisiers, Synchrotron SOLEIL, F-91192 Gyf Sur Yvette, France.
RAS, Kirensky Inst Phys, Fed Res Ctr KSC SB, Akad Gorodok 50,Bld 38, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Averyanov, D. V.; Sokolov, Ivan S.; Platunov, M. S.; Платунов, Михаил Сергеевич; Wilhelm, Fabrice; Rogalev, Andrei; Gargiani, Pierluigi; Valvidares, Manuel; Jaouen, Nicolas; Parfenov, Oleg E.; Taldenkov, Alexander N.; Karateev, Igor A.; Tokmachev, Andrey M.; Storchak, V. G.
}
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Crystal growth, structure, magnetic properties and theoretical exchange interaction calculations of Cu2MnBO5 / S. Sofronova [et al.] // J. Magn. Magn. Mater. - 2016. - Vol. 420. - P. 309-316, DOI 10.1016/j.jmmm.2016.07.019. - Cited References: 35. - X-ray diffraction experiment was carried out at the Centre on Molecular Design and Ecologically Safe Technologies at the Novosibirsk State University. The reported study was funded by Russian Foundation for Basic Research (RFBR) and Government of Krasnoyarsk Territory according to the research project No. 16-42-243028. . - ISSN 0304-8853

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
SPIN-GLASS BEHAVIOR
   SINGLE-CRYSTALS
   SUPEREXCHANGE INTERACTIONS
   LUDWIGITE
   DIELECTRICS
   CO3B2O6NI3B2O6
   WARWICKITES
   FE3O2BO3
   IFEFFIT
   NI3B2O6
Кл.слова (ненормированные):
Oxyborates -- Ludwigites -- XMCD -- EXAFS -- Magnetism
Аннотация: Single crystals of ludwigite Cu2MnBO5 were synthesized by flux growth technique. The detailed structural and magnetic characterizations of the synthesized samples have been carried out. The cations composition of the studied crystal was determined using X-ray diffraction and EXAFS technique, the resulting composition differ from the content of the initial Mn2O3–CuO components of the flux. Magnetic susceptibility measurements and the calculations of the exchange integrals in frameworks of indirect coupling model revealed that monoclinic distortions strongly affect exchange interactions and appearance of magnetic ordering phase at the temperature T=93 K. The hypothesis of the existence of several magnetic subsystems was supposed. © 2016 Elsevier B.V.

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Держатели документа:
L.V. Kirensky Institute of Physics, Siberian Branch of Russian Academy of Science, Krasnoyarsk, Russian Federation
M V Reshetnev Siberian State Aerospace University, Krasnoyarsk, Russian Federation
V.S. Sobolev Institute of Geology and Mineralogy, SB RAS, Novosibirsk, Russian Federation
Novosibirsk State University, Novosibirsk, Russian Federation
Institute of Physics, University of Mainz, Mainz, Germany
Institute of Inorganic and Analytical Chemistry, University of Mainz, Mainz, Germany
Lund University, MAX IV Laboratory, Lund, Sweden
National Research Centre “Kurchatov Institute”, Moscow, Russian Federation

Доп.точки доступа:
Sofronova, S. N.; Софронова, Светлана Николаевна; Moshkina, E. M.; Мошкина, Евгения Михайловна; Nazarenko, I. I.; Назаренко, Илья Иванович; Seryotkin, Yu. V.; Nepijko, S. A.; Ksenofontov, V.; Medjanik, K.; Veligzhanin, A. A.; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич
}
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Evidence of Co-Fe antiferromagnetic coupling in Co2FeO2BO3 through XMCD study / M. S. Platunov [et al.] // VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. P3.1. - P. 183. - References: 3. - This work has been partially financed by the Council for Grants of the President of the Russian Federation (SP-938.2015.5), the Russian Foundation for Basic Research (project nos. 16-32-60049 mol_a_dk, 16-32-00206 mol_a), SB RAS program № II.2P contract 0358-2015-0005, and UMNIK program . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
oxides -- magnetization -- XANES -- XMCD

Доп.точки доступа:
Platunov, M. S.; Платунов, Михаил Сергеевич; Kazak, N. V.; Казак, Наталья Валерьевна; Knyazev, Yu. V.; Князев, Юрий Владимирович; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Rogalev, A.; Рогалев А.; Wilhelm, Fabrice; Eugen Weschke, Eugen; Schierle, Enrico; Счайле И.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН

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Identification of local magnetic contributions in a Co2FeBO5 single crystal by XMCD spectroscopy / M. S. Platunov [et al.] // JETP Letters. - 2013. - Vol. 96, Is. 10. - P. 650-654DOI 10.1134/S0021364012220109
Аннотация: The temperature dependences of the X-ray absorption spectra (XAS) and of the spectra of X-ray magnetic circular dichroism (XMCD) are measured near the L 3,2 absorption edges of Co and Fe in ludwigite Co2FeBO5 single crystals. The antiparallel orientation of the magnetic moments of cobalt and iron is demonstrated. The coercive fields related to cobalt and iron ions are determined. The orbital (m l ) and (m s ) spin contributions to the total magnetic moments of cobalt and iron ions are identified. The ratios and relative directions of ml and ms are found.

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Публикация на русском языке Разделение локальных магнитных вкладов в монокристалле Co2FeBO5 посредством XMCD-спектроскопии // Письма в "Журнал экспериментальной и теоретической физики". - 2012. - Т. 96, Вып. 10. - С. 723-727

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Helmholtz Zentrum, BESSY 2, D-12489 Berlin, Germany
Natl Acad Sci Ukraine, Donetsk Inst Phys & Engn, UA-83114 Donetsk, Ukraine

Доп.точки доступа:
Platunov, M. S.; Платунов, Михаил Сергеевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Kazak, N. V.; Казак, Наталья Валерьевна; Ivanova, N. B.; Иванова, Наталья Борисовна; Zabluda, V. N.; Заблуда, Владимир Николаевич; Weschke, E.; Весчке И.; Schierle, И.E.; Счайле; Lamonova, K. V.; Ламонова К.В.
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    Magnetic and XMCD studies of Pr1-xSrxMnO3 manganite films / Y. E. Samoshkina [et al.] // J. Magn. Magn. Mater. - 2017. - Vol. 428. - P. 43-49, DOI 10.1016/j.jmmm.2016.12.014. - Cited References: 52. - The work was supported by the Russian Foundation for Basic Research, Project no's. 14-02-01211, 16-32-00209 mol_a, and also the Grant of the President of the Russian Federation no. NSh- 7559.2016.2, and the Ministry of Education and Science of the Russian Federation, Project no. 1362. . - ISSN 0304-8853
   Перевод заглавия: Магнитное и XMCD изучение пленок манганита Pr1−xSrxMnO3
Кл.слова (ненормированные):
Hole-doped manganites -- Thin films -- Magnetic measurements -- Spin-glass behavior -- X-ray magnetic circular dichroism
Аннотация: Magnetic properties of the Pr0.8Sr0.2MnO3 and Pr0.6Sr0.4MnO3 polycrystalline films have been studied using temperature and magnetic field dependences of the static magnetization and X-ray magnetic circular dichroism (XMCD) spectroscopy. For the both compositions, the difference between the temperature dependences of magnetization obtained in the zero fields cooling (ZFC) and field cooling (FC) modes has been revealed. The ZFC curves demonstrate a pronounced maximum at temperature Tm. It is shown that the Tm value dependence on the magnetic field follows the Almeida-Thouless line typical for the classic spin glass, what allows us to assume the possible spin-glass behavior of the films. Effect of the disorder in a direction of the crystallites easy-axis on the difference between FC and ZFC curves has been discussed also. Magnetic field dependences of the sample magnetization are presented by the hysteresis loops with the shape changing upon temperature variation. This behavior has been attributed to the effect of crystallographic anisotropy and Pr ions. The spectra and magnetic field dependences of XMCD at the Pr L2- and Mn K-edges have been studied at 90 K. The magnetic field dependences of the XMCD at the Pr L2-edge had shown Van Vleck paramagnetism from Pr3+ ions. © 2016 Elsevier B.V.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Ural Federal University, Yekaterinburg, Russian Federation
European Synchrotron Radiation Facility (ESRF), BP 220, Grenoble, France
National University of Science and Technology “MISiS”, Moscow, Russian Federation

Доп.точки доступа:
Samoshkina, Yu. E.; Самошкина, Юлия Эрнестовна; Edelman, I. S.; Эдельман, Ирина Самсоновна; Stepanova, E. A.; Neznakhin, D. S.; Ollefs, K.; Andreev, N. V.; Chichkov, V. I.
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Samoshkina, Yu. E.
Electronic and magnetic states of Pr and Mn in the Pr1–xSrxMnO3 films studied by XANES and XMCD spectroscopy / Y. E. Samoshkina, A. Rogalev // J. Exp. Theor. Phys. - 2018. - Vol. 126, Is. 5. - P. 660-665, DOI 10.1134/S1063776118040131. - Cited References: 35. - We thank V.I. Chichkov and N.V. Andreev (National University of Science and Technology MISiS) for the preparation of the manganite films. - This work was supported by the Russian Foundation for Basic Research (project no. 16-32-00209 mol_a) and a grant of the President of the Russian Federation (NSh-7559.2016.2). . - ISSN 1063-7761
Кл.слова (ненормированные):
Circular dichroism spectroscopy -- Dichroism -- Film growth -- Magnetic moments -- Manganese -- Praseodymium -- Strontium compounds -- X ray absorption
Аннотация: The spectral dependences of X-ray absorption near-edge spectroscopy (XANES) and X-ray magnetic circular dichroism (XMCD) and the field dependences of XMCD near the K edge of Mn and the L2,3 edges of Pr in the Pr0.8Sr0.2MnO3 and Pr0.6Sr0.4MnO3 films at T = 90 K are studied. The spectral dependences point to a mixed valence state of Mn and Pr in the films. It is found that, as compared to XANES, XMCD is more sensitive to the valence state of Pr4+. The field dependences of XMCD point to ferromagnetic behavior of Mn ions and the Van Vleck paramagnetism of Pr ions, which makes a significant contribution to the total magnetization of the films. It is shown that as the Sr concentration increases, the XMCD intensity at the K edge of Mn increases, which indicates a growth of the total magnetic moment of the film due to an increase in the 4p–3d hybridization.

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Публикация на русском языке Самошкина, Юлия Эрнестовна. Электронные и магнитные состояния Pr и Mn в пленках Pr1-xSrxMnO3 по данным спектроскопии XANES и XMCD [Текст] / Ю. Э. Самошкина, А. Л. Рогалев // Журн. эксперим. и теор. физ. - 2018. - Т. 153 Вып. 5. - С. 794-799

Держатели документа:
Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Scientific Center,” Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
European Synchrotron Radiation Facility, Grenoble, CS, France

Доп.точки доступа:
Rogalev, A.; Самошкина, Юлия Эрнестовна
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Unraveling dynamic Jahn-Teller effect and magnetism in FeTiF6×6H2O single crystal / M. S. Platunov, N. A. Fedorova, Yu. V. Pyastolova [et al.] // J. Alloys Compd. - 2024. - Vol. 999. - Ст. 175104, DOI 10.1016/j.jallcom.2024.175104. - Cited References: 51. - The authors thank the Joint Supercomputer Center (JSCC) of the Russian Academy of Sciences. The authors would like to express their sincere gratitude to the ID12 beamline staff their exceptional dedication and professionalism in performing the synchrotron experiment during the challenging circumstances of the COVID-pandemic. We are particularly grateful to the postdocs, scientists, and technicians who took part in the experiment, ensuring its successful completion. We also gratefully acknowledge the provision of beamtime (Proposal HC-4375) by the European Synchrotron Radiation Facility (ESRF). The access to this world-class facility was instrumental in obtaining the high-quality data that formed the basis of our research. We are deeply appreciative of the contributions of all involved, and we extend our heartfelt thanks to each and every one of them . - ISSN 0925-8388. - ISSN 1873-4669
Кл.слова (ненормированные):
Dynamic Jahn-Teller effect -- Density functional theory -- B3LYP -- Magnetic and electronic properties -- Mossbauer spectroscopy -- XMCD -- XANES
Аннотация: Hydrated iron fluoridotitanate (FeTiF6 × 6 H2O) single crystals are fascinating magnetic materials with unique properties. To understand the underlying mechanisms, this study combines X-ray absorption near-edge structure (XANES) and X-ray magnetic circular dichroism (XMCD) techniques, complemented by density functional theory (DFT) calculations. Polarization-dependent X-ray absorption spectroscopy, encompassing XANES and XMCD, is a powerful technique for probing the local structures and magnetic properties of materials. It is element-selective, bulk-sensitive, and compatible with a wide range of experimental conditions. In this study, we used XANES and XMCD spectroscopies to investigate the local structures and magnetic properties of Fe and Ti in FeTiF6 × 6 H2O single crystals. XANES analysis revealed distinct local environments around Fe and Ti, providing insights into their coordination environments. Element-selective magnetization measurement at the Fe K-edge demonstrated that iron sites in the oxidation state Fe2+ have an unambiguous paramagnetic contribution to the magnetization along the b-axis. Notably, the absence of an XMCD signal at the Ti K-edge confirmed the absence of a magnetic moment in Ti atoms within the crystal. DFT calculations corroborate the experimental findings and provide insights into the electronic structure and magnetic interactions. The combined results provide a comprehensive understanding of the dynamic Jahn-Teller effect in FeTiF6 × 6 H2O single crystals, highlighting the significance of polarization-dependent X-ray absorption spectroscopy in unraveling the intricate magnetic behavior of such materials. This study contributes to the fundamental understanding of magnetism in these materials and paves the way for the development of novel magnetic materials with tailored properties.

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Держатели документа:
Synchrotron Radiation Facility SKIF, Boreskov Institute of Catalysis SB RAS, Kol’tsovo 630559 , Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Institute of Chemistry, Far Eastern Branch of RAS, Vladivostok 690022, Russia

Доп.точки доступа:
Platunov, M. S.; Платунов, Михаил Сергеевич; Fedorova, N. A.; Федорова, Наталья А.; Pyastolova, Yu. V.; Пястолова, Юлия Валентиновна; Laptash, N. M.; Knyazev, Yu. V.; Князев, Юрий Владимирович; Tomilin, F. N.; Томилин, Феликс Николаевич; Dubrovskiy, A. A.; Дубровский, Андрей Александрович
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XAFS и XMCD методики в исследовании влияния катионного замещения на структурные и магнитные свойства оксиборатов на основе Co3-xMexBO5 / М. С. Платунов [и др.] // XLVIII Школа ПИЯФ по физике конденсированного состояния. ФКС-2014 : сб. тез. и список участников. - 2014. - С. 25

Материалы конференции
Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Платунов, Михаил Сергеевич; Platunov, M. S.; Овчинников, Сергей Геннадьевич; Ovchinnikov, S. G.; Заблуда, Владимир Николаевич; Zabluda, V. N.; Иванова, Наталья Борисовна; Ivanova, N.B.; Казак, Наталья Валерьевна; Kazak, N. V.; Князев, Юрий Владимирович; Rogalev, A.; Wilhelm, F.; Weschke, E.; Schierle, E.; Зубавичус, Я. В.; Школа Петербургского института ядерной физики им. Б.П. Константинова по физике конденсированного состояния(48 ; 2014 ; 10-15 март ; С.-Петербург); "Курчатовский институт", научно-исследовательский центр; Петербургский институт ядерной физики им. Б.П. Константинова
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10.

    XANES and XMCD study of ludwigite Co3BO5 and Co2FeBO5 single crystals / M. S. Platunov [и др.] // MRS Fall Meeting and Exhibit . - 2012. - P. 37
   Перевод заглавия: XANES и XMCD исследование монокристаллов людвигитов Co3BO5 и Co2FeBO5

Программа конференции

Доп.точки доступа:
Platunov, M. S.; Платунов, Михаил Сергеевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Kazak, N. V.; Казак, Наталья Валерьевна; Ivanova, N. B.; Иванова, Наталья Борисовна; Rogalev, A.; Wilhelm, F.; Zabluda, V. N.; Заблуда, Владимир Николаевич; Magnetic Materials under Extreme Conditions. Workshop associated to the ESRF Users’ Meeting (2012 ; февр. ; 7-8 ; Grenoble, France)
}
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