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1.
HEAT-
CAPACITY
OF RBALF4
/ V. N. VORONOV [и др.]> // Fiz. Tverd. Tela. - 1989. -
Vol. 31
,
Is. 5
. - P. 303-305. - Cited References: 10 . - ISSN 0367-3294
РУБ
Physics, Condensed Matter
WOS
Доп.точки доступа:
VORONOV, V. N.; GOREV, M. V.; KOT, L. A.; FLEROV, I. N.
}
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2.
Thermodynamic investigations of
ferroelastic phase transitions in K 2ZnCl4 and K2CoCl4 / I. N. Flerov [et al.]> // Journal of the Physical Society of Japan. - 1992. -
Vol. 61
,
Is. 5
. - P. 1606-1608,
DOI
10.1143/JPSJ.61.1606 . - ISSN 0031-9015
Кл.слова (ненормированные):
(NH4) 2SO4 family ferroelectrics
--
Ferroelasticity
--
Ferroelectricity
--
Heat
capacity
--
Hydrostatic pressure
--
K2CoCl4
--
K2ZnCl4
--
Rb2ZnCl 4group ferroelectrics
Аннотация:
Using the adiabatic calorimeter the heat
capacity
of K2ZnCl 4 and K2CoCl4 crystals was measured in temperature range 100?300 K. The entropy change for ferroelastic phase transition was estimated to be ? S=0.34 (Zn) and 0.33 (Co) JВ·mol-1K-1. The effect of hydrostatic pressure on the phase transition was investigated for both crystals.
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Держатели документа:
L. V. Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation
Department of Electrical Engineering, College of Science and Engineering, Meisei University, 2-1-1 Hodokubo, Hino-shi, Tokyo 191, Japan
Department of Electronic Engineering, College of Science and Engineering, Iwaki Meisei University, 5-5-1 Iino, Chuohdai, Iwaki-shi, Fukushima-ken 970, Japan
Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Yamaguchi, T.; Sawada, S.; Горев, Михаил Васильевич; Gorev, M. V.; Aleksandrov, K. S.; Александров, Кирилл Сергеевич
}
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3.
HEAT-
CAPACITY
MEASUREMENT OF
THE SUCCESSIVE PHASE-TRANSITIONS IN CS2ZNI4 / J. J. MELERO [et al.]> // Solid State Commun. - 1995. -
Vol. 95
,
Is. 4
. - P. 201-206,
DOI
10.1016/0038-1098(95)00261-8. - Cited References: 20 . - ISSN 0038-1098
РУБ
Physics, Condensed Matter
Рубрики:
INCOMMENSURATE PHASE
SEQUENCE
CRYSTALS
CS2CDI4
Кл.слова (ненормированные):
FERROELECTRICS
--
HEAT
CAPACITY
--
PHASE TRANSITIONS
--
INCOMMENSURATE PHASES
Аннотация:
The heat
capacity
of a Cs2ZnI4 single crystal has been measured by means of AC calorimetry. Three anomalies have been detected corresponding to a normal to inconmensurate phase transition at T-I = 116.9+/-0.1 K, an incommensurate to commensurate lock-in transition at T-L = 107.58+/-0.05 K, and a structural transition from a commensurate orthorhombic to a monoclinic phase at T-C = 93.77+/-0.05 K with thermal hysteresis. The lock-in transition has the peculiarity of being discontinuous but not showing any measurable hysteresis. After comparison with the Landau model predictions for the heat
capacity
, derived for the k(Delta) = (1/2 + Delta)a* case, it is concluded that Cs2ZnI4 lies close to the Lifschitz point of coexistence of the normal, incommensurate and commensurate phases.
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,
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Держатели документа:
RUSSIAN ACAD SCI,LV KIRENSKY PHYS INST,SIBERIAN BRANCH,KRASNOYARSK 660036,RUSSIA
Instituto de Ciencia de Materiales de Aragon. C.S.I.C. - Universidad de Zaragoza, 50009 Zaragoza. Spain.
ИФ СО РАН
Доп.точки доступа:
MELERO, J. J.; BARTOLOME, J.; BURRIEL, R.; ALEKSANDROVA, I. P.; Александрова, Инга Петровна; PRIMAK, S.
}
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4.
Hydrostatic pressure effect
on phase transitions in perovskites with ammonium cations / K. S. Aleksandrov [et al.]> // Phys. Status Solidi B. - 2000. -
Vol. 217
,
Is. 2
. - P. 785-791,
DOI
10.1002/(SICI)1521-3951(200002)217:2785::AID-PSSB7853.0.CO;2-Y. - Cited References: 36 . - ISSN 0370-1972
РУБ
Physics, Condensed Matter
Рубрики:
XMF3 CUBIC PEROVSKITES
THERMAL-PROPERTIES
HEAT-
CAPACITY
TEMPERATURE DEPENDENCE
DIELECTRIC PROPERTIES
X-RAY
NH4ZNF3
NH4MNCL3
NH4COF3
NH4CDF3
Аннотация:
The pressure dependence of the structural phase transition temperature has been measured for the powder samples of NH4MgF3, NH4ZnF3, NH4MnF3, NH4CoF3, NH4CdF3, and NH4MnCl3 perovskites in the pressure range 0 to 600 MPa. It was found that the values of dT(0)/dP are negative for the Mg, Zn. Co. Mn trifluorides and positive for NH4CdF3 and NH4MnCl3. Comparison with the known data for other halide and oxide perovskites allowed to conclude that the sign of dT(0)/dP is correlated with the value of the Goldschmidt tolerance factor of the perovskite, and its value is closely related to the temperature and mechanism of the transition.
WOS
Держатели документа:
Univ Zaragoza, CSIC, Inst Ciencia Mat Aragon, Zaragoza 50009, Spain
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Bartolome, J.; Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич
}
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5.
Flerov, I. N.
Heat
capacity
and p-T phase diagrams of the ordered perovskites Pb2MgWO6 and Pb2CoWO6 / I. N. Flerov, M. V. Gorev, P. . Sciau> // J. Phys.: Condens. Matter. - 2000. -
Vol. 12
,
Is. 5
. - P. 559-567,
DOI
10.1088/0953-8984/12/5/304. - Cited References: 25 . - ISSN 0953-8984
РУБ
Physics, Condensed Matter
Рубрики:
CRYSTAL-STRUCTURE
X-RAY
TRANSITIONS
PRESSURE
Аннотация:
The heat capacities of Pb2MgWO6 and Pb2CoWO6 and the effect of hydrostatic pressure on the phase transitions have been studied on powdered samples by means of an adiabatic calorimeter and DTA performed under pressure, respectively. Thermodynamic parameters, such as change of total excess entropy, latent hear and hysteresis of the phase transition temperature were determined. Entropies and p-T phase diagrams are discussed in connection with structural data.
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Держатели документа:
LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L V Kirensky Institute of Physics, 660036 Krasnoyarsk, Russian Federation
CEMES-CNRS, 29 rue Jeanne Marvig, 31055 Toulouse, France
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Sciau, P.; Флёров, Игорь Николаевич
}
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6.
Gorev, M. V.
Heat
capacity
and the p-T phase diagram of Pb2MgTeO6 elpasolite / M. V. Gorev, I. N. Flerov, P. . Sciau> // Phys. Solid State. - 2001. -
Vol. 43
,
Is. 2
. - P. 345-349,
DOI
10.1134/1.1349486. - Cited References: 17 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
ORDERED PEROVSKITE PB2MGTEO6
CRYSTAL-STRUCTURE
PB2COWO6
PB2MGWO6
Аннотация:
The heat
capacity
of Pb2MgTeO6 is measured in the temperature range 80-300 K. It is found that the heat
capacity
exhibits an anomaly associated with the phase transition at T-0 = 186.9 K. The thermodynamic parameters of the structural transformation are determined. The effect of hydrostatic pressure up to 0.5 GPa on the phase transition temperature is examined. (C) 2001 MAIK "Nauka/Interperiodica".
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, Ctr Mat Improvement & Struct Invest, F-31055 Toulouse, France
ИФ СО РАН
Kirenskii Inst. of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CNRS Ctr. for Mat. I., Tuluza, 31055, France
Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Sciau, P.; Горев, Михаил Васильевич
}
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7.
Heat
capacity
study
of relaxor PbMg1/3Nb2/3O3 in a wide temperature range / M. V. Gorev [et al.]> // J. Exp. Theor. Phys. - 2003. -
Vol. 96
,
Is. 3
. - P. 531-537,
DOI
10.1134/1.1567427. - Cited References: 21 . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Рубрики:
DIFFUSE PHASE-TRANSITION
FERROELECTRICS
Кл.слова (ненормированные):
Differential scanning calorimetry
--
Mathematical models
--
Phonons
--
Random processes
--
Specific heat
--
Spectrum analysis
--
Thermal effects
--
Bond-random field models
--
Wide temperature intervals
--
Lead compounds
Аннотация:
Heat
capacity
of the PbMg1/3Nb2/3O3 compound is measured using the methods of adiabatic and differential scanning calorimetry in the temperature range 80-750 K. Two blurred anomalies on the C-p(T) dependence are observed in wide temperature intervals of 200- 400 K and 500-700 K. The results of studies are discussed together with data on the structure and phonon spectrum in the framework of spherical random bond-random field model. (C) 2003 MAIK "Nauka/Interperiodica".
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L. V. Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CEMES-CNRS, 31055 Toulouse, France
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Sciau, P.
}
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8.
Heat
capacity
of
the PbFe1/2Ta1/2O3 perovskite-like compound / M. V. Gorev [et al.]> // Phys. Solid State. - 2004. -
Vol. 46
,
Is. 3
. - P. 521-525,
DOI
10.1134/1.1687872. - Cited References: 26 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
SINGLE-CRYSTALS
PBFE0.5TA0.5O3
FERROELECTRICS
DIFFRACTION
NIOBATE
GROWTH
Аннотация:
The heat
capacity
C-p(T) of the complex perovskite PbFe1/2Ta1/2O3 has been studied using adiabatic calorimetry in the temperature range 150-370 K. Three diffuse anomalies in C-p(T) are found to exist at temperatures T-d approximate to 350 K, T-m approximate to 250-300 K, and T-c approximate to 205 K. The anomalous and the lattice contribution to the heat
capacity
are separated, and the change in the entropy is determined. The results of the study are discussed jointly with the data on the structure and physical properties of the compound. (C) 2004 MAIK "Nauka / Interperiodica".
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
INFM, I-090124 Cagliari, Italy
Dipartimento Fis, I-090124 Cagliari, Italy
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CEMES-CNRS, 29 Rue Jeanne Marvig, Toulouse, 31055, France
Inst. Naz. di Fisica della Materia, Dipartimento di Fisica, Monserrato (Cagliari), 090124, Italy
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Sciau, P.; Lehmann, A. G.
}
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9.
Heat
capacity
and
thermal expansion study of relaxor-ferroelectric Ba0.92Ca0.08Ti0.76Zr0.24O3 / M. . Gorev [et al.]> // J. Phys.: Condens. Matter. - 2004. -
Vol. 16
,
Is. 39
. - P. 7143-7150,
DOI
10.1088/0953-8984/16/39/045. - Cited References: 18 . - ISSN 0953-8984
РУБ
Physics, Condensed Matter
Рубрики:
CERAMICS
BA(TI1-XZRX)O-3
PEROVSKITES
Кл.слова (ненормированные):
Calorimetry
--
Dielectric properties
--
Ferroelectric materials
--
Perovskite
--
Phase transitions
--
Solid solutions
--
Specific heat
--
Thermal expansion
--
Adiabatic calorimetry
--
Frequency dispersion
--
Polar domains
--
Relaxor ferroelectrics
--
Barium compounds
Аннотация:
Heat
capacity
and thermal expansion of the Ba0.92Ca0.08Ti0.76Zr0.24O3 compound is measured using the methods of adiabatic calorimetry and optic-mechanical dilatometry in the temperature range 100-370 K. Three blurred anomalies on the C-p(T) and alpha(T) dependencies are observed in the temperature range 200-360 K. The results of the studies are discussed together with data on the structure and dielectric properties in the framework of spherical random bond-random field model.
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Держатели документа:
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L V kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Sciau, P.; Savariault, J. M.
}
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10.
Flerov, I. N.
Heat
capacity
and phase transitions in NH4LiSO4, Cs-x(NH4)(1-x) LiSO4, and RbLiSO4 / I. N. Flerov, A. V. Kartashev, V. A. Grankina> // Phys. Solid State. - 2005. -
Vol. 47
,
Is. 4
. - P. 720-728,
DOI
10.1134/1.1913987. - Cited References: 29 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
ROOM-TEMPERATURE
MONTE-CARLO
LINH4SO4
SUBSTITUTION
CRYSTALS
SULFATE
CSLISO4
Аннотация:
The heat
capacity
of NH4LiSO4, RbLiSO4, and Cs-x(NH4)(1 - x) LiSO4 crystals and its behavior over a broad temperature range including the phase transition regions were studied. The entropy changes corresponding to structural transformations in these crystals were found not to be characteristic of straightforward ordering of structural blocks. The results obtained are discussed in terms of phenomenological theory and model concepts. (C) 2005 Pleiades Publishing, Inc.
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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Доп.точки доступа:
Kartashev, A. V.; Карташев, Андрей Васильевич; Grankina, V. A.; Флёров, Игорь Николаевич
}
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11.
Rotter, I.
Zeros in single-channel transmission through double quantum dots / I. . Rotter, A. F. Sadreev> // Phys. Rev. E. - 2005. -
Vol. 71
,
Is. 4
. - Ст. 46204,
DOI
10.1103/PhysRevE.71.046204. - Cited References: 28 . - ISSN 1063-651X
РУБ
Physics, Fluids & Plasmas + Physics, Mathematical
Рубрики:
PHASE EVOLUTION
RESONANCE
TRANSPORT
SYSTEMS
Кл.слова (ненормированные):
Fano interference
--
Fano resonances
--
Overlapping resonances
--
Transmission amplitude
--
Channel
capacity
--
Eigenvalues and eigenfunctions
--
Function evaluation
--
Hamiltonians
--
Mathematical models
--
Mathematical operators
--
Matrix algebra
--
Resonance
--
Signal interference
--
Semiconductor quantum dots
Аннотация:
By using a simple model we consider single-channel transmission through a double quantum dot that consists of two single dots coupled by a wire of finite length L. Each of the two single dots is characterized by a few energy levels only, and the wire is assumed to have only one level whose energy depends on the length L. The transmission is described by using S matrix theory and the effective non-Hermitian Hamilton operator H-eff of the system. The decay widths of the eigenstates of H-eff depend strongly on energy. The model explains the origin of the transmission zeros of the double dot that is considered by us. Mostly, they are caused by (destructive) interferences between neighboring levels and are of first order. When, however, both single dots are identical and their transmission zeros are of first order, those of the double dot are of second order. First-order transmission zeros cause phase jumps of the transmission amplitude by pi, while there are no phase jumps related to second-order transmission zeros. In this latter case, a phase jump occurs due to the fact that the width of one of the states vanishes when crossing the energy of the transmission zero. The parameter dependence of the widths of the resonance states is determined by the spectral properties of the two single dots.
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Держатели документа:
Max Planck Inst Phys Komplexer Syst, D-01187 Dresden, Germany
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Linkoping Univ, Dept Phys & Measurement Technol, S-58183 Linkoping, Sweden
Astafev Krasnoyarsk Pedag Univ, Krasnoyarsk 660049, Russia
ИФ СО РАН
Max-Planck-Inst. Phys. Komplexer S., D-01187 Dresden, Germany
Kirensky Institute of Physics, Krasnoyarsk, 660036, Russian Federation
Dept. of Phys. and Msrmt. Technology, Linkoping University, S-58183 Linkoping, Sweden
Astaf'ev Krasnoyarsk Pedagogical U., Krasnoyarsk, 660049, Russian Federation
Доп.точки доступа:
Sadreev, A. F.; Садреев, Алмаз Фаттахович
}
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12.
Heat
capacity
study
of double perovskite-like compounds BaTi1-xZrxO3 / M. V. Gorev [et al.]> // Phys. Solid State. - 2005. -
Vol. 47
,
Is. 12
. - P. 2304-2308,
DOI
10.1134/1.2142895. - Cited References: 19 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
BATIO3
BA(TI1-XZRX)O-3
FERROELECTRICS
CERAMICS
STATE
FILMS
FIELD
Аннотация:
The temperature dependence of the heat
capacity
of two compositions in the solid solution system BaTi1 - xZrxO3 (x = 0.25, 0.35) was measured using adiabatic calorimetry. In the T-x phase diagram, these compounds occupy positions near the crossover from conventional ferroelectric behavior to the relaxor state. Both compounds reveal diffuse heat
capacity
anomalies: two anomalies in the temperature ranges 250-350 and 150-200 K at x = 0.35 and one anomaly within the range similar to 150-320 K at x = 0.25. The results obtained are discussed together with structural and dielectric measurements. (c) 2005 Pleiades Publishing, Inc.
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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok, 660036, Russian Federation
CEMES-CNRS, 29 rue Jeanne Marvig, Toulouse, 31055, France
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Sciau, P.; Savariault, J. M.
}
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13.
Gorev, M. V.
Heat
capacity
study of PMN near field induced phase transition / M. V. Gorev, V. S. Bondarev, K. S. Aleksandrov> //
Abstract book of The Fifth International Seminar on Ferroelactic Physics. - 2006. - P. 104
Доп.точки доступа:
Bondarev, V. S.; Бондарев, Виталий Сергеевич; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Горев, Михаил Васильевич; International Seminar on Ferroelactic Physics(5 ; 2006 ; Sept. ; 10-13 ; Voronezh)
}
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14.
Heat
capacity
, structural
disorder, and the phase transition in cryolite (NH4)(3)Ti(O-2)F-5 / I. N. Flerov [et al.]> // Phys. Solid State. - 2006. -
Vol. 48
,
Is. 8
. - P. 1559-1567,
DOI
10.1134/S1063783406080221. - Cited References: 18 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
PEROVSKITE-LIKE OXYFLUORIDES
CRYSTAL-STRUCTURES
(NH4)(3)TIOF5
(NH4)(3)WO3F3
DIFFRACTION
Аннотация:
The heat
capacity
, T-p phase diagrams, and unit cell parameters of cryolite (NH4)(3)Ti(O-2)F-5 were studied over a wide temperature range. A phase transition was found near 226 K, and its thermodynamic characteristics and their dependence on the crystallization conditions were determined. The coordinates and thermal parameters of atoms in the Fm3m phase were refined. An analysis of the electron density distribution and the transition entropy showed that the mechanism of the structural transition involves, above all, rotation of the Ti(O-2)F-5 octahedra. Possible models of disordering of tetrahedral ammonium groups are considered.
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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russian Federation
Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Fokina, V. D.; Фокина, Валентина Дмитриевна; Molokeev, M. S.; Молокеев, Максим Сергеевич; Vasil'ev, A. D.; Васильев, Александр Дмитриевич; Bovina, A. F.; Бовина, Ася Федоровна; Laptash, N. M.
}
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15.
Heat
capacity
study
of relaxors BaTi0.65Zr0.35O3 and BaTi0.60Zr0.40O3 / M. . Gorev [et al.]> // J. Phys.: Condens. Matter. - 2006. -
Vol. 18
,
Is. 17
. - P. 4407-4416,
DOI
10.1088/0953-8984/18/17/026. - Cited References: 21 . - ISSN 0953-8984
РУБ
Physics, Condensed Matter
Рубрики:
CERAMICS
BA(TI1-XZRX)O-3
BATIO3
Кл.слова (ненормированные):
Calorimetry
--
Composition
--
Data reduction
--
Lead compounds
--
Mathematical models
--
Permittivity
--
Specific heat
--
Adiabatic calorimetry
--
Burns temperature
--
Diffuse anomalies
--
Barium compounds
Аннотация:
The heat
capacity
of two relaxors BaTi(1-x)ZrxO(3) (x = 0.35, 0.40) was measured using adiabatic calorimetry in the temperature range 100-360 K. The Cp(T) dependence of both compositions is characterized by the presence of two diffuse anomalies near the Burns temperature T-d and the temperature of the maximum in permittivity T-m in the temperature ranges 250-350 K and 120 200 K. The anomalous heat
capacity
near T-d was analysed taking into account the distribution of Zr concentration in nanoregions leading to the distribution of their transition temperatures into the polar phase. Excess heat
capacity
near Tm was discussed in the framework of the spherical random bond-random field model. The results are compared with the data obtained by the same procedures for PbMg1/3Nb2/3O3 studied experimentally earlier.
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
ИФ СО РАН
L V Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CEMES-CNRS, 31055 Toulouse, France
Доп.точки доступа:
Gorev, M.; Bondarev, V.; Sciau, P.; Savariault, J. M.
}
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16.
Heat
capacity
and
thermal expansion study of Ba0.9Bi0.067(Ti1-xZrx)O-3 ceramics / M. . Gorev [et al.]> // J. Phys.: Condens. Matter. - 2007. -
Vol. 19
,
Is. 34
. - Ст. 346237,
DOI
10.1088/0953-8984/19/34/346237. - Cited References: 15 . - ISSN 0953-8984
РУБ
Physics, Condensed Matter
Рубрики:
BA(TI1-XZRX)O-3
STATE
Кл.слова (ненормированные):
Adiabatic calorimeters
--
Temperature range
--
Temperature regions
--
Thermal expansion anomaly
--
Barium
--
Ceramic materials
--
Dielectric properties
--
Expansion
--
Specific heat
--
Zirconium
--
Thermal expansion
Аннотация:
For Ba0.9Bi0.067(Ti1-xZrx)O-3 (x = 0.04, 0.15) ceramics, the heat
capacity
C-p(T) and the thermal expansion alpha(T) were measured using an adiabatic calorimeter and an optical-mechanical dilatometer in the temperature range 100-420 K. Both compounds reveal diffuse heat
capacity
and thermal expansion anomalies: three anomalies in the temperature regions 150-250 K, 250-300 K (alpha(T) only) and 300-400 K at x = 0.04 and two anomalies in the regions 200 250 K and 250-350 K at x = 0.15. The results obtained are discussed together with the data on the dielectric properties.
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Держатели документа:
[Gorev, Michail
Bondarev, Vitaly
Flerov, Igor] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
[Maglione, Mario
Simon, Annie] Univ Bordeaux 1, CNRS, ICMCB, F-33608 Pessac, France
ИФ СО РАН
LVKirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
ICMCB-CNRS, Universite de Bordeaux i, 87 avenue ASchweitzer, 33608 Pessac, France
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Maglione, M.; Simon, A.
}
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17.
Heat
capacity
, structure,
and p-T phase diagram of elpasolite (NH4)(2)KMoO3F3 / I. N. Flerov [et al.]> // Phys. Solid State. - 2007. -
Vol. 49
,
Is. 1
. - P. 141-147,
DOI
10.1134/S1063783407010234. - Cited References: 8 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
TRANSITIONS
Аннотация:
Thermophysical and structural studies of an (NH4)(2)KMoO3F3 crystal show that this crystal belongs to the family of elpasolites (space group Fm (3) over barm) and undergoes an order-disorder phase transition at To 241.5 K. Under hydrostatic pressure, this phase transition splits into two consecutive transitions at the tricritical point with parameters T-tr = 232.5 K and p(tr)= 0.21 GPa. It was found that anomalous hysteresis and relaxation phenomena accompany the transitions from the cubic to both distorted phases. The results are analyzed taking into account the data on the phase transition in the related elpasolite (NH4)(2)KWO3F3.
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Держатели документа:
Russian Acad Sci, Siberian Div, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Russian Acad Sci, Far Eastern Div, Inst Chem, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry, Far Eastern Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation
Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Fokina, V. D.; Фокина, Валентина Дмитриевна; Bovina, A. F.; Бовина, Ася Федоровна; Molokeev, M. S.; Молокеев, Максим Сергеевич; Pogorel'tsev, E. I.; Laptash, N. M.
}
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18.
Gorev, M. V.
Heat
capacity
of PMN near an electric-field-induced phase transition / M. V. Gorev, V. S. Bondarev, K. S. Aleksandrov> // JETP Letters. - 2007. -
Vol. 85
,
Is. 6
. - P. 283-285,
DOI
10.1134/S0021364007060045. - Cited References: 9 . - ISSN 0021-3640
Аннотация:
The heat
capacity
of a single crystal of Pb(Mg1/3Nb2/3)O-3 (PMN) in an electric filed with E = 3 kV/cm applied along the [111] direction has been measured using adiabatic calorimetry over the temperature range 170-250 K. Anomalies in C-P have been found, which correspond to a field-induced phase transition from a relaxor to a ferroelectric state at 225 K under field cooling conditions or at 235-240 K on the subsequent field heating. The field-induced ferroelectric phase persists in a metastable state at low temperatures and is destroyed on zero-field heating at 210 K. The small entropy change Delta S approximate to 0.028R in the field-induced phase transition suggests an insignificant change in the volume fraction of existing polar nanoregions.
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Публикация на русском языке
Горев, Михаил Васильевич. Исследование теплоемкости PMN вблизи индуцированного электрическим полем фазового перехода [Текст] / М. В. Горев, В. С. Бондарев, К. С. Александров // Письма в Журн. эксперим. и теор. физ. - 2007. - Т. 85 Вып. 5-6. - С. 340-342
Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Доп.точки доступа:
Bondarev, V. S.; Бондарев, Виталий Сергеевич; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Горев, Михаил Васильевич
}
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19.
Gorev, M. V.
Heat
capacity
study of PMN near fieldinduced phase transition / M. V. Gorev, V. S. Bondarev, K. S. Aleksandrov> //
Ferroelectrics. - 2007. -
Vol. 360
,
Is. 1
,
Pt. 2
. - P. 37-43,
DOI
10.1080/00150190701515964. - Cited References: 11 . - ISSN 0015-0193
Кл.слова (ненормированные):
Field-induced phase transition
--
Heat
capacity
--
PMN
--
Field cooling
--
Field model
--
Field-induced phase transition
--
Heat capacities
--
Heat
capacity
measurements
--
Single crystal wafers
--
Temperature range
--
Zero-field heating
--
Electric fields
--
Single crystals
--
Specific heat
--
Phase transitions
Аннотация:
Heat
capacity
measurements were performed for a single crystal wafer of PMN in the temperature range of 170-250 K applying an electric field E = 3.0 kV/cm along the [111] direction. The heat
capacity
anomalies related to the phase transition at Tc = 210 K upon zero field heating after field cooling and at Tc = 223 K upon field cooling have been found. The results obtained are discussed together with the data of previous studies in the frame of the spherical random bondrandom field model.
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,
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Доп.точки доступа:
Bondarev, V. S.; Бондарев, Виталий Сергеевич; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Горев, Михаил Васильевич; International Seminar on Ferroelactic Physics(5 ; 2006 ; Sept. ; 10-13 ; Voronezh)
}
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20.
Heat
capacity
and
thermal expansion study of Ba0.9Bi0.067(Ti1-xZrx)O3 ceramics [Text] / M. Gorev [et al.]> // Journal of Physics: Condensed Matter. - 2007. -
Т. 19
,
№ 34
. - С. 346237,
DOI
10.1088/0953-8984/19/34/346237 . - ISSN 0953-8984. - ISSN 1361-648X
ГРНТИ
29.19
РИНЦ
Держатели документа:
ICMCB-CNRS,Universite de Bordeaux i
LVKirensky Institute of Physics,Siberian Division,Russian Academy of Sciences
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Maglione, M.; Simon, A.
}
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