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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova N. B., Platunov M. S., Knyazev Yu. V., Kazak N. V., Bezmaternykh L. N., Eremin E. V., Vasiliev A. D.
Заглавие : Spin-glass magnetic ordering in CoMgGaO2BO3 ludwigite
Место публикации : Физ. низких температур: Физико-технический институт низких температур им. Б.И. Веркина НАН Украины, 2012. - Т. 38, Вып. 2. - С.214-217. - ISSN 0132-6414. - ISSN 1816-0328
Примечания : Библиогр.: 13 назв. - This work was supported by the Russian Foundation for Basic Research (project No. 09-02-00171-a), the Federal Agency for Science and Innovation (Rosnauka) (project No. MK-5632.2010.2), the Physics Division of the Russian Academy of Sciences, the program "Strongly Correlated Electrons" (project 2.3.1).
Предметные рубрики: AC Magnetic susceptibility
DC magnetization
Field cooled
Flux methods
Frequency dependent
Magnetic system
Magnetic transitions
Needle shape
Parent compounds
Spin-glasses freezing
Temperature dependencies
Unit-cell volume
Zero-field-cooled
Cobalt
Cobalt compounds
Freezing
Glass
Magnetic susceptibility
Magnetism
Single crystals
X-ray diffraction
Spin glass
Ключевые слова (''Своб.индексиров.''): spin-glass freezing--transition metal ludwigites
Аннотация: The single crystal needle shape samples of diamagnetically diluted cobalt ludwigite CoMgGaO2BO3 have been grown by the flux method. The results of x-ray diffraction and both dc and ac magnetic measurements are presented. The unit cell volume undergoes a noticable growth under dilution from 328.31 Å3 for the parent compound Co3O2BO3 to 345.46 Å3 for CoMgGaO2BO3. The temperature of magnetic transition is considerably lower for the latter compound (25 K against 43 Kfor Co3O2BO3). The dc magnetization temperature dependencies undergo the splitting of field cooled and zero-field cooled regimes and the ac magnetic susceptibility temperature dependencies are frequency dependent pointing out a possible spin-glass freezing in the magnetic system.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Сутормин, Виталий Сергеевич, Крахалев, Михаил Николаевич, Зырянов, Виктор Яковлевич
Заглавие : Динамика отклика электрооптической ячейки на основе слоя нематика с управляемым поверхностным сцеплением
Место публикации : Письма в журн. техн. физ. - 2013. - Т. 39, Вып. 13. - С. 1-8
Аннотация: Исследованы электрооптические характеристики ячейки на основе слоя нематического жидкого кристалла, управляемого за счет модификации поверхностного сцепления ионным сурфактантом. Использовалась инверсная мода эффекта, при этом нематик был сориентирован гомеотропно в исходном состоянии и переходил к гибридной гомеопланарной структуре под действием постоянного электрического поля. Рассмотрены зависимости динамических параметров оптического отклика от величины приложенного напряжения.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sutormin V. S., Krakhalev M. N., Zyryanov V. Ya.
Заглавие : The dynamics of the response of an electro-optic cell based on a nematic layer with controlled surface anchoring
Место публикации : Tech. Phys. Lett. - 2013. - Vol. 39, Is. 7. - P.583-586. - ISSN 1063-7850, DOI 10.1134/S1063785013070134
Аннотация: We investigate the electrooptical characteristics of a cell based on a nematic liquid crystal layer controlled with the use of modification of the surface anchoring by an ionic surfactant. The inverse mode of the effect is used with the nematic oriented homeotropically in the initial state and transferring to the hybrid homeoplanar structure in an applied dc electric field. We consider the applied voltage dependences of the dynamic parameters of the optical response. В© 2013 Pleiades Publishing, Ltd.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Rashchenko S. V., Likhacheva A. Y., Krylov A. S., Mikhno A. O.
Заглавие : Diamond anvil cell in high-pressure petrology: studying the metamorphic reactions in situ
Коллективы : International Eclogite Conference (10; 2013 ; Sept. ; 2-10; Courmayeur, Italy)
Место публикации : Int. Ecologite Conf.: Abstract Vol. - 2013. - P.104
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T. G., Kiselev E. G., Shishatskaya E. I., Zhila N. O., Boyandin A. N., Syrvacheva D. A., Vinogradova O. N., Kalacheva G. S., Vasiliev A. D., Peterson I. V.
Заглавие : Cell growth and accumulation of polyhydroxyalkanoates from CO2 and H2 of a hydrogen-oxidizing bacterium, Cupriavidus eutrophus B-10646
Место публикации : Bioresource Technol. - 2013. - Vol. 146. - P.215-222. - ISSN 0960-8524, DOI 10.1016/j.biortech.2013.07.070
Ключевые слова (''Своб.индексиров.''): autotrophic synthesis--cupriavidus eutrophus--polyhydroxyalkanoates
Аннотация: Synthesis of polyhydroxyalkanoates (PHAs) by a new strain of Cupriavidus - Cupriavidus eutrophus B-10646 - was investigated under autotrophic growth conditions. Under chemostat, at the specific flow rate D=0.1h-1, on sole carbon substrate (CO2), with nitrogen, sulfur, phosphorus, potassium, and manganese used as growth limiting elements, the highest poly(3-hydroxybutyrate) [P(3HB)] yields were obtained under nitrogen deficiency. In batch autotrophic culture, in the fermenter with oxygen mass transfer coefficient 0.460h-1, P(3HB) yields reached 85% of dry cell weight (DCW) and DCW reached 50g/l. Concentrations of supplementary PHA precursor substrates (valerate, hexanoate, ?-butyrolactone) and culture conditions were varied to produce, for the first time under autotrophic growth conditions, PHA ter- and tetra-polymers with widely varying major fractions of 3-hydroxybutyrate, 4-hydroxybutyrate, 3-hydroxyvalerate, and 3-hydroxyhexanoate monomer units. Investigation of the high-purity PHA specimens showed significant differences in their physicochemical and physicomechanical properties. В© 2013 Elsevier Ltd.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Molokeev M. S., Misyul' S. V.
Заглавие : Structural changes during phase transitions and the critical and noncritical order parameters in the (NH4)3Nb(O2)2F4 crystal
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 54, Is. 1. - P.143-154. - ISSN 1063-7834, DOI 10.1134/S1063783412010234. - ISSN 1090-6460
Примечания : Cited References: 17. - This study was supported by the Russian Foundation for Basic Research (project no. 09-02-00062) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (grant no. NSh-4645.2010.2).
Предметные рубрики: TRANSFORMATIONS
OXYFLUORIDE
CELL
Аннотация: The structures of two phases of the (NH4)3Nb(O2)2F4 crystal, namely, the parent cubic phase and the most distorted low-temperature phase, have been determined from data of an X-ray diffraction experiment performed for a powder sample. The profile and structural parameters have been refined according to the procedure implemented in the DDM program. The results obtained have been discussed with invoking the group-theoretical analysis of the complete order parameter condensate, which takes into account the critical and noncritical atomic displacements and allows the interpretation of the obtained experimental data. It has been found that the most probable sequence of structural transformations occurring in the crystal can be schematically represented in the following form: Fm3¯m−→−−−−(η1,η1,η)Γ+5(11−7)C2/m−→−−−−−−−−−−−−−−−−(η1,η1,η)(0,0,0,0,0,ξ,0−ξ,0,0,0,0)Γ+5(11−7)⊗Σ2(4−2)P21/m−→−−−−−−−−−−−−−−−−−−−−−−−−−−−−(η1,η1,η)(0,0,0,0,0,ξ,0−ξ,0,0,0,0)(0,0,0,0,0,ε,0,ε,0,0,0,0)Γ+5(11−7)⊗Σ2(4−2)⊗Σ3(4−3)P21/n.\begin{gathered} Fm\bar 3m\xrightarrow[{(\eta 1,\eta 1,\eta )}]{{\Gamma _5. + (11 - 7)}}C2/m\xrightarrow[{(\eta 1,\eta 1,\eta )(0,0,0,0,0,\xi ,0 - \xi ,0,0,0,0)}]{{\Gamma _5. + (11 - 7) \otimes \Sigma _2 (4 - 2)}}P2_1 /m \hfill \\ \xrightarrow[{(\eta 1,\eta 1,\eta )(0,0,0,0,0,\xi ,0 - \xi ,0,0,0,0)(0,0,0,0,0,\varepsilon ,0,\varepsilon ,0,0,0,0)}]{{\Gamma _5. + (11 - 7) \otimes \Sigma _2 (4 - 2) \otimes \Sigma _3 (4 - 3)}}P2_1 /n. \hfill \\ \end{gathered}
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sutormin V. S., Krakhalev M. N., Prishchepa O. O., Lee W., Zyryanov V. Ya.
Заглавие : Electro-optical response of an ionic-surfactantdoped nematic cell with homeoplanar-twisted configuration transition
Коллективы : Russian Foundation for Basic Research [12-03-00816]; Siberian Branch of the Russian Academy of Sciences (SB RAS) [30, 24.32]; Ministry of Science and Technology of Taiwan through an NSC-SB-RAS joint project [NSC 103-2923-M-009-003-MY3]
Место публикации : Opt. Mater. Express: Optical Society of America, 2014. - Vol. 4, Is. 4. - P.810-815. - ISSN 2159-3930, DOI 10.1364/OME.4.000810
Примечания : Cited References: 16. - This work was partially supported by the Russian Foundation for Basic Research (project No. 12-03-00816), and by the Siberian Branch of the Russian Academy of Sciences (SB RAS) through Grants Nos. 30, 24.32, and by the Ministry of Science and Technology of Taiwan under Grant No. NSC 103-2923-M-009-003-MY3 through an NSC-SB-RAS joint project.
Предметные рубрики: LIQUID-CRYSTAL
ORIENTATION
SURFACES
LAYER
Аннотация: This study is concerned with the optical response of an electro-optical material consisting of nematic liquid crystal as well as ionic surfactant as a dopant. The dopant is a key component to carry out the working of the resulting device through configuration switching. The operational principle is based on the surface anchoring transition induced by a steady electric field. The dynamic characteristics of the electro-optical cell can be considerably improved when the nematic layer is reoriented from the initially homeoplanar director configuration into the twisted state. Besides, a method to shorten the relaxation time is demonstrated by using a controlling pulse with a bipolar waveform. (C)2014 Optical Society of America
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Wang H. T., Timofeev I. V., Chang K., Zyryanov V. Ya., Lee W.
Заглавие : Tunable narrow-bandpass filter based on an asymmetric photonic bandgap structure with a dual-mode liquid crystal
Коллективы : Ministry of Science and Technology of Taiwan [NSC 101-2112-M-009-018-MY3, NSC 103-2923-M-009-003-MY3]; Russian Foundation for Basic Research [14-02-3124814]; Siberian Branch of the Russian Academy of Sciences [43, 24.29 and 101]
Место публикации : Opt. Express: Optical Society of America, 2014. - Vol. 22, Is. 12. - P.15097-15103. - ISSN 1094-4087, DOI 10.1364/OE.22.015097
Примечания : Cited References: 23. - This work was supported by the Ministry of Science and Technology of Taiwan through Grant No. NSC 101-2112-M-009-018-MY3 as well as Grant No. NSC 103-2923-M-009-003-MY3 dedicated to a joint project between Taiwan and Russia. Both I. V. Timofeev and V. Ya. Zyryanov would like to thank the Russian Foundation for Basic Research (project No. 14-02-3124814) and the Siberian Branch of the Russian Academy of Sciences (grants Nos. 43, 24.29 and 101).
Предметные рубрики: DEVICE
LAYER
CELL
Аннотация: A one-dimensional asymmetric photonic crystal with dual-frequency liquid crystal as a central defect layer was demonstrated. Such asymmetric structure was characterized by the dramatic increase in intensity of the electric field of light localized at the overlapped photonic bandgap edges, thereby enhancing the observed transmittance of the spectral windows originating from the defect layer. The defect layer was made of a dual-mode liquid crystal that exhibited not only electrical tunability and switchability but also optical bistability. Consequently, tunable and bistable defect modes can be realized in the photonic structure. This asymmetric photonic crystal structure is promising and should be further explored for photonic device applications. (C) 2014 Optical Society of America
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Goryainov S. V., Krylov A. S., Vtyurin A. N., Pan Y.
Заглавие : Raman study of datolite CaBSiO4(OH) at simultaneously high pressure and high temperature
Коллективы : Russian Foundation for Basic Research [N 14-05-00616, 13-05-00185], Ministry of Education and Science of the Russian Federation
Место публикации : J. Raman Spectrosc.: Wiley-Blackwell, 2015. - Vol. 46, Is. 1. - P.177-181. - ISSN 0377, DOI 10.1002/jrs.4614. - ISSN 10974555(eISSN)
Примечания : Cited References:30. - This work was partly supported by the Russian Foundation for BasicResearch (grants N 14-05-00616 and 13-05-00185) and the Ministry ofEducation and Science of the Russian Federation.
Предметные рубрики: X-RAY-DIFFRACTION
CRYSTAL-STRUCTURE
HYDROGEN-BOND
SPECTROSCOPY
Ключевые слова (''Своб.индексиров.''): raman spectra--datolite--high pressure--high temperature--diamond anvil--cell
Аннотация: Using an in situ method of Raman spectroscopy and resistance-heated diamond anvil cell, the system datolite CaBSiO4(OH) – water has been investigated at simultaneously high pressure and temperature (up to Р ~5 GPa and Т ~250 °С). Two polymorphic transitions have been observed: (1) pressure-induced phase transition or the feature in pressure dependence of Raman band wavenumbers at P = 2 GPа and constant T = 22 °С and (2) heating-induced phase transition at T ~90 °С and P ~5 GPа. The number of Raman bands is retained at the first transition but changed at the second transition. The first transition is mainly distinguished by the changes in the slopes of pressure dependence of Raman peaks at 2 GPa. The second transition is characterized by several strong changes: the wavenumber jumps of major bands, the merging of strong doublets at 378 and 391 cm−1 (values for ambient conditions), the splitting of the intermediate-intensity band at 292 cm−1, and the transformation of some low-wavenumber bands at 160–190 cm−1. No spectral and visual signs of overhydration and amorphization have been observed. No noticeable dissolution of datolite in the water medium occurred at 5 GPa and 250 °С after 3 h, which corresponds to typical conditions of the ‘cold’ zones of slab subduction. Copyright © 2014 John Wiley & Sons, Ltd.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Timofeev I. V., Gunyakov V. A., Sutormin V. S., Myslivets S. A., Arkhipkin V. G., Vetrov S. Ya., Lee W., Zyryanov V. Ya.
Заглавие : Geometric phase and ο-mode blueshift in a chiral anisotropic medium inside a Fabry-Pérot cavity
Место публикации : Phys. Rev. E: American Physical Society, 2015. - Vol. 92, Is. 5. - Ст.052504. - ISSN 15393755 (ISSN), DOI 10.1103/PhysRevE.92.052504
Примечания : Cited References: 92. - This work was supported in part by Russian Foundation for Basic Research Grants No. 14-02-31248 and No. 15-02-06924; Ministry of Education and Science of the Russian Federation under the Government program, Project No. 3.1276.2014/K; and the Ministry of Science and Technology of Taiwan under Grant No. NSC 103-2923-M-009-003-MY3 through an NSC–SB RAS joint project
Предметные рубрики: NEMATIC LIQUID-CRYSTAL
DIMENSIONAL PHOTONIC CRYSTAL
OPTICAL-PROPERTIES
ELECTROMAGNETIC PROPAGATION
DISPLAYS
SYSTEMS
FILTER
LIGHT
CELL
FORMULATION
Аннотация: Anomalous spectral shift of transmission peaks is observed in a Fabry-Pérot cavity filled with a chiral anisotropic medium. The effective refractive index value resides out of the interval between the ordinary and the extraordinary refractive indices. The spectral shift is explained by contribution of a geometric phase. The problem is solved analytically using the approximate Jones matrix method, numerically using the accurate Berreman method, and geometrically using the generalized Mauguin-Poincaré rolling cone method. The o-mode blueshift is measured for a 4-methoxybenzylidene-4′-n-butylaniline twisted-nematic layer inside the Fabry-Pérot cavity. The twist is electrically induced due to the homeoplanar-twisted configuration transition in an ionic-surfactant-doped liquid crystal layer. Experimental evidence confirms the validity of the theoretical model. © 2015 American Physical Society.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Молостов, Илья Петрович, Щербинин, Всеволод Владиславович
Заглавие : Коаксиальная измерительная ячейка для широкополосных измерений диэлектрической проницаемости
Место публикации : Известия АлтГУ. - 2015. - Т. 2, Вып. 1. - С. 56-60. - ISSN 1561-9443, DOI 10.14258/izvasu(2015)1.2-09
Примечания : Библиогр.: 7
Ключевые слова (''Своб.индексиров.''): коаксиальный волновод--диэлькометрия--ксвн--измерительная ячейка--coaxial waveguide--permittivity measurement--vswr--measuring cell
Аннотация: Рассмотрено несколько вариантов конструкции коаксиальных ячеек, рассчитанных на работу в линии передачи с волновым сопротивлением 50 Ом и предназначенных для измерения комплексной диэлектрической проницаемости дисперсных и жидких материалов в диапазоне частот от 0.01 до 16 ГГц. Проведено численное моделирование коаксиальных ячеек с использованием метода конечных разностей во временной области. Проанализировано распространение ТЕМ-волны через ячейки и рассчитаны их S-параметры. Выполнен сравнительный анализ рассмотренных ячеек и сделаны выводы о возможности их использования для проведения точных измерений комплексной диэлектрической проницаемости в диапазоне частот от 0.01 до 16 ГГц. Рассмотрены особенности различных вариантов конструкции коаксиальной ячейки с точки зрения технической реализации. Приведены экспериментальные результаты коэффициента стоячей волны напряжения для одного из вариантов предлагаемых конструкций. Наблюдается хорошее согласование экспериментальных данных с результатами численного моделирования в диапазоне частот 0.01-12 ГГц. Расхождение модельных и экспериментальных данных в диапазоне частот 12-16 ГГц можно объяснить погрешностями в геометрии ячейки и конечной проводимостью используемых проводников.Some variants of coaxial measuring cells for 50 Ohm line and complex permittivity measurements of liquid and disperse matters in 0.01-16 GHz frequency band has been considered. Numerical modeling using finite difference method in time domain has been carried out. TEM-wave propagation through cells has been analyzed and S-parameters were calculated. Comparative analysis of considered cells has been carried out. Conclusions about its application to complex permittivity measurement in frequency band 0.01-16 GHz has been formulated. Technical features of arbitrary variants have been considered. Experimental results of the voltage standing wave ratio for one of the variants of the proposed designs have been presented. Good agreement between the experimental data and the results of numerical modeling in a frequency band 0.01-12 GHz is observed. The disagreement between the model and experimental data in the frequency band 12-16 GHz can be explained by the errors in the cell geometry and the finite conductivity of the conductors.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fokina V. D., Bovina A. F., Bogdanov E. V., Pogorel'tsev E. I., Laptash N. M., Gorev M. V., Flerov I. N.
Заглавие : Specific heat, cell parameters, phase T-p diagram, and permittivity of cryolite (NH4)(3)Nb(O-2)(2)F-4
Разночтения заглавия :авие SCOPUS: Specific heat, cell parameters, phase T-p diagram, and permittivity of cryolite (NH4)3Nb(O2)2F4
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2011. - Vol. 53, Is. 10. - P2147-2153. - ISSN 1063-7834, DOI 10.1134/S1063783411100131
Примечания : Cited References: 19. - This study was performed within the Interdisciplinary integration project of the Siberian Branch of the Russian Academy of Science no. 34 and supported by the grant of the President of the Russian Federation for Leading Scientific Schools of the Russian Federation (NSh-4645.2010.2).
Предметные рубрики: CRYSTAL-STRUCTURES
TRANSITIONS
(NH4)(3)TIOF5
OXYFLUORIDE
COMPLEXES
CAPACITY
DISORDER
Аннотация: The temperature dependences of the specific heat, unit cell parameters, susceptibility to hydrostatic pressure, and permittivity of cryolite (NH4)(3)Nb(O-2)(2)F-4 have been studied. Phase transitions of nonferroelectric nature have been detected. Entropy parameters point to the relation of structure distortions to ordering processes.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Divin A., Markidis S., Lapenta G., Semenov V. S., Erkaev N. V., Biernat H. K.
Заглавие : Model of electron pressure anisotropy in the electron diffusion region of collisionless magnetic reconnection
Коллективы :
Место публикации : Phys. Plasmas: AMER INST PHYSICS, 2010. - Vol. 17, Is. 12. - Ст.122102. - ISSN 1070-664X, DOI 10.1063/1.3521576
Примечания : Cited References: 42. - The present work is supported partially by the Onderzoekfonds KU Leuven (Research Fund KU Leuven) and by the European Commission's Seventh Framework Programme (FP7/2007-2013) under grant Agreement No. 218816 (SOTERIA project, www.soteria- space.eu). Additional support is provided by RFBR (Grant No. 09-05-91000-ANF-a). V.S.S. thanks ISSI for hospitality and financial support. The simulations were conducted on the resources of the Vlaams Supercomputer Centrum (VSC) at the Katholieke Universiteit Leuven.
Предметные рубрики: CURRENT SHEETS
X-LINE
PLASMA
DISSIPATION
FIELD
SIMULATIONS
ACCELERATION
TRANSPORT
Ключевые слова (''Своб.индексиров.''): analytical results--antiparallel configuration--collisionless--electron diffusion--electron population--electron pressures--magnetic reconnections--neutral line--new model--particle-in-cell simulations--two particles--anisotropy--astrophysics--collisionless plasmas--computer simulation--diffusion--geophysics--magnetic fields--magnetic properties--plasma simulation--electrons
Аннотация: A new model of the electron pressure anisotropy in the electron diffusion region in collisionless magnetic reconnection is presented for the case of antiparallel configuration of magnetic fields. The plasma anisotropy is investigated as source of collisionless dissipation. By separating electrons in the vicinity of the neutral line into two broad classes of inflowing and accelerating populations, it is possible to derive a simple closure for the off-diagonal electron pressure component. The appearance of these two electron populations near the neutral line is responsible for the anisotropy and collisionless dissipation in the magnetic reconnection. Particle-in-cell simulations verify the proposed model, confirming first the presence of two particle populations and second the analytical results for the off-diagonal electron pressure component. Furthermore, test-particle calculations are performed to compare our approach with the model of electron pressure anisotropy in the inner electron diffusion region by Fujimoto and Sydora [Phys. Plasmas 16, 112309 (2009)]. (C) 2010 American Institute of Physics. [doi:10.1063/1.3521576]
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aver'yanov E. M.
Заглавие : Local-Field Anisotropy of a Light Wave in Quasi-Two-Dimensional Soft-Matter Objects
Коллективы :
Разночтения заглавия :авие SCOPUS: Local-field anisotropy of a light wave in quasi-two-dimensional soft-matter objects
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 110, Is. 4. - P622-636. - ISSN 1063-7761, DOI 10.1134/S1063776110040102
Примечания : Cited References: 73. - This study was supported by the Presidium of the Russian Academy of Sciences within the Program of Basic Research (project no. 27.1) and the Siberian Branch of the Russian Academy of Sciences within the Program of Interdisciplinary Basic Research (project no. 5).
Предметные рубрики: INTEGRATED OPTICAL TECHNIQUES
LANGMUIR-BLODGETT-FILMS
SMECTIC LIQUID-CRYSTALS
UNIAXIAL POLYMER-FILMS
MOLECULAR-ORIENTATION
INTERNAL FIELD
DIELECTRIC-CONSTANT
SPECTRAL FEATURES
REFRACTIVE-INDEX
THIN-FILMS
Ключевые слова (''Своб.индексиров.''): anisotropic films--bilayer lipid membrane--chemical structure--comblike polymers--conductive polymer--discotics--dispersion of refractive index--experimental data--experimental values--hexatic-b phase--isotropization--langmuir films--light wave--lorentz--macromolecular polymers--model approach--molecular polarizabilities--optical axis--order parameter--orientational order parameters--orientational orderings--orientational orders--smectic layers--smectic-a--smectics--soft matter--structural unit--sub-micron films--substrate types--tensor components--visible range--anisotropy--cell membranes--conductive plastics--conjugated polymers--electronic structure--light measurement--liquid crystal polymers--molecules--multilayer films--organic polymers--phase transitions--polarization--polymers--refractive index--substrates--tensors--two dimensional--conductive films
Аннотация: Experimental values of the Lorentz tensor components L-j for uniaxial quasi-two dimensional "soft matter" objects on substrates (bilayer lipid membranes, multilayer Langmuir films, smectics A, hexatic smectics B, submicron films of discotics Col(hd), micron anisotropic films of liquid-crystal comblike polymers and macromolecular polymers, submicron films of conjugated conductive polymers), freely suspended sub-micron films of smectics A, and uniaxially stretched micron films of conjugated conductive polymers have been determined using dispersion of refractive indices in the visible range. The dependences of the components L-j on the type of orientation (axial, planar) of uniaxial molecules (structural units of the film) with respect to the optical axis of the film, the film thickness, the substrate type, the chemical structure of molecules, and their long-range orientational order are established. It is revealed that the smectic A-hexatic B phase transition and two-dimensional crystallization of the smectic layer lead to changes in the components L-j due to the change in the orientational ordering of molecules as a result of the relation between the orientational and hexatic order parameters. All the above objects are characterized by isotropization of the Lorentz tensor L and the local-field tensor f with a simultaneous decrease in the birefringence of the sample and in the anisotropy of the molecular polarizability due to the change in the electronic structure of molecules. The correction for the anisotropy of the local-field tensor f to the orientational order parameter or the anisotropy of the molecular polarizability increases. The existing model approaches to calculating the components L-j for the objects under consideration are compared with the experimental data.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ding Y., Haskel D., Ovchinnikov S. G., Tseng Y. C., Orlov Y. S., Lang J. C., Mao H. K.
Заглавие : Novel pressure-induced magnetic transition in magnetite (Fe(3)O(4))
Разночтения заглавия :авие SCOPUS: Novel pressure-induced magnetic transition in magnetite (Fe3O4)
Место публикации : Phys. Rev. Lett.: AMER PHYSICAL SOC, 2008. - Vol. 100, Is. 4. - Ст.45508. - ISSN 0031-9007, DOI 10.1103/PhysRevLett.100.045508
Примечания : Cited References: 39
Предметные рубрики: MULTIPLE-SCATTERING THEORY
X-RAY DICHROISM
LOWER MANTLE
VERWEY TRANSITION
K-EDGE
CIRCULAR-DICHROISM
SPIN TRANSITION
BAND-STRUCTURE
IRON
FE
Ключевые слова (''Своб.индексиров.''): emission spectroscopy--magnetoelectronics--pressure effects--synchrotron radiation--diamond anvil cell--magnetic transition--x-ray magnetic circular dichroism--magnetite
Аннотация: Fe K-edge x-ray magnetic circular dichroism of magnetite (Fe(3)O(4)) powders was measured with synchrotron radiation under variable pressure and temperature conditions in diamond anvil cell. The magnetic dichroism was observed to decrease discontinuously by similar to 50% between 12 and 16 GPa, independent of temperature. The magnetic transition is attributed to a high-spin to intermediate-spin transition of Fe(2+) ions in the octahedral sites and could account for previously observed structural and electrical anomalies in magnetite at this pressure range. The interpretation of x-ray magnetic circular dichroism data is supported by x-ray emission spectroscopy and theoretical cluster calculations.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kodirov M. K., Popov A. K., Slabko V. V., Yakhnin V. Z.
Заглавие : Atom-density distribution in a metal vapor cell studied by 3rd-harmonic generation
Разночтения заглавия :авие SCOPUS: Atom-density distribution in a metal vapor cell studied by third-harmonic generation
Место публикации : Appl. Phys. B. - 1988. - Vol. 45, Is. 1. - P.47-52. - ISSN 0721-7269, DOI 10.1007/BF00692341
Примечания : Cited References: 20
Ключевые слова (''Своб.индексиров.''): 42.65--42.80--cesium and alloys - applications--light - nonlinear optical effects--spectroscopy - measurements--atom-density distribution--cesium vapors--metal vapor cell--third-harmonic generation--vapors
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volova T. G., Vinogradova O. N., Zhila N. O., Peterson I. V., Kiselev E. G., Vasiliev A. D., Sukovatiy A. G., Shishatskaya E. I.
Заглавие : Properties of a novel quaterpolymer P(3HB/4HB/3HV/3HHx)
Место публикации : Polymer: Elsevier, 2016. - Vol. 101. - P.67-74. - ISSN 00323861 (ISSN), DOI 10.1016/j.polymer.2016.08.048
Ключевые слова (''Своб.индексиров.''): physicochemical and mechanical properties--polyhydroxyalkanoates--quaterpolymers--biocompatibility--cell culture--chain length--chains--decomposition--3-hydroxyhexanoate--degrees of crystallinity--elongation at break--physico-chemical and mechanical properties--polyhydroxyalkanoates--quaterpolymers--short chain lengths--thermal decomposition temperature--film preparation
Аннотация: Cupriavidus eutrophus В10646 was used to synthesize a series of polyhydroxyalkanoate (PHA) quaterpolymers composed of the short-chain-length 3-hydroxybutyrate (3HB), 4-hydroxybutyrate (4HB), and 3-hydroxyvalerate (3HV) and the medium-chain-length 3-hydroxyhexanoate (3HHx). The molar fraction of 3HB in the quaterpolymers varied between 63.5 and 93.1 mol.%, 3HV – between 1.1 and 24.6 mol.%, 4HB – between 2.4 and 15.6 mol.%, and 3HHx – between 0.4 and 4.8 mol.%. The properties of PHA quaterpolymers were significantly different from those of the P(3HB) homopolymer: they had much lower degrees of crystallinity (up to 30–45%), and lower melting points and thermal decomposition temperatures, with the interval between these temperatures remaining practically unchanged. Films prepared from PHA quaterpolymers were rougher and more porous than P(3HB) films; they showed higher values of elongation at break (up to 6–113%), i.e. were more elastic. Films prepared from PHA quaterpolymers were biocompatible and had no toxic effect on mouse fibroblast NIH 3T3 cells. © 2016 Elsevier Ltd
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Morozov E. V., Falaleev O. V., Martyanov O. N.
Заглавие : New insight into the wax precipitation process: in situ NMR imaging study in a cold finger cell
Место публикации : Energy Fuels: American Chemical Society, 2016. - Vol. 30, Is. 11. - P.9003-9013. - ISSN 08870624 (ISSN), DOI 10.1021/acs.energyfuels.6b01535
Примечания : Cited References: 69. - This research was performed with the financial support of the Russian Science Foundation (Project No. 15-19-00119).
Ключевые слова (''Своб.индексиров.''): cells--crude oil--cytology--deposits--diffusion--gelation--magnetic resonance imaging--ostwald ripening--phase separation--polymer blends--deposit formation--deposit structures--diffusion controlled growth--dominant mechanism--lower temperatures--morphology and dynamics--phase-separation process--temperature regimes--image processing
Аннотация: A cold finger cell intended for the wax deposition measurements was fabricated and integrated into an NMR imaging probe for the noninvasive study of wax precipitation processes in situ. The cell was first tested with a model system; then, a series of experiments with different thermal gradients applied to the cell were performed for a waxy crude oil. NMR imaging of the operating cell revealed the formation of a deposit with the morphology and dynamics strongly correlating with the temperature regime. At higher temperatures of cold finger, the incipient wax gel ages uniformly, giving rise to the hard and thin inner layer of deposit accompanied by a branched loosely consolidated outer layer. Conversely, the lower temperatures facilitate formation of a thick deposit which no longer ages uniformly and slow down the diffusion-controlled growth of the branched deposit structure. The results obtained are consistent with the majority of the data previously reported. Thus, gelation of the wax at temperatures below the cloud point and subsequent thermal-driven diffusion processes are considered to be the dominant mechanisms of the deposit formation. The counter diffusion and Ostwald ripening aging concepts were found to be relevant in the case of the cold finger study and account for the phenomena observed in this work. The information obtained via NMR imaging is highly complementary to the results obtained by other techniques that can aid in understanding the essential processes behind the wax precipitation phenomena. The approach developed can be effectively extended to study any thermal-driven phase separation process. © 2016 American Chemical Society.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zamay T. N., Zamay G. S., Belyanina I. V., Zamay S. S., Denisenko V. V., Kolovskaya O. S., Ivanchenko T. I., Grigorieva V. L., Garanzha I. V., Veprintsev D. V., Glazyrin Y. E., Shabanov A. V., Prinz V., Seleznev V. A., Sokolov A. E., Prokopenko V. S., Kim P. D., Gargaun A., Berezovski M. V., Zamay A. S.
Заглавие : Noninvasive microsurgery using aptamer-functionalized magnetic microdisks for tumor cell eradication
Место публикации : Nucl. Acid Therapeutics. - 2017. - Vol. 27, No. 2. - P.105-114. - DOI 10.1089/nat.2016.0634
Примечания : Cited References: 18
Ключевые слова (''Своб.индексиров.''): aptamer--magnetic microdisks--magnetodynamic therapy--tumor eradication
Аннотация: Magnetomechanical cell disruption using nano- and microsized structures is a promising biomedical technology used for noninvasive elimination of diseased cells. It applies alternating magnetic field (AMF) for ferromagnetic microdisks making them oscillate and causing cell membrane disruption with cell death followed by apoptosis. In this study, we functionalized the magnetic microdisks with cell-binding DNA aptamers and guided the microdisks to recognize cancerous cells in a mouse tumor in vivo. Only 10 min of the treatment with a 100 Hz AMF was enough to eliminate cancer cells from a malignant tumor. Our results demonstrate a good perspective of using aptamer-modified magnetic microdisks for noninvasive microsurgery for tumors.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sutormin V. S., Timofeev I. V., Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Orientational transition in the cholesteric layer induced by electrically controlled ionic modification of the surface anchoring
Коллективы : Russian Foundation for Basic Research (RFBR) [15-02-06924, 16-53-00073]; Siberian Branch of the Russian Academy of Sciences [II.2P 0358-2015-0010]; RFBR [16-32-60036, 16-32-00164]
Место публикации : Liq. Cryst.: Taylor & Francis, 2017. - Vol. 44, Is. 3. - P.484-489. - ISSN 0267-8292, DOI 10.1080/02678292.2016.1218557. - ISSN 1366-5855(eISSN)
Примечания : Cited References:38. - This work was supported by Russian Foundation for Basic Research (RFBR) [Grant Numbers 15-02-06924 and 16-53-00073] and by the Siberian Branch of the Russian Academy of Sciences under Complex Program [II.2P 0358-2015-0010]. V.S.S. acknowledges financial support from RFBR [Grant Numbers 16-32-60036 and 16-32-00164].
Предметные рубрики: NEMATIC LIQUID-CRYSTALS
FIELD
DROPLETS
CELL
ALIGNMENT
GRATINGS
Ключевые слова (''Своб.индексиров.''): cholesteric--ionic surfactant--anchoring transition--twisted hybrid--structure--electrooptics
Аннотация: A reorientation of cholesteric liquid crystal with a large helix pitch induced by the electrically controlled ionic modification of the surface anchoring has been studied. In initial state, the cholesteric helix is untwisted completely owing to the normal surface anchoring specified by the cations adsorbed at the substrates. As a result, the homeotropic director configuration is observed within the cell. Under the action of DC electric field, one of the substrates becomes free from the layer of surface active cations, therefore, setting the planar surface anchoring. The latter, in turn, leads to the formation of the hybrid chiral structure. The threshold value and dynamic parameters have been estimated for this process as well as the range of control voltages, which do not allow the electrohydrodynamic instabilities. The twisted hybrid director configuration observed in the experiment has been analysed by means of the simulation of polarisation change of light propagating through the cholesteric layer with asymmetric (planar and homeotropic) surface anchoring on the cell substrates.
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