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1.


   
    Heteronuclear µ-vinylidene complexes containing Re, Cu, Fe, Pt, Pd. Synthesis, structure, IR and NMR spectra [Text] / A. B. Antonova, O. S. Chudin [et al.] // Carbene Chemistry Conference The Ocean Maya. - P. 38


Доп.точки доступа:
Antonova, A.B.; Chudin, O.S.; Rubaylo, A.I.; Pavlenko, N.I.; Sokolenko, W.A.; Verpekin, V.V.; Vasiliev, A.D.; Semeikin, O.V.; Carbene Chemistry Conference The Ocean Maya(2009 ; FEB ; 18-21 ; Playa del Carmen , Mexico)
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2.


   
    Vinylidene carbonylation on the dinuclear MnFe center [Text] / A. B. Antonova, O. S. Chudin [et al.] // Carbene Chemistry Conference The Ocean May. - P. 39


Доп.точки доступа:
Antonova, A.B.; Chudin, O.S.; Sokolenko, W.A.; Rubaylo, A.I.; Pavlenko, N.I.; Verpekin, V.V.; Vasiliev, A.D.; Semeikin, O.V.; Carbene Chemistry Conference The Ocean Maya(2009 ; FEB ; 18-21, ; Playa del Carmen , Mexico)
}
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3.


   
    Определение условий образования наночастиц серебра при восстановлении глюкозой в водных расворах / Е. А. Вишнякова, С. В. Сайкова [и др.] // Журнал Сибирского федерального университета. Серия "Химия". - Т. 2, № 1. - С. 48-55 ; J. Sib. Fed. Univ. Chem.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Вишнякова, Е. А. ; Сайкова, С. В. ; Жарков, Сергей Михайлович; Zharkov, S. M.; Лихацкий, М. Н. ; Михлин, Ю. Л.

}
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4.


   
    Synthesis and properties of the NdSF compound, phase diagram of the NdF3–Nd2S3 system / V. M. Grigorchenko, M. S. Molokeev, A. S. Oreshonkov [et al.] // J. Solid State Chem. - 2024. - Vol. 333. - Ст. 124640, DOI 10.1016/j.jssc.2024.124640. - Cited References: 48. - This research was funded by the Tyumen Oblast Government as part of the West-Siberian Interregional Science and Education Center’s project No. 89-DON (3). - The studies ab initio simulation of electron band structure, analysis of optical properties, XRD analysis was partially supported by "Priority-2030" program for the Siberian Federal University, and the state assignment of Kirensky Institute of Physics . - ISSN 0022-4596. - ISSN 1095-726X
   Перевод заглавия: Синтез и свойства соединения NdSF, фазовая диаграмма системы NdF3–Nd2S3
Кл.слова (ненормированные):
Neodymium fluorosulfide -- Phase diagram -- Optical band gap -- Microhardness
Аннотация: The NdF3–Nd2S3 system attracts attention of researchers due to the possibility of using LnSF compounds (Ln = rare earth element) as possible new p- and n-type materials. The samples of this system were synthesized from NdF3 and Nd2S3. The NdSF compound belongs to the PbFCl structural type, P4/nmm space group, unit cell parameters: a = 3.9331(20) Å, c = 6.9081(38) Å. The experimentally determined direct and indirect NdSF bandgaps are equal to 2.68 eV and 2.24 eV. The electronic band structure was calculated via DFT simulation. The NdSF compound melts congruently at T = 1385 ± 10°С, ΔНm = 40.5 ± 10 kJ/mol, ΔS = 24.4 ± 10 J/mol. The NdSF microhardness is 455 ± 10 HV. Five phase transformations in the NdF3–Nd2S3 system were recorded by DSC; their balance equations were derived. The liquidus of the system calculated from the Redlich–Kister equation is fully consistent with the DSC data.

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Держатели документа:
Tyumen State University, Tyumen, Volodarsky str. 6, 625003, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Akademgorodok str. 50, Building 38, 660036, Russia
Siberian Federal University, Krasnoyarsk, Svobodnyj av. 79, 660079, Russia
Department of Physical and Applied Chemistry, Kurgan State University, Sovetskaya str. 63/4, Kurgan, 640020, Russia
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Yekaterinburg, Pervomaiskaya str. 91, 620990, Russia
Saint-Petersburg State University, 7/9 Universitetskaya Emb., 199034, St. Petersburg, Russia

Доп.точки доступа:
Grigorchenko, V.M.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Kertman, A.V.; Abulkhaev, M.U.; Mereshchenko, A.S.; Yurev, I.O.; Shulaev, N.А.; Kamaev, D.N.; Elyshev, A.V.; Andreev, O.V.
}
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5.


   
    Получение и активация TiO2 фотонно- кристаллических структур для повышения эффективности реакции фотоэлектрохимического разложения воды / Т. А. Кенова, Н. А. Зосько, М. В. Пятнов [и др.] // Журн. СФУ. Химия. - 2024. - Т. 17, № 1. - С. 27-38 ; J. Sib. Fed. Univ. Chem. - Библиогр.: 25. - Исследование выполнено за счет гранта Российского научного фонда и Красноярского краевого фонда поддержки научной и научно-технической деятельности № 22-22-20078, https://rscf.ru/project/22-22-20078/ с использованием оборудования Красноярского регионального центра коллективного пользования ФИЦ КНЦ СО РАН . - ISSN 1998-2836. - ISSN 2313-6049
   Перевод заглавия: Synthesis and activation of TiO2 photonic crystal structures for enhanced photoelectrochemical water splitting
Кл.слова (ненормированные):
фотонно-кристаллические TiO2 наноструктуры -- активация TiO2 фотонных кристаллов -- фотоэлектрохимическая активность -- разложение воды -- photonic-crystal TiO2 nanostructures -- TiO2 photonic crystals activation -- photoelectrochemical activity -- water splitting
Аннотация: Наноструктурированные фотонно-кристаллические пленки TiO2 анодно синтезированы при импульсном и ступенчатом изменениях напряжения. Полученные фотонные структуры активированы методом циклической вольтамперометрии в 0,5M Na2SO4. Фотоэлектрохимическая активность электродов исследована в реакции разложения воды в области длин волн 360–700 нм. Активация приводит к изменению энергии запрещенной зоны, красному сдвигу спектра IPCE и увеличению его значений в исследованном диапазоне длин волн.
TiO2 photonic crystal nanostructure films are anodic synthesized with pulsed and stepwise voltage changes. The obtained photonic structures were activated by cyclic voltammetry in 0.5M Na2SO4. The photoelectrochemical activity of the electrodes was studied in the water splitting reaction in the wavelength range 360–700 nm. Activation leads to a change in the band gap energy, a red shift in the IPCE spectrum and an increase in its values in the studied wavelength range.

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Держатели документа:
Институт химии и химической технологии СО РАН ФИЦ "Красноярский научный центр СО РАН", Российская Федерация, Красноярск
Институт физики им. Л.В. Киренского СО РАН ФИЦ "Красноярский научный центр СО РАН", Российская Федерация, Красноярск
Сибирский федеральный университет, Российская Федерация, Красноярск

Доп.точки доступа:
Кенова, Т. А.; Зосько, Н. А.; Пятнов, Максим Владимирович; Pyatnov, M. V.; Александровский, Александр Сергеевич; Aleksandrovsky, A. S.; Максимов, Н. Г.; Жижаев, А. М.; Таран, О. П.

}
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6.


   
    The phases formed in Sn/Co thin bilayer upon heating / L. Eremin, A. Matsynin, Yu. Balashov [et al.] // J. Solid State Chem. - 2024. - Vol. 334. - Ст. 124693, DOI 10.1016/j.jssc.2024.124693. - Cited References: 33 . - ISSN 0022-4596. - ISSN 1095-726X
Кл.слова (ненормированные):
Thin films -- Solid-state chemistry -- Metallic bilayer -- Annealing
Аннотация: The structure and phases formed in Sn/Co thin films are interesting both from the solid-state chemistry point of view and due to applications of such a metallic bilayer. The phases forming in thin films Sn/Co obtained by thermal vacuum evaporation on two different substrates SiO2 and MgO(100) at different annealing temperatures have been studied. Annealing above 110°С results in intermetallics formation in the films. The hcp-cobalt is grown in the films on SiO2 substrate, and the fcc-Co is observed on MgO(100) substrate. It is found that the stable α-Co3Sn2 intermetallic is formed at higher annealing temperature in film on MgO(100) substrate. We show that transformations related to mass transfer in the Sn/Co bilayers were up to 500°С and were finished upon reaching the thermodynamically equilibrium phase composition at this temperature.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Applied Physics Department, Reshetnev Siberian State University of Science and Technology, 660037, Krasnoyarsk, Russia

Доп.точки доступа:
Eremin, L. A.; Еремин, Леонид Аркадьевич; Matsynin, A. A.; Мацынин, Алексей Александрович; Balashov, Yu. Yu.; Балашов, Юрий Юрьевич; Myagkov, V. G.; Мягков, Виктор Григорьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Bykova, L. E.; Быкова, Людмила Евгеньевна; Komogortsev, S. V.; Комогорцев, Сергей Викторович
}
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7.


   
    Absorption spectra of the purple nonsulfur bacteria light-harvesting complex: A DFT study of the B800 part / L. V. Begunovich, E. A. Kovaleva, M. M. Korshunov, V. F. Shabanov // J. Photochem. Photobiol. A: Chem. - 2024. - Vol. 450. - Ст. 115454, DOI 10.1016/j.jphotochem.2023.115454. - Cited References: 42. - This work was supported by the state assignment of the Ministry of Science and Higher Education of the Russian Federation. Authors would like to thank Information Technology Centre, Novosibirsk State University for providing access to their supercomputers. L.V.B. would like to thank Irkutsk Supercomputer Center of SB RAS for providing the access to HPC-cluster «Akademik V.M. Matrosov» (Irkutsk Supercomputer Center of SB RAS, Irkutsk: ISDCT SB RAS; http://hpc.icc.ru, accessed 20.10.2023) . - ISSN 1010-6030. - ISSN 1873-2666
Кл.слова (ненормированные):
Photosynthesis -- LH2 -- Light harvesting -- Rhodoblastus acidophilus -- Bacteriochlorophyll -- DFT -- DFTB -- Optical spectra
Аннотация: We’ve studied the B800 part of Rhodoblastus acidophilus light-harvesting complex (LH2) by several quantum chemical techniques based on the density functional theory (DFT) and determined the specific method and a minimal reliable model suitable for further studies of the LH2. In addition to bacteriochlorophyll a molecules, the minimal model includes two α and one β chain amino acids. Within the model, we are able to reproduce the contribution of the B800 ring of nine bacteriochlorophyll a molecules to the near infrared Qy absorption band. We also discuss the use of hybrid DFT calculations for precise energy and optical estimations and DFT-based tight binding (DFTB) method for the large-scale calculations. Crucial importance of Hartree-Fock exchange interaction for the correct description of B800 peak position was shown.

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Держатели документа:
Federal Research Center KSC SB RAS, Krasnoyarsk, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia

Доп.точки доступа:
Begunovich, L. V.; Kovaleva, E. A.; Korshunov, M. M.; Коршунов, Максим Михайлович; Shabanov, V. F.; Шабанов, Василий Филиппович
}
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8.


   
    Two-dimensional hybrid perovskite with high-sensitivity optical thermometry sensors / M. Guan, J. Hao, L. Qiu [et al.] // Inorg. Chem. - 2024. - Vol. 63, Is. 8. - P. 3835-3842, DOI 10.1021/acs.inorgchem.3c04140. - Cited References: 37. - This work was supported by the National Natural Science Foundation of China (Grant Nos. 52072349, 52172162, 12374386, and 11974022). Z.D. acknowledges support from the Fundamental Research Funds for the Central Universities, China University of Geosciences (Wuhan) (No.162301202610), the Natural Science Foundation of Guangdong Province (2022A1515012145), and Shenzhen Science and Technology Program(JCYJ20220530162403007). G.L. acknowledges support from the Natural Science Foundation of Zhejiang Province (LR22E020004). M.M. acknowledges the support from the Ministry of Science and High Education of Russian Federation (Project No. FSRZ-2023-0006) . - ISSN 0020-1669. - ISSN 1520-510X
   Перевод заглавия: Двумерный гибридный перовскит с высокочувствительными датчиками оптической термометрии
Аннотация: Optical thermometry has gained significant attention due to its remarkable sensitivity and noninvasive, rapid response to temperature changes. However, achieving both high absolute and relative temperature sensitivity in two-dimensional perovskites presents a substantial challenge. Here, we propose a novel approach to address this issue by designing and synthesizing a new narrow-band blue light-emitting two-dimensional perovskite named (C8H12NO2)2PbBr4 using a straightforward solution-based method. Under excitation of near-ultraviolet light, (C8H12NO2)2PbBr4 shows an ultranarrow emission band with the full width at half-maximum (FWHM) of only 19 nm. Furthermore, its luminescence property can be efficiently tuned by incorporating energy transfer from host excitons to Mn2+. This energy transfer leads to dual emission, encompassing both blue and orange emissions, with an impressive energy transfer efficiency of 38.3%. Additionally, we investigated the temperature-dependent fluorescence intensity ratio between blue emission of (C8H12NO2)2PbBr4 and orange emission of Mn2+. Remarkably, (C8H12NO2)2PbBr4:Mn2+ exhibited maximum absolute sensitivity and relative sensitivity values of 0.055 K–1 and 3.207% K–1, respectively, within the temperature range of 80–360 K. This work highlights the potential of (C8H12NO2)2PbBr4:Mn2+ as a promising candidate for optical thermometry sensor application. Moreover, our findings provide valuable insights into the design of narrow-band blue light-emitting perovskites, enabling the achievement of single-component dual emission in optical thermometry sensors.

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Держатели документа:
Anhui Key Laboratory of Optoelectric Materials Science and Technology, Key Laboratory of Functional Molecular Solids, Ministry of Education Anhui Normal University, Wuhu 241000, China
Faculty of Materials Science and Chemistry, China University of Geosciences, Wuhan 430074, China
Shenzhen Research Institute China University of Geosciences, Shenzhen 518063, China
Zhejiang Institute China University of Geosciences, Hangzhou 311305, China
Department of Materials and Chemical Engineering, Taiyuan University, Taiyuan 030032, China
Department of Physics, Far Eastern State Transport University, Khabarovsk 680021, Russia
Siberian Federal University, Krasnoyarsk 660041, Russia
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Guan, M.; Hao, J.; Qiu, L.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ning, L.; Dai, Zh.; Li, G.
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9.


   
    Highly efficient and thermostable far-red phosphor for promoting root growth in plants / Sh. Ouyang, J. Yin, L. Su [et al.] // J. Mater. Chem. C. - 2024. - Vol. 12, Is. 9. - P. 3272-3279, DOI 10.1039/D3TC02823B. - Cited References: 59. - The authors would like to gratefully acknowledge funds from the National Natural Science Foundation of China (Grant No. 51974123), the Key R&D Projects in Hunan Province (2021SK2047, 2022NK2044), the Natural Science Foundation of Hunan Province, China (Grant No. 2021JJ40261), the Wangcheng Science and Technology Plan (KJ221017), the Science and Technology Innovation Program of Hunan Province (2022WZ1022) and Superior Youth Project of the Science Research Project of Hunan Provincial Department of Education, (22B0211) and the Russian Federation as part of World-class Research Center Program: "Advanced Digital Technologies", contract no. 075-15-2020-935 . - ISSN 2050-7526. - ISSN 2050-7534
   Перевод заглавия: Высокоэффективный и термостабильный инфракрасный люминофор для стимулирования роста корней растений
Аннотация: Phytochrome PFR plays a key role in plant photomorphogenesis, and its perception of far-red light is essential, but how to obtain an efficient far-red phosphor to achieve accurate light filling remains a huge challenge. In this study, Gd1−y−zAl3−x(BO3)4:xCr3+,yLu3+,zSm3+ (GAB:xCr3+,yLu3+,zSm3+) series phosphors were synthesized by a high-temperature solid-state method. By doping Lu3+, the emission intensity of Cr3+ could increase as high as 20%. With the introduction of Sm3+, the emission intensity of Cr3+ was further increased by 29%. Particularly, the emission spectra can be tuned by varying the concentration ratio of Sm3+ and Cr3+, more suitable for the absorption spectrum of PFR. Moreover, the internal quantum yield and external quantum yield of GL0.1AB:0.03Cr3+ and GL0.1AB:0.03Cr3+,0.003Sm3+ were 83.1% and 24.7% and 78.1% and 26.3%, respectively. There were high anti-thermal quenching properties in the prepared phosphors at 423 K, with 107.6% (GAB:0.03Cr3+), 103.1% (GL0.1AB:0.03Cr3+), and 102.7% (GL0.1AB:0.003Sm3+,0.03Cr3+). Finally, the phosphors were made into pc-LED devices, which can realize the adjustable orange-red and far-red luminescence and meet the needs of plant lighting applications. In the light-regulated plant growth experiment, compared with the control group, far-red light promoted root growth in plants, confirming the application potential of the prepared phosphors in indoor plant cultivation.

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Держатели документа:
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, P. R. China
Hunan Rare Earth Metal Material Research Institute Co. Ltd, No. 108 Longyuan 2nd Road, Longping High-tech Park, Changsha, Hunan, P. R. China
Hunan Optical Agriculture Engineering Technology Research Center, Changsha 410128, P. R. China
College of Agronomy, Hunan Agricultural University, Changsha 410128, P. R. China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
World-Class Research Center “Advanced Dicita Technoloaies” University of Tvumen, Russia

Доп.точки доступа:
Ouyang, Sh.; Yin, J.; Su, L.; Yao, M.; Wang, G.; Yang, J.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zhou, Zh.; Zhang, S.; Xia, M.
}
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10.


   
    Solid state synthesis, structural, DFT and spectroscopic analysis of EuAl3(BO3)4 / A. S. Oreshonkov, A. S. Aleksandrovsky, O. D. Chimitova [et al.] // Mater. Chem. Phys. - 2024. - Vol. 320. - Ст. 129400, DOI 10.1016/j.matchemphys.2024.129400. - Cited References: 55. - The work was carried out within the state assignment No FWES-2024-0003 of Kirensky Institute of Physics. This work was partially supported by the state order of BINM SB RAS (0273-2021-0008). The samples for this research were synthesized using equipment of the CCU BINM SB RAS. The reflectance spectrum was obtained at the Center for Optical and Laser Materials Research of Research park of St. Petersburg State University. The SEM measurements were performed at Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" . - ISSN 0254-0584. - ISSN 1879-3312
   Перевод заглавия: Твердофазный синтез, структурный, квантово-химический (DFT) и спектроскопический анализ EuAl3(BO3)4
Кл.слова (ненормированные):
EuAl(BO) -- Huntite -- X-ray diffraction -- SEM -- DFT -- Charge transfer -- Raman -- Infrared -- Luminescence
Аннотация: Huntite-like borates are versatile and promising materials with wide range of applications in frequency conversion, UV light generation, lighting, displays, quantum information storage, and more, demonstrated by their various properties and uses in scientific research. In this work, EuAl3(BO3)4 powder was prepared through multi-stage solid-state reaction method using high-purity starting reagents: Eu2O3, Al2O3 and H3BO3, considering a 20 wt% excess of H3BO3 to compensate for B2O3 volatilization. Obtained samples undergo several treatments at varying temperatures and their phase purity is subsequently verified through powder X-ray diffraction analysis. The scanning electron microscopy reveals that resulting EuAl3(BO3)4 powder consists of granules exhibiting irregular morphologies with dimensions of 0.5–8 μm. The electronic band structure of EuAl3(BO3)4, calculated using the GGA PBE method, reveals f-states of Eu near 4 eV. These states do not produce emphasized peaks on simulated absorbance spectra. Using of DFT + U for the f-states of Eu pushed up f-bands above 6 eV and the charge transfer from p-O to d-Eu was obtained (Egdirect = 5.63 eV, Egindirect = 5.37 eV using Ueff = 4 eV). The variation of Ueff has a weak influence on the position of the bottom of the conduction band. The experimental bandgaps of EuAl3(BO3)4 crystalline powder, both direct and indirect, are found to be 3.96 and 3.67 eV, correspondingly. These values are lower than theoretical values what is associated with limitations of DFT calculations involving f electrons. The Raman spectrum of EuAl3(BO3)4 powder is discussed, detailing the contributions of different ions to specific spectral bands. Investigation of high-resolution luminescence spectra shows the possibility to estimate the content of defects by the testing the violation of the prohibition of ultranarrow 5D0 → 7F0 line that is forbidden in the ideal crystalline structure of trigonal EuAl3(BO3)4.

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Держатели документа:
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
School of Engineering and Construction, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Oxide Systems, Baikal Institute of Nature Management, SB RAS, Ulan-Ude, 670047, Russia
Center for Optical and Laser Materials Research, Saint-Petersburg State University, Saint-Petersburg, 199034, Russia
Emanuel Institute of Biochemical Physics of Russian Academy of Sciences, Moscow, 119334, Russia
Plekhanov Russian University of Economics, Moscow, 117997, Russia
Moscow Institute of Physics and Technology, Dolgoprudny, 141700, Russia
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
School of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russia
Institute of Automation and Electrometry, Russian Academy of Sciences, Novosibirsk, 630090, Russia
Department of Molecular Electronics, Federal Research Center Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, 660036, Russia
Institute of Fundamental Biology and Biotechnology, Siberian Federal University, Krasnoyarsk, 660041, Russia

Доп.точки доступа:
Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chimitova, O.D.; Pankin, D.V.; Popov, Z.I.; Sukhanova, E.V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Adichtchev, S.V.; Pugachev, A.M.; Nemtsev, I. V.; Немцев, Иван Васильевич
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