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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Andryushchenko T. A., Lyashchenko S. A., Varnakov S. N., Lukyanenko A. V., Nemtsev I. V., Yakovlev I. A., Shevtsov D. V., Maximova O. A., Ovchinnikov S. G.
Заглавие : Auger electron spectroscopy of thin Cr2GeC films
Колич.характеристики :7 с
Место публикации : Phys. Met. Metallogr. - 2023. - Vol. 124, Is. 14. - P.1776-1782. - ISSN 0031918X (ISSN), DOI 10.1134/S0031918X2360135X. - ISSN 15556190 (eISSN)
Примечания : Cited References: 33. - The research was supported by the Russian Science Foundation (grant no. 21-12-00226, http://rscf.ru/project/21-12-00226/)
Аннотация: Auger electron spectroscopy was used to determine the phase composition of Cr2GeC MAX phase thin films. A distinctive feature of the formation of carbon-containing MAX phases is the shape of carbon Auger peaks, which is characteristic of metal carbides spectra. Features of the Auger spectra in the presence of secondary phases of chromium germanides are found. Their presence can manifest itself in an increase in the energy of the germanium peaks, which is caused by a chemical shift during the formation of the Cr–Ge bond. Moreover, we have detected the accumulation of electronic charge, which can be explained by the features of the surface morphology.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Berzhanskii V. N., Gavrichkov S. A., Ivanov V. I., Kalinnikov V. T.
Заглавие : Bond formation effect on the g-factor of chalcogenide chromium spinels
Место публикации : Fiz. Tverd. Tela. - 1982. - Vol. 24, Is. 3. - P.945-948. - ISSN 0367-3294
Примечания : Cited References: 15
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gavrichkov V. A., Ivanova N. B., Ovchinnikov S. G., Balaev A. D., Aminov T. G., Shabunina G. G., Chernov V. K., Petukhov M. V.
Заглавие : Comparison of negative magnetoresistance mechanisms in manganese perovskites and chromium spinels
Место публикации : Phys. Solid State: AMER INST PHYSICS, 1999. - Vol. 41, Is. 10. - P1652-1655. - ISSN 1063-7834, DOI 10.1134/1.1131064
Примечания : Cited References: 17
Предметные рубрики: ANISOTROPIC MAGNETORESISTANCE
TRANSPORT-PROPERTIES
THIN-FILMS
ALLOYS
Аннотация: A transition of the field dependence of the electrical resistivity from a square law (similar to H-2) above T-c to a linear function (similar to H) below T-c is observed in the degenerate ferromagnetic semiconductor HgCr2Se4(n). Together with the large negative magnetoresistance, these magnetoelectric effects correspond to effects observed in the perovskite-type oxides La1-xCaxMnOdelta. Inasmuch as the undoped semiconductor HgCr2Se4 is a ferromagnet with approximately the same critical temperature as the doped semiconductor and in view of the total lack of data on the Jahn-Teller effect in this compound, we infer that our results cast doubt on existing hypotheses (polaron and binary exchange) regarding the origin of the giant magnetoresistance in La1-xCaxMnOdelta. Impurity sd scattering is discussed as a possible magnetoresistance mechanism for both compounds. (C) 1999 American Institute of Physics. [S1063-7834(99)01710-4].
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Udod L. V., Sitnikov M. N., Kretinin V. V., Molokeev M. S., Mironova-Ulmane N.
Заглавие : Dipole glass in chromium-substituted bismuth pyrostannate
Коллективы : Russian Foundation for Basic Research [N 18-52-00009 Bel_a, 18-32-00079 mol_a, 3.5743.2017/6.7]
Место публикации : Mater. Res. Express. - 2018. - Vol. 5, Is. 11. - Ст.115202. - ISSN 2053-1591, DOI 10.1088/2053-1591/aaddd9
Примечания : Cited References: 33. - This study was supported by the Russian Foundation for Basic Research project N 18-52-00009 Bel_a, No 18-32-00079 mol_a, the state order No 3.5743.2017/6.7.
Предметные рубрики: BI4TI3O12 THIN-FILMS
NEUTRON-DIFFRACTION
RAMAN-SPECTROSCOPY
BI2SN2O7
Ключевые слова (''Своб.индексиров.''): dipole glass--permittivity--polarization--raman scattering spectra--structural transition
Аннотация: To establish the existence of dipole glass in the chromium-substituted bismuth pyrostannate solid solutions, the frequency and temperature dependences of the permittivity have been measured in the temperature range of 300–750 K. The field and dynamic dependences of polarization in the temperature range of 80–550 K have been determined. Using the Raman scattering spectra, the absence of inversion center has been established. The maximum of electrical resistance has been found in the vicinity of the dipole moment freezing point. The carrier type has been determined from the thermopower data. The polarization relaxation is shown to be nonexponential. The experimental data are explained within the model of dipole glass in the α- phase and the model of charged crystalline domain walls with the electron-polarization relaxation mechanism above the α–β structural transition.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tomilin F. N., Shubin A. A., Kozak V. V., Ivanova D. A., Fedorova N. A., Ol’shevskaya Y. S., Kovaleva A. V., Avramov P. V., Ovchinnikov S. G.
Заглавие : Effect of substitution on magnetic moments of iron and chromium atoms in MAX phases of type (Cr4 – xFex)0.5SiC: Theoretical calculation
Место публикации : Phys. Met. Metallogr. - 2022. - Vol. 123, Is. 7. - P.640-644. - ISSN 0031918X (ISSN), DOI 10.1134/S0031918X22070195
Примечания : Cited References: 25. - The study is supported by the Russian Science Foundation (project no. 21-12-00226) and by the Interagency Supercomputer Center of the Russian Academy of Sciences (MVS-100K and MVS-10P)
Аннотация: MAX phases are a family of ternary layered compounds with formal stoichiometry M2AX and have a layered hexagonal structure. Calculations with the B3LYP density functional show that, by varying the ratio between the chromium and iron in the MAX phase (Cr4 – xFex)0.5SiC, it is possible to change the lattice parameters and the magnetic moment on metal atoms. In this phase, a partial substitution of one metal for the other can be considered a technique of intended variation of their magnetic properties.
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6.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Mikhashenok N. V., Pankrats A. I., Gudim I. A., Skorobogatov S. A., Molokeev M. S.
Заглавие : Effect of synthesis conditions on the magnetic properties of chromium borate single crystals
Коллективы : International Baltic Conference on Magnetism, Балтийский федеральный университет им. И. Канта
Место публикации : V International Baltic Conference on Magnetism. IBCM: Book of abstracts. - 2023. - P.127
Примечания : Cited References: 5. - РФН № 22-12-20019 ; Красноярский регион. фонд науки
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivantsov R. D., Edelman I. S., Zharkov S. M., Velikanov D. A., Petrov D. A., Ovchinnikov S. G., Lin C.-R., Li O., Tseng Y.-T.
Заглавие : Effects of processing parameters on the morphology, structure, and magnetic properties of Cu1-xFexCr2Se4 nanoparticles synthesized with chemical methods
Место публикации : J. Alloys Compd.: Elsevier, 2015. - Vol. 650. - P.887-895. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2015.08.017
Примечания : Cited References: 36. - The paper was partially supported by the Russian Foundation for Basic Research (grant #14-02-01211), by the President of Russia (grant #NSh-2886.2014.2), and by the Ministry of Education and Science of the Russian Federation (grant #2014/71/1763 in the framework of the state assignment for the Siberian Federal University for 2014-2016). We also thank the Ministry of Science and Technology of Taiwan and the Siberian Branch of RAS (MOST 102-2112-M-153 -002 -MY3) for financial support.
Предметные рубрики: CuCr2Se4 SINGLE-CRYSTALS
TRANSPORT-PROPERTIES
CHROMIUM SPINELS
NANOSTRUCTURES
DIFFRACTION
Li
Ключевые слова (''Своб.индексиров.''): copper selenide--magnetic nanoparticles--visible magnetic circular dichroism
Аннотация: Cu1-xFexCr2Se4 nanoparticles with x = 0, 0.2, and 0.4 were synthesized via thermal decomposition of metal nitrate or chloride salts and selenium powder using different precursor compositions and processing details. Single crystalline nano-belts or nano-rods coexist in the synthesized powder samples with hexagon-shaped plates in dependence on the precursor composition. The belts gathered into conglomerates forming "hierarchical" particles. Visible magnetic circular dichroism (MCD) of Cu1-xFexCr2Se4 nanoparticles embedded into a transparent matrix was investigated for the first time. The similarity of the MCD spectra of all samples showed the similarity of the nanoparticles electronic structure independent of their morphology. Basing on the MCD spectral maxima characteristics, electron transitions from the ground to the excited states were identified with the help of the conventional band theory and the multi-electron approach. © 2015 Elsevier B.V.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abramova G. M., Patrin G. S., Kiselev N. I., Petrakovskii G. A.
Заглавие : Electrical properties of chromium films
Место публикации : Phys. Solid State. - 1999. - Vol. 41, Is. 3. - P.341-343. - ISSN 1063-7834, DOI 10.1134/1.1130779
Примечания : Cited References: 11
Предметные рубрики:
Аннотация: We have investigated experimentally the influence of a constant electric current on the magnitude and temperature dependence of the resistance of chromium films prepared by vacuum-thermal condensation. The results are interpreted in terms of the Frohlich conductivity model. (C) 1999 American Institute of Physics. [S1063-7834(99)00303-2].
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Zharkov S. M., Pankrats A. I., Vorotynov A. M., Tugarinov V. I., Ivantsov R. D., Petrov D. A., Velikanov D. A., Lin C. -R., Chen C. -C., Tseng Y. -T., Hsu H. -S.
Заглавие : Electron spin resonance in Cu1−xFexCr2Se4 nanoparticles synthesized with the thermal decomposition method
Место публикации : J. Magn. Magn. Mater.: Elsevier, 2017. - Vol. 436. - P.21-30. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2017.04.006
Примечания : Cited References: 34. - The paper was partially supported by the President of Russia (Grant #NSh-7559.2016.2). We also thank the Ministry of Science and Technology of Taiwan, Taiwan, and the Siberian Branch of RAS, Russian Federation (MOST 102-2112-M-153-002-MY3) for the financial support.
Ключевые слова (''Своб.индексиров.''): anisotropy--association reactions--chromium compounds--decomposition--electrospinning--inorganic compounds--magnetic moments--magnetocrystalline anisotropy--nanoparticles--plates (structural components)--resonance--spin dynamics--synthesis (chemical)--temperature distribution--thermolysis--inter-particle interaction--nanoparticle (nps)--resonance spectrum--single-crystalline--temperature behavior--temperature decrease--temperature dependence--thermal decomposition methods--electron spin resonance spectroscopy
Аннотация: IIn this paper, we present a study of the electron spin resonance (ESR) of nanoparticles (NPs) of Cu1−xFexCr2Se4 chalcogenides with x = 0, 0.2, and 0.4. NPs were synthesized via the thermal decomposition of metal chloride salts and selenium powder in a high-temperature organic solvent. According to the XRD and HRTEM data, the NPs were single crystalline nearly hexagonal plates with the structure close to CuCr2Se4 (Fd-3m, a = 10.337 Å). For x = 0 and 0.2, the NPs tend to form long stacks consisting of the plates “face to face” attached to each other due to the magnetostatic interparticle interaction. Only separate NPs were observed in the case of x = 0.4. Peculiarities were revealed in the ESR temperature behavior for the NPs with x = 0 and 0.2 consistent with the features in the temperature dependences of the NPs magnetization. The non-monotonous dependence of the resonance field Hres on the temperature with a kink near 130 K and the energy gap in the resonance spectrum depending on the type of nanoparticle compacting are the distinct peculiarities. One of the main factors is discussed in order to explain the peculiarities: the coexistence of two types of anisotropy in the Cu1−xFexCr2Se4 NPs, in-plain shape anisotropy and magnetocrystalline anisotropy with four easy axes, which increases strongly with the temperature decrease.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Berzhanskii V. N., GAVRICHKOV S. A., IVANOV V. I.
Заглавие : Electron-paramagnetic-res relaxation in chromium chalcogenide spinels
Место публикации : Fiz. Tverd. Tela. - 1982. - Vol. 24, Is. 7. - P.2215-2218. - ISSN 0367-3294
Примечания : Cited References: 8
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