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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Petrakovskaya E. A., Bulina N. V., Churilov G. N., Puzyr' A. P.
Заглавие : A study of the synthesis products of fullerenes with nickel and cobalt
Место публикации : Tech. Phys.: AMER INST PHYSICS, 2001. - Vol. 46, Is. 1. - P42-46. - ISSN 1063-7842, DOI 10.1134/1.1340883
Примечания : Cited References: 15
Предметные рубрики: COMPLEXES
SPECTRA
Аннотация: Qualitative analysis of the products of plasmochemical synthesis of fullerenes with metallic nickel and cobalt has been carried out using electron paramagnetic resonance (EPR) and electron microscopy. These studies show that the synthesis products are mainly fullerenes, metallic nanoparticles coated with an insulating layer, and isolated atomic clusters. (C) 2001 MAIK "Nauka/Interperiodica".
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Avramov P. V., Sakai S., Entani S., Matsumoto Y., Naramoto, Hiroshi
Заглавие : Ab initio LC-DFT study of graphene, multilayer graphenes and graphite
Место публикации : Chem. Phys. Lett.: Elsevier Science BV, 2011. - Vol. 508, Is. 1-3. - P.86-89. - ISSN 0009-2614, DOI 10.1016/j.cplett.2011.04.016
Примечания : Cited References: 32. - This work was supported by JAEA Research fellowship (P.V.A.). P.V.A. also acknowledges JAEA ASRC and Molecular Spintronics Group for hospitality and fruitful collaboration.
Предметные рубрики: DENSITY
NANORIBBONS
PERFORMANCE
FUNCTIONALS
FULLERENE
COBALT
FILMS
Аннотация: Atomic structure of graphene, bi-, tri-, tetralayer graphenes and graphite as well was studied using ab initio HSE, LDA and PBE DFT approaches in periodic boundary conditions. Based on comparison of theoretical results with experimental data the performance of the methods was estimated. It was found that long-range corrected HSE potential is the most reliable DFT approximation to reproduce the atomic structure of weakly bound multilayer graphenes and graphite as well. (C) 2011 Elsevier B. V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chzhan A. V., Podorozhnyak S. A., Mal'tsev V. K., Krayukhin I. N., Patrin G. S.
Заглавие : Allotropic modifications of cobalt upon chemical deposition
Место публикации : Phys. Solid State. - 2021. - Vol. 63, Is. 1. - P.42-46. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783421010054
Примечания : Cited References: 17. - This study was supported in part by the Russian Foundation for Basic Research, project no. 18-02-00161-a
Аннотация: The effect of the solution acidity on the crystal structure of cobalt during its chemical deposition is reported. It has been shown using the structural and magnetic examination and nuclear magnetic resonance study that the change in the working solution acidity leads to deposition of cobalt with different allotropic modifications in the nearest environment: the hcp type in the small (up to ~8.5) pH region and the fcc type in the large (over ~8.5) pH region. The formation of these cobalt modifications is attributed to the size effects caused by a decrease in the particle size with increasing pH.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Stolyar S. V., Li O. A., Nikolaeva E. D., Vorotynov A. M., Velikanov D. A., Knyazev Yu. V., Bayukov O. A., Iskhakov R. S., P’yankov V. F., Volochaev M. N.
Заглавие : An effective method of magnetic hyperthermia based on the ferromagnetic resonance phenomenon
Место публикации : Phys. Met. Metallogr. - 2023. - Vol. 124, Is. 2. - P.174-180. - ISSN 0031918X (ISSN), DOI 10.1134/S0031918X22601834. - ISSN 15556190 (eISSN)
Примечания : Cited References: 15. - This study was supported by grant no. 22-14-20020 from the Russian Science Foundation and the Krasnoyarsk Regional Fund for Support of Scientific and Technological Activities. The authors are grateful to the Krasnoyarsk Regional Center for Collective Use at Federal Research Center Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, for providing their research facilities
Аннотация: Nickel and cobalt ferrite nanoparticles have been synthesized using the chemical precipitation method; the nanoparticle sizes were found to be 63 ± 22 and 26 ± 4 nm, respectively. The static hysteresis loops and Mossbauer spectra have been measured. It is shown that cobalt ferrite powders are magnetically harder than nickel ferrite powders. Ferromagnetic resonance (FMR) curves have been studied. It is found that the FMR absorption for cobalt ferrite is observed at room temperature and above. The time dependences of the nanoparticle warm-up under FMR conditions have been measured. The maximum temperature changes for nickel ferrite and cobalt ferrite particles are 8 and 11 K, respectively. Using the example of cobalt ferrite powder, the possibility of effectively heating of particles in the FMR mode in their own field without using a DC magnetic field source is shown. The observed effect can be used in magnetic hyperthermia.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kazak N. V., Arauzo A., Bartolome J., Molokeev M. S., Dudnikov V. A., Solovyov L., Borus A., Ovchinnikov S. G.
Заглавие : Anisotropic thermal expansion and electronic transitions in the Co3BO5 ludwigite
Место публикации : Dalton Trans.: Royal Society of Chemistry, 2022. - Vol. 51, Is. 16. - С. 6345-6357. - ISSN 14779226 (ISSN), DOI 10.1039/d2dt00270a
Примечания : Cited References: 57. - We are grateful to the Russian Foundation for Basic Research (project no. 20-02-00559 and 21-52-12033) for supporting this paper. This work was performed within the framework of the budget project no. 0287-2021-0013 for the Institute of Chemistry and Chemical Technology SB RAS. We acknowledge the financial support from the Spanish Ministry of Economy, Industry and Competitiviness (MINECO), (Grant No. MAT2017-83468-R) and from the regional Government of Aragón (E12-20R RASMIA project)
Аннотация: The investigations of the crystal structure, magnetic and electronic properties of Co3BO5 at high temperatures were carried out using powder X-ray diffraction, magnetic susceptibility, electrical resistivity, and thermopower measurements. The orthorhombic symmetry (Sp.gr. Pbam) was observed at 300 K and no evidence of structural phase transitions was found up to 1000 K. The compound shows a strong anisotropy of the thermal expansion. A large negative thermal expansion along the a-axis is observed over a wide temperature range (T = 300–600 K) with αa = −35 M K−1 at T = 500 K with simultaneous expansion along the b- and c-axes with αb = 70 M K−1 and αc = 110 M K−1, respectively. The mechanisms of thermal expansion are explored by structural analysis. The activation energy of the conductivity decreases significantly above 700 K. Electronic transport was found to be a dominant conduction mechanism in the entire temperature range. The correlations between the thermal expansion, electrical resistivity, and effective magnetic moment were revealed and attributed to the evolution of the spin state of Co3+ ions towards the spin crossover and gradual charge-ordering transition.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Baksheev N. V., Mushailov E. S.
Заглавие : Spin reorientation effect of conductive electrons in iron matrix doped with cobalt
Место публикации : Fiz. Tverd. Tela. - 1981. - Vol. 23, Is. 2. - P.631-633. - ISSN 0367-3294
Примечания : Cited References: 9
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Izotov A. V.
Заглавие : FMR study of the anisotropic properties of an epitaxial Fe3Si film on a Si(111) vicinal surface
Место публикации : JETP Letters. - 2016. - Vol. 103, Is. 1. - P.41-45. - ISSN 00213640 (ISSN), DOI 10.1134/S0021364016010033
Примечания : Cited References: 28
Предметные рубрики: Thin magnetic-films
Ferromagnetic-resonance
Cobalt films
Metal-films
Spectrometer
Spintronics
Roughness
Аннотация: The anisotropic characteristics of an iron silicide (Fe3Si) epitaxial thin magnetic film grown on a Si(111) silicon vicinal surface with a misorientation angle of 0.14° have been measured by the ferromagnetic resonance method. It has been shown that the polar and azimuth misorientation angles of the crystallographic plane of the substrate can be determined simultaneously from the angular dependences of the ferromagnetic resonance field of the epitaxial film. The effective saturation magnetization of the film M eff = 1105 G and the constant of the cubic magnetocrystalline anisotropy K 4 = 1.15 × 105 erg/cm3 have been determined. The misorientation of the substrate plane leads to the formation of steps on the film surface and, as a result, to the appearance of uniaxial magnetic anisotropy of the magnetic dipole nature with the constant K 2 = 796 erg/cm3. Small unidirectional magnetic anisotropy (K 1 = 163 erg/cm3), which may be associated with symmetry breaking on the steps of the film and is due to the Dzyaloshinskii–Moriya interaction, has been detected.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kablov E. N., Piskorskii V. P., Valeev R. A., Ospennikova O. G., Rezchikova I. I., Volkov N. V., Shaikhutdinov K. A.
Заглавие : Boron mobility in sintered (Pr, Dy)–(Fe, Co)–B materials with a high cobalt content
Место публикации : Russ. Metall. (Metally): Pleiades Publishing, 2014. - Vol. 2014, Is. 9. - P.721–724. - ISSN 0036-0295, DOI 10.1134/S0036029514090080. - ISSN 1555-6255
Примечания : Cited References: 15
Аннотация: Sintered (Pr, Dy)–(Fe1 – yCoy)–B materials with up to y ≈ 0.5 atomic fractions have been studied. Boron is found to be a movable element, and its diffusion between principal magnetic phase A and other boron containing phases determines the properties of the materials. The structure of principal magnetic phase grains is sufficiently complex: their periphery is enriched in boron. The enrichment is shown to cause a decrease in the coercive force of the materials to zero after sintering.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kurilova A. V., Klimenko D. I., Kundelev E. V., Sukhachev A. L., Shulga K. V., Dubavik A. U., Sokolov A. Е.
Заглавие : Chiromagnetic oxide cobalt nanoparticles: synthesis and magnitooptical properties
Коллективы : Российская академия наук, Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН, Казанский (Приволжский) федеральный университет, Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022): Book of abstracts/ program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 1, Sect.: Spintronics and magnetic nanostructures. - Ст.A.P59. - P.209-210. - ISBN 978-5-94469-051-7
Примечания : Cited References: 7. - The reported study was funded by RFBR, project number 20-32-90144
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kazak N. V., Belskaya N. A., Moshkina E. M., Bezmaternykh L. N., Vasiliev A. D., Bartolome J., Arauzo A., Velikanov D. A., Gavrilkin S. Y., Gorev M. V., Patrin G. S., Ovchinnikov S. G.
Заглавие : Co5/3Nb1/3BO4: A new cobalt oxyborate with a complex magnetic structure
Место публикации : J. Magn. Magn. Mater. - 2021. - Vol. 534. - Ст.168056. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2021.168056
Примечания : Cited References: 50. - The authors acknowledge M. Molokeev for the orientating the single crystal for magnetic measurements. The X-ray diffraction and specific heat measurements were carried out in the Common Access Facility Centres of SB RAS (Krasnoyarsk, Russia) and P.N. Lebedev Physical Institute of RAS (Moscow, Russia). This work has been financed by the Russian Foundation for Basic Research (project no. 20-02-00559). We acknowledge financial support from the Spanish MINECO DWARFS project MAT2017-83468-R and Gobierno de Aragón (Group, E12-20R)
Аннотация: Needle-shape single crystals of Co5/3Nb1/3BO4 warwickite were grown using the flux technique. X-ray diffraction measurements have revealed an orthorhombic structure (Sp. Gr. Pbnm) where the octahedral M1 site is occupied by a mixture of Co2+/Nb5+ ions and the M2 site is exclusively filled by Co2+ ions. Using dc magnetization measurements it was established that the new material undergoes two magnetic transitions: an antiferromagnetic transition at TN1 = 27 K and a ferrimagnetic one at TN2 = 14 K, below which a hysteresis cycle opens. Both magnetic transitions are marked by anomalies in the specific heat. High magnetic anisotropy with c-axis as a hard magnetization direction was detected.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Komogortsev S. V., Patrusheva T. N., Balaev D. A., Denisova E. A., Ponomarenko I. V.
Заглавие : Cobalt ferrite nanoparticles in a mesoporous silicon dioxide matrix
Коллективы : Development of the Scientific Potential of Higher Education [RNP. 2.1.1/2584]; Krasnoyarsk Regional Science Foundation; Russian Foundation for Basic Research [r-Enisei-a 03-07-96803, 09-02-98002-r_sibir'_a]
Место публикации : Tech. Phys. Lett. - 2009. - Vol. 35, Is. 10. - P.882-884. - ISSN 1063-7850, DOI 10.1134/S1063785009100022
Примечания : Cited References: 10. - This study was supported in part by the Federal Program "Development of the Scientific Potential of Higher Education" (project no. RNP. 2.1.1/2584) and jointly by the Krasnoyarsk Regional Science Foundation and the Russian Foundation for Basic Research (project nos. r-Enisei-a 03-07-96803 and 09-02-98002-r_sibir'_a).
Предметные рубрики: MAGNETIC-PROPERTIES
NANOSIZED COFE2O4
ANISOTROPY
POWDERS
CURVES
Аннотация: We have studied magnetic nanoparticles of cobalt ferrite obtained by the extraction-pyrolysis method in a mesoporous silicon dioxide (MSM-41) molecular sieve matrix. The X-ray diffraction data show evidence for the formation of CoFe(2)O(4) particles with a coherent scattering domain size of similar to 40 nm. Measurements of the magnetization curves showed that powders consisting of these nanoparticles are magnetically hard materials with a coercive field of H (c)(4.2 K) = 9.0 kOe and H (c)(300 K) = 1.8 kOe and a reduced remanent magnetization of M (r)/M (s)(4.2 K) = 0.83 and M (r)/M (s)(300 K) = 0.49. The shape of the low-temperature (4.2 K) magnetization curves is adequately described in terms of the Stoner-Wohlfarth model for randomly oriented single-domain particles with a cubic magnetic anisotropy.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova E. A., Kuzovnikova L. A., Iskhakov R. S., Kuzovnikov A. A., Nemtsev I. V., Mal'tsev V. K.
Заглавие : Cobalt-based bulk nanostructured materials prepared via the dynamic compacting of core–shell composite particles
Место публикации : Bull. Russ. Acad. Sci. Phys.: Allerton Press, 2016. - Vol. 80, Is. 11. - P.1377-1380. - ISSN 10628738 (ISSN), DOI 10.3103/S1062873816110198
Примечания : Cited References: 12. - This work was supported by the Russian Foundation for Basic Research, project nos. 15-08-06673, 16-03-00969, and RFBR and KRFS 15-42-04171.
Ключевые слова (''Своб.индексиров.''): composite materials--bulk nanostructured materials--chemical deposition--cobalt-based--composite particles--dynamic compaction--magnetic characteristic--nano-structured--structural and magnetic characteristics--powders
Аннотация: Bulk nanostructured Co–P/Cu and Al2O3/Co–P composites are fabricated via dynamic compaction. The initial core–shell particles are synthesized by means of chemical deposition. Structural and magnetic characteristics of the composites are investigated. It is shown that the use of composite particles allows homogeneous compacts with the structure and magnetic characteristics of initial powders to be obtained. © 2016, Allerton Press, Inc.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kazak N. V., Ivanova N. B., Rudenko V. V., Ovchinnikov S. G., Vasil'Ev A. D., Knyazev Yu. V.
Заглавие : Conductivity study of Co3O2BO3 and Co 3-xFexO2BO3 oxyborates
Коллективы : Moscow International Symposium on Magnetism
Место публикации : Solid State Phenomena. - 2009. - Vol. 152-153. - С. 104-107. - ISSN 10120394 (ISSN); 390845168X (ISBN); 9783908451686 (ISBN), DOI 10.4028/www.scientific.net/SSP.152-153.104
Ключевые слова (''Своб.индексиров.''): doped cobaltite--electrical conductivity--ludwigite--variable-range hopping--crystal structure--electric conductivity--magnetic materials--single crystals--crystal structure--electric conductivity--magnetic materials--magnetism--single crystals--electrical conductivity--electrical resistivity--experimental data--mott variable-range hopping--oxyborates--temperature regions--variable-range hopping--doped cobaltite--ludwigite--variable range hopping--cobalt--cobalt
Аннотация: Single crystals of cobalt oxyborates Co3O2BO 3 and Co3-xFexO2BO3 were synthesized. The crystal structure and electric properties were investigated. The difference in the electrical resistivity behaviors was found. For parent Co3O2BO3 nor simple activation law, nor Mott variable range hopping (VRH) are acquirable to describe the experimental data in wide temperature region. In contrast for Co3-xFex O 2BO3 Mott's variable-range hopping conductivity clearly dominates.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Orlov Yu. S., Sokolov A. Е., Dudnikov V. A., Shulga K. V., Volochaev M. N., Zharkov S. M., Shestakov N. P., Vysotin M. A., Ovchinnikov S. G.
Заглавие : Contribution of the multiplicity fluctuation in the temperature dependence of phonon spectra of rare-earth cobaltites
Место публикации : Molecules. - 2020. - Vol. 25, Is. 18. - Ст.4316. - ISSN 14203049 (ISSN), DOI 10.3390/molecules25184316
Примечания : Cited References: 34. - This work was supported by the Russian Science Foundation grant 18-02-00022. The scanning electron microscopy investigations were conducted in the SFU Joint Scientific Center, supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation. The other research was carried out at the Krasnoyarsk Regional Center of Research Equipment of the Federal Research Center “Krasnoyarsk Science Center SB RAS”
Аннотация: We have studied, both experimentally and theoretically, the unusual temperature dependence of the phonon spectra in NdCoO3, SmCoO3 and GdCoO3, where the Co3+ ion is in the low-spin (LS) ground state, and at the finite temperature, the high-spin (HS) term has a nonzero concentration nHS due to multiplicity fluctuations. We measured the absorption spectra in polycrystalline and nanostructured samples in the temperature range 3–550 K and found a quite strong breathing mode softening that cannot be explained by standard lattice anharmonicity. We showed that the anharmonicity in the electron–phonon interaction is responsible for this red shift proportional to the nHS concentration.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Samardak A. S., Nasirpouri F., Nadi M., Sukovatitsina E. V., Ognev A. V., Chebotkevich L. A., Komogortsev S. V.
Заглавие : Conversion of magnetic anisotropy in electrodeposited Co-Ni alloy nanowires
Коллективы : Russian Ministry of Education and Science, Far Eastern Federal University, Iranian Nanotechnology Initiative Council
Место публикации : J. Magn. Magn. Mater.: ELSEVIER SCIENCE BV, 2015. - Vol. 383. - P.94-99. - ISSN 0304, DOI 10.1010/j.jmmm.2014.10.047. - ISSN 18734766(eISSN)
Примечания : Cited References:24. - This work was supported in part by the Russian Ministry of Education and Science and Far Eastern Federal University. M.N acknowledges the student financial support of Iranian Nanotechnology Initiative Council.
Предметные рубрики: COBALT NANOWIRES
ARRAYS
Ключевые слова (''Своб.индексиров.''): coercive force--magnetic anisotropy--magnetic hysteresis--binary alloy--nanowires--alumina template--electrodeposition
Аннотация: In this paper, the influence of alternating current (ac) electrodeposition frequency and waveform is reported on chemical composition, microstructure and consequently magnetic properties of Co-Ni binary alloy nanowire arrays embedded in an alumina template. For sinusoidal and square electrodeposition waveforms the easy axis of magnetization rotates from being parallel to perpendicular orientation to nanowire long axis as the deposition frequency increases from 200 to 800 Hz. The reason for the drastic change of magnetic anisotropy in nanowires is attributed to the increase of cobalt content and the crystal structure phase transformation from fcc-hcp mixture at high Ni content to imp at high Co content. We explain the conversion of magnetic behavior of nanowire arrays in terms of a competition between the shape and magnetocrystalline anisotropies. (C) 2014 Elsevier B.V. All rights reserved.
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16.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Denisova E. A., Chekanova L. A., Komogortsev S. V., Rautskii M. V., Nemtsev I. V., Iskhakov R. S., Tkachev V. V., Plotnikov V. S., Dolgopolova M. V.
Заглавие : Core-shell and Bi-segmented cobalt-nickel nanorods prepared by electroless deposition
Коллективы : IEEE International Magnetics Conference
Место публикации : IEEE International Magnetics Virtual Conference (INTERMAG'21): Digest book. - 2021. - P.1342
Примечания : Cited References: 2. - This work was funded by the RFBR, the Government of the Krasnoyarsk Territory, the KRFS (project no. 20-43-240003)
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova E. A., Chekanova L. A., Komogortsev S. V., Rautsky M. V., Nemtsev I. V., Iskhakov R. S., Plotnikov V. S., Tkachev V. V., Li O. A., Dolgopolova M. V.
Заглавие : Core-shell and bi-segmented cobalt-nickel nanorods prepared by electroless deposition
Место публикации : IEEE Trans. Magn. - 2022. - Vol. 58, Is. 2. - Ст.2300805. - ISSN 00189464 (ISSN), DOI 10.1109/TMAG.2021.3098747
Примечания : Cited References: 27. - This work was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-43-240003. The authors thank the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center“ Krasnoyarsk Science Center SB RAS” for the provided equipment
Аннотация: A porous polymer loaded with segmented nanorods of magnetic metal is very promising for the design of novel microwave devices. Arrays of bi-segmented Ni/Co and core-shell Ni@Co rods were prepared by electroless deposition into porous of polycarbonate track etched membrane. An intrinsic effective magnetic field of the magnetic composite nanorods aligned in the nonmagnetic template was studied by magnetization curves and ferromagnetic resonance. The effect of the interface boundaries for two types of bi-segmented rods with coaxial and along-axis Co/Ni segmentation to effective field was established.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Voronkov M. G., Zel'bst E. A., Vasiliev A. D., Soldatenko A. S., Bolgova Y. I., Trofimova O. M.
Заглавие : Crystal and molecular structure of the complex of N-(1-silatranylmethyl)-3,5-dimethylpyrazole with cobalt dichloride
Место публикации : J. Struct. Chem.: Springer, 2012. - Vol. 53, Is. 3. - P.614-617. - ISSN 0022-4766, DOI 10.1134/S0022476612030316
Примечания : Cited References: 11
Ключевые слова (''Своб.индексиров.''): n-(1-silatranylmethyl)-3,5-dimethylpyrazole--cobalt dichloride--molecular structure--single crystal x-ray diffraction
Аннотация: X-ray diffraction is used to determine the crystal and molecular structure of the complex of N-(1-silatranylmethyl)-3,5-dimethylpyrazole with cobalt dichloride (I). This is yet another example of the participation of the endocyclic oxygen atom of the silatrane fragment in complexation with a metal atom. Metal dichloride interconnects two heterocyclic systems of dimethylpyrazole (DMP) and silatrane (Sa). The coordination polyhedron of the cobalt atom is a tetrahedron.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ehrling S., Senkovska I., Bon V., Evans J. D., Petkov P., Krupskaya Y., Kataev V., Wulf T., Krylov A. S., Vtyurin A. N., Krylova S. N., Adichtchev S., Slyusareva E., Weiss M. S., Buchner B., Heine T., Kaskel S.
Заглавие : Crystal size: Versus paddle wheel deformability: Selective gated adsorption transitions of the switchable metal-organic frameworks DUT-8(Co) and DUT-8(Ni)
Место публикации : J. Mater. Chem. A. - 2019. - Vol. 7, Is. 37. - P.21459-21475. - ISSN 20507488 (ISSN), DOI 10.1039/c9ta06781g
Примечания : Cited References: 106. - The authors thank DFG (FOR 2433) for financial support. We thank HZB for the allocation of synchrotron radiation beam-time and financial support. PP, TW and TH used high performance facilities of ZIH Dresden. TW thanks the European Social Funds for Germany for a PhD fellowship.
Аннотация: Switchable pillared layer metal–organic frameworks M2(2,6-ndc)2(dabco) (DUT-8(M), M = Ni, Co, 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo-[2.2.2]octane, DUT – Dresden University of Technology) were synthesised in two different crystallite size regimes to produce particles up to 300 μm and smaller particles around 0.1 μm, respectively. The textural properties and adsorption-induced switchability of the materials, obtained from both syntheses, were studied by physisorption of N2 at 77 K, CO2 at 195 K and n-butane at 273 K, revealing pronounced differences in adsorption behavior for Ni and Co analogues. While the smaller nano-sized particles (50–200 nm) are rigid and show no gating transitions confirming the importance of crystallite size, the large particles show pronounced switchability with characteristic differences for the two metals resulting in distinct recognition effects for various gases and vapours. Adsorption of various vapours demonstrates consistently a higher energetic barrier for the “gate opening” of DUT-8(Co) in contrast to DUT-8(Ni), as the “gate opening” pressure for Co based material is shifted to a higher value for adsorption of dichloromethane at 298 K. Evaluation of crystallographic data, obtained from single crystal and powder X-ray diffraction analysis, showed distinct geometric differences in the paddle wheel units of the respective MOFs. These differences are further disclosed by solid-state UV-vis, FT-IR and Raman spectroscopy. Magnetic properties of DUT-8(Co) and DUT-8(Ni) were investigated, indicating a high-spin state for both materials at room temperature. Density functional theory (DFT) simulations confirmed distinct energetic differences for Ni and Co analogues with a higher energetic penalty for the structural “gate opening” transformation for DUT-8(Co) compared to DUT-8(Ni) explaining the different flexibility behaviour of these isomorphous MOFs.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Knyazev Yu.V., Ivanova N. B., Kazak N. V., Platunov M. S., Bezmaternykh L. N., Velikanov D. A., Vasiliev A. D., Ovchinnikov S. G., Yurkin G. Yu.
Заглавие : Crystal structure and magnetic properties of Mn substituted ludwigite Co3O2BO3
Место публикации : J. Magn. Magn. Mater.: Elsevier Science BV, 2012. - Vol. 324, Is. 6. - P.923-927. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2011.07.044
Примечания : Cited References: 15. - The study was supported by the Russian Foundation for Basic Research (Project no. 09-02-00171-a), the Federal Agency for Science and Innovation (Rosnauka) (Project no. MK-5632.2010.2), the Physical Division of the Russian Academy of Science, the program "Strongly Correlated Electrons", Project 2.3.1.
Предметные рубрики: BOND VALENT SUMS
COORDINATION CHEMISTRY
OXIDATION -STATE
O BONDS
COMPLEXES
MANGANESE
COBALT
Ключевые слова (''Своб.индексиров.''): transition metal oxyborate--distinct crystallographic position--spin glass magnetic ordering
Аннотация: The needle shape single crystals Co3−x MnxO2BO3 with ludwigite structure have been prepared. According to the X-ray diffraction data the preferable character of distinct crystallographic positions occupation by Mn ions is established. Magnetization field and temperature dependencies are measured. Paramagnetic Curie temperature value Θ=−100 K points out the predominance of antiferromagnetic interactions. Spin-glass magnetic ordering takes the onset at TN=41 K. The crystallographic and magnetic properties of Co3O2BO3:Mn are compared with the same for the isostructural analogs Co3O2BO3 and CoO2BO3:Fe.
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