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1.
Antioxidant Activity and
Toxicity of Fullerenols via Bioluminescence Signaling: Role of Oxygen Substituents / E. S. Kovel [et al.]> // Int. J. Mol. Sci. - 2019. -
Vol. 20
,
Is. 9
. - Ст. 2324,
DOI
10.3390/ijms20092324. - Cited References: 74. - This work was supported by PRAN-32, Program: 'Nanostructures: physics, chemistry, biology, technological basis'; RFBR 18-29-19003; RFBR-Krasnoyarsk Regional Foundation 18-44-240004, Tomsk Polytechnic University CE Program. . - ISSN 1422-0067
Кл.слова (ненормированные):
bioactive
compound
--
fullerenol
--
antioxidant activity
--
toxicity
--
reactive oxygen species
--
bioluminescence bioassay
Аннотация:
Fullerenols are nanosized water-soluble polyhydroxylated derivatives of fullerenes, a specific allotropic form of carbon, bioactive compounds, and perspective basis for drug development. Our paper analyzes the antioxidant activity and toxicity of a series of fullerenols with different number of oxygen substituents. Two groups of fullerenols were under investigation: (1) C60Oy(OH)(x), C60,70Oy(OH)(x), where x+y = 24-28 and (2) C60,70Oy(OH)(x), Fe0,5C60Oy(OH)(x), Gd@C82Oy(OH)(x), where x+y = 40-42. Bioluminescent cellular and enzymatic assays (luminous marine bacteria and their enzymatic reactions, respectively) were applied to monitor toxicity in the model fullerenol solutions and bioluminescence was applied as a signaling physiological parameter. The inhibiting concentrations of the fullerenols were determined, revealing the fullerenols' toxic effects. Antioxidant fullerenol' ability was studied in solutions of model oxidizer, 1,4-benzoquinone, and detoxification coefficients of general and oxidative types (D-GT and D-OxT) were calculated. All fullerenols produced toxic effect at high concentrations (>0.01 g L-1), while their antioxidant activity was demonstrated at low and ultralow concentrations (<0.001 g L-1). Quantitative toxic and antioxidant characteristics of the fullerenols (effective concentrations, concentration ranges, D-GT, and D-OxT) were found to depend on the number of oxygen substituents. Lower toxicity and higher antioxidant activity were determined in solutions of fullerenols with fewer oxygen substituents (x+y ⋍ 24-28). The differences in fullerenol properties were attributed to their catalytic activity due to reversible electron acceptance, radical trapping, and balance of reactive oxygen species in aqueous solutions. The results provide pharmaceutical sciences with a basis for selection of carbon nanoparticles with appropriate toxic and antioxidant characteristics. Based on the results, we recommend, to reduce the toxicity of prospective endohedral gadolinium-fullerenol preparations Gd@C82Oy(OH)(x), decreasing the number of oxygen groups to x+y ⋍ 24-28. The potential of bioluminescence methods to compare toxic and antioxidant characteristics of carbon nanostructures were demonstrated.
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Держатели документа:
Institute of Biophysics SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Physics SB RAS, Krasnoyarsk, 660036, Russian Federation
National Research Tomsk Polytechnic University, Tomsk, 634050, Russian Federation
Institute of Physics SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Institute of Biophysics SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Доп.точки доступа:
Kovel, E. S.; Ковель, Екатерина Сергеевна; Sachkova, A. S.; Vnukova, N. G.; Внукова, Наталья Григорьевна; Churilov, G. N.; Чурилов, Григорий Николаевич; Knyazeva, E. M.; Kudryasheva, N. S.
}
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2.
Aplesnin, S. S.
Existence of massive singlet excitations in an antiferromagnetic alternating chain with S=1/2 / S. S. Aplesnin> // Phys. Rev. B. - 2000. -
Vol. 61
,
Is. 10
. - P. 6780-6784,
DOI
10.1103/PhysRevB.61.6780. - Cited References: 26 . - ISSN 1098-0121
РУБ
Physics, Condensed Matter
Рубрики:
PEIERLS
COMPOUND
CUGEO3
SPIN SYSTEMS
TRANSITION
Аннотация:
The one-dimensional Heisenberg model with alternating antiferromagnetic bond and spin-1/2 has been studied by the Monte Carlo method. The thermodynamic characteristics, spin-spin, and four spin-correlation function have been calculated. From several maxima of the correlation radius of the four spin-correlation function and sharp slopes of the dimer order parameter, a longitudinal component of the total spin square as a function of temperature and magnetic field, the existence of two mass singlet excitation branches with Delta S-z=0 and one triplet with Delta S-z=1 is suggested. Critical temperatures and fields related to singlet filled bands have been estimated. From these results low-temperature (TT-SP) properties of spin-Peierls (SP) compounds CuGeO3 and NaV2O5 have been explained.
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Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Доп.точки доступа:
Аплеснин, Сергей Степанович
}
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3.
Aplesnin, S. S.
Modeling a dimer state in CuGeO3 in the two-dimensional anisotropic Heisenberg model with alternated exchange interaction / S. S. Aplesnin> // J. Exp. Theor. Phys. - 1997. -
Vol. 85
,
Is. 6
. - P. 1196-1203,
DOI
10.1134/1.558393. - Cited References: 33 . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Рубрики:
SPIN-PEIERLS TRANSITION
HIGH MAGNETIC-FIELDS
COMPOUND
CUGEO3
GROUND-STATE
SYSTEMS
NEUTRON
Аннотация:
The two-dimensional Heisenberg spin-1/2 model with alternated exchange interaction along the c axis and an anisotropic distribution of the exchange interaction in the lattice, J(b)/J(c)=0.1, is examined. A quantum Monte Carlo method is used to calculate the phase diagrams of the antiferromagnet, the dimer state in a plane, the value of the alternation delta of the exchange interaction, and the anisotropy Delta=1-J(xy)/J(z) of the exchange interaction, Delta similar to delta(0.58(6)). The following characteristics are calculated for Delta=0.25: the dependence of the temperature of the dimer-state-paramagnet transition on the alternation of the exchange interaction, T-c(delta)=0.55(4(delta-0.082(6))(0.50(3)), the singlet-triplet energy gap, and the dependence of the magnetization on the external field for some values of delta. The value of the exchange interaction, J(c)=127 K, the alternation of the exchange interaction, delta=0.11J(c), and the correlation radius along the c axis, xi(c) approximate to 28c, are determined. Finally, it is found that the temperature dependence of the susceptibility and the specific heat are in good agreement with the experimental data. (C) 1997 American Institute of Physics. [S1063-7761(97)01912-4].
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Доп.точки доступа:
Аплеснин, Сергей Степанович
}
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4.
Aplesnin, S. S.
Quantum Monte Carlo investigation of the magnetic properties of weakly interacting antiferromagnetic chains with an alternating exchange interaction with spin S=1/2 / S. S. Aplesnin> // J. Exp. Theor. Phys. - 2000. -
Vol. 90
,
Is. 1
. - P. 194-201,
DOI
10.1134/1.559075. - Cited References: 35 . - ISSN 1063-7761
РУБ
Physics, Multidisciplinary
Рубрики:
PEIERLS
COMPOUND
CUGEO3
MAGNON DISPERSION
BI2CUO4
EXCITATIONS
RESONANCE
SYSTEMS
SCATTERING
DYNAMICS
NEUTRON
PHASE
Аннотация:
An approximation dependence of the spontaneous magnetic moment at a site, sigma/sigma(0) - 1 = 0.71(6)delta(2.5(2)), and the antiferromagnet-singlet state phase boundary, J(2)/J(1) = 0.52(3)delta, are determined by the quantum Monte Carlo method in the self-consistent sublattice molecular field approximation for weakly interacting (J(2)) antiferromagnetic chains with spin S = 1/2 and alternating exchange interaction (J(1) +/- delta). The Neel temperature and a number of critical temperatures which could be related with the filling energy of two singlets (Delta S-z = 0) and one triplet (Delta S-z= 1) spin bands, each of which is split by the sublattice field (h(x,y)not equal h(z)) into two subbands, are determined on the basis of the computed correlation radii of the two- and four-spin correlation function, the squared total spin (S-z)(2) with respect to the longitudinal components, the dimerization parameter, and the correlation functions between the nearest neighbors with respect to longitudinal and transverse spin components. On the basis of the Monte Carlo calculations, the critical temperatures and possible energy gaps at the band center are determined for the antiferromagnets CuWO4 and Bi2CuO4 and for the singlet compounds (VO)(2)P2O7 and CuGeO3 , agreeing satisfactorily with existing results, and new effects are also predicted. (C) 2000 MAIK "Nauka / Interperiodica".
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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Доп.точки доступа:
Аплеснин, Сергей Степанович
}
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5.
Aver'yanov, E. M.
Structural and thermodynamic consequencies of the interaction of conformational degrees of freedom of azomethines in the nematic phase / E. M. Aver'yanov> // J. Struct. Chem. - 2014. -
Vol. 55
,
Is. 4
. - P. 605-611,
DOI
10.1134/S0022476614040039. - Cited References: 21 . - ISSN 0022-4766. - ISSN 1573-8779
РУБ
Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
CONJUGATED POLY(AZOMETHINE)S
TERMINAL SUBSTITUENTS
ELECTRONIC-STRUCTURES
FLUORINATED ANALOGS
INTERNAL-ROTATION
MOLECULES
COMPOUND
ANGLES
STATE
NMR
Кл.слова (ненормированные):
azomethines
--
benzylideneaniline
--
conformation
--
steric effects of substituents
--
nematic-isotropic liquid transition
--
conformational polymorphism
Аннотация:
The interaction of the conformational degrees of freedom of azomethines in the nematic phase, which is induced by electronic donor-acceptor properties of the terminal substituents of the benzylideneaniline core is studied. These degrees of freedom related to the rotation angles phi (k) around the bonds between the substituent and the aniline ring (phi(1)) and also between the CH=N bridge and the aniline ring (omega(2)) are characterized by the parameters Q (k) = aOE (c) cos(2)phi (k) >. It is found that the interaction of these degrees of freedom is manifested in the linear dependence Q (2)(Q (1)). Within the phenomenological theory the effect of this interaction on changes delta (k) in the Q (k) values during the nematic liquid crystal-isotropic liquid phase transition is revealed along with the temperature T (NI) and character of this transition. The derivation of previously established empirical dependences T (NI)(Q (k) ) is presented in the presence of direct and indirect steric effects of side substituents affecting the Q (k) values. A diverse combination of delta (k) signs in the nematic phase, which is a prerequisite for the conformational polymorphism of the nematic phases of azomethines, is shown.
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Публикация на русском языке
Аверьянов, Евгений Михайлович. Структурные и термодинамические следствия взаимодействия конформационных степеней свободы азометинов [Текст] / Е. М. Аверьянов // Журн. структ. химии. - Новосибирск : Изд-во СО РАН, 2014. - Т. 55 № 4. - С. 641 - 647
Доп.точки доступа:
Аверьянов, Евгений Михайлович
}
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6.
Barinov, G. I.
Influence of high-pressure thermal-treatment on the phase
compound
and phase-transformation kinetics of a system magnetite-wustite / G. I. Barinov, Y. V. Babkin> // Izvestiya vysshikh uchebnykh zavedenii Fizika. - 1990. -
Vol. 33
,
Is. 5
. - P. 95-96 ; Russian Physics Journal ; Известия высших учебных заведений. Физика. - Cited References: 4 . - ISSN 0021-3411
РУБ
Physics, Multidisciplinary
WOS
Доп.точки доступа:
Babkin, Y. V.
}
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7.
Bayukov, O. A.
Orbital ordering in CuGeO3 / O. A. Bayukov, G. A. Petrakovskii, A. F. Savitskii> // Phys. Solid State. - 1998. -
Vol. 40
,
Is. 9
. - P. 1534-1539,
DOI
10.1134/1.1130602. - Cited References: 25 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
SPIN-PEIERLS TRANSITION
COMPOUND
CUGEO3
DIMERIZATION
STATE
SUSCEPTIBILITY
(VO)2P2O7
LADDER
Аннотация:
The combined effect of the ligand crystal field and the exchange interaction on the Cu2+ cation in CuGeO3 is examined. It is shown that, if the magnitude of the exchange interaction exceeds the splitting of the energy levels of the d(x2-y2) and d(xy) orbitals, then an alternate filling of the d orbitals along a chain (orbital ordering) is possible. This effect creates an antiferromagnetic interaction between Cu2+ pairs in 90 degrees exchange and a doubling of the lattice period. A Jahn-Teller pseudoeffect causes singletization of the ground state of the antiferromagnetic chain of Cu2+ spins. (C) 1998 American Institute of Physics. [S1063-7834(98)02609-4].
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Доп.точки доступа:
Petrakovskii, G. A.; Петраковский, Герман Антонович; Savitskii, A. F.; Баюков, Олег Артемьевич
}
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8.
Bis(μ3-barbiturato−O,O,O′)-(μ2-aqua)- aqua-barium(II): crystal
structure, spectroscopic and thermal properties / L. A. Solovyov [et al.]> // J. Coord. Chem. - 2017. -
Vol. 70
,
Is. 12
. - P. 1984-1993,
DOI
10.1080/00958972.2017.1319943. - Cited References: 21 . - ISSN 0095-8972
Перевод заглавия:
Бис(μ3-барбитурат-O,O,O')-(μ2-аква)-аква-бария(II): Кристаллическая структура, спектроскопические и термические свойства
Кл.слова (ненормированные):
Barbituric acid
--
barium
--
coordination
compound
--
X-ray diffraction
--
infrared spectroscopy
--
thermal analysis
Аннотация:
A polymeric coordination
compound
, [Ba(H2O) 2(Hba)2] (1) (H2ba – barbituric acid, C4H4N2O3), was obtained. The structure of 1 was solved using powder X-ray diffraction methods. The Ba2+ ion in 1 formed a three-capped trigonal prism. The BaO9 polyhedra, connected with each other by the edges and faces, formed a chain. Several 4- and 12-membered cycles due to the bridging μ2-H2O and bridging μ3-Hba– also formed implementing a 3-D polymer structure. The structures of 1 and other thiobarbiturate complexes were compared. The replacement of a S atom by an O atom in the heterocyclic ligand Htba− (thiobarbiturate ion) of the
compound
Ba(H2O)2(Htba)2 resulted in changes of the coordination number Ba(II) and supramolecular structure. The intermolecular hydrogen bonds O–H⋯O and N–H⋯O formed a 3-D net where pronounced 2-D layers of Hba– ions could be found. A new topological net in 1 was observed. The IR and thermal stability were investigated.
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Держатели документа:
Institute of Chemistry and Chemical Technology, SB RAS, FRC “Krasnoyarsk Science Center SB RAS”, Krasnoyarsk, Russian Federation
Department of Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, Russian Federation
Доп.точки доступа:
Solovyov, L. A.; Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lesnikov, M. K.
}
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9.
Coexisting 1D and
3D magnetic interactions in the insulating copper-oxygen
compound
CuB2O4 / M. . Boehm [et al.]> // Physica B. - 2006. -
Vol. 378-80
: International Conference on Strongly Correlated Electron Systems (SECES 05) (JUL 26-30, 2005, Vienna, AUSTRIA). - P. 1128-1129,
DOI
10.1016/j.physb.2006.01.540. - Cited References: 8 . - ISSN 0921-4526
РУБ
Physics, Condensed Matter
Рубрики:
SPIN-WAVE SPECTRUM
PHASE 10 K
METABORATE
Кл.слова (ненормированные):
cuprates
--
magnetic soliton lattice
--
Heisenberg exchange
--
low-dimensional excitations
--
Cuprates
--
Heisenberg exchange
--
Low-dimensional excitations
--
Magnetic soliton lattice
--
Dispersions
--
Insulating materials
--
Magnetic properties
--
Neutron scattering
--
Positive ions
--
Cuprates
--
Heisenberg exchange
--
Low-dimensional excitations
--
Magnetic soliton lattice
--
Copper compounds
Аннотация:
We performed inelastic neutron scattering measurements on CuB2O4 with a magnetic field applied in the tetragonal basal plane. The spin dynamics in this cuprate is determined by the interplay of two magnetic Cu2+ subsystems, the magnetic cage with predominant 3d Heisenberg exchange and quasi Id zig-zag chains. The comparison of the dispersion spectra along the chain direction in zero field and under applied field suggests a decoupling of the two magnetic sublattices under field. (c) 2006 Elsevier B.V. All rights reserved.
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Держатели документа:
Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France
Paul Scherrer Inst, Neutron Scattering Lab, CH-5232 Villigen, Switzerland
Russian Acad Sci, Inst Phys, SB, Krasnoyarsk 660036, Russia
ИФ СО РАН
Institut Laue Langevin, 6, rue Jules Horowitz, F-38042 Cedex 9, France
Laboratory of Neutron Scattering, Paul Scherrer Institute, CH-5232 Villigen, Switzerland
Institute of Physics, SB RAS, 660036 Krasnoyarsk, Russian Federation
Доп.точки доступа:
Boehm, M.; Roessli, B.; Schefer, J.; Ouladdiaf, B.; Kulda, J.; Petrakovskii, G. A.; Петраковский, Герман Антонович
}
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10.
Commensurate spin density
wave in LaFeAsO: A local probe study / H. H. Klauss [et al.]> // Phys. Rev. Lett. - 2008. -
Vol. 101
,
Is. 7
. - Ст. 77005,
DOI
10.1103/PhysRevLett.101.077005. - Cited References: 28 . - ISSN 0031-9007
РУБ
Physics, Multidisciplinary
Рубрики:
LAYERED QUATERNARY
COMPOUND
SUPERCONDUCTIVITY
Кл.слова (ненормированные):
Arsenic compounds
--
Chlorine compounds
--
Ferromagnetism
--
Magnetic materials
--
Magnetic properties
--
Magnetization
--
Magnets
--
Molybdenum
--
Phase transitions
--
Spin density waves
--
Commensurate spin density wave
--
External fields
--
Magnetic orders
--
Muon spin relaxations
--
Order parameter
--
Ordered moments
--
Probe measurements
--
Ssbauer spectroscopy
--
Structural phase transition
--
Sublattice magnetizations
--
Temperature dependences
--
Spin dynamics
Аннотация:
We present a detailed study on the magnetic order in the undoped mother
compound
LaFeAsO of the recently discovered Fe-based superconductor LaFeAsO(1-x)F(x). In particular, we present local probe measurements of the magnetic properties of LaFeAsO by means of (57)Fe Mossbauer spectroscopy and muon-spin relaxation in zero external field along with magnetization and resistivity studies. These experiments prove a commensurate static magnetic order with a strongly reduced ordered moment of 0.25(5)mu(B) at the iron site below T(N)=138 K, well separated from a structural phase transition at T(S)=156 K. The temperature dependence of the sublattice magnetization is determined and compared to theory. Using a four-band spin density wave model both, the size of the order parameter and the quick saturation below T(N) are reproduced.
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Держатели документа:
[Klauss, H. -H.] Tech Univ Dresden, Inst Festkorperphys, D-01069 Dresden, Germany
Amato, A.] Paul Scherrer Inst, Lab Muon Spin Spect, CH-5232 Villigen, Switzerland
Buechner, B.] Leibniz Inst Festkorper & Weskstoffforsch IFW, D-01171 Dresden, Germany
Kraken, M.] Tech Univ Carolo Wilhelmina Braunschweig, Inst Phys Kondensierten Mat, D-38106 Braunschweig, Germany
Eremin, I.] Max Planck Inst Phys Komplexer Syst, D-01187 Dresden, Germany
[Korshunov, M. M.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Eremin, I.] Tech Univ Carolo Wilhelmina Braunschweig, Inst Math Phys, D-38106 Braunschweig, Germany
Institut fur Festkorperphysik, TU Dresden, D-01069 Dresden, Germany
Laboratory for Muon-Spin Spectroscopy, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland
Leibniz-Institut fur Festkorper- und Werkstoffforschung (IFW) Dresden, D-01171 Dresden, Germany
Institut fur Physik der Kondensierten Materie, TU Braunschweig, D-38106 Braunschweig, Germany
Max-Planck-Institut fur Physik Komplexer Systeme, D-01187 Dresden, Germany
L.V. Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, 660036 Krasnoyarsk, Russian Federation
Institut fur Mathematische Physik, TU Braunschweig, D-38106 Braunschweig, Germany
Доп.точки доступа:
Klauss, H. H.; Luetkens, H.; Klingeler, R.; Hess, C.; Litterst, F. J.; Kraken, M.; Korshunov, M. M.; Коршунов, Максим Михайлович; Eremin, I.; Drechsler, S. L.; Khasanov, R.; Amato, A.; Hamann-Borrero, J. E.; Leps, N.; Kondrat, A.; Behr, G.; Werner, J.; Buchner, B.
}
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11.
Electro-optical and dielectric
properties of polymer-stabilized blue phase liquid crystal impregnated with a fluorine-containing
compound
/ P. C. Wu [et al.]> // J. Mol. Liq. - 2018. -
Vol. 267
. - P. 138-143,
DOI
10.1016/j.molliq.2017.12.062. - Cited References: 47. - The authors are indebted to Prof. Mon-Juan Lee of Chang-Jung Christian University for valuable discussions on photopolymerization. This work was financially supported by the Ministry of Science and Technology, Taiwan, through Grant Nos. 104-2112-M-009-008-MY3 and 106-2923-M-009-002-MY3, and by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research projects 16-42-240704 and 17-42-240464. . - ISSN 0167-7322. - ISSN 1873-3166
РУБ
Chemistry, Physical + Physics, Atomic, Molecular & Chemical
Рубрики:
HYSTERESIS
TEMPERATURE
MONOMERS
Кл.слова (ненормированные):
Polymer-stabilized blue phase
--
Liquid crystal
--
Fluorine-containing
--
compound
--
Operating voltage
--
Ionic effect
Аннотация:
The effects of a fluorine-containing
compound
(4,4′-difluorobenzophenone; DF) on the electro-optical and dielectric properties of polymer-stabilized blue phase (PSBP) liquid crystals were investigated. When a PSBP cell was driven by an in-plane electric field, the addition of DF up to 2.7 wt% effectively reduced the operation voltage by ~ 30%. Further inspection by dielectric spectroscopy indicated that the ionic concentration in PSBP decreased with increasing loading of DF. This finding can be ascribed to the complexation of impurity ions near the ketone group and carbon–fluorine bonds of the DF
compound
that restrained the ion transport after photopolymerization. As a result, the DF
compound
can be regarded as a superior ion-suppressor, enabling the reduction in the ionic effect and, in turn, the promotion of the electro-optical response of a PSBP.
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Держатели документа:
Natl Chiao Tung Univ, Coll Photon, Inst Imaging & Biomed Photon, Tainan 71150, Taiwan.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Lab Nonlinear Opt & Spect, Krasnoyarsk 660041, Russia.
Доп.точки доступа:
Wu, Po-Chang; Chen, Hsin-Li; Rudakova, Natalya V.; Timofeev, I. V.; Тимофеев, Иван Владимирович; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Lee, Wei; Ministry of Science and Technology, Taiwan [104-2112-M-009-008-MY3, 106-2923-M-009-002-MY3]; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [16-42-240704, 17-42-240464]
}
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12.
EPR Study of
Solid Solutions Based on the
Compound
ScF3 [Text] / Voronov V.N., Petrakovskaya E.A., Alexandrovskaya A.V.> // Functional Materials. - 2010. -
Vol. 17
,
Is. 3
. - P324-328
Доп.точки доступа:
Voronov, V. N.; Воронов Владимир Николаевич; Petrakovskaya, E. A.; Петраковская Элеонора Анатольевна; Alexandrovskaya, A. V.
}
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13.
EPR study of
solid solutions, based on the
compound
ScF3 [Text] / V. N. Voronov, E. A. Petrakovskaya, A. V. Alexandrovskaya> //
International Conference "Functional Materials" (ICFM-09) : book of abstracts : october 5-10, Ukraine, Crimea, Partenit. - 2009. - P61
Доп.точки доступа:
Voronov, V.N.; Petrakovskaya, E.A.; Alexandrovskaya, A.V.; "Functional Materials", International Conference(4 ; 2009 ; OCT ; Partenit, Crimea, Ukraine)
}
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14.
ERUKHIMOV, M. S.
MAGNETIC-SUSCEPTIBILITY OF INTERMEDIATE VALENCE
COMPOUND
FILMS / M. S. ERUKHIMOV> // Fiz. Tverd. Tela. - 1982. -
Vol. 24
,
Is. 11
. - P. 3485-3487. - Cited References: 4 . - ISSN 0367-3294
РУБ
Physics, Condensed Matter
WOS
}
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15.
Ferromagnetic interlayer coupling
in C60-Co
compound
/Ni bilayer structure / Y. Matsumoto [et al.]> // Chemical Physics Letters. - 2011. -
Т. 511
,
№ 1-3
. - P. 68-72,
DOI
10.1016/j.cplett.2011.05.038 . - ISSN 0009-2614. - ISSN 1873-4448
РИНЦ
Держатели документа:
Advanced Science Research Center,Japan Atomic Energy Agency
Department of Materials Molecular Science,Institute for Molecular Science
Доп.точки доступа:
Matsumoto, Y.; Sakai, S.; Entani, S.; Naramoto, H.; Avramov, P.; Takagi, Y.; Nakagawa, T.; Yokoyama, T.
}
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16.
First outer-sphere 1,3-diethyl-2-thiobarbituric
compounds [M(H2O)6](1,3-diethyl-2-thiobarbiturate)2·2H2O (M = Co2+, Ni2+): Crystal structure, spectroscopic and thermal properties / N. N. Golovnev [et al.]> // Chem. Phys. Lett. - 2016. -
Vol. 653
. - P. 54-59,
DOI
10.1016/j.cplett.2016.04.059. - Cited References: 50. - The study was carried out within the public task of the Ministry of Education and Science of the Russian Federation for research engineering of the Siberian Federal University in 2015-2016. V.V. A. is grateful to the Ministry of Education and Science of the Russian Federation for the financial support of the investigation. X-ray data were obtained with use the analytical equipment of Krasnoyarsk Center of collective use of SB RAS. . - ISSN 0009-2614
Перевод заглавия:
Первые соединения с внешнесферным 1,3-диэтил-2-тиобарбитуратом [M(H2O)6](1,3-диэтил-2-2тиобарбитурат)2·2H2O (M=Co2+, Ni2+): кристаллическая структура, спектроскопия и тепловые свойства
РУБ
Chemistry, Physical + Physics, Atomic, Molecular & Chemical
Рубрики:
Thiobarbituric acid complexes
Transition-metal-complexes; 2-thiobarbituric acid; hydrogen-bond
2-thiobarbituric acid
Hydrogen-bond
Chemistry
Transformation
Diffraction
Ligand
Series
Copper
Кл.слова (ненормированные):
1,3-Diethyl-2-thiobarbituric acid
--
Nickel(II)
--
Cobalt(II)
--
Coordination
compound
--
X-ray diffraction
--
Infrared spectroscopy
--
Thermal analysis
Аннотация:
Two new d-element compounds, [Co(H2O)6](Detba)2·2H2O (1) and [Ni(H2O)6](Detba)2·2H2O (2) (HDetba - 1,3-diethyl-2-thiobarbituric acid) were synthesized and characterized by single-crystal and powder X-ray diffraction analysis, TG-DSC and FT-IR. Structural analysis revealed that (1) and (2) are discrete structures, in which M2+ ion (M = Co, Ni) is six-coordinated by water molecules and it forms an octahedron. The outer-sphere Detba- ions and H2O molecules participate in O-H?(O/S) intermolecular hydrogen bonds which form the 2D layer. Thermal decomposition includes the stage of dehydration and the following stage of oxidation of Detba- with a release of CO2, SO2, H2O, NH3 and isocyanate gases. © 2016 Elsevier B.V. All rights reserved.
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Держатели документа:
Department of Chemistry, Siberian Federal University, 79 Svobodny Aven., Krasnoyarsk, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, SB RAS, bld. 38, Akademgorodok 50, Krasnoyarsk, Russian Federation
Department of Physics, Far Eastern State Transport University, 47 Seryshev Str., Khabarovsk, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, 13 Lavrentiev Aven., Novosibirsk, Russian Federation
Functional Electronics Laboratory, Tomsk State University, 36 Lenin Aven., Tomsk, Russian Federation
Laboratory of Semiconductor and Dielectric Materials, Novosibirsk State University, 2 Pirogov Str., Novosibirsk, Russian Federation
Доп.точки доступа:
Golovnev, N. N.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Lesnikov, M. K.; Atuchin, V. V.
}
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17.
Formation of Cu6Sn5
intermetallic in Cu/Sn thin films / L. E. Bykova, S. M. Zharkov, V. G. Myagkov [et al.]> // Phys. Solid State. - 2022. -
Vol. 64
,
Is. 14
. - P. 2414-2418,
DOI
10.21883/PSS.2022.14.54350.139. - Cited References: 16. - This research was supported financially by the Russian Foundation for Basic Research (grant No. 19-43-240003). Electron microscopic studies were carried out at the Krasnoyarsk Regional Research Equipment Sharing Center of the Federal Research Center Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences and the Electron Microscopy Laboratory of the Research Equipment Sharing Center of the Siberian Federal University, supported under the state assignment of the Ministry of Science and Higher Education of the Russian Federation (scientific topic code FSRZ-2020-0011) . - ISSN 1063-7834. - ISSN 1090-6460
Кл.слова (ненормированные):
thin films
--
Cu6Sn5 intermetallic
compound
--
transmission electron microscopy
--
electron diffraction
Аннотация:
The study of the formation of the Cu6Sn5 intermetallic
compound
in Sn(55 nm)/Cu(30 nm) thin bilayer films was carried out directly in the column of a transmission electron microscope (electron diffraction mode) by heating the film sample from room temperature to 300oC and recording the electron diffraction patterns. The thin films formed as a result of a solid state reaction were monophase and consisted of the η-Cu6Sn5 hexagonal phase. The temperature range for the formation of the η-Cu6Sn5 phase was determined. The estimate of the effective interdiffusion coefficient of the reaction suggests that the main mechanism for the formation of the Cu6Sn5 intermetallic is diffusion along the grain boundaries and dislocations.
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Публикация на русском языке
Формирование интерметаллида Cu6Sn5 в тонких пленках Cu/Sn [Текст] / Л. Е. Быкова, С. М. Жарков, В. Г. Мягков [и др.] // Физ. тверд. тела. - 2021. - Т. 63 Вып. 12. - С. 2205-2209
Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Siberian Federal University, Krasnoyarsk, Russia
Доп.точки доступа:
Bykova, L. E.; Быкова, Людмила Евгеньевна; Zharkov, S. M.; Жарков, Сергей Михайлович; Myagkov, V. G.; Мягков, Виктор Григорьевич; Balashov, Yu. Yu.; Балашов, Юрий Юрьевич; Patrin, G. S.; Патрин, Геннадий Семёнович
}
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18.
Giant magnetostriction of
CuGeO3 / L. . Gladczuk [et al.]> //
Czech. J. Phys. - 1996. -
Vol. 46
. - P. 1969-1970,
DOI
10.1007/BF02570976. - Cited References: 10 . - ISSN 0011-4626
Рубрики:
SPIN-PEIERLS TRANSITION
COMPOUND
CUGEO3
SYSTEM CUGEO3
STATE
Аннотация:
The magnetostriction of CuGcO(3) single crystals has been measured in the temperature range from 5 to 16 K in magnetic fields up to 12 T. Giant values of the magnetostrictive strains along the b-axis is observed near the phase transition from the dimerized phase to the high field magnetic phase. The field induced magnetostriction in the antiferromagnetic phase is considerably smaller than in the dimerized phase.
WOS
,
Scopus
Доп.точки доступа:
Gladczuk, L.; Szymczak, R.; Nabialck, A.; Krynetskii, I.; Petrakovskii, G. A.; Петраковский, Герман Антонович; Sablina, K. A.; Саблина, Клара Александровна; Vorotynov, A. M.; Воротынов, Александр Михайлович; Szymczak, H.; International Conference on Low Temperature Physics(21 ; 1996 ; Aug. 8-14 ; Prague)
}
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19.
Guillemet-Fritsch S. Thermal
expansion study of CaCu3Ti4012
compound
in temperature range 150-200 К [Text] / M. V. Gorev, I. N. Flerov, A. V. Kartashev> //
12th European Meeting on Ferroelectricity : Abstracts. - 2011. - Ст. P9-1
Доп.точки доступа:
Gorev, M.V.; Flerov, I.N.; Kartashev, A.V.; European Meeting on Ferroelectricity(12 ; 2011 ; 26 June - 1 July ; Bordeaux, France)
}
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20.
Heat capacity of
the PbFe1/2Ta1/2O3 perovskite-like
compound
/ M. V. Gorev [et al.]> // Phys. Solid State. - 2004. -
Vol. 46
,
Is. 3
. - P. 521-525,
DOI
10.1134/1.1687872. - Cited References: 26 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
SINGLE-CRYSTALS
PBFE0.5TA0.5O3
FERROELECTRICS
DIFFRACTION
NIOBATE
GROWTH
Аннотация:
The heat capacity C-p(T) of the complex perovskite PbFe1/2Ta1/2O3 has been studied using adiabatic calorimetry in the temperature range 150-370 K. Three diffuse anomalies in C-p(T) are found to exist at temperatures T-d approximate to 350 K, T-m approximate to 250-300 K, and T-c approximate to 205 K. The anomalous and the lattice contribution to the heat capacity are separated, and the change in the entropy is determined. The results of the study are discussed jointly with the data on the structure and physical properties of the
compound
. (C) 2004 MAIK "Nauka / Interperiodica".
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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, CEMES, F-31055 Toulouse, France
INFM, I-090124 Cagliari, Italy
Dipartimento Fis, I-090124 Cagliari, Italy
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CEMES-CNRS, 29 Rue Jeanne Marvig, Toulouse, 31055, France
Inst. Naz. di Fisica della Materia, Dipartimento di Fisica, Monserrato (Cagliari), 090124, Italy
Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bondarev, V. S.; Бондарев, Виталий Сергеевич; Sciau, P.; Lehmann, A. G.
}
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