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Study of phase transitions in single crystals with elpasolite structure / K. S. Aleksandrov [et al.] // Ferroelectrics. - 1983. - Vol. 54, Is. 1. - P. 577-580 . - ISSN 0015-0193
Кл.слова (ненормированные):
CRYSTALS - Structure -- ELPASOLITE STRUCTURE -- PHASE TRANSISTIONS -- FERROELECTRIC MATERIALS
Аннотация: Structural distortions and physical properties of some fluorides with the elpasolite structure were studied. Different types of distortions at ferroelastic phase transitions for fluorides and chlorides are discussed.

Scopus

Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bovina, A. F.; Бовина, Ася Федоровна; Voronov, V. N.; Воронов, Владимир Николаевич; Горев, Михаил Васильевич; Gorev, M. V.; Melnikova, S. V.; Мельникова, Светлана Владимировна; Misjul, S. V.; Мисюль, Сергей Валентинович; European Meeting on Ferroelectricity(5 ; 1983 ; Sept. ; 26-30 ; Malaga, Sp)
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The study of phase-transitions in single-crystals with elpasolite structure / K. S. Aleksandrov [et al.] // Ferroelectrics. - 1984. - Vol. 54, Is. 1. - P. 237/577-240/580, DOI 10.1080/00150198408215859. - Cited References: 7. - В WoS указаны стр. 577-580 . - ISSN 0015-0193

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter

Аннотация: Structural distortions and physical properties of some fluorides with the elpasolite structure were studied. Different types of distortions at ferroelastic phase transitions for fluorides and chlorides are discussed.

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Доп.точки доступа:
Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Bovina, A. F.; Бовина, Ася Федоровна; Voronov, V. N.; Воронов, Владимир Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Melnikova, S. V.; Мельникова, Светлана Владимировна; Misjul, S. V.; Мисюль, Сергей Валентинович
}
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Aleksandrov, K. S.
Successive phase-transitions in ferroelastic cs2rbdyf6 with elpasolite-type structure / K. S. Aleksandrov, S. V. Melnikova, S. V. Misyul // Phys. Status Solidi A. - 1987. - Vol. 104, Is. 2. - P. 545-548, DOI 10.1002/pssa.2211040205. - Cited References: 6 . - ISSN 0031-8965

РУБ Materials Science, Multidisciplinary + Physics, Applied + Physics, Condensed Matter

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Доп.точки доступа:
Melnikova, S. V.; Мельникова, Светлана Владимировна; Misyul, S. V.; Мисюль, Сергей Валентинович; Александров, Кирилл Сергеевич
}
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    Phase-transitions in elpasolite Rb2KSCF6 / I. N. Flerov [et al.] // Fiz. Tverd. Tela. - 1992. - Vol. 34, Is. 7. - P. 2185-2195. - Cited References: 24 . - ISSN 0367-3294
Рубрики:
RB2KMIIIF6 ELPASOLITES
   CS2NANDCL6
   SCATTERING
   RB2NADYF6
   CS2RBDYF6
   RB2KDYF6
   CRYSTAL
   MODE

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Публикация на русском языке Фазовые переходы в эльпасолите Rb[2]KScF[6] [Текст] / И. Н. Флеров [и др.] // Физ. тверд. тела. - 1992. - Т. 34 Вып. 7. - С. 2185-2195

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Melnikova, S. V.; Мельникова, Светлана Владимировна; Misyul, S. V.; Мисюль, Сергей Валентинович; Voronov, V. N.; Воронов, Владимир Николаевич; Aleksandrov, K. S.; Александров, Кирилл Сергеевич
}
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Zinenko, V. I.
Lattice dynamics of K2NaAlF6, K3AlF6, and Na3AlF6 crystals with the elpasolite structure / V. I. Zinenko, N. G. Zamkova, S. N. Sofronova // J. Exp. Theor. Phys. - 1998. - Vol. 87, Is. 5. - P. 944-951, DOI 10.1134/1.558743. - Cited References: 10 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary

Аннотация: This paper presents the results of a nonempirical calculation of the static and dynamic properties of K2NaAlF6, K3AlF6, and Na3AlF6 crystals with the elpasolite structure. The calculation is based on a microscopic model of an ionic crystal that allows for the deformability and polarizability of the ions. The deformability parameters of the ions are determined by minimizing the total energy of the crystal. The total energy is regarded as a functional of the electron density, using the local Thomas-Fermi approximation and taking into account exchange (correlation) effects. The results of the calculations of the equilibrium lattice parameters and of the permittivities are in good agreement with the experimental data. Unstable vibrational modes are found in the spectrum of the lattice vibrations, with these modes occupying the phase space in the entire Brillouin zone. (C) 1998 American Institute of Physics. [S1063-7761(98)01311-0].

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Sect, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Krasnoyarsk 660041, Russia
ИФ СО РАН

Доп.точки доступа:
Zamkova, N. G.; Замкова, Наталья Геннадьевна; Sofronova, S. N.; Софронова, Светлана Николаевна; Зиненко, Виктор Иванович
}
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Flerov, I. N.
Specific heat of the elpasolite Pb2MgWO6 / I. N. Flerov, M. V. Gorev, P. . Sciau // Phys. Solid State. - 1999. - Vol. 41, Is. 9. - P. 1544-1546, DOI 10.1134/1.1131020. - Cited References: 12 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
PEROVSKITE PB2MGWO6
Аннотация: The specific heat of Pb2MgWO6 has been measured in the temperature interval 83-370 K. An anomaly in the specific heat associated with the phase transition at T-0=312.8 K has been discovered. The thermodynamic parameters of the structural phase transition Fm3m-Pmcn have been determined. (C) 1999 American Institute of Physics. [S1063-7834(99)03209-8].

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Публикация на русском языке Флеров, Игорь Николаевич. Теплоемкость эльпасолита Pb2MgWO6 [Текст] / И. Н. Флеров, М. В. Горев, Ф. Сью // Физ. тверд. тела. - Санкт-Петербург, 1999. - Т. 41 Вып. 9. - С. 1686-1688

Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
CNRS, Ctr Elaborat Mat & Etud Struct, F-31055 Toulouse, France
ИФ СО РАН

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Sciau, P.; Флёров, Игорь Николаевич
}
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Thermodynamic properties of (NH4)(2)KGaF6 elpasolite / I. N. Flerov [et al.] // Phys. Solid State. - 2001. - Vol. 43, Is. 12. - P. 2301-2306, DOI 10.1134/1.1427960. - Cited References: 19 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
NUCLEAR MAGNETIC-RESONANCE
   PHASE-TRANSITIONS
   CRYOLITE (NH4)(3)SCF6
   MOTIONS
   F-19
   H-1
Аннотация: The heat capacity of (NH4)(2)KGaF6 elpasolite is measured in the temperature range from 80 to 350 K. A sequence of three phase transitions at T-1 = 288.5 K, T-2 = 250 K, and T-3 = 244.5 K is revealed, and the thermodynamic characteristics of these transitions are determined. The influence of hydrostatic pressure on the phase transition temperature is investigated. The results obtained are discussed within the model of orientational ordering of NH4+ and GaF63- ionic groups. (C) 2001 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Afanas'ev, M. L.; Ushakova, T. V.
}
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Soft-mode condensation in Raman spectra of the Rb2KScF6 elpasolite / A. N. Vtyurin [et al.] // Phys. Solid State. - 2001. - Vol. 43, Is. 11. - P. 2154-2157, DOI 10.1134/1.1417197. - Cited References: 11 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
STRUCTURAL PHASE-TRANSITION
SCATTERING
Аннотация: This paper reports on the first observation of soft-mode condensation in the Raman spectra of the Rb2KScF6 elpasolite crystal below the transition points from the cubic to tetragonal and, subsequently, monoclinic phase. (C) 2001 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, Kirenskii Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Univ Maine, F-72085 Le Mans, France
ИФ СО РАН
Kirenskii Inst. of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Universite du Maine, Le Mans, Cedex 9, 72085, France

Доп.точки доступа:
Vtyurin, A. N.; Втюрин, Александр Николаевич; Bulou, A.; Krylov, A. S.; Крылов, Александр Сергеевич; Voronov, V. N.; Воронов, Владимир Николаевич
}
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Gorev, M. V.
Heat capacity and the p-T phase diagram of Pb2MgTeO6 elpasolite / M. V. Gorev, I. N. Flerov, P. . Sciau // Phys. Solid State. - 2001. - Vol. 43, Is. 2. - P. 345-349, DOI 10.1134/1.1349486. - Cited References: 17 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
ORDERED PEROVSKITE PB2MGTEO6
   CRYSTAL-STRUCTURE
   PB2COWO6
   PB2MGWO6
Аннотация: The heat capacity of Pb2MgTeO6 is measured in the temperature range 80-300 K. It is found that the heat capacity exhibits an anomaly associated with the phase transition at T-0 = 186.9 K. The thermodynamic parameters of the structural transformation are determined. The effect of hydrostatic pressure up to 0.5 GPa on the phase transition temperature is examined. (C) 2001 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
CNRS, Ctr Mat Improvement & Struct Invest, F-31055 Toulouse, France
ИФ СО РАН
Kirenskii Inst. of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
CNRS Ctr. for Mat. I., Tuluza, 31055, France

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Sciau, P.; Горев, Михаил Васильевич
}
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10.

The p-T phase diagram of ammonium hexafluoroaluminate / M. V. Gorev [et al.] // J. Phys.: Condens. Matter. - 2002. - Vol. 14, Is. 25. - P. 6447-6453, DOI 10.1088/0953-8984/14/25/312. - Cited References: 17 . - ISSN 0953-8984

РУБ Physics, Condensed Matter
Рубрики:
NUCLEAR MAGNETIC-RESONANCE
   TRANSITIONS
   MOTIONS
   F-19
   H-1
Кл.слова (ненормированные):
Entropy -- Hydrostatic pressing -- Mathematical models -- Order disorder transitions -- Phase diagrams -- Specific heat of solids -- Ammonium hexafluoroaluminate -- Crolite -- Elpasolite -- Ammonium compounds
Аннотация: The heat capacity and the effect of hydrostatic pressure on structural phase transitions in ammonium hexafluoroaluminate, (NH4)(3)AlF6, have been studied. Two heat capacity anomalies have been found with maxima at T-1 = 218.5 +/- 0.5 K and T-2 = 179 +/- 2 K. Respective entropy changes of phase transitions are DeltaS(1) = 15.3 +/- 0.5 J mol(-1) K-1 and DeltaS(2) = 2.5 +/- 0.5 J mol(-1) K-1. It is shown that the p-T phase diagram of this compound is rather complex and contains a triple point (p(tp) = 0.12 GPa, T-tp = 221 K) and high-pressure phase. The mechanism of transformations and generalized p-T phase diagram for compounds of the (NH4)(3)(MF6)-F-III family are discussed within the framework of the rotational order-disorder model.

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Держатели документа:
LV Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Inst Chim Mat Condensee Bordeaux, F-33608 Pessac, France
ИФ СО РАН
L. V. Kirensky Institute of Physics, 660036 Krasnoyarsk, Russian Federation
Institut de Chimie de la Matiere Condensee de Bordeaux, 33608 Pessac, France

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Flerov, I. N.; Флёров, Игорь Николаевич; Tressaud, A.; Durand, E.
}
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11.

Low-temperature specific heat of the Rb2KScF6 elpasolite / I. N. Flerov [et al.] // Phys. Solid State. - 2003. - Vol. 45, Is. 1. - P. 167-170, DOI 10.1134/1.1537430. - Cited References: 9 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
PHASE-TRANSITIONS
   CRYOLITE (NH4)(3)SCF6
   DISTORTED PHASES
   SYMMETRY
Аннотация: The specific heat of single-crystal Rb2KScF6 is measured using ac calorimetry in the range 4-280 K. The results are discussed in the context of a group-theoretical analysis of possible distortions of the elpasolite structure and of experimental data obtained earlier with an adiabatic calorimeter in a narrower temperature region. (C) 2003 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, Siberian Div, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Univ Zaragoza, CSIC, Inst Sci Mat Aragon, E-50009 Zaragoza, Spain
ИФ СО РАН
Kirenskii Inst. of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Inst. de Sciencia de Mat. de Aragon, CSIC, Universidad de Zaragoza, Zaragoza 50009, Spain

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Burriel, R.; Gorev, M. V.; Горев, Михаил Васильевич; Isla, P.; Voronov, V. N.; Воронов, Владимир Николаевич
}
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12.

Raman spectra and phase transitions in the Rb2KScF6 elpasolite / A. S. Krylov [et al.] // Ferroelectrics. - 2003. - Vol. 284. - P. 221-238, DOI 10.1080/00150190390204709. - Cited References: 13 . - ISSN 0015-0193

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
LIGHT-SCATTERING
OPTICAL PHONONS
MODE
Кл.слова (ненормированные):
Rb2KScF6 -- phase transitions -- Raman scattering -- soft modes
Аннотация: Raman spectra of Rb2KScF6 elpasolite crystal have been studied in a wide temperature range, including two transition points: from cubic to tetragonal, and then-to the monoclinic phase. For the first time both for this crystal and for fluoride elpasolites in general soft modes restoration has been found below transition points; in agreement with selection rules a splitting of degenerate modes has been observed as well both for lattice vibrations and internal modes of ScF6 octahedrons. Parameters of Raman lines have been quantitatively analyzed and found in good agreement with known thermodynamic characteristics of these transitions; in particular, lines widths are shown to be determined by tree-phonons anharmonic interactions. A wide region of pretransitional fluctuations was found above the upper transition point.

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Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Bulou, A.; Voronov, V. N.; Воронов, Владимир Николаевич; Russian-CIS-Baltic-Japanese symposium on ferroelectricity(7 ; 2002 ; Jun ; 24-28 ; St.-Petersburg)
}
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13.

Lattice dynamics and raman scattering spectrum of elpasolite Rb2KScF6: Comparative analysis / S. N. Krylova [et al.] // Phys. Solid State. - 2004. - Vol. 46, Is. 7. - P. 1311-1319, DOI 10.1134/1.1778457. - Cited References: 18 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
STRUCTURAL PHASE-TRANSITION
   LIGHT-SCATTERING
   OPTICAL PHONONS
   SOFT-MODE
   CRYSTAL
Аннотация: Raman scattering spectra of elpasolite Rb2KScF6 are studied in a wide temperature range including two phase transitions: from the cubic to the tetragonal phase and then to the monoclinic phase. The experimental Raman scattering spectrum is compared with the lattice vibration spectra of these phases calculated using an ab initio approach. A number of anomalies (caused by structural rearrangement during the phase transitions) are revealed and quantitatively analyzed in the ranges of both the intramolecular vibrations of the octahedron molecular ScF6 ions and low-frequency intermolecular lattice vibrations. The interaction between low-frequency intramolecular vibrations and the intermolecular modes is found to be significant, and strong resonance interaction of the rotational soft modes (which are recovered below the phase transition points) with hard low-frequency vibrations of the rubidium ion sublattice is detected. These interactions are shown to substantially complicate the spectra. (C) 2004 MAIK "Nauka / Interperiodica".

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
Univ Maine, F-72085 Le Mans 9, France
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Universite du Maine, Le Mans, Cedex 9, 72085, France

Доп.точки доступа:
Krylova, S. N.; Крылова, Светлана Николаевна; Vtyurin, A. N.; Втюрин, Александр Николаевич; Bulou, A.; Krylov, A. S.; Крылов, Александр Сергеевич; Zamkova, N. G.; Замкова, Наталья Геннадьевна
}
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14.

Calorimetric and x-ray diffraction studies of the (NH4)(3)WO3F3 and (NH4)(3)TiOF5 perovskite-like oxyfluorides / I. N. Flerov [et al.] // Phys. Solid State. - 2004. - Vol. 46, Is. 5. - P. 915-921, DOI 10.1134/1.1744971. - Cited References: 11 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
PHASE-TRANSITIONS
ELPASOLITE
K3MOO3F3
Аннотация: The heat capacity and unit cell parameters of the (NH4)(3)WO3F3 and (NH4)(3)TiOF5 perovskite-like oxyfluorides were measured in the temperature interval from 80 to 300 K; the existence of two and one phase transitions in these compounds, respectively, was demonstrated, and their thermodynamic parameters were determined. The effect of a hydrostatic pressure of up to 0.5 GPa on the phase transition temperatures was studied. Triple points and high-pressure phases were found in the T vs. p diagrams. An analysis of entropy changes suggests that all the structural transformations revealed are associated with the ordering of structural blocks. (C) 2004 MAIK "Nauka / Interperiodica".

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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Chem, Far E Div, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Institute of Chemistry, Far East Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok, 690022, Russian Federation

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Fokina, V. D.; Фокина, Валентина Дмитриевна; Bovina, A. F.; Бовина, Ася Федоровна; Laptash, N. M.
}
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15.

Ferroelastic phase transitions in fluorides with cryolite and elpasolite structures / I. N. Flerov, M. V. Gorev, K. S. Aleksandrov [et al.] // Kristallogr. - 2004. - Vol. 49, Is. 1. - P. 107-115 . - ISSN 0023-4761

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Другая переводная версия

Публикация на русском языке Сегнетоэластические фазовые переходы во фторидах со структурой криолита и эльпасолита [Текст] / И. Н. Флеров [и др.] // Кристаллография. - 2004. - Т. 49 Вып. 1. - С. 107-114

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Tressaud, A.; Fokina, V. D.; Фокина, Валентина Дмитриевна
}
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16.

    Ferroelastic phase transitions in fluorides with cryolite and elpasolite structures / I. N. Flerov [et al.] // Crystallogr. Rep. - 2004. - Vol. 49, Is. 1. - P. 100-107, DOI 10.1134/1.1643969. - Cited References: 43 . - ISSN 1063-7745
Рубрики:
NUCLEAR MAGNETIC-RESONANCE
   THERMODYNAMIC PROPERTIES
   RB2KMIIIF6 ELPASOLITES
   NEUTRON-DIFFRACTION
   CRYSTALS
   PEROVSKITES
   DIAGRAM
   SC
   RB2KGAXSC1-XF6
   SCATTERING
Аннотация: The ferroelastic phase transitions are investigated in several series of fluoride crystals belonging to the elpasolite and cryolite families (space group Fm (3) over barm) with the general formula A(2)BB'F-6. The influence of the size and shape of cations and anions on the entropy and the mechanism of structural distortions is discussed. (C) 2004 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Inst Chim Mat Condensee Bordeaux, F-33608 Pessac, France
ИФ СО РАН

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Aleksandrov, K. S.; Александров, Кирилл Сергеевич; Tressaud, A.; Fokina, V. D.; Фокина, Валентина Дмитриевна
}
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17.

Structural phase transition in elpasolite-like (NH4)(2)KWO3F3 / I. N. Flerov [et al.] // Phys. Solid State. - 2006. - Vol. 48, Is. 1. - P. 106-112, DOI 10.1134/S1063783406010215. - Cited References: 16 . - ISSN 1063-7834

РУБ Physics, Condensed Matter

Аннотация: A new chemical compound, (NH4) 2KWO3 F-3, was synthesized. The Rietveld-refined crystal structure was found to be cubic at room temperature and to belong to the elpasolite family (space group). The heat capacity and unit cell parameters were studied within a broad temperature range. A second-order phase transition was found to occur at 235.4 K and to be well described in terms of phenomenological theory. Hydro-static pressure broadens the temperature interval of stability of the cubic phase (dT(0)/dp = -10.8K GPa(-1)). A possible model of structural ordering based on a comparison of the entropy parameters and electron density distribution in oxygen and fluorine atoms is discussed.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Fokina, V. D.; Фокина, Валентина Дмитриевна; Bovina, A. F.; Бовина, Ася Федоровна; Molokeev, M. S.; Молокеев, Максим Сергеевич; Boiko, Y. V.; Voronov, V. N.; Воронов, Владимир Николаевич; Kocharova, A. G.; Кочарова, Алла Георгиевна
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18.

A study of phase transition in (NH4)(3)WO3F3 oxyfluoride by Raman scattering / A. S. Krylov [et al.] // Phys. Status Solidi B. - 2006. - Vol. 243, Is. 2. - P. 435-441, DOI 10.1002/pssb.200541259. - Cited References: 11 . - ISSN 0370-1972

РУБ Physics, Condensed Matter
Рубрики:
ELPASOLITE RB2KSCF6
Аннотация: Raman scattering spectra of perovskite-like (NH4)(3)WO3F3 oxyfluoride are studied in the 70-3600 cm(-1) frequency range and the 93-323 K temperature range including the transition point from orientationally disordered cubic phase into the lower symmetry one. Internal vibrations of ammonium ions and WO3F3 octahedra have been found to exhibit transition anomalies. Analysis of measurements suggests that the transition under study is due mainly to the ordering of octahedra.

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Держатели документа:
Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Inst Chem, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, 660036 Krasnoyarsk, Russian Federation
Institute of Chemistry, 690022 Vladivostok, Russian Federation

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Gerasimova, J. V.; Герасимова, Юлия Валентиновна; Vtyurin, A. N.; Втюрин, Александр Николаевич; Fokina, V. D.; Фокина, Валентина Дмитриевна; Laptash, N. M.; Voyt, E. I.
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19.

Heat capacity, structure, and p-T phase diagram of elpasolite (NH4)(2)KMoO3F3 / I. N. Flerov [et al.] // Phys. Solid State. - 2007. - Vol. 49, Is. 1. - P. 141-147, DOI 10.1134/S1063783407010234. - Cited References: 8 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
TRANSITIONS
Аннотация: Thermophysical and structural studies of an (NH4)(2)KMoO3F3 crystal show that this crystal belongs to the family of elpasolites (space group Fm (3) over barm) and undergoes an order-disorder phase transition at To 241.5 K. Under hydrostatic pressure, this phase transition splits into two consecutive transitions at the tricritical point with parameters T-tr = 232.5 K and p(tr)= 0.21 GPa. It was found that anomalous hysteresis and relaxation phenomena accompany the transitions from the cubic to both distorted phases. The results are analyzed taking into account the data on the phase transition in the related elpasolite (NH4)(2)KWO3F3.

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Держатели документа:
Russian Acad Sci, Siberian Div, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Russian Acad Sci, Far Eastern Div, Inst Chem, Vladivostok 690022, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Chemistry, Far Eastern Division, Russian Academy of Sciences, pr. Stoletiya Vladivostoka 159, Vladivostok 690022, Russian Federation

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Fokina, V. D.; Фокина, Валентина Дмитриевна; Bovina, A. F.; Бовина, Ася Федоровна; Molokeev, M. S.; Молокеев, Максим Сергеевич; Pogorel'tsev, E. I.; Laptash, N. M.
}
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20.

Oxyfluorides with Elpasolite-Cryolite Structure as Materials of Fundamental and Practical Interests / Fokina V.D., Laptash N.M., Flerov I.N. // Advanced inorganic fluorides : the Third International Siberian workshop Intersibfluorine - 2008, September 01-06, 2008, Vladivostok, Russia : proceedings of ISIF-2008. - Vladivostok, 2008. - p. 29-30 . - ISBN 978-5-98128-036-8

Доп.точки доступа:
Fokina, V. D.; Фокина, Валентина Дмитриевна; Laptash, N. M.; Flerov, I. N.; Флёров, Игорь Николаевич; "Advanced inorganic fluorides", International Siberian workshop(3 ; 2008 ; SEP. ; Vladivostok)
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