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Parameters of the effective singlet-triplet model for band structure of high-T-c cuprates by alternative approaches / M. M. Korshunov [et al.] // J. Exp. Theor. Phys. - 2004. - Vol. 99, Is. 3. - P. 559-565, DOI 10.1134/1.1809685. - Cited References: 48 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
DENSITY-FUNCTIONAL CALCULATION
   TIGHT-BINDING METHOD
   COPPER OXIDES
   ENERGY-BANDS
   SUPERCONDUCTORS
   HOLE
   LA2-XSRXCUO4
   PLANE
   SR2CUO2CL2
   INSULATORS
Кл.слова (ненормированные):
Band structure -- Carbon dioxide lasers -- Copper oxides -- Doping (additives) -- Parameter estimation -- Electron systems -- Generalized tight binding (GTB) -- Parameters extraction -- Singlet triplet model -- Technetium compounds
Аннотация: We consider the problem of determining the parameters for high-T-c superconducting copper oxides. Alternative approaches, the ab initio LDA and LDA + U calculations and the generalized tight-binding (GTB) method for strongly correlated electron systems, are used to calculate hopping and exchange parameters of the effective singlet-triplet model for the CuO2 layer. The resulting parameters are in remarkably good agreement with each other and with parameters extracted from experiment. This set of parameters is proposed for proper quantitative description of the physics of hole-doped high-T-c cuprates in the framework of effective models. (C) 2004 MAIK "Nauka / Interperiodica".

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Met Phys, Ural Div, Ekaterinburg 620219, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Institute of Metal Physics, Ural Division, Russian Academy of Sciences, Ekaterinburg, 620219, Russian Federation

Доп.точки доступа:
Korshunov, M. M.; Коршунов, Максим Михайлович; Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Pchelkina, Z. V.; Nekrasov, I. A.; Korotin, M. A.; Anisimov, V. I.
}
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Features of the magnetic properties of La0.7Sr0.3MnO3 manganite films obtained by an extraction-pyrolysis method / G. S. Patrin [et al.] // Tech. Phys. Lett. - 2007. - Vol. 33, Is. 4. - P. 330-332, DOI 10.1134/S1063785007040177. - Cited References: 12 . - ISSN 1063-7850

РУБ Physics, Applied
Рубрики:
PHASE-SEPARATION
MAGNETORESISTANCE
Аннотация: We have experimentally studied the magnetic properties of manganite films obtained for first time using an extraction-pyrolysis technique. It is established that the characteristics of samples significantly depend on the conditions of final annealing. The annealing at temperatures T-a 970 K is accompanied by strong thermomagmetic effects. and the resulting films possess properties similar to those of spin glasses. When the annealig temperature is increased to T-a = 1020 K, the films exhibit magnetic properties typical of ferromagnetic systems.

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Держатели документа:
Russian Acad Sci, Siberian Div, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Krasnoyarsk 660041, Russia
Krasnoyarsk State Polytech Univ, Krasnoyarsk 660062, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Patrin, G. S.; Патрин, Геннадий Семёнович; Polyakova, K. P.; Полякова, Клавдия Павловна; Patrusheva, T. N.; Патрушева, Тамара Николаевна; Velikanov, D. A.; Великанов, Дмитрий Анатольевич
}
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Nanosize Magnetic Films and Powders Prepared by Extraction-Pyrolysis Technique [Text] / Patrusheva T.N.Polyakova K.P. [et al.] // J. Ma ter. Sci. Engin. - 2010. - Vol. 4, Is .2. - P19-25

Доп.точки доступа:
Patrusheva, T. N.; Патрушева Тамара Николаевна; Polyakova, K. P.; Полякова Клавдия Павловна; Seredkin, V. A.; Середкин Виталий Александрович; Komogortsev, S. V.; Комогорцев Сергей Викторович; Patrushev, V. V.; Patrin, G. S.; Патрин Геннадий Семёнович
}
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Polycrystalline La1-xSrxMnO3 films prepared by extraction pyrolitic method [Text] / G. S. Patrin, K. P. Polyakova [et al.] // IV Euro-Asian Symposium "Trends in MAGnetism" Nanospintronics (EASTMAG-2010). School for young scientist "Spintronics" : June 28 - Lule 2, 2010"Book of abstracts. - Ekaterinburg, 2010. - P. 199

РИНЦ

Доп.точки доступа:
Patrin, G.S.; Polyakova, K.P.; Patrusheva, T.N.; Klabukov, A.A.; Seredkin, V.A.; Patrin, K.G.; Polyakov, V.V.; Euro-Asian Symposium "Trends in MAGnetism"(4 ; 2010 ; Jun.-Jul. ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(4 ; 2010 ; Jun.-Jul. ; Ekaterinburg); Уральское отделение РАН
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    Simultaneous ion exchange recovery of platinum and rhodium from chloride solutions / O. N. Kononova [et al.] // Hydrometallurgy. - 2011. - Vol. 105, Is. 3-4. - P. 341-349, DOI 10.1016/j.hydromet.2010.11.009. - Cited Reference Count: 46 . - JAN. - ISSN 0304-386X
Рубрики:
GROUP-METALS PGM
   SEPARATION
   CATALYST
   ANION
   ADSORPTION
   EXTRACTION
   CHEMISTRY
   RESIN
Кл.слова (ненормированные):
platinum -- rhodium -- sorption -- anion exchangers -- chloride solutions -- anion exchangers -- chloride solutions -- platinum -- rhodium -- sorption -- ammonium thiocyanate -- anion exchangers -- basic parameters -- chemical structure -- chloride solutions -- diffusion coefficients -- distribution coefficient -- exchange capacities -- kinetic properties -- noble metals -- purolite -- rhodium chloride -- separation factors -- sorption ability -- work focus -- ammonium compounds -- chlorine compounds -- desorption -- hydrochloric acid -- ion exchange -- ion exchange resins -- ions -- platinum -- platinum compounds -- potassium hydroxide -- precious metals -- recovery -- rhodium -- sulfuric acid -- thioureas -- urea -- rhodium compounds
Аннотация: This work focuses on the sorption recovery of platinum (II, IV) and rhodium (III) simultaneously present in chloride solutions, freshly prepared and stored over 3 months, on commercial anion exchangers with different physical and chemical structure. The sorption was carried out from solutions with 0.001-4.0 mol/L HCl. The initial platinum and rhodium concentrations in contacting solutions were 0.25-2.5 mmol/L Sorption and kinetic properties of the chosen anion exchangers were investigated and the basic parameters of exchange capacity, recovery, distribution coefficients, separation factors, process rate, diffusion coefficients and half-exchange times were calculated. It is shown that anion exchangers investigated possess high sorption ability to platinum and rhodium chloride complexes, which does not deteriorate in case of stored solutions. Desorption of platinum and rhodium from the resins investigated was carried out with hydrochloric acid (2 mol/L), thiourea (1 mol/L) in sulfuric acid (2 mol/L) or in potassium hydroxide (2 mol/L) as well as by ammonium thiocyanate (2 mol/L). It was shown that complete separation of platinum and rhodium can be carried out with 2 mol/L HCl on anion exchanger Purolite S 985, whereas 2 mol/L NH(4)SCN as an elution agent leads to complete separation of noble metals on anion exchangers Purolite S 985, Purolite A 500 and AM-2B. (C) 2010 Elsevier B.V. All rights reserved.

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Держатели документа:
Siberian Fed Univ, Dept Chem, Krasnoyarsk 660041, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Dept, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Kononova, O.N.; Melnikov, A.M.; Borisova, T.V.; Krylov, A. S.; Крылов, Александр Сергеевич
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Ion exchange equilibria in simultaneous extraction of platinum(II, IV) and rhodium(III) from hydrochloric solutions / A. M. Mel'nikov [et al.] // Russ. J. Phys. Chem. A. - 2012. - Vol. 86, Is. 6. - P. 1018-1024, DOI 10.1134/S0036024412060192. - Cited References: 24 . - ISSN 0036-0244

РУБ Chemistry, Physical

Кл.слова (ненормированные):
platinum -- rhodium -- ionites -- ion exchange equilibria -- hydrochloric acid solutions -- sorption
Аннотация: Regularities of sorption extraction of platinum(II, IV) and rhodium(III) by anion exchangers of various physical and chemical structure in the presence of hydrochloric media were studied. It is established that AM-2B, Purolite A 500, and Purolite S 985 ionites adsorb complex anions of platinum metals employing mixed mechanism. A high affinity of the studied anionites for the studied complex anions of platinum and rhodium is established.

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Публикация на русском языке Ионообменные равновесия при совместном извлечении платины (II, IV) и родия (III) из солянокислых растворов [Текст] / А. М. Мельникова [и др.] // Журн. физ. химии. - 2012. - Т. 86 № 6. - С. 1129-1135

Держатели документа:
[Mel'nikov, A. M.] Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660041, Russia
[Kononova, O. N.
Pavlenko, N. I.] Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660049, Russia
[Krylov, A. S.] Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Mel'nikov, A. M.; Kononova, O. N.; Pavlenko, N. I.; Krylov, A. S.; Крылов, Александр Сергеевич
}
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Luminescent oxide materials obtained by the extraction pyrolytic method / T. N. Patrusheva [et al.] // Theor. Found. Chem. Eng. - 2012. - Vol. 46, Is. 4. - P. 379-383, DOI 10.1134/S0040579512040069. - Cited References: 13. - The work was supported by the Russian Foundation for Basic Research project (no. 10-03-00188a). . - ISSN 0040-5795

РУБ Engineering, Chemical

Кл.слова (ненормированные):
extraction pyrolytic method -- luminescent films -- X-ray diffraction -- luminescence spectra
Аннотация: Luminescent Y1.74Eu0.16Bi0.1O3 films have been obtained by extraction pyrolytic method. The formation of a crystalline structure in the film upon isothermal annealing in air at 600–650°C was established by X-ray diffraction. Single-phase Y1.74Eu0.16Bi0.1O3 films begin to exhibit luminescent properties after pyrolysis at 500°C; the intensity of luminescence increases with increasing temperature. The films annealed at 800°C consists of defect-free homogeneous crystallites with sizes of about 0.7 μm and demonstrats high luminescence intensity.

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Публикация на русском языке Оксидные люминисцентные материалы, полученные экстракционно-пиролитическим методом [Текст] / Т. Н. Патрушева [и др.] // Хим. технол. : ООО "Наука и технологии", 2010. - № 4. - С. 198-203

Держатели документа:
[Patrusheva, T. N.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Inst Phys, Krasnoyarsk 660036, Akademgorodok, Russia
Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

Доп.точки доступа:
Patrusheva, T. N.; Патрушева, Тамара Николаевна; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Khval'ko, A. A.; Kolovskii, Yu.V.; Polyushkevich, A. V.; Khol'kin, A. I.
}
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Ion-exchange extraction of platinum(II,IV) from chloride solutions in the presence of iron(III) / O. N. Kononova [et al.] // Russ. J. Phys. Chem. A. - 2015. - Vol. 89, Is. 8. - P. 1464-1470, DOI 10.1134/S0036024415080166. - Cited References: 28 . - ISSN 0036-0244. - ISSN 1531-863X

РУБ Chemistry, Physical
Рубрики:
RHODIUM
Кл.слова (ненормированные):
platinum -- iron -- ionites -- sorption -- hydrochloric solutions -- sorption
Аннотация: The sorption concentration of platinum(II,IV) in the presence of iron(III) is studied on new samples of domestically produced ionites of the CYBBER brand. In comparing the sorption and kinetic properties of the new ionites to those of sorbents of the Purolite brand studied earlier, the higher effectiveness of the former is demonstrated via the extraction of platinum(II,IV) ions from strongly and weakly acidic chloride solutions. It is found that the sorbed platinum ions can be completely separated from iron(III) ions through separate elution using 0.01-0.001 M HCl (iron ions) and a thiourea solution (80 g/L) in 0.3 M H2SO4 (platinum ions).

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Публикация на русском языке Ионообменное извлечение платины (II, IV) в присутствии железа (III) из хлоридных растворов [Текст] / О. Н. Кононова [и др.] // Журн. физ. химии : Наука, 2015. - Т. 83 № 8. - С. 1305-1312

Держатели документа:
Institute of Nonferrous Metals and Materials Science, Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Kononova, O. N.; Duba, E. V.; Karplyakova, N. S.; Krylov, A. S.; Крылов, Александр Сергеевич
}
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Transparent conductive ITO coatings obtained by pyrolysis of metal extracts / T. N. Patrusheva [et al.] // J. Appl. Chem. Sci. Int. - 2015. - Vol. 3, Is. 1. - P. 21-28 . - ISSN 2395-3705
Кл.слова (ненормированные):
Indium-tin oxide -- thin films -- extraction-pyrolysis technique -- liquid precursors -- nanocrystalline structure
Аннотация: Thin films of indium-tin oxide (ITO) have been prepared by pyrolysis of liquid organic-extracts of indium and tin. The films were deposited on glass substrate in the atmospheric condition. Extraction-pyrolytic method adopted here uses cheap starting materials and provides the required stoichiometric ratio by mixing the stable liquid precursors in appropriate concentration. Thermal decomposition processes are induced in the narrow temperature range of 350–400°C. The zirconium-yttrium oxide (ZYO) sublayer was deposited on glass substrate in advance to provide homo epitaxial growth. This would induce reduction in intrinsic stress of the films due to matching in thermal expansion coefficient with ITO film. XPS studies showed the absence of impurity elements in these extraction-pyrolytic technique derived ITO films and the spectra is quite similar to that for ITO films deposited in vacuum environment. ITO film has a nanocrystalline structure with grain size of about 6 nm.

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Доп.точки доступа:
Patrusheva, T. N.; Патрушева, Тамара Николаевна; Snezhko, N. Yu.; Belousov, A. L.; Rizhenkov, A. V.; Mikhlin, Y. L.; Михлин, Юрий Леонидович; Kirik, S. D.; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Zharkov, S. M.; Жарков, Сергей Михайлович; Romanov, A. A.
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10.

Yttrium-containing endohedral metallofullerenes: Synthesis and extraction / G. N. Churilov [et al.] // Phys. Solid State. - 2017. - Vol. 59, Is. 8. - P. 1662-1665, DOI 10.1134/S1063783417080054. - Cited References:11. - This study was supported by the Ministry of Education and Science of the Russian Federation, Russian/Japanese Project, agreement no. 14.613.21.0010, ID RFMEFl61314X0010. . - ISSN 1063-7834. - ISSN 1090-6460

РУБ Physics, Condensed Matter
Рубрики:
FULLERENES
PRESSURE
PLASMA
Аннотация: Yttrium-containing endohedral metallofullerenes are synthesized in an RF arc discharge in the helium flow with embedded Y2O3. It is shown that the formation of the metallofullerenes depends on the helium pressure in a chamber; however, this dependence cannot be explained using the model of formation of conventional fullerenes without a guest atom in a molecule. The results of extraction of Y@C-82 by pyridine and carbon disulfide are reported. The pressure corresponding to the maximum yttrium-containing endohedral metallofullerene content is shown to be 60 kPa; under this pressure, extraction by carbon disulfide allows obtaining 27.1 wt % of the endohedral metallofullerene, while extraction by pyridine yields its amount of 17.3 wt %.

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Публикация на русском языке Эндоэдральные металлофуллерены с иттрием: синтез и выделение [Текст] / Г. Н. Чурилов [и др.] // Физ. тверд. тела. - 2017. - Т. 59 Вып. 8. - С. 1638-1641

Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Fed Res Ctr KSC SB RAS, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Churilov, G. N.; Чурилов, Григорий Николаевич; Vnukova, N. G.; Внукова, Наталья Григорьевна; Tomashevich, E. V.; Dudnik, A. I.; Дудник, Александр Иванович; Glushchenko, G. A.; Глущенко, Гарий Анатольевич; Dubinina, I. A.; Дубинина, Ирина Александровна; Gulyaeva, U. E.; Гуляева, Ульяна Евгеньевна; Mel'nikova, E. I.; Ministry of Education and Science of the Russian Federation, Russian/Japanese Project [14.613.21.0010, RFMEFl61314X0010]
}
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