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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Бегунов А. И., Демидов А. А., Гудим, Ирина Анатольевна, Еремин, Евгений Владимирович
Заглавие : Магнитные свойства ферробората Nd0.95Dy0.05Fe3(BO3)4 с малым замещением в редкоземельной подсистеме
Место публикации : Журн. эксперимент. и теор. физ. - 2013. - Т. 144, Вып. 5. - С. 990-1003. - DOI 10.7868/S0044451013110102
Примечания : Исследование выполнено при финансовой поддержке РФФИ (грант № 12-02-31007 мол_а) и гранта МК-1700.2013.2 Президента РФ
Аннотация: Экспериментально и теоретически исследованы магнитные свойства монокристалла ферробората замещенного состава Nd0.95Dy0.05Fe3(BO3)4 с конкурирующими обменными Nd-Fe- и Dy-Fe-взаимодействиями. Обнаружены спонтанный спин-переориентационный переход вблизи T=4.3 К и аномалии на низкотемпературных кривых намагничивания вдоль тригональной оси c и в базисной плоскости ab. Измеренные свойства и обнаруженные эффекты проинтерпретированы в рамках единого теоретического подхода, который базируется на приближении молекулярного поля и расчетах в модели кристаллического поля для редкоземельного иона. Описаны экспериментальные температурные зависимости начальной магнитной восприимчивости от 2 до 300 К, аномалии на кривых намагничивания при B ll c и B⊥ c в полях до 1.5 Тл, а также полевые и температурные зависимости намагниченности в полях до 9 Тл. Проанализировано влияние малого замещения в редкоземельной подсистеме на магнитные свойства. При интерпретации экспериментальных данных определены параметры кристаллического поля и параметры обменных R-Fe- и Fe-Fe-взаимодействий.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Демидов А. А., Волков Д. В., Гудим, Ирина Анатольевна, Еремин, Евгений Владимирович, Темеров, Владислав Леонидович
Заглавие : Магнитные свойства редкоземельного ферробората SmFe3( BO3)4
Место публикации : Журн. эксперим. и теор. физ. - 2013. - Т. 143, Вып. 5. - С. 922-928. - DOI 10.7868/S0044451013050145
Аннотация: Экспериментально и теоретически исследованы магнитные свойства тригонального антиферромагнетика SmFe3( BO3)4. Измеренные характеристики рассмотрены в рамках теоретического подхода, который базируется на приближении молекулярного поля и модели кристаллического поля для редкоземельного иона. Описаны температурные зависимости начальной магнитной восприимчивости, полевые и температурные зависимости намагниченности в полях до 5 Тл, а также аномалия на кривой намагничивания при вблизи 1 Тл, свидетельствующая о наличии фазового перехода первого рода.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zinenko V. I., Pavlovskii M. S., Krylov A. S., Gudim, I. A., Eremin E. V.
Заглавие : Vibrational spectra and elastic, piezoelectric, and magnetoelectric properties of HoFe3(BO3)(4) and HoAl3(BO3)(4) crystals
Коллективы : Russian Federation under the program "Leading Scientific Schools" [NSh 4828.12.2]; Russian Foundation for Basic Research [12-02-00025-a]; Ministry of Education and Science of the Russian Federation [8365]
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2013. - Vol. 117, Is. 6. - P.1032-1041. - ISSN 1063-7761, DOI 10.1134/S1063776113140203. - ISSN 1090-6509
Примечания : Cited References: 17. - This study was supported financially by the President of the Russian Federation under the program "Leading Scientific Schools" (grant no. NSh 4828.12.2), the Russian Foundation for Basic Research (project no. 12-02-00025-a), and the Ministry of Education and Science of the Russian Federation (contract no. 8365).
Предметные рубрики: MAGNETOELASTIC PROPERTIES
SINGLE-CRYSTALS
FERROBORATE
Аннотация: Raman spectra of light are obtained for HoFe3(BO3)(4) and HoAl3(BO3)(4) crystals at various temperatures and are used for determining the frequencies of crystal lattice vibrations at the center of the Brillouin zone. It is also found that the HoFe3(BO3)(4) crystal exhibits a phase transition at T (c) a parts per thousand 366 K. The magnetoelectric effect in the paramagnetic phase of these compounds is studied experimentally. The lattice vibration frequencies, elastic and piezoelectric moduli, Born dynamic charges, and the high-frequency permittivity are calculated using the density functional method. A peculiar behavior of the transverse acoustic vibration branch is observed in the I" - Z direction of the Brillouin zone of the HoFe3(BO3)(4) crystal. The electric polarization induced by an external field is estimated using the calculated values of piezoelectric moduli and experimental values of magnetostriction.Спектры КР света получены для HoFe3 (BO3) 4 и HoAl3 (BO3) 4 кристаллы при различных температурах и используются для определения частоты колебаний кристаллической решетки в центре зоны Бриллюэна. Также обнаружено, что HoFe3 (BO3) 4 демонстрирует фазовый переход при Tc ≈ 366 К. Магнитоэлектрический эффект в парамагнитной фазе этих соединений экспериментально исследован. Частоты колебаний решетки, упругие и пьезоэлектрические модули, Борновские динамические заряды, и высокочастотная проницаемость рассчитываются с использованием метода функционала плотности. Своеобразное поведение поперечной ветви акустических колебаний наблюдается в направлении Γ Z зоны Бриллюэна в HoFe3 (BO3) 4.Электрическая поляризация индуцированная внешним полем оценивается с помощью расчетные значения пьезомодулей и экспериментальных значений магнитострикции.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Moshkina E. M., Gudim I. A., Temerov V. L., Krylov A. S.
Заглавие : Temperature-dependent absorption lines observation in Raman spectra of SmFe3 (BO3)4 ferroborate
Коллективы : RFBR [18-02-00696, 18-02-00754]
Место публикации : J. Raman Spectrosc. - 2018. - Vol. 49, Is. 10. - P.1732-1735. - ISSN 0377-0486, DOI 10.1002/jrs.5430. - ISSN 1097-4555(eISSN)
Примечания : Cited References: 12. - RFBR, Grant/Award Numbers: 18-02-00696 and 18-02-00754
Предметные рубрики: SmFe3 (BO3)4
Ho1-xNdxFe3(BO3)4
CRYSTALS
Ключевые слова (''Своб.индексиров.''): absorption--ferroborates--huntite--level splitting--magnetic phase--transitions
Аннотация: The paper demonstrates possibilities of observation and thermal dependency study of the absorption lines as a co‐product of Raman spectroscopy study in SmFe3 (BO3)4 ferroborate. Raman spectra of the ferroborate were studied in a wide temperature range (T = 10÷300 K). Temperature‐dependent absorption lines sensitive to the magnetic phase transition have been observed in Raman spectra at two spectral ranges.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Krylov A. S., Safronova S., Gudim, I. A., Moshkina E. M., Oreshonkov A. S., Shabanov A. V., Vtyurin A. N., Krylova S. N.
Заглавие : Temperature and high pressure study of structural and magnetic phase transitions in rear earth ferroborate crystals by raman spectroscopy
Коллективы : European Meeting on Ferroelectricity
Место публикации : The 13th Europ. Meeting on Ferroelectricity (EMF 2015): program. - 2015. - P.57
Аннотация: Crystals of the RFe3(BO3)4 family (R is rare earth ion) were reported to possess multiferroic features, demonstrating both structural and magnetic phase transitions [1-4], where transition points may be varied by rare earth composition. In this work we used Raman spectroscopy to study Ho(1 – x)NdxFe3(BO3)4 (x = 0, 0.25, 0.5, 0.75) crystals. Temperature measurements were performed in the temperature range 10–400 K. The aim of this study is to investigate possible existence of a soft mode related to structural order parameter and effects of magnetic transitions on Raman spectra. Structural transitions manifest clearly by soft mode restoration and new Raman lines appearance below 366 K and 203 K for x = 0 и x = 0.25 compositions respectively. In Nd-doped crystals significant modification of Raman scattering was induced by magnetic ordering below the Neel temperature (about 40 K), that include both magnon scattering and strong intensity redistribution of high frequency lattice modes. Analysis of vibrational spectra and its numerical simulation demonstrate that bigger cell volume of Nd-containing solid solutions provides bigger displacements of oxygen ions in a BO3 groups below the Neel temperature that results in stronger magnetoelastic interactions. This leads to the appearance of additional lines in the Raman spectra and rapid increase of their intensity with increasing magnetic order. Raman measurements on HoFe3(BO3) crystal were carried out at pressures up to 7 GPa and at temperatures up to 680 K by using a diamond anvil cell in order to determine the pressure–temperature phase diagram. From the changes in the Raman spectrum at the phase transition, the stability regions of phases I, II were investigated. After reaching 675 K and 2.5 GPa Raman spectra lines disappear and formation of a new crystalline form was discovered. This form persists ambient condition after removing high pressure and temperature. The work was supported by Grant of the Ministry of Education and the Russian Foundation for Basic Research Grants 13-02-00825.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Krylov A. S., Gudim, I. A., Krylova S. N., Vtyurin A. N.
Заглавие : Study of phase transitions in ferroborate crystals with structure of huntite mineral
Коллективы : "GeoRaman", International conference, Российская академия наук, Сибирское отделение РАН, Институт геологии и минералогии им. В.С. Соболева Сибирского отделения РАН
Место публикации : XII Int. conf. "GeoRaman-2016": abstract volume/ compiled and edited by T.A. Alifirova, S.V. Rashchenko, A.V. Korsakov. - Novosibirsk: Офсет, 2016. - P.16. - ISBN 978-5-85957-124-6
Примечания : References: 3
Аннотация: Multiferroic materials showing the coexistence of at least two ferroic orders ((anti)ferroelectric, (anti)ferromagnetic and (anti)ferroelasticity) are expected to find potential applications in many devices. Amongst these properties the coexistence of ferroelectricity and ferromagnetism is highly desired. Besides their coexistence, of utmost importance is a strong coupling between the two ferroic orders. In multiferroic materials, the coupling interaction between the different order parameters can produce additional functionalities. The application of multiferroics will make possible to significantly enlarge the functional possibilities of spintronics. Crystals of the RFe3(BO3)4 family (R is rare earth ion) with huntite mineral structure were reported to possess multiferroic features, demonstrating both structural and magnetic phase transitions [1 –4], where transition points may be varied by rare earth composition. In this work we used Raman spectroscopy to study Ho1–xNdxFe3(BO3)4 (x = 0, 0.25, 0.5, 0.75) single crystals. Raman measurements on HoFe3(BO3) crystal were carried out at pressures up to 7 GPa and at temperatures up to 680 K by using a diamond anvil cell in order to determine the pressure–temperature phase diagram. From the changes in the Raman spectrum at the phase transition, the stability regions of phases I, II were investigated (Figure 1). After reaching 675 K and 2.5 GPa Raman spectra lines disappear and formation of a new crystalline form was discovered. This form persists ambient condition after removing high pressure and temperature.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Vtyurin A. N., Krylov A. S., Sofronova S. N., Gerasimova J. V., Gudim, I. A.
Заглавие : Structural and magnetic phase transitions in rear earth ferroborate crystals – Raman scattering study
Коллективы : Joint Russia/CIS/Baltic/Japan Symposium on Ferroelectricity, International Conference Functional Materials and Nanotechnologies
Место публикации : Joint 12th Russia/CIS/Baltic/Japan Symp. Ferroelectricity. 9th Int. Conf. Funct. Mater. Nanotechnologies: book of abstracts/ mem. of progr. comm.: I. N. Flerov, V. I. Zinenko. - 2014. - P.156
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Krylov A. S., Sofronova S. N., Gudim, I. A., Krylova S. N., Vtyurin A. N.
Заглавие : Raman spectroscopic study of phase transitions in rare earth ferroborate multiferroic crystals under temperature and high-pressure
Коллективы : International conference on advanced vibrational spectroscopy at TU wien
Место публикации : The 8th International Conference on Advanced Vibrational Spectroscopy at TU Wien: abstracts. - 2015. - P.320. - ISBN 978-3-200-04205-6
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Peschanskii A. V., Yeremenko A. V., Fomin V. I., Bezmaternykh L. N., Gudim, I. A.
Заглавие : Raman scattering under structural and magnetic phase transitions in terbium ferroborate
Место публикации : Low Temp. Phys.: American Institute of Physics, 2014. - Vol. 40, Is. 2. - P.171-178. - ISSN 1063-777X, DOI 10.1063/1.4865566. - ISSN 1090-6517
Примечания : Cited References: 24
Предметные рубрики: SPIN-PHONON INTERACTION
GDFE3(BO3)4
Аннотация: The Raman scattering spectrum of single crystal TbFe3(BO3)4 was studied in the frequency range 3–500 cm−1 at temperatures from 2 to 300 K. It was found that in high- and low-temperature phases there exist additional phonon lines which were not known before. In the high-temperature phase, these lines originate from LO–TO splitting of polar phonons. Appearance of the additional lines in the low temperature phase is due to both a reduction of the crystal symmetry under the phase transition and an increase of the primitive cell volume. It was established that the frequencies of some phonon lines in the magneto-ordered phase are shifted towards the high-energy region upon applying an external magnetic field along the third-order axis. The spectrum of two-magnon Raman scattering was investigated. It was shown that at low temperatures the two-magnon band has a complex shape that reflects specific features in the density of state of the magnon branches. The magnon energy at the Brillouin zone boundary was determined.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Glamazda, A. Yu., Gnezdilov V. P., Lemmens P., Zvyagina G. A., Gudim I. A.
Заглавие : Raman scattering study of the rare-earth binary ferroborate Nd0.75Dy0.25Fe3(BO3)4 single crystal
Коллективы : DFG Excellence Cluster Quantum FrontiersGerman Research Foundation (DFG) [EXC 2123-390837967, DFG Le967/16-1, DFG-RTG 1952/1]
Место публикации : Low Temp. Phys. - 2021. - Vol. 47, Is. 12. - P.1011-1021. - ISSN 1063-777X, DOI 10.1063/10.0007074. - ISSN 1090-6517(eISSN)
Примечания : Cited References: 25. - A. Yu. Glamazda thanks Dr. A. V. Peschanskii for fruitful discussions. P. Lemmens acknowledges funding by the DFG Excellence Cluster Quantum Frontiers, EXC 2123-390837967, DFG Le967/16-1, and DFG-RTG 1952/1
Предметные рубрики: MAGNETIC PHASE-TRANSITIONS
SPIN REORIENTATION
Аннотация: We report comprehensive Raman scattering measurements on a single crystal of binary ferroborate Nd0.75Dy0.25Fe3(BO3)4 in the temperature range of 7–295 K with 532 nm (18797 cm−1) laser excitation. The performed analysis of the polarized Raman spectra revealed the bands assigned to phonon, magnetic, and electronic excitations. The temperature evolution of these quasiparticle excitations has allowed us to ascertain the intricate coupling and interplay between lattice, magnetic, and electronic degrees of freedom. Analysis of the measured Raman spectra made it possible to identify all A1 and E phonon modes predicted by the group-theoretical analysis. The splitting energies between the LO and TO components of the polar E phonons were determined. Below the magnetic ordering temperature of the Fe sublattice, TN, we have revealed a multiple peaked two-magnon excitation. Analyzing the temperature evolution of low-frequency modes in the spectra, we also identified modes that are associated with electronic transitions between the crystal field levels of the Nd3+ ions with ground-state 4I9/2 and of the Dy3+ ions with ground-state 6H15/2 multiplets. In addition to the already known temperatures of magnetic transitions, analysis of the temperature behavior of low-frequency phonon and electronic excitations made it possible to establish a temperature T* = 100 K, presumably associated with local distortions of the crystal lattice. The presence of this temperature is confirmed by our ultrasonic study. A group of intense bands observed in the frequency range 1700–2200 cm−1 has been associated with the mixed low-lying electronic Raman transitions 4I9/2→4I11/2 and the high-energy luminescence ones 4G5/2+2G7/2→4I9/2 for the Nd3+ ion.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Glamazda A. Yu., Gnezdilov V. P., Lemmens P., Zvyagina G. A., Gudim I. A.
Заглавие : Raman scattering study of the rare-earth binary ferroborate Nd0.75Dy0.25Fe3(BO3)4 single crystal
Место публикации : Физ. низких температур. - 2021. - Т. 47, Вып. 12. - С.1107-1118. - ISSN 01326414 (ISSN); Fiz. Nizk. Temp.
Примечания : Cited References: 26. - A. Yu. Glamazda thanks to Dr. A. V. Peschanskii for fruitful discussions. P. Lemmens acknowledges funding by the DFG Excellence Cluster Quantum Frontiers, EXC 2123-390837967, DFG Le967/16-1, and DFG-RTG 1952/1
Аннотация: We report comprehensive Raman scattering measurements on a single crystal of binary ferroborate Nd0.75Dy0.25Fe3(BO3)4 in the temperature range of 7–295 K with 532 nm (18797 cm–1) laser excitation. The performed analysis of the polarized Raman spectra revealed the bands assigned to phonon, magnetic, and electronic excitations. The temperature evolution of these quasiparticle excitations has allowed us to ascertain the intricate coupling and interplay between lattice, magnetic, and electronic degrees of freedom. Analysis of the measured Raman spectra made it possible to identify all A1 and Е phonon modes of predicted by the group-theoretical analysis. The splitting energies between the LO and TO components of the polar E phonons were determined. Below the magnetic ordering temperature of the Fe sublattice, TN, we have revealed a multiple peaked two-magnon excitation. Analyzing the temperature evolution of low-frequency modes in the spectra, we also identi-fied modes that are associated with electronic transitions between the crystal field levels of the Nd3+ ions with ground-state 4I9/2 and of the Dy3+ ions with ground-state 6H15/2 multiplets. In addition to the already known temperatures of magnetic transitions, analysis of the temperature behavior of low-frequency phonon and electronic excitations made it possible to establish a temperature T * = 100 K, presumably associated with local distortions of the crystal lattice. The presence of this temperature is confirmed by our ultrasonic study. A group of intense bands observed in the frequency range of 1700–2200 cm–1 has been associated with the mixed low-lying electronic Raman transitions 4I9/2→4I11/2 and the high-energy luminescence ones 4G5/2+2G7/2→4I9/2 for the Nd3+ ion.Представлено результати раманівських досліджень монокристала бінарного фероборату Nd0,75Dy0,25Fe3(BO3)4 при лазерному збудженні 532 нм (18797 см–1) в діапазоні температур 7–295 K. Аналіз отриманих поляризованих раманівських спектрів виявив смуги, які були віднесені до фононних, магнітних та електронних збуджень. На підставі температурної еволюції смуг встановлено складний зв’язок та взаємодію між гратковими, магнітними й електронними ступенями свободи. Аналіз отриманих спектрів дозволив виявити всі А1 та Е фононні моди, передбачені груповим теоретичним аналізом. Визначено енергії розщеплення між LO і TO компонентами полярних E-фононів. Нижче температури магнітного впорядкування Fe-підгратки, TN, виявлена складна багатопікова смуга, яка віднесена до двомагнонного збудження.Температурна залежність низькочастотних раманівських спектрів виявила моди, пов’язані з електронними переходами між рівнями мультиплетів 4I9/2 основного стану Nd3+ та 6H15/2 основного стану Dy3+, отримані в результаті дії кристалічного поля. Аналіз температурної поведінки низькочастотних фононних та електронних збуджень дозволив встановити аномалію поблизу T * = 100 K, ймовірно, пов’язану з локальними спотвореннями кристалічної гратки. Наявність цієї температури підтверджується ультразвуковими дослідженнями. Група інтенсивних смуг, що спостерігається в раманівському спектрі в діапазоні частот 1700–2200 см–1, пов’язана зі змішаними низько розташованими електронними раманівськими 4I9/2 → 4I11/2 та високоенергетичними люмінесцентними 4G5/2 + 2G7/2→4I9/2 переходами в Nd3+ іоні.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Peschanskii A. V., Fomin V. I., Gudim I. A.
Заглавие : Raman scattering in multiferroic SmFe3(BO3)4
Место публикации : Low Temp. Phys.: American Institute of Physics, 2016. - Vol. 42, Is. 6. - P.475-483. - ISSN 1063-777X, DOI 10.1063/1.4954783. - ISSN 1090-6517(eISSN)
Примечания : Cited References:21
Предметные рубрики: SINGLE-CRYSTALS
MAGNETOELASTIC PROPERTIES
PHASE-TRANSITIONS
FERROBORATE
PHONONS
Аннотация: Raman spectrum of single-crystal SmFe3(BO3)4 was studied in the frequency range from 3 to 1500 cm−1 at temperatures 10–300 K. All the A 1 and E phonon modes predicted by the group theory for a given symmetry of the crystal were observed. The magnitudes of splitting between the LO and TO components of polar E phonons were determined. It was found that under the transition to a magnetically ordered phase, the behavior of the intensity of the line corresponding to the A 1 vibrational mode is anomalous. It was shown that at low temperatures the spectrum of two-magnon excitations has a complex shape and is observed with both nondiagonal and diagonal components of the scattering tensor. This complex shape reflects the features in the density of states of the magnetic branches. An estimate of the magnon energy Em at the Brillouin zone boundary gave ∼47 cm−1. The structure of the ground multiplet 6 H 5/2 of a Sm+3 ion in paramagnetic and antiferromagnetic states as well as the effect of the magnetic phase transition on it were studied. Electron-phonon interaction for the electronic excitation at 225 cm−1 was revealed.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Krylova S. N., Gudim I. A., Kitaev Y., Golovkina E., Zhang H., Vtyurin A. N.
Заглавие : Pressure–temperature phase diagram of multiferroic TbFe2.46Ga0.54(BO3)4
Место публикации : Magnetochemistry. - 2022. - Vol. 8, Is. 6. - Ст.59. - ISSN 23127481 (ISSN), DOI 10.3390/magnetochemistry8060059
Примечания : Cited References: 48. - The research of Krylov A. and Gudim I. was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-42-240009. This work of Vtyurin A., Krylova S. was financially supported by the Russian Foundation for Basic Research and DFG (Deutsche Forschungsgemeinschaft) project number No 21-52-12018. The experiments were performed in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS”
Аннотация: The pressure–temperature phase diagram of the multiferroic TbFe2.46Ga0.54(BO3)4 was studied for hydrostatic pressures up to 7 GPa and simultaneously with temperatures up to 400 K by the Raman spectroscopy technique. The structural phase transition from the R32 phase to the P3121 phase was determined by observing the condensation of soft modes and the appearance of new lines. An increase in pressure leads to an increase in the temperature of the structural phase transition. These phases are stable over the entire investigated temperature and pressure range. No other phases have been found.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Pavlovskiy M. S., Kitaev Y., Gudim I. A., Andryshin N. D., Vtyurin A. N., Jiang, Qinghui, Krylova S. N.
Заглавие : Phase transitions and p–T phase diagram of the multiferroic TbFe3(BO3)4 crystal
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-42-240009]; Russian Foundation for Basic Research and DFG (Deutsche Forschungsgemeinschaft)German Research Foundation (DFG) [448809307, 21-52-12018]
Место публикации : J. Raman Spectrosc. - 2022. - Vol. 53, Is. 6. - P.1179-1187. - ISSN 0377-0486, DOI 10.1002/jrs.6341. - ISSN 1097-4555(eISSN)
Примечания : Cited References: 48. - Russian Foundation for Basic Research; RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, Grant/Award Number: 20-42-240009; Russian Foundation for Basic Research and DFG (Deutsche Forschungsgemeinschaft), Grant/Award Numbers: 448809307, 21-52-12018
Предметные рубрики: BILBAO CRYSTALLOGRAPHIC SERVER
RAMAN-SPECTRA
HIGH-TEMPERATURE
Аннотация: The structural phase transitions in multiferroic TbFe3(BO3)4 with change hydrostatic pressures and temperatures have been studied by Raman spectroscopy and calculation within density functional theory. Lattice dynamics calculations in the TbFe3(BO3)4 crystal in the ��32 phase under various values of applied hydrostatic pressure (from 0 up to 5 GPa with 1 GPa step) were performed. The calculation performed in this work in a TbFe3(BO3)4 crystal showed that the applied pressure can increase the phase transition temperature. Raman spectra of the TbFe3(BO3)4 crystal have been investigated at simultaneously high temperature and high pressure (up to 5.14 GPa and 465 K). The appearance of a soft mode was observed with decreasing temperature at normal pressure. The manifestations of the interaction of the structural and magnetic order parameters in the range from 13 to 50 K were observed at normal pressure. With increasing pressure and a fixed temperature, recovery of the soft modes is also observed. The experimental p–T phase diagram of TbFe3(BO3)4 was established. An increase in pressure leads to an increase in the temperature of transition.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Diab M., Gudim I. A., Popova M. N.
Заглавие : Optical linear dichroism in the ab-plane of NdFe3(BO3)4 ferroborate
Колич.характеристики :6 с
Место публикации : J. Exp. Theor. Phys. - 2023. - Vol. 137, Is. 4: Special Issue dedicated to the 95th Anniversary of L. A. Prozorova. - P.486-491. - ISSN 10637761 (ISSN), DOI 10.1134/S1063776123100011. - ISSN 10906509 (eISSN)
Примечания : Cited References: 16. - This study was supported by the Ministry of Science and Higher Education (project no. FFUU-2022-0003) and partially (K.N. B., dichroism measurements) by the Russian Science Foundation (grant no. 19-72-10132P)
Аннотация: The high-resolution optical absorption spectra of NdFe3(BO3)4 single crystals have been recorded at temperatures from 4 to 40 K in the IR range of f–f transitions in a Nd3+ ion. Light linearly polarized at different angles to the C2 axes in the basal plane has been passed along the trigonal C3 axis. Below the temperature of magnetic moment ordering into a collinear antiferromagnetic structure (TN ≈ 30 K), dichroism, that is, the absorption versus polarization dependence, arises. The temperature and angular dependences of dichroism indicate that the magnetic moments of iron are directed along the C2 axes up to about 17 K, the number of domains with variously directed C2 axes being different. The mechanism of linear dichroism has been discussed. Below 17 K, a smooth transition to the helicoidal magnetic phase has been observed, with the collinear phase coexisting with the helicoidal one. Data presented in this article contradict the earlier concept of magnetic moments fluctuating in the low-temperature phase near the C2 axis within the ±10° interval.
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16.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Gavrichkov V. A., Malakhovskii A. V., Ovchinnikov S. G.
Заглавие : Nd-Fe exchange interaction in Nd ferroborate with multiferroic properties under optical pumping
Коллективы : "Functional materials", International conference, Крымский федеральный университет имени В.И. Вернадского
Место публикации : Ovchinnikov S. G. International conference "Functional materials": book of abstracts/ ed. V. N. Berzhansky ; org. com. S. G. Ovchinnikov [et al.]. - Simferopol, 2021. - P.253-254
Примечания : Библиогр.: 1 назв. - The reported study was supported by the grant RFFI 19-02-00034 and the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, and Krasnoyarsk Regional Fund of Science according to the research project ”Studies of superexchange and ICFM’2021 254 electron-phonon interactions in correlated systems as a basis for searching for promising functional materials No. 20-42-240016
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gudim I. A., Eremin E. V., Temerov V. L.
Заглавие : Melt‒solution synthesis and magnetic properties of SmFe2.8Sc0.2(BO3)4 ferroborate
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [18-42240011_a]; Krasnoyarsk Territory Government Foundation
Место публикации : Crystallogr. Rep. - 2020. - Vol. 65, Is. 2. - P.307-308. - ISSN 1063-7745, DOI 10.1134/S1063774520020108. - ISSN 1562-689X(eISSN)
Примечания : Cited References: 7. - This study was supported by joint grant no. 18-42240011_a of the Russian Foundation for Basic Research and the Krasnoyarsk Territory Government Foundation for scientific-technical support.
Аннотация: Single crystals of SmFe2.8Sc0.2(BO3)(4) ferroborates are grown in melt-solutions based on bismuth trimolybdate. The magnetic properties of grown single crystals are studied. The presence of long-range magnetic order in these crystals is found.
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18.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Zvyagina G., Zhekov K., Zvyagin A., Bilych I., Gudim I. A., Temerov V. L., Volkov N. V.
Заглавие : Magnetoelastic effects in the neodymium ferroborate
Коллективы : Moscow International Symposium on Magnetism
Место публикации : Moscow Int. Symp. on Magnet. (MISM-2011): Book of abstracts. - 2011. - Ст.23PO-K-27. - P.496-497
Примечания : Библиогр.: 3
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zvyagina G. A., Zhekov K. R., Bezmaternykh L. N., Gudim I. A., Bilych I. V., Zvyagin A. A.
Заглавие : Magnetoelastic effects in terbium ferroborate
Место публикации : Low Temp. Phys. - 2008. - Vol. 34, Is. 11. - P.901-908. - ISSN 1063-777X, DOI 10.1063/1.3009584; \b Физика низких температур
Примечания : Cited References: 17
Предметные рубрики: CRYSTAL-STRUCTURE
ND
Ключевые слова (''Своб.индексиров.''): acoustic wave velocity--antiferromagnetic materials--elastic moduli--exchange interactions (electron)--iron compounds--magnetoelastic effects--solid-state phase transformations--terbium compounds
Аннотация: The behavior of the elastic moduli and sound absorption in a terbium orthoborate single crystal at low temperatures is studied. The components of the tensor of the elastic moduli of this system are determined. A structural phase transition and a transition of the magnetic subsystem into an antiferromagnetically ordered state appear in the temperature dependences of the sound velocities and absorption. The magnetic field dependences of the velocities of transverse sound exhibit singularities in the form of jumps at a magnetic field equal to the field of the spin-flop transition of the antiferromagnetic subsystem. Theoretical analysis shows that the observed behavior of the acoustic characteristics are associated not with the rare-earth subsystem of ferroborate but rather with the renormalization of the exchange interaction between iron ions as a result of the magnetoelastic coupling.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Demidov A. A., Volkov D. V., Gudim, I. A., Eremin E. V., Temerov V. L.
Заглавие : Magnetic properties of the rare-earth ferroborate SmFe3(BO3)(4)
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2013. - Vol. 116, Is. 5. - P.800-805. - ISSN 1063-7761, DOI 10.1134/S1063776113050038
Примечания : Cited References: 22. - This work was supported by the Russian Foundation for Basic Research, project no. 12-02-31007mol_a.
Аннотация: The magnetic properties of trigonal antiferromagnet SmFe3(BO3)(4) are studied experimentally and theoretically. The measured characteristics are considered in terms of a theoretical approach based on the molecular field approximation and a crystal field model for a rare-earth ion. The temperature dependences of the initial magnetic susceptibility and the field and temperature dependences of magnetization in fields up to 5 T are described, and the anomaly in the magnetization curve for B aSyen c near 1 T, which points to a first-order phase transition, is analyzed.
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