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Structure and properties of multiferroic ferroborates of mixed composition SmFe3-xAlx(BO3)4 and Eu1-yLayFe3(BO3)4 / K. V. Frolov, E. S. Smirnova, E. V. Sidorova [et al.] // Book of abstacts of Samarkand International Symposium on Magnetism (SISM-2023) / int. adv. com. S. G. Ovchinnikov [et al.]. - 2023. - Ст. 3PO-L8-3. - P. 195. - Cited References: 6. - РНФ 23-22-00286 . - ISBN 978-5-00202-320-2

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Держатели документа:
Kirensky Institute of Physics SB RAS

Доп.точки доступа:
Ovchinnikov, S. G. \int. adv. com.\; Овчинников, Сергей Геннадьевич; Frolov, K. V.; Smirnova, E. S.; Sidorova, E. V.; Alekseeva, O. A.; Sorokin, T. A.; Artemov, V. V.; Chmelenin, D. N.; Gudim, I. A.; Гудим, Ирина Анатольевна; Samarkand International Symposium on Magnetism(2023 ; July 2-6 ; Samarkand); Samarkand State University
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Phase diagram and soft modes behavior TbFe3–xGax(BO3)4 solid solutions with huntite structure / A. S. Krylov, A. N. Vtyurin, I. A. Gudim [et al.] // Opt. Spectrosc. - 2023. - Vol. 131, Is. 9. - P. 840-848, DOI 10.1134/S0030400X23070081. - Cited References: 40. - The authors are grateful to the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory and the Krasnoyarsk Regional Science Foundation for funding within the framework of the scientific project, grant no. 20-42-240009 r_a_Krasnoyarsk, as well as the Russian Foundation for Basic Research and the German Scientific Research Community (Deutsche Forschungsgemeinschaft) for financial support within the project no. 21-52-12018 NNIO_a . - ISSN 0030-400X. - ISSN 1562-6911
Кл.слова (ненормированные):
Raman spectroscopy -- temperature dependence -- soft modes -- ferroborates -- phase diagramm
Аннотация: The Raman spectra of four crystals of TbFe3–xGax(BO3)4 solid solutions (x from 0 to 0.54) were studied in the temperature range from 8 to 350 K. The temperatures of structural phase transitions were determined. The observed spectral behavior is characteristic to condensation and restoration of soft modes. Soft modes are associated with a structural phase transition from the R32 phase to the P3121 phase. The Compositions-Temperature phase diagram was constructed.

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Публикация на русском языке Фазовая диаграмма и особенности поведения мягких мод в твердых растворах со структурой хантита TbFe3-xGax(BO3)4 [Текст] / А. С. Крылов, А. Н. Втюрин, И. А. Гудим [и др.] // Опт. и спектроскоп. - 2022. - Т. 130 Вып. 1. - С. 84-91

Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia
Siberian Federal University, 660041, Krasnoyarsk, Russia
Federal Research Center KSC SB, Russian Academy of Sciences, “Krasnoyarsk Scientific Center of the Siberian Branch of RAS”, 660036, Krasnoyarsk, Russia

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Nemtsev, I. V.; Немцев, Иван Васильевич; Krylova, S. N.; Крылова, Светлана Николаевна
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Comparison of magnetic properties of GdFe3(BO3)4, ferroborates grown using various solvents / I. A. Gudim, E. V. Eremin, N. V. Mikhashenok, V. R. Titova // Phys. Solid State. - 2023. - Vol. 65, Is. 2. - P. 235-239, DOI 10.21883/PSS.2023.02.55406.505. - Cited References: 18. - This study was supported by grant No. 22-12-20019 provided by the Russian Science Foundation and the Krasnoyarsk Regional Science Foundation (https://rscf.ru/project/22-72-00017/) . - ISSN 1063-7834. - ISSN 1090-6460
Кл.слова (ненормированные):
crystal growth -- antiferromagnets -- multferroics
Аннотация: GdFe3(BO3)4, single crystals were grown from melt-solutions based on bismuth trimolybdate and lithium tungstate. Single crystals of gadolinium ferroborate from lithium-tungstate solution-melt were grown for the first time. The magnetic properties of the grown crystals are compared. It is shown that the GdFe3(BO3)4, ferroborate obtained using bismuth solution-melt trimolybdate contains impurities of Bi3+ ions (6% at.), which replace Gd3+ ions. Whereas GdFe3(BO3)4, ferroborate grown from a solution-melt based on lithium tungstate does not seem to contain such uncontrolled impurities.

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Публикация на русском языке Сравнение магнитных свойств ферроборатов GdFe3(BO3)4, выращенных с использованием различных растворителей [Текст] / И. А. Гудим, Е. В. Еремин, Н. В. Михашенок, В. Р. Титова // Физ. тверд. тела. - 2023. - Т. 65 Вып. 2. - С. 243-247

Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia

Доп.точки доступа:
Gudim, I. A.; Гудим, Ирина Анатольевна; Eremin, E. V.; Еремин, Евгений Владимирович; Mikhashenok, N. V.; Михашенок, Наталья Владимировна; Titova, V. R.; Титова, Вероника Романовна
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    Krylov, A. S.
    Phase transitions in multiferroics ferroborates with huntite structure / A. S. Krylov // Materials Science and Nanotechnology (MSN-2023) : abstract book of International conference / Ural Federal University; org. com. A. N. Vtyurin et al. - Ekaterinburg, 2023. - Ст. 114. - P. 25. - Cited References: 3. - RFBR funded the reported study according to the research project № 21-52-12018 . - ISBN 978-5-9500624-6-9
   Перевод заглавия: Фазовые переходы в мультиферроиках ферроборатов со структурой хантита

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Держатели документа:
Kirensky Institute of Physics SB RAS

Доп.точки доступа:
Vtyurin, A. N. \org. com.\; Втюрин, Александр Николаевич; Крылов, Александр Сергеевич; Уральский Федеральный университет им. Первого Президента России Б.Н. Ельцина; Ural Federal University; "Materials science and nanotechnology", International conference(2023 ; Aug. 27-30 ; Ekaterinburg)
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Phase diagram and soft modes behavior TbFe3–xGax(BO3)4 solid solutions with huntite structure / A. S. Krylov, A. N. Vtyurin, I. A. Gudim [et al.] // Opt. Spectrosc. - 2022. - Vol. 130, Is. 1. - P. 78-85, DOI 10.21883/EOS.2022.01.52990.38-21. - Cited References: 40. - The authors are grateful to the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory and the Krasnoyarsk Regional Science Foundation for funding within the framework of the scientific project, grant № 20-42-240009 r a Krasnoyarsk, as well as the Russian Foundation for Basic Research and the German Scientific Research Community (Deutsche Forschungsgemeinschaft) for financial support within the project № 21-52-12018 NNIO_a . - ISSN 0030-400X. - ISSN 1562-6911
Кл.слова (ненормированные):
Raman spectroscopy -- temperature dependence -- soft modes -- ferroborates -- phase diagramm
Аннотация: The Raman spectra of four crystals of TbFe3–xGax(BO3)4 solid solutions (x from 0 to 0.54) were studied in the temperature range from 8 to 350 K. The temperatures of structural phase transitions were determined. The observed spectral behavior is characteristic to condensation and restoration of soft modes. Soft modes are associated with a structural phase transition from the R32 phase to the P3121 phase. The Compositions-Temperature phase diagram was constructed.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB, Russian Academy of Sciences, Krasnoyarsk, Russia
Siberian State University of Science and Technology, Krasnoyarsk, Russia
Krasnoyarsk Scientific Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, Russia

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Nemtsev, I. V.; Немцев, Иван Васильевич; Krylova, S. N.; Крылова, Светлана Николаевна
}
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Comparison of the absorption spectra of Nd3+ ions in the NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and Ho0.75Nd0.25Fe3(BO3)4 crystals / A. L. Sukhachev, A. V. Malakhovskii, C. S. Nelson [et al.] // Phys. Solid State. - 2021. - Vol. 63, Is. 1. - P. 113-121, DOI 10.1134/S1063783421010200. - Cited References: 21. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: number 19-42-240003 “Influence of the local en-vironment on magneto-optical properties of f–f transitions in rare-earth aluminum and iron borates” . - ISSN 1063-7834
Кл.слова (ненормированные):
neodymium -- hantite-structure ferroborates -- f–f electronic transitions -- structural transition
Аннотация: The polarized optical absorption spectra in the region of a series of the f–f transitions of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and NdFe3(BO3)4 crystals at 90 K have been compared. The spectral features related to the difference in the local environment of Nd3+ ions in these crystals have been established. In the region of the transition 4I9/2 → 4G5/2 + 2G7/2 of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4 crystal, the appearance of some absorption lines at the structural transition R32 → P3121 around ~200 K due to the local symmetry variation has been found. The intensity of these lines smoothly increases with a decrease in temperature from the transition point. The temperature dependence of the lattice parameters of the Ho0.75Nd0.25Fe3(BO3)4 crystal has been measured. It has been found that, at the transition temperature, the lattice parameter a changes stepwise, which is indicative of the occurrence of a first-order phase transition. The lattice parameter c changes smoothly.

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Публикация на русском языке Сравнение спектров поглощения ионов Nd3+ в кристаллах NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4 и Ho0.75Nd0.25Fe3(BO3)4 [Текст] / А. Л. Сухачев, А. В. Малаховский, C. S. Nelson [и др.] // Физ. тверд. тела. - 2021. - Т. 63 Вып. 1. - С. 111-119

Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
National Synchrotron Light Source II, Brookhaven National Laboratory, Upton, NY 11973, United States

Доп.точки доступа:
Sukhachev, A. L.; Сухачев, Александр Леонидович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Nelson, C. S.; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович
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    Raman scattering study of the rare-earth binary ferroborate Nd0.75Dy0.25Fe3(BO3)4 single crystal / A. Yu. Glamazda, V. P. Gnezdilov, P. Lemmens [et al.] // Физ. низких температур. - 2021. - Т. 47, Вып. 12. - С. 1107-1118 ; Fiz. Nizk. Temp. - Cited References: 26. - A. Yu. Glamazda thanks to Dr. A. V. Peschanskii for fruitful discussions. P. Lemmens acknowledges funding by the DFG Excellence Cluster Quantum Frontiers, EXC 2123-390837967, DFG Le967/16-1, and DFG-RTG 1952/1 . - ISSN 0132-6414
   Перевод заглавия: Раманівська спектроскопія монокристала рідкісноземельного бінарного фероборату Nd0,75Dy0,25Fe3(BO3)4
Кл.слова (ненормированные):
ferroborates -- Raman spectroscopy -- luminescence -- фероборати -- раманівськa спектроскопія -- люмінесценція
Аннотация: We report comprehensive Raman scattering measurements on a single crystal of binary ferroborate Nd0.75Dy0.25Fe3(BO3)4 in the temperature range of 7–295 K with 532 nm (18797 cm–1) laser excitation. The performed analysis of the polarized Raman spectra revealed the bands assigned to phonon, magnetic, and electronic excitations. The temperature evolution of these quasiparticle excitations has allowed us to ascertain the intricate coupling and interplay between lattice, magnetic, and electronic degrees of freedom. Analysis of the measured Raman spectra made it possible to identify all A1 and Е phonon modes of predicted by the group-theoretical analysis. The splitting energies between the LO and TO components of the polar E phonons were determined. Below the magnetic ordering temperature of the Fe sublattice, TN, we have revealed a multiple peaked two-magnon excitation. Analyzing the temperature evolution of low-frequency modes in the spectra, we also identi-fied modes that are associated with electronic transitions between the crystal field levels of the Nd3+ ions with ground-state 4I9/2 and of the Dy3+ ions with ground-state 6H15/2 multiplets. In addition to the already known temperatures of magnetic transitions, analysis of the temperature behavior of low-frequency phonon and electronic excitations made it possible to establish a temperature T * = 100 K, presumably associated with local distortions of the crystal lattice. The presence of this temperature is confirmed by our ultrasonic study. A group of intense bands observed in the frequency range of 1700–2200 cm–1 has been associated with the mixed low-lying electronic Raman transitions 4I9/2→4I11/2 and the high-energy luminescence ones 4G5/2+2G7/2→4I9/2 for the Nd3+ ion.
Представлено результати раманівських досліджень монокристала бінарного фероборату Nd0,75Dy0,25Fe3(BO3)4 при лазерному збудженні 532 нм (18797 см–1) в діапазоні температур 7–295 K. Аналіз отриманих поляризованих раманівських спектрів виявив смуги, які були віднесені до фононних, магнітних та електронних збуджень. На підставі температурної еволюції смуг встановлено складний зв’язок та взаємодію між гратковими, магнітними й електронними ступенями свободи. Аналіз отриманих спектрів дозволив виявити всі А1 та Е фононні моди, передбачені груповим теоретичним аналізом. Визначено енергії розщеплення між LO і TO компонентами полярних E-фононів. Нижче температури магнітного впорядкування Fe-підгратки, TN, виявлена складна багатопікова смуга, яка віднесена до двомагнонного збудження.Температурна залежність низькочастотних раманівських спектрів виявила моди, пов’язані з електронними переходами між рівнями мультиплетів 4I9/2 основного стану Nd3+ та 6H15/2 основного стану Dy3+, отримані в результаті дії кристалічного поля. Аналіз температурної поведінки низькочастотних фононних та електронних збуджень дозволив встановити аномалію поблизу T * = 100 K, ймовірно, пов’язану з локальними спотвореннями кристалічної гратки. Наявність цієї температури підтверджується ультразвуковими дослідженнями. Група інтенсивних смуг, що спостерігається в раманівському спектрі в діапазоні частот 1700–2200 см–1, пов’язана зі змішаними низько розташованими електронними раманівськими 4I9/2 → 4I11/2 та високоенергетичними люмінесцентними 4G5/2 + 2G7/2→4I9/2 переходами в Nd3+ іоні.

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Переводная версия Raman scattering study of the rare-earth binary ferroborate Nd0.75Dy0.25Fe3(BO3)4 single crystal [Текст] / A. Y. Glamazda, V. P. Gnezdilov, P. Lemmens [et al.] // Low Temp. Phys. - 2021. - Vol. 47 Is. 12.- P.1011-1021

Держатели документа:
B. Verkin Institute for Low Temperature Physics and Engineering, National Academy of Sciences of Ukraine, Kharkiv, 61103, Ukraine
V. N. Karazin Kharkiv National University, Kharkiv, 61022, Ukraine
Institute for Condensed Matter Physics, TU-Braunschweig, Braunschweig, 38106, Germany
Laboratory for Emerging Nanometrology, International Graduate School of Metrology, TU-Braunschweig, Braunschweig, 38106, Germany
L. V. Kirenskii Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Glamazda, A. Yu.; Gnezdilov, V. P.; Lemmens, P.; Zvyagina, G. A.; Gudim, I. A.; Гудим, Ирина Анатольевна

}
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Malakhovskii, A. V.
Magnetic circular dichroism and absorption spectra of f–f transitions 5I8 → 5F2 and 5F3 in the HoFe3(BO3)4 single crystal / A. V. Malakhovskii, V. V. Sokolov, I. A. Gudim // Low Temp. Phys. - 2020. - Vol. 46, Is. 7. - P. 734-739, DOI 10.1063/10.0001371. - Cited References: 16. - The study was supported by the Russian Foundation for Basic Research, grant No. 19-02-00034, and also by the Krasnoyarsk Krai Russian Foundation for Basic Research and the Krasnoyarsk Krai Regional Fund of Science as part of project No. 19-42-240003 on "The influence of the local environment on the magneto-optical properties of f-f transitions in rare-earth aluminoborates and ferroborates" . - ISSN 1063-777X. - ISSN 1090-6517

РУБ Physics, Applied
Рубрики:
MAGNETOOPTICAL ACTIVITY
ELECTRON-STRUCTURE
ERFE3(BO3)4
Кл.слова (ненормированные):
magnetic circular dichroism -- f-ftransitions -- rare earth ferroborates
Аннотация: Magnetic circular dichroism (MCD) and absorption spectra of multiferroic HoFe3(BO3)4 of 5I8 → 5F2 and 5F3 f–f transitions are measured at T = 90 K. The absorption spectra are expanded into Lorentzian components, and the transition intensities are obtained. The Zeeman splitting of some transitions is determined using the MCD and absorption spectra. The MCD spectra and Zeeman splitting are theoretically analyzed in the free-atom |J, ±MJ〉wave function approximation by using the concept of a crystalline quantum number. An inconsistency is revealed when this concept is applied to ions with an integer moment, and a modification of the concept is proposed. Anomalously intense vibronic repetitions of electronic transitions from excited sublevels of the ground multiplet are found.

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Публикация на русском языке Малаховский, Александр Валентинович. Магнитный круговой дихроизм и поглощение кристалла HoFe3(BO3)4 в области f–f переходов 5I8 → 5F2 и 5F3 [Текст] / А. В. Малаховский, В. В. Соколов, И. А. Гудим // Физ. низких температур. - 2020. - Т. 46 № 7. - С. 869-876

Держатели документа:
Russian Acad Sci, Siberian Branch, Fed Res Ctr Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Малаховский, Александр Валентинович; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-02-00034]; Krasnoyarsk Krai Russian Foundation for Basic Research; Krasnoyarsk Krai Regional Fund of Science [19-42-240003]
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Paramagnetic magneto-optical activity of f-f transitions in HoFe3(BO3)4 and HoAl3(BO3)4 single crystals / V. V. Sokolov [et al.] // Opt Mater. - 2019. - Vol. 94. - P. 35-40, DOI 10.1016/j.optmat.2019.05.024. - Cited References: 38. - The work was supported by the Russian Foundation for Basic Researches grant 19-02-00034. . - ISSN 0925-3467
Кл.слова (ненормированные):
Magnetic circular dichroism -- f-f transitions -- Rare earth ferroborates -- Rare earth alumoborates
Аннотация: Absorption and magnetic circular dichroism (MCD) spectra of HoFe3(BO3)4 and HoAl3(BO3)4 single crystals were measured as a function of temperature in the range of 90–293 K. Based on integrals of f-f absorption and МСD bands, temperature dependences of the paramagnetic magneto-optical activity (MOA) of f-f transitions were obtained for the first time. It was revealed that MOA of the same f-f transitions in the studied crystals were substantially different and their temperature dependences did not follow the Curie-Weiss law in contrast to the properties of allowed transitions. The observed phenomena were accounted for as a consequence of the nature of f-f transitions allowance. In temperature dependences of the MOA of two transitions the singularities were revealed, which indicated to some local structural distortions in the corresponding excited states.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна
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10.

    Temperature-dependent absorption lines observation in Raman spectra of SmFe3 (BO3)4 ferroborate / E. Moshkina [et al.] // J. Raman Spectrosc. - 2018. - Vol. 49, Is. 10. - P. 1732-1735, DOI 10.1002/jrs.5430. - Cited References: 12. - RFBR, Grant/Award Numbers: 18-02-00696 and 18-02-00754 . - ISSN 0377-0486. - ISSN 1097-4555
   Перевод заглавия: Температурно зависимые линии поглощения в спектрах комбинационного рассеяния ферробората SmFe3(BO3)4

РУБ Spectroscopy
Рубрики:
SmFe3 (BO3)4
Ho1-xNdxFe3(BO3)4
CRYSTALS
Кл.слова (ненормированные):
absorption -- ferroborates -- huntite -- level splitting -- magnetic phase -- transitions
Аннотация: The paper demonstrates possibilities of observation and thermal dependency study of the absorption lines as a co‐product of Raman spectroscopy study in SmFe3 (BO3)4 ferroborate. Raman spectra of the ferroborate were studied in a wide temperature range (T = 10÷300 K). Temperature‐dependent absorption lines sensitive to the magnetic phase transition have been observed in Raman spectra at two spectral ranges.

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Держатели документа:
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian State Univ Sci & Technol, Krasnoyarsk, Russia.

Доп.точки доступа:
Moshkina, E. M.; Мошкина, Евгения Михайловна; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович; Krylov, A. S.; Крылов, Александр Сергеевич; RFBR [18-02-00696, 18-02-00754]
}
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11.

Spectroscopic properties of HoFe3(BO3)4, NdFe3(BO3)4 and Ho0.75Nd0.25Fe3(BO3)4 single crystals / A. L. Sukhachev [et al.] // Opt. Mater. - 2018. - Vol. 83. - P. 87-92, DOI 10.1016/j.optmat.2018.05.078. - Cited References: 39. - A.L. Sukhachev thanks for support Project of Russian Academy of Science No. 0356-2017-0030. A.V. Malakhovskii thanks Russian Foundation for Basic Researches (RFBR) Grant No. 16-02-00273. A.S. Aleksandrovsky thanks RFBR Grant No. 17-52-53031. I.A. Gudim and V.L. Temerov thank RFBR Grant No. 17-52-45091. . - ISSN 0925-3467
Кл.слова (ненормированные):
Holmium and neodymium ferroborates -- Judd–Ofelt parameters
Аннотация: Polarized absorption spectra of ferroborates HoFe3(BO3)4, NdFe3(BO3)4 and Ho0.75Nd0.25Fe3(BO3)4 were measured at room temperature in spectral range 4000–24500 cm−1 (400–2500 nm). The studied single crystals were grown from solution-melts. Intensities of the f-f transitions were measured and the Judd–Ofelt parameters Ωλ of Ho3+ and Nd3+ ions in the studied crystals were calculated. It was revealed that the crystals content not strongly influences the Judd–Ofelt parameters. The Ω2 parameter for Ho3+ ion is the most sensitive to the crystal content. Linear dichroism of the hypersensitive transitions appeared to be the largest one for both rare earth ions.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Sukhachev, A. L.; Сухачев, Александр Леонидович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович
}
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12.

Gudim, I. A.
Growth of single crystals of trigonal ferroborates (Ho1-xNdx) Fe3 (BO3)4 with the khantite structure depending on the crystallochemical growth conditions / I. A. Gudim, V. R. Titova // Sixth European Conference on Crystals Growth (ECCG-6). - 2018. - Ст. S02P. - Библиогр.: 2

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Материалы конференции

Доп.точки доступа:
Titova, Veronika; Гудим, Ирина Анатольевна; European Conference on Crystals Growth(6 ; 2018 ; Sept ; 15-20 ; Varna, Bulgaria); Bulgarian Academy of SciencesEuropean Network of Crystal Growth
}
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13.

Local properties of rare earth ferroborates in the optically excited states / A. V. Malakhovskii [et al.] // XVII International Feofilov Symposium on spectroscopy of crystals doped with rare earth and transition metal ions (IFS'XVII) : book of abstracts. - 2018. - P. 209-210

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Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Gnatchenko, S. L.; Kachur, I. S.; Piryatinskaya, V. G.; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович; International Feofilov Symposium on spectroscopy of crystals doped with rare earth and transition metal ions(17 ; 2018 ; Sept. ; 23-28 ; Ekaterinburg, Russia)
}
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14.

Malakhovskii, A. V.
Influence of the low local symmetry of Er3+ ions on magnetic circular dichroism and absorption spectra of f-f transitions in ErFe3(BO3)4 single crystal / A. V. Malakhovskii, V. V. Sokolov, I. A. Gudim // J. Magn. Magn. Mater. - 2018. - Vol. 465. - P. 700-708, DOI 10.1016/j.jmmm.2018.06.057. - Cited References: 29. - The work was supported by the Russian Foundation for Basic Researches grant 16-02-00273 and by the Project of Russian Academy of Science No. 0356-2017-0030. . - ISSN 0304-8853
Кл.слова (ненормированные):
Er3+ ion -- f-f transitions -- Magnetic circular dichroism -- Rare earth ferroborates
Аннотация: Linearly polarized absorption spectra and magnetic circular dichroism (MCD) spectra of ErFe3(BO3)4 single crystal were measured in the range of 9000–23000 cm−1 at 90 K. The absorption spectra of f-f transitions were decomposed into the Lorentz shape components and intensities of the components were found. MCD spectra permitted us to measure the Zeeman splitting of some transitions and so to determine changes of the Landé factor along the C3 axis of the crystal during these transitions. Optical and magneto-optical properties of f-f transitions in the ErFe3(BO3)4 crystal were compared with those in the ErAl3(BO3)4 crystal. Substantial difference of the properties connected with the difference of the Er3+ ions local symmetry in two crystals was revealed. Large splitting of one of the f-f transitions without magnetic field, which is not possible for the Kramers doublets, was observed. It was explained by appearance of two absorbing centers due to the local decrease of symmetry in the excited state. Appreciable difference of the local vibrations energy in some excited states was revealed.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Малаховский, Александр Валентинович
}
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15.

Gudim, I. A.
Growth of single crystals of trigonal ferroborates (Ho1- xNdx)Fe3(BO3)4 with the huntite structure depending on the crystallochemical growth conditions / I. A. Gudim, V. R. Titova // Магнитные материалы. Новые технологии : тез. докл. VIII Байкал. междунар. конф. BICMM-2018 / чл. прогр. ком. R. S. Iskhakov [et al.]. - Иркутск, 2018. - P. 189. - Библиогр.: 2 . - ISBN 978-5-00133-051-6

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Материалы конференции,
Материалы конференции,
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Доп.точки доступа:
Iskhakov, R. S. \чл. прогр. ком.\; Исхаков, Рауф Садыкович; Ovchinnikov, S. G. \чл. прогр. ком.\; Овчинников, Сергей Геннадьевич; Aplesnin, S. S. \чл. прогр. ком.\; Аплеснин, Сергей Степанович; Balaev, D. A. \чл. прогр. ком.\; Балаев, Дмитрий Александрович; Titova, Veronika; Гудим, Ирина Анатольевна; Байкальская международная конференция "Магнитные материалы. Новые технологии"(8 ; 2018 ; авг. ; 24-28 ; Иркутск); "Магнитные материалы. Новые технологии", Байкальская международная конференция(8 ; 2018 ; авг. ; 24-28 ; Иркутск); "Magnetic materials. New tecnologies", Baikal International Conference(8 ; 2018 ; Aug. 24-28 ; Irkutsk); Иркутский государственный университет
}
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16.

    Raman study of HoFe3(BO3)4 at simultaneously high pressure and high temperature: p–T phase diagram / A. S. Krylov [et al.] // J. Raman Spectrosc. - 2017. - Vol. 48, Is. 11. - P. 1406-1410, DOI 10.1002/jrs.5078. - Cited References:35. - Authors are grateful to Prof. A.N. Vtyurin for his valuable discussion. This work was supported by the Russian Foundation for Basic Research (grant no. 17-02-00694) . - ISSN 0377-0486. - ISSN 1097-4555
   Перевод заглавия: Исследование методом комбинационного рассеяния света HoFe3(BO3)4 при одновременном высоком давлении и высокой температуре: фазовая диаграмма p-T

РУБ Spectroscopy
Рубрики:
HYDRATE FORMATION
   SINGLE-CRYSTALS
   WATER SYSTEM
   TRANSITIONS
Кл.слова (ненормированные):
phase transitions -- high hydrostatic pressure -- ferroborates -- p-T phase -- diagram -- nanocrystal
Аннотация: Raman spectra of a HoFe3(BO3)4 crystal chip has been investigated at simultaneously high temperature and high pressure (up to 7.1 GPa and 560 K). On the basis of Raman analysis, the assignment to one of the two possible crystal phases has been made. The experimental p–T phase diagram of HoFe3(BO3)4 was established. An increase in the pressure leads to an increase in the temperature of transition. The phase boundary equation was obtained. Neither triple points nor a phase with new symmetry was revealed in the phase diagram. A critical point with the temperature T = 560 K and the pressure p = 2.53 GPa was found. The nanocrystals with different shapes began to grow on crystal surface after reaching that point. The composition of new nanocrystals is identical to the composition of initial crystal.

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Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Gudim, I. A.; Гудим, Ирина Анатольевна; Nemtsev, I. V.; Немцев, Иван Васильевич; Krylova, S. N.; Крылова, Светлана Николаевна; Shabanov, A. V.; Шабанов, Александр Васильевич; Krylov, A. A.; International GeoRAMAN Conference(12th ; June 9-15, 2016 ; Novosibirsk, Russia)
}
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17.

    Low-temperature features of Raman spectra below magnetic transitions in multiferroic Ho1–xNdxFe3(BO3)4 and Sm1–yLayFe3(BO3)4 single crystals / A. Krylov [et al.] // Ferroelectrics. - 2017. - Vol. 509, Is. 1. - P. 92-96, DOI 10.1080/00150193.2017.1294040. - Cited References: 12 . - ISSN 0015-0193
   Перевод заглавия: Низкотемпературные особенности спектров комбинационного рассеяния ниже магнитных переходов в монокристаллах мультиферроиков Ho1-xNdxFe3 (BO3) 4 и Sm1-yLayFe3 (BO3)4
Кл.слова (ненормированные):
Raman spectra -- magnetic ordering -- huntite -- rare-earth ferroborates
Аннотация: Raman spectra changes in multiferroic Ho1–xNdxFe3(BO3)4 (x = 0, 0.25, 0.5, 0.75) and Sm1–yLayFe3(BO3)4 (y = 0, 0.75) single crystals at low temperatures have been analyzed. The anomalies corresponding to the phase transition of the second order have been detected at the temperatures of magnetic phase transitions, being consistent with previously reported results of the magnetization study. A number of anomalies in the temperature dependences of the spectral lines associated with the occurrence of magnetic order. A mode corresponding to two-magnon scattering was revealed. Comparison of the features of low-temperature low-frequency spectra of solid solutions Ho-Nd and Sm-La has been carried out.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Moshkina, E. M.; Мошкина, Евгения Михайловна; Sofronova, S. N.; Софронова, Светлана Николаевна; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович; Vtyurin, A. N.; Втюрин, Александр Николаевич
}
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18.

Magnetopiezoelectric effects in easy plane ferroborates / I. V. Bilych [et al.] // Moscow International Symposium on Magnetism (MISM-2017) : 1-7 July 2017 : book of abstracts. - 2017. - Ст. 4PO-J-46. - P. 925

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Доп.точки доступа:
Bilych, I. V.; Zhekov, K. R.; Gaydamak, T. N.; Burma, N. G.; Kolodyazhnaya, M. P.; Zvyagina, G. A.; Fil', V. D.; Gudim, I. A.; Гудим, Ирина Анатольевна; Moscow International Symposium on Magnetism(7 ; 2017 ; Jul. ; Moscow); Московский государственный университет им. М.В. Ломоносова; Российский фонд фундаментальных исследований
Нет сведений об экземплярах (Источник в БД не найден)
}
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19.

Transformation from an easy-plane to an easy-axis antiferromagnetic structure in the mixed rare-earth ferroborates PrxY1-xFe3(BO3)4: Magnetic properties and crystal field calculations / A. I. Pankrats [et al.] // J. Phys.: Condens. Matter. - 2016. - Vol. 28, Is. 39. - Ст. 396001, DOI 10.1088/0953-8984/28/39/396001. - Cited References: 27. - This work was supported by the Russian Foundation for Basic Research (project no. 15-42-04186_r_sibir'_a). . - ISSN 0953-8984

РУБ Physics, Condensed Matter

Кл.слова (ненормированные):
magnetic phase transitions -- rare-earth ferroborates RFe3(BO3)4 -- antiferromagnetic resonance
Аннотация: The magnetic structure of the mixed rare-earth system PrxY1-xFe3(BO3)4 (x = 0.75, 0.67, 0.55, 0.45, 0.25) was studied via magnetic and resonance measurements. These data evidence the successive spin reorientation from the easy-axis antiferromagnetic structure formed in PrFe3(BO3)4 to the easy-plane one of YFe3(BO3)4 associated with the weakening of the magnetic anisotropy of the Pr subsystem due to its diamagnetic dilution by nonmagnetic Y. This reorientation occurs through the formation of an inclined magnetic structure, as was confirmed by our previous neutron research in the range of x = 0.67 ? 0.45. In the compounds with x = 0.75 and 0.67 whose magnetic structure is close to the easy-axis one, a two-step spin reorientation takes place in the magnetic field H||c. Such a peculiarity is explained by the formation of an interjacent inclined magnetic structure with magnetic moments of Fe ions located closer to the basal plane than in the initial state, with these intermediate states remaining stable in some ranges of the magnetic field. An approach based on a crystal field model for the Pr3+ ion and the molecular-field approximation is used to describe the magnetic characteristics of the system PrxY1-xFe3(BO3)4. With the parameters of the d-d and f-d exchange interactions, of the magnetic anisotropy of the iron subsystem and of the crystal field parameters of praseodymium thus determined, it is possible to achieve a good agreement between the experimental and calculated temperature and field dependences of the magnetization curves (up to 90 kOe) and magnetic susceptibilities (2-300 K). © 2016 IOP Publishing Ltd.

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Держатели документа:
Kirensky Institute of Physics, Siberian Branch of RAS, Krasnoyarsk, Russian Federation
Bryansk State Technical University, Bryansk, Russian Federation
Institut Laue-Langevin, BP 156, Grenoble, France

Доп.точки доступа:
Pankrats, A. I.; Панкрац, Анатолий Иванович; Demidov, A. A.; Ritter, C.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Semenov, S. V.; Семёнов, Сергей Васильевич; Tugarinov, V. I.; Тугаринов, Василий Иванович; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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20.

    Crystal growth and Raman spectroscopy study of Sm1-xLaxFe3(BO3)4 ferroborates / E. Moshkina [et al.] // Cryst. Growth Des. - 2016. - Vol. 16, Is. 12. - P. 6915-6921, DOI 10.1021/acs.cgd.6b01079. - Cited References: 17. - This work was supported by the Russian Foundation for Basic Research, Project No. 14-02-00307. . - ISSN 1528-7483
   Перевод заглавия: Рост кристаллов и исследование ферроборатов Sm1-xLaxFe3(BO3)4 методом спектроскопии комбинационного рассеяния света
Кл.слова (ненормированные):
Crystal lattices -- Iron compounds -- Raman spectroscopy -- Single crystals -- Crystal nucleation -- Flux methods -- Internal structure -- Magnetic phase transitions -- Magnon scattering -- Spectral region -- Temperature range -- Wave numbers -- Lanthanum
Аннотация: Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals were synthesized using the flux method. The crystal nucleation procedure and flux parameters are reported. Conditions for growing the Sm1-xLaxFe3(BO3)4 (x = 0, 0.75) single crystals are described. The prepared crystals were studied by Raman spectroscopy in the temperature range of T = 10-300 K. The spectral region corresponding to temperatures of T = 10-55 K, which involves the temperatures of the magnetic phase transition TN = 32 K for x = 0 and TN = 31 K for x = 0.75, was thoroughly analyzed. Anomalies related to the magnetic ordering established in both compounds were found. The main changes occur in the low-wavenumber region (up to 100 cm-1), where the mode corresponding to magnon scattering arises. This mode is shown to have the internal structure indicative of the occurrence of unstable vibrations (40-80 cm-1). The results obtained are analyzed by calculating the empirical lattice dynamics in Sm1-xLaxFe3(BO3)4 with x = 0 and x = 1. © 2016 American Chemical Society.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Moshkina, E. M.; Мошкина, Евгения Михайловна; Krylov, A. S.; Крылов, Александр Сергеевич; Sofronova, S. N.; Софронова, Светлана Николаевна; Gudim, I. A.; Гудим, Ирина Анатольевна; Temerov, V. L.; Темеров, Владислав Леонидович
}
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