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1.


   
    Vibrational spectroscopy study of phase transition in K3WO3F3: temperature and high pressure investigations [Text] / Ekimov A.A.Krylov A.S. [et al.] // Advanced inorganic fluorides : the Third International Siberian workshop Intersibfluorine - 2008, September 01-06, 2008, Vladivostok, Russia : proceedings of ISIF-2008. - Vladivostok, 2008. - p. 188 . - ISBN 978-5-98128-036-8


Доп.точки доступа:
Ekimov, A. A.; Krylov, A. S.; Крылов, Александр, Сергеевич; Vtyurin, A. N.; Ivanenko, A. A.; Иваненко, Александр, Анатольевич; Shestakov, N. P.; Шестаков, Николай, Петрович; Goryainov, S. V.; Kocharova, A. G.; Кочарова, Алла, Георгиевна; "Advanced inorganic fluorides", International Siberian workshop(3 ; 2008 ; SEP. ; Vladivostok)
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2.


   
    Unusual sequence of phase transitions in (NH4)3TiF7 detected by optic and calorimetric studies / S. V. Mel'nikova [et al.] // J. Fluor. Chem. - 2014. - Vol. 165. - P. 14-19, DOI 10.1016/j.jfluchem.2014.05.016. - Cited References: 13. - This work was supported by Russian Foundation for Basic Research (Grant no. 12-02-00056), and the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools of the Russian Federation (Grant no. NSh-924.2014.2). . - ISSN 0022-1139. - ISSN 1873-3328
РУБ Chemistry, Inorganic & Nuclear + Chemistry, Organic
Рубрики:
CRYSTAL-STRUCTURE
   DIFFRACTION

   NH4F

Кл.слова (ненормированные):
Cubic fluorides -- Phase transitions -- Crystal-optic -- Calorimetry
Аннотация: For the first time structural transformations were observed for one of the compounds belonging to the family of double salt fluorides A3MeF7 = A2MeF6·AF. Single crystals of (NH4)3TiF7 = (NH4)2TiF6·NH4F were grown by evaporation of the aqueous solution. Polarizing optical observations, heat capacity and birefringence Δn = (no − ne) measurements were performed in a wide temperature range 100–400 K. Two reversible, first order structural phase transitions were found to be followed by an unusual sequence of symmetry changes: cubic (G3) (T2↓ = 287.5 K; T2↑ = 291–310 K) ↔ P4/mnc (G2) (T1↓ = 358.5 K; T1↑ = 360 K) ↔ 4/m (G1). The twin structures observed were described assuming the existence of cubic parent phase G0 with P m 3 ¯ m symmetry.

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Держатели документа:
RAS, LV Kirensky Phys Inst, Siberian Dept, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660074, Russia
Russian Acad Sci, Inst Chem, Far Eastern Dept, Vladivostok 690022, Russia

Доп.точки доступа:
Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.; Russian Foundation for Basic Research [12-02-00056]; Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools of the Russian Federation [NSh-924.2014.2]
}
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3.


   
    Thermal, structural, optical, dielectric and barocaloric properties at ferroelastic phase transition in trigonal (NH4)2SnF6: A new look at the old compound / I. N. Flerov [et al.] // J. Fluor. Chem. - 2016. - Vol. 183. - P. 1-9, DOI 10.1016/j.jfluchem.2015.12.010. - Cited References: 25. - The reported study was partially supported by RFBR, research project No. 15-02-02009a. . - ISSN 0022-1139
РУБ Chemistry, Inorganic & Nuclear + Chemistry, Organic
Рубрики:
Heat-capacity
   Ammonium

   (NH4)3TiF7

   Pressure

Кл.слова (ненормированные):
Fluorides -- Structural disorder -- Phase transitions -- Entropy -- Barocaloric effect
Аннотация: Structural phase transition P-3m1 → P-1 of the first order and nonferroelectric nature was found in (NH4)2SnF6 at about 110 K in the process of thermal, optical, dielectric and X-ray studies. Order-disorder transformation is accompanied by large changes of entropy (ΔS0 = 16.4 J/mol K) and volume (ΔV0/V ≈ 1%). The structural model associated with three orientations of NH4 tetrahedra in P-3m1 phase and their complete ordering in P-1 phase was suggested with the entropy change (ΔS0 = 18.3 J/mol K) close to the experimental value. A good agreement between baric coefficients measured in a direct way (dT0/dp = -157 K/GPa) and evaluated using entropy and volume changes at phase transition (-170 K/GPa) was found. Barocaloric effects in (NH4)2SnF6 are comparable with those of known solid state refrigerants and are characterised by a low-pressure need for realising their maximum values. © 2015 Elsevier B.V. All rights reserved.

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Держатели документа:
Kirensky Institute of Physics, Siberian Branch of RAS, Akademgorodok 50, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian State University, Krasnoyarsk, Russian Federation
Astafijev Krasnoyarsk State Pedagogical University, Krasnoyarsk, Russian Federation
Krasnoyarsk State Agrarian University, Krasnoyarsk, Russian Federation
Far Eastern State Transport University, Khabarovsk, Russian Federation
Institute of Chemistry, Far Eastern Branch of RAS, Vladivostok, Russian Federation

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Kartashev, A. V.; Карташев, Андрей Васильевич; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Mel'nikova, S. V.; Мельникова, Светлана Владимировна; Molokeev, M. S.; Молокеев, Максим Сергеевич; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Laptash, N. M.
}
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4.


   
    Thermal properties of (NH4)2MeF6·NH4F (Me: Ti, Sn) crystals undergoing transformation between two cubic phases / E. I. Pogoreltsev [et al.] // Ferroelectrics. - 2016. - Vol. 501, Is. 1. - P. 20-25, DOI 10.1080/00150193.2016.1198659. - Cited References: 9. - The reported study was partially supported by RFBR, research project No 15-02-02009-a . - ISSN 0015-0193
   Перевод заглавия: Тепловые свойства кристаллов (NH4)2MeF6ћNH4F (Me: Ti, Sn) претерпевающих трансформацию между двумя кубическими фазами
Кл.слова (ненормированные):
Phase transitions -- fluorides -- heat capacity -- entropy -- phase diagram
Аннотация: The heat capacity, thermal expansion, and T-p phase diagrams of (NH4)3TiF7 and (NH4)3SnF7 were studied in wide temperature and pressure ranges. The total excess entropies at successive Pa-3 ↔ P4/mnc ↔ 4/m (Ti) and single Pa-3 ↔ Pm-3m (Sn) phase transitions are close to each other and characteristic for the order–disorder processes. The Pm-3m cubic phase and direct Pa-3 ↔ Pm-3m transformation were found at high pressure in (NH4)3TiF7. The different sign of baric coefficients for phase transition between two cubic phases in (NH4)3TiF7 and (NH4)3SnF7 was supposed due to nonlinear phase boundary with pressure in the latter fluoride.

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Держатели документа:
Kirensky Institute of Physics, Siberian Department of RAS, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radioelectronic, Siberian State University, Krasnoyarsk, Russian Federation
Krasnoyarsk State Agrarian University, Krasnoyarsk, Russian Federation
Far Eastern State Transport University, Khabarovsk, Russian Federation
Institute of Chemistry, Far Eastern Department of RAS, Vladivostok, Russian Federation

Доп.точки доступа:
Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Kartashev, A. V.; Карташев, Андрей Васильевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
}
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5.


   
    Thermal properties and phase transitions in (NH4) 3ZrF7 / V. D. Fokina [et al.] // Journal of Fluorine Chemistry. - 2013. - Vol. 154. - P. 1-6, DOI 10.1016/j.jfluchem.2013.07.001 . - ISSN 0022-1139
Кл.слова (ненормированные):
Cubic fluorides -- Entropy -- Permittivity -- Phase transitions -- Pressure effect -- Thermal dilatation
Аннотация: The heat capacity, thermal dilatation, permittivity, and T-p phase diagram of (NH4)3ZrF7 have been studied in wide temperature and pressure ranges. Two phase transitions were found in addition to previously known structural transformations. The stability of crystal phases to temperature and pressure has been examined and a possibility of transition between two cubic phases has been discussed. The total excess entropy change SDSi = Rln6 is characteristic for the order-disorder processes, but its stepwise increase is not consistent with the structural model associated with the strong disorder assumed in the initial cubic phase. В© 2013 Elsevier B.V. All rights reserved.

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Держатели документа:
RAS, Siberian Dept, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660074, Russia
Krasnoyarsk State Agr Univ, Krasnoyarsk 660049, Russia
RAS, Far Eastern Dept, Inst Chem, Vladivostok 690022, Russia

Доп.точки доступа:
Fokina, V. D.; Фокина, Валентина Дмитриевна; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Pogoreltsev, E. I.; Погорельцев, Евгений Ильич; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
}
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6.


   
    Thermal properties and phase transition in the fluoride, (NH4)3SnF7 / A. V. Kartashev [et al.] // J. Solid State Chem. - 2016. - Vol. 237. - P. 269-273, DOI 10.1016/j.jssc.2016.02.027. - Cited References: 18. - This study was partially supported by the Russian Foundation for Basic Research (RFBR), research Project no. 15-02-02009a. . - ISSN 0022-4596
РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
Heat-capacity
   Chemistry

Кл.слова (ненормированные):
Phase transition -- Fluorides -- Heat capacity -- Entropy -- Thermal expansion -- High pressure
Аннотация: Calorimetric, dilatometric and differential thermal analysis studies were performed on (NH4)3SnF7 for a wide range of temperatures and pressures. Large entropy (δS0=22 J/mol K) and elastic deformation (δ(ΔV/V)0=0.89%) jumps have proven that the Pa-3虠Pm-3m phase transition is a strong first order structural transformation. A total entropy change of ΔS0=32.5 J/mol K is characteristic for the order-disorder phase transition, and is equal to the sum of entropy changes in the related material, (NH4)3TiF7, undergoing transformation between the two cubic phases through the intermediate phases. Hydrostatic pressure decreases the stability of the high temperature Pm-3m phase in (NH4)3SnF7, contrary to (NH4)3TiF7, characterised by a negative baric coefficient. The effect of experimental conditions on the chemical stability of (NH4)3SnF7 was observed. © 2016 Elsevier Inc.

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Держатели документа:
Kirensky Institute of Physics, Siberian Department of the Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Astafijev Krasnoyarsk State Pedagogical University, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian State University, Krasnoyarsk, Russian Federation
Krasnoyarsk State Agrarian University, Krasnoyarsk, Russian Federation
Institute of Chemistry, Far Eastern Department of the Russian Academy of Sciences, Vladivostok, Russian Federation

Доп.точки доступа:
Kartashev, A. V.; Карташев, Андрей Васильевич; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Flerov, I. N.; Флёров, Игорь Николаевич; Laptash, N. M.
}
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7.


   
    The role of chemical pressure in the formation of the structure and barocaloric properties of complex fluorides and oxyfluorides / I. N. Flerov, M. V. Gorev, E. V. Bogdanov, N. M. Laptash // Crystallogr. Rep. - 2023. - Vol. 68, Is. 5. - P. 765-778, DOI 10.1134/S1063774523600485. - Cited References: 67 . - ISSN 1063-7745. - ISSN 1562-689X
Аннотация: The role of chemical pressure as an effective tool in the processes of formation of initial and distorted (as a result of structural transformations) phases, thermodynamic properties, and direct and inverse barocaloric effects in some complex oxyfluorides and fluorides with octahedral, tetrahedral, and spherical anion and cation groups in the structure has been studied. It is found that, due to the small temperature hysteresis and high baric sensitivity of materials, the maximum values of absolute and integral barocaloric characteristics can be implemented at low pressures. Correspondingly, the temperature range of reversibility of thermodynamic cycles based on fluorides/oxyfluorides as solid-state coolants can be expanded.

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Публикация на русском языке Роль химического давления в формировании структуры и барокалорических свойств комплексных фторидов и оксифторидов [Текст] / И. Н. Флёров, М. В. Горев, Е. В. Богданов, Н. М. Лапташ. - 14 с. // Кристаллография. - 2023. - Т. 68 № 5. - С. 776-789

Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, Russia
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, Krasnoyarsk, Russia
Institute of Chemistry, Far Eastern Branch, Vladivostok, Russia

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Laptash, N. M.
}
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8.


    Flerov, I. N.
    The role of chemical pressure in the formation of the piezocaloric effect in fluorine–oxygen ferroics / I. Flerov, M. Gorev // Ferroelectrics. - 2020. - Vol. 567, Is. 1 : Special Issue in Honor of Professor Stanislav A. Grindev on the Occasion of His 83rd Birthday. - P. 1-12, DOI 10.1080/00150193.2020.1791581. - Cited References: 25 . - ISSN 0015-0193
Кл.слова (ненормированные):
Fluorides -- phase transitions -- entropy -- high pressure -- caloric effect
Аннотация: We performed an analysis of the phase diagrams and piezocaloric properties of fluorine–oxygen ferroics (NH4)2MeOxF6-x (Me: W, Mo, Nb; x: 1, 2) with orthorhombic symmetry. The nature of the influence of chemical pressure on the caloric efficiency has been elucidated. Substitutions of central atoms, Mo → W and Nb → W, lead to an increase in absolute and integral piezocaloric effects.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Gorev, M. V.; Горев, Михаил Васильевич; Флёров, Игорь Николаевич
}
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9.


    Malakhovskii, A. V.
    Temperature dependence of the fine structure of the C and E absorption bands in RbMnF3 below the Neel temperature / A. V. Malakhovskii, T. P. Morozova // Phys. Solid State. - 2006. - Vol. 48, Is. 2. - P. 283-290, DOI 10.1134/S1063783406020156. - Cited References: 24 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
PEROVSKITE FLUORIDES
   VIBRONIC SPECTRA

   CRYSTALS

   MNF2

   INTENSITY

   DICHROISM

   STATES

Аннотация: The variation in the parameters (width, position, intensity) of the fine structure lines in the C[(6)A(1g) - (4)A(1g), E-4(g)((4)G)] and E[(6)A(1g) - E-4(g)(D-4)] bands in RbMnF3 with temperature is studied in the temperature range 10-70 K. In the C band, two narrow ( 6 cm(-1)) lines are are distinguished at distances of 77 and 80 cm(-1) from the exciton line at T

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Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Morozova, T. P.; Малаховский, Александр Валентинович
}
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10.


   
    Structure-based machine learning enables discovery of Mn4+-activated red-light fluorides for ultrawide-gamut mini-light-emitting diodes / Yu. Wang, W. Tang, Ch. Zhang [et al.] // Adv. Funct. Mater. - 2024. - Vol. 34, Is. 14. - Ст. 2313490, DOI 10.1002/adfm.202313490. - Cited References: 61. - This research was financially supported by the National Key R& D Program of China (Grant No. 2022YFB3503800) and the National Natural Science Foundation of China (Grant Nos. 52202170 and 52322208). This research was supported by the Tyumen Oblast Government, as part of the West-Siberian Interregional Science and Education Center's project No. 89-DON (3) . - ISSN 1616-301X. - ISSN 1616-3028
   Перевод заглавия: Структурное машинное обучение позволяет обнаружить Mn4+-активированные фториды красного света для мини-светодиодов со сверхширокой гаммой
Кл.слова (ненормированные):
fluorides -- mini-light-emitting diodes -- Mn4+ -- red light -- wide-gamut displays
Аннотация: Mn4+-activated fluorides with a saturated red color and sharp line emission are ideal for applications in the light-emitting diodes (LEDs) backlight for displays. However, the emissions attributed to 2E→4A2 parity and spin-forbidden transitions limit the design and adjustments of emission wavelength and chromaticity coordinates. Herein, machine learning algorithms are used to build a wavelength-prediction model for Mn4+-activated fluorides. The model precisely identifies the key structural features that affect wavelengths and discovers target materials. The predicted candidate Cs2NaAlF6:Mn4+ (CNAF) with a long-wavelength zero-phonon-line emission at 628 nm exhibits a redshift in comparison with other reported Mn4+-activated fluorides and commercial K2SiF6:Mn4+, but maintains narrow spectral emission with full-width half maximum (FWHM) of 11.2 nm. The redshift and narrow spectra result in a color purity of 99.7% and Commission Internationale de L'Eclairage (CIE) chromaticity coordinate of (0.7032,0.2967) that is close to the pure red-light point of Recommendation BT. 2020 (Rec. 2020). Moreover, CNAF is prepared as a transparent red-light film, and the device fabricated using the blue-light mini-LEDs, green quantum-dot film, and CNAF film exhibits a wide color-gamut of 121.5% National Television Standards Committee (NTSC) or 90.6% Rec. 2020, suggesting that CNAF has potential for wide-color-gamut displays.

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Держатели документа:
School of Physics and Optoelectronics, South China University of Technology, Guangzhou 510641, P. R. China
State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, School of Materials Science and Engineering, South China University of Technology, Guangzhou 510641, P. R. China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Department of Engineering Physics and Radioelectronic, Siberian Federal University, Krasnoyarsk 660041, Russia
Laboratory of Theory and Optimization of Chemical and Technological Processes, University of Tyumen, Tyumen 625003, Russia
Guangdong-Hong Kong-Macao Joint Laboratory for Intelligent Micro-Nano Optoelectronic Technology, School of Physics and Optoelectronic Engineering, Foshan University, Foshan 528225, China

Доп.точки доступа:
Wang, Yuanjing; Tang, Wenyu; Zhang, Chuang; Molokeev, M. S.; Молокеев, Максим Сергеевич; Ming, Hong; Zhou, Yayun; Peng, Shuai; Song, Enhai; Zhang, Qinyuan
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