Библиотека института физики им. Л.В. Киренского СО РАН

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Каталог книг и брошюр библиотеки ИФ СО РАН

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Труды сотрудников ИФ СО РАН

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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zharkov S. M., Moiseenko E. T., Altunin R. R., Zeer G. M.
Заглавие : In situ transmission electron microscopy and electron diffraction investigation of solid-state reactions and atomic ordering in Cu/Au bilayer nanofilms
Место публикации : J. Sib. Fed. Univ. Chem. - 2013. - Vol. 6, Is. 3. - P.230-240; Журн. СФУ. Сер. "Химия"
Ключевые слова (''Своб.индексиров.''): cu/au nanofilm--intermetallics--solid state reaction--phase transition--atomic ordering--superstructure--нанопленка cu/au--интерметаллиды--твердофазная реакция--фазовый переход--атомное упорядочение--сверхструктура
Аннотация: Solid-state reaction processes and atomic ordering in Cu/Au bilayer nanofilms (with the atomic ratio Cu:Au≈50:50) have been studied in situ by the methods of transmission electron microscopy and electron diffraction in the process of heating from room temperature up to 700 ºС at a heating rate of 4-8 ºС/min. The solid-state reaction between the nanolayers of copper and gold has been established to begin at 180 ºС. The process of atomic ordering has been shown to start simultaneously with the process of the formation of the disordered phase of Cu50Au50 at 245 ºС. The formation processes of the ordered phases of: CuAuI (L10 superstructure) and CuAuII (long period superstructure) have been studied, as well as the phase transition processes: disorder - order (the transition of the disordered structure into the ordered one) and order - disorder (the transition of the ordered structure into the disordered one).Методами просвечивающей электронной микроскопии и дифракции электронов проведены in situ-исследования процессов твердофазных реакций и атомного упорядочения в двухслойных нанопленках Cu/Au (с атомным соотношением Cu:Au≈50:50) при нагреве от комнатной температуры до 700 ºС при скорости нагрева 4-8 ºС/мин. Установлено, что твердофазная реакция между нанослоями меди и золота начинается при 180 ºС. Показано, что процесс атомного упорядочения начинается одновременно с процессом формирования неупорядоченной фазы Cu50Au50 при 245 ºС. Исследованы процессы формирования атомно-упорядоченных фаз: CuAuI (L10 сверхструктура) и CuAuII (длинно-периодическая сверхструктура), а также процессы фазовых переходов беспорядок-порядок (переход неупорядоченной структуры в атомно-упорядоченную) и порядок-беспорядок (переход атомно-упорядоченной структуры в неупорядоченную)
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zharkov S. M., Altunin R. R., Moiseenko E. T., Zeer G. M., Varnakov S. N., Ovchinnikov S. G.
Заглавие : Solid-state reactions in Fe/Si multilayer nanofilms
Коллективы : Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации : Solid State Phenom.: Selected, peer reviewed papers/ ed.: S. G. Ovchinnikov, A. Samardak: Trans Tech Publications, 2014. - Vol. 215: Trends in Magnetism: Nanomagnetism (EASTMAG-2013). - P.144-149. - ISSN 1662-9779, DOI 10.4028/www.scientific.net/SSP.215.144. - ISSN 978-303835054-5
Примечания : Cited References: 16. - The work was supported by the Presidium of RAS (project No. 24.34), the Russian Foundation for Basic Research (grant #13-02-01265)
Ключевые слова (''Своб.индексиров.''): fe/si multilayer nanofilm--intermetallics--solid state reaction--phase transition--magnetic properties--electron diffraction--transmission electron microscopy
Аннотация: Solid-state reaction processes in Fe/Si multilayer nanofilms have been studied in situ by the methods of transmission electron microscopy and electron diffraction in the process of heating from room temperature up to 900ºС at a heating rate of 8-10ºС/min. The solid-state reaction between the nanolayers of iron and silicon has been established to begin at 350-450ºС increasing with the thickness of the iron layer.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kuklin A. V., Kuzubov A. A., Krasnov P. O., Lykhin A. O., Tikhonova L. V.
Заглавие : Ni-doping effect of Mg(0 0 0 1) surface to use it as a hydrogen storage material
Место публикации : J. Alloys Compd.: Elsevier Science, 2014. - Vol. 609. - P.93-99. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2014.04.160. - ISSN 1873-4669
Примечания : Cited References: 38
Предметные рубрики: INITIO MOLECULAR-DYNAMICS
AUGMENTED-WAVE METHOD
MINIMUM ENERGY PATHS
ELASTIC BAND METHOD
METAL-HYDRIDES
SADDLE-POINTS
MAGNESIUM
Mg
TRANSITION
Pd
Ключевые слова (''Своб.индексиров.''): hydrogen absorbing materials--intermetallics--diffusion--dft--mg-based hydride
Аннотация: A detailed study of Ni-doped Mg(0 0 0 1) surface performed by PAW method and the gradient corrected density functional GGA-PBE within the framework of generalized Kohn–Sham density functional theory (DFT) is presented in this work. Structural and electronic properties of magnesium surface interaction with nickel for the purpose of such compounds use for creation of hydrogen storage matrixes were investigated here. Choice of the PBE functional was caused by the good accordance of its prediction of the cell parameters with experimental results. It was shown that Ni atoms prefer to substitute for Mg atoms. Using NEB method, the diffusion barrier was calculated, and the most probable reaction path was established. In particular, when the Ni atom dopes the magnesium surface, it can migrate to the bulk and substitute for Mg in subsurface layers. Also a possibility of nickel cluster formation on clean surface of magnesium was examined. The kinetic factors hinder the movement of the nickel atoms to each other and make problematic the formation of clusters. The studies presented here showed that the diffusion barriers of the nickel atom migration from the cluster on the surface to the bulk of magnesium are 1.179 eV and 1.211 eV for the forward and reverse reactions, respectively. Therefore an improvement of the hydrogenation properties of Ni-doped magnesium surface depends on deposition not of the individual atoms, but their clusters. Hydrogenation of Ni cluster doping the magnesium surface was investigated. Initially Kubas complexes arise on the Ni cluster with hydrogen–hydrogen bond lengths equal to 0.80–0.87 Å. Next the cluster needs to be saturated by hydrogen atoms to allow them later to migrate from cluster to magnesium.
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Вид документа : Статья из журнала
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Автор(ы) : Moiseenko E. T., Altunin R. R., Zharkov S. M.
Заглавие : In situ electron diffraction and resistivity characterization of solid state reaction process in Cu/Al bilayer thin films
Место публикации : Metall. Mat. Trans. A. - 2020. - Vol. 51, Is. 3. - P.1428-1436. - ISSN 10735623 (ISSN), DOI 10.1007/s11661-019-05602-5
Примечания : Cited References: 52. - The authors wish to thank the financial support from the Russian Science Foundation (Grant #18-13-00080)
Аннотация: Solid state reaction processes in Cu/Al thin films have been studied using the methods of in situ electron diffraction and electrical resistivity measurements. The solid state reaction in the Cu/Al thin films has been found to begin already at 88 °C with the formation of the Al2Cu phase in the process of thermal heating in vacuum. The phase sequence at the solid state reaction in the films under study has been determined to be the following: Al2Cu → AlCu → Al4Cu9. A model has been suggested for describing the initial formation stage of intermetallic compounds at the solid state reaction in Cu/Al thin films. According to this model, at the initial stage, the intermetallic compounds are formed as separate crystallites at the interface in the Cu/Al thin films. The suggested model can be applied both to the formation of the first phase, Al2Cu, and to the subsequent phases: AlCu and Al4Cu9. For the Al4Cu9 phase the temperature coefficient of the electrical resistivity has been determined to be equal to αAl4Cu9= 1.1 × 10−3 K−1.
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Вид документа : Статья из журнала
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Автор(ы) : Bykova L. E., Zharkov S. M., Myagkov V. G., Balashov Yu. Yu., Patrin G. S.
Заглавие : Formation of the Cu6Sn5 intermetallics in Cu/Sn thin films
Место публикации : Phys. Solid State. - 2022. - Vol. 64, Is. 2. - P.33-37. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783422010048
Примечания : Cited References: 16. - The study was supported by the Russian Foundation for Basic Research, project no. 19-43-240003. The electron microscopy study was carried out at the Krasnoyarsk Regional Center for Collective Use of the Krasnoyarsk Scientific Center, Siberian Branch of the Russian Academy of Sciences and at the Laboratory of Electron Microscopy of the Center for Collective Use of the Siberian Federal University within the state assignment of the Ministry of Science and Higher Education of the Russian Federation, research theme code FSRZ-2020-0011
Аннотация: The formation of the Cu6Sn5 intermetallic in Sn(55nm)/Cu(30nm) thin-film bilayers has been studied upon heating the film sample from room temperature to 300°C directly in a column of a transmission electron microscope in the electron diffraction mode with recording electron diffraction patterns. The thin films synthesized by the solid-state reaction have been found to be single-phase and consist of the η-Cu6Sn5 hexagonal phase (95‒260°C). It has been suggested basing on the effective interdiffusion coefficient (5 × 10‒16 m2/s) estimated in the course of the reaction that the main mechanism of the formation of the Cu6Sn5 thin films is diffusion along grain boundaries and dislocations.
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Вид документа : Статья из журнала
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Автор(ы) : Myagkov V. G., Bykova L. E., Zhigalov V. S., Matsynin A. A., Zharkov S. M., Ivanenko A. A., Bondarenko G. N., Velikanov D. A.
Заглавие : Solid-state synthesis, magnetic and structural properties of epitaxial D03-Fe3Rh(001) thin films
Место публикации : Intermetallics. - 2023. - Vol. 157. - Ст.107871. - ISSN 09669795 (ISSN), DOI 10.1016/j.intermet.2023.107871. - ISSN 18790216 (eISSN)
Примечания : Cited References: 27. - The authors are grateful to L.A. Solovyov for carrying out the XRD φ-scan experiments and I.V. Nemtsev for the measurements of the sample composition. The work is partially based upon the experiments performed at Krasnoyarsk Regional Center of Research Equipment of Federal Research Center « Krasnoyarsk Science Center SB RAS». This research did not receive any specific grant from funding agencies in the public, commercial, or not-for-profit sectors
Аннотация: Here we first report on the formation of epitaxial D03-Fe3Rh(001) films grown during solid-state reaction in Rh/Fe(001) bilayers on MgO(001) substrates. Samples of the Fe68Rh32 composition above 400 °C showed the formation of a new ordered phase, in addition to the ordered B2–FeRh phase (space group Pm-3m, lattice constant a = 0.2993 nm), which becomes the dominant phase in Fe76Rh24 samples. These results and the results of the asymmetrical XRD φ-scan prove that the new ordered phase is the ordered D03-Fe3Rh(001) phase (space group Fm-3m, lattice constant a = 0.5888 nm), forming a cube-on-cube orientation relationship with respect to the MgO(001) substrate. The D03-Fe3Rh sample is a soft magnetic material with high saturation magnetization.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Moiseenko E. T., Yumashev V. V., Altunin R. R., Solovyov L. A., Volochaev M. N., Belousov O. V., Zharkov S. M.
Заглавие : Thermokinetic study of intermetallic phase formation in an Al/Cu multilayer thin film system
Место публикации : Materialia. - 2023. - Vol. 28. - Ст.101747. - ISSN 25891529 (eISSN), DOI 10.1016/j.mtla.2023.101747
Примечания : Cited References: 53. - This work was supported by the Russian Science Foundation under grant # 22-13-00313
Аннотация: The solid-state reaction process in a multilayer thin film system (Al/Cu)50 has experimentally been studied using the methods of simultaneous thermal analysis (STA) and in situ electron diffraction. A detailed kinetic analysis of the phase formation processes during the solid-state reaction has shown that the observed solid-state transformations can be described by a statistically significant kinetic model where each stage corresponds to the reaction of the n-th order with autocatalysis. The low-temperature stage has been demonstrated to be attributable to the formation of the θ-Al2Cu phase, with the medium-temperature and high-temperature ones corresponding to the α2-AlCu3 and γ1-Al4Cu9 phases, respectively. The kinetic parameters for the formation of the phases θ-Al2Cu, α2-AlCu3 and γ1-Al4Cu9 have been determined. It has been shown that the kinetic model describing the solid-state reaction in the Al–Cu multilayer thin film system is in best agreement with the experimental data in the case of a competition between the formation stages of the α2-AlCu3 and γ1-Al4Cu9 phases.
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