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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korshunov M. M., Togushova Yu. N.
Заглавие : Superconducting order parameter structure in the nematic phase of iron-based materials
Колич.характеристики :6 с
Место публикации : JETP Lett. - 2024. - Vol. 119, Is. 4. - P.310-315. - ISSN 00213640 (ISSN), DOI 10.1134/S0021364024600046. - ISSN 10906487 (eISSN)
Примечания : Cited References: 28
Аннотация: We consider the effect of the nematic order on the formation of the superconducting state in iron pnictides and chalcogenides. Nematic order with the B2g symmetry is modelled as the d-type Pomeranchuk instability and treated within the mean-field approach. Calculated nematic order parameter depends on the nematic interaction coefficient and abruptly changes with the coefficient’s increase. The superconducting solution is obtained within the spin-fluctuation pairing theory. We show that the leading solution in the nematic phase has a sπ± structure. From the critical temperature Tc estimations, we conclude that the nematic superconducting state of the sπ± type is more favorable than the usual s± and dx2-y2 type states appearing in the absence of the nematicity.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zagorskiy D.L., Semenov S. V., Komogortsev S. V., Balaev D. A., Doludenko I.M., Panina L.V.
Заглавие : Magnetization processes in two-dimensional arrays of iron nanowires
Колич.характеристики :8 с
Место публикации : J. Magn. Magn. Mater. - 2024. - Vol. 595. - Ст.171573. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2023.171573. - ISSN 18734766 (eISSN)
Примечания : Cited References: 48. - This work was supported by Russian Scientific Foundation (RSF) Grant 22-22-00983
Аннотация: Arrays of iron nanowires (NWs) obtained by template-assisted electrodeposition constitute a promising composite material characterized by a combination of high magnetization in the filler and perpendicular magnetic anisotropy. The properties of these composites arise from the interplay between the behavior of individual NWs and their magnetostatic interactions. In this study, we investigated NW arrays with identical wire diameters but varying spatial arrangements. Major hysteresis loops were studied under various field directions relative to the NW axis. Key parameters such as the slope of the magnetization curve, saturation magnetization, and coercive force were quantified. Additionally, FORC (First Order Reversal Curve) measurements were conducted with the field oriented longitudinally with respect to the NW, offering insights into the inhomogeneity of the demagnetizing field influenced by the NW array's configuration. In the sample with the highest NW density, we observed isotropic behavior of the effective demagnetizing field, and we proposed an explanation for this phenomenon using the effective media approach. Micromagnetic simulations revealed that the magnetic behavior of individual NWs with a 100 nm diameter can be described as an interchange between volumes characterized by vortex and uniform magnetization patterns. Calculations of the demagnetizing field using the effective medium model demonstrated excellent agreement with experimental data across arrays featuring different NW densities. Remarkably, the quantitative consistency of coercive field values obtained from micromagnetic simulations and experimental measurements in the range of angles from 0° to 45° for the studied samples underscores the structural homogeneity of the obtained NWs.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bondarenko L., Baimuratova R., Dzeranov A., Pankratov D., Kicheeva A., Sushko E., Kudryasheva N., Valeev R., Tropskaya N., Dzhardimalieva G., Kydralieva K.
Заглавие : Fenton reaction-driven pro-oxidant synergy of ascorbic acid and iron oxide nanoparticles in MIL-88B(Fe)
Колич.характеристики :19 с
Место публикации : New J. Chem. - 2024. - Vol. 48, Is. 22. - P.10142-10160. - ISSN 11440546 (ISSN), DOI 10.1039/D4NJ00963K. - ISSN 13699261 (eISSN)
Примечания : Cited References: 94
Аннотация: MIL-88B, a promising Fe-based 3D porous metal–organic framework (MOF) catalyst for the Fenton reaction, requires modifications to enhance its pro-oxidant activity and enable magnetic control of the sample. This study reports the successful modification of MIL-88B with iron oxide (Fe3O4) and ascorbic acid (AA). The characterization of the crystal structure and morphology of the Fe3O4–AA MOF sample using X-ray diffraction, Raman and Mossbauer spectroscopy, and scanning electron microscopy revealed that AA facilitated the formation of magnetite with a composition approaching a stoichiometry of Fe2.96O4 while preserving the MOF structure. Specifically, in the presence of hydrogen peroxide (H2O2), Fe3O4–AA–MOF exhibited a 3-fold increase in the Fenton reaction rate for methylene blue degradation compared to the conventional homogeneous system at pH 4.5. Furthermore, Fe3O4–AA–MOF retained the antibacterial properties of AA, as evidenced by its ability to increase reactive oxygen species in luminescent marine bacterium Photobacterium phosphoreum at low concentrations while exhibiting moderate cytotoxicity. The enhanced pro-oxidant activity of the Fe3O4–AA–MOF/H2O2 system is attributed to an AA-promoted surface Fe2+/Fe3+ cycle. A possible mechanism for this system is proposed.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vazhenina I. G., Stolyar S. V., Tyumentsev A. V., Volochaev M. N., Iskhakov R. S., Komogortsev S. V., Pyankov V. F., Nikolaeva E. D.
Заглавие : Study of magnetic iron oxide nanoparticles coated with silicon oxide by ferromagnetic method
Колич.характеристики :5 с
Коллективы : Nanophysics and Nanoelectronics, International Symposium
Место публикации : Phys. Solid State. - 2023. - Vol. 65, Is. 6. - P.884-888. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2023.06.56095.01H. - ISSN 10906460 (eISSN)
Примечания : Cited References: 20. - The study was supported by grant No. 22-14-20020 provided by the Russian Science Foundation, Krasnoyarsk Regional Science Foundation
Аннотация: agnetic nanoparticles of magnetite with a size of ~8 nm synthesized with a different type of coating were studied by ferromagnetic resonance in the temperature range from 7 to 300 K. The features of the experimental temperature dependences of the parameters of the ferromagnetic resonance curve (the magnitude of the resonant field, line width and intensity) and their approximation allowed us to estimate the values of characteristic temperatures. Firstly, the value of the Vervey temperature and the dependence of its value on the type of coating were determined. Secondly, the temperature of transition of nanoparticles to the superparamagnetic state (blocking temperature) and the temperature range within which the magnetic structure of the outer shell of the magnetic nanoparticle is in the spin glass state are established.
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5.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Семенов, Сергей Васильевич, Комогорцев, Сергей Викторович, Балаев, Александр Дмитриевич, Загорский Д. Л.
Заглавие : Магнитодипольное взаимодействие в двумерном ансамбле нанонитей железа
Коллективы : Байкальская международная конференция "Магнитные материалы. Новые технологии", "Магнитные материалы. Новые технологии", Байкальская международная конференция, "Magnetic materials. New tecnologies", Baikal International Conference, Иркутский государственный университет
Место публикации : Магнитные материалы. Новые технологии: тез. докл. IX Байкал. междунар. конф. BICMM-2023/ чл. прогр. ком.: S. S. Aplesnin [et al.] ; чл. орг. ком. R. S. Iskhakov [et al.]. - Иркутск, 2023. - С. 30. - ISBN 978-5-962402178-0, DOI 10.26516/978-5-9624-2178-0.2023.1-207
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Dubrovskii A. A., Knyazev Yu. V., Semenov S. V., Kirillov V. L., Martianov O. N.
Заглавие : The manifestation of surface and size effects in the magnetic properties of ε-Fe2O3 nanoparticles. (Brief overview)
Колич.характеристики :9 с
Коллективы : Nanophysics and Nanoelectronics, International Symposium
Место публикации : Phys. Solid State. - 2023. - Vol. 65, Is. 6. - P.938-946. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2023.06.56105.12H. - ISSN 10906460 (eISSN)
Примечания : Cited References: 66
Аннотация: Polymorphic modification of iron oxide, known as ε-Fe2O3, exists only in the form of nanoparticles with characteristic sizes up to several tens of nanometers. Particles of these sizes exhibit a large coercive force, about 20 kOe at room temperature. In the temperature range of 80–150 K, a magnetic transition occurs in ε-Fe2O3, accompanied by a sharp decrease in the coercive force. At the same time, there are significant differences in the magnetic behavior of "large" (~20 nm) particles and ultra-small particles (up to 6 nm). A number of experimental facts indicate the manifestation of size effects that lead to a change in the magnetic structure in particles of these sizes. In addition, a surface effect is also manifested for such particles - a significant contribution to the magnetic behavior is governed by surface magnetic anisotropy. In this paper, a brief review of the manifestation of these size and surface effects in the magnetic properties of ε-Fe2O3 nanoparticles is carried out.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhlin, Yuri L., Borisov, Roman V., Likhatski, Maxim N., Bayukov O. A., Knyazev Yu. V., Zharkov S. M., Vorobyev, Sergey A., Tomashevich, Yevgeny V., Ivaneeva, Anastasiya D., Karacharov, Anton A., Karpov, Denis V., Velikanov D. A., Rautskii M. V., Smolyakov D. A., Tarasov A. S.
Заглавие : Facile synthesis and selected characteristics of two-dimensional material composed of iron sulfide and magnesium-based hydroxide layers (tochilinite)
Место публикации : New J. Chem. - 2023. - Vol. 47, Is. 25. - P.11869-11881. - ISSN 11440546 (ISSN), DOI 10.1039/D3NJ00758H. - ISSN 13699261 (eISSN)
Примечания : Cited References: 97. - This research was financially supported by the Russian Science Foundation, project 22-13-00321
Аннотация: We report here a simple hydrothermal synthesis of 100–200 nm flakes of tochilinite (Fe1−xS)·n(Mg,Fe)(OH)2 constructed by interchanging atomic sulfide and hydroxide sheets as a representative of a new platform of multifunctional two-dimensional materials. The reliable formation of tochilinites was ensured by an excess of sodium sulfide, with the assembly of the metal sulfide and hydroxide sheets driven by their opposite electric charges. X-ray photoelectron spectroscopy found that the hydroxide layers involved Fe3+ cations from 10 to 40% of total iron tuned by addition of Al and Li entering the layers; the Fe1−xS sheets comprised comparable amounts of high-spin Fe3+ and Fe2+ centers, and minor S–S bonding. The room-temperature Mössbauer spectra fitted with several doublets (chemical shift of 0.35–0.4 mm s−1 and varying quadrupole splitting) transformed to three six-line patterns (hyperfine fields of ∼290, 350 and 480 kOe) due to magnetic ordering at 4.2 K, albeit the paramagnetic behavior observed in SQUID experiments. A series of UV-vis absorption maxima were explained in terms of both the high-index all-dielectric Mie resonance, in line with the permittivity measurement data, and the ligand-metal charge transfer resembling that in Fe–S clusters in proteins. Prospective properties and applications of the materials are discussed.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Zelenov F. V., Semenov S. V., Bayukov O. A.
Заглавие : Anomalies in the magnetic properties of bismuth-substituted diluted yttrium iron garnet
Колич.характеристики :9 с
Место публикации : J. Magn. Magn. Mater. - 2023. - Vol. 582. - Ст.171030. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2023.171030. - ISSN 18734766 (eISSN)
Примечания : Cited References: 61. - The authors are grateful to T. N. Tarasenko for providing samples for magnetic measurements
Аннотация: The magnetic properties and Mossbauer spectra of the Y1.8Bi1.2Fe3.5Ga1.5O12 compound were investigated. A linear temperature dependence of the saturation magnetization, hysteresis, and stability of the coercive field in the magnetically ordered state were found. Using the Mossbauer measurements, the distribution of iron ions over octahedral and tetrahedral sites and the concentration of paramagnetic iron ions were determined. Two critical temperatures – the sublattice magnetization compensation temperature and the ferrimagnet–paramagnet transition temperature – were established. The disappear of the phonon mode in the vicinity of the magnetic transition was observed. The experimental data have been interpreted in terms of the spin–lattice interaction model.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shapovalov V. V., Shapovalov V. A., Sluzhbin Yu. A., Drokina T. V., Vorotynov A. M., Valkov V. I.
Заглавие : Characteristics of nanocomplexes with iron Fe3+ in Glass Ionomer Cement powder by ESR method
Место публикации : Phys. Solid State. - 2023. - Vol. 65, Is. 2. - P.296-298. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2023.02.55415.489. - ISSN 10906460 (eISSN)
Примечания : Cited References: 13
Аннотация: The study is part of nanomedical biotechnology and is carried out by probing these systems using the Electronic Spin Resonance (ESR) method. The paper investigates Glass Ionomer Cement powder widely used in dental practice Glass Ionomer Cement C-Plus Triplekit-TM. To assess the quality of Glass Ionomer Cement and use ESR radiospectroscopy in the range from low (T=4.2 K) to room (T=300 K) temperatures. A new characteristic of compounds with nanocomplexes of magnetic iron ions Fe3+ is applied.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanov D. A., Togushova Y. N., Korshunov M. M.
Заглавие : Changes of the Fermi surface topology in the three-orbital model for iron pnictides with the spin-orbit coupling
Колич.характеристики :9 с
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2023. - Vol. 16, Is. 6. - P.795-803. - ISSN 19971397 (ISSN); Журн. СФУ. Матем. и физ. - ISSN 23136022 (eISSN)
Примечания : Cited References: 28
Аннотация: Effect of the spin-orbit coupling on the band structure and the Fermi surface of the three-orbital model is studied. The inter-orbital part of the model is reformulated to fully conform with the iron lattice symmetry. Because there are two iron ions in the unit cell, we introduce the intra-and inter-ion spin-orbit coupling constants to separate the effect of the related couplings on the band structure and the Fermi surface. Both the intra-and inter-ion parts lift the degeneracy of some bands at the Γ = (0, 0) point and the splitting of bands along the (0, π) ‒ (π, π) direction of the Brillouin zone. We show that the inter-ion part of the spin-orbit coupling leads to the topological change of the Fermi surface — the splitting of two Fermi surface sheets around the M = (π, π) point.Изучено влияние спин-орбитального взаимодействия на зонную структуру и поверхность Ферми в трехорбитальной модели. Межорбитальная часть модели изменена для полного соответствия с симметрией решетки железа. Из-за наличия двух ионов железа в элементарной ячейке мы вводим внутри- и межионную константы спин-орбитального взаимодействия для разделения эффектов соответствующих взаимодействий на зонную структуру и поверхность Ферми. И внутри, и межионная части снимают вырождение некоторых зон в точке Γ = (0, 0) и вырождение вдоль направления (0, π) − (π, π) зоны Бриллюэна. Показано, что межионная часть спин-орбитального взаимодействия приводит к изменению топологии поверхности Ферми, а именно к разделению листов поверхности Ферми вблизи точки M = (π, π).
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