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Luminescence of manganese ions in yttrium aluminium borate / Aleksandrovsky A.S., Gudim I.A., Krylov A.S, Temerov V.E. // 15th International Conference on Luminescence and Optical Spectroscopy of Condensed Matter, Lyon, 2008, p.482

Доп.точки доступа:
Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Gudim, I. A.; Гудим, Ирина, Анатольевна; Krylov, A. S; Temerov, V. E.
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Optical absorption and luminescence of Tm3+ and Yb3+ ions in huntite structure / Malakhovskii A.V., Edelman I.S., Sokolov A.E., Sukhachov A.L., Temerov V.L., Gnatchenko S.L., Kachur I.S., Piryatinskaya V.G., Valiev U.V. // Республиканская конференция «Оптические методы в современной физике», Ташкент, Узбекистан, 2008, с. 33-35

Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Edelman, I. S.; Эдельман, Ирина Самсоновна; Sokolov, A. Е.; Соколов, Алексей Эдуардович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Temerov, V. L.; Темеров, Владислав Леонидович; Gnatchenko, S. L.; Kachur, I. S.; Piryatinskaya, V. G.; Valiev, U. V.
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Temperature/component-dependent luminescence in lead-free hybrid metal halides for temperature sensor and anti-counterfeiting / G. Zhou, Y. Wang, Y. Mao [et al.] // Adv. Funct. Mater. - 2024. - Ст. 2401860, DOI 10.1002/adfm.202401860. - Cited References: 89. - G.J.Z. and Y.T.W. contributed equally to this work. This work was supported by the National Natural Science Foundation of China (No.52202177, 22271211), Fundamental Research Program of Shanxi Province (No.20210302124054), Science and Technology Innovation Project of Colleges and Universities in Shanxi Province (No.2021L262), 1331 Project of Shanxi Province, Postgraduate Innovation Project of Shanxi Province (No.2023KY462), and supported by the Ministry of Science and High Education of Russian Federation (No.FSRZ-2023-0006). The authors would like to thank Prof. Haijun Jiao, Leibniz-Institut für Katalyse e.V., Germany, for the theoretical support on the electron-transition mechanism . - Article in press. - ISSN 1616-301X. - ISSN 1616-3028
Кл.слова (ненормированные):
electron-transition -- hybrid metal halides -- optical-functional applications -- self-trapped excitons -- tunable photoluminescence
Аннотация: Hybrid metal halides (HMHs) have emerged as a promising platform for optically functional crystalline materials, but it is extremely challenging to thoroughly elucidate the electron transition coupled to additional ligand emission. Herein, to discover sequences of lead-free HMHs with distinct optically active metal cations are aimed, that is, Sb3+ (5s2) with the lone-pair electron configuration and In3+ (4d10) with the fully-filled electron configuration. (Me2NH2)4MCl6·Cl (Me = −CH3, M = Sb, In) exhibits the superior temperature/component-dependent luminescence behaviors resulting from the competition transition between triplet-states (Tn-S0) self-trapped excitons (STEs) of inorganic units and singlet-state (S1-S0) of organic cations, which is manipulated by the optical activity levels of [SbCl6]3− and [InCl6]3−. The bonding differences between Sb3+/In3+ and Cl− in terms of electronic excitation and hybridization are emphasized, and the different electron-transition mechanisms are established according to the PL spectra at the extreme temperature of 5 to 305 K and theoretical calculations. By fine-tuning the B-site Sb3+/In3+ alloying, the photoluminescence quantum yield (PLQY = 81.5%) and stability are optimized at 20% alloying of Sb3+. This research sheds light on the rules governing PL behaviors of HMHs, as well as exploring the optical-functional application of aviation temperature sensors and access-control systems.

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Держатели документа:
Key Laboratory of Magnetic Molecules and Magnetic Information Materials (Ministry of Education), School of Chemistry and Material Science, Shanxi Normal University, Taiyuan 030031, P. R. China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
International Research Center of Spectroscopy and Quantum Chemistry-IRC SQC, Siberian Federal University, Krasnoyarsk 660041, Russia
State Key Laboratory of Luminescent Materials and Devices, Guangdong Provincial Key Laboratory of Fiber Laser Materials and Applied Techniques, Guangdong Engineering Technology Research and Development Center of Special Optical Fiber Materials and Devices, School of Physics and Optoelectronics, South China University of Technology, Guangzhou, Guangdong 510641, P. R. China
College of Chemistry & Chemical Engineering, Key Laboratory of Interface Science and Engineering in Advanced Material, Ministry of Education, Taiyuan University of Technology, Taiyuan, Shanxi 030024, P. R. China

Доп.точки доступа:
Zhou, G.; Wang, Y.; Mao, Y.; Guo, C.; Zhang, J.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Xia, Z.; Zhang, X.-M.
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    Solid state synthesis, structural, DFT and spectroscopic analysis of EuAl3(BO3)4 / A. S. Oreshonkov, A. S. Aleksandrovsky, O. D. Chimitova [et al.] // Mater. Chem. Phys. - 2024. - Vol. 320. - Ст. 129400, DOI 10.1016/j.matchemphys.2024.129400. - Cited References: 55. - The work was carried out within the state assignment No FWES-2024-0003 of Kirensky Institute of Physics. This work was partially supported by the state order of BINM SB RAS (0273-2021-0008). The samples for this research were synthesized using equipment of the CCU BINM SB RAS. The reflectance spectrum was obtained at the Center for Optical and Laser Materials Research of Research park of St. Petersburg State University. The SEM measurements were performed at Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" . - ISSN 0254-0584. - ISSN 1879-3312
   Перевод заглавия: Твердофазный синтез, структурный, квантово-химический (DFT) и спектроскопический анализ EuAl3(BO3)4
Кл.слова (ненормированные):
EuAl(BO) -- Huntite -- X-ray diffraction -- SEM -- DFT -- Charge transfer -- Raman -- Infrared -- Luminescence
Аннотация: Huntite-like borates are versatile and promising materials with wide range of applications in frequency conversion, UV light generation, lighting, displays, quantum information storage, and more, demonstrated by their various properties and uses in scientific research. In this work, EuAl3(BO3)4 powder was prepared through multi-stage solid-state reaction method using high-purity starting reagents: Eu2O3, Al2O3 and H3BO3, considering a 20 wt% excess of H3BO3 to compensate for B2O3 volatilization. Obtained samples undergo several treatments at varying temperatures and their phase purity is subsequently verified through powder X-ray diffraction analysis. The scanning electron microscopy reveals that resulting EuAl3(BO3)4 powder consists of granules exhibiting irregular morphologies with dimensions of 0.5–8 μm. The electronic band structure of EuAl3(BO3)4, calculated using the GGA PBE method, reveals f-states of Eu near 4 eV. These states do not produce emphasized peaks on simulated absorbance spectra. Using of DFT + U for the f-states of Eu pushed up f-bands above 6 eV and the charge transfer from p-O to d-Eu was obtained (Egdirect = 5.63 eV, Egindirect = 5.37 eV using Ueff = 4 eV). The variation of Ueff has a weak influence on the position of the bottom of the conduction band. The experimental bandgaps of EuAl3(BO3)4 crystalline powder, both direct and indirect, are found to be 3.96 and 3.67 eV, correspondingly. These values are lower than theoretical values what is associated with limitations of DFT calculations involving f electrons. The Raman spectrum of EuAl3(BO3)4 powder is discussed, detailing the contributions of different ions to specific spectral bands. Investigation of high-resolution luminescence spectra shows the possibility to estimate the content of defects by the testing the violation of the prohibition of ultranarrow 5D0 → 7F0 line that is forbidden in the ideal crystalline structure of trigonal EuAl3(BO3)4.

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Держатели документа:
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
School of Engineering and Construction, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Oxide Systems, Baikal Institute of Nature Management, SB RAS, Ulan-Ude, 670047, Russia
Center for Optical and Laser Materials Research, Saint-Petersburg State University, Saint-Petersburg, 199034, Russia
Emanuel Institute of Biochemical Physics of Russian Academy of Sciences, Moscow, 119334, Russia
Plekhanov Russian University of Economics, Moscow, 117997, Russia
Moscow Institute of Physics and Technology, Dolgoprudny, 141700, Russia
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
School of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russia
Institute of Automation and Electrometry, Russian Academy of Sciences, Novosibirsk, 630090, Russia
Department of Molecular Electronics, Federal Research Center Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, 660036, Russia
Institute of Fundamental Biology and Biotechnology, Siberian Federal University, Krasnoyarsk, 660041, Russia

Доп.точки доступа:
Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chimitova, O.D.; Pankin, D.V.; Popov, Z.I.; Sukhanova, E.V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Adichtchev, S.V.; Pugachev, A.M.; Nemtsev, I. V.; Немцев, Иван Васильевич
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Solid solution structural engineering enhances the luminescence of SrMgAl10O17:Cr3+ for agricultural lighting / Y. Ma, W. Liao, B. Quan [et al.] // J. Lumin. - 2024. - Vol. 270. - Ст. 120553, DOI 10.1016/j.jlumin.2024.120553. - Cited References: 46. - The authors would like to gratefully acknowledge funds from the Key R & D Projects in Hunan Province (2021SK2047, 2022NK2044), the Wangcheng Science and Technology Plan (KJ221017), the Science and Technology Innovation Program of Hunan Province (2022WZ1022). The work was supported by the Ministry of Science and Higher Education of the Russian Federation as part of the World-class Research Center program: ‘‘Advanced Digital Technologies’’, contract no. 075-15-2020-935. Research Foundation of Education Bureau of Hunan Province, China (22B0211) . - ISSN 0022-2313. - ISSN 1872-7883
Кл.слова (ненормированные):
Optical material -- Indoor plant cultivation -- Far-red light -- SrMgAlO
Аннотация: Lead-free non-rare earth oxide phosphors have attracted wide attention due to their environmental protection, sustainability, and potential to replace halides and fluorides in the field of plant lighting. Among them, the Cr3+-excited aluminate phosphor exhibits high brightness, high thermal stability, and far red to near-infrared (NIR) emission due to the influence of the crystal field strength (CFS). This property gives rise to a variety of strategies used to modulate the CFS, for example, single ion substitution, chemical unit co-substitution, etc. Here, we chose the substitution of a single ion, with [BaO6] gradually replacing [SrO6] to form a solid solution. Their structural characteristics and the local structure of Cr3+ are studied and discussed. The device is packaged to evaluate the feasibility of the material for practical application. The prepared phosphor had a bright far-red light emission of 693 nm under blue light excitation, and this spectrum strongly matched the absorption of plant phytochrome PFR. This work provides the design principle of far red light emission activated by Cr3+ aluminate solid solution, which can inspire further research on pc-LED lights for plant lighting.

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Держатели документа:
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, PR China
Hunan Optical Agriculture Engineering Technology Research Center, Changsha 410128, PR China
World-Class Research Center “Advanced Digital Technologies”, University of Tyumen, Tyumen 625003, Russia
Dongguan Ledstar Optoelectronics Technology Co., Ltd, Dongguan, 523000, PR China

Доп.точки доступа:
Ma, Y.; Liao, W.; Quan, B.; Kong, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zolotov, A.; Cheng, M.; Chen, X.; Zhou, Zh.; Xia, M.
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Achieving ultra-broadband sunlight-like emission in single-phase phosphors: The interplay of structure and luminescence / Sh. Liu, L. Li, X. Qin [et al.] // Adv. Mater. - 2024. - Ст. 2406164, DOI 10.1002/adma.202406164. - Cited References: 43. - S.L. and L.L. contributed equally to this work. This work was ﬁnancially supported by grants from the National Natural Science Foundationof China (NSFC, No. 52272174) and its joint project with Guangdong(Nos. U22A20135, U1801253 and U1301242) Province. J. Wang acknowl-edges Southern Marine Science and Engineering Guangdong Laboratory(Zhuhai) projects SML2021SP204, SML2023SP215/218/238. The authorsare grateful to Prof. Peter A. Tanner and Prof. Ka-Leung Wong for the indepth communication and valuable advice on the improvement of the manuscript. - Open access funding provided by Ecole Polytechnique Federale de Lausanne . - Article in press. - ISSN 0935-9648. - ISSN 1521-4095
Кл.слова (ненормированные):
artificial light source -- Ca9LiMg1-xAl2x/3(PO4)7:0.1Eu2+ -- convolutional neural network analysis -- mimicking sunlight -- portable photodetection devices
Аннотация: The quest for artificial light sources mimicking sunlight has been a long-standing endeavor, particularly for applications in anticounterfeiting, agriculture, and color hue detection. Conventional sunlight simulators are often cost-prohibitive and bulky. Therefore, the development of a series of single-phase phosphors Ca9LiMg1-xAl2x/3(PO4)7:0.1Eu2+ (x = 0-0.75) with sunlight-like emission represents a welcome step towards compact and economical light source alternatives. The phosphors are obtained by an original heterovalent substitution method and emit a broad spectrum spanning from violet to deep red. Notably, the phosphor with x = 0.5 exhibits an impressive full width at half-maximum of 330 nm. A synergistic interplay of experimental investigations and theory unveils the mechanism behind sunlight-like emission due to the local structural perturbations introduced by the heterovalent substitution of Al3+ for Mg2+, leading to a varied distribution of Eu2+ within the lattice. Subsequent characterization of a series of organic dyes combining absorption spectroscopy with convolutional neural network analysis convincingly demonstrates the potential of this phosphor in portable photodetection devices. Broad-spectrum light source testing empowers the model to precisely differentiate dye patterns. This points to the phosphor being ideal for mimicking sunlight. Beyond this demonstrated application, the phosphor's utility is envisioned in other relevant domains, including visible light communication and smart agriculture.

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Держатели документа:
School of Chemical Engineering and Technology/School of Marine Sciences, Sun Yat-sen University, Zhuhai 519082, P. R. China
College of Materials, Xiamen University, Xiamen 361005, P. R. China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center SB RAS, Akademgorodok 50 bld.38, Krasnoyarsk 660036, Russia
International Research Center of Spectroscopy and Quantum Chemistry-IRC SQC, Siberian Federal University, 79 Svobodny Ave, Krasnoyarsk 660041, Russia
Institute of Sustainability for ChemicalsEnergy and Environment (ISCE2) Agency for ScienceTechnology and Research (A*STAR), 1 Pesek Road, Jurong Island 627833, Singapore
Institute of Chemical Sciences and Engineering Swiss Federal Institute of Technology Lausanne (EPFL), Lausanne, Switzerland

Доп.точки доступа:
Liu, Sh.; Li, L.; Qin, X.; Du, R.; Sun, Y.; Xie, Sh.; Wang, J.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Xi, Sh.; Bunzli, J.-C. G.; Zhou, L.; Wu, M.
}
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    Synergetic manipulation of components and multiple activator sites towards full-spectrum lighting in Eu2+-doped whitlockite phosphors for high color-rendering WLED / H. Chen, Z. Zhang, R. Mi [et al.] // J. Lumin. - 2024. - Vol. 275. - Ст. 120795, DOI 10.1016/j.jlumin.2024.120795. - Cited References: 47. - We acknowledge the financial support from the National Natural Science Foundation of China (Grant No. 52104272 and 52072348), the Young Elite Scientists Sponsorship Program by CAST (2024QNRC001) and the Program National Key R&D Program of China (2021YFC1910602-01) . - ISSN 0022-2313. - ISSN 1872-7883
   Перевод заглавия: Синергетическое манипулирование составом и множеством позиций активаторов для обеспечения широкоспектрального освещения в витлокитовых люминофорах, легированных Eu2+, для высокой цветопередачи белых светодиодов
Кл.слова (ненормированные):
Components regulation -- Multi-site occupancies -- Whitlockite phosphors -- Eu -- High color rendering
Аннотация: Tuning the components and multiple activator sites possesses profound significances on the regulation for corresponding luminescent properties of target phosphors. However, it is still challenging to realize full-visible emission via single activator in a single phase owing to the matrix diversity and uncertainty for multi-site occupation. Herein, we developed a family of whitlockite-type solid-solution phosphors Ca8MgGa1-yLay(PO4)7: Eu2+(y = 0–1) via inducing the La3+ ions into Ca8MgGa(PO4)7:Eu2+. The local environments of Eu2+ ions and corresponding tunable photoluminescent properties, decay times and thermal stability are revealed systematically in detail. Specially, the excitation and emission spectra of Ca8MgGa1-yLay(PO4)7: Eu2+ are broadened gradually, finally towards a full-visible emission with 152 nm bandwidth spectrum for the phosphor Ca8MgLa(PO4)7: Eu2+. WLED with a high color rendering index (CRI = 95) and low color temperature (CCT = 3764 K) was fabricated based on the full-visible emission Ca8MgGa0.2La0.8(PO4)7: 0.08Eu2+ phosphors under a 365 nm chip, indicating the prominent potentials for high-color-rendering WLEDs. These results in current work provide new ideas for synergetic manipulation of components and multiple activator sites towards a full-visible emission in single-phase applied for white lighting.

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Держатели документа:
Engineering Research Center of Ministry of Education for Geological Carbon Storage and Low Carbon Utilization of Resources, Beijing Key Laboratory of Materials Utilization of Nonmetallic Minerals and Solid Wastes, National Laboratory of Mineral Materials, School of Materials Science and Technology, China University of Geosciences (Beijing), 100083, China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Siberian Federal University, Krasnoyarsk, 660041, Russia
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russia
School of Chemical and Environmental Engineering, Anhui Polytechnic University, Wuhu, 241000, China

Доп.точки доступа:
Chen, H.; Zhang, Z.; Mi, R.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Liu, Yu.; Wang, B.; Mei, L.; Fang, M.; Wu, X.; Min, X.; Liu, Ya.
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Photophysical properties of luminophores based on 3-(1,3-benzothiazol-2-yl)-4-hydroxybenzenesulfonic acid / E. V. Parfenova, N. V. Slyusarenko, S. V. Kulagin [et al.] // Bull. Russ. Acad. Sci.: Phys. - 2024. - Vol. 88, Is. 6. - P. 940-945, DOI 10.1134/S1062873824706858. - Cited References: 25. - The authors are grateful to OLBO Company for the presented samples. - The work was supported by the Priority 2030 Program, the project "Design of New Luminescent Materials for Multifunctional Purposes", and the Grant Council of the President of the Russian Federation (project no. MK-995.2022.1.2) . - ISSN 1062-8738. - ISSN 1934-9432
Кл.слова (ненормированные):
luminophores -- anomalously large Stokes shift -- excited state intramolecular proton transfer -- luminescence -- quantum yield -- quantum chemical calculation -- density functional theory -- electronic spectrum
Аннотация: Water-soluble organic luminophores based on 3-(1,3-benzothiazol-2-yl)-4-hydroxybenzenesulfonic acid were studied both experimentally and by density functional theory for the first time. Because of peculiarities in chemical structure, one of them has a large Stokes shift, which results from excited state intramolecular proton transfer.

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Держатели документа:
Siberian Federal University, Krasnoyarsk, 660041 Russia
OLBO, Moscow, 107143 Russia
Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Scientific Center”, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036 Russia

Доп.точки доступа:
Parfenova, E. V.; Slyusarenko, N. V.; Kulagin, S. V.; Rogova, A. V.; Tomilin, F. N.; Томилин, Феликс Николаевич; Slyusareva, E. A.
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    Unveiling temperature-induced structural phase transition and luminescence in Mn2+-doped Cs2NaBiCl6 double perovskite / S. Banerjee, S. Saikia, M. S. Molokeev, A. Nag // Chem. Mater. - 2024. - Vol. 36, Is. 9. - P. 4750-4757, DOI 10.1021/acs.chemmater.4c00514. - Cited References: 49. - Authors acknowledge Dr. Arup Rath’s lab NCL Pune and SAIF-IIT Bombay for diffuse reflectance spectroscopy and ICP-AES measurements, respectively. A.N. acknowledges Science & Engineering Research Board, India, for Swarnajayanti Fellowship (SB/SJF/2020-21/02), and BRICS grant (e-27558) of the Department of Science and Technology, India. Authors acknowledge the Department of Science and Technology India (FIST program, SR/FST/CS-II/2019/105) for temperature-dependent powder XRD and EPR data. S.B. is grateful to IISER Pune for a research fellowship. S.S. acknowledges Prime Minister’s Research Fellowship (PMRF), Ministry of Education, India. M.M. acknowledges the Russian Science Foundation, grant 24-43-00006 . - ISSN 0897-4756. - ISSN 1520-5002
   Перевод заглавия: Обнаружение температурно-индуцированного структурного фазового перехода и люминесценции в двойном перовските Cs2NaBiCl6, легированном Mn2+
Аннотация: Halide double perovskites like Cs2NaBiCl6 are good host materials for luminescent dopants like Mn2+. The nature of photoluminescence (PL) depends on the local structure around the dopant ion, and doping may sometimes influence the global structure of the host. Here, we unveil the correlation between the temperature-induced (global) structural phase transition of Mn2+-doped Cs2NaBiCl6 with the local structure and PL of the Mn2+ dopant. X-ray diffraction analysis shows Mn2+-doped Cs2NaBiCl6 is in a cubic (Fm3m) phase between 300 and 110 K, below which the phase changes to tetragonal (I4/mmm), which persists at least until 15 K. The small (∼1%) doping amount does not alter the phase transition behavior of Cs2NaBiCl6. Importantly, the phase transition does not influence the Mn2+ d-electron PL. The PL peak energy, intensity, spectral width, and lifetime do not show any signature of the phase transition between 300–6 K. The hyperfine splitting in temperature-dependent electron paramagnetic spectra of Mn2+ ions also remain unchanged across the phase transition. These results suggest that the global structural phase transition of the host does not influence the local structure and emission property of the dopant Mn2+ ion. This structure–property insight might be explored for other transition-metal- and lanthanide-doped halide double perovskites as well. The stability of dopant emission regardless of the structural phase transition bodes well for their potential applications in phosphor-converted light emitting diodes.

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Держатели документа:
Department of Chemistry, Indian Institute of Science Education and Research (IISER), Pune, 411008, India
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Institute of Engineering Physics and Radioelectronic, Siberian Federal University, Krasnoyarsk, 660041 Russia

Доп.точки доступа:
Banerjee, S.; Saikia, S.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Nag, A.
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10.

Near-unity PLQY and high anti-thermal quenching red luminescence from one-dimensional hybrid manganese chloride for efficient and stable white light-emitting diodes / B. Su, M. S. Molokeev, R. Chen, T. Zhang // J. Mater. Chem. C. - 2024, DOI 10.1039/D4TC01477D. - Cited References: 46 . - Article in press. - ISSN 2050-7526. - ISSN 2050-7534
Аннотация: The discovery of novel Mn2+-based metal halides with excellent luminescence properties and thermostability is particularly of great importance for solid-state lighting (SSL). Herein, a novel one-dimensional hybrid manganese chloride (TMA)MnCl3 of a hexagonal system with a P63/m space group is synthesized via a simple saturation crystallization method. Under 443 nm excitation, (TMA)MnCl3 single crystals exhibit a strong broad-band red emission peak at 645 nm originating from the 4T1 → 6A1 transition of Mn2+ ions with a full width at half maximum of 99 nm and a photoluminescence quantum yield (PLQY) of 98.6%. Moreover, (TMA)MnCl3 shows a high anti-thermal quenching behavior, and the integrated PL intensity still retains 100% of the initial intensity measured at 300 °C, caused by the high structural rigidity. Benefiting from its strong blue light excitation, high PLQY, and excellent thermal stability, a stable white light-emitting diode device is fabricated by combining a 465 nm blue LED chip, green-emitting Lu3Al5O12:Ce3+ and the (TMA)MnCl3 red phosphor with a high color rendering index of 94.3% and a correlated color temperature of 3995 K. This work develops a novel hybrid manganese chloride red-emitter and paves a new path to explore high-performance phosphors excited by blue light for SSL.

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Держатели документа:
School of Materials Science and Engineering, Xi’an University of Science and Technology, Xi’an, Shaanxi, P. R. China
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Department of Engineering Physics and Radioelectronics, Siberian Federal University, Krasnoyarsk 660041, Russia
Research and Development Department, Kemerovo State University, Kemerovo, Russia

Доп.точки доступа:
Su, B.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Chen, R.; Zhang, T.
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