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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Tarasov I. A., Visotin M. A., Solovyov L. A., Fedorov A. S., Yakovlev I. A., Tarasov A. S., Varnakov S. N., Ovchinnikov S. G.
Заглавие : A way for targeted synthesis of higher manganese silicides: a new Mn17Si30 phase and its distinctive features
Коллективы : Nanostructures: Physics and Technology, International Symposium, Институт физики им. Б. И. Степанова НАН Беларуси, Санкт-Петербургский национальный исследовательский Академический университет Российской академии наук, Физико-технический институт им. А.Ф. Иоффе РАН, Научно-технологический центр микроэлектроники и субмикронных гетероструктур Российской академии наук
Место публикации : Nanostructures: physics and technology: proc. 26th Int. symp. - 2018. - P.209-210. - ISBN 978-985-7202-35-5
Примечания : Cited References: 3
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Tarasov I. A., Visotin M. A., Kuznetsova T. V., Solovyov L. A., Fedorov A. S., Yakovlev I. A., Tarasov A. S., Varnakov S. N., Ovchinnikov S. G.
Заглавие : A way for targeted synthesis of higher manganese silicides: a new Mn17Si3O phase and its distinctive features
Коллективы : Federal Research Center KSC SB RAS, Kirensky Institute of Physics, Research Institute of Agriculture and Ecology of the Arctic, Siberian Federal Univercity
Место публикации : International school/workshop on actual problems of condensed matter physics: Program. Book of abstracts/ ed. S. G. Ovchinnikov. - Norilsk, 2018. - P.14-15. - ISBN 978-5-904603-08-3
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhandun V. S., Nemtsev A. V.
Заглавие : Ab initio comparative study of the magnetic, electronic and optical properties of AB2O4 (A, B= Mn, Fe) spinels
Место публикации : Mater. Chem. Phys. - 2021. - Vol. 259. - Ст.124065. - ISSN 0254-0584 (ISSN), DOI 10.1016/j.matchemphys.2020.124065. - ISSN 1879-3312 (eISSN)
Примечания : Cited References: 32. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research project № 19-42-240016: «Control of structural, magnetic, electronic, and optical properties by pressure and intercalation into functional compounds with a spinel structure containing 3d and 4f ions » The calculations were performed with the computer resources of “Complex modeling and data processing research installations of mega-class” SRC “Kurchatovsky Institute” (http://ckp.urcki.ru)
Аннотация: The comparison of the magnetic, electronic, and optical properties of the spinel transition-metal oxides AB2O4 (A, B = Fe, Mn) and their relationship with the structure and composition were studied within DFT-GGA + U approximation. The spinels were considered both in the normal and inverse structure. We have found that regardless of composition and structure, the studied spinels are ferrimagnetic with antiparallel magnetic moments on A- and B-site cations. Electronic and structural properties of spinels depend on the composition: FeMn2O4 has a tetragonal structure and half-metallic properties; however, in the inverse FeMn2O4, the bandgap opens for the spin-up channel. MnFe2O4 is a cubic insulator with a bandgap of about 1.5 eV, which decreases in the inverse structure. The superexchange constants estimate within the simple indirect coupling model and have values close to the experimental ones. The total magnetization of FeMn2O4 is drop-down to zero under hydrostatic pressure above 60 GPa due to the strong dependence of the magnetic moment of octahedral manganese ion on the pressure. The microscopic mechanisms of the relationship between the structure, composition and properties are studied.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Nemtsev A. V., Zhandun V. S., Zinenko V. I.
Заглавие : Ab initio study of the polarization, electronic, magnetic, and optical properties of perovskite SrMO3 (M = Fe, Mn) crystals and thin films containing magnetic ions
Место публикации : J. Exp. Theor. Phys. - 2018. - Vol. 126, Is. 4. - P.497-505. - ISSN 10637761 (ISSN), DOI 10.1134/S1063776118030056
Примечания : Cited References: 30
Ключевые слова (''Своб.индексиров.''): antiferromagnetism--density functional theory--electronic properties--iron compounds--manganese compounds--optical properties--perovskite--perovskite solar cells--polarization--strontium compounds
Аннотация: The magnetic, electronic, and polarization properties of the SrFeO3 and SrMnO3 compounds with a perovskite structure are calculated using the density functional theory in the bulk and thin-film states. A ferroelectric instability is found to be absent in the bulk state, and the polar mode is softened in the thin-film state of SrMnO3 in the presence of tensile stresses in the substrate. As a result, a polar phase with a polarization of 23 μC/cm2 appears, which agrees with experimental data. The study of the magnetic and electronic properties demonstrates the existence of G-type antiferromagnetic ordering in SrMnO3 and the appearance of a dielectric gap of about 1.5 eV in its thin film. A ferromagnetic phase with metallic conduction in both the bulk and thin-film states is detected in SrFeO3.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vasilyeva I. G., Dovlitova L. S., Zaikovskii V. I., Malakhov V. V., Edel'man I. S., Stepanov A. S., Aleksandrov K. S.
Заглавие : Actual composition and structure of manganese ferrite nanoparticles dispersed in the borate glass matrix
Место публикации : Doklady Chemistry. - 2005. - Vol. 401, Is. 1-3. - P.47-50. - ISSN 0012-5008, DOI 10.1007/s10631-005-0029-y
Ключевые слова (''Своб.индексиров.''): boric acid--ferrite--glass--manganese derivative--analytic method--article--chemical composition--chemical structure--nanoparticle--stoichiometry--structure analysis--transmission electron microscopy--x ray analysis
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gavrichkov V. A., Ovchinnikov S. G.
Заглавие : An impurity resistivity of doped manganese perovskites
Место публикации : Physica B: ELSEVIER SCIENCE BV, 1999. - Vol. 259-61: International Conference on Strongly Correlated Electron Systems (SCES 98) (JUL 15-18, 1998, PARIS, FRANCE). - P828-830. - ISSN 0921-4526, DOI 10.1016/S0921-4526(98)00875-8
Примечания : Cited References: 4
Предметные рубрики:
Ключевые слова (''Своб.индексиров.''): manganese perovskites--mobility--linear and quadratic magnetoresistance
Аннотация: We present a two-time of relaxation approach at an analysis of a magnetoresistance in ferromagnetic manganese perovskites La(1-x)(Ca,Sr)(x)MnO. To explain a change in the low-held response from predominantly quadratic dR/dH\(H--0) = 0 for T T(c) to linear dR/dH\(H--0) for T T(c) as noted in the measurements in thin films La(0.7)Ca(0.3)MnO(3) we calculated held and temperature dependences of a impurity contribution to a carrier mobility in a framework of the 2p(O)- and 3d(Mn)-scattering model elaborated for manganese perovskites. We obtained the field-dependent impurity contribution to the overall scattering of carriers that show a transition in the low-field (H) dependence of R from quadratic above T(c) to linear below consistent with an experiment. The calculated negative magnetoresistance ratio is sharply peaked at a temperature-near T(c) or below. (C) 1999 Elsevier Science B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Eremin E. V., Volkov N. V., Sablina K. A., Bayukov O. A., Molokeev M. S., Komarov V. Y.
Заглавие : Analysis of the exchange magnetic structure in Pb3Mn7O15
Место публикации : J. Exp. Theor. Phys.: Maik Nauka-Interperiodica Publishing, 2017. - Vol. 124, Is. 5. - P.792-804. - ISSN 10637761 (ISSN), DOI 10.1134/S1063776117040112
Примечания : Cited References: 16
Ключевые слова (''Своб.индексиров.''): crystallography--magnetic properties--magnetic structure--magnetism--manganese--indirect couplings--manganese ions--structural and magnetic properties--single crystals
Аннотация: The indirect-coupling model is used to analyze the exchange magnetic structure of Pb3Mn7O15 in the hexagonal setting. The ratios of manganese ions Mn4+/Mn3+ in each nonequivalent position are determined. Pb3(Mn0.95Ge0.05)7O15 and Pb3(Mn0.95Ga0.05)7O15 single crystals are grown by the solution–melt method in order to test the validity of the proposed model. The structural and magnetic properties of the single crystals are studied. The magnetic properties of the grown single crystals are compared with those of nominally pure Pb3Mn7O15. © 2017, Pleiades Publishing, Inc.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Petrakovskii G. A., Ryabinkina L. I., Abramova G. M., Velikanov D. A., Bovina A. F.
Заглавие : Antiferromagnet-ferromagnet transition in alpha-MnxS manganese sulfides
Разночтения заглавия :авие SCOPUS: Antiferromagnet-ferromagnet transition in α-MnxS manganese sulfides; авие SCOPUS: Antiferromagnet-ferromagnet transition in ?-MnxS manganese sulfides
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2001. - Vol. 43, Is. 3. - P493-495. - ISSN 1063-7834, DOI 10.1134/1.1356126; Phys. Solid State. - 2001. - Vol. 43, Is. 3. - P493-495. - Вариант Sopus
Примечания : Cited References: 7
Аннотация: Off-stoichiometric manganese monosulfides alpha -MnxS (1 less than or equal to x less than or equal to 1.25) are synthesized, and their crystal structure and magnetic properties are studied in the 4.2- to 300-K range. The compounds have a NaCl fcc lattice. Increasing the manganese ion concentration x in the antiferromagnetic semiconductors alpha -MnxS is found to result in concentration- (x(c) similar to 1.05) and temperature-driven (T-c similar to 50 K) magnetic transitions from the antiferromagnetic to ferromagnetic state, with the cubic structure remaining unchanged. (C) 2001 MAIK "Nauka/Interperiodica".
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Sitnikov M. N., Zhivul'ko A. M.
Заглавие : Change in the magnetocapacity in the paramagnetic region in a cation-substituted manganese selenide
Коллективы : Russian Foundation for Basic Research [17-32-50080, 16-52-00045 Bel_a, 3.5743.2017/6.7]
Место публикации : Phys. Solid State. - 2018. - Vol. 60, Is. 4. - P.673-680. - ISSN 1063-7834, DOI 10.1134/S1063783418040029. - ISSN 1090-6460(eISSN)
Примечания : Cited References:19. - This work is supported by the Russian Foundation for Basic Research (project no. 17-32-50080), grant no. 16-52-00045 Bel_a, and state task no. 3.5743.2017/6.7.
Предметные рубрики: MULTIFERROICS
Аннотация: The capacity and the dielectric loss tangent of a Gd x Mn1–xSe (x ≤ 0.2) solid solution have been measured in the frequency range 1–300 kHz without a magnetic field and in a magnetic field of 8 kOe in the temperature range 100–450 K, and the magnetic moment of the solid solution has been measured in a field of 8.6 kOe. The magnetocapacity effect and the change in the magnetocapacity sign have been observed in room temperature in the paramagnetic region. A correlation of the changes in the dielectric permittivity and the magnetic susceptibility with temperature has been revealed. The magnetocapacity is described using the model with orbital electron ordering and the Maxwell–Wagner model.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kosyrev N. N., Varnakov S. N., Tarasov I. A., Lyashenko S. A., Ovchinnikov S. G.
Заглавие : Characterization of manganese and iron silicides by in situ spectral generalized magneto-optical ellipsometry
Коллективы : Workshop Ellipsometry (7; 2012 ; март ; 5-7; Leipzig, Germany)
Место публикации : 7th Workshop on Ellipsometry: abstract book. - 2012. - P. - 82
Аннотация: Dilute magnetic semiconductors (DMS) combine the electronic transport properties of semiconductors and memory characteristics of magnetic materials. The complementary properties of semiconductor and ferromagnetic material can manipulate both degrees of freedoms of electrons0 spins and charges for spintronic devices. In recent years, group IV(Ge,Si)-based DMSs attract considerable experimental effort due to the compatibility with mainstream silicon technology. In ourworkwe present the investigation of structural,magnetic and optical properties ofmanganese and iron silicides thin films on Si (100) substrate by in situ spectral generalizedmagneto-optical ellipsometry. Themeasurementswere performed by spectral and laser ellipsometers (“Spectroscan“ and “LEF-71“ respectively by Institute Semiconductors Physics SB RAS), optimized tomeasure not only traditional ellipsometric parameters, but also magneto-optical response of the sample. The magnetoellipsometers were integrated into the ultrahigh vacuum chambers of molecular beam epitaxy setup, which allowed to control the optical and magnetic properties of thin films directly in the growth process. As a result of the magneto-optical response analysis, it was found that iron and manganese silicides in magnetic phase were formed on the Si surface and by analysis of the ellipsometric parameters dependence on evaporation time the silicide nanoclusters were identified and their structural properties were found. The work was supported by project 4.1 of the OFN RAS, project 27.10 of the Presidium RAS, integration project22 of SB RAS and FEB RAS, and also the FCP NK-744P/6 .
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Antonova A.B., Chudin O.S., Pavlenko N.I., Sokolenko W.A., Rubaylo A.I., Vasiliev A. D., Verpekin V.V., Semeikin O.V.
Заглавие : Chemistry of vinylidene complexes
Место публикации : Russ. Chem. Bull. - NEW YORK: SPRINGER, 2009. - Vol. 58, Is. 5. - С. 955-963. - MAY. - ISSN 1066-5285, DOI 10.1007/s11172-009-0122-3
Примечания : Cited Reference Count: 35. - Гранты: This work was financially supported by the Krasnoyarsk Regional Science Foundation (Grants Nos. 10TS145 and 17G002), the Council on Grants at the President of the Russian Federation (Program for State Support of Leading Scientific Schools, Grant NSh-4137.2006.2), and the Presidium of the Russian Academy of Sciences (Program for Basic Research, Project No. 18.18).Финансирующая организация: Krasnoyarsk Regional Science Foundation [10TS145, 17G002]; Council on Grants at the President of the Russian Federation [NSh-4137.2006.2]; Presidium of the Russian Academy of Sciences [18.18]
Предметные рубрики: RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE
PHENYLVINYLIDENE LIGANDS
BRIDGED COMPLEXES
TRANSITION-METALS
CARBONYL LIGAND
BINUCLEAR
DERIVATIVES
DINUCLEAR
RHENIUM
Ключевые слова (''Своб.индексиров.''): vinylidene complexes--heterometallic complexes--manganese--rhenium--palladium--platinum--ir and nmr spectroscopy--x-ray diffraction study--heterometallic complexes--ir and nmr spectroscopy--manganese--palladium--platinum--rhenium--vinylidene complexes--x-ray diffraction study
Аннотация: The reactions of Cp(CO)(2)Re=C=CHPh (2) with M(PPh(3))(4) (M = Pd, Pt) gave the mu-vinylidene complexes Cp(CO)(2)RePd(mu-C=CHPh)(PPh(3))(2) (3) and Cp(CO)(2)RePt(mu-C=CHPh)(PPh(3))(2) (1), respectively. The substitution of Ph(2)PCH(2)PPh(2) (dppm) for the PPh(3) ligands in 1 resulted in the formation of Cp(CO)RePt(mu-C(1)=C(2)HPh)(mu-CO)(dppm) (4). The structure of complex 4 has been determined by single-crystal X-ray diffraction analysis. The structural and spectroscopic characteristics of complexes 1, 3, and 4 were compared with the corresponding parameters of the manganese-containing analogs Cp(CO)(2)MnPd(mu-C=CHPh)(PPh(3))(2) (5), Cp(CO)(2)MnPt(mu-C=CHPh)(PPh(3))(2) (6) and Cp(CO)(2)MnPt(mu-C=CHPh)(dppm) (7).
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Antonova A. B., Chudin O. S., Vasiliev A. D., Rubaylo A. I., Verpekin V. V., Sokolenko W. A., Pavlenko N. I., Semeikin O. V.
Заглавие : Chemistry of vinylidene complexes. XX. Intramolecular carbonylation of vinylidene on the MnFe center: Spectroscopic and structural study. X-ray structure of the new trimethylenemethane type MnFe complex
Место публикации : J. Organomet. Chem.: Elsevier, 2011. - Vol. 696, Is. 4. - P.963-970. - ISSN 0022-328X, DOI 10.1016/j.jorganchem.2010.10.035
Примечания : Cited References: 52. - This work was partially supported by the Presidium of the Russian Academy of Sciences (Program for Basic Research, Project No. 7.18) and Russian Foundation for Basic Research (Grant No. 09-03-90745-mob_st). Authors are grateful to Prof. N.A. Ustynyuk for useful discussions, Dr. E.A. Shor and Dr. A.M. Shor for giving the data of quantum chemical study.
Предметные рубрики: MOLECULAR-STRUCTURE
ORGANOMETALLIC CHEMISTRY
TRICARBONYL COMPLEXES
UNSATURATED CARBENES
METAL VINYLIDENES
TRANSITION-METALS
ORGANIC-SYNTHESIS
CRYSTAL-STRUCTURE
IRON TRICARBONYL
MANGANESE
Ключевые слова (''Своб.индексиров.''): manganese--iron--carbonyl complexes--heteronuclear vinylidene complexes--intramolecular vinylidene carbonylation--trimethylenemethane complexes
Аннотация: Reactions of Fe-2(CO)(9) with Cp(CO)(2)Mn=C=CHPh (1) and Cp(CO)(PPh3)Mn=C=CHPh (3) gave the heterometallic trimethylenemethane complexes eta(4)-{C[Mn(CO)(2)Cp](CO)CHPh}Fe(CO)(3) (2) and eta(4)-{C[Mn(CO)(PPh3)Cp](CO)CHPh}Fe(CO)(3) (4), respectively. The formation of the benzylideneketene [PhHC=C=C=O] fragment included in complexes 2 and 4 occurs via intramolecular coupling of the carbonyl and vinylidene ligands. The structures of 3 and 4 were determined by single crystal XRD methods. The influence of the nature of the L ligands at the Mn atom on the structural and spectroscopic characteristics of eta(4)-{C[Mn(CO)(L)Cp](CO)CHPh}Fe(CO)(3) (L = CO (2), PPh3 (4)) is considered. According to the VT H-1 and C-13 NMR spectra, complex 2 reversibly transforms in solution into mu-eta(1):eta(1)-vinylidene isomer Cp(CO)(2)MnFe(mu-C=CHPh)(CO)(4) (2a), whereas complex 4 containing the PPh3 ligand is not able to a similar transformation. (C) 2010 Elsevier B.V. All rights reserved.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Verpekin V. V., Kondrasenko A. A., Chudin O. S., Vasiliev A. D., Burmakina G. V., Pavlenko N. I., Rubaylo A. I.
Заглавие : Chemistry of vinylidene complexes. XXIII. Binuclear rhenium-palladium vinylidene bridged complexes, their reactions with diiron nonacarbonyl
Место публикации : J. Organomet. Chem.: Elsevier Science, 2014. - Vol. 770. - P.42-50. - ISSN 0022-328X, DOI 10.1016/j.jorganchem.2014.07.024. - ISSN 1872-8561
Примечания : Cited References: 56. - This article is dedicated to the memory of Alla B. Antonova.
Предметные рубрики: TRANSITION-METAL-COMPLEXES
CATIONIC CARBYNE COMPLEXES
RAY CRYSTAL-STRUCTURE
MOLECULAR-STRUCTURE
HETEROBIMETALLIC COMPLEXES
LIGANDS
MANGANESE
CLUSTERS
DINUCLEAR
PD2CL2(MU-PH2PCH2PPH2)2
Ключевые слова (''Своб.индексиров.''): rhenium--palladium--iron--vinylidene complexes--heterometallic complexes
Аннотация: The reaction of [Cp(CO)2ReCCHPh] (1) with [Pd(PPh3)4] followed by the treatment of resulting [Cp(CO)2RePd(μ-CCHPh)(PPh3)2] (2) with diphosphines (dppe, dppp) gave new complexes [Cp(CO)2RePd(μ-CCHPh)(dppe)] (3) and [Cp(CO)2RePd(μ-CCHPh)(dppp)] (4). Treatment of the synthesized complexes with [Fe2(CO)9] led to mixtures of [Cp(CO)2ReFe(μ-CCHPh)(CO)4] (5), [(dppe)PdFe2(CO)8] (6), [CpReFe2(μ3-CCHPh)(CO)8] (7), [CpReFePd(μ3-CCHPh)(CO)5(dppe)] (8) and of 5, [(dppp)PdFe2(CO)8] (9), [CpReFePd(μ3-CCHPh)(CO)5(dppp)] (10), respectively. The main products of both reactions were trinuclear μ3-vinylidene clusters 8 and 10. Reactions of the trinuclear μ3-vinylidene ReFePd clusters 8 and 10 with Fe2(CO)9 were also studied. New complexes were characterized by IR, 1H, 13C, 31P NMR spectroscopy and cyclic voltammetry. The structure of [CpReFe2(μ3-CCHPh)(CO)8] was determined by single-crystal X-ray diffraction.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Verpekin V. V., Chudin O. S., Kondrasenko A. A., Burmakina G. V., Vasiliev A. D., Zimonin D. V., Rubaylo A. I.
Заглавие : Chemistry of vinylidene complexes—XXVII—new µ-vinylidene MnPt complexes with platinum-coordinated 1-adamantyl isocyanide ligand: spectroscopic, structural and electrochemical study
Место публикации : Transition Met. Chem. - 2022. - Vol. 47. Is. 7-8. - P.283-292. - ISSN 03404285 (ISSN), DOI 10.1007/s11243-022-00511-w
Примечания : Cited References: 46. - This work was conducted within the framework of the budget project 0287–2021-0012 for Institute of Chemistry and Chemical Technology SB RAS
Аннотация: New binuclear MnPt µ-vinylidene complexes Cp(CO)2Mn(µ-C=CHPh)Pt(CN–Ad)(L) [L=PPh3 (1a), P(OPri)3 (2a)] bearing a terminal platinum-coordinated 1-adamantyl isocyanide ligand were prepared by the treatment of Cp(CO)2Mn(µ-C=CHPh)Pt(CO)(L) [L=PPh3 (1b), P(OPri)3 (2b)] with CN-Ad. At the same time the reaction between Cp(CO)2Mn(µ-C=CHPh)Pt(L)2 [L=PPh3 (1c), P(OPri)3 (2c)] and CN-Ad did not proceed. The new complexes were characterized by IR and 1H, 13C, 31P NMR spectroscopy. The molecular structure of Cp(CO)2Mn(µ-C=CHPh)Pt(CN–Ad)[P(OPri)3] (2a) was determined by an X-ray diffraction study. The redox properties of the new complexes and their reactions of chemical oxidation were studied. An influence of the platinum-coordinated 1-adamantyl isocyanide ligand on the properties of the synthesized µ-vinylidene compounds 1a and 2a was revealed.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gavrichkov V. A., Ivanova N. B., Ovchinnikov S. G., Balaev A. D., Aminov T. G., Shabunina G. G., Chernov V. K., Petukhov M. V.
Заглавие : Comparison of negative magnetoresistance mechanisms in manganese perovskites and chromium spinels
Место публикации : Phys. Solid State: AMER INST PHYSICS, 1999. - Vol. 41, Is. 10. - P1652-1655. - ISSN 1063-7834, DOI 10.1134/1.1131064
Примечания : Cited References: 17
Предметные рубрики: ANISOTROPIC MAGNETORESISTANCE
TRANSPORT-PROPERTIES
THIN-FILMS
ALLOYS
Аннотация: A transition of the field dependence of the electrical resistivity from a square law (similar to H-2) above T-c to a linear function (similar to H) below T-c is observed in the degenerate ferromagnetic semiconductor HgCr2Se4(n). Together with the large negative magnetoresistance, these magnetoelectric effects correspond to effects observed in the perovskite-type oxides La1-xCaxMnOdelta. Inasmuch as the undoped semiconductor HgCr2Se4 is a ferromagnet with approximately the same critical temperature as the doped semiconductor and in view of the total lack of data on the Jahn-Teller effect in this compound, we infer that our results cast doubt on existing hypotheses (polaron and binary exchange) regarding the origin of the giant magnetoresistance in La1-xCaxMnOdelta. Impurity sd scattering is discussed as a possible magnetoresistance mechanism for both compounds. (C) 1999 American Institute of Physics. [S1063-7834(99)01710-4].
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova O. B., Sitnikov M. N., Loginov Yu. Yu., Abdelbaki H.
Заглавие : Concentration dependences of the structural, magnetic and kinetic properties of manganese chalcogenides doped with tellurium
Коллективы : Reshetnev Readings 2019
Место публикации : IOP Conf. Ser.: Mater. Sci. Eng. - 2022. - Vol. 1230. - Ст.012016. - ISSN 1757-8981 (ISSN), DOI 10.1088/1757-899X/1230/1/012016. - ISSN 1757-899X (eISSN)
Примечания : Cited References: 26. - The reported study was funded by RFBR according to the research project No 20-52-00005 Bel_a
Аннотация: The effect of anionic substitution on the structural, magnetic, and kinetic properties of chalcogenides of the MnSe1-XTeX system in the temperature range of 77-400K in magnetic fields up to 12 kOe was studied. With an increase in the substitution concentration, changes in the structural and magnetic characteristics, which correlate with changes in the electronic structure, were found. The type and mobility of the main current carriers were determined from the Hall effect measurements.
https://doi.org/10.1088/1757-899X/1230/1/012016
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17.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Romanova O. B., Aplesnin S. S., Sitnikov M. N., Kharkov A. M., Demidenko O. F., Galyas A. I., Yanyshkevich K. I.
Заглавие : Conductivity, structural and magnetic properties of manganese chalcogenide films under anionic substitution by tellurium
Коллективы : Moscow International Symposium on Magnetism, Московский государственный университет им. М.В. Ломоносова, Российский фонд фундаментальных исследований
Место публикации : Moscow International Symposium on Magnetism (MISM-2017): 1-7 July 2017 : book of abstracts. - 2017. - Ст.4PO-I1-30. - P.885 (Шифр 29916280)
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Ryabinkina L. I., Abramova G. M., Romanova O. B., Vorotynov A. M., Velikanov D. A., Kiselev N. I., Balaev A. D.
Заглавие : Conductivity, weak ferromagnetism, and charge instability in an alpha-MnS single crystal
Разночтения заглавия :авие SCOPUS: Conductivity, weak ferromagnetism, and charge instability in an α-MnS single crystal; авие SCOPUS: Conductivity, weak ferromagnetism, and charge instability in an ?-MnS single crystal
Место публикации : Phys. Rev. B: AMERICAN PHYSICAL SOC, 2005. - Vol. 71, Is. 12. - Ст.125204. - ISSN 1098-0121, DOI 10.1103/PhysRevB.71.125204; Phys. Rev. B Condens. Matter Mater. Phys. - 2005. - Vol. 71, Is. 12. - Ст.125204. - Вариант Sopus
Примечания : Cited References: 11
Предметные рубрики: MANGANITES
Ключевые слова (''Своб.индексиров.''): ferromagnetic material--manganese derivative--absorption spectroscopy--article--calculation--conductance--crystal--electron spin resonance--hybridization--magnetic field--magnetism--measurement--molecular interaction--temperature dependence--temperature measurement--ferromagnetic material--manganese derivative--absorption spectroscopy--article--calculation--conductance--crystal--electron spin resonance--hybridization--magnetic field--magnetism--measurement--molecular interaction--temperature dependence--temperature measurement
Аннотация: The temperature dependence of resistivity, magnetization, and electron-spin resonance of the α-MnS single crystal were measured in temperature range of 5 K T 550 K. Magnetization hysteresis in an applied magnetic field up to 0.7 T at T
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Molokeev M. S., Sterkhova I. V., Lesnikov M. K., Atuchin V. V.
Заглавие : Coordination effects in hydrated manganese(II) 1,3-diethyl-2-thiobarbiturates and their thermal stability
Место публикации : Polyhedron: Elsevier, 2017. - Vol. 134. - P.120-125. - ISSN 02775387 (ISSN), DOI 10.1016/j.poly.2017.06.002
Примечания : Cited References: 25
Ключевые слова (''Своб.индексиров.''): 1,3-diethyl-2-thiobarbituric acid--complexes--x-ray diffraction--infrared spectroscopy--manganese(ii)
Аннотация: Three new complexes of 1,3-diethyl-thiobarbituric acid (HDetba), barbiturate-bridged 2D Mn(II) polymer [Mn(H2O)2(Detba)2] (1), trinuclear [Mn3(H2O)10(Detba)6] (2) and discrete molecular [Mn(H2O)4(Detba)2]·H2O (3) are synthesized and structurally characterized by the X-ray single crystal technique. In 1–3, the Detba− ions are coordinated to Mn(II) only through O atoms with manganese ions in the octahedral environment. In 1, the Mn(II) ion is coordinated by four μ2 bridge Detba− ions and two terminal H2O molecules. In 2, the Mn1 ion is coordinated by three terminal H2O molecules, two terminal and one μ2 bridge Detba− ion, and Mn2 is connected with two μ2-Detba− ions and four H2O molecules. In 3, the Mn(II) ion is coordinated by two terminal Detba− ions and four terminal H2O molecules. There are intermolecular hydrogen bonds O–H⋯O, O–H⋯S in the structures of 1–3 which form the 3D networks. Structure 2 is stabilized by the π–π interaction. The compounds thermal decomposition comprises dehydration steps and the organic ligand oxidation.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Knyazev Yu.V., Ivanova N. B., Kazak N. V., Platunov M. S., Bezmaternykh L. N., Velikanov D. A., Vasiliev A. D., Ovchinnikov S. G., Yurkin G. Yu.
Заглавие : Crystal structure and magnetic properties of Mn substituted ludwigite Co3O2BO3
Место публикации : J. Magn. Magn. Mater.: Elsevier Science BV, 2012. - Vol. 324, Is. 6. - P.923-927. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2011.07.044
Примечания : Cited References: 15. - The study was supported by the Russian Foundation for Basic Research (Project no. 09-02-00171-a), the Federal Agency for Science and Innovation (Rosnauka) (Project no. MK-5632.2010.2), the Physical Division of the Russian Academy of Science, the program "Strongly Correlated Electrons", Project 2.3.1.
Предметные рубрики: BOND VALENT SUMS
COORDINATION CHEMISTRY
OXIDATION -STATE
O BONDS
COMPLEXES
MANGANESE
COBALT
Ключевые слова (''Своб.индексиров.''): transition metal oxyborate--distinct crystallographic position--spin glass magnetic ordering
Аннотация: The needle shape single crystals Co3−x MnxO2BO3 with ludwigite structure have been prepared. According to the X-ray diffraction data the preferable character of distinct crystallographic positions occupation by Mn ions is established. Magnetization field and temperature dependencies are measured. Paramagnetic Curie temperature value Θ=−100 K points out the predominance of antiferromagnetic interactions. Spin-glass magnetic ordering takes the onset at TN=41 K. The crystallographic and magnetic properties of Co3O2BO3:Mn are compared with the same for the isostructural analogs Co3O2BO3 and CoO2BO3:Fe.
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