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1.


   
    Structural and magnetic interplay in multiferroic Ho0.5Nd0.5Fe3(BO3)4 / A. Tripathy, K. Gautam, K. Dey [et al.] // Phys. Rev. B. - (ISSN). - 2023. - Vol. 107, Is. 21. - Ст. 214106, DOI 10.1103/PhysRevB.107.214106. - Cited References: 63. - A.T. and D.K.S. gratefully acknowledge financial support from the Department of Science and Technology (DST) in India for travel support through the India-DESY Collaboration for performing experiments at PETRA-III, DESY. D.K.S. acknowledges support from the DST, New Delhi, India, through Grant No. INI/RUS/RFBR/P-269 (DST-RSF project). The authors acknowledge K. Sharma for help during magnetization measurements . - ISSN 2469-9950. - ISSN 2469-9969
Аннотация: Rare-earth iron borates, RFe3(BO3)4 (R = rare earth), are of considerable interest because of their structural and magnetic complexities due to the involvement of both 3d and 4f magnetic interactions in a helical lattice. Among them Ho0.5Nd0.5Fe3(BO3)4 has attracted the most attention, as it exhibits a multiferroic property with a large, spontaneous, and magnetic-field-induced electric polarization (P) below the antiferromagnetic transition temperature (TN ~ 32 K). This compound has been reported to be noncentrosymmetric (nonpolar) down to the lowest temperature, and the origin of spontaneous electric polarization below TN is not known. By utilizing temperature-dependent synchrotron x-ray powder diffraction, we report here the observation of structural phase transition, i.e., the lowering of crystal symmetry from R32 to P3121 below TN in Ho0.5Nd0.5Fe3(BO3)4, which is further confirmed by single-crystal x-ray diffraction measurements as well as substantiated by dielectric and Raman spectroscopic results. With the help of x-ray resonant magnetic scattering, we have studied the element-specific magnetic ordering behavior, and by combining all the results, we show that the spontaneous electric polarization below the antiferromagnetic ordering transition emerges through the p-d hybridization mechanism associated with the FeO6 octahedra. The observations of subtle structural changes at low temperature and element-specific magnetic ordering behavior provide a comprehensive understanding of the multiferroicity in this family of compounds.

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Держатели документа:
UGC-DAE Consortium for Scientific Research, Indore 452001, India
Department of Physics, Aligarh Muslim University, Aligarh 202002, India
Accelerator Physics and Synchrotrons Utilization Division, Raja Ramana Centre for Advance Technology, Indore 452013, India
Homi Bhabha National Institute, Training School Complex, Anushakti Nagar, Mumbai 400094, India
Deutsches Elektronen-Synchrotron, Notkestrasse 85, D-22607 Hamburg, Germany
L. V. Kirensky Institute of Physics, Siberian Branch of Russian Academy of Sciences, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Tripathy, A.; Gautam, K.; Dey, K.; Sahu, S. R.; Ahad, A.; Upadhyay, A.; Sagdeo, A.; Francoual, S.; Bereciartua, P. J.; Gudim, I. A.; Гудим, Ирина Анатольевна; Strempfer, J.; Sathe, V. G.; Shukla, D. K.
}
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2.


   
    Magnetic ordering and chirality in multiferroic Dy1-xHoxMnO3 (x = 0.2) / A. N. Matveeva, I. A. Zobkalo, A. Sazonov [и др.] // Phys. B: Condens. Matter. - 2023. - Vol. 658. - Ст. 414821, DOI 10.1016/j.physb.2023.414821. - Cited References: 41. - The authors are grateful to D.A. Balaev for fruitful discussions and crystal growth management. This work was supported by the Russian Foundation for Basic Research grant # 19-52-12047, and DFG grant # SA3688/1-1, also by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research projects number 18-42-243024 and 20-42-243008. The neutron data were obtained at the instrument POLI operated jointly by RWTH Aachen University and Jülich Centre for Neutron Science within JARA cooperation . - ISSN 0921-4526. - ISSN 1873-2135
Кл.слова (ненормированные):
Neutron diffraction -- Crystal structure -- Multiferroics -- Magnetic structure -- Manganites
Аннотация: Effect of substitution Dy by Ho on the magneto-electric behavior of the compound Dy0.8Ho0.2MnO3 was investigated by the different methods of polarized and classical neutron diffraction and macroscopic methods. It is shown that substitution by Ho of 20% on the position of Dy do not change overall crystal symmetry of compound. It remains of Pbnm type down to the very low temperatures. Magnetic ordering, its temperature and field evolution was determined by the use of single crystal neutron diffraction and magnetization measurements. Chiral type of magnetic structure on Mn subsystem is confirmed below Tc ≈ 16 K. Using polarized neutron diffraction the 3-component character of rare earth magnetic ordering in Dy0.8Ho0.2MnO3 in contrast to DyMnO3 could be revealed. It was shown that doping by 20% Ho suppresses the spontaneous rare-earth ordering with its own propagation vector and provides the situation when two magnetic subsystems, manganese and rare earth ones have a coherent incommensurate spatial propagation. The influence of the external electric field on the magnetic chirality could be directly evidenced, proving strong magneto-electric coupling in multiferroic phase. The study of the electric polarization under similar temperatures and fields on the same samples provides the direct correlation between the results of the microscopic and macroscopic investigations.

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Держатели документа:
Petersburg Nuclear Physics Institute by B.P. Konstantinov of NRC «Kurchatov Institute», 188300, Gatchina, Russia
Institute of Crystallography, RWTH Aachen University and Jülich Centre for Neutron Science at Heinz Maier- Leibnitz Zentrum, Garching, Germany
Kirensky Institute of Physics, Federal Research Center, Krasnoyarsk, 660036, Russia
Siberian Federal University, Krasnoyarsk, 660041, Russia

Доп.точки доступа:
Matveeva, A. N.; Zobkalo, I. A.; Sazonov, A.; Freidman, A. L.; Фрейдман, Александр Леонидович; Semenov, S. V.; Семёнов, Сергей Васильевич; Kolkov, M. I.; Колков, Максим Игоревич; Terentjev, K. Yu.; Терентьев, Константин Юрьевич; Pavlovskiy, N. S.; Павловский, Николай Сергеевич; Shaykhutdinov, K. A.; Hutanu, V.
}
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3.


   
    Complex interplay between 3d and 4f magnetic systems in multiferroic DyMnO3 / A. N. Matveeva, I. A. Zobkalo, M. Meven [et al.] // J. Magn. Magn. Mater. - 2023. - Vol. 569. - Ст. 170415, DOI 10.1016/j.jmmm.2023.170415. - Cited References: 28. - The authors are grateful to S.V. Gavrilov for the technical assistance. This work was supported by the Russian Foundation for Basic Research grant # 19-52-12047, and DFG grant # SA 3688/1-1, also by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science to the research projects number 18-42-243024 and 20-42-243008. The neutron data were obtained at the instrument HEiDi operated jointly by RWTH Aachen University and Jülich Centre for Neutron Science within JARA cooperation . - ISSN 0304-8853
Кл.слова (ненормированные):
Neutron diffraction -- Crystal structure -- Multiferroics -- Magnetic structure -- Manganites
Аннотация: Structural and magnetic properties of single crystals of DyMnO3 were investigated by neutron diffraction in order to study the peculiarities of 3d-4f interactions in this compound. Precise magnetic order and its detailed temperature evolution were determined using single crystal neutron diffraction. Elliptical cycloid on manganese subsystem below TCh = 19 K was confirmed, with temperature decrease the elipticity of the Mn magnetic structure reduces significantly, creating almost circular cycloid. Temperature evolution of the magnetic structure demonstrate specific hysteretic behavior. The results show a complex interplay between transition metal and rare earth magnetic sublattices leading to so-called “Mn- controlled” and “Dy- controlled” magnetic states. The strong and complicate 3d-4f interaction leads to the unusual very slow magnetic structure relaxation.

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Держатели документа:
Petersburg Nuclear Physics Institute by B.P. Konstantinov of NRC «Kurchatov Institute», Gatchina, 188300, Russian Federation
Institute of Crystallography, RWTH Aachen University and Julich Centre for Neutron Science at Heinz Maier- Leibnitz Zentrum, Garching, Germany
Kirensky Institute of Physics, Federal Research Center, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Matveeva, A. N.; Zobkalo, I. A.; Meven, M.; Freidman, A. L.; Фрейдман, Александр Леонидович; Semenov, S. V.; Семёнов, Сергей Васильевич; Terentjev, K. Yu.; Терентьев, Константин Юрьевич; Pavlovskiy, N. S.; Павловский, Николай Сергеевич; Kolkov, M. I.; Колков, Максим Игоревич; Shaykhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Hutanu, V.
}
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4.


   
    Effect of uncontrolled impurities on magnetic and structural transitions of the GdFe3(BO3)4 multiferroic / I. A. Gudim, E. V. Eremin, A. S. Krylov, V. R. Titova // V International Baltic Conference on Magnetism. IBCM : Book of abstracts. - 2023. - P. 128. - Cited References: 3. - Support by RSF and KRFS № 22-12-20019 are acknowledged

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS

Доп.точки доступа:
Gudim, I. A.; Гудим, Ирина Анатольевна; Eremin, E. V.; Еремин, Евгений Владимирович; Krylov, A. S.; Крылов, Александр Сергеевич; Titova, V. R.; International Baltic Conference on Magnetism(5 ; 2023 ; Aug. 20-24 ; Svetlogorsk, Russia); Балтийский федеральный университет им. И. Канта
}
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5.


   
    Structure and properties of multiferroic ferroborates of mixed composition SmFe3-xAlx(BO3)4 and Eu1-yLayFe3(BO3)4 / K. V. Frolov, E. S. Smirnova, E. V. Sidorova [et al.] // Book of abstacts of Samarkand International Symposium on Magnetism (SISM-2023) / int. adv. com. S. G. Ovchinnikov [et al.]. - 2023. - Ст. 3PO-L8-3. - P. 195. - Cited References: 6. - РНФ 23-22-00286 . - ISBN 978-5-00202-320-2

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Держатели документа:
Kirensky Institute of Physics SB RAS

Доп.точки доступа:
Ovchinnikov, S. G. \int. adv. com.\; Овчинников, Сергей Геннадьевич; Frolov, K. V.; Smirnova, E. S.; Sidorova, E. V.; Alekseeva, O. A.; Sorokin, T. A.; Artemov, V. V.; Chmelenin, D. N.; Gudim, I. A.; Гудим, Ирина Анатольевна; Samarkand International Symposium on Magnetism(2023 ; July 2-6 ; Samarkand); Samarkand State University
}
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6.


   
    Magnetic circular dichroism of f-f transitions in multiferroic antiferromagnet Ho0.75Nd0.25Fe3(BO3)4 / A. V. Malakhovskii, V. V. Sokolov, A. L. Sukhachev, I. A. Gudim // International conference "Functional materials" : book of abstracts / ed. V. N. Berzhansky ; org. com. S. G. Ovchinnikov [et al.]. - Simferopol, 2023. - P. 100-101. - Cited References: 2

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Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS,

Доп.точки доступа:
Berzhansky, V. N. \ed.\; Бержанский, Владимир Наумович; Ovchinnikov, S. G. \org. com.\; Овчинников, Сергей Геннадьевич; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sokolov, V. V.; Соколов, Валерий Владимирович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; "Functional materials", International conference(2023 ; Oct. 2-6 ; Crimea, Foros); Крымский федеральный университет имени В.И. Вернадского
}
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7.


    Eremin, E. V.
    Magnetic properties of GdFe3(BO3)4 multiferroic grown from various melt solutions / E. V. Eremin, I. A. Gudim, V. R. Titova // V International Baltic Conference on Magnetism. IBCM : Book of abstracts. - 2023. - P. 76. - Cited References: 1. - РНФ № 22-12-20019 ; Красноярский регион. фонд науки

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS

Доп.точки доступа:
Gudim, I. A.; Гудим, Ирина Анатольевна; Titova, V. R.; Титова, Вероника Романовна; Еремин, Евгений Владимирович; International Baltic Conference on Magnetism(5 ; 2023 ; Aug. 20-24 ; Svetlogorsk, Russia); Балтийский федеральный университет им. И. Канта
}
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8.


   
    Phase transitions and p–T phase diagram of the multiferroic TbFe3(BO3)4 crystal / A. Krylov, M. Pavlovskiy, Y. Kitaev [et al.] // J. Raman Spectrosc. - 2022. - Vol. 53, Is. 6. - P. 1179-1187, DOI 10.1002/jrs.6341. - Cited References: 48. - Russian Foundation for Basic Research; RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, Grant/Award Number: 20-42-240009; Russian Foundation for Basic Research and DFG (Deutsche Forschungsgemeinschaft), Grant/Award Numbers: 448809307, 21-52-12018 . - ISSN 0377-0486. - ISSN 1097-4555
РУБ Spectroscopy
Рубрики:
BILBAO CRYSTALLOGRAPHIC SERVER
   RAMAN-SPECTRA

   HIGH-TEMPERATURE

Кл.слова (ненормированные):
ab initio calculation -- ferroborate -- multiferroic -- phase transitions -- p-T phase diagram
Аннотация: The structural phase transitions in multiferroic TbFe3(BO3)4 with change hydrostatic pressures and temperatures have been studied by Raman spectroscopy and calculation within density functional theory. Lattice dynamics calculations in the TbFe3(BO3)4 crystal in the 32 phase under various values of applied hydrostatic pressure (from 0 up to 5 GPa with 1 GPa step) were performed. The calculation performed in this work in a TbFe3(BO3)4 crystal showed that the applied pressure can increase the phase transition temperature. Raman spectra of the TbFe3(BO3)4 crystal have been investigated at simultaneously high temperature and high pressure (up to 5.14 GPa and 465 K). The appearance of a soft mode was observed with decreasing temperature at normal pressure. The manifestations of the interaction of the structural and magnetic order parameters in the range from 13 to 50 K were observed at normal pressure. With increasing pressure and a fixed temperature, recovery of the soft modes is also observed. The experimental p–T phase diagram of TbFe3(BO3)4 was established. An increase in pressure leads to an increase in the temperature of transition.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk, Russia.
Siberian Fed Univ, Photon & Laser Technol, Krasnoyarsk, Russia.
Ioffe Inst, Politekhnicheskaya 26, St Petersburg, Russia.
Huazhong Univ Sci & Technol, State Key Lab Mat Proc & Die & Mould Technol, Wuhan, Peoples R China.
Huazhong Univ Sci & Technol, Sch Mat Sci & Engn, Wuhan, Peoples R China.

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Pavlovskiy, M. S.; Павловский, Максим Сергеевич; Kitaev, Y.; Gudim, I. A.; Гудим, Ирина Анатольевна; Andryshin, N. D.; Андрюшин, Никита Дмитриевич; Vtyurin, A. N.; Втюрин, Александр Николаевич; Jiang, Qinghui; Krylova, S. N.; Крылова, Светлана Николаевна; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-42-240009]; Russian Foundation for Basic Research and DFG (Deutsche Forschungsgemeinschaft)German Research Foundation (DFG) [448809307, 21-52-12018]
}
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9.


   
    Crystal structure of bis­muth-containing NdFe3(BO3)4 in the temperature range 20–500 K / E. S. Smirnova, O. A. Alekseeva, A. P. Dudka [et al.] // Acta Crystallogr. B. - 2022. - Vol. 78, Pt. 1. - P. 1-13, DOI 10.1107/S205252062101180X. - Cited References: 44. - This work was performed using the equipment of the Shared Research Center FSRC `Crystallography and Photonics' RAS supported by the Russian Ministry of Science and Higher Education. This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC `Crystallography and Photonics' RAS . - ISSN 2052-5206
РУБ Chemistry, Multidisciplinary + Crystallography
Рубрики:
MAGNETIC PHASE-TRANSITIONS
   UNIT-CELL PARAMETERS

   DIFFRACTION

Кл.слова (ненормированные):
neodymium iron borate -- multiferroic -- crystal structure -- multi-temperature -- single-crystal X-ray diffraction -- Mossbauer spectroscopy -- characteristic temperature
Аннотация: Neodymium iron bor­ate NdFe3(BO3)4 is an intensively studied multiferroic with high electric polarization values controlled by a magnetic field. It is char­ac­ter­ized by a large quadratic magnetoelectric effect, rigidity in the base plane and a rather strong piezoelectric effect. In this work, the atomic structure of (Nd0.91Bi0.09)Fe3(BO3)4 was studied by single-crystal X-ray diffraction in the tem­per­ature range 20–500 K (space group R32, Z = 3). The Bi atoms found in the com­position partially substitute the Nd atoms in the 3a position; they entered the structure due to the growth conditions in the presence of Bi2Mo3O12. It was shown that in the tem­per­ature range 20–500 K there is no structural phase transition R32→P3121, which occurs in rare-earth iron bor­ates (RE = Eu–Er, Y) with an effective rare-earth cation radius smaller than that of Nd. The tem­per­ature dependence of the unit-cell c parameter reveals a slight increase on cooling below 90 K, which is similar to the results obtained previously for iron bor­ates of Gd, Y and Ho. The atomic distances (Nd,Bi)—O, (Nd,Bi)—B, (Nd,Bi)—Fe, Fe—O, Fe—B and Fe—Fe in the iron chains and between chains decrease steadily with decreasing tem­per­ature from 500 to 90 K, whereas the B1(3b)—O distance does not change and the average B2(9e)—O distance increases slightly. There is a uniform decrease in the atomic displacement parameters with decreasing tem­per­ature, with a more pronounced decrease for the Nd(3a) and O2(9e) atoms. The O2(9e) atoms are characterized by the maximum atomic displacement parameters and the most elongated atomic displacement ellipsoids. The characteristic Debye and Einstein tem­per­atures, and the static com­ponent in the atomic displacements were determined for cations using multi-tem­per­ature diffraction data. It was shown that the Nd cations have the weakest bonds with the surrounding atoms and the B cations have the strongest.

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Держатели документа:
Russian Acad Sci, Fed Sci Res Ctr Crystallog & Photon, Shubnikov Inst Crystallog, Moscow 119333, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Smirnova, E. S.; Alekseeva, O. A.; Dudka, A. P.; Verin, I. A.; Artemov, V. V.; Lyubutina, M. V.; Gudim, I. A.; Гудим, Ирина Анатольевна; Frolov, K. V.; Lyubutin, I. S.; Russian Ministry of Science and Higher Education; Ministry of Science and Higher Education within the State assignment FSRC 'Crystallography and Photonics' RAS
}
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10.


   
    Pressure–temperature phase diagram of multiferroic TbFe2.46Ga0.54(BO3)4 / A. Krylov, S. Krylova, I. Gudim [et al.] // Magnetochemistry. - 2022. - Vol. 8, Is. 6. - Ст. 59, DOI 10.3390/magnetochemistry8060059. - Cited References: 48. - The research of Krylov A. and Gudim I. was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-42-240009. This work of Vtyurin A., Krylova S. was financially supported by the Russian Foundation for Basic Research and DFG (Deutsche Forschungsgemeinschaft) project number No 21-52-12018. The experiments were performed in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” . - ISSN 2312-7481
   Перевод заглавия: Фазовая диаграмма температура-давление мультиферроика TbFe2.46Ga0.54(BO3)4
Кл.слова (ненормированные):
ferroborate -- phase transitions -- multiferroics -- p–T phase diagram
Аннотация: The pressure–temperature phase diagram of the multiferroic TbFe2.46Ga0.54(BO3)4 was studied for hydrostatic pressures up to 7 GPa and simultaneously with temperatures up to 400 K by the Raman spectroscopy technique. The structural phase transition from the R32 phase to the P3121 phase was determined by observing the condensation of soft modes and the appearance of new lines. An increase in pressure leads to an increase in the temperature of the structural phase transition. These phases are stable over the entire investigated temperature and pressure range. No other phases have been found.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Ioffe Institute, Politekhnicheskaya 26, St. Petersburg, 194021, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
State Key Laboratory of Material Processing and Die and Mould Technology, School of Materials Science and Engineering, Huazhong University of Science and Technology, Wuhan, 430074, China

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Krylova, S. N.; Крылова, Светлана Николаевна; Gudim, I. A.; Гудим, Ирина Анатольевна; Kitaev, Y.; Golovkina, E.; Zhang, H.; Vtyurin, A. N.; Втюрин, Александр Николаевич
}
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