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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Patrin G. S., Mataev M. M., Abdraimova M. R., Tursinova, Zh. I., Kezdikbaeva A. T., Shiyan Ya. G., Plekhanov V. G.
Заглавие : Magnetic properties of the DyMn2O5-Mn3O4 nanoparticle composite
Коллективы : Ministry of Education and Science of the Republic of KazakhstanGovernment of the Republic of KazakhstanMinistry of Education and Science of the Republic of Kazakhstan [05130165]; Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0011]
Место публикации : Tech. Phys. - 2021. - Vol. 66, Is. 4. - P.635-641. - ISSN 1063-7842, DOI 10.1134/S1063784221040137. - ISSN 1090-6525(eISSN)
Примечания : Cited References: 34. - This study was supported by the Ministry of Education and Science of the Republic of Kazakhstan (project no. 05130165) and within the framework of a state assignment of the Ministry of Science and Higher Education of the Russian Federation (theme no. FSRZ-2020-0011) in the framework of the Cooperation Agreement between Siberian Federal University, Kirensky Institute of Physics, and Kazakh National Women's Teacher Training University
Предметные рубрики: CRYSTAL-STRUCTURE
Аннотация: The magnetic and resonance properties of the DyMn2O5–Mn3O4 nanoparticle composite have been experimentally investigated. Two magnetic transitions at temperatures of T1 ≈ 65 K and T2 ≈ 230 K have been established; the T1 value differs from the temperatures of the transitions in the initial materials, which has been attributed to the interparticle interactions. Temperature T2 corresponds to the DyMnO3 impurity phase (1 at %). Three microwave absorption peaks have been observed in the magnetic resonance spectrum, which is explained within the model of a magnetically two-phase system. One resonance is attributed to Mn3O4, and the other two peaks are attributed to an ensemble of highly anisotropic DyMn2O5 particles with a random distribution of anisotropy axes.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kostyukov A. S., Isaev I. L., Ershov A. E., Gerasimov V. S., Polyutov S. P., Karpov S. V.
Заглавие : Part I. Nanobubbles in pulsed laser fields for anticancer therapy: in search of adequate models and simulation approaches
Коллективы : Ministry of Science and High Education of Russian Federation [FSRZ-2020-0008]; RFBRRussian Foundation for Basic Research (RFBR); Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-42-240003]
Место публикации : J. Phys. D. - 2022. - Vol. 55, Is. 17. - Ст.175401. - ISSN 0022-3727, DOI 10.1088/1361-6463/ac4c20. - ISSN 1361-6463(eISSN)
Примечания : Cited References: 99. - The research was supported by the Ministry of Science and High Education of Russian Federation (Project No. FSRZ-2020-0008), and was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, Project Number 20-42-240003
Предметные рубрики: INDUCED CELL-LYSIS
GOLD NANOPARTICLES
SELECTIVE NANOPHOTOTHERMOLYSIS
Аннотация: We numerically investigate the conditions for the laser-induced formation of nanobubbles in aqueous medium around plasmonic nanoparticles (NPs) bound to the malignant cell membranes that is considered as the method of their irreversible damage. We proposed employing the versatile and accessible simulation software as a research tool based on the finite volume method underlying the ANSYS Fluent package and supplemented with our user-defined functions that adapt it to solution of the stated problems. This adaptation allows to verify the model using experimental data for the same conditions. We determined the conditions for the pressure growth on the cell membrane at the initial moment of bubble formation significantly exceeding the threshold of irreversible damage. The model can be used for investigation of hydrodynamic effects accompanying irradiation of plasmonic NPs using both different types of pulsed lasers and ideally absorbing NPs with resonance in the hemoglobin spectral transparency range, as well as to uncover previously unknown effects. They include the conditions for localization of a damaging factor non-affecting the normal cells, the conditions for generation of ultrahigh pressure pulse that enables to damage the cell membrane and precedes formation of thin vapor shell around NPs, which, unlike large bubbles, requires registration using highly sensitive experimental measurements. An extensive overview of key publications summarizing the state-of-art in this area is presented.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kostyukov A. S., Isaev I. L., Ershov A. E., Gerasimov V. S., Polyutov S. P., Karpov S. V.
Заглавие : Part II. Nanobubbles around plasmonic nanoparticles in terms of modern simulation modeling: what makes them kill the malignant cells?
Коллективы : Ministry of Science and High Education of Russian Federation [FSRZ-2020-0008]; RFBRRussian Foundation for Basic Research (RFBR); Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science [20-42-240003]
Место публикации : J. Phys. D. - 2022. - Vol. 55, Is. 17. - Ст.175402. - ISSN 0022-3727, DOI 10.1088/1361-6463/ac4c1f. - ISSN 1361-6463(eISSN)
Примечания : Cited References: 49. - The research was supported by the Ministry of Science and High Education of Russian Federation (Project No. FSRZ-2020-0008), and was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, Project No. 20-42-240003
Предметные рубрики: STRESS WAVES
LASER
MEMBRANE
DAMAGE
DEATH
LYSIS
Аннотация: We have established numerically the physical pattern and conditions for formation of nanosized bubbles in aqueous medium around biocompatible plasmonic nanoparticles (NPs) selectively bound to the membrane of the malignant cells by means of DNA-aptamers under the action of picosecond laser radiation. The results obtained are based on the finite volume method and hydrodynamic models underlying the ANSYS Fluent package with extended capabilities. We have found the main features and previously unknown dominant factors of the damage effect on the cell membrane at the moment of the bubble nucleation around the plasmonic NPs of different types taking into account the influence of the closely located membrane. Information on the kinetics of spatial distribution of pressure, temperature and the relative proportion of vapor in the 'nanoparticle-membrane-medium' system have been obtained. The attention is drawn to the advantages of using biocompatible, perfectly absorbing core–shell plasmonic NPs for anti-tumor therapy characterized by an increased mechanical effect on malignant cell membranes at lower laser radiation intensity and the spectral position of their plasmon resonance (λ = 700 nm) in the hemoglobin transparency range. This ensures penetration of laser radiation deep into tissues. The paper is provided with an extensive review of key publications and the state-of-art in this area.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kliava J., Edelman I., Ivanova O., Ivantsov R., Petrakovskaja E. A., Hennet L., Thiaudire D., Saboungi M. L.
Заглавие : Electron magnetic resonance and magnetooptical studies of nanoparticle-containing borate glasses
Место публикации : Journal of Magnetism and Magnetic Materials. - 2011. - Vol. 323, Is. 5. - P.451-460. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2010.09.045
Примечания : Cited Reference Count: 40. - RFBRRussian Foundation for Basic Research (RFBR) [07-02-92174]; CNRSCentre National de la Recherche Scientifique (CNRS)European Commission [07-02-92174]; Russian Federal Program [FCP NK-209P/GK P1227], This work was supported in part by RFBR-CNRS joint project, Grant no. 07-02-92174 and by the Russian Federal Program, project FCP NK-209P/GK P1227. It is a pleasure to thank I. Bruckental and Y. Yeshurun for the magnetization measurements.
ГРНТИ : 29.19
Ключевые слова (''Своб.индексиров.''): borate glasses--electron magnetic resonance--magnetic nanoparticles--magnetooptics
Аннотация: We report electron magnetic resonance (EMR) and magnetooptical studies of borate glasses of molar composition 22.5K2O22.5Al2O 355B2O3 co-doped with low concentrations of Fe2O3
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Stolyar S. V., Knyazev Yu. V., Yaroslavtsev R. N., Pankrats A. I., Vorotynov A. M., Krasikov A. A., Velikanov D. A., Bayukov O. A., Ladygina V. P., Iskhakov R. S.
Заглавие : Role of the surface effects and interparticle magnetic interactions in the temperature evolution of magnetic resonance spectra of ferrihydrite nanoparticle ensembles
Место публикации : Results Phys. - 2022. - Vol. 35. - Ст.105340. - ISSN 22113797 (ISSN), DOI 10.1016/j.rinp.2022.105340
Примечания : Cited References: 119. - Authors thank to A.D. Balaev, S.V. Komogortsev for fruitful discussions and M.N. Volochaev for TEM studies. The TEM study and measurements of X-band FMR spectra were carried out on the equipment of the Krasnoyarsk Territorial Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences. This study was supported by the Russian Science Foundation, project no. 21-72-00025 (https://rscf.ru/project/21-72-00025/) "Tuning the Magnetic Properties of Ultrafine Biocompatible Ferrihydrite Nanoparticles through Interparticle Interactions"
Аннотация: Ferrihydrite is characterized by the antiferromagnetic ordering and, in ferrihydrite nanoparticles, as in nanoparticles of any antiferromagnetic material, an uncompensated magnetic moment is formed. We report on the investigations of ferrihydrite powder systems with an average particle size of ∼ 2.5 nm obtained (i) as a product of the vital activity of bacteria (sample FH-bact) and (ii) by a chemical method (sample FH-chem). In the first approximation, these samples can be considered to be identical. However, in sample FH-chem, particles contact directly, while in sample FH-bact, they have organic shells; therefore, the interparticle magnetic interactions in these samples have different degrees. The main goal of this work has been to establish the effects of the interparticle magnetic interactions and individual characteristics of ferrihydrite nanoparticles on ferromagnetic resonance (FMR) spectra. The FMR spectra have been measured at different (9.4–75 GHz) frequencies in a wide temperature range. It has been found that, at low temperatures, the field-frequency dependence ν(HR) of the investigated systems has a gap ν/γ = HR + HA, where HR is the resonance field and HA is the induced anisotropy, which decreases with increasing temperature. To estimate a degree of the effect of interparticle interactions on the results obtained and to correctly determine the temperature range of the superparamagnetic (or blocked) state, the static magnetic measurement and Mössbauer spectroscopy data have been obtained and analyzed. It has been shown that the most striking feature of the FMR spectra - a gap in the field-frequency dependences - is a manifestation of individual characteristics of ferrihydrite nanoparticles. The induced anisotropy is caused by freezing of a subsystem of surface spins and its coupling with the particle core, which is observed in both samples at a temperature of ∼80 K. The temperature range (below 80 K) in which the gap exists corresponds to the blocked state in the FMR technique. In sample FH-bact, the ratio between the FMR parameters HA and linewidth ΔH obeys the standard expression HA ∼ (ΔH)3. In sample FH-chem, however, the interparticle magnetic interactions dramatically affect the behavior of parameters of the FMR spectra, which change nonmonotonically upon temperature variation. This fact is attributed to the collective freezing of the magnetic moments of particles under the conditions of sufficiently strong interactions, which follows from the temperature dependence of the particle magnetic moment relaxation time determined from the Mössbauer spectroscopy and static magnetometry data obtained in weak magnetic fields.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Edelman. I., Ivanova O., Ivantsov R., Velikanov D., Zubavichus Y., Veligzhanin A., Curely J.
Заглавие : Magnetic properties and morphology of ferrite nanoparticle dispersed in glass
Коллективы : Moscow International Symposium on Magnetism
Место публикации : Moscow Int. Symp. on Magnet. (MISM-2011): Book of abstracts. - 2011. - Ст.23OR-B-9. - P.281-282
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Edelman I. S., Ivanova O. S., Ivantsov R. D.
Заглавие : Magnetooptical Studies of Nanoparticle-Containing Borate Glasses
Коллективы : Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium
Место публикации : Solid State Phenomena. - 2011. - Vol. 168-169. - P.525-528. - ISBN 1012-0394, DOI 10.4028/www.scientific.net/SSP.168-169.525
Примечания : Cited Reference Count: 9
Предметные рубрики: Materials Science, Multidisciplinary
Physics, Condensed Matter
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--oxide glasses--faraday rotation--magnetic circular dichroism
Аннотация: Faraday rotation (FR) and magnetic circular dichroism (MCD) of nanocomposite structures based on potassium-aluminum-germanium-boron glasses co-doped with Fe and rare earth (RE) or Y+Bi oxides have been studied. Formation of magnetic nanoparticles as a result of the glass heat treatment ensures them magnetic and magneto-optical properties typical of magnetically ordered substances. At the same time, glasses keep transparence in visual spectral range owing to low paramagnetic oxides concentration. FR and MCD spectra of the heat treated glasses are shown to be very close to those of gamma-Fe(2)O(3) and practically independent of the RE element nature for the light wave energies lower than 22000 cm(-1). For higher energies, the MCD spectrum shape depends strongly an RE what evidences the different origin of magneto-optical effects in two spectral ranges.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Khaydarov R., Gapurova O., Abdukhakimov M., Sadikov I., Garipov I., Krishnamurthy P. T., Zharkov S. M., Zeer G. M., Abolentseva P. A., Prudnikova S. V., Evgrafova S. Y.
Заглавие : Antimicrobial properties of nanofiltration membranes modified with silver nanoparticles
Коллективы : SFU Joint Scientific Center; Ministry of Science and Higher Education of the Russian Federation [FSRZ-2020-0011]
Место публикации : Emerg. Mater. - 2022. - Vol. 5, Is. 5. - P.1477-1483. - ISSN 2522-5731, DOI 10.1007/s42247-021-00330-2. - ISSN 2522-574X(eISSN)
Примечания : Cited References: 31. - The SEM and TEM analysis was carried out in the SFU Joint Scientific Center under the support of the Ministry of Science and Higher Education of the Russian Federation (#FSRZ-2020-0011)
Аннотация: The growth of bacteria and fungi on a nanofiltration (NF) membrane is known to reduce its permeability and lifetime and increase overall energy use. Over the last decade, application of silver nanoparticles (AgNPs) has shown to present a strong potential in preventing biofouling of NF membrane processes. The paper deals with a novel facile method developed to in situ incorporate nanosilver stabilized with the polyhexamethylene biguanide hydrochloride (PHMB) onto the commercial NF membrane surface. The scanning electron microscopy (SEM) investigations confirmed a uniform distribution of AgNPs on the surface of NF membrane although AgNPs tend to agglomerate into nano-sized colloidal clusters. Our results showed that AgNPs had little impact on the performance of the NF membrane, including salt rejection and water permeation properties. To evaluate the antibacterial properties of nanocomposite membranes, a "time-kill" analysis, a microbiological technique for measuring the change in a population of microorganisms under the impact of a specific sample, has been used against representatives of Gram-positive and Gram-negative bacteria. Inductively coupled mass spectrometry (ICP-MS) was used to study kinetics of Ag release from modified NF membrane. Leaching rates of Ag were low that will possibly result in long-established antimicrobial and antifungal properties. The present research offers a potential for its further use as a new type of modified NF membrane mitigating biofouling.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ershov A. E., Gerasimov V. S., Isaev I. L., Gavrilyuk A. P., Karpov S. V.
Заглавие : Processes underlying the laser photochromic effect in colloidal plasmonic nanoparticle aggregates*
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk Territory [18-42-243023]; Krasnoyarsk Regional Fund of Science [18-42-243023]; RF Ministry of Science and Higher Education; Siberian Federal University for Scientific Research; Russian FederationRussian Federation [075-15-2019-676]
Место публикации : Chin. Phys. B. - 2020. - Vol. 29, Is. 3. - Ст.037802. - ISSN 1674-1056, DOI 10.1088/1674-1056/ab6551. - ISSN 1741-4199(eISSN)
Примечания : Cited References: 38. - Project funded by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science (Grant 18-42-243023), the RF Ministry of Science and Higher Education, and the State Contract with Siberian Federal University for Scientific Research. A.E. thanks the grant of the President of Russian Federation (agreement 075-15-2019-676).
Предметные рубрики: SELECTIVE PHOTOMODIFICATION
LIGHT
FORCES
OPTICS
Аннотация: We have studied the dynamic and static processes occurring in disordered multiparticle colloidal Ag aggregates with natural structure and affecting their plasmonic absorption spectra under pico- and nanosecond pulsed laser radiations, as well as the physical origin responsible for these processes. We have shown that depending on the duration of the laser pulse, the mechanisms of laser modification of such aggregates can be associated both with changes in the resonant properties of the particles due to their heating and melting (picosecond irradiation mode) and with the particle shifts in the resonant domains of the aggregates (nanosecond pulses) which depend on the wavelength, intensity, and polarization of the radiation. These mechanisms result in formation of a narrow dip in the plasmonic absorption spectrum of the aggregates near the laser radiation wavelength and affect the shape and position of the dip. The effect of polydispersity of nanoparticle aggregates on laser photochromic reaction has been studied.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Utyushev A. D., Isaev I. L., Gerasimov V. S., Ershov A. E., Zakomirnyi V. I., Rasskazov I. L., Polyutov S. P., Ågren H., Karpov S. V.
Заглавие : Engineering novel tunable optical high-Q nanoparticle array filters for a wide range of wavelengths
Место публикации : Opt. Express. - 2020. - Vol. 28, Is. 2. - P.1426-1438. - ISSN 1094-4087, DOI 10.1364/OE.28.001426
Примечания : Cited References: 62. - The reported study was funded by the Russian Science Foundation, project No. 18-13-00363; the grant of the President of Russian Federation for young scientists No. 075-15-2019-676 (calculations of the electromagnetic field configurations in NPs array)
Предметные рубрики: Nanophotonics, Metamaterials, and Photonic Crystals
Аннотация: The interaction of non-monochromatic radiation with arrays comprising plasmonic and dielectric nanoparticles has been studied using the finite-difference time-domain electrodynamics method. It is shown that LiNbO3, TiO2, GaAs, Si, and Ge all-dielectric nanoparticle arrays can provide a complete selective reflection of an incident plane wave within a narrow spectral line of collective lattice resonance with a Q-factor of 103 or larger at various spectral ranges, while plasmonic refractory TiN and chemically stable Au nanoparticle arrays provide high-Q resonances with moderate reflectivity. Arrays with fixed dimensional parameters make it possible to fine-tune the position of a selected resonant spectral line by tilting the array relative to the direction of the incident radiation. These effects provide grounds for engineering novel selective tunable optical high-Q filters in a wide range of wavelengths, from visible to middle-IR.
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