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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Sutormin V. S., Prishchepa O. O., Kuz'menok N. M., Mikhalyonok S. G., Bezborodov V. S., Zyryanov V. Ya.
Заглавие : Anionic-cationic surfactant mixture providing the electrically controlled homeotropic surface anchoring of liquid crystals
Коллективы : International conference on Hole Burning, Single Molecule, and Related Spectroscopies: Science and Applications - 2018 , Belarusian Republican Foundation for Fundamental Research [X16P-110]; Russian Foundation for Basic Research (RFBR) [16-53-00073]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-42-243006]
Место публикации : J. Mol. Liq. - 2019. - Vol. 282: Suzdal Conference (2018, Suzdal, RUSSIA). - P.57-62. - ISSN 0167-7322, DOI 10.1016/j.molliq.2019.02.132. - ISSN 1873-3166(eISSN)
Примечания : Cited References: 30. - The reported study was supported by the Belarusian Republican Foundation for Fundamental Research (project No X16P-110) and Russian Foundation for Basic Research (RFBR) (project No 16-53-00073). Mikhail N. Krakhalev and Vitaly S. Sutormin acknowledge financial support from RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (project No 18-42-243006).
Предметные рубрики: IONIC MODIFICATION
TRANSITION
DROPLETS
CONFIGURATION
LAYER
Аннотация: In search of a substance able to function as an anionic surfactant applied for the electrically-induced anchoring transitions in liquid crystals, the compound 4-heptyloxybenzoate benzyl dodecyldimethylammonium (HOBBDDA) has been synthesized. Its orienting influence on nematic liquid crystal 4-pentyl-4'-cyanobiphenyl (5CB) has been tested. HOBBDDA dissolved up to 1.4%in 50 droplets dispersed in polymer film does not change the tangential surface anchoring inherent to polyvinyl alcohol matrix used. Homeotropic surface anchoring is realized if the HOBBDDA content exceeds 1.7%. The molecules of the surfactant in 5CB dissociate into anions and cations. The anions modify the surface anchoring under the action of DC electric field both in the normal and inverse mode. The mixture of HOBBDDA and cetyltrimethylammonium bromide can function as a binary ionic cationic surfactant which significantly expands the prospects for using the ionic-surfactant method to control liquid crystal materials. (C) 2019 Elsevier B.V. All rights reserved.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Archibald A.J., Lin Y.-T., Zyryanov V.Ya., Lee W.
Заглавие : Berreman 4 x 4 matrix method for light propagation in a one-dimensional photonic crystal with a twisted-nematic defect layer
Коллективы : International Photonics Conference
Место публикации : Int. Photonics Conf.: Paper in Proceedings. - 2011. - С. 125
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Krakhalev M. N., Prishchepa O. O., Gardymova A. P., Zyryanov V. Ya.
Заглавие : Bipolar configuration with a twisted defect loop in chiral nematic droplets
Коллективы : European Conference on Liquid Crystals, Московский государственный университет им. М.В. Ломоносова
Место публикации : 14th Eur. Conf. Liq. Cryst. (ECLC): conf. programme/ чл. нац. орг. и прогр. ком. V. Ya. Zyryanov. - 2017. - Ст.P133. - Poster
Примечания : Библиогр.: 3
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Gardymova A. P., Prishchepa O. O., Rudyak V. Yu., Emelyanenko A. V., Liu J. -H., Zyryanov V. Ya.
Заглавие : Bipolar configuration with twisted loop defect in chiral nematic droplets under homeotropic surface anchoring
Место публикации : Sci. Rep. - 2017. - Vol. 7, Is. 1. - Ст.14582. - ISSN 20452322 (ISSN), DOI 10.1038/s41598-017-15049-6
Примечания : Cited References: 45. - We are grateful to Dr. Timofeev Ivan Vladimirovich for valuable comments and discussions. This work was supported by the Russian Foundation for Basic Research (RFBR) under Grants Nos 15-02-06924, 16-53-00073, and Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project No. 16-42-240704, and by the Siberian Branch of the Russian Academy of Sciences under Complex Program II.2P 0358-2015-0010. The work of V.Y.R. and À.V.Å. on the simulation of droplet structure and texture was supported by the Russian Science Foundation (project No. 16-43-03010). The work of J.H.L. was supported by the Ministry of Science and Technology of Taiwan (contract No. MOST105-2923-E-006-007).
Аннотация: Optical textures and appropriate orientational structures have been studied within droplets of chiral nematic dispersed in polymer assigning the homeotropic anchoring. The helix axis of the chiral structure inside droplets forms the bipolar configuration. The optical droplet textures were analysed in the unpolarised light, analyser switching-off scheme and in crossed polarisers. The twisted loop defect reveals itself convincingly in all schemes. Its appearance at the optical patterns of the chiral nematic droplets has been examined depending on their size and the aspect direction. The existence of the defect has been verified by the structural and optical calculations. The effect of an electric field on both the defect line shape and the orientational structure of chiral nematic has been studied.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Parshin A. M., Zyryanov V. Ya., Shabanov V. F., Nazarov V. G.
Заглавие : Bipolar-homogeneous structural phase transition in nematic droplets formed in the polymer matrix in a magnetic field
Место публикации : Crystallogr. Rep. - New York: Maik Nauka/Interperiodica/Springer, 2009. - Vol. 54, Is. 7. - С. 1191-1196. - DEC. - ISSN 1063-7745, DOI 10.1134/S1063774509070098
Примечания : Cited Reference Count: 19. - Гранты: This study was supported by the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools ( grant no. NSh-3818.2008.3), the Russian Foundation for Basic Research ( project no. 08-03-01007), the Presidium of the Russian Academy of Sciences ( project no. 27.1), and the Siberian Branch of the Russian Academy of Sciences ( project nos. 110 and 144).Финансирующая организация: President of the Russian Federation [NSh-3818.2008.3]; Russian Foundation for Basic Research [08-03-01007]; Russian Academy of Sciences [27.1, 110, 144]
Предметные рубрики: DISPERSED LIQUID-CRYSTALS
FRANK CONSTANTS
ALIGNMENT
Ключевые слова (''Своб.индексиров.''): bipolar configuration--bipolar structure--cyanobiphenyls--homogeneous structure--mutual transformations--nematic director--nematic droplets--order parameter--poly(vinyl butyral)--structural phase transition--temperature range--thermal fluctuations--crystal structure--drop formation--liquid crystals--magnetic fields--nematic liquid crystals--phase transitions
Аннотация: The phase transition from the bipolar structure to the homogeneous structure in droplets formed from the nematic liquid crystal 4-n-pentyl-4'-cyanobiphenyl in poly(vinyl butyral) in the presence of a magnetic field has been investigated. The phase transition is associated with the expansion of the regions with a tilted orientation of the director in the vicinity of defects (the disappearance of boojums) and with the alignment of the nematic director lines in the bulk of the droplet in the direction of the magnetic field. In the temperature range T = 24-34A degrees C, cyclic mutual transformations between the bipolar configuration of the nematic director and the homogeneous structure, which have a period of similar to 0.5-3.5 s and result from thermal fluctuations of the order parameter, are observed in droplets 3-15 A mu m in size after the forming field is switched off.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Gunyakov V. A., Timofeev I. V., Krakhalev M. N., Lee W., Zyryanov V. Ya.
Заглавие : Bisector effect in a twisted-nematic Fabry–Pйrot cavity
Коллективы : European Conference on Liquid Crystals, Московский государственный университет им. М.В. Ломоносова
Место публикации : 14th Eur. Conf. Liq. Cryst. (ECLC): conf. programme/ чл. нац. орг. и прогр. ком. V. Ya. Zyryanov. - 2017. - Ст.O61. - P.10
Примечания : Библиогр.: 3
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Parshin A. M., Nazarov V. G., Zyryanov V. Ya., Shabanov V. F.
Заглавие : Bistable director configurations in polymer dispersed nematic liquid crystals
Коллективы : IInternational LC Conference
Место публикации : 22nd International LC Conference: Abstracts. - 2008. - Vol. 1. - P.382
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aver'yanov E. M.
Заглавие : Change in the polarizability of MBBA molecules upon the nematic-isotropic liquid transition and physical consequences
Место публикации : Phys. Solid State. - 2013. - Vol. 55, Is. 10. - P.2136-2141. - ISSN 1063-7834, DOI 10.1134/S106378341310003X
Аннотация: The Lorentz tensor components Lj and the polarizability tensor components ?j of 4-methoxyben-zylidene-4?-butylaniline (MBBA) liquid crystal molecules in nematic and isotropic phases have been determined experimentally. The quadratic dependences of the mean value ?(S) and anisotropy ??(S) of the polarizability in the nematic phase on the orientational order parameter S of molecules have been established. Within the phenomenological approach, the dependences ?(S) and ??(S) have been derived, and their features for MBBA and other known objects have been interpreted. The relation of the dependences ?(S) and ??(S) to the features of the nematic-isotropic liquid phase transition has been found. В© 2013 Pleiades Publishing, Ltd.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Aver'yanov E. M.
Заглавие : Change in the polarizability of molecules at the phase transitions isotropic liquid -nematic - smectic-A - crystal-B in liquid crystal 4О.8
Коллективы : European Conference on Liquid Crystals, Московский государственный университет им. М.В. Ломоносова
Место публикации : 14th Eur. Conf. Liq. Cryst. (ECLC): conf. programme/ чл. нац. орг. и прогр. ком. V. Ya. Zyryanov. - 2017. - Ст.P3. - Poster
Примечания : Библиогр.:
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : AVERYANOV E. M.
Заглавие : CHANGE OF MOLECULE CONFORMATION AND CHARACTER OF NEMATIC-ISOTROPIC LIQUID-PHASE TRANSITION
Место публикации : Fiz. Tverd. Tela: MEZHDUNARODNAYA KNIGA, 1982. - Vol. 24, Is. 9. - P2839-2841. - ISSN 0367-3294
Примечания : Cited References: 15
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shabanov A. V., Presnyakov V. V., Zyryanov V. Y., Vetrov S. Y.
Заглавие : Characteristics of the process of reorientation of bipolar drops of a nematic with rigidly fixed poles
Место публикации : JETP Letters. - 1998. - Vol. 67, Is. 9. - P.733-737. - ISSN 0021-3640, DOI 10.1134/1.567739
Примечания : Cited References: 9
Аннотация: The director configuration in a bipolar drop of a nematic with rigidly fixed poles is calculated as a function of the electric field directed perpendicular to the symmetry axis of the drop. It is shown that the reorientation of the drop is a dual process: a threshold process in the region where the initial director orientation is orthogonal to the electric field, and a nonthreshold process elsewhere in the drop. A relation for determining the critical field is obtained. Experimental investigations of the characteristics of scattered light for a film of polymer-encapsulated liquid crystals confirm the computational results. (C) 1998 American Institute of Physics. [S0021-3640(98)01709-5].
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12.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Presnyakov V. V., Shabanov V. F., Zyryanov V. Ya., Komitov L.
Заглавие : Chiral additive effects on electrooptical response and dropletstructure in uniaxially oriented films of polymer dispersed nematic
Коллективы : International Liquid Crystal Conference
Место публикации : 18th International Liquid Crystal Conference (ILCC 2000): program and abstract book. - 2000. - P.495. - DOI 10.1080/10587250108028657; \b Molecular crystals and liquid crystals science and technology : section A- Molecular crystals and liquid crystals. - 2001. - Vol. 367, Is. 1. - P.369-377
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abdullaev A. S., Kostikov D. A., Krakhalev M. N., Zyryanov V. Ya.
Заглавие : Complete light polarization control using a chiral-nematic cell with tangential-conical boundary conditions
Колич.характеристики :7 с
Место публикации : Opt. Mater. - 2023. - Vol. 146. - Ст.114521. - ISSN 09253467 (ISSN), DOI 10.1016/j.optmat.2023.114521. - ISSN 18731252 (eISSN)
Примечания : Cited References: 20
Аннотация: Light polarization control by the chiral-nematic cell with hybrid tangential-conical boundary conditions has been studied by means of photo- and electrically induced transformations of the orientational structure. The polarization azimuth changes due to the power ratio of ultraviolet and blue radiations, at which the director twist angle in the chiral nematic varies smoothly. The light polarization ellipticity is controlled by an electric field applied perpendicular to the liquid crystal cell changing the effective anisotropy of the refractive index. The optical material under study is promising to develop the devices for the light polarization converter over the entire visible range, as well as for photo-controlled rotators of linear polarization of white light.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Averyanov E. M., Zhuikov V. A., Adomenas P. V.
Заглавие : Conformational change induced in mesomolecules by smectic a-nematic-isotropic liquid-phase transitions
Место публикации : JETP Letters. - 1981. - Vol. 33, Is. 5. - P.248-251. - ISSN 0021-3640
Примечания : Cited References: 11
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aver'yanov E. M.
Заглавие : Correlation of the molecular structure of discotic nematic liquid crystals with their orientational order and specific features of the nematic-isotropic phase transition
Место публикации : Phys. Solid State: AMER INST PHYSICS, 2004. - Vol. 46, Is. 8. - P1554-1559. - ISSN 1063-7834, DOI 10.1134/1.1788794
Примечания : Cited References: 32
Предметные рубрики: MONTE-CARLO
ANISOTROPIC SYSTEMS
COMPUTER-SIMULATION
BEHAVIOR
TRIPHENYLENE
DISCOGEN
MESOGEN
FIELD
Аннотация: The orientational order parameter S of molecules in high-temperature discotic nematic liquid-crystal phases of triphenylene derivatives is investigated as a function of the length of side flexible molecular chains at different temperatures. It is established that the orientational order parameters S in the range of the transition from the nematic phase to the isotropic liquid phase (the N-D-I transition) are smaller than those predicted from the molecular-statistical theory and computer simulation. It is shown that the N-D-I transition is close to both the isolated Landau point and the tricritical point (regardless of the chemical structure of the molecules and the anisotropy of dispersion intermolecular interactions). Consistent explanations are offered for a number of experimental findings, such as the anomalously small changes in the enthalpy and entropy upon the N-D-I transition (as compared to those revealed upon the N-I transition in calamitic nematic liquid crystals), the anomalously strong response of the isotropic phase of discotic nematic liquid crystals to external fields (thermodynamically conjugate to the order parameter S) and the long relaxation times of this response, and the formation of cybotactic discotic molecular clusters in the isotropic phase in the vicinity of the N-D-I transition. (C) 2004 MAIK "Nauka / Interperiodica".
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Averyanov E. M., Zhuikov V. A., Korets A. Ya., Shabanov V. F., Adomenas P. V.
Заглавие : Critical increase of the bending fluctuations of molecules and the nematic-to-isotropic liquid-phase transition
Место публикации : JETP Letters. - 1980. - Vol. 31, Is. 9. - P.480-483. - ISSN 0021-3640
Примечания : Cited References: 5
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17.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Gunyakov V. A., Krakhalev M. N., Shabanov V. F., Wu, Pochang, Lee, Wei, Zyryanov V. Ya.
Заглавие : Defect modes control in photonic structure based on electro-hydrodynamic effect in nematic LC
Коллективы : Asian Conference on Liquid Crystals
Место публикации : The 2nd Asian Conf. on Liq. Cryst. (ACLC 2015): abstr. book. - 2015. - Ст.PB-20. - P.149
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gunyakov V. A., Parshin A. M., Khrustalev B. P., Shabanov V. F.
Заглавие : Determination of anchoring energy for nematic onto ferroelectric substrate
Место публикации : Solid State Commun.: PERGAMON-ELSEVIER SCIENCE LTD, 1993. - Vol. 87, Is. 9. - P.751-753. - ISSN 0038-1098, DOI 10.1016/0038-1098(93)90406-D
Примечания : Cited References: 8
Предметные рубрики: LIQUID-CRYSTALS
SURFACE
Аннотация: A technique to determine anchoring energy of planar MBBA layer with cleavage surfaces of triglycine sulphate is presented. The method is based on guest-host phenomenon in impure nematic. The anchoring energy W = (1.0 +/- 0.3).10(-4) erg/cm2 is calculated within Rapini-Papoular approximation.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Drokin N. A., Shabanov V. F., Shepov V. N.
Заглавие : Dielectric anisotropy of nematic 4-pentil-4'-cyanobiphenyl
Место публикации : Molecular crystals and liquid crystals science and technology : section A- Molecular crystals and liquid crystals. - 2001. - Vol. 366, Is. 1. - P.305-312. - DOI 10.1080/10587250108023973
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Prishchepa O. O., Shabanov A. V., Zyryanov V. Y.
Заглавие : Director configurations in nematic droplets with inhomogeneous boundary conditions
Место публикации : Phys. Rev. E: AMERICAN PHYSICAL SOC, 2005. - Vol. 72, Is. 3. - Ст.31712. - ISSN 1539-3755, DOI 10.1103/PhysRevE.72.031712
Примечания : Cited References: 22
Предметные рубрики: DISPERSED LIQUID-CRYSTALS
TRANSITION
Ключевые слова (''Своб.индексиров.''): lecithin contents--nematic droplets--polarizers--radial structures--approximation theory--boundary conditions--drop breakup--free energy--polarization--textures--nematic liquid crystals
Аннотация: The nematic droplets with director configurations intermediate between the bipolar and radial structures have been investigated experimentally and theoretically. The liquid crystal 4(')-n-pentyl-4-cyanobiphenyl (5CB) with a variable addition of the lecithin dispersed in polyvinylbutyral has been used. The characteristic textures of the droplets formed at various lecithin contents have been examined using polarizing microscope both in the crossed polarizers and without analyzer. The computer simulation has been performed for proper ordering of the director in spherical nematic droplets by minimizing the free energy in the one-constant approximation. The inhomogeneous boundary conditions with strong anchoring of the molecules at the interface have been used. The distribution of the anchoring angle at the droplet surface has been estimated based on analysis of observed patterns. The simulated textures of the droplets under crossed polarizers are shown to compare well with the experimental ones.
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