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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Masyugin A. N., Volochaev M. N., Ishibashi T.
Заглавие : Coexistence of the electric polarization and conductive current in the bismuth–neodymium ferrite garnet films
Место публикации : J. Mater. Sci. Mater. Electron. - 2021. - Vol. 32. - P.3766-3781. - ISSN 09574522 (ISSN), DOI 10.1007/s10854-020-05121-9
Примечания : Cited References: 42
Аннотация: The Nd1Bi2Fe5O12/Nd2Bi1Fe4Ga1O12 polycrystalline films on the glass substrate and the Nd0.5Bi2.5Fe5O12 epitaxial films on the single-crystal gadolinium gallium garnet substrate have been investigated by impedance and dielectric spectroscopy. The inductive contribution to the impedance and two relaxation channels related to ferroelectric domains and migration polarization have been established. The magnetocapacitance and magnetoimpedance have been determined. The conductive and polarization currents and the phase difference between them for the films of two types have been determined. The critical temperatures of the polarization disappearance and hysteresis I–V have been found. A model of the polarization caused by the piezoelectric effect and flexoelectric interaction has been proposed. I–V hysteresis is explained by the presence of ferroelectric domains near the interface and is associated with the hysteresis of the electric polarization.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhachev A. L., Malakhovskii A. V., Nelson C. S., Gudim I. A., Temerov V. L.
Заглавие : Comparison of the absorption spectra of Nd3+ ions in the NdFe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and Ho0.75Nd0.25Fe3(BO3)4 crystals
Место публикации : Phys. Solid State. - 2021. - Vol. 63, Is. 1. - P.113-121. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783421010200
Примечания : Cited References: 21. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: number 19-42-240003 “Influence of the local en-vironment on magneto-optical properties of f–f transitions in rare-earth aluminum and iron borates”
Аннотация: The polarized optical absorption spectra in the region of a series of the f–f transitions of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4, Nd0.5Gd0.5Fe3(BO3)4, and NdFe3(BO3)4 crystals at 90 K have been compared. The spectral features related to the difference in the local environment of Nd3+ ions in these crystals have been established. In the region of the transition 4I9/2 → 4G5/2 + 2G7/2 of Nd3+ ions in the Ho0.75Nd0.25Fe3(BO3)4 crystal, the appearance of some absorption lines at the structural transition R32 → P3121 around ~200 K due to the local symmetry variation has been found. The intensity of these lines smoothly increases with a decrease in temperature from the transition point. The temperature dependence of the lattice parameters of the Ho0.75Nd0.25Fe3(BO3)4 crystal has been measured. It has been found that, at the transition temperature, the lattice parameter a changes stepwise, which is indicative of the occurrence of a first-order phase transition. The lattice parameter c changes smoothly.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Smirnova E. S., Alekseeva O. A., Dudka A. P., Verin I. A., Artemov V. V., Lyubutina M. V., Gudim I. A., Frolov K. V., Lyubutin I. S.
Заглавие : Crystal structure of bis­muth-containing NdFe3(BO3)4 in the temperature range 20–500 K
Коллективы : Russian Ministry of Science and Higher Education; Ministry of Science and Higher Education within the State assignment FSRC 'Crystallography and Photonics' RAS
Место публикации : Acta Crystallogr. B. - 2022. - Vol. 78, Pt. 1. - P.1-13. - ISSN 2052-5206(eISSN), DOI 10.1107/S205252062101180X
Примечания : Cited References: 44. - This work was performed using the equipment of the Shared Research Center FSRC `Crystallography and Photonics' RAS supported by the Russian Ministry of Science and Higher Education. This work was supported by the Ministry of Science and Higher Education within the State assignment FSRC `Crystallography and Photonics' RAS
Предметные рубрики: MAGNETIC PHASE-TRANSITIONS
UNIT-CELL PARAMETERS
DIFFRACTION
Аннотация: Neodymium iron bor­ate NdFe3(BO3)4 is an intensively studied multiferroic with high electric polarization values controlled by a magnetic field. It is char­ac­ter­ized by a large quadratic magnetoelectric effect, rigidity in the base plane and a rather strong piezoelectric effect. In this work, the atomic structure of (Nd0.91Bi0.09)Fe3(BO3)4 was studied by single-crystal X-ray diffraction in the tem­per­ature range 20–500 K (space group R32, Z = 3). The Bi atoms found in the com­position partially substitute the Nd atoms in the 3a position; they entered the structure due to the growth conditions in the presence of Bi2Mo3O12. It was shown that in the tem­per­ature range 20–500 K there is no structural phase transition R32→P3121, which occurs in rare-earth iron bor­ates (RE = Eu–Er, Y) with an effective rare-earth cation radius smaller than that of Nd. The tem­per­ature dependence of the unit-cell c parameter reveals a slight increase on cooling below 90 K, which is similar to the results obtained previously for iron bor­ates of Gd, Y and Ho. The atomic distances (Nd,Bi)—O, (Nd,Bi)—B, (Nd,Bi)—Fe, Fe—O, Fe—B and Fe—Fe in the iron chains and between chains decrease steadily with decreasing tem­per­ature from 500 to 90 K, whereas the B1(3b)—O distance does not change and the average B2(9e)—O distance increases slightly. There is a uniform decrease in the atomic displacement parameters with decreasing tem­per­ature, with a more pronounced decrease for the Nd(3a) and O2(9e) atoms. The O2(9e) atoms are characterized by the maximum atomic displacement parameters and the most elongated atomic displacement ellipsoids. The characteristic Debye and Einstein tem­per­atures, and the static com­ponent in the atomic displacements were determined for cations using multi-tem­per­ature diffraction data. It was shown that the Nd cations have the weakest bonds with the surrounding atoms and the B cations have the strongest.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Masyugin A. N., Sitnicov M. N., Rybina U. I., Ishibashi T.
Заглавие : Colossal magnetostriction and electrostriction of bismuth-substituted neodymium iron garnet films
Место публикации : J. Magn. Magn. Mater. - 2018. - Vol. 464. - P.44-49. - ISSN 03048853 (ISSN), DOI 10.1016/j.jmmm.2018.05.038
Примечания : Cited References: 27. - This study were supported by the Russian Foundation for Basic Research project №18-52-00009 Bel_a, № 18-32-00079 mol_a, the state order № 3.5743.2017/6.7.
Ключевые слова (''Своб.индексиров.''): thermal expansion--magnetostriction--electrostriction
Аннотация: Electro- and magnetostriction mechanisms and temperature behavior of the length of bismuth-substituted neodymium iron garnet films on glass and gallium gadolinium garnet have been investigated. Electric- and magnetic-field and temperature dependences of the electro- and magnetostriction constants have been determined. It has been established that the magnetostriction constant changes its sign upon temperature variation. The experimental data are explained using a model of dipole glass with the magnetoelectric and magnetoelastic interaction.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Sukhachev A. L., Malakhovskii A. V., Aleksandrovsky A. S., Gudim I. A., Temerov V. L.
Заглавие : Spectroscopic properties of HoFe3(BO3)4, NdFe3(BO3)4 and Ho0.75Nd0.25Fe3(BO3)4 single crystals
Место публикации : Opt. Mater. - 2018. - Vol. 83. - P.87-92. - ISSN 09253467 (ISSN), DOI 10.1016/j.optmat.2018.05.078
Примечания : Cited References: 39. - A.L. Sukhachev thanks for support Project of Russian Academy of Science No. 0356-2017-0030. A.V. Malakhovskii thanks Russian Foundation for Basic Researches (RFBR) Grant No. 16-02-00273. A.S. Aleksandrovsky thanks RFBR Grant No. 17-52-53031. I.A. Gudim and V.L. Temerov thank RFBR Grant No. 17-52-45091.
Ключевые слова (''Своб.индексиров.''): holmium and neodymium ferroborates--judd–ofelt parameters
Аннотация: Polarized absorption spectra of ferroborates HoFe3(BO3)4, NdFe3(BO3)4 and Ho0.75Nd0.25Fe3(BO3)4 were measured at room temperature in spectral range 4000–24500 cm−1 (400–2500 nm). The studied single crystals were grown from solution-melts. Intensities of the f-f transitions were measured and the Judd–Ofelt parameters Ωλ of Ho3+ and Nd3+ ions in the studied crystals were calculated. It was revealed that the crystals content not strongly influences the Judd–Ofelt parameters. The Ω2 parameter for Ho3+ ion is the most sensitive to the crystal content. Linear dichroism of the hypersensitive transitions appeared to be the largest one for both rare earth ions.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golosovsky I. V., Vasilev A. I., Mukhin A. A., Ressouche E., Skumryev V., Urcelay-Olabarria I., Gudim I. A., Bezmaternykh L. N.
Заглавие : Complex magnetic order in the Nd(Tb)Fe3(BO3)4 multiferroic revealed by single-crystal neutron diffraction
Место публикации : Phys. Rev. B. - 2019. - Vol. 99, Is. 13. - Ст.134439. - ISSN 24699950 (ISSN) , DOI 10.1103/PhysRevB.99.134439
Примечания : Cited References: 33. - This work was supported by the Russian Grant No. RFBR 16-02-00058. A.A.M. acknowledges the financial support from the Russian Science Foundation (16-12-10531).
Аннотация: Magnetic structure of the substituted multiferroics-ferroborates Nd0.9Tb0.1Fe3(BO3)4 and Nd0.8Tb0.2Fe3(BO3)4 were determined in the framework of a self-consistent refinement of the single crystal neutron diffraction data. The small substitution of Nd for Tb leads to the reorientation of the main antiferromagnetic vector L from the basal plane towards the hexagonal axis. The reorientation takes place via an angular structure for which L does not coincide with the principal crystallographic directions and evolves with temperature due to competing magnetic anisotropies of Fe, Nd, and Tb subsystems. Our refinement at 2 K reveals the existence of distortions in the collinear antiferromagnetic Fe spin arrangement suggested before in other ferroborates. Therefore, besides the main antiferromagnetic vector L, the magnetic structure involves additional fine symmetrized combinations of spin components allowed by symmetry. They coexist with certain L components and could originate from the antisymmetric Dzyaloshinsky-Moriya Fe-Fe exchange interactions. At higher temperatures, the magnetic structure is described by the simple collinear model, where the L vector is deviated from the hexagonal plane. © 2019 American Physical Society.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chukalina E. P., Jablunovskis A., Gudim I. A.
Заглавие : Study of the magnetic properties of neodymium and samarium iron borates by the method of erbium spectroscopic probe
Место публикации : Opt. Spectrosc. - 2022. - Vol. 130, Is. 1. - P.98-104. - ISSN 0030400X (ISSN), DOI 10.21883/EOS.2022.01.52993.23-21. - ISSN 15626911 (eISSN)
Примечания : Cited References: 30. - This paper was carried out under financial support of the Russian Science Foundation (grant № 19-12-00413)
Аннотация: Iron borates NdFe3(BO3)4 and SmFe3(BO3)4 activated with 1% erbium, with a huntite structure (space symmetry group R32) were investigated by the method of erbium spectroscopic probe. From an analysis of the temperature dependence of the transmission spectra in the region of the 4I15/2 → 4I13/2 transition in the Er3+ ion, it was found that both studied compounds order antiferromagnetically at TN ≈ 33 K into an easy-plane magnetic structure. No other phase transitions were found.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Grigorchenko V.M., Molokeev M. S., Oreshonkov A. S., Aleksandrovsky A. S., Kertman A.V., Abulkhaev M.U., Mereshchenko A.S., Yurev I.O., Shulaev N.А., Kamaev D.N., Elyshev A.V., Andreev O.V.
Заглавие : Synthesis and properties of the NdSF compound, phase diagram of the NdF3–Nd2S3 system
Колич.характеристики :9 с
Место публикации : J. Solid State Chem. - 2024. - Vol. 333. - Ст.124640. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2024.124640. - ISSN 1095726X (eISSN)
Примечания : Cited References: 48. - This research was funded by the Tyumen Oblast Government as part of the West-Siberian Interregional Science and Education Center’s project No. 89-DON (3)The studies ab initio simulation of electron band structure, analysis of optical properties, XRD analysis was partially supported by "Priority-2030" program for the Siberian Federal University, and the state assignment of Kirensky Institute of Physics
Аннотация: The NdF3–Nd2S3 system attracts attention of researchers due to the possibility of using LnSF compounds (Ln = rare earth element) as possible new p- and n-type materials. The samples of this system were synthesized from NdF3 and Nd2S3. The NdSF compound belongs to the PbFCl structural type, P4/nmm space group, unit cell parameters: a = 3.9331(20) Å, c = 6.9081(38) Å. The experimentally determined direct and indirect NdSF bandgaps are equal to 2.68 eV and 2.24 eV. The electronic band structure was calculated via DFT simulation. The NdSF compound melts congruently at T = 1385 ± 10°С, ΔНm = 40.5 ± 10 kJ/mol, ΔS = 24.4 ± 10 J/mol. The NdSF microhardness is 455 ± 10 HV. Five phase transformations in the NdF3–Nd2S3 system were recorded by DSC; their balance equations were derived. The liquidus of the system calculated from the Redlich–Kister equation is fully consistent with the DSC data.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chukalina E. P., Jablunovskis A., Gudim I. A.
Заглавие : Study of the magnetic properties of neodymium and samarium iron borates by the method of erbium spectroscopic probe
Колич.характеристики :7 с
Место публикации : Opt. Spectrosc. - 2023. - Vol. 131, Is. 8. - P.630-636. - ISSN 0030400X (ISSN), DOI 10.1134/S0030400X23060024. - ISSN 15626911 (eISSN)
Примечания : Cited References: 30. - This paper was carried out under financial support of the Russian Science Foundation (grant № 19-12-00413)
Аннотация: Iron borates NdFe3(BO3)4 and SmFe3 (BO3)4 activated with 1% erbium, with ahuntite structure (space symmetry group R32) were investigated by the method of erbium spectroscopic probe. From an analysis of the temperature dependence of the transmission spectra in the region of the 4I15/2 → 4113/2 transition in the Er3+ ion, it was found that both studied compounds order antiferromagnetically at TN ≈ 33 K into an easy-plane magnetic structure. No other phase transitions were found.
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10.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Zvyagina G., Zhekov K., Zvyagin A., Bilych I., Gudim I. A., Temerov V. L., Volkov N. V.
Заглавие : Mag­netoelastic effects in the neodymium ferroborate
Коллективы : Moscow International Symposium on Magnetism
Место публикации : Moscow Int. Symp. on Magnet. (MISM-2011): Book of abstracts. - 2011. - Ст.23PO-K-27. - P.496-497
Примечания : Библиогр.: 3
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