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Вид документа : Однотомное издание
Шифр издания :
Автор(ы) : Loiko V. A., Konkolovich A. V., Miskevich A. A., Krakhalev M. N., Prishchepa O. O., Shabanov A. V., Zyryanov V. Ya.
Заглавие : Electro-optical response of a monolayer polymer dispersed nematic liquid crystal film doped with surfactant
Место публикации : Liquid Crystal Polymer Nanocomposites: Woodhead Publishing, 2022. - Chapter 7. - P.163-211. - , DOI 10.1016/B978-0-12-822128-0.00006-6
Примечания : Cited References: 86
Аннотация: Light scattering and transmission by a monolayer polymer dispersed liquid crystal film containing liquid crystal droplets with inhomogeneous anchoring of liquid crystal molecules at the polymer-droplet interface is considered theoretically and experimentally. The developed optical model is based on the anomalous diffraction and interference approximations of the theory of scattering of waves. It is applied to describe the interference quenching effect for the coherently transmitted light and electrically controllable symmetry breaking effect in small-angle structure of light scattered by film containing droplets with inhomogeneous anchoring. The analysis of transmittance and reflectance of the one-dimensional photonic crystals composed of monolayers is carried out. The formation of the photonic band gaps is analyzed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Hsiao Y. C., Hou C. T., Lee W., Zyryanov V. Y.
Заглавие : Multichannel photonic devices based on tristable polymer-stabilized cholesteric textures
Место публикации : Optics Express: Optical Society of America, 2011. - Т. 19, № 24. - С. 23952-23957. - ISSN 1094-4087, DOI 10.1364/OE.19.023952
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Гардымова, Анна Петровна, Тихонов, Алексей Яковлевич, Зырянов, Виктор Яковлевич
Заглавие : Оптическая мультистабильность в композиционном материале на основе полимера, жидкого кристалла и ионного сурфактанта при воздействии электрического поля
Место публикации : Перспективные материалы. - Москва: Общество с ограниченной ответственностью "Интерконтакт Наука", 2011. - № 4. - С. 32-35. - ISSN 1028-978X
Ключевые слова (''Своб.индексиров.''): cholesteric liquid crystal--polymer--ionic surfactant--optical multistability--холестерический жидкий кристалл--полимер--ионный сурфактант--оптическая мультистабильность
Аннотация: Разработан композиционный материал на основе полимера, жидкого кристалла (ЖК) и ионного сурфактанта, характеризующийся оптической мультистабильностью и механической гибкостью. Оптические свойства данного материала варьируются за счет переключения капель холестерического ЖК между различными структурными состояниями, остающимися стабильными после выключения управляющего электрического сигнала. Функциональным инструментом для управления ориентационной структурой капель холестерика внешним электрическим полем является наноразмерный слой ионного сурфактанта. Подобраны параметры электрических сигналов, переключающих капли в новые стабильные состояния, а также возвращающих их в исходную радиальную структуру.A composite material based on polymer, liquid crystal and ionic surfactant is developed, which is characterized by the optical multistability and mechanical flexibility. Optical properties of the material are varied by switching the cholesteric droplets between different structural states remaining stable after breaking the control electrical signal. Functional tool to control the orientational structure of cholesteric droplets by an external electric field is a nanosized layer of ionic surfactant. The parameters of electrical signals switching the droplets in new stable states and returning them in the initial radial structure are chosen.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Loiko V. A., Konkolovich A. V., Miskevich A. A., Zyryanov V. Ya., Maschke U.
Заглавие : Small-angle light scattering by monolayer of liquid crystal droplets in polymer matrix
Место публикации : Atti della Accademia Peloritana dei Pericolanti, Classe di Scienze Fisiche, Matematiche e Naturali. - 2011. - Т. 89, №SUPPL. 1. - ISSN 0365-0359, DOI 10.1478/C1V89S1P059. - ISSN 1825-1242(eissn)
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Loiko V. A., Konkolovich A. V., Misckevich A. A., Krakhalev M. N., Prishchepa O. O., Shabanov A. V., Zyryanov V. Ya.
Заглавие : Electro-optical response of a monolayer polymer dispersed nematic liquid crystal film doped with surfactant
Место публикации : Liquid crystal polymer nanocomposites/ ed.: P. M. Visakh [et al.]: Elsevier, 2022. - Chap. 7. - P.163-211. - (Woodhead publishing in materials). - ISBN 978-0-12-822128-0, DOI https://doi.org/10.1016/B978-0-12-822128-0.00006-6
Примечания : References: 86
Аннотация: Light scattering and transmission by a monolayer polymer dispersed liquid crystal film containing liquid crystal droplets with inhomogeneous anchoring of liquid crystal molecules at the polymer-droplet interface is considered theoretically and experimentally. The developed optical model is based on the anomalous diffraction and interference approximations of the theory of scattering of waves. It is applied to describe the interference quenching effect for the coherently transmitted light and electrically controllable symmetry breaking effect in small-angle structure of light scattered by film containing droplets with inhomogeneous anchoring. The analysis of transmittance and reflectance of the one-dimensional photonic crystals composed of monolayers is carried out. The formation of the photonic band gaps is analyzed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vijayamma R., Maria H. J., Thomas S., Shishatskaya E. I., Kiselev E. G., Nemtsev I. V., Sukhanova A. A., Volova T. G.
Заглавие : A study of the properties and efficacy of microparticles based on P(3HB) and P(3HB/3HV) loaded with herbicides
Место публикации : J. Appl. Polym. Sci. - 2022. - Vol. 139, Is. 10. - Ст.51756. - ISSN 00218995 (ISSN), DOI 10.1002/app.51756
Примечания : Cited References: 58. - This work was supported by Project “Agropreparations of the new generation: a strategy of construction and realization” (Agreement No 074-02-2018-328) in accordance with Resolution No 220 of the Government of the Russian Federation of April 9, 2010, “On measures designed to attract leading scientists to the Russian institutions of higher learning”. Instruments of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» were used
Аннотация: The wide use of pesticides in agriculture has caused uncontrolled distribution of these chemicals in the environment, calling for the development and investigation of new environmentally friendly formulations, which would reduce human impact on nature. In the present study, the metribuzin (MET), tribenuron-methyl (TBM), and fenoxaprop-P-ethyl (FPE) herbicides were encapsulated in microparticles of degradable microbial polymers – polyhydroxyalkanoates (PHAs) – of two types – poly-3-hydroxybutyrate [P(3HB)] and poly(3-hydroxybutyrate-co-3-hydroxyvalerate [P(3HB/3HV)]. The use of P(3HB) resulted in higher yields of microparticles (63% to 79%) and larger sizes of the particles, whose average diameter was 0.60 ± 0.06–0.75 ± 0.11 μm, while the average diameter of copolymer particles varied between 0.43 ± 0.12 and 0.55 ± 0.05 μm. Encapsulation efficiency was rather determined by the type of herbicide and its solubility, varying from 24.7% to 48.2%. In vitro herbicide release from microparticles to water was affected by herbicide solubility and PHA chemical composition. The readily soluble MET showed the highest release rate, and over 30 days, 64% and 78% of the encapsulated amounts were released from P(3HB) and P(3HB/3HV) microparticles, respectively. High herbicidal activity of microparticles loaded with metribuzin and tribenuron-methyl was demonstrated in the laboratory stands of the Elsholtzia ciliata weed plant.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Фейзер, Кристина Андреевна, Крахалев, Михаил Николаевич, Шабанов, Василий Филиппович, Зырянов, Виктор Яковлевич
Заглавие : Электрооптический отклик пленок капсулированного полимером нематика с коническими граничными условиями
Место публикации : Сиб. аэрокосм. журн. - 2021. - Т. 22, № 1. - С. 201-209. - ISSN 2587-6066, DOI 10.31772/2712-8970-2021-22-1-201-209
Примечания : Библиогр.: 16
Аннотация: Исследован электрооптический отклик пленок капсулированного полимером нематика с коническими граничными условиями. В каплях нематика формируется аксиал-биполярная конфигурация директора. Показано, что изначально ориентация осей симметрии структуры капель хаотичная как в плоскости образца, так и по отношению к нормали к подложкам. Приложенное напряжение U ориентирует биполярные оси капель параллельно электрическому полю, а процесс переориентации является пороговым только в случае исходно ортогональной ориентации биполярной оси и нормали к подложкам. Соответственно, в исходном состоянии образцы интенсивно рассеивают свет, а процесс отклика на электрическое поле имеет беспороговый характер. Исследовались образцы с толщиной пленки 5, 10, 20 и 30 мкм. Для всех исследуемых образцов характерно высокое значение максимального коэффициента пропускания и коэффициента контрастности, которые для пленки толщиной 30 мкм равны 84 % и 5536, соответственно, и достигаются при напряжении U = 12 В. Полученные результаты актуальны для использования в оптоэлектронных устройствах с низким энергопотреблением, которые требуются для развития энергосберегающих технологий в аэрокосмической технике.The electrooptic response of films of polymer dispersed nematic under conical boundary conditions has been investigated. An axial-bipolar director configuration is formed in nematic droplets. It has been shown that initially, the orientation of droplet’s bipolar axes is chaotic both in the sample plane and relative to the normal to the substrates. The applied voltage U orients the droplet’s bipolar axes parallel to the electric field and the reorientation process is threshold only when the bipolar axis is initially orthogonal to the substrate normal. Accordingly, the samples strongly scatter light in the initial state, and the optical response to an electric field is thresholdless. The samples with a film thickness of 5, 10, 20 and 30 μm have been studied. All the samples under study are characterized by a high transmittance and contrast ratio, which for a 30 μm sample are equal to 84 % and 5536, respectively, and achieved at U = 12 V. The results obtained are relevant for use in low-power optoelectronic devices required for the development of energy-saving technologies in aerospace engineering.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boyandin A. N., Sukhanova, Anna Alekseevna, Nikolaeva, Elena Dmitrievna, Nemtsev I. V.
Заглавие : Chemical modification of films from biosynthetic poly-3-hydroxybutyrate aimed to improvement of their surface properties
Коллективы : International Conference on Progress on Polymers and Composites , Ministry of Science and Higher Education of the Russian Federation [FEFE-2020-0015]
Место публикации : International Conference on Progress on Polymers and Composites (4th ; 26-28 Nov. 2020). Macromolecular Symposia. - 2021. - Vol. 395: 4th International Conference on Progress on Polymers and Composites (NOV 26-28, 2020, Electr. Network), Is. 1. - Ст.2000281. - ISSN 1022-1360, DOI 10.1002/masy.202000281. - ISSN 1521-3900(eISSN)
Примечания : Cited References: 11. - This work was carried out by the team of the scientific laboratory "Smart Materials and Structures" within the state assignment of the Ministry of Science and Higher Education of the Russian Federation for the implementation of the project "Development of multifunctional smart materials and structures based on modified polymer composite materials capable to function in extreme conditions" (No. FEFE-2020-0015). The surface of the samples was investigated using a scanning electron microscope Hitachi TM3000 in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS"
Аннотация: Films from biodegradable poly-3-hydroxybutyrate are treated with chemical reagents to improve their hydrophilicity and biocompatibility. Two approaches are tested: a single treatment with alkali, acids, oxidizing or reducing agents, and a step-by step treatment of the alkali pre-activated surface of polymer films with bromine water and amino-compounds (ammonia or triethylamine). The maximal level of hydrophilicity (the lowest water contact angle and the highest polar component of the surface free energy) is registered after a single treatment with NaOH and after the step-by-step treatment. These samples also showed the best adhesion of mouse fibroblasts of NIH 3T3 line on the film surface. So, the proposed methods can be used to enhance hydropilicity and biocompatibility of biopolymer surface.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Volova T. G., Golubev A. I., Nemtsev I. V., Lukyanenko A. V., Dudaev A. E., Shishatskaya E. I.
Заглавие : Laser processing of polymer films fabricated from phas differing in their monomer composition
Коллективы : "Biotechnology of new materials - environment - quality of life", International scientific conference, "Биотехнология новых материалов - окружающая среда - качество жизни", международная научная конференция
Место публикации : Биотехнология новых материалов - окружающая среда - качество жизни: материалы IV Международной научной конференция : Красноярск, 10–13 октября 2021 г. - Красноярск, 2021. - С. 51-54
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10.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Krakhalev M.N., Prishchepa О.О., Gardymova А.Р., Sutormin V.S., Zyryanov V.Ya., Fee W.
Заглавие : Electrooptical characteristics of polymer dispersed liquid crystal films
Коллективы : International Display Manufacturing Conference
Место публикации : International Display Manufacturing Conference (IDMC’ll). - 2011. - С. 52-53
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kudashev S. V., Kondrasenko A. A., Maiulev A. N., Babkin V. A., Belousova V. S., Andreev D. S., Zheltobryukhov V. F., Kuznetsova N. V.
Заглавие : Modification of polycaproamide composites based on 1H,1H,13H-rihydroperfluorotridecan-1-ol and montmorillonite
Место публикации : Fibre Chem. - 2022. - Vol. 53, Is. 5. - P.291-295. - ISSN 00150541 (ISSN), DOI 10.1007/s10692-022-10287-5
Примечания : Cited References: 24
Аннотация: Modification of polycaproamide by 1H,1H,13H-trihydroperfluorotridecan-1-ol immobilized on montmorillonite produced an F-containing polymer composite. The structure of the resulting composite was investigated using x-ray structure analysis and solid-state 19F NMR spectroscopy. The polymorphous composition of this heterochain polymer was shown to reorganize to enhance its thermal stability and diminish its flammability. Possible mechanisms for the stabilizing effect of the used modifier that were related to the involvement of organo-clay paramagnetic centers in the binding of macroradicals formed during thermal decomposition of macromolecular chains were discussed.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Сутормин, Виталий С., Крахалев, Михаил Н., Прищепа, Оксана О.
Заглавие : Температурно индуцированные изменения конфигурации директора в каплях нематика, диспергированного в поли- винилпирролидоне
Место публикации : Журнал Сибирского федерального университета. Серия: Математика и физика. - Красноярск: Федеральное государственное автономное образовательное учреждение высшего образования Сибирский федеральный университет, 2009. - Т. 2, № 3. - С. 352-359. - ISSN 1997-1397
Ключевые слова (''Своб.индексиров.''): граница раздела--interface--polymer dispersed liquid crystals--nematic--surfactant--surface anchoring--director configuration--капсулированные полимером жидкие кристаллы--нематик--сурфактант--поверхностное сцепление--конфигурация директора
Аннотация: В работе изучены преобразования конфигурации директора в каплях нематика, вызванные тер- моиндуцированной модификацией граничных условий. Исследования проводились для нематиче- ского жидкого кристалла 5СВ (4-н-пентил-4-цианобифенил), который допировался сурфактан- том лецитином, а затем диспергировался в поливинилпирролидоне. Показано, что при нагре- вании граничные условия изменяются от планарных к гомеотропным, что приводит к транс- формации конфигурации директора в капле нематика. При охлаждении образца наблюдалось об- ратное изменение поверхностного сцепления от гомеотропного к планарному. В обоих случаях ориентационно-структурные превращения могут происходить по двум различным сценариям.The transformations of the director configuration within the nematic droplets induced by temperature modification of boundary conditions have been studied. Nematic liquid crystal 5CB (4-n-penthyl-4- cyanobiphenyl) doped with lecithin and dispersed in polyvinylpyrrolidone has been tested. As was shown, under heating the boundary conditions are changed from planar to homeotropic. It results in transformation of the director configuration in the nematic droplets. The inverse modification of the surface anchoring from homeotropic to planar has been observed at cooling. In both cases the transformations of orientational structure may occur in two different scenarios.
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13.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Feizer K., Krakhalev M. N., Prishchepa O. O., Sutormin V. S., Loiko V. A., Zyryanov V. Ya.
Заглавие : Electro-optical properties of the polymer dispersed liquid crystal films with conical boundary conditions
Коллективы : International Liquid Crystal Conference
Место публикации : Abstracts of 28th International Liquid Crystal Conference (ILCC 2022). - 2022. - Ст.PF.326
Примечания : Cited References: 2
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Murueva A. V., Shershneva A. M., Nemtsev I. V., Shishatskaya E. I., Volova T. G.
Заглавие : Collagen conjugation to carboxyl-modified poly(3-hydroxybutyrate) microparticles: preparation, characterization and evaluation in vitro
Место публикации : J. Polym. Res. - 2022. - Vol. 29, Is. 8. - Ст.324. - ISSN 10229760 (ISSN), DOI 10.1007/s10965-022-03181-5
Примечания : Cited References: 45. - This work was supported by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020–0006
Аннотация: The objective of this study was to produce and characterize collagen conjugated poly(3-hydroxybutyrate) (P3HB) microparticles. The double emulsion solvent evaporation technique was used to fabricate biopolymer microparticles. Alkaline hydrolysis method was used for carboxylation of P3HB microparticles followed by collagen (type I) conjugation using 1-ethyl-3-(3-dime-thylaminopropyl) carbodiimide and N-hydroxysuccinimide cross linkers. The successful chemical modification of P3HB-MP surface was evidenced by XPS analysis and FTIR spectroscopy, confirming an increase in the number of carboxyl groups and covalent bonding of collagen on the surface of functionalized P3HB microparticles (Col-P3HB-MPs). The amount of collagen present on Col-P3HB-MPs microparticles was quantified by the Lowry method. The average diameter and zeta-potential of microparticles were found to be dependent upon the method of preparation. The absence of cytotoxicity of modified Col-P3HB-MPs to fibroblast NIH 3T3 cells in vitro was corroborated by results of MTT assay. Staining with the fluorescent dye showed enhanced adhesion of fibroblasts onto Col-P3HB-MPs compared to the unmodified P3HB-MPs.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gardymova A. P., Krakhalev M. N., Rudyak V. Yu., Barbashov V. A., Zyryanov V. Ya.
Заглавие : Polymer-dispersed cholesteric liquid crystal under homeotropic anchoring: Electrically induced structures with λ1/2-disclination
Место публикации : Polymers. - 2022. - Vol. 14, Is. 7. - Ст.1454. - ISSN 20734360 (ISSN), DOI 10.3390/polym14071454
Примечания : Cited References: 44. - This research was funded by Russian Science Foundation, Grant No. 20-72-10038
Аннотация: Orientational structures of polymer-dispersed cholesteric liquid crystal under homeotropic anchoring and their transformations under the action of an electric field are studied. The switching of cholesteric droplets between different topological states are experimentally and theoretically demonstrated. Structures with λ+1/2-disclination are found and considered. These structures are formed during the transformation of a twisted toroidal configuration induced by a decrease in the electric field when a relative chiral parameter N06.3. The transformation of the initial structure with a bipolar distribution of the helix axis into a twisted toroidal configuration and then into a structure with λ+1/2-disclination is investigated in detail. The behavior of these structures under the influence of an external electric field, as well as the appearance of structures with λ−1/2-disclination, are studied. Obtained results are promising for the development of optical materials with programmable properties.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Slabko V.V., Volova T.G., Shishatskaya E.I., Kuzubov A.A., Krasnov P.O.
Заглавие : Surface modification of bioresorbable polymer scaffolds by laser treatment
Место публикации : Biophysics. - 2010. - Vol. 55, Is. 2. - С. 234-238. - ISSN 00063509 (ISSN), DOI 10.1134/S0006350910020120
Ключевые слова (''Своб.индексиров.''): hydrophilicity--laser irradiation--microbial biocompatible and biodegradable polymers--polyhydroxybuturate--surface properties
Аннотация: The effect of laser irradiation on the properties of the surface of films prepared from a bioresorbable polymer poly(hydroxybuturate) has been studied. To determine the spectral region of the polymer optimal for the effective action of radiation on electron molecular bonds, theoretical investigations have been performed, which have shown that, for modifying the surface of PHB scaffolds, it is expedient to use a vacuum laser at a wavelength of 160 nm. Using laser irradiation at a power from 3 to 30 W, a series of films with modified surface, from roughnesses to perforations, have been obtained. The microstructure and properties of the film surface depending on the mode of irradiation have been examined, and conditions have been found under which the contact marginal angles of film wetting with water can be decreased to 50° (compared with 76-80° in starting products). Thus, conditions of laser treatment of PHB scaffolds have been theoretically substantiated and experimentally realized that provide a beneficial effect on the properties of the surface without destroying the structure of the material. © 2010 Pleiades Publishing, Ltd.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Inverse mode of ion-surfactant method of director reorientation inside nematic droplets
Место публикации : Mol. Cryst. Liquid Cryst. - 2009. - Vol. 512, Is. 1. - P.1998-2003. - ISSN 1542-1406, DOI 10.1080/15421400903050814
Примечания : Cited Reference Count: 8. - Гранты: This work was partially supported by the grants Nos. NSh-3818.2008.3; 02.740.11.0220, and No. 08-03-01007 of RFBR, and Nos. 27.1; 110; 144 of SB RAS. M. Krakhalev acknowledges the financial support from K. I. Zamaraev MBN Foundation. O. Prishchepa acknowledges the financial support from Russian Science Support Foundation.Финансирующая организация: RFBR [NSh-3818.2008.3, 02.740.11.0220, 08-03-01007]; SB RAS [27.1; 110; 144]; Zamaraev MBN Foundation; Russian Science Support Foundation
Ключевые слова (''Своб.индексиров.''): electrically commanded surfaces--ion surfactant--nematic--polymer dispersed liquid crystals--surface anchoring--electrically commanded surfaces--ion surfactant--nematic--polymer dispersed liquid crystals--surface anchoring--applied voltages--crossed polarizers--director fields--director reorientation--droplet structure--electrically commanded surfaces--high concentration--homeotropic--initial state--ionic modification--liquid-crystal droplets--nematic droplets--nematic polymer--surface-active cations--surface-anchoring--trimethyl--ammonium compounds--cationic surfactants--crystals--drop formation--dyes--ionization of liquids--ions--liquid crystal displays--liquid crystals--liquids--nematic liquid crystals
Аннотация: Inverse mode of a novel electrooptical effect caused by the ionic modification of boundary conditions has been studied for liquid crystal droplets. We have considered the droplets of nematic 5CB doped with cationic surfactant cetyl-trimethyl-ammonium-bromide and dispersed in polyvinyl alcohol. In the initial state the surface anchoring was normal on the whole interface due to the high concentration of homeotropic surfactant. Applied voltage results in the purification of a section of the interface from the surface-active cations thereby restoring here a tangential anchoring and stimulating the significant transformation of droplet structure. At that three different types of director field distribution can be realized within the same droplet. The proper textures of the droplet both in the crossed polarizers and without analyzer are considered.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Parshin A. M., Zyryanov V. Ya., Shabanov V. F., Nazarov V. G.
Заглавие : Bipolar-homogeneous structural phase transition in nematic droplets formed in the polymer matrix in a magnetic field
Место публикации : Crystallogr. Rep. - New York: Maik Nauka/Interperiodica/Springer, 2009. - Vol. 54, Is. 7. - С. 1191-1196. - DEC. - ISSN 1063-7745, DOI 10.1134/S1063774509070098
Примечания : Cited Reference Count: 19. - Гранты: This study was supported by the Council on Grants from the President of the Russian Federation for the Support of Leading Scientific Schools ( grant no. NSh-3818.2008.3), the Russian Foundation for Basic Research ( project no. 08-03-01007), the Presidium of the Russian Academy of Sciences ( project no. 27.1), and the Siberian Branch of the Russian Academy of Sciences ( project nos. 110 and 144).Финансирующая организация: President of the Russian Federation [NSh-3818.2008.3]; Russian Foundation for Basic Research [08-03-01007]; Russian Academy of Sciences [27.1, 110, 144]
Предметные рубрики: DISPERSED LIQUID-CRYSTALS
FRANK CONSTANTS
ALIGNMENT
Ключевые слова (''Своб.индексиров.''): bipolar configuration--bipolar structure--cyanobiphenyls--homogeneous structure--mutual transformations--nematic director--nematic droplets--order parameter--poly(vinyl butyral)--structural phase transition--temperature range--thermal fluctuations--crystal structure--drop formation--liquid crystals--magnetic fields--nematic liquid crystals--phase transitions
Аннотация: The phase transition from the bipolar structure to the homogeneous structure in droplets formed from the nematic liquid crystal 4-n-pentyl-4'-cyanobiphenyl in poly(vinyl butyral) in the presence of a magnetic field has been investigated. The phase transition is associated with the expansion of the regions with a tilted orientation of the director in the vicinity of defects (the disappearance of boojums) and with the alignment of the nematic director lines in the bulk of the droplet in the direction of the magnetic field. In the temperature range T = 24-34A degrees C, cyclic mutual transformations between the bipolar configuration of the nematic director and the homogeneous structure, which have a period of similar to 0.5-3.5 s and result from thermal fluctuations of the order parameter, are observed in droplets 3-15 A mu m in size after the forming field is switched off.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhila N. O., Sapozhnikova K. Yu., Kiselev E. G., Vasiliev A. D., Nemtsev I. V., Shishatskaya E. I., Volova T. G.
Заглавие : Properties of degradable polyhydroxyalkanoates (PHAs) synthesized by a new strain, Cupriavidus necator IBP/SFU-1, from various carbon sources
Место публикации : Polymers. - 2021. - Vol. 13, Is. 18. - Ст.3142. - ISSN 20734360 (ISSN), DOI 10.3390/polym13183142
Примечания : Cited References: 78. - This work was financially supported by Project “Agropreparations of the new generation: a strategy of construction and realization” (Agreement No 075-15-2021-626) in accordance with Resolution No 220 of the Government of the Russian Federation of 9 April 2010, “On measures designed to attract leading scientists to the Russian institutions of higher learning” (strain isolation, polymer synthesis and investigation), and by the State Assignment of the Ministry of Science and Higher Education of the Russian Federation No. FSRZ-2020-0006 (study of film properties)
Аннотация: The bacterial strain isolated from soil was identified as Cupriavidus necator IBP/SFU-1 and investigated as a PHA producer. The strain was found to be able to grow and synthesize PHAs under autotrophic conditions and showed a broad organotrophic potential towards different carbon sources: sugars, glycerol, fatty acids, and plant oils. The highest cell concentrations (7–8 g/L) and PHA contents were produced from oleic acid (78%), fructose, glucose, and palm oil (over 80%). The type of the carbon source influenced the PHA chemical composition and properties: when grown on oleic acid, the strain synthesized the P(3HB-co-3HV) copolymer; on plant oils, the P(3HB-co-3HV-co-3HHx) terpolymer, and on the other substrates, the P(3HB) homopolymer. The type of the carbon source influenced molecular-weight properties of PHAs: P(3HB) synthesized under autotrophic growth conditions, from CO2, had the highest number-average (290 ± 15 kDa) and weight-average (850 ± 25 kDa) molecular weights and the lowest polydispersity (2.9 ± 0.2); polymers synthesized from organic carbon sources showed increased polydispersity and reduced molecular weight. The carbon source was not found to affect the degree of crystallinity and thermal properties of the PHAs. The type of the carbon source determined not only PHA composition and molecular weight but also surface microstructure and porosity of the polymer films. The new strain can be recommended as a promising P(3HB) producer from palm oil, oleic acid, and sugars (fructose and glucose) and as a producer of P(3HB-co-3HV) from oleic acid and P(3HB-co-3HV-co-3HHx) from palm oil.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Loiko V. A., Konkolovich A. V., Miskevich A. A., Krakhalev M. N., Prishchepa O. O., Zyryanov V. Ya.
Заглавие : Small-angle scattering and radiation polarization by a stretched polymer film with nematic liquid crystal droplets having a single-domain structure
Коллективы : Belarusian Republican Foundation for Fundamental Research [F18RA-003]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of Krasnoyarsk krai; Krasnoyarsk Krai Foundation of Science [18-42-243006]
Место публикации : Opt. Spectrosc. - 2020. - Vol. 128, Is. 3. - P.331-338. - ISSN 0030-400X, DOI 10.1134/S0030400X20030121. - ISSN 1562-6911(eISSN)
Примечания : Cited References: 24. - This work was carried out within the framework of the agreement on interacademic collaboration between the National Academy of Sciences of Belarus and Siberian Branch of the Russian Academy of Sciences. It was supported by the Belarusian Republican Foundation for Fundamental Research (project no. F18RA-003). M.N. Krakhalev acknowledges the support of the Russian Foundation for Basic Research, the Government of Krasnoyarsk krai, and Krasnoyarsk Krai Foundation of Science (grant no. 18-42-243006).
Предметные рубрики: IONIC MODIFICATION
LIGHT
Аннотация: The coefficient of directed transmittance of a stretched polymer-dispersed liquid crystal film with a defect-free single-domain liquid crystal droplet structure formed by a stretched surfactant-doped film and the polarization degree of forward-transmitted light in the visible and near-infrared spectrum ranges are studied. Results are presented for the 5CB, E7, and E44 nematic liquid crystals. Dependences of the transmission coefficient and polarizing ability of the film on the photodetector field of view are studied. Relationships allowing one to determine film parameters at which the transmission coefficient and polarizing ability of the films simultaneously reach values close to limit ones (0.5 and ±1.0, respectively) are obtained in the Foldy–Twersky and anomalous diffraction approximations.
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