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Invar effect and solid-state synthesis in Ni/Fe(001)/MgO(001) thin films: structural and magnetic studies / V. G. Myagkov, V. C. Zhigalov, L. E. Bykova, G. N. Bondarenko // Байкальская международная конференция”Магнитные материалы: Новые технологии”, Россия, Иркутск, 2008, С.56

Доп.точки доступа:
Myagkov, V. G.; Мягков, Виктор Григорьевич; Zhigalov, V. S.; Жигалов, Виктор Степанович; Bykova, L. E.; Быкова, Людмила Евгеньевна; Bondarenko, G. N.; Бондаренко, Галина Николаевна
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Influence of growth environment on structural and optical characteristics of higher plants / E. Bukhanov, V. N. Shikhov, V. V. Velichko [et al.] // AIP Conf. Proc. - 2024. - Vol. 2924: Proceedings of the 3rd International Advances in Applied Physics and Materials Science Congress & Exhibition, Is. 1. - Ст. 040003, DOI 10.1063/5.0181655. - Cited References: 26 . - ISSN 0094-243X. - ISSN 1551-7616. - ISSN 978-07354
Аннотация: Two barley samples were taken for the study – one grown in the field and the other in a special chamber under intensive light. Chloroplasts structure was obtained during electron microscopy process. The results showed that the maximum quantum yield of photosystem II in both samples was in the range of values typical for normal physiological state of plants. At the same time, electron transport speed comparison shows that electrons are transferred 1.7 times faster in the vegetation chamber compared to field environment. Such difference is confirmed by the results of microscopy performed with flag leaves tissue samples of barley grown under intensive light in a chamber and in the field. A grana structure significantly denser and better organized was observed in chloroplasts of barley grown in chamber. This study shows a clear connection between the environment, the ordering of thylakoid structures and fluorescent indicators of photosynthesis.

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Держатели документа:
Kirensky Institute of Physics FRC, «KSC of SB RAS», Krasnoyarsk, 660036, Russian Federation
Federal Research Center, «KSC of SB RAS», Krasnoyarsk, Russian Federation
Institute of Biophysics FRC, «KSC of SB RAS», Krasnoyarsk, 660036, Russian Federation
Krasnoyarsk Research Institute of Agriculture FRC, «KSC of SB RAS», Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Bukhanov, E. R.; Буханов, Евгений Романович; Shikhov, V. N.; Velichko, V. V.; Lipshin, A. G.; Surin, N. A.; International Advances in Applied Physics and Materials Science Congress and Exhibition(3 ; April 22-28, 2022 ; Oludeniz, Turkey)
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Chemical pressure as an effective tool for tuning the structural disordering and barocaloric efficiency of complex fluorides (NH4)3MF7 (M: Sn, Ti, Ge, Si) / I. N. Flerov, M. V. Gorev, E. V. Bogdanov, N. M. Laptash // J. Phys. D: Appl. Phys. - 2024. - Vol. 57, Is. 17. - Ст. 175301, DOI 10.1088/1361-6463/ad211b. - Cited References: 39. - The study was supported by a Grant from the Russian Science Foundation No. 23-22-00115, https://rscf.ru/project/23-22-00115/ . - ISSN 0022-3727. - ISSN 1361-6463
Кл.слова (ненормированные):
fluorides -- phase transformation -- phase diagram -- entropy -- pressure -- barocaloric effect
Аннотация: Double fluoride salts (NH4)3M4+F7 (M4+: Sn, Ti, Ge, Si) demonstrate a high efficiency of using chemical pressure as a tool for control and tuning structural ordering/disordering, sensitivity to hydrostatic pressure, successions of the phase transitions, etc and, as a result, for purposeful variation within a wide range of parameters of barocaloric effect (BCE). The conventional and inverse BCEs near the triple points were found on the T − p phase diagrams, combination of which can be used to construct original cooling cycle in narrow temperature and pressure ranges. Reconstructive transformation between two cubic phases, Pm3-m ↔ Pa3-, realized in (NH4)3SnF7 at atmospheric pressure and in (NH4)3TiF7 at p ˃ 0.4 GPa are characterized by rather low thermal hysteresis, δT0 = 1 K, and a great entropy change, ΔSBCE = 110–152 J (kg · K)−1, depending on the size of the central atom. At above 300–350 K, a contribution to BCE associated with the regular thermal expansion of the crystal lattice becomes comparable to entropy and temperature changes under pressure in the region of the phase transitions. An analysis of the absolute, relative and integral barocaloric characteristics of (NH4)3M4+F7 compounds showed their high competitiveness with respect to other barocaloric materials considered as promising solid-state refrigerants.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Institute of Engineering Physics and Radioelectronics, Siberian Federal University, 660074 Krasnoyarsk, Russia
Institute of Engineering Systems and Energy, Krasnoyarsk State Agrarian University, 660049 Krasnoyarsk, Russia
Institute of Chemistry, Far Eastern Department of RAS, 690022 Vladivostok, Russia

Доп.точки доступа:
Flerov, I. N.; Флёров, Игорь Николаевич; Gorev, M. V.; Горев, Михаил Васильевич; Bogdanov, E. V.; Богданов, Евгений Витальевич; Laptash, N. M.
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Solid solution structural engineering enhances the luminescence of SrMgAl10O17:Cr3+ for agricultural lighting / Y. Ma, W. Liao, B. Quan [et al.] // J. Lumin. - 2024. - Vol. 270. - Ст. 120553, DOI 10.1016/j.jlumin.2024.120553. - Cited References: 46. - The authors would like to gratefully acknowledge funds from the Key R & D Projects in Hunan Province (2021SK2047, 2022NK2044), the Wangcheng Science and Technology Plan (KJ221017), the Science and Technology Innovation Program of Hunan Province (2022WZ1022). The work was supported by the Ministry of Science and Higher Education of the Russian Federation as part of the World-class Research Center program: ‘‘Advanced Digital Technologies’’, contract no. 075-15-2020-935. Research Foundation of Education Bureau of Hunan Province, China (22B0211) . - ISSN 0022-2313. - ISSN 1872-7883
Кл.слова (ненормированные):
Optical material -- Indoor plant cultivation -- Far-red light -- SrMgAlO
Аннотация: Lead-free non-rare earth oxide phosphors have attracted wide attention due to their environmental protection, sustainability, and potential to replace halides and fluorides in the field of plant lighting. Among them, the Cr3+-excited aluminate phosphor exhibits high brightness, high thermal stability, and far red to near-infrared (NIR) emission due to the influence of the crystal field strength (CFS). This property gives rise to a variety of strategies used to modulate the CFS, for example, single ion substitution, chemical unit co-substitution, etc. Here, we chose the substitution of a single ion, with [BaO6] gradually replacing [SrO6] to form a solid solution. Their structural characteristics and the local structure of Cr3+ are studied and discussed. The device is packaged to evaluate the feasibility of the material for practical application. The prepared phosphor had a bright far-red light emission of 693 nm under blue light excitation, and this spectrum strongly matched the absorption of plant phytochrome PFR. This work provides the design principle of far red light emission activated by Cr3+ aluminate solid solution, which can inspire further research on pc-LED lights for plant lighting.

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Держатели документа:
School of Chemistry and Materials Science, Hunan Agricultural University, Changsha 410128, PR China
Hunan Optical Agriculture Engineering Technology Research Center, Changsha 410128, PR China
World-Class Research Center “Advanced Digital Technologies”, University of Tyumen, Tyumen 625003, Russia
Dongguan Ledstar Optoelectronics Technology Co., Ltd, Dongguan, 523000, PR China

Доп.точки доступа:
Ma, Y.; Liao, W.; Quan, B.; Kong, Z.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Zolotov, A.; Cheng, M.; Chen, X.; Zhou, Zh.; Xia, M.
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Structural, electronic, and optical properties of ferroelectric hybrid (Me2NH2)[NaFe(CN)5(NO)] crystal: Density functional theory simulation / S. Krylova, W. -J. Xu, J. Rocha, A. Kholkin // Mater. Today Commun. - 2024. - Vol. 40. - Ст. 109623, DOI 10.1016/j.mtcomm.2024.109623. - Cited References: 50. - This work was developed within the scope of the project CICECOAveiro Institute of Materials, UIDB/50011/2020 (DOI 10.54499/UIDB/50011/2020), UIDP/50011/2020 (DOI 10.54499/UIDP/50011/2020) and LA/P/0006/2020 (DOI 10.54499/LA/P/0006/2020), financed by national funds through the FCT/MCTES (PIDDAC). W-JX, JR, and AK were supported by the Fundação para a Ciência e a Tecnologia (FCT) through the project ‘‘PhotoMultiFerro’’ (PTDC/CTM-CTM/4044). SK acknowledges the support by the state assignment of the Kirensky Institute of Physics FRC KSC SB RAS. We would like to express our gratitude to Prof. Pierre Cazade for the valuable insights and constructive discussions he has provided . - ISSN 2352-4928
Кл.слова (ненормированные):
Sodium nitroprusside -- Density functional theory -- Electronic properties -- Hybrid crystal
Аннотация: Utilizing density functional theory (DFT), we embarked on a comprehensive investigation of the structural, electronic, and optical properties characteristic of the ferroelectric hybrid (Me2NH2)[NaFe(CN)5(NO)] crystal. The geometry of the crystal structure in the Pna21 phase was optimized. We simulated the electronic band structure within the first Brillouin zone. The calculated band gap for the indirect U-X transition is 2.401 eV, indicative of a wide band gap semiconductors. We also simulated the density of electronic states across the Brillouin zone. The simulation of the electronic structure revealed that the crystal comprises both ionic and covalent bonds. We accurately predicted various optical parameters including the dielectric function, conductivity, reflectivity, loss function, absorption, and refractive index. The reflectivity of the crystal does not exceed 21 percent. All calculated optical properties of the (Me2NH2)[NaFe(CN)5(NO)] crystal are anisotropic.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Department of Chemistry & CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal
Department of Physics & CICECO – Aveiro Institute of Materials, University of Aveiro, 3810-193, Aveiro, Portugal

Доп.точки доступа:
Krylova, S. N.; Крылова, Светлана Николаевна; Xu, W.-J.; Rocha, J.; Kholkin, A.
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    Unveiling temperature-induced structural phase transition and luminescence in Mn2+-doped Cs2NaBiCl6 double perovskite / S. Banerjee, S. Saikia, M. S. Molokeev, A. Nag // Chem. Mater. - 2024. - Vol. 36, Is. 9. - P. 4750-4757, DOI 10.1021/acs.chemmater.4c00514. - Cited References: 49. - Authors acknowledge Dr. Arup Rath’s lab NCL Pune and SAIF-IIT Bombay for diffuse reflectance spectroscopy and ICP-AES measurements, respectively. A.N. acknowledges Science & Engineering Research Board, India, for Swarnajayanti Fellowship (SB/SJF/2020-21/02), and BRICS grant (e-27558) of the Department of Science and Technology, India. Authors acknowledge the Department of Science and Technology India (FIST program, SR/FST/CS-II/2019/105) for temperature-dependent powder XRD and EPR data. S.B. is grateful to IISER Pune for a research fellowship. S.S. acknowledges Prime Minister’s Research Fellowship (PMRF), Ministry of Education, India. M.M. acknowledges the Russian Science Foundation, grant 24-43-00006 . - ISSN 0897-4756. - ISSN 1520-5002
   Перевод заглавия: Обнаружение температурно-индуцированного структурного фазового перехода и люминесценции в двойном перовските Cs2NaBiCl6, легированном Mn2+
Аннотация: Halide double perovskites like Cs2NaBiCl6 are good host materials for luminescent dopants like Mn2+. The nature of photoluminescence (PL) depends on the local structure around the dopant ion, and doping may sometimes influence the global structure of the host. Here, we unveil the correlation between the temperature-induced (global) structural phase transition of Mn2+-doped Cs2NaBiCl6 with the local structure and PL of the Mn2+ dopant. X-ray diffraction analysis shows Mn2+-doped Cs2NaBiCl6 is in a cubic (Fm3m) phase between 300 and 110 K, below which the phase changes to tetragonal (I4/mmm), which persists at least until 15 K. The small (∼1%) doping amount does not alter the phase transition behavior of Cs2NaBiCl6. Importantly, the phase transition does not influence the Mn2+ d-electron PL. The PL peak energy, intensity, spectral width, and lifetime do not show any signature of the phase transition between 300–6 K. The hyperfine splitting in temperature-dependent electron paramagnetic spectra of Mn2+ ions also remain unchanged across the phase transition. These results suggest that the global structural phase transition of the host does not influence the local structure and emission property of the dopant Mn2+ ion. This structure–property insight might be explored for other transition-metal- and lanthanide-doped halide double perovskites as well. The stability of dopant emission regardless of the structural phase transition bodes well for their potential applications in phosphor-converted light emitting diodes.

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Держатели документа:
Department of Chemistry, Indian Institute of Science Education and Research (IISER), Pune, 411008, India
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk 660036, Russia
Institute of Engineering Physics and Radioelectronic, Siberian Federal University, Krasnoyarsk, 660041 Russia

Доп.точки доступа:
Banerjee, S.; Saikia, S.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Nag, A.
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    Solid state synthesis, structural, DFT and spectroscopic analysis of EuAl3(BO3)4 / A. S. Oreshonkov, A. S. Aleksandrovsky, O. D. Chimitova [et al.] // Mater. Chem. Phys. - 2024. - Vol. 320. - Ст. 129400, DOI 10.1016/j.matchemphys.2024.129400. - Cited References: 55. - The work was carried out within the state assignment No FWES-2024-0003 of Kirensky Institute of Physics. This work was partially supported by the state order of BINM SB RAS (0273-2021-0008). The samples for this research were synthesized using equipment of the CCU BINM SB RAS. The reflectance spectrum was obtained at the Center for Optical and Laser Materials Research of Research park of St. Petersburg State University. The SEM measurements were performed at Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" . - ISSN 0254-0584. - ISSN 1879-3312
   Перевод заглавия: Твердофазный синтез, структурный, квантово-химический (DFT) и спектроскопический анализ EuAl3(BO3)4
Кл.слова (ненормированные):
EuAl(BO) -- Huntite -- X-ray diffraction -- SEM -- DFT -- Charge transfer -- Raman -- Infrared -- Luminescence
Аннотация: Huntite-like borates are versatile and promising materials with wide range of applications in frequency conversion, UV light generation, lighting, displays, quantum information storage, and more, demonstrated by their various properties and uses in scientific research. In this work, EuAl3(BO3)4 powder was prepared through multi-stage solid-state reaction method using high-purity starting reagents: Eu2O3, Al2O3 and H3BO3, considering a 20 wt% excess of H3BO3 to compensate for B2O3 volatilization. Obtained samples undergo several treatments at varying temperatures and their phase purity is subsequently verified through powder X-ray diffraction analysis. The scanning electron microscopy reveals that resulting EuAl3(BO3)4 powder consists of granules exhibiting irregular morphologies with dimensions of 0.5–8 μm. The electronic band structure of EuAl3(BO3)4, calculated using the GGA PBE method, reveals f-states of Eu near 4 eV. These states do not produce emphasized peaks on simulated absorbance spectra. Using of DFT + U for the f-states of Eu pushed up f-bands above 6 eV and the charge transfer from p-O to d-Eu was obtained (Egdirect = 5.63 eV, Egindirect = 5.37 eV using Ueff = 4 eV). The variation of Ueff has a weak influence on the position of the bottom of the conduction band. The experimental bandgaps of EuAl3(BO3)4 crystalline powder, both direct and indirect, are found to be 3.96 and 3.67 eV, correspondingly. These values are lower than theoretical values what is associated with limitations of DFT calculations involving f electrons. The Raman spectrum of EuAl3(BO3)4 powder is discussed, detailing the contributions of different ions to specific spectral bands. Investigation of high-resolution luminescence spectra shows the possibility to estimate the content of defects by the testing the violation of the prohibition of ultranarrow 5D0 → 7F0 line that is forbidden in the ideal crystalline structure of trigonal EuAl3(BO3)4.

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Держатели документа:
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
School of Engineering and Construction, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Coherent Optics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Oxide Systems, Baikal Institute of Nature Management, SB RAS, Ulan-Ude, 670047, Russia
Center for Optical and Laser Materials Research, Saint-Petersburg State University, Saint-Petersburg, 199034, Russia
Emanuel Institute of Biochemical Physics of Russian Academy of Sciences, Moscow, 119334, Russia
Plekhanov Russian University of Economics, Moscow, 117997, Russia
Moscow Institute of Physics and Technology, Dolgoprudny, 141700, Russia
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
School of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russia
Institute of Automation and Electrometry, Russian Academy of Sciences, Novosibirsk, 630090, Russia
Department of Molecular Electronics, Federal Research Center Krasnoyarsk Science Center of the Siberian Branch of the Russian Academy of Sciences, Krasnoyarsk, 660036, Russia
Institute of Fundamental Biology and Biotechnology, Siberian Federal University, Krasnoyarsk, 660041, Russia

Доп.точки доступа:
Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chimitova, O.D.; Pankin, D.V.; Popov, Z.I.; Sukhanova, E.V.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Adichtchev, S.V.; Pugachev, A.M.; Nemtsev, I. V.; Немцев, Иван Васильевич
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Shchapova, Yuliya V..
Structural characteristics of radiation-amorphized ZrSiO4:U,Th according to Raman spectroscopy of Boson peak / Yu. V. Shchapova, A. S. Krylov, S. L. Votyakov // J. Raman. Spectrosc. - 2023. - Vol. 54, Is. 6. - P. 662-673, DOI 10.1002/jrs.6526. - Cited References: 66. - The study was carried out within IGG UB RAS State assignment, registration number 123011800012-9 (YVS and SLV). The authors thank Dmitry Zamyatin for performing electron probe microanalysis of zircon chemical composition. The authors are grateful to Olga Galakhova for X-ray diffraction measurements. The equipment of the «Geoanalitik» shared research facilities of the IGG UB RAS was used, the re-equipment and comprehensive development of which is financially supported by the grant of the Ministry of Science and Higher Education of the Russian Federation, Agreement No. 075-15-2021-680 (YVS and SLV). The temperature Raman experiments were performed in the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center ‘Krasnoyarsk Science Center SB RAS’ . - ISSN 0377-0486. - ISSN 1097-4555
Кл.слова (ненормированные):
amorphous-crystalline structure -- Boson peak -- radiation damage -- zircon
Аннотация: The structure of the amorphous fraction and the tensile-compressive stressesin amorphous-crystalline radiation-damaged zircon ZrSiO:U,Th depending on radiation dose and temperature (8–350 K) are investigated according to Raman spectroscopy of Boson peak for the first time. The Boson peak at 60–70 cm-1 associated with localized phonon states in the amorphous fraction (fa) is recorded at low temperatures (T ˂ 100 K) for samples with fa ˂ 30% and over the entire temperature range 8–350 K for fa ˃ 70%. The wider localized states distribution in the latter case is considered as a sign of the amorphous phase structure evolution with an increase in radiation dose. The estimates of anatomic correlation radius based on the Ioffe–Regel criterion are similar to those in glasses, Rc2:0 – 2:3 nm. The monotonic increase in Rc value during heating of zircon with fa ˃ 70% is governed by thermal expansion of the percolating amorphous fraction. The nonmonotonic variations of the Rc value in zircon with fa ˂ 30% is determined by the stresses in the amorphous fraction due to the mismatch in thermal expansion coefficient (CTE) and elastic moduli of the amorphous and crystalline phases depending on temperature; a change in the sign of the crystalline fraction CTE at 30 K is assumed. The Boson peak disappearance at 100 K in zircon with fa ˂ 30% during heating conforms to with the violation of the phonon localization as a consequence of amorphous fraction contraction and partial ordering. The data obtained are important for predicting the thermal and mechanical properties of heterogeneous radiation-damaged materials and nanocomposites.

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Держатели документа:
Zavaritsky Institute of Geology and Geochemistry of the Ural Branch of the Russian Academy of Sciences,Yekaterinburg, Russia
Ural Federal University named after the first President of Russia B. N. Yeltsin,Yekaterinburg, Russia
Kirensky Institute of Physics, Federal Research Center KSC SB RAS,Krasnoyarsk, Russia

Доп.точки доступа:
Krylov, A. S.; Крылов, Александр Сергеевич; Votyakov, Sergei L.
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    Аверьянов, Евгений Михайлович.
    Молекулярно-оптическая и структурная анизотропия одноосных монодоменных/полидоменных пленок сопряженного полимера F8BT с аксиальной/плоскостной ориентацией макромолекул / Е. М. Аверьянов // Жидк. крист. и их практич. использ. - 2023. - Т. 23, № 1. - С. 68-77 ; Liq. Cryst. Appl., DOI 10.18083/LCAppl.2023.1.68. - Библиогр.: 14 . - ISSN 1991-3966. - ISSN 2499-9644
   Перевод заглавия: Molecular-optical and structural anisotropy of uniaxial single-domain/ polydomain films of conjugated polymer F8BT with axial/planar orientation of macromolecules
Кл.слова (ненормированные):
тонкие полимерные пленки -- двумерные поликристаллы -- сопряженные полимеры -- F8BT -- ориентационный порядок -- оптическая и спектральная анизотропия -- thin polymer films -- two-dimensional polycrystals -- conjugated polymers -- F8BT -- orientation order -- optical and spectral anisotropy
Аннотация: На практике используются одноосные полимерные пленки двух типов: монодоменные пленки на ориентирующих подложках с аксиальной ориентацией макромолекул относительно оптической оси пленки n, параллельной плоскости подложки (тип ОА); полидоменные пленки на изотропных подложках с плоскостной ориентацией макромолекул и оптической осью n, нормальной к подложке (тип ОP). Молекулярно-оптическая анизотропия пленки определяется средней по ансамблю анизотропией δγ = γ|| – γ⊥ компонент поляризуемости γj мономерных звеньев полимерных цепей для поляризаций световой волны вдоль (j = ||) и нормально (j = ⊥) оси n. Структурную анизотропию пленки описывают параметры ориентационного порядка U дипольных моментов m электронных (колебательных) переходов в мономерных звеньях макромолекул относительно оси n. Для пленок одного полимера значения параметров Rδ(λ) = δγА/δγP и RU = UA/UP характеризует степень близости полидоменной пленки к идеальному двумерному поликристаллу. В данной работе исследованы зависимость Rδ(λ) от длины световой волны λ в видимой области прозрачности и параметры порядка UA(P) для дипольного момента длинноволнового электронного перехода в монодоменных и полидоменных пленках сопряженного полимера F8BT. Значения Rδ(λ) получены из показателей преломления пленок nj(λ) с учетом компонент fj(λ) = 1 + Lj[nj2(λ) – 1] тензора локального поля. Компоненты Lj тензора Лорентца определены с использованием зависимостей nj(λ). Значения Rδ(λ) согласуются с Rδ = –2 для двумерного поликристалла, состоящего из одноосных кристаллитов. Параметры UA(P) определены с использованием фоновых величин nbj и максимальных значений kjmax компонент комплексного показателя преломления Nj(λ) = nj(λ) + ikj(λ) пленок в области длинноволновой полосы электронного поглощения при учете фоновых значений fbj = 1 + Lj(nbj2 – 1). Экспериментальное значение RU отличается от RU = –2 для двумерного поликристалла, что показывает чувствительность параметра UP к ориентационному беспорядку мономерных звеньев макромолекул в междоменных областях полидоменных пленок.
Two types of uniaxial polymer films are used in practice. The first type is singledomain film on orienting substrate with axial orientation of macromolecules with respect to the optical axis of the film n which is parallel to the substrate plane (type ОА). The second type is polydomain film on isotropic substrate with in-plane orientation of macromolecules and the optical axis of the film n which is perpendicular to the substrate plane (type ОP). The molecular-optical anisotropy of a film is defined by the ensemble-averaged anisotropy δγ = γ|| – γ⊥ of the components γj of the polarizability of the monomer units of a polymer for the light-wave polarizations along (j = ||) and across (j = ⊥) the optical axis n. The structural anisotropy of the film is described by the orientation order parameters U of the dipole moments m of the electronic (oscillatory) transitions in monomer units of macromolecule with respect to axis n. For films of the same polymer, the values of Rδ(λ) = δγА/δγP and RU = UA/UP characterize the closeness degree of the polydomain film to the ideal twodimensional polycrystal. In this work, the dependence Rδ(λ) on the light-wavelength λ in the visible range and the order parameters UA(P) for the dipole moment of the long-wavelength electronic transition in single-domain and polydomain films of the conjugated polymer F8BT were studied. The values Rδ(λ) were determined from the refractive indices nj(λ) of the films with the local-field tensor components fj(λ) = 1 + Lj[nj2(λ) – 1]. The Lorentz-tensor components Lj were obtained using the dependences nj(λ). The values Rδ(λ) are in agreement with Rδ = –2 for two-dimensional polycrystal consisted of the uniaxial crystallites. The parameters UA(P) were determined with the use of the background values nbj and maximal values kjmax of the components of the complex refractive indices Nj(λ) = nj(λ) + ikj(λ) of the films in the region of their long-wavelength electronic absorption band, taking into account the background values fbj = 1 + Lj(nbj2 – 1). The experimental value RU differs from RU = –2 for two-dimensional polycrystal. This difference reveals the sensitivity of the parameter UP to the orientation disorder of the monomer units of macromolecules in interdomain regions of polydomain films.

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Держатели документа:
Институт физики им. Л. В. Киренского, ФИЦ КНЦ СО РАН, Красноярск, Россия

Доп.точки доступа:
Aver'yanov, E. M.

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10.

Structural and magnetic transitions in the Bi2Fe4O9/BiFeO3 composite / L. V. Udod, S. S. Aplesnin, M. N. Sitnikov [et al.] // J. Alloys Compd. - 2023. - Vol. 958. - Ст. 170445, DOI 10.1016/j.jallcom.2023.170445. - Cited References: 51 . - ISSN 0925-8388. - ISSN 1873-4669
Кл.слова (ненормированные):
Сomposite materials -- Magnetisation -- Optical properties -- Scanning electron microscopy (SEM) -- Ultrasonics -- Phase transitions
Аннотация: A Bi2Fe4O9/BiFeO3 composite with a percentage ratio of 67/33 has been synthesized, its morphological analysis has been carried out. The average crystallite sizes for each phase have been determined. The magnetization hysteresis has been established and the temperature of its disappearance has been found. Using the infrared absorption spectra, temperatures of the magnetic phase transitions in each phase have been determined from the magnetic susceptibility, magnetostriction constant, ultrasound damping coefficient, and phonon mode softening. The change of magnetostriction constant sign observed in the vicinity of the spin reorientation transition and antiferromagnetic transition in mullite has been attributed to the change of the sign of the magnetoelastic constants. The interaction between the phases in the composite and the correlation of its structural and magnetic properties have been established.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russia
Reshetnev Siberian State University of Science and Technology, 660037 Krasnoyarsk, Russia
Siberian Federal University, 660041 Krasnoyarsk, Russia

Доп.точки доступа:
Udod, L. V.; Удод, Любовь Викторовна; Aplesnin, S. S.; Аплеснин, Сергей Степанович; Sitnikov, M. N.; Eremin, E. V.; Еремин, Евгений Владимирович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Shabanov, A. V.; Шабанов, Александр Васильевич; Romanova, O. B.; Романова, Оксана Борисовна; Kharkov, A. M.
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