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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Lyubutin I. S., Starchikov S. S., Lin Chun-Rong, Lu Shin-Zong, Shaikh M. O., Funtov K. O., Dmitrieva T. V., Ovchinnikov S. G., Edelman I. S., Ivantsov R. D.
Заглавие : Magnetic, structural, and electronic properties of iron sulfide Fe3S4 nanoparticles synthesized by the polyol mediated process
Место публикации : J. Nanopart. Res.: Springer, 2013. - Vol. 15. - P.1397. - DOI 10.1007/s11051-012-1397-0
Аннотация: Iron sulfide nanoparticles Fe3S4 with the spinel-type crystal structure were synthesized by the polyol mediated process. The particle size depends on preparation conditions and varies from 9 to 20 nm. Mössbauer data have revealed that the dominating fraction of iron ions in the 9-nm sample is in the high-spin ferric state. This implies an occurrence of the cation vacancies in nonstoichiometric greigite. The stoichiometric phase of greigite Fe3S4 dominates in the 18-nm-size nanoparticles. Magnetic measurements have shown a ferrimagnetic behavior of all samples at temperatures between 78 and 300 K. The estimated value of magnetic moment of the stoichiometric greigite nanoparticles is about 3.5 μB per Fe3S4 unit. The Mössbauer spectra indicate a superparamagnetic behavior of small particles, and some fraction of superparamagnetic phase is observed in all samples synthesized which may be caused by the particle size distribution. The blocking temperatures of T B ≈ 230 and 250 K are estimated for the 9 and 14 nm particles, respectively. The Mössbauer parameters indicate a great degree of covalency in the Fe–S bonds and support the fast electron Fe3+ ⇆ Fe2+ exchange in the B-sites of greigite. An absence of the Verwey transition at temperatures between 90 and 295 K is established supporting a semimetal type of conductivity. The temperature and magnetic field dependences of the magnetic circular dichroism (MCD) of optical spectra were measured in Fe3S4 for the first time. The spectra differ substantially from that of the isostructural oxide Fe3O4. It is supposed that the MCD spectra of greigite nanoparticles result from the collective electron excitations in a wide band with superimposed peaks of the d–d transitions in Fe ions.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Bazarov B. G., Grossman V. G., Molokeev M. S., Bazarova Zh.G.
Заглавие : Structural field of K2Al2B2O7-family [borate] crystals
Коллективы : Nonlinear Optics and Applications (7; 2013 ; Apr. ; 15; Prague)
Место публикации : Proc. SPIE. - 2013. - Vol. 8772. - Ст.877210. - P. - DOI 10.1117/12.2017099
Аннотация: The known crystal structures of borate compounds with general composition AI2MIII 2B2O7 (AI: Na, K, Cs, Rb) have been considered. The structures in space groups P63/m, P-31c, P321 and P21/c have been found depending on cation combination. Criterion k = (r(MIII)+r(B)+2r(O))/r(AI) has been formulated and it controls the formation of trigonal K2Al2B2O7 (KABO) type structure. The existence of noncentrosymmetric KABO-type borates is possible over the range of k = 2.7 – 2.06. This range is promising for searching new borate crystals and solid solutions with pronounced nonlinear optical properties. © (2013) COPYRIGHT Society of Photo-Optical Instrumentation Engineers (SPIE). Downloading of the abstract is permitted for personal use only.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Chimitova O. D., Adichtchev S. V., Bazarova Zh.G., Gavrilova T. A., Molokeev M. S., Surovtsev N. V., Bazarov B. G.
Заглавие : Synthesis, structural and vibrational properties of microcrystalline β-RbSm(MoO4)2
Место публикации : Mater. lett. - 2013. - Vol. 106. - P.26-29. - DOI 10.1016/j.matlet.2013.04.039
Аннотация: Low-temperature rubidium samarium dimolybdate, β-RbSm(MoO4)2, microplates have been prepared by solid state synthesis at 723 K by 70 h and 893 K by 150 h. The crystal structure of β-RbSm(MoO4)2 has been first refined by the Rietveld method in the space group Pbcn with unit cell parameters a=5.1431(2) Å, b=18.8195(7) Å, and c=8.1641(3) Å (RB=4.82%). The crystal structure of β-RbSm(MoO4)2 consists of the layers of MoO4 tetrahedrons corner-sharing with SmO8 square antiprisms. About 20 narrow Raman lines have been observed in Raman spectra recorded for the β-RbSm(MoO4)2 powder sample.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Krylov A. S., Vtyurin A. N., Oreshonkov A. S., Voronov V. N., Krylova S. N.
Заглавие : Structural transformations in a single-crystal Rb2NaYF6: Raman scattering study
Место публикации : J. Raman Spectrosc. - 2013. - Vol. 44, Is. 5. - P.763-769. - DOI 10.1002/jrs.4263
Аннотация: This paper reports Raman spectroscopy investigation of phase transitions in Rb2NaYF6 crystal. The experimental spectra were compared with the calculated one. The spectra were obtained in temperature range from 8 to 300 K. The Raman spectra shows anomalous temperature-dependent behavior at T1 = 154 and T2 = 122 K. Soft mode restoration has been found, which allows us to attribute first transition at 154 K to displacive type. Detailed analysis temperature dependencies of the line positions and widths have been performed. We found no effects of possible lattice disorder anywhere, except narrow (about 20 K) range above the T1 temperature. The Raman spectra of Rb2NaYF6 crystal have been obtained and analyzed under hydrostatic pressure up to 4.33 GPa (at T = 295 K). The high pressure experiment up to 4.33 GPa did not disclose any effects associated with phase transitions. The lattice vibration spectra were calculated up to 10 GPa. The calculation has been demonstrated that the Rb2NaYF6 does not undergo high pressure phase transition.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Zhiguo Xia, Molokeev M. S., Oreshonkov A. S., Atuchin V. V.
Заглавие : Synthesis, structural and photoluminescence properties of Ca2Al3O6F:Eu2+ phosphor
Коллективы : Russian-French workshop on Nanosciences and Nanotechnologies, Российская академия наук, Сибирское отделение РАН, Институт неорганической химии им. А.В. Николаева Сибирского отделения РАН, Институт катализа им. Г.К. Борескова Сибирского отделения РАН, Институт физики полупроводников им. А.В. Ржанова Сибирского отделения РАН
Место публикации : The 7th Russian-French workshop on Nanosciences and Nanotechnologies: Program and abstract book. - Novosibirsk, 2013. - P.65. - ISBN 978-5-901688-29-8
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Chimitova O. D., Atuchin V. V., Bazarov B. G., Molokeev M. S., Bazarova Zh.G.
Заглавие : The formation and structural parameters of new double molybdates RbLn(MoO4)2 (Ln = Pr, Nd, Sm, Eu) : Proceedings paper
Коллективы : Metamaterials (8; 2013 ; April ; 15; Prague, Czech Republic)
Место публикации : Proc. of SPIE. - 2013. - Vol. 8771. - Ст.87711A. - P. - DOI 10.1117/12.2017816
Аннотация: The structures of double molybdates with general compositions ALn(MoO4)2 (A – alkaline metals, Cu or Tl) have been considered and compared. It has been shown that the ionic radii ratio RLn/RA is a key factor governing crystal symmetry. Different structure fields in ALn(MoO4)2 (A = Li+, Na+, K+, Cu+, Rb+, Ag+, Cs+, Tl+) molybdates have been defined as a function of element composition.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Тамбасов, Игорь Анатольевич, Мягков, Виктор Григорьевич, Иваненко, Александр Анатольевич, Немцев, Иван Васильевич, Быкова, Людмила Евгеньевна, Бондаренко, Галина Николаевна, Mikhlin Y. L., Максимов И. А., Иванов В. В., Балашов С. В., Карпенко Д. С.
Заглавие : Структурные и оптические свойства тонких пленок In2O3, полученных автоволновым окислением
Место публикации : Физ. и техника полупроводников. - 2013. - Т. 47, Вып. 4. - С. 546-550
Аннотация: Пленки кубической фазы In2O3 получены автоволновой реакцией окисления. Электронно-микроскопические исследования и фотоэлектронная спектроскопия профилей распределения показали, что образцы однородны по всей площади и толщине, характерный размер зерна 20--40 нм. Проведены исследования оптических и электрических свойств пленок In2O3, полученных при различном давлении в вакуумной камере. В диапазоне длины волн 400--1100 нм пленки имели прозрачность более 85% и удельное сопротивление 1.8· 10-2 Ом·см.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Tambasov I. A., Myagkov V. G., Ivanenko A. A., Nemtsev I. V., Bykova L. E., Bondarenko G. N., Mihlin J. L., Maksimov I. A., Ivanov V. V., Balashov S. V., Karpenko D. S.
Заглавие : Structural and optical properties of thin In2O3 films produced by autowave oxidation
Место публикации : Semiconductors. - 2013. - Vol. 47, Is. 4. - P.569-573. - DOI 10.1134/S1063782613040210
Аннотация: Cubic-phase In2O3 films are produced by the autowave oxidation reaction. Electron microscopy and photoelectron spectroscopy of the atomic profiles show that the samples are homogeneous over the entire area and throughout the thickness, with the typical grain size being 20–40 nm. The optical and electrical properties are studied for In2O3 films fabricated at different pressures in the vacuum chamber. In the wave-length range from 400 to 1100 nm, the transparency of the films was higher than 85%; the resistivity of the films was 1.8 × 10–2Ω cm.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Astakhov A. M., Vasiliev A. D., Revenko V. A.
Заглавие : Crystal and molecular structure of 1-phenyl-2-nitroguanidine
Место публикации : J. Struct. Chem.: Springer, 2012. - Vol. 53, Is. 5. - P.1013-1016. - ISSN 0022-4766, DOI 10.1134/S0022476612050265
Примечания : Cited References: 12
Ключевые слова (''Своб.индексиров.''): nitrimines--nitroguanidine--single crystal x-ray diffraction study--molecular structure
Аннотация: The molecular structure of 1-phenyl-2-nitroguanidine is nonplanar, but contains two almost planar fragments: nitroguanyl and phenyl groups. Unlike previously studied nitroguanidines, in 1-phenyl-2-nitroguanidine, the nitro group is turned to the secondary amino group. However, the structural parameters of the nitroguanyl group are little different from those of nitroguanidine and its alkyl derivatives. In the benzene ring, the symmetry in the geometric parameters is not observed, which is explained by the intermolecular interaction with the neighboring molecule.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Bazarov B. G., Gavrilova T. A., Grossman V. G., Molokeev M. S., Bazarova Zh. G.
Заглавие : Preparation and structural properties of nonlinear optical borates K 2(1-x)Rb 2xAl 2B 2O 7, 0 ˂ x ˂ 0.75
Место публикации : J. Alloys Compd.: Elsevier, 2012. - Vol. 515. - P.119-122. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2011.11.115
Примечания : Cited References: 30. - This study was supported by SB RAS (Grant 34) and RFBR Grants 11-02-90706-mob_st and 11-03-00867a.
Предметные рубрики: UV-light generation
Frequence-conversion
K2Al2B2O7 crystal
Composition ratio
Mixed-crystals
Growth
KRbAl2B2O7
NLO properties
Non-linear optical
Non-linear optical properties
Rietveld analysis of X-ray powder diffraction data
Solubility limits
Space Groups
Structural parameter
Ключевые слова (''Своб.индексиров.''): krbal2b2o7--solid solution--crystal structure--nlo properties
Аннотация: The structures of K 2(1-x)Rb 2xAl 2B 2O 7, x = 0.25, 0.5, 0.75, have been determined in space group P321 through Rietveld analysis of X-ray powder diffraction data. The solubility limit in K 2(1-x)Rb 2xAl 2B 2O 7 crystals has been estimated as x similar to 0.83-0.9. Nonlinear optical properties of KRbAl 2B 2O 7 have been verified by powder Kurtz-Perry method. Mechanisms of structural parameter variation in K 2Al 2B 2O 7 crystal family have been discussed.
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11.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Atuchin V. V., Bazarov B. G., Grossman V. G., Molokeev M. S., Bazarova Zh.G.
Заглавие : Structural limits of K2Al2B2O7-family borate crystals
Коллективы : Институт нанотехнологий микроэлектроники РАН, Ульяновский государственный университет, Российский фонд фундаментальных исследований, Академия наук Татарстана, "Opto-, nanoelectronics, nanotechnology, and microsystems", International Conference (2013 ; Jul. ; 26-30; Ulyanovsk, Russia), "Опто-, наноэлектроника, нанотехнологии и микросистемы", международная конференция (2013 ; июль.; 26-30; Ульяновск)
Место публикации : XVI Международная конференция "Опто-, наноэлектроника, нанотехнологии и микросистемы": Труды. - Ульяновск, 2013. - P.102-103
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12.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Atuchin V. V., Chimitova O. D., Bazarov B. G., Molokeev M. S., Bazarova Zh.G.
Заглавие : Structural parameters of double molybdates ALn(MoO4)2
Коллективы : Институт нанотехнологий микроэлектроники РАН, Ульяновский государственный университет, Российский фонд фундаментальных исследований, Академия наук Татарстана, "Opto-, nanoelectronics, nanotechnology, and microsystems", International Conference (2013 ; Jul. ; 26-30; Ulyanovsk, Russia), "Опто-, наноэлектроника, нанотехнологии и микросистемы", международная конференция (2013 ; июль.; 26-30; Ульяновск)
Место публикации : XVI Международная конференция "Опто-, наноэлектроника, нанотехнологии и микросистемы": Труды. - Ульяновск, 2013. - P.239-240
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Avramov P. V., Fedorov D. G., Sorokin P. B., Sakai S., Entani S., Ohtomo M., Matsumoto Y., Naramoto H.
Заглавие : Intrinsic edge asymmetry in narrow zigzag hexagonal heteroatomic nanoribbons causes their subtle uniform curvature
Место публикации : J. Phys. Chem. Lett. - 2012. - Vol. 3, Is. 15. - P.2003-2008. - ISSN 1948-7185, DOI 10.1021/jz300625t
Примечания : Cited References: 42. - This work was supported by JAEA Research fellowship (P.V.A.). P.V.A. also acknowledges JAEA ASRC and the Molecular Spintronics Group for hospitality and fruitful collaboration. D.G.F. thanks Prof. Kazuo Kitaura for many fruitful discussions and the Next Generation SuperComputing Project, Nanoscience Program and Strategic Programs for Innovative Research (MEXT, Japan) for financial support. This work was partially supported by Russian Ministry of Education and Science (Contract No. 16.552.11.7014) (P.B.S.).
Предметные рубрики: MOLECULAR-ORBITAL METHOD
WALLED CARBON NANOTUBES
GRAPHENE NANORIBBONS
ELECTRONIC-STRUCTURE
OPTICAL-TRANSITIONS
SOLIDS
BOND
Aromatic rings
Conical surfaces
Finite length
Fragment molecular orbital methods
Graphene nanoribbons
Intrinsic curvature
Nanoribbons
Out-of-plane
Structural stress
Ключевые слова (''Своб.индексиров.''): zigzag nanoribbons--hexagonal atomic lattices--fluorine-terminated graphene
Аннотация: The atomic and electronic structure of narrow zigzag nanoribbons with finite length, consisting of graphene terminated by fluorine on one side, hexagonal (h) h-BN, and h-SiC were studied with density functional theory. It is found that the asymmetry of nanoribbon edges causes a uniform curvature of the ribbons due to structural stress in the aromatic ring plane. Narrow graphene nanoribbons terminated with fluorine on one side demonstrate a considerable out-of-plane bend, suggesting that the nanoribbon is a fraction of a conical surface. It is shown that the intrinsic curvature of the narrow nanoribbons destroys the periodicity and results in a systematic cancellation of the dipole moment. The in- and out- of-plane curvature of thin arcs allows their closure in nanorings or cone fragments of giant diameter. Using the fragment molecular orbital method, we optimized the structure of a planar giant arc and a closed ring of h-BN with a diameter of 105 nm.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vasiliev A. D., Zel'bst E. A., Soldatenko A. S., Bolgova Yu.I., Trofimova O. M., Voronkov M. G.
Заглавие : Synthesis and molecular structure of cobalt(II) complex with 1-(1-silatranylmethyl)-1,2,4-triazole
Место публикации : Struct. Chem.: Springer/Plenum Publishers, 2013. - Vol. 24, Is. 4. - P.1001-1005. - ISSN 1040-0400, DOI 10.1007/s11224-012-0121-0
Примечания : Cited References: 24
Предметные рубрики: REACTIVITY
DERIVATIVES
CRYSTAL
SPECTRA
Ключевые слова (''Своб.индексиров.''): complexes--1-(1-silatranylmethyl)-1,2,4-triazole--cobalt dichloride--x-ray diffraction
Аннотация: Reaction of cobalt chloride with 1-(1-silatranylmethyl)-1,2,4-triazole in benzene afforded complex CoCl2 center dot 2L (L = 1-(1-silatranylmethyl)-1,2,4-triazole). It was isolated as the solvate [CoCl2 center dot 2L]center dot CH2Cl2 (1) by recrystallization from dichloromethane and structurally characterized by single-crystal X-ray diffraction. It crystallizes in the monoclinic space group P2(1)/m with a = 6.798(2) E, b = 20.326(5) E, c = 11.005(3) E, and Z = 4. The cobalt atom is in slightly distorted square-planar environment, coordinated to two nitrogen atoms from two ligands and two chloride ions.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Molokeev M. S., Belash M. Y.
Заглавие : Crystal structure of potassium 2-thiobarbiturate
Место публикации : J. Struct. Chem.: MAIK Nauka-Interperiodica / Springer, 2013. - Vol. 54, Is. 3. - P.566-570. - ISSN 0022-4766, DOI 10.1134/S0022476613030141
Примечания : Cited References: 18. - The work was supported by the grant of the President of the Russian Federation for the support of leading scientific schools of the Russian Federation (NSh-4828.2012.2) and the Federal Targeted Program "Scientific and Scientific Pedagogical Personnel of Innovative Russia, 2009-2013" (State contracts Nos. 02.740.11.0269 and 02.740.11.0629).
Предметные рубрики: ACID
Ключевые слова (''Своб.индексиров.''): crystal structure--potassium thiobarbiturate--hydrogen bonds--pi-pi interaction
Аннотация: The crystal and molecular structure of potassium thiobarbiturate C4H3KN2O2S (C4H4N2O2S-2-thiobarbituric acid, H(2)TBA) is determined. Crystallographic data for KHTBA are as follows: a = 11.2317(17) , b = 3.8687(6) , c = 14.557(2) , beta = 97.448(4)A degrees, V = 627.18(17) (3), space group P2/c, Z = 4. Each potassium ion is linked with four oxygen atoms and two S atoms forming a distorted octahedron. N-HaEuro broken vertical bar O and C-HaEuro broken vertical bar S hydrogen bonds form a branched three-dimensional network. The structure is also stabilized by the pi-pi interaction of heterocyclic HTBA(-) ions.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Vasiliev A. D., Golovnev N. N.
Заглавие : Crystal structure of two hydrate phases of ciprofloxacindi-um tetrachloridocobaltate(II)
Место публикации : J. Struct. Chem.: MAIK Nauka-Interperiodica / Springer, 2013. - Vol. 54, Is. 3. - P.607-612. - ISSN 0022-4766, DOI 10.1134/S0022476613030219
Примечания : Cited References: 9
Ключевые слова (''Своб.индексиров.''): ciprofloxacindi-um tetrachloridocobaltate(ii)--crystal structure--hydrogen bonds--pi-pi interaction
Аннотация: New (C17H20FN3O3)(2)[CoCl4](2)center dot 3H(2)O (I) and C17H20FN3O3[CoCl4]center dot H2O (II) compounds, where C17H18FN3O3 is ciprofloxacin (CfH), are synthesized and their crystal structures are determined. Crystallographic data for I: a = 18.441(5) , b = 9.030(3) , c = 27.551(8) , V = 4588(4) (3), space group Pca2(1), Z = 4; for II: a = 9.305(3) , b = 9.885(3) , c = 12.999(4) , alpha = 82.782(4)A degrees, beta = 72.954(4)A degrees, gamma = 89.736(4)A degrees, V = 1133(1) (3), P-1 space group, Z = 2. Both structures contain CfH (3) (2+) ion pairs bonded by the pi-pi interaction. Additionally, in the crystal of I there is a stacking interaction between the pi clouds of aromatic rings and hydrogen atoms of the cyclopropyl group linking the pairs of molecules with each other. The structure of the centrosymmetric crystal of triclinic phase II is also formed from CfH (3) (2+) ion pairs bonded by the pi-pi interaction, which, in this case, are not independent because they are related by the symmetry center. Hydrogen bonds form a branched three-dimensional network linking the CfH (3) (2+) and CoCl (4) (2-) ions and water molecules.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Antipina L. Yu., Tomilin F. N., Vysotski E. S., Ovchinnikov S. G.
Заглавие : A quantum chemical study of the formation of 2-hydroperoxy-coelenterazine in the Сa2+-regulated photoprotein obelin
Место публикации : J. Struct. Chem.: Springer, 2011. - Vol. 52, Is. 5. - P.870-875. - ISSN 0022-4766
Примечания : Cited References: 19. - The work was supported by RFBR (07-04-00930-a), the "Molecular and Cell Biology" Program of the Presidium of the Russian Academy of Sciences, and the Program of the Siberian Division of the Russian Academy of Sciences (project No. 2) within the implementation of the Federal Targeted Program "Scientific and Scientific Pedagogical Personnel of Innovative Russia, 2010" (P333 and P213).
Предметные рубрики: CALCIUM-DISCHARGED OBELIN
SEMIEMPIRICAL METHODS
1.7 ANGSTROM
OPTIMIZATION
PARAMETERS
MECHANISM
FLUORESCENCE
ELEMENTS
PROTEIN
EMITTER
Ключевые слова (''Своб.индексиров.''): coelenterazine--2-hydroperoxy-coelenterazine--obelia longissima--renilla muelleri
Аннотация: The Ca2+-regulated photoprotein obelin determines the luminescence of the marine hydroid Obelia longissima. Bioluminescence is initiated by calcium and appears as a result of the oxidative decarboxylation related to the coelenterazine substrate. The luciferase of the luminescent marine coral Renilla muelleri (RM) also uses coelenterazine as a substrate. However, three proteins are involved in the in vivo bioluminescence of these animals: luciferase, green fluorescent protein, and Ca2+-regulated coelenterazine-binding protein (CBP). In fact, CBP that contains one strongly bound coelenterazine molecule is the RM luciferase substrate in the in vivo bioluminescent reaction. Coelenterazine becomes available for oxygen and the reaction with luciferase only after binding CBP with calcium ions. Unlike Ca2+-regulated photoproteins, the coelenterazine molecule is not activated by oxygen in the CBP molecule. In this work, by means of quantum chemical methods the behavior of substrates in these proteins is analyzed. It is shown that coelenterazine can form different tautomers: CLZ(2H) and CLZ(7H). The formation of 2-hydroperoxy-coelenterazine is studied. According to the obtained data, these proteins use different forms of the substrates for the reaction. In obelin, the substrate is in the CLZ(2H) form that affords hydrogen peroxide. In RM, coelenterazine is in the CLZ(7H) form, and therefore, CBP is not activated by oxygen.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Antonova A. B., Chudin O. S., Vasiliev A. D., Rubaylo A. I., Verpekin V. V., Sokolenko W. A., Pavlenko N. I., Semeikin O. V.
Заглавие : Chemistry of vinylidene complexes. XX. Intramolecular carbonylation of vinylidene on the MnFe center: Spectroscopic and structural study. X-ray structure of the new trimethylenemethane type MnFe complex
Место публикации : J. Organomet. Chem.: Elsevier, 2011. - Vol. 696, Is. 4. - P.963-970. - ISSN 0022-328X, DOI 10.1016/j.jorganchem.2010.10.035
Примечания : Cited References: 52. - This work was partially supported by the Presidium of the Russian Academy of Sciences (Program for Basic Research, Project No. 7.18) and Russian Foundation for Basic Research (Grant No. 09-03-90745-mob_st). Authors are grateful to Prof. N.A. Ustynyuk for useful discussions, Dr. E.A. Shor and Dr. A.M. Shor for giving the data of quantum chemical study.
Предметные рубрики: MOLECULAR-STRUCTURE
ORGANOMETALLIC CHEMISTRY
TRICARBONYL COMPLEXES
UNSATURATED CARBENES
METAL VINYLIDENES
TRANSITION-METALS
ORGANIC-SYNTHESIS
CRYSTAL-STRUCTURE
IRON TRICARBONYL
MANGANESE
Ключевые слова (''Своб.индексиров.''): manganese--iron--carbonyl complexes--heteronuclear vinylidene complexes--intramolecular vinylidene carbonylation--trimethylenemethane complexes
Аннотация: Reactions of Fe-2(CO)(9) with Cp(CO)(2)Mn=C=CHPh (1) and Cp(CO)(PPh3)Mn=C=CHPh (3) gave the heterometallic trimethylenemethane complexes eta(4)-{C[Mn(CO)(2)Cp](CO)CHPh}Fe(CO)(3) (2) and eta(4)-{C[Mn(CO)(PPh3)Cp](CO)CHPh}Fe(CO)(3) (4), respectively. The formation of the benzylideneketene [PhHC=C=C=O] fragment included in complexes 2 and 4 occurs via intramolecular coupling of the carbonyl and vinylidene ligands. The structures of 3 and 4 were determined by single crystal XRD methods. The influence of the nature of the L ligands at the Mn atom on the structural and spectroscopic characteristics of eta(4)-{C[Mn(CO)(L)Cp](CO)CHPh}Fe(CO)(3) (L = CO (2), PPh3 (4)) is considered. According to the VT H-1 and C-13 NMR spectra, complex 2 reversibly transforms in solution into mu-eta(1):eta(1)-vinylidene isomer Cp(CO)(2)MnFe(mu-C=CHPh)(CO)(4) (2a), whereas complex 4 containing the PPh3 ligand is not able to a similar transformation. (C) 2010 Elsevier B.V. All rights reserved.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Chimitova O. D., Gavrilova T. A., Molokeev M. S., Kim S. J., Surovtsev N. V., Bazarov B. G., Bazarova Zh.G.
Заглавие : Synthesis, structural and vibrational properties of microcrystalline RbNd(MoO4)(2)
Коллективы : International Conference on Crystal Growth, International Conference on Vapor Growth and Epitaxy
Место публикации : J. Cryst. Growth: Elsevier Science BV, 2011. - Vol. 318, Is. 1. - P.683-686. - ISSN 0022-0248, DOI 10.1016/j.jcrysgro.2010.09.076
Примечания : Cited References: 26
Предметные рубрики: MOLYBDENUM TRIOXIDE
DOUBLE MOLYBDATES
CRYSTAL-STRUCTURE
GROWTH
LASER
MOO3
Ключевые слова (''Своб.индексиров.''): crystal structure--solid state synthesis--molybdate
Аннотация: Rubidium neodymium dimolybdate, RbNd(MoO4)(2), microcrystals have been fabricated by solid state synthesis at T=550-600 degrees C by t=324 ks. Crystal structure of RbNd(MoO4)(2) has been refined by Rietveld method in space group Pbcn with cell parameters a = 5.1772(1) angstrom, b = 18.7293(4) angstrom, and c = 8.2774(1) angstrom (R-B=5.05%). The crystal structure of RbNd(MoO4)(2) consists of layers of MoO4 tetrahedrons cornersharing with NdO8 square antiprisms. These layers are perpendicular to b-axis of the unit cell. About 20 narrow Raman lines have been observed in Raman spectrum recorded for RbNd(MoO4)(2) powder sample. (C) 2010 Elsevier B.V. All rights reserved.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balasoiu M., Ischenko L. A., Stolyar S. V., Iskhakov R. S., Raikher Y. L., Kuklin A. I., Soloviov D. V., Kurkin T. S., Aranghel D., Arzumanian G. M.
Заглавие : Structural investigation of biogenic ferrihydrite nanoparticles dispersion
Коллективы :
Место публикации : Optoelectron. Adv. Mater.-Rapid Commun. - 2010. - Vol. 4, Is. 12. - P.2136-2139. - ISSN 1842-6573
Примечания : Cited References: 21. - The financial support from the Grants No.224 it.7 and No.56 it.5 of the Romanian Governmental Plenipotentiary at JINR and the support from the JINR theme No. 04-4-1069-2009/2011 are acknowledged. S.S. Abramchyuk (Advanced Technologies Center, Moscow) for the HRTEM images is acknowledged.
Предметные рубрики: S-LAYER PROTEINS
METAL NANOPARTICLES
BIOLOGICAL SYNTHESIS
BIOSYNTHESIS
MICROORGANISMS
FUNGI
Ключевые слова (''Своб.индексиров.''): bacterial nanoparticles--ferrihydrite--small angle x-ray scattering--high-resolution electron microscopy
Аннотация: Structural properties of biogenic ferrihydrite nanoparticles produced by bacteria Klebsiella oxytoca are investigated. Investigations of morphology and size of particles dispersed in water by means of high-resolution transmission electron microscopy and small angle X-ray scattering measurements were performed. By model calculations followed by fitting procedure the structural parameters of a cylinder of radius R = 4.87 +/- 0.02 nm and height L = 2.12 +/- 0.04 nm are obtained.
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