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    Переход металл-диэлектрик в катион-замещенных соединениях ReхMn1-xS (Re = Gd, Sm, Ho) / О. Б. Романова [и др.] // Вестник СибГАУ. - 2015. - Т. 16, № 2. - С. 478-484. - Библиогр.: 38. - Работа выполнена при финансовой поддержке РФФИ № 15-42-04099 р_Cибирь_а и государственного задания № 114090470016. . - ISSN 1816-9724
   Перевод заглавия: Metal-insulator transition in the cation-substituted compounds RexMn1-xS (Re = Gd, Sm, Ho)
Кл.слова (ненормированные):
СУЛЬФИДЫ РЕДКОЗЕМЕЛЬНЫХ ЭЛЕМЕНТОВ -- ПРОВОДИМОСТЬ -- ПЕРЕХОД МЕТАЛЛ-ДИЭЛЕКТРИК -- ТЕРМОЭДС -- SULFIDES OF RARE-EARTH ELEMENTS -- CONDUCTIVITY -- TRANSITION METAL-INSULATOR -- THERMOELECTRIC POWER
Аннотация: Представлены результаты исследования транспортных свойств катион-замещенных сульфидов RexMn1-xS (Re = Gd, Sm, Ho) с ГЦК-решеткой типа NaCl в области температур 77-1200 К. С увеличением степени катионного замещения в этих соединениях RexMn1-xS (Re = Gd, Sm, Ho) изменяется тип проводимости от полупроводникового до металлического при критической концентрации Х С. Концентрационный переход металл-диэлектрик в системе Gd XMn 1-XS сопровождается уменьшением величины удельного электросопротивления на 12 порядков и коэффициента термоЭДС (α) на два порядка. Катионное замещение в твердых растворах GdxMn1-xS приводит к смене дырочного типа проводимости (α > 0), свойственного моносульфиду марганца, на электронный (α < 0). Уменьшение величины α с увеличением содержания гадолиния в решетке MnS указывает на то, что Gd действует как донорная примесь. Для Sm 0,2Mn 0,8S обнаружен резкий максимум сопротивления при Т = 100 К, который может быть вызван рассеянием электронов проводимости на спиновых флуктуациях локализованных электронов. Установлен металлический тип проводимости для Sm 0,25Mn 0,75S и механизм электрического сопротивления, который связан с рассеянием электронов на акустических фононах и с магнитным рассеянием на нескомпенсированных антиферромагнитных кластерах марганца при Т < 180 К. В результате замещения марганца самарием в твердом растворе SmxMn1-xS электронная структура перестраивается, и сопротивление невозможно объяснить на основе протекания ионов самария. Общей закономерностью температурных зависимостей коэффициента термоЭДС как для системы с гадолинием, так и для системы с самарием является проявление отрицательного значения термоЭДС во всем диапазоне температур с ростом Х. В системе HoxMn1-xS переход металл-диэлектрик обнаружен для ХС = 0,3 с уменьшением величины удельного электросопротивления на десять порядков. Цель данной работы - установить условия реализации перехода металл-диэлектрик в катион-замещенных системах RexMn1-xS (Re = Gd, Sm, Ho).
This paper presents the results of a study of the transport properties of cation-substituted sulfides Re XMn 1-XS (Re = = Gd, Sm, Ho) with FCC NaCl type in the temperature range 77-1200 K. With increasing degree of cation substitution in these compounds Re XMn 1- ХS (Re = Gd, Sm, Ho) the conductivity type changes from the semiconductor to the «metal» at the critical concentration X C. The concentration of metal-insulator transition in the system Gd XMn 1-XS is accompanied by a decreasing in the electrical resistivity of value on 12 orders and Seebeck coefficient (α) is on two orders. The cation-substitution in the solid solutions Gd XMn 1-XS leads to p-type conductivity (α > 0), as comprising to electronic (α < 0) for manganese monosulfide. Decrease of α with increasing gadolinium concentration in the MnS lattice indicates that the Gd acts as a donor impurity. For Sm 0,2Mn0,8S a maximum resistance at T = 100 K attributed to the scattering of conduction electrons by spin fluctuations of localized electrons. The metallic conductivity for Sm 0.25Mn 0.75S and the mechanism of electrical resistance, which is related to the scattering of electrons by acoustic phonons and magnetic scattering by uncompensated antiferromagnetic manganese clusters at T < 180 K were revealed. As a result of the substitution of manganese to samarium in solid solution Sm XMn 1-XS the electron structure is reconstructed, and the resistance cannot be explained on the basis of the percolation of samarium ions. The temperature dependence of Seebeck coefficient for systems with gadolinium and with samarium reveals the negative values of thermoelectric power in the all range of temperatures with increasing concentration (X). The metal-insulator transition for system Ho XMn 1-XS at Х С= 0,3 is observed with decreasing resistivity on ten orders. The purpose of this work is to establish conditions for the realization of the metal-insulator transition in a cation-substituted systems Re XMn 1-XS (Re = Gd, Sm, Ho).

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Держатели документа:
Институт физики им. Л. В. Киренского СО РАН
Сибирский государственный аэрокосмический университет имени акад. М. Ф. Решетнева

Доп.точки доступа:
Романова, Оксана Борисовна; Romanova, O. B.; Харьков, Анатолий Михайлович; Kharkov A. M.; Ситников, Максим Николаевич; Sitnicov M. N.; Кретинин, В. В.; Kretinin, V. V.
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    Романова, Оксана Борисовна.
    Кинетические эффекты в сульфидах марганца замещенных тулием и иттербием / О. Б. Романова, С. С. Аплеснин, Л. В. Удод // Новое в магнетизме и магнитных материалах : сборник трудов XXIV международной конференции / прогр. ком.: Р. С. Исхаков, С. Г. Овчинников. - 2021. - Секция 7: Кинетические эффекты в магнетиках. - С. 17-20. - Библиогр.: 9. - Исследование выполнено при финансовой поддержке РФФИ и БРФФИ в рамках научного проекта No 20-52-00005
   Перевод заглавия: Kinetic effects in manganese sulfides substituted by thulium and ytterbium
Аннотация: Данная работа посвящена изучению кинетических эффектов в сульфидах марганца допированных элементами с переменной валентностью (Yb и Tm с Х≤0.05) измеренных в диапазоне температур (77-400 K) и магнитных полей до 12 кЭ. Из ВАХ определены механизмы проводимости, для системы Yb0.05Mn0.99S преобладает Пула– Френкеля, а для Tm0.01Mn0.99S описывается законом Ома. Обнаружен эффект магнитосопротивления в этих системах. Наблюдаются аномалии на температурной зависимости термоЭДС.
This work is to the study of kinetic effects in manganese sulfides doped with elements with variable valence (Yb and Tm with X≤0.05) measured in the temperature range (77-400 K) and magnetic fields up to 12 kOe. The conduction mechanisms are determined by I – V characteristics: for the Yb0.05Mn0.99S is Poole – Frenkel, and for Tm0.01Mn0.99S it is described by Ohm's law. The effect of magnetoresistance is found in these systems. Anomalies are observed in the temperature dependence of the thermoEMF.

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Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Исхаков, Рауф Садыкович \прогр. ком.\; Iskhakov, R. S.; Овчинников, Сергей Геннадьевич \прогр. ком.\; Ovchinnikov, S. G.; Аплеснин, Сергей Степанович; Aplesnin, S. S.; Удод, Любовь Викторовна; Udod, L. V.; Romanova, O. B.; "Новое в магнетизме и магнитных материалах", международная конференция(24 ; 2021 ; 1-8 июля ; Москва); Научный совет по физике конденсированных сред РАН; МИРЭА - Российский технологический университет; Московский государственный университет им. М.В. Ломоносова; Магнитное общество России
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Transport properties and ferromagnetism of Co(x)Mn(1-x)Ssulfides / S. S. Aplesnin [et al.] // J. Exp. Theor. Phys. - 2008. - Vol. 106, Is. 4. - P. 765-772, DOI 10.1134/S1063776108040158. - Cited References: 39 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
GIANT VOLUME MAGNETOSTRICTION
   COLOSSAL MAGNETORESISTANCE
   MAGNETIC SEMICONDUCTORS
   ELECTRICAL-PROPERTIES
   ROOM-TEMPERATURE
   ALPHA-MNS
   SPINTRONICS
   TRANSITION
   FEXMN1-XS
   FIELDS
Кл.слова (ненормированные):
Coulomb interactions -- Current voltage characteristics -- Electromotive force -- Ferromagnetism -- Magnetic susceptibility -- Magnetization -- Thermoelectricity -- Transport properties -- Charge susceptibility -- External magnetic fields -- Temperature intervals -- Thermoelectromotive force -- Cobalt compounds
Аннотация: We have studied the resistivity and thermoelectromotive force (thermo emf) in a temperature range of T = 80-1000 K, the magnetic susceptibility and magnetization in a temperature range of T= 4.2-300 K at an external magnetic field of up to 70 kOe, and the structural characteristics of CoxMn1 - S-x sulfides (0 <= x <= 0.4). Anomalies in the transport properties of these compounds have been found in the temperature intervals Delta T-1 = 200-270 K and Delta T-2 = 530-670 K and at T-3 similar to T-N. The temperature dependences of the magnetic susceptibility, magnetization, and resistivity, as well as the current-voltage characteristics, exhibit hysteresis. In the domain of magnetic ordering at temperatures below the Neel temperature (TN), the anti ferromagnetic CoxMn1 - xS sulfides possess a spontaneous magnetic moment that is explained using a model of the orbital ordering of electrons in the t(2g) bands. The influence of the cobalt-ion-induced charge ordering on the transport and magnetic properties of sulfides has been studied. The calculated values of the temperatures corresponding to the maxima of charge susceptibility, which are related to a competition between the on-site Coulomb interaction of holes in various subbands and their weak hybridization, agree well with the experimental data.

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Держатели документа:
[Aplesnin, S. S.
Ryabinkina, L. I.
Romanova, O. B.
Velikanov, D. A.
Balaev, A. D.
Balaev, D. A.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Aplesnin, S. S.
Bandurina, O. N.] Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
[Yanushkevich, K. I.
Galyas, A. I.
Demidenko, O. F.] Natl Acad Sci, Joint Inst Solid State & Semicond Phys, Minsk 220072, Byelarus
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation
Reshetnev Siberian State Aerospace University, Krasnoyarsk 660014, Russian Federation
Joint Institute of Solid State and Semiconductor Physics, National Academy of Sciences of Belarus, Minsk 220072, Belarus

Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Ryabinkina, L. I.; Рябинкина, Людмила Ивановна; Romanova, O. B.; Романова, Оксана Борисовна; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Balaev, A. D.; Балаев, Александр Дмитриевич; Balaev, D. A.; Балаев, Дмитрий Александрович; Yanushkevich, K. I.; Galyas, A. I.; Demidenko, O. F.; Bandurina, O. N.
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The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases / I. O. Yurev, A. S. Aleksandrovsky, D. N. Kamaev [et al.] // J. Therm. Anal. Calorim. - 2024. - Vol. 149, Is. 5. - P. 2057-2073, DOI 10.1007/s10973-023-12792-z. - Cited References: 90. - The authors thank Prof. P.P. Fedorov, Chief Researcher of Prokhorov Institute of General Physics, Russian Academy of Sciences, for scientific advices. The authors thank N.I. Lozhkin, engineer of the Department of Inorganic and Physical Chemistry, Tyumen State University for the technical support of the visual thermal analysis setup. The authors thank N.A. Shulaev, research engineer of the Center for Nature-Inspired Engineering, Tyumen State University, for determining the elemental composition of samples by scanning electron microscopy. The authors thank I.V. Palamarchuk, research engineer of the Center for Collective Use "Rational Nature Management and Physical and Chemical Research" of the Tyumen State University, for measuring the diffuse reflectance spectra. The authors thank Doctor of Philology O.V. Trofimova, Professor at the Institute of Social Sciences and Humanities of the Tyumen State University, for her advices on academic writing. - This study was funded by the Russian Science Foundation, Project No. 23–23-00488 “Search for EMF generation conditions in gradient ceramics of samarium monosulfide (SmS)” . - ISSN 1388-6150. - ISSN 1588-2926
Кл.слова (ненормированные):
Samarium sulfides -- Refractory system -- Thermal analysis -- Ternary eutectic -- Phase diagram -- Band gap
Аннотация: Samarium monosulfide, a strain gauge and barometric material, exists in equilibrium with Sm3S4 and Sm2O2S in the S-Sm–O system. Therefore, studying phase equilibria in the refractory Sm2S3-X-SmS-Sm2O2S system is a scientifically interesting task. In this system, 49 samples were synthesized and studied by powder XRD, differential scanning calorimetry, visual thermal analysis, and microstructural analysis. Melting points of Sm3S4, SmS, and Sm2O2S compounds were determined. Eutectic diagrams of Sm3S4-Sm2O2S, SmS-Sm2O2S, SmS-Sm3S4 systems were constructed. Temperatures and compositions of the binary eutectic points were determined. Fusion enthalpies for Sm3S4, SmS, and Sm2O2S phases were estimated using the Schröder–Le Chatelier equation. The liquidus lines were calculated using second-degree polynomials and Redlich–Kister model. Coordinates of the ternary eutectic point in the Sm3S4-SmS-Sm2O2S system were calculated using the cutting-plane method and the Scheffé method. The calculated compositions of ternary eutectic points were averaged at one most probable point, in accordance with the data on the samples microstructure. The experimental temperature of the ternary eutectic point coincides with the calculated values within the margin of error. Positions of eutectic valleys and approximate positions of isotherms in the system were established. Thermodynamic parameters of the α-Sm2S3 → γ-Sm2S3 polymorphic transition and the dependence of the Sm2S3-X composition on heat treatment conditions were determined. According to the scanning electron microscopy data, the approximate composition of the crystallized from the melt Sm2S3 sample is Sm2S2.95. The Sm10S14O phase decomposes at 1470 ± 15 °C in the course of a solid-phase reaction. The phase diagram of the Sm2S3-X-Sm2O2S system was revisited. Optical band gaps of Sm10S14O and Sm2O2S phases were determined. The Sm10S14O compound was optically characterized for the first time; its direct and indirect optical bandgaps were found equal to 2.48 and 2.37 eV, respectively. The determined direct and indirect optical bandgaps of Sm2O2S (4.4 eV and 3.95 eV, respectively) agree with the earlier measurements, thus confirming the accuracy of the chosen synthesis procedures.

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Держатели документа:
Institute of Chemistry, Tyumen State University, Volodarsky Str. 6, Tyumen, 625003, Russia
Department of Physical and Applied Chemistry, Kurgan State University, Sovetskaya Str. 63/4, Kurgan, 640020, Russian Federation
Federal Research Center KSC SB RAS, Kirensky Institute of Physics, Akademgorodok Str. 50, Building 38, Krasnoyarsk, 660036, Russia
Siberian Federal University, Svobodnyj Av. 79, Krasnoyarsk, 660079, Russia
Institute of Physical Materials Science, SB RAS, Sakhyanova Str. 6, Ulan-Ude, 670047, Russian Federation
Institute of Solid State Chemistry, Ural Branch, Russian Academy of Sciences, Pervomaiskaya Str. 91, Yekaterinburg, 620990, Russian Federation

Доп.точки доступа:
Yurev, I. O.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Kamaev, D. N.; Polkovnikov, A. A.; Grigorchenko, V. M.; Yarovenko, A. A.; Zelenaya, A. E.; Parfenova, M. D.; Andreev, O. V.
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    Synthesis, structure, melting and optical properties of three complex orthorhombic sulfides BaDyCuS3, BaHoCuS3 and BaYbCuS3 / N. O. Azarapin, V. V. Atuchin, N. G. Maximov [et al.] // Mater. Res. Bull. - 2021. - Vol. 140. - Ст. 111314, DOI 10.1016/j.materresbull.2021.111314. - Cited References: 60. - This study was supported by the Russian Science Foundation (19-42-02003). The authors would like to thank Alexey A. Lubin for his studies on SEM. The studies were carried out on the basis of laboratory of electron and probe microscopy in REC ‘Nanotechnologies’. This work was partially supported by the DST-RSF project under the India-Russia Programme of Cooperation in Science and Technology (No. DST/ INT/RUS/RSF/P-20 dated May 16, 2019). Shaibal Mukherjee would like to thank MeitY for the YFRF under the Visvesvaraya Ph.D. Scheme for Electronics and IT. This publication is an outcome of the R&D work undertaken in the project under the Visvesvaraya Ph.D. Scheme of MeitY being implemented by Digital India Corporation (formerly Media Lab Asia). We are grateful to the Krasnoyarsk Regional Center of Research Equipment of the Federal Research Center «Krasnoyarsk Science Center SB RAS» for the provided equipment . - ISSN 0025-5408
   Перевод заглавия: Синтез, строение, плавление и оптические свойства трех сложных орторомбических сульфидов BaDyCuS3, BaHoCuS3 и BaYbCuS3
Кл.слова (ненормированные):
Complex sulfides -- Crystal structure -- SEM -- Raman -- Melting point
Аннотация: Complex sulfides BaDyCuS3, BaHoCuS3 and BaYbCuS3 were synthesized in a flow of sulfiding gases (CS2, H2S) at 900°C from standard solutions of lanthanide and copper nitrates, as well as from the same standard Ba(OH)2 solution. The crystal structures of BaDyCuS3, BaHoCuS3 and BaYbCuS3 were obtained by the Rietveld refinement method. All three compounds crystallize in the Cmcm space group (KZrCuS3 structural type) as predicted by the tolerance factor analysis. Their micromorphological, thermal and spectroscopic properties are evaluated. BaDyCuS3 and BaHoCuS3 melt congruently at 1376.5 °C and 1363.8 °C. BaYbCuS3 melts incongruently at 1353.3 °C. The optical band gap is 2.45 eV for BaDyCuS3, 2.37 eV for BaHoCuS3 and 1.82 eV for BaYbCuS3. The low bandgap of BaYbCuS3 is explained by the charge transfer band of Yb at the bottom of conduction band. The vibrational parameters of BaDyCuS3, BaHoCuS3 and BaYbCuS3 crystals were determined with the use of Raman and Infrared spectroscopies.

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Держатели документа:
Institute of Chemistry, Tyumen State University, Tyumen, 625003, Russian Federation
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russian Federation
Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russian Federation
Institute of Chemistry and Chemical Technology, Federal Research Center KSC SB RAS, Krasnoyarsk, 660049, Russian Federation
Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Institute of Nanotechnology, Spectroscopy and Quantum Chemistry, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Laboratory of Crystal Physics, Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russian Federation
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Hybrid Nanodevice Research Group (HNRG), Electrical Engineering and Centre for Advanced Electronics (CAE), Indian Institute of Technology IndoreMadhya Pradesh 453552, India
Laboratory of the Chemistry of Rare Earth Compounds, Institute of Solid State Chemistry, UB RAS, Ekaterinburg, 620137, Russian Federation

Доп.точки доступа:
Azarapin, N. O.; Atuchin, V. V.; Maximov, N. G.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Shestakov, N. P.; Шестаков, Николай Петрович; Krylov, A. S.; Крылов, Александр Сергеевич; Burkhanova, T. M.; Mukherjee, S.; Andreev, O. V.
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Synthesis, structure, and properties of EuLnCuSe3 (Ln = Nd, Sm, Gd, Er) / O. V. Andreev, V. V. Atuchin, A. S. Aleksandrovsky [et al.] // Crystals. - 2022. - Vol. 12, Is. 1. - Ст. 17, DOI 10.3390/cryst12010017. - Cited References: 60. - The study was funded by the Ministry of Science and Higher Education of the Russian Ferderation (Projects AAAA-A21-121011390011-4 and AAAA-A19-119031890025-9), as well as the Government of the Tyumen Region (grant to non-profit organizations No. 2. 89-don, dated 7 December 2020) . - ISSN 2073-4352

РУБ Crystallography + Materials Science, Multidisciplinary
Рубрики:
RARE-EARTH
   CRYSTAL-STRUCTURE
   MAGNETIC-PROPERTIES
   CHALCOGENIDES
Кл.слова (ненормированные):
rare earth elements -- complex sulfides -- chalcogenides -- crystal structure -- magnetic properties
Аннотация: EuLnCuSe3 (Ln = Nd, Sm, Gd, Er), due to their complex composition, should be considered new materials with the ability to purposefully change the properties. Samples of the EuLnCuSe3 were prepared using Cu, rare earth metal, Se (99.99%) by the ampoule method. The samples were obtained by the crystallization from a melt and annealed at temperatures 1073 and 1273 K. The EuErCuSe3 crystal structure was established using the single-crystal particle. EuErCuSe3 crystallizes in the orthorhombic system, space group Cmcm, KCuZrS3 structure type, with cell parameters a = 4.0555 (3), b = 13.3570 (9), and c = 10.4602 (7) Å, V = 566.62 (6) Å3. In structure EuErCuSe3, erbium ions are coordinated by selenium ions in the octahedral polyhedron, copper ions are in the tetrahedral coordination, europium ions are between copper and erbium polyhedra layers and are coordinated by selenium ions as two-cap trigonal prisms. The optical band gap is 1.79 eV. At 4.7 K, a transition from the ferrimagnetic state to the paramagnetic state was detected in EuErCuSe3. At 85 and 293 K, the compound is in a paramagnetic state. According to XRPD data, EuLnCuSe3 (Ln = Nd, Sm, Gd) compounds have a Pnma orthorhombic space group of the Eu2CuS3 structure type. For EuSmCuSe3, a = 10.75704 (15) Å, b = 4.11120 (5) Å, c = 13.37778 (22) Å. In the series of EuLnCuSe3 compounds, the optical band gap increases 1.58 eV (Nd), 1.58 eV (Sm), 1.72 eV (Gd), 1.79 eV (Er), the microhardness of the 205 (Nd), 210 (Sm), 225 (Gd) 235 ± 4 HV (Er) phases increases, and the thermal stability of the phases increases significantly. According to the measurement data of differential scanning calorimetry, the EuNdCuSe3 decomposes, according to the solid-phase reaction T = 1296 K, ΔH = 8.2 ± 0.8 kJ/mol. EuSmCuSe3 melts incongruently T = 1449 K, ΔH = 18.8 ± 1.9 kJ/mol. For the EuGdCuSe3, two (Tα↔β = 1494 K, ΔHα↔β = 14.8 kJ/mol, Tβ↔γ = 1530 K, ΔHβ↔γ = 4.8 kJ/mol) and for EuErCuSe3 three polymorphic transitions (Tα↔β = 1561 K, ΔHα↔β = 30.3 kJ/mol, Tβ↔γ = 1579 K, ΔHβ↔γ = 4.4 kJ/mol, and Tγ↔δ = 1600 K, ΔHγ↔δ = 10.1 kJ/mol). The compounds melt incongruently at the temperature of 1588 K, ΔHmelt = 17.9 ± 1.8 kJ/mol and 1664 K, ΔHmelt = 25.6 ± 2.5 kJ/mol, respectively. Incongruent melting of the phases proceeds with the formation of a solid solution of EuSe and a liquid phase.

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Держатели документа:
Univ Tyumen, Inst Chem, Tyumen 625003, Russia.
RAS, Inst Semicond Phys, Lab Opt Mat & Struct, SB, Novosibirsk 630090, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
Novosibirsk State Tech Univ, Dept Ind Machinery Design, Novosibirsk 630073, Russia.
RAS, KSC, Fed Res Ctr, Kirensky Inst Phys,SB, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660036, Russia.
Ind Univ Tyumen, Dept Gen & Special Chem, Tyumen 625000, Russia.
RAS, Boreskov Inst Catalysis, SB, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Lab Mol Design & Ecol Safe Technol, Novosibirsk 630090, Russia.
RAS, Inst Solid State Chem, UB, Ekaterinburg 620990, Russia.

Доп.точки доступа:
Andreev, O. V.; Atuchin, V. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Denisenko, Y. G.; Zakharov, B. A.; Tyutyunnik, A. P.; Habibullayev, N. N.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Ulybin, D. A.; Shpindyuk, D. D.; Ministry of Science and Higher Education of the Russian Ferderation [AAAA-A21-121011390011-4, AAAA-A19-119031890025-9]; Government of the Tyumen Region [2. 89-don]
}
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    Synthesis, structural and spectroscopic properties of orthorhombic compounds BaLnCuS3 (Ln = Pr, Sm) / N. O. Azarapin [et al.] // J. Alloys Compd. - 2020. - Vol. 832. - Ст. 153134, DOI 10.1016/j.jallcom.2019.153134. - Cited References: 68. - This study was supported by the Russian Science Foundation (19-42-02003). Also, this study was supported by RFBR (18-32-20011, 18-03-00750, in part of Raman analysis). This work was partially supported by DST-RSF project under the India-Russia Programme of Cooperation in Science and Technology (No. DST/INT/RUS/RSF/P-20 dated May 16, 2019). Shaibal Mukherjee would like to thank the Ministry of Electronics and Information Technology (MeitY) for the Young Faculty Research Fellowship (YFRF) under Visvesvaraya Ph.D. Scheme for Electronics and IT. This publication is an outcome of the R&D work undertaken in the project under the Visvesvaraya Ph.D. Scheme of MeitY being implemented by Digital India Corporation (formerly Media Lab Asia). SEM investigations were carried out using the equipment of CKP “Nanostructures”, Novosibirsk, Russia. . - ISSN 0925-8388. - ISSN 1873-4669
   Перевод заглавия: Синтез, структурные и спектроскопические свойства ромбических кристаллов BaLnCuS3 (Ln = Pr, Sm)
Кл.слова (ненормированные):
Complex sulfides -- Crystal structure -- SEM -- Raman
Аннотация: Ternary sulfides BaPrCuS3 and BaSmCuS3 are first synthesized by the sulphidation reaction of a mixture of related oxides and metal Cu in a flow of (CS2, H2S) at 1170 K. The crystal structures of BaPrCuS3 and BaSmCuS3 are obtained by Rietveld method. BaPrCuS3 crystallizes in space group Pnma with unit cell parameters a = 10.56074(6), b = 4.11305(2) and c = 13.42845(7) Å, V = 583.289 (5) Å3, Z = 2 (structure type Eu2CuS3). BaSmCuS3 crystallizes in space group Cmcm with unit cell parameters a = 4.07269(4), b = 13.4499(1) and c = 10.3704(1) Å, V = 568.06 (1) Å3, Z = 2 (structure type KZrCuS3). The structural model is proposed for the Cmcm→Pnma transition in ABCX3 (X = S, Se) compounds for the sequence Sm-Pm-Nd-Pr. The dimensionless tolerance factor t = IR(A) × IR(C)/IR(B)2 is suggested to control the boundary between the Cmcm and Pnma structures. The micromorphological, thermal and spectroscopic properties are evaluated for BaPrCuS3. The compound melts incongruently at Tmelt = 1580.9 K. In BaPrCuS3, the band gap is estimated to be 2.1 eV. The vibrational parameters of BaPrCuS3 and BaSmCuS3 are comparatively observed by Raman spectroscopy.

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Держатели документа:
Institute of Chemistry, Tyumen State University, Tyumen, 625003, Russia
Laboratory of Coherent Optics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Department of Photonics and Laser Technologies, Siberian Federal University, Krasnoyarsk, 660041, Russia
Laboratory of Optical Materials and Structures, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russia
Functional Electronics Laboratory, Tomsk State University, Tomsk, 634050, Russia
Research and Development Department, Kemerovo State University, Kemerovo, 650000, Russia
Laboratory of Nanodiagnostics and Nanolithography, Institute of Semiconductor Physics, SB RAS, Novosibirsk, 630090, Russia
Laboratory of Molecular Spectroscopy, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Laboratory of Crystal Physics, Kirensky Institute of Physics Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russia
Department of Physics, Far Eastern State Transport University, Khabarovsk, 680021, Russia
Siberian Federal University, Krasnoyarsk, 660079, Russia
Hybrid Nanodevice Research Group (HNRG), Electrical Engineering, Indian Institute of Technology Indore, Madhya Pradesh, 453552, India

Доп.точки доступа:
Azarapin, N. O.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Atuchin, V. V.; Gavrilova, T. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Mukherjee, S.; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Andreev, O. V.; Андреев О. В.
}
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Study of electrical and thermoelecrical properties of sulfides TmxMn1-xS / S. S. Aplesnin [et al.] // Phys. Solid State. - 2016. - Vol. 58, Is. 1. - P. 19-24, DOI 10.1134/S1063783416010029. - Cited References: 25. - This study was supported by the Russian Foundation for Basic Research (project no. 15-42-04099 r_si-bir_a) and State Contract no. 114090470016. . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
SmxMn1-xS solid-solutions
   MnS
   Gd
   Transition
   Transport
   Crystal
Аннотация: Variable-valence TmxMn1–xS (0 ⩽ x ⩽ 0.15) compounds have been synthesized and their structural, electrical, and thermoelectrical properties have been studied in the temperature range of 80–1100 K. The regions of existence of solid solutions of sulfides TmxMn1–xS with the NaCl-type fcc lattice have been determined. It has been found that, as thulium ions are substituted for manganese cations, the electrical resistivity increases, and the lattice parameter increases more sharply than that corresponding to the Vegard’s law. The study of the temperature dependences of the thermopower coefficient has revealed that the current carrier sign is retained to 500 K for all the substitution concentrations, and the charge carrier type changes from the hole type to the electron type with variations in the temperature. The experimental data have been explained in terms of the exciton model.

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Публикация на русском языке Исследование электрических и термоэлектрических свойств сульфидов TmxMn1-xS [Текст] / С. С. Аплеснин [и др.] // Физ. тверд. тела : Физико-технический институт им. А. Ф. Иоффе РАН, 2016. - Т. 58 Вып. 1. - С. 21-26

Держатели документа:
Kirensky Institute of Metals, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50–38, Krasnoyarsk, Russian Federation
Reshetnikov Siberian Aerospace University, pr. imeni Gazety “Krasnoyarskii Rabochii” 31, Krasnoyarsk, Russian Federation
Scientific–Practical Materials Centre, National Academy of Sciences of Belarus, ul. P. Brovki 19, Minsk, Belarus
Institute of Inorganic Chemistry, Siberian Branch of the Russian Academy of Sciences, pr. Akademika Lavrent’eva 3, Novosibirsk, Russian Federation

Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Romanova, O. B.; Романова, Оксана Борисовна; Galyas, A. I.; Sokolov, V. V.
}
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Romanova, O. B.
Structural properties of sulfides chalcogenides manganese substituted by elements with variable valency / O. B. Romanova, L. V. Udod, O. F. Demidenko // IOP Conf. Ser.: Mater. Sci. Eng. - 2020. - Vol. 918, Is. 1. - Ст. 012101DOI 10.1088/1757-899X/918/1/012101. - Cited References: 33. - The reported study was funded by RFBR according to the research project №20-52-00005 Bel_a
Аннотация: The structure and transport of YbXMn1-XS and TmXMn1-XS sulfides (0.05=X=0.2) was studied in the temperature range 80-500K. The temperature ranges of local deformations and a decrease of the thermal expansion coefficient with increasing concentration X caused of anomalous compressibility in the magnetically ordered region are determined for a system doped with ytterbium. Pinning temperatures of lattice polarons are established, which are accompanied by lattice deformation and IR mode condensation for a system doped with thulium.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center Ksc Sb Ras, Krasnoyarsk, 660036, Russian Federation
Reshetnev Siberian State University of Science and Technology, Krasnoyarsk, 660037, Russian Federation
Scientific-Practical Materials Research Center Nas, Minsk, 220072, Belarus

Доп.точки доступа:
Udod, L. V.; Удод, Любовь Викторовна; Demidenko, O. F.; Романова, Оксана Борисовна; International Scientific Conference Transport of Siberia 2020(8th ; (22-27 May 2020 ; Novosibirsk, Russia)
}
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10.

Physical properties and colossal magnetoresistance in 3d-sulfides / G. M. Abramova [et al.] // Workshop INTAS - Sib. Branch of the RAS Sci. Cooperation on the Res. Project “New Layered 3d-Materials for Spintronics” / chairman G. A. Petrakovskii. - 2007. - P. 12
Аннотация: INTAS (The International Association for the Promotion of Cooperation with Scientists from the New Independent States of the Former Soviet Union) — международная ассоциация по содействию сотрудничеству с учёными новых независимых государств бывшего Советского Союза. Некоммерческая организация, финансировалась главным образом из бюджета Европейского Союза. Являлась крупнейшим фондом, поддерживающим научное сотрудничество между учёными стран бывшего СССР и Европейского Союза с 1993 г. Программы INTAS охватывали широкий круг научно-исследовательских проблем. 22 сентября 2006 года было принято решение о прекращении осуществления программы на основании рекомендации Европейской Комиссии. С 1 апреля 2007 года прекратилось распределение новых грантов.

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Доп.точки доступа:
Petrakovskii, G. A. \chairman\; Петраковский, Герман Антонович; Abramova, G. M.; Абрамова, Галина Михайловна; Petrakovskii, G. A.; Volkov, N. V.; Волков, Никита Валентинович; Bayukov, O. A.; Баюков, Олег Артемьевич; Vorotynov, A. M.; Воротынов, Александр Михайлович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Kiselev, N.; Bovina, A. F.; Бовина, Ася Федоровна; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Sokolov, V. V.; Соколов В.В.; Boehm, M.; Szymchak, R.; Roessli, B.; "New Layered 3d-Materials for Spintronics", Workshop INTAS - Siberian Branch of the Russian Academy of Sciences Scientific Cooperation on the Research Project(2007 ; March 20-23 ; Krasnoyarsk)
}
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11.

Phase transitions and colossal magnetoresistance in CuVxCr1-xS2 layered disulfides / G. M. Abramova [et al.] // JETP Letters. - 2006. - Vol. 83, Is. 3. - P. 118-121, DOI 10.1134/S0021364006030088. - Cited References: 10 . - ISSN 0021-3640

РУБ Physics, Multidisciplinary
Рубрики:
SULFIDES
Аннотация: New substances CuVxCr1-xS2 are synthesized in which colossal magnetoresistance (T-C = 95 K, delta(H) = -60%, H = 7 kOe), as well as the sequence of phase transitions with change in the conduction type and magnetic order, is observed as temperature is varied. The change found in the magnetic and electric properties of the CuVxCr1-xS2 compounds may be a consequence of a specific disintegration into Cu+Cr+S2 and CU2+Cr2+S2 and a change in the concentration relation between these electronic phases in the substance bulk.

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Держатели документа:
Russian Acad Sci, Kirenskii Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
Bashkortostan State Univ, Ufa 450074, Russia
ИФ СО РАН
Kirenski Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw, Poland
Bashkortostan State University, ul. Frunze 32, Ufa 450074, Russian Federation

Доп.точки доступа:
Abramova, G. M.; Абрамова, Галина Михайловна; Petrakovskii, G. A.; Петраковский, Герман Антонович; Vorotynov, A. M.; Воротынов, Александр Михайлович; Velikanov, A. A.; Kiselev, N. I.; Bovina, A. F.; Бовина, Ася Федоровна; Szymczak, R.; Al'mukhametov, R. F.
}
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12.

Neutron investigation of FeXMn1–XS under pressure / G. M. Abramova [et al.] // VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. P3.6. - P. 188. - References: 2 . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
sulfides -- pressure -- magnetism -- neutron experiment

Доп.точки доступа:
Abramova, G. M.; Абрамова, Галина Михайловна; Boehm, M.; Schefer, Juerg; Piovano, Andrea; Mita, Yoshimi; Sokolov, V. V.; Соколов В. В.; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН

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13.

Mossbauer studies of FexMn1-xS single crystals / G. M. Abramova [et al.] // Phys. Solid State. - 2008. - Vol. 50, Is. 2. - P. 237-240, DOI 10.1134/S1063783408020042. - Cited References: 16 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
METAL-INSULATOR-TRANSITION
   MAGNETIC-PROPERTIES
   ALPHA-MNS
   SULFIDES
   MAGNETORESISTANCE
   PRESSURE
   SYSTEM
   OXIDES
Аннотация: Single crystals of iron manganese sulfides FexMn1-xS (0.25

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Держатели документа:
[Abramova, G. M.
Petrakovskii, G. A.
Bayukov, O. A.
Bovina, A. F.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Varnek, V. A.
Sokolov, V. V.] Russian Acad Sci, Siberian Branch, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
ИФ СО РАН

Доп.точки доступа:
Abramova, G. M.; Абрамова, Галина Михайловна; Petrakovskii, G. A.; Петраковский, Герман Антонович; Bayukov, O. A.; Баюков, Олег Артемьевич; Varnek, V. A.; Sokolov, V. V.; Bovina, A. F.; Бовина, Ася Федоровна
}
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14.

Abramova, G. M.
Metal-insulator transition, magnetoresistance, and magnetic properties of 3d-sulfides (Review) / G. M. Abramova, G. A. Petrakovskii // Low Temp. Phys. - 2006. - Vol. 32, Is. 8-9. - P. 725-734 ; Физика низких температур, DOI 10.1063/1.2219495. - Cited References: 74 . - ISSN 1063-777X

РУБ Physics, Applied
Рубрики:
GIANT-MAGNETORESISTANCE
   PHASE-TRANSITION
   ALPHA-MNS
   COLOSSAL MAGNETORESISTANCE
   SINGLE-CRYSTALS
   FES-MNS
   SULFIDES
   FERROMAGNETISM
   SEMICONDUCTORS
   TEMPERATURE
Аннотация: The results of a study of the transport and magnetic properties of some sulfides of 3d elements are reported. The concentration transitions with a change of conductivity type and a change of magnetic order are considered, and the features of the colossal magnetoresistance in FexMn1-xS and CuVxCr1-xS2 solid solutions are discussed.

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Держатели документа:
Russian Acad Sci, LV Kirenskii Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
L. V. Kirenskii Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, Akademgorodok 660036, Russian Federation

Доп.точки доступа:
Petrakovskii, G. A.; Петраковский, Герман Антонович; Абрамова, Галина Михайловна

}
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15.

Metal-insulator transition in FexMn1-xS crystals / G. M. Abramova [et al.] // JETP Letters. - 2007. - Vol. 86, Is. 6. - P. 371-374, DOI 10.1134/S0021364007180051. - Cited References: 15 . - ISSN 0021-3640

РУБ Physics, Multidisciplinary
Рубрики:
ALPHA-MNS
PHASE-TRANSITION
SULFIDES
Аннотация: Results of an experimental study of MnS, FeS, and FexMn1-xS single crystals are presented. The phase composition, the lattice parameters, and the state of paramagnetic ions in FexMn1-xS have been determined by x-ray diffraction analysis and Mossbauer spectroscopy. A sequence of transitions have been found in iron manganese sulfide with x = 0.29 at temperatures T-1 approximate to 25-50 K, T-2 approximate to 125 K, and T-3 approximate to 190 K with a change in kinetic properties and the formation of a metallic state at low temperatures T approximate to 2 K. The possibility of a Mott-Hubbard transition in FexMn1-xS sulfides with variation of the composition and the temperature is discussed.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Russian Acad Sci, Nikolaev Inst Inorgan Chem, Novosibirsk 630090, Russia
Osaka Univ, Toyonaka, Osaka 5608531, Japan
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation
Nikolaev Institute of Inorganic Chemistry, Siberian Branch, Russian Academy of Sciences, Novosibirsk 630090, Russian Federation
Osaka University, Toyonaka, Osaka 560-8531, Japan

Доп.точки доступа:
Abramova, G. M.; Абрамова, Галина Михайловна; Volkov, N. V.; Волков, Никита Валентинович; Petrakovskii, G. A.; Петраковский, Герман Антонович; Mita, Y.; Bayukov, O. A.; Баюков, Олег Артемьевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Vorotynov, A. A.; Sokolov, V. V.; Bovina, A. F.; Бовина, Ася Федоровна
}
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16.

Metal-dielectric transitions, magnetism, and electronic structure in a system of manganese-doped vanadium sulfides / G. V. Loseva [et al.] // Phys. Solid State. - 2000. - Vol. 42, Is. 3. - P. 539-543, DOI 10.1134/1.1131245. - Cited References: 12 . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
TRANSPORT
Аннотация: The effect of the manganese doping of vanadium monosulfide in a system of the V1-xMnxS (0 x less than or equal to 0.3) solid solutions on their structure and thermal, electrical, and magnetic properties has been investigated. The metal-dielectric transitions are revealed in the studied ranges of concentrations and temperatures. These transitions are accompanied by a change in the magnetic properties. It is demonstrated that the correlation in changes of the electrical and magnetic properties of the sulfides under investigation is characteristic of the metal-dielectric transitions in strongly correlated systems. (C) 2000 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
ИФ СО РАН

Доп.точки доступа:
Loseva, G. V.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Balaev, A. D.; Балаев, Александр Дмитриевич; Kiselev, N. I.
}
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17.

Magnetotransport effects and electronic phase separation in manganese sulfides with electron-hole doping / O. B. Romanova, S. S. Aplesnin, M. N. Sitnikov, L. V. Udod // J. Exp. Theor. Phys. - 2021. - Vol. 132, Is. 5. - P. 831-842, DOI 10.1134/S106377612103016X. - Cited References: 38. - This study was supported by the Russian Foundation for Basic Research and the Belarussian Republic Foundation for Basic Research (project no. 20-52-00005) . - ISSN 1063-7761. - ISSN 1090-6509

РУБ Physics, Multidisciplinary
Рубрики:
MAGNETIC-PROPERTIES
TRANSITION
MAGNETORESISTANCE
Аннотация: We analyze the effect of electron and hole doping with a low substituent concentration (x = 0.01) on the magnetic and electron subsystems in disordered semiconductors MexMn1-xS (Me = Ag and Tm) in a wide range of temperatures (77–1000 K) and magnetic fields up to 12 kOe. Using magnetic measurements, we have established the domains of ferron (polaron) formation in the vicinity of the magnetic phase transition. We have detected the magnetoimpedance and magnetoresistance, the magnitude and sign of which depend on the electric field, temperature, and the type of the substituent element. We have determined the temperatures of thermopower peaks associated with deformation of the crystalline structure. We have established the phonon and magnon contributions to charge carrier relaxation using the method of impedance spectroscopy and the Jahn–Teller mode of oscillations from the IR spectra for the system containing silver. We have determined the diffusion contribution to the conductivity from the impedance hodograph in TmxMn1-xS semiconductors. The experimental results are described using the models of supermagnetic clusters, ferroelectric domains, and the Debye model.

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Публикация на русском языке Магнитотранспортные эффекты и электронное фазовое расслоение в сульфидах марганца с электронно-дырочным допированием [Текст] / О. Б. Романова, С. С. Аплеснин, М. Н. Ситников, Л. В. Удод // Журн. эксперим. и теор. физ. - 2021. - Т. 159 Вып. 5. - С. 938-951

Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia.

Доп.точки доступа:
Romanova, O. B.; Романова, Оксана Борисовна; Aplesnin, S. S.; Аплеснин, Сергей Степанович; Sitnikov, M. N.; Udod, L. V.; Удод, Любовь Викторовна; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Belarussian Republic Foundation for Basic Research [20-52-00005]
}
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18.

Magnetoresistance, magnetoimpedance, magnetothermopower, and photoconductivity in silver-doped manganese sulfides / O. B. Romanova [et al.] // J. Appl. Phys. - 2019. - Vol. 125, Is. 17. - Ст. 175706, DOI 10.1063/1.5085701. - Cited References: 29. - This study was supported by the Russian Foundation for Basic Research (Project No. 18-52-00009 Bel_a). The reported study was funded by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (Project No. 18-42-240001 r_a), to the research project: "Inversion of the Sign of the Components of the Magnetoelectric Tensor on the Temperature in Films of Bismuth Garnet Ferrite Replaced by Neodymium." This study was carried out in the framework of the state task No. 3.5743.2017/6.7. . - ISSN 0021-8979. - ISSN 1089-7550

РУБ Physics, Applied
Рубрики:
MAGNETIC-PROPERTIES
RESISTIVITY
Аннотация: New multifunction materials in the AgXMn1‒XS (Х = 0.05) system have been synthesized and investigated in the temperature range of 77‒500 K in magnetic fields up to 12 kOe. Near the temperature of the magnetic transition (ТN = 176 K), the anomalous behavior of the temperature dependence of magnetization has been observed and has been attributed to the formation of ferrons. An analysis of the infrared spectroscopy data and I‒V characteristics has revealed the spin-polaron subband splitting. Several conductivity channels have been found from the impedance spectra. The temperature and magnetic field dependences of the carrier relaxation time have been obtained. The magnetoresistance (−21%), magnetoimpedance (−65%), magnetothermopower (−40%), and photoconductivity effects have been detected. The majority carrier type, density, and mobility have been determined from the Hall-effect measurement data. The observed effects have been explained using a ferron model.
Синтезированы и исследованы новые многофункциональные материалы системы AgXMn1-XS (Х=0.05) в интервале температур 77-500К в магнитных полях до 12 кЭ. В близи температуры магнитного перехода (ТN=176К) наблюдается аномальное поведение температурной зависимости намагниченности, вызванное образованием ферронов. Найдено расщепление спин-поляронной подзоны из ИК спектроскопии и вольт-амперных характеристик. Установлено несколько каналов проводимости из спектров импеданса, отличающихся частоте. Определена зависимость времени релаксации носителей заряда от температуры и магнитного поля. Обнаружено четыре эффекта: магнитосопротивление (-21%), магнитоимпеданс (-65%), магнитотермоЭДС (-40%) и фотопроводимость. Найдены: тип, концентрация и подвижность основных носителей заряда из холловских измерений. Обнаруженные эффекты объясняются в модели ферронов.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.
Siberian State Univ Sci & Technol, Dept Phys, Krasnoyarsk 660014, Russia.
Sci Pract Mat Res Ctr NAS, Minsk 220072, BELARUS.

Доп.точки доступа:
Romanova, O. B.; Романова, Оксана Борисовна; Aplesnin, S. S.; Аплеснин, Сергей Степанович; Udod, L. V.; Удод, Любовь Викторовна; Sitnikov, M. N.; Kretinin, V. V.; Yanushkevich, K. I.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Russian Foundation for Basic Research [18-52-00009 Bel_a]; Government of Krasnoyarsk Territory; Krasnoyarsk Regional Fund of Science [18-42-240001 r_a]
}
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19.

    Magnetoresistance and magnetoimpedance in holmium manganese sulfides / O. B. Romanova, S. S. Aplesnin, M. N. Sitnikov [et al.] // Appl. Phys. A. - 2022. - Vol. 128, Is. 2. - Ст. 124, DOI 10.1007/s00339-021-05198-x. - Cited References: 46. - Funding was provided by Russian Foundation for Fundamental Investigations (20-42-243002) . - ISSN 0947-8396. - ISSN 1432-0630
   Перевод заглавия: Магнитосопротивление и магнитоимпеданс в гольмиевом сульфиде марганца

РУБ Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
PHASE-SEPARATION
IMPEDANCE
Кл.слова (ненормированные):
Sulfides -- I-V characteristics -- Electrical polarization -- Magnetoresistance -- Magnetoimpedance
Аннотация: The structure, transport characteristics, real and imaginary parts of the impedance components and electric polarization of the HoXMn1-XS (X = 0.1 and 0.2) system have been investigated in the temperature range of 80-500 K in magnetic fields of up to 12 kOe. The morphology of synthesized samples has been studied. The influence of the magnetic field on the transport characteristics, on both direct and alternating currents of holmium manganese sulfides, have been established. The negative effects of DC magnetoresistance in the region of the magnetic phase transition and positive AC magnetoimpedance up to 4% in the paramagnetic region have been established. The critical temperatures of the existence of the electric polarization have been determined. At a substitution concentration of X = 0.1, the activation character of the relaxation time versus temperature has been found. The diffusion contribution for the composition with X = 0.2 has been established by the impedance hodograph.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660014, Russia.

Доп.точки доступа:
Romanova, O. B.; Романова, Оксана Борисовна; Aplesnin, S. S.; Аплеснин, Сергей Степанович; Sitnikov, M. N.; Udod, L. V.; Удод, Любовь Викторовна; Kharkov, A. M.; Russian Foundation for Fundamental InvestigationsRussian Foundation for Basic Research (RFBR) [20-42-243002]
}
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20.

Magnetoelastic coupling in the triangular lattice antiferromagnet CuCrS2 / JCE Rasch [et al.] // Phys. Rev. B. - 2009. - Vol. 80, Is. 10. - Ст. 104431, DOI 10.1103/PhysRevB.80.104431. - Cited References: 30. - We are grateful for support and allocated beam time at the Institut Laue-Langevin (D1A, IN3),Grenoble, France, the spallation neutron source SINQ (TriCS, DMC) and the SLS-MS beamline, both Paul Scherrer Insitut, Villigen, Switzerland. This work was supported by INTAS Grant No. 06-1000013-9002 of the Russian Academy of Science (RAS), Siberian Branch. . - ISSN 1098-0121

РУБ Physics, Condensed Matter
Рубрики:
NEUTRON POWDER DIFFRACTION
   MAGNETIC-STRUCTURE
   STRUCTURAL-PROPERTIES
   PHASE-TRANSITION
   SOLID OXYGEN
   ALPHA-PHASES
   BETA-PHASES
   SELENIDES
   SULFIDES
Аннотация: CuCrS2 is a triangular lattice Heisenberg antiferromagnet with a rhombohedral crystal structure. We report on neutron and synchrotron powder diffraction results which reveal a monoclinic lattice distortion at the magnetic transition and verify a magnetoelastic coupling. CuCrS2 is therefore an interesting material to study the influence of magnetism on the relief of geometrical frustration.

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Держатели документа:
[Rasch, Julia C. E.
Boehm, Martin
Ritter, Clemens
Mutka, Hannu] Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France
[Rasch, Julia C. E.
Schefer, Juerg
Keller, Lukas] ETH, Neutron Scattering Lab, CH-5232 Villigen, Switzerland
[Cervellino, Antonio] Paul Scherrer Inst, Swiss Light Source, CH-5232 Villigen, Switzerland
[Abramova, Galina M.] SB RAS, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Loeffler, Joerg F.] ETH, Dept Mat, Lab Met Phys & Technol, CH-8093 Zurich, Switzerland
ИФ СО РАН
Institut Laue-Langevin, 6 Rue Jules Horowitz, 38042 Grenoble Cedex 9, France
Laboratory for Neutron Scattering, ETH Zurich, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland
L.V. Kirensky Institute of Physics, SB, RAS, Krasnoyarsk 660036, Russian Federation
Swiss Light Source, Paul Scherrer Institut, CH-5232 Villigen PSI, Switzerland
Laboratory of Metal Physics and Technology, Department of Materials, ETH Zurich, 8093 Zurich, Switzerland

Доп.точки доступа:
Rasch, JCE; Boehm, M.; Ritter, C.; Mutka, H.; Schefer, J.; Keller, L.; Abramova, G. M.; Абрамова, Галина Михайловна; Cervellino, A.; Loffler, J. F.; Russian Academy of Science (RAS), Siberian Branch [06-1000013-9002]
}
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