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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Романова, Оксана Борисовна, Харьков, Анатолий Михайлович, Ситников, Максим Николаевич, Кретинин В. В.
Заглавие : Переход металл-диэлектрик в катион-замещенных соединениях ReхMn1-xS (Re = Gd, Sm, Ho)
Место публикации : Вестник СибГАУ. - Красноярск: СибГАУ, 2015. - Т. 16, № 2. - С. 478-484. - ISSN 1816-9724 (Шифр В22/2015/16/2)
Примечания : Библиогр.: 38. - Работа выполнена при финансовой поддержке РФФИ № 15-42-04099 р_Cибирь_а и государственного задания № 114090470016.
Ключевые слова (''Своб.индексиров.''): сульфиды редкоземельных элементов--проводимость--переход металл-диэлектрик--термоэдс--sulfides of rare-earth elements--conductivity--transition metal-insulator--thermoelectric power
Аннотация: Представлены результаты исследования транспортных свойств катион-замещенных сульфидов RexMn1-xS (Re = Gd, Sm, Ho) с ГЦК-решеткой типа NaCl в области температур 77-1200 К. С увеличением степени катионного замещения в этих соединениях RexMn1-xS (Re = Gd, Sm, Ho) изменяется тип проводимости от полупроводникового до металлического при критической концентрации Х С. Концентрационный переход металл-диэлектрик в системе Gd XMn 1-XS сопровождается уменьшением величины удельного электросопротивления на 12 порядков и коэффициента термоЭДС (α) на два порядка. Катионное замещение в твердых растворах GdxMn1-xS приводит к смене дырочного типа проводимости (α 0), свойственного моносульфиду марганца, на электронный (α 0). Уменьшение величины α с увеличением содержания гадолиния в решетке MnS указывает на то, что Gd действует как донорная примесь. Для Sm 0,2Mn 0,8S обнаружен резкий максимум сопротивления при Т This paper presents the results of a study of the transport properties of cation-substituted sulfides Re XMn 1-XS (Re = = Gd, Sm, Ho) with FCC NaCl type in the temperature range 77-1200 K. With increasing degree of cation substitution in these compounds Re XMn 1- ХS (Re = Gd, Sm, Ho) the conductivity type changes from the semiconductor to the «metal» at the critical concentration X C. The concentration of metal-insulator transition in the system Gd XMn 1-XS is accompanied by a decreasing in the electrical resistivity of value on 12 orders and Seebeck coefficient (α) is on two orders. The cation-substitution in the solid solutions Gd XMn 1-XS leads to p-type conductivity (α 0), as comprising to electronic (α 0) for manganese monosulfide. Decrease of α with increasing gadolinium concentration in the MnS lattice indicates that the Gd acts as a donor impurity. For Sm 0,2Mn0,8S a maximum resistance at T
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2.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Романова, Оксана Борисовна, Аплеснин, Сергей Степанович, Удод, Любовь Викторовна
Заглавие : Кинетические эффекты в сульфидах марганца замещенных тулием и иттербием
Коллективы : "Новое в магнетизме и магнитных материалах", международная конференция, Научный совет по физике конденсированных сред РАН, МИРЭА - Российский технологический университет, Московский государственный университет им. М.В. Ломоносова, Магнитное общество России
Место публикации : Новое в магнетизме и магнитных материалах: сборник трудов XXIV международной конференции/ прогр. ком.: Р. С. Исхаков, С. Г. Овчинников. - 2021. - Секция 7: Кинетические эффекты в магнетиках. - С. 17-20
Примечания : Библиогр.: 9. - Исследование выполнено при финансовой поддержке РФФИ и БРФФИ в рамках научного проекта No 20-52-00005
Аннотация: Данная работа посвящена изучению кинетических эффектов в сульфидах марганца допированных элементами с переменной валентностью (Yb и Tm с Х≤0.05) измеренных в диапазоне температур (77-400 K) и магнитных полей до 12 кЭ. Из ВАХ определены механизмы проводимости, для системы Yb0.05Mn0.99S преобладает Пула– Френкеля, а для Tm0.01Mn0.99S описывается законом Ома. Обнаружен эффект магнитосопротивления в этих системах. Наблюдаются аномалии на температурной зависимости термоЭДС.This work is to the study of kinetic effects in manganese sulfides doped with elements with variable valence (Yb and Tm with X≤0.05) measured in the temperature range (77-400 K) and magnetic fields up to 12 kOe. The conduction mechanisms are determined by I – V characteristics: for the Yb0.05Mn0.99S is Poole – Frenkel, and for Tm0.01Mn0.99S it is described by Ohm's law. The effect of magnetoresistance is found in these systems. Anomalies are observed in the temperature dependence of the thermoEMF.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Ryabinkina L. I., Romanova O. B., Velikanov D. A., Balaev A. D., Balaev D. A., Yanushkevich K. I., Galyas A. I., Demidenko O. F., Bandurina O. N.
Заглавие : Transport properties and ferromagnetism of Co(x)Mn(1-x)Ssulfides
Разночтения заглавия :авие SCOPUS: Transport properties and ferromagnetism of Co x Mn 1 - X S sulfides
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 106, Is. 4. - P765-772. - ISSN 1063-7761, DOI 10.1134/S1063776108040158
Примечания : Cited References: 39
Предметные рубрики: GIANT VOLUME MAGNETOSTRICTION
COLOSSAL MAGNETORESISTANCE
MAGNETIC SEMICONDUCTORS
ELECTRICAL-PROPERTIES
ROOM-TEMPERATURE
ALPHA-MNS
SPINTRONICS
TRANSITION
FEXMN1-XS
FIELDS
Ключевые слова (''Своб.индексиров.''): coulomb interactions--current voltage characteristics--electromotive force--ferromagnetism--magnetic susceptibility--magnetization--thermoelectricity--transport properties--charge susceptibility--external magnetic fields--temperature intervals--thermoelectromotive force--cobalt compounds
Аннотация: We have studied the resistivity and thermoelectromotive force (thermo emf) in a temperature range of T = 80-1000 K, the magnetic susceptibility and magnetization in a temperature range of T= 4.2-300 K at an external magnetic field of up to 70 kOe, and the structural characteristics of CoxMn1 - S-x sulfides (0
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Yurev I. O., Aleksandrovsky A. S., Kamaev D. N., Polkovnikov A. A., Grigorchenko V. M., Yarovenko A. A., Zelenaya A. E., Parfenova M. D., Andreev O. V.
Заглавие : The Sm2S3-X-SmS-Sm2O2S refractory system: thermal analysis, phase diagram, and properties of the phases
Колич.характеристики :17 с
Место публикации : J. Therm. Anal. Calorim. - 2024. - Vol. 149, Is. 5. - P.2057-2073. - ISSN 13886150 (ISSN), DOI 10.1007/s10973-023-12792-z. - ISSN 15882926 (eISSN)
Примечания : Cited References: 90. - The authors thank Prof. P.P. Fedorov, Chief Researcher of Prokhorov Institute of General Physics, Russian Academy of Sciences, for scientific advices. The authors thank N.I. Lozhkin, engineer of the Department of Inorganic and Physical Chemistry, Tyumen State University for the technical support of the visual thermal analysis setup. The authors thank N.A. Shulaev, research engineer of the Center for Nature-Inspired Engineering, Tyumen State University, for determining the elemental composition of samples by scanning electron microscopy. The authors thank I.V. Palamarchuk, research engineer of the Center for Collective Use "Rational Nature Management and Physical and Chemical Research" of the Tyumen State University, for measuring the diffuse reflectance spectra. The authors thank Doctor of Philology O.V. Trofimova, Professor at the Institute of Social Sciences and Humanities of the Tyumen State University, for her advices on academic writingThis study was funded by the Russian Science Foundation, Project No. 23–23-00488 “Search for EMF generation conditions in gradient ceramics of samarium monosulfide (SmS)”
Аннотация: Samarium monosulfide, a strain gauge and barometric material, exists in equilibrium with Sm3S4 and Sm2O2S in the S-Sm–O system. Therefore, studying phase equilibria in the refractory Sm2S3-X-SmS-Sm2O2S system is a scientifically interesting task. In this system, 49 samples were synthesized and studied by powder XRD, differential scanning calorimetry, visual thermal analysis, and microstructural analysis. Melting points of Sm3S4, SmS, and Sm2O2S compounds were determined. Eutectic diagrams of Sm3S4-Sm2O2S, SmS-Sm2O2S, SmS-Sm3S4 systems were constructed. Temperatures and compositions of the binary eutectic points were determined. Fusion enthalpies for Sm3S4, SmS, and Sm2O2S phases were estimated using the Schröder–Le Chatelier equation. The liquidus lines were calculated using second-degree polynomials and Redlich–Kister model. Coordinates of the ternary eutectic point in the Sm3S4-SmS-Sm2O2S system were calculated using the cutting-plane method and the Scheffé method. The calculated compositions of ternary eutectic points were averaged at one most probable point, in accordance with the data on the samples microstructure. The experimental temperature of the ternary eutectic point coincides with the calculated values within the margin of error. Positions of eutectic valleys and approximate positions of isotherms in the system were established. Thermodynamic parameters of the α-Sm2S3 → γ-Sm2S3 polymorphic transition and the dependence of the Sm2S3-X composition on heat treatment conditions were determined. According to the scanning electron microscopy data, the approximate composition of the crystallized from the melt Sm2S3 sample is Sm2S2.95. The Sm10S14O phase decomposes at 1470 ± 15 °C in the course of a solid-phase reaction. The phase diagram of the Sm2S3-X-Sm2O2S system was revisited. Optical band gaps of Sm10S14O and Sm2O2S phases were determined. The Sm10S14O compound was optically characterized for the first time; its direct and indirect optical bandgaps were found equal to 2.48 and 2.37 eV, respectively. The determined direct and indirect optical bandgaps of Sm2O2S (4.4 eV and 3.95 eV, respectively) agree with the earlier measurements, thus confirming the accuracy of the chosen synthesis procedures.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Azarapin N. O., Atuchin V. V., Maximov N. G., Aleksandrovsky A. S., Molokeev M. S., Oreshonkov A. S., Shestakov N. P., Krylov A. S., Burkhanova T. M., Mukherjee S., Andreev O. V.
Заглавие : Synthesis, structure, melting and optical properties of three complex orthorhombic sulfides BaDyCuS3, BaHoCuS3 and BaYbCuS3
Место публикации : Mater. Res. Bull. - 2021. - Vol. 140. - Ст.111314. - ISSN 00255408 (ISSN), DOI 10.1016/j.materresbull.2021.111314
Примечания : Cited References: 60. - This study was supported by the Russian Science Foundation (19-42-02003). The authors would like to thank Alexey A. Lubin for his studies on SEM. The studies were carried out on the basis of laboratory of electron and probe microscopy in REC ‘Nanotechnologies’. This work was partially supported by the DST-RSF project under the India-Russia Programme of Cooperation in Science and Technology (No. DST/ INT/RUS/RSF/P-20 dated May 16, 2019). Shaibal Mukherjee would like to thank MeitY for the YFRF under the Visvesvaraya Ph.D. Scheme for Electronics and IT. This publication is an outcome of the R&D work undertaken in the project under the Visvesvaraya Ph.D. Scheme of MeitY being implemented by Digital India Corporation (formerly Media Lab Asia). We are grateful to the Krasnoyarsk Regional Center of Research Equipment of the Federal Research Center «Krasnoyarsk Science Center SB RAS» for the provided equipment
Аннотация: Complex sulfides BaDyCuS3, BaHoCuS3 and BaYbCuS3 were synthesized in a flow of sulfiding gases (CS2, H2S) at 900°C from standard solutions of lanthanide and copper nitrates, as well as from the same standard Ba(OH)2 solution. The crystal structures of BaDyCuS3, BaHoCuS3 and BaYbCuS3 were obtained by the Rietveld refinement method. All three compounds crystallize in the Cmcm space group (KZrCuS3 structural type) as predicted by the tolerance factor analysis. Their micromorphological, thermal and spectroscopic properties are evaluated. BaDyCuS3 and BaHoCuS3 melt congruently at 1376.5 °C and 1363.8 °C. BaYbCuS3 melts incongruently at 1353.3 °C. The optical band gap is 2.45 eV for BaDyCuS3, 2.37 eV for BaHoCuS3 and 1.82 eV for BaYbCuS3. The low bandgap of BaYbCuS3 is explained by the charge transfer band of Yb at the bottom of conduction band. The vibrational parameters of BaDyCuS3, BaHoCuS3 and BaYbCuS3 crystals were determined with the use of Raman and Infrared spectroscopies.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Andreev O. V., Atuchin V. V., Aleksandrovsky A. S., Denisenko Y. G., Zakharov B. A., Tyutyunnik A. P., Habibullayev N. N., Velikanov D. A., Ulybin D. A., Shpindyuk D. D.
Заглавие : Synthesis, structure, and properties of EuLnCuSe3 (Ln = Nd, Sm, Gd, Er)
Коллективы : Ministry of Science and Higher Education of the Russian Ferderation [AAAA-A21-121011390011-4, AAAA-A19-119031890025-9]; Government of the Tyumen Region [2. 89-don]
Место публикации : Crystals. - 2022. - Vol. 12, Is. 1. - Ст.17. - ISSN 2073-4352(eISSN), DOI 10.3390/cryst12010017
Примечания : Cited References: 60. - The study was funded by the Ministry of Science and Higher Education of the Russian Ferderation (Projects AAAA-A21-121011390011-4 and AAAA-A19-119031890025-9), as well as the Government of the Tyumen Region (grant to non-profit organizations No. 2. 89-don, dated 7 December 2020)
Предметные рубрики: RARE-EARTH
CRYSTAL-STRUCTURE
MAGNETIC-PROPERTIES
CHALCOGENIDES
Аннотация: EuLnCuSe3 (Ln = Nd, Sm, Gd, Er), due to their complex composition, should be considered new materials with the ability to purposefully change the properties. Samples of the EuLnCuSe3 were prepared using Cu, rare earth metal, Se (99.99%) by the ampoule method. The samples were obtained by the crystallization from a melt and annealed at temperatures 1073 and 1273 K. The EuErCuSe3 crystal structure was established using the single-crystal particle. EuErCuSe3 crystallizes in the orthorhombic system, space group Cmcm, KCuZrS3 structure type, with cell parameters a = 4.0555 (3), b = 13.3570 (9), and c = 10.4602 (7) Å, V = 566.62 (6) Å3. In structure EuErCuSe3, erbium ions are coordinated by selenium ions in the octahedral polyhedron, copper ions are in the tetrahedral coordination, europium ions are between copper and erbium polyhedra layers and are coordinated by selenium ions as two-cap trigonal prisms. The optical band gap is 1.79 eV. At 4.7 K, a transition from the ferrimagnetic state to the paramagnetic state was detected in EuErCuSe3. At 85 and 293 K, the compound is in a paramagnetic state. According to XRPD data, EuLnCuSe3 (Ln = Nd, Sm, Gd) compounds have a Pnma orthorhombic space group of the Eu2CuS3 structure type. For EuSmCuSe3, a = 10.75704 (15) Å, b = 4.11120 (5) Å, c = 13.37778 (22) Å. In the series of EuLnCuSe3 compounds, the optical band gap increases 1.58 eV (Nd), 1.58 eV (Sm), 1.72 eV (Gd), 1.79 eV (Er), the microhardness of the 205 (Nd), 210 (Sm), 225 (Gd) 235 ± 4 HV (Er) phases increases, and the thermal stability of the phases increases significantly. According to the measurement data of differential scanning calorimetry, the EuNdCuSe3 decomposes, according to the solid-phase reaction T = 1296 K, ΔH = 8.2 ± 0.8 kJ/mol. EuSmCuSe3 melts incongruently T = 1449 K, ΔH = 18.8 ± 1.9 kJ/mol. For the EuGdCuSe3, two (Tα↔β = 1494 K, ΔHα↔β = 14.8 kJ/mol, Tβ↔γ = 1530 K, ΔHβ↔γ = 4.8 kJ/mol) and for EuErCuSe3 three polymorphic transitions (Tα↔β = 1561 K, ΔHα↔β = 30.3 kJ/mol, Tβ↔γ = 1579 K, ΔHβ↔γ = 4.4 kJ/mol, and Tγ↔δ = 1600 K, ΔHγ↔δ = 10.1 kJ/mol). The compounds melt incongruently at the temperature of 1588 K, ΔHmelt = 17.9 ± 1.8 kJ/mol and 1664 K, ΔHmelt = 25.6 ± 2.5 kJ/mol, respectively. Incongruent melting of the phases proceeds with the formation of a solid solution of EuSe and a liquid phase.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Azarapin N. O., Aleksandrovsky A. S., Atuchin V. V., Gavrilova T. A., Krylov A. S., Molokeev M. S., Mukherjee S., Oreshonkov A. S., Andreev O. V.
Заглавие : Synthesis, structural and spectroscopic properties of orthorhombic compounds BaLnCuS3 (Ln = Pr, Sm)
Место публикации : J. Alloys Compd. - 2020. - Vol. 832. - Ст.153134. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2019.153134. - ISSN 1873-4669 (eISSN)
Примечания : Cited References: 68. - This study was supported by the Russian Science Foundation (19-42-02003). Also, this study was supported by RFBR (18-32-20011, 18-03-00750, in part of Raman analysis). This work was partially supported by DST-RSF project under the India-Russia Programme of Cooperation in Science and Technology (No. DST/INT/RUS/RSF/P-20 dated May 16, 2019). Shaibal Mukherjee would like to thank the Ministry of Electronics and Information Technology (MeitY) for the Young Faculty Research Fellowship (YFRF) under Visvesvaraya Ph.D. Scheme for Electronics and IT. This publication is an outcome of the R&D work undertaken in the project under the Visvesvaraya Ph.D. Scheme of MeitY being implemented by Digital India Corporation (formerly Media Lab Asia). SEM investigations were carried out using the equipment of CKP “Nanostructures”, Novosibirsk, Russia.
Аннотация: Ternary sulfides BaPrCuS3 and BaSmCuS3 are first synthesized by the sulphidation reaction of a mixture of related oxides and metal Cu in a flow of (CS2, H2S) at 1170 K. The crystal structures of BaPrCuS3 and BaSmCuS3 are obtained by Rietveld method. BaPrCuS3 crystallizes in space group Pnma with unit cell parameters a = 10.56074(6), b = 4.11305(2) and c = 13.42845(7) Å, V = 583.289 (5) Å3, Z = 2 (structure type Eu2CuS3). BaSmCuS3 crystallizes in space group Cmcm with unit cell parameters a = 4.07269(4), b = 13.4499(1) and c = 10.3704(1) Å, V = 568.06 (1) Å3, Z = 2 (structure type KZrCuS3). The structural model is proposed for the Cmcm→Pnma transition in ABCX3 (X = S, Se) compounds for the sequence Sm-Pm-Nd-Pr. The dimensionless tolerance factor t = IR(A) × IR(C)/IR(B)2 is suggested to control the boundary between the Cmcm and Pnma structures. The micromorphological, thermal and spectroscopic properties are evaluated for BaPrCuS3. The compound melts incongruently at Tmelt = 1580.9 K. In BaPrCuS3, the band gap is estimated to be 2.1 eV. The vibrational parameters of BaPrCuS3 and BaSmCuS3 are comparatively observed by Raman spectroscopy.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aplesnin S. S., Romanova O. B., Galyas A. I., Sokolov V. V.
Заглавие : Study of electrical and thermoelecrical properties of sulfides TmxMn1-xS
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 58, Is. 1. - P.19-24. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783416010029
Примечания : Cited References: 25. - This study was supported by the Russian Foundation for Basic Research (project no. 15-42-04099 r_si-bir_a) and State Contract no. 114090470016.
Предметные рубрики: SmxMn1-xS solid-solutions
MnS
Gd
Transition
Transport
Crystal
Аннотация: Variable-valence TmxMn1–xS (0 ⩽ x ⩽ 0.15) compounds have been synthesized and their structural, electrical, and thermoelectrical properties have been studied in the temperature range of 80–1100 K. The regions of existence of solid solutions of sulfides TmxMn1–xS with the NaCl-type fcc lattice have been determined. It has been found that, as thulium ions are substituted for manganese cations, the electrical resistivity increases, and the lattice parameter increases more sharply than that corresponding to the Vegard’s law. The study of the temperature dependences of the thermopower coefficient has revealed that the current carrier sign is retained to 500 K for all the substitution concentrations, and the charge carrier type changes from the hole type to the electron type with variations in the temperature. The experimental data have been explained in terms of the exciton model.
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9.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Romanova O. B., Udod L. V., Demidenko O. F.
Заглавие : Structural properties of sulfides chalcogenides manganese substituted by elements with variable valency
Коллективы : International Scientific Conference Transport of Siberia 2020
Место публикации : IOP Conf. Ser.: Mater. Sci. Eng. - 2020. - Vol. 918, Is. 1. - Ст.012101. - DOI 10.1088/1757-899X/918/1/012101
Примечания : Cited References: 33. - The reported study was funded by RFBR according to the research project №20-52-00005 Bel_a
Аннотация: The structure and transport of YbXMn1-XS and TmXMn1-XS sulfides (0.05=X=0.2) was studied in the temperature range 80-500K. The temperature ranges of local deformations and a decrease of the thermal expansion coefficient with increasing concentration X caused of anomalous compressibility in the magnetically ordered region are determined for a system doped with ytterbium. Pinning temperatures of lattice polarons are established, which are accompanied by lattice deformation and IR mode condensation for a system doped with thulium.
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10.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Abramova G. M., Petrakovskii G. A., Volkov N. V., Bayukov O. A., Vorotynov A. M., Velikanov D. A., Kiselev N., Bovina A. F., Vasiliev A. D., Sokolov V. V., Boehm M., Szymchak R., Roessli B.
Заглавие : Physical properties and colossal magnetoresistance in 3d-sulfides
Коллективы : "New Layered 3d-Materials for Spintronics", Workshop INTAS - Siberian Branch of the Russian Academy of Sciences Scientific Cooperation on the Research Project
Место публикации : Workshop INTAS - Sib. Branch of the RAS Sci. Cooperation on the Res. Project “New Layered 3d-Materials for Spintronics”/ chairman G. A. Petrakovskii. - 2007. - P.12
Аннотация: INTAS (The International Association for the Promotion of Cooperation with Scientists from the New Independent States of the Former Soviet Union) — международная ассоциация по содействию сотрудничеству с учёными новых независимых государств бывшего Советского Союза. Некоммерческая организация, финансировалась главным образом из бюджета Европейского Союза. Являлась крупнейшим фондом, поддерживающим научное сотрудничество между учёными стран бывшего СССР и Европейского Союза с 1993 г. Программы INTAS охватывали широкий круг научно-исследовательских проблем. 22 сентября 2006 года было принято решение о прекращении осуществления программы на основании рекомендации Европейской Комиссии. С 1 апреля 2007 года прекратилось распределение новых грантов.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abramova G. M., Petrakovskii G. A., Vorotynov A. M., Velikanov A. A., Kiselev N. I., Bovina A. F., Szymczak R., Al'mukhametov R. F.
Заглавие : Phase transitions and colossal magnetoresistance in CuVxCr1-xS2 layered disulfides
Разночтения заглавия :авие SCOPUS: Phase transitions and colossal magnetoresistance in CuVxCr 1-x S2 layered disulfides
Место публикации : JETP Letters. - 2006. - Vol. 83, Is. 3. - P.118-121. - ISSN 0021-3640, DOI 10.1134/S0021364006030088
Примечания : Cited References: 10
Предметные рубрики: SULFIDES
Аннотация: New substances CuVxCr1-xS2 are synthesized in which colossal magnetoresistance (T-C = 95 K, delta(H) = -60%, H = 7 kOe), as well as the sequence of phase transitions with change in the conduction type and magnetic order, is observed as temperature is varied. The change found in the magnetic and electric properties of the CuVxCr1-xS2 compounds may be a consequence of a specific disintegration into Cu+Cr+S2 and CU2+Cr2+S2 and a change in the concentration relation between these electronic phases in the substance bulk.
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12.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Abramova G. M., Boehm M., Schefer, Juerg, Piovano, Andrea, Mita Yoshimi, Sokolov V. V.
Заглавие : Neutron investigation of FeXMn1–XS under pressure
Коллективы : Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium, Институт физики им. Л.В. Киренского Сибирского отделения РАН
Место публикации : VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016): abstracts/ ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk: KIP RAS SB, 2016. - Ст.P3.6. - P.188. - ISBN 978-5-904603-06-9 (Шифр -478014040)
Примечания : References: 2
Ключевые слова (''Своб.индексиров.''): sulfides--pressure--magnetism--neutron experiment
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abramova G. M., Petrakovskii G. A., Bayukov O. A., Varnek V. A., Sokolov V. V., Bovina A. F.
Заглавие : Mossbauer studies of FexMn1-xS single crystals
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 50, Is. 2. - P237-240. - ISSN 1063-7834, DOI 10.1134/S1063783408020042
Примечания : Cited References: 16
Предметные рубрики: METAL-INSULATOR-TRANSITION
MAGNETIC-PROPERTIES
ALPHA-MNS
SULFIDES
MAGNETORESISTANCE
PRESSURE
SYSTEM
OXIDES
Аннотация: Single crystals of iron manganese sulfides FexMn1-xS (0.25
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abramova G. M., Petrakovskii G. A.
Заглавие : Metal-insulator transition, magnetoresistance, and magnetic properties of 3d-sulfides (Review)
Место публикации : Low Temp. Phys. - 2006. - Vol. 32, Is. 8-9. - P.725-734. - ISSN 1063-777X, DOI 10.1063/1.2219495; \b Физика низких температур
Примечания : Cited References: 74
Предметные рубрики: GIANT-MAGNETORESISTANCE
PHASE-TRANSITION
ALPHA-MNS
COLOSSAL MAGNETORESISTANCE
SINGLE-CRYSTALS
FES-MNS
SULFIDES
FERROMAGNETISM
SEMICONDUCTORS
TEMPERATURE
Аннотация: The results of a study of the transport and magnetic properties of some sulfides of 3d elements are reported. The concentration transitions with a change of conductivity type and a change of magnetic order are considered, and the features of the colossal magnetoresistance in FexMn1-xS and CuVxCr1-xS2 solid solutions are discussed.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Abramova G. M., Volkov N. V., Petrakovskii G. A., Mita Y., Bayukov O. A., Velikanov D. A., Vorotynov A. A., Sokolov V. V., Bovina A. F.
Заглавие : Metal-insulator transition in FexMn1-xS crystals
Разночтения заглавия :авие SCOPUS: Metal-insulator transition in Fe x Mn1-x S crystals
Место публикации : JETP Letters. - 2007. - Vol. 86, Is. 6. - P.371-374. - ISSN 0021-3640, DOI 10.1134/S0021364007180051
Примечания : Cited References: 15
Предметные рубрики: ALPHA-MNS
PHASE-TRANSITION
SULFIDES
Аннотация: Results of an experimental study of MnS, FeS, and FexMn1-xS single crystals are presented. The phase composition, the lattice parameters, and the state of paramagnetic ions in FexMn1-xS have been determined by x-ray diffraction analysis and Mossbauer spectroscopy. A sequence of transitions have been found in iron manganese sulfide with x = 0.29 at temperatures T-1 approximate to 25-50 K, T-2 approximate to 125 K, and T-3 approximate to 190 K with a change in kinetic properties and the formation of a metallic state at low temperatures T approximate to 2 K. The possibility of a Mott-Hubbard transition in FexMn1-xS sulfides with variation of the composition and the temperature is discussed.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Loseva G. V., Ovchinnikov S. G., Balaev A. D., Kiselev N. I.
Заглавие : Metal-dielectric transitions, magnetism, and electronic structure in a system of manganese-doped vanadium sulfides
Место публикации : Phys. Solid State: AMER INST PHYSICS, 2000. - Vol. 42, Is. 3. - P539-543. - ISSN 1063-7834, DOI 10.1134/1.1131245
Примечания : Cited References: 12
Предметные рубрики: TRANSPORT
Аннотация: The effect of the manganese doping of vanadium monosulfide in a system of the V1-xMnxS (0 x less than or equal to 0.3) solid solutions on their structure and thermal, electrical, and magnetic properties has been investigated. The metal-dielectric transitions are revealed in the studied ranges of concentrations and temperatures. These transitions are accompanied by a change in the magnetic properties. It is demonstrated that the correlation in changes of the electrical and magnetic properties of the sulfides under investigation is characteristic of the metal-dielectric transitions in strongly correlated systems. (C) 2000 MAIK "Nauka/Interperiodica".
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova O. B., Aplesnin S. S., Sitnikov M. N., Udod L. V.
Заглавие : Magnetotransport effects and electronic phase separation in manganese sulfides with electron-hole doping
Коллективы : Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Belarussian Republic Foundation for Basic Research [20-52-00005]
Место публикации : J. Exp. Theor. Phys. - 2021. - Vol. 132, Is. 5. - P.831-842. - ISSN 1063-7761, DOI 10.1134/S106377612103016X. - ISSN 1090-6509(eISSN)
Примечания : Cited References: 38. - This study was supported by the Russian Foundation for Basic Research and the Belarussian Republic Foundation for Basic Research (project no. 20-52-00005)
Предметные рубрики: MAGNETIC-PROPERTIES
TRANSITION
MAGNETORESISTANCE
Аннотация: We analyze the effect of electron and hole doping with a low substituent concentration (x = 0.01) on the magnetic and electron subsystems in disordered semiconductors MexMn1-xS (Me = Ag and Tm) in a wide range of temperatures (77–1000 K) and magnetic fields up to 12 kOe. Using magnetic measurements, we have established the domains of ferron (polaron) formation in the vicinity of the magnetic phase transition. We have detected the magnetoimpedance and magnetoresistance, the magnitude and sign of which depend on the electric field, temperature, and the type of the substituent element. We have determined the temperatures of thermopower peaks associated with deformation of the crystalline structure. We have established the phonon and magnon contributions to charge carrier relaxation using the method of impedance spectroscopy and the Jahn–Teller mode of oscillations from the IR spectra for the system containing silver. We have determined the diffusion contribution to the conductivity from the impedance hodograph in TmxMn1-xS semiconductors. The experimental results are described using the models of supermagnetic clusters, ferroelectric domains, and the Debye model.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova O. B., Aplesnin S. S., Udod L. V., Sitnikov M. N., Kretinin V. V., Yanushkevich K. I., Velikanov D. A.
Заглавие : Magnetoresistance, magnetoimpedance, magnetothermopower, and photoconductivity in silver-doped manganese sulfides
Коллективы : Russian Foundation for Basic Research [18-52-00009 Bel_a]; Government of Krasnoyarsk Territory; Krasnoyarsk Regional Fund of Science [18-42-240001 r_a]
Место публикации : J. Appl. Phys. - 2019. - Vol. 125, Is. 17. - Ст.175706. - ISSN 0021-8979, DOI 10.1063/1.5085701. - ISSN 1089-7550(eISSN)
Примечания : Cited References: 29. - This study was supported by the Russian Foundation for Basic Research (Project No. 18-52-00009 Bel_a). The reported study was funded by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (Project No. 18-42-240001 r_a), to the research project: "Inversion of the Sign of the Components of the Magnetoelectric Tensor on the Temperature in Films of Bismuth Garnet Ferrite Replaced by Neodymium." This study was carried out in the framework of the state task No. 3.5743.2017/6.7.
Предметные рубрики: MAGNETIC-PROPERTIES
RESISTIVITY
Аннотация: New multifunction materials in the AgXMn1‒XS (Х = 0.05) system have been synthesized and investigated in the temperature range of 77‒500 K in magnetic fields up to 12 kOe. Near the temperature of the magnetic transition (ТN = 176 K), the anomalous behavior of the temperature dependence of magnetization has been observed and has been attributed to the formation of ferrons. An analysis of the infrared spectroscopy data and I‒V characteristics has revealed the spin-polaron subband splitting. Several conductivity channels have been found from the impedance spectra. The temperature and magnetic field dependences of the carrier relaxation time have been obtained. The magnetoresistance (−21%), magnetoimpedance (−65%), magnetothermopower (−40%), and photoconductivity effects have been detected. The majority carrier type, density, and mobility have been determined from the Hall-effect measurement data. The observed effects have been explained using a ferron model.Синтезированы и исследованы новые многофункциональные материалы системы AgXMn1-XS (Х=0.05) в интервале температур 77-500К в магнитных полях до 12 кЭ. В близи температуры магнитного перехода (ТN=176К) наблюдается аномальное поведение температурной зависимости намагниченности, вызванное образованием ферронов. Найдено расщепление спин-поляронной подзоны из ИК спектроскопии и вольт-амперных характеристик. Установлено несколько каналов проводимости из спектров импеданса, отличающихся частоте. Определена зависимость времени релаксации носителей заряда от температуры и магнитного поля. Обнаружено четыре эффекта: магнитосопротивление (-21%), магнитоимпеданс (-65%), магнитотермоЭДС (-40%) и фотопроводимость. Найдены: тип, концентрация и подвижность основных носителей заряда из холловских измерений. Обнаруженные эффекты объясняются в модели ферронов.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Romanova O. B., Aplesnin S. S., Sitnikov M. N., Udod L. V., Kharkov A. M.
Заглавие : Magnetoresistance and magnetoimpedance in holmium manganese sulfides
Коллективы : Russian Foundation for Fundamental InvestigationsRussian Foundation for Basic Research (RFBR) [20-42-243002]
Место публикации : Appl. Phys. A. - 2022. - Vol. 128, Is. 2. - Ст.124. - ISSN 0947-8396, DOI 10.1007/s00339-021-05198-x. - ISSN 1432-0630(eISSN)
Примечания : Cited References: 46. - Funding was provided by Russian Foundation for Fundamental Investigations (20-42-243002)
Предметные рубрики: PHASE-SEPARATION
IMPEDANCE
Аннотация: The structure, transport characteristics, real and imaginary parts of the impedance components and electric polarization of the HoXMn1-XS (X = 0.1 and 0.2) system have been investigated in the temperature range of 80-500 K in magnetic fields of up to 12 kOe. The morphology of synthesized samples has been studied. The influence of the magnetic field on the transport characteristics, on both direct and alternating currents of holmium manganese sulfides, have been established. The negative effects of DC magnetoresistance in the region of the magnetic phase transition and positive AC magnetoimpedance up to 4% in the paramagnetic region have been established. The critical temperatures of the existence of the electric polarization have been determined. At a substitution concentration of X = 0.1, the activation character of the relaxation time versus temperature has been found. The diffusion contribution for the composition with X = 0.2 has been established by the impedance hodograph.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Rasch JCE, Boehm M., Ritter C., Mutka H., Schefer J., Keller L., Abramova G. M., Cervellino A., Loffler J. F.
Заглавие : Magnetoelastic coupling in the triangular lattice antiferromagnet CuCrS2
Коллективы : Russian Academy of Science (RAS), Siberian Branch [06-1000013-9002]
Место публикации : Phys. Rev. B. - 2009. - Vol. 80, Is. 10. - Ст.104431. - ISSN 1098-0121, DOI 10.1103/PhysRevB.80.104431
Примечания : Cited References: 30. - We are grateful for support and allocated beam time at the Institut Laue-Langevin (D1A, IN3),Grenoble, France, the spallation neutron source SINQ (TriCS, DMC) and the SLS-MS beamline, both Paul Scherrer Insitut, Villigen, Switzerland. This work was supported by INTAS Grant No. 06-1000013-9002 of the Russian Academy of Science (RAS), Siberian Branch.
Предметные рубрики: NEUTRON POWDER DIFFRACTION
MAGNETIC-STRUCTURE
STRUCTURAL-PROPERTIES
PHASE-TRANSITION
SOLID OXYGEN
ALPHA-PHASES
BETA-PHASES
SELENIDES
SULFIDES
Аннотация: CuCrS2 is a triangular lattice Heisenberg antiferromagnet with a rhombohedral crystal structure. We report on neutron and synchrotron powder diffraction results which reveal a monoclinic lattice distortion at the magnetic transition and verify a magnetoelastic coupling. CuCrS2 is therefore an interesting material to study the influence of magnetism on the relief of geometrical frustration.
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