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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhou G., Ren Q., Molokeev M. S., Zhou Y., Zhang J., Zhang X. -M.
Заглавие : Unraveling the ultrafast self-assembly and photoluminescence in zero-dimensional Mn2+-based halides with narrow-band green emissions
Место публикации : ACS Appl. Electron. Mater. - 2021. - Vol. 3, Is. 9. - P.4144-4150. - ISSN 26376113 (ISSN), DOI 10.1021/acsaelm.1c00606
Примечания : Cited References: 37. - This work is supported by the Natural Science Foundation of China (no. 21871167) and the 1331 project of Shanxi Province and funded by RFBR according to the research project no. 19-52-80003
Аннотация: The discovery of narrow-band luminescent materials remains an immense challenge to optimize the performance of white light-emitting diodes (LEDs). So far, the zero-dimensional (0D) Mn2+-based halides with near-unity narrow-band emissions have emerged as a class of promising phosphors in solid-state displays, but the related large-scale synthesis strategies have not been proposed and evaluated. Herein, we report an in situ synthetic process of 0D Mn2+-based halides and utilize (C20H20P)2MnBr4 as a case to investigate the photoluminescence characteristics and the structural essence of ultrafast self-assembly. The bright green emission peak at 523 nm with a full width at half maximum of 48 nm for (C20H20P)2MnBr4 is attributed to the d–d transition (4T1–6A1) of tetrahedrally coordinated [MnBr4]2– centers, and the fabricated white LED device shows a wide color gamut of 103.7% National Television System Committee (NTSC) standard. Remarkably, the experimental and theoretical results indicate that there are hydrogen bonding of C–H···Br and weak van der Waals interactions between [C20H20P]+ and [MnBr4]2–, resulting in the root for the realization of ultrafast self-assembly in 0D Mn2+-based halides. This work reveals a feasible and general synthesis method for preparing 0D Mn2+-based halides, thereby providing a possibility for their industrial application in solid-state displays.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Aleksandrovsky A. S., Gerasimova M. A., Tomilin F. N., Mironov V. A., Demina A. V., Xia Z., Molokeev M. S.
Заглавие : Luminescent zero-dimensional hybrid lead thiohalide nanostructures for high quantum yield and broadband excitation
Место публикации : ACS Appl. Nano Mat. - 2021. - Vol. 4, Is. 4. - P.3654-3663. - ISSN 25740970 (ISSN), DOI 10.1021/acsanm.1c00162
Примечания : Cited References: 55. - This work is supported by the RFBR according to the research project No. 19-52-80003. This work is also supported by the National Natural Science Foundation of China (51961145101). V.M. thanks Russian Foundation for Basic Research (project number 19-03-00043) for funding. The use of equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS” is acknowledged. The authors thank JSCC RAS for providing computational resources
Аннотация: Luminescent trans-[Pb(DMTU-S)4Cl2] (DMTU: N,N′-dimethylthiourea) was designed and prepared via either mechanochemical or solvothermal methods, and the structures of DMTU and trans-[Pb(DMTU-S)4Cl2] have been resolved using X-ray single-crystal diffraction. Upon excitation over broadband covering the range from 450 to 250 nm, trans-[Pb(DMTU-S)4Cl2] shows yellow-green emission peaking at 549 nm with a spectral width of 110 nm, which is assigned to the triplet–singlet transition of Pb2+ ions within distorted heterogeneous S4Cl2 octahedra. The broadband excitation comprised singlet–singlet transitions of Pb2+ ions and energy transfer from orbitals involving those of organic ligands. Simultaneous analysis of the luminescent bandwidth and Stokes shift gives for Pb2+ ions in S4Cl2 octahedra the value of the Huang–Rhys parameter S = 4.25 and the energy of phonon involved in the formation of the luminescence spectrum of the order of 90 meV. Quantum yield as high as 91% is detected for excitation at 365 nm. This high quantum yield indicates the absence of noticeable concentration quenching at an average distance of 9.4 Å between the Pb2+ ions within the structure of trans-[Pb(DMTU)4Cl2]. The weak spin–orbit intersystem crossing is deduced from a high photoluminescence quantum yield (PLQY) value. Time dependent-density functional theory (TD-DFT) calculations of the nanocluster indicate the red shift of absorption bands in Pb(DMTU)4Cl2 with respect to parent DMTU. The high-performance photoluminescence and stability demonstrated promising applications in photonics.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhou, Guojun, Liu, Zhiyang, Molokeev M. S., Xiao, Zewen, Xia, Zhiguo, Zhang, Xian-Ming
Заглавие : Manipulation of Cl/Br transmutation in zero-dimensional Mn2+-based metal halides toward tunable photoluminescence and thermal quenching behaviors
Место публикации : J. Mater. Chem. C. - 2021. - Vol. 9, Is. 6. - P.2047-2053. - ISSN 2050-7526, DOI 10.1039/d0tc05137c. - ISSN 2050-7534(eISSN)
Примечания : Cited References: 56. - The present work was financially supported by the Natural Science Foundation of China (21871167), and 1331 Project of Shanxi Province and the Postgraduate Innovation Project of Shanxi Normal University (2019XBY018), and funded by RFBR according to the research project no. 19-52-80003
Аннотация: Low-dimensional-networked metal halides are attractive for the screening of emitters applied in solid-state lighting and displays, but the lead toxicity and poor stability are obstacles that must be overcome in industrial applications. Herein, we aim at the discovery of bright and stable photoluminescence in zero-dimensional (0D) Mn2+-based metal halides. By manipulation of Cl/Br transmutation, the nature of the halogen can be confirmed as a pivotal factor to tune the PL behaviors, and the optimum Mn2+ emission with a high PLQY of 99.8% and a short lifetime of 0.372 ms can be achieved in (C24H20P)2MnBr4. The thermal quenching behaviors have been discussed in depth, indicating that the synergistic effect of good chemical stability of organic groups, a long Mn⋯Mn distance of 10.447 Å and a relatively large activation energy (ΔE = 0.277 eV) provides a platform for achieving excellent thermal stability in (C24H20P)2MnBr4. Moreover, the as-fabricated white LED device with a high luminous efficacy of 118.9 lm W−1 and a wide color gamut of 105.3% National Television System Committee (NTSC) shows that (C24H20P)2MnBr4 can be employed as a desirable narrow-band green emitter for LED displays. This work provides a new understanding of fine tailoring halogens, and proposes a feasible approach to achieving high thermal stability emitters toward the targeted practical applications.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Deng, Chenkai, Hao, Shiqiang, Liu, Kunjie, Molokeev M. S., Wolverton, Christopher, Fan, Liubing, Zhou, Guojun, Chen, D.a., Zhao, Jing, Liu, Quanlin
Заглавие : Broadband light emitting zero-dimensional antimony and bismuth-based hybrid halides with diverse structures
Коллективы : Beijing Municipal Natural Science FoundationBeijing Natural Science Foundation [2182080]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51972021, 51702329]; Fundamental Research Funds for the Central UniversitiesFundamental Research Funds for the Central Universities [FRF-IDRY-19-005]; RFBRRussian Foundation for Basic Research (RFBR) [19-52-80003]; Department of Energy, Office of Science Basic Energy SciencesUnited States Department of Energy (DOE) [DE-SC0014520]
Место публикации : J. Mater. Chem. C. - 2021. - Vol. 9, Is. 44. - P.15942-15948. - ISSN 2050-7526, DOI 10.1039/d1tc04198c. - ISSN 2050-7534(eISSN)
Примечания : Cited References: 52. - This work was supported by Beijing Municipal Natural Science Foundation (2182080) and the National Natural Science Foundation of China (51972021 and 51702329). The work was partly supported by the Fundamental Research Funds for the Central Universities (FRF-IDRY-19-005) and by the RFBR according to the research project No. 19-52-80003. S. H. and C. W. (DFT calculations) acknowledge support from the Department of Energy, Office of Science Basic Energy Sciences under Grant DE-SC0014520. Access to QUEST, the supercomputing resources facilities at Northwestern University, is also acknowledged
Предметные рубрики: CRYSTAL-STRUCTURE
LONE-PAIR
EMISSION
PEROVSKITES
TIN
LUMINESCENCE
Аннотация: Low-dimensional organic–inorganic metal halides have recently attracted extensive attention because of their various structures and distinguished photoelectric properties. Herein, we report a series of new zero-dimensional organic–inorganic hybrid metal halides: (TMEDA)3Bi2Cl12·H2O, (TMEDA)3Bi2Br12·H2O, (TMEDA)3Sb2Br12·H2O, and (TMEDA)5Sb6Cl28·2H2O [TMEDA = N,N,N′·trimethylethylenediamine]. (TMEDA)3M2X12·H2O (M = Bi or Sb, X = Cl or Br) crystallizes in the monoclinic space group P21/n, and (TMEDA)5Sb6Cl28·2H2O crystallizes in the orthorhombic space group Pnma. (TMEDA)3M2X12 possesses a zero-dimensional structure with the metal halide ions of [MBr6]3− isolated by the organic TMEDA2+ cations. Interestingly, the (TMEDA)5Sb6Cl28·2H2O structure consists of a combination of corner-connected octahedra [Sb4Cl18]6− and edge-shared [Sb2Cl10]4−, which is quite rare. The light emission of all these compounds was measured, and (TMEDA)3Sb2Br12·H2O exhibits the most intense luminescence. Upon 400 nm ultraviolet light excitation, (TMEDA)3Sb2Br12·H2O exhibited strong broadband yellow emission centered at 625 nm with a full-width at half-maximum of ∼150 nm originating from self-trapped excitons. This work suggests the possibility of new types of hybrid halides by introducing different metal centers and probing the structural evolution and photoluminescent properties, serving as a reference for the relationship between structure and luminescent performance and demonstrating their potential use as phosphors in light-emitting diodes.
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Ignatchenko V. A., Polukhin D. S.
Заглавие : Magnetoelastic Resonance in Zero-Mean Magnetostrictive Media
Коллективы : Euro-Asian Symposium "Trends in MAGnetism", Russian Acad Sci, Inst Metal Phys
Место публикации : TRENDS IN MAGNETISM. - STAFA-ZURICH: TRANS TECH PUBLICATIONS LTD, 2011. - Vol. 168-169. - P.101-104. - (Solid State Phenomena). - ISBN 1012-0394, DOI 10.4028/www.scientific.net/SSP.168-169.101
Примечания : Cited Reference Count: 7
Предметные рубрики: Materials Science, Multidisciplinary
Physics, Condensed Matter
Ключевые слова (''Своб.индексиров.''): spin waves--elastic waves--magnetoelastic coupling--inhomogeneities--self-consistent approximation--dynamic susceptibility
Аннотация: The interaction between two wave fields of different nature that are caused by rms fluctuations of the coupling parameter between these fields in media with zero-mean coupling parameter is. considered. Taking into consideration the multiple scattering processes of waves on the inhomogeneities leads to the results considerably different from those that have been obtained for the same situation in the Bourret approximation earlier [4,5]. Instead of the degeneration removal of frequencies in the wave spectrum and the appearance of two resonance peaks in the dynamic susceptibility at the intersection of the initial dispersion laws, the sharp broadening of the self-mode peak has to be observed. The consideration is done by the example of magnetoelastic waves in zero-mean magnetostrictive media.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhou, Guojun, Ding, Jialiang, Jiang, Xingxing, Zhang, Jian, Molokeev M. S., Ren, Qiqiong, Zhou, Jun, Li, Shili, Zhang, Xian-Ming
Заглавие : Coordination units of Mn2+ modulation toward tunable emission in zero-dimensional bromides for white light-emitting diodes
Место публикации : J. Mater. Chem. C. - 2022. - Vol. 10, Is. 6. - P.2095-2102. - ISSN 2050-7526, DOI 10.1039/d1tc05680h. - ISSN 2050-7534(eISSN)
Примечания : Cited References: 57. - The present work was supported by the Natural Science Foundation of China (21871167), the 1331 Project of Shanxi Province and the Postgraduate Innovation Project of Shanxi Normal University (2019XBY018), the Beijing Natural Science Foundation (No. 2214068) and funded by RFBR according to the research project no. 19-52-80003
Предметные рубрики: HALIDE PEROVSKITE NANOCRYSTALS
RECENT PROGRESS
DOPING MN2+
Аннотация: Organic–inorganic metal halides have become a multifunctional platform for manipulating photoluminescence due to highly efficient and tunable emissions, especially for lead-free Mn2+-based halides. Herein, the zero-dimensional (0D) bromides of (C5H14N3)2MnBr4 and (CH6N3)2MnBr4 with different coordination environments were designed and synthesized by a solvent evaporation method. They exhibit green and red broadband emission peaks at 528 nm and 627 nm with high photoluminescence quantum yields of 86.83% and 61.91%, respectively, which are attributed to the d–d transition (4T1(G) → 6A1(S)) of [MnBr4]2− tetrahedral and [Mn3Br12]6− octahedral units. The cases emphasize the effect of organic ligands on the intrinsic emissions of Mn2+ ions, thereby revealing the luminescence mechanism of Mn2+ ions in 0D isolated structures through the Tanabe–Sugano (TS) energy diagram. Thanks to their bright and stable emissions, the fabricated white light-emitting diode (LED) based on (C5H14N3)2MnBr4 and (CH6N3)2MnBr4 provides an outstanding color rendering index (Ra) of 90.8 at a correlated color temperature (CCT) of 3709 K, along with the CIE chromaticity coordinates of (0.3985, 0.3979) and a luminous efficacy of 51.2 lm W−1. This work aims at clarifying the relationship between the coordination units of Mn2+ and tunable emissions, and in particular, proposes a new strategy to explore phosphors excited by blue light for white LEDs.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Molokeev M. S., Su, Binbin, Aleksandrovsky A. S., Golovnev, Nicolay N., Plyaskin M. E., Xia, Zhiguo
Заглавие : Machine learning analysis and discovery of zero-dimensional ns2 metal halides toward enhanced photoluminescence quantum yield
Место публикации : Chem. Mat. - 2022. - Vol. 34, Is. 2. - P.537-546. - ISSN 0897-4756, DOI 10.1021/acs.chemmater.1c02725. - ISSN 1520-5002(eISSN)
Примечания : Cited References: 66. - This work is supported by the National Natural Science Foundation of China (51961145101 and 51972118), International Cooperation Project of National Key Research and Development Program of China (2021YFE0105700), Guangzhou Science and Technology Project (202007020005), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01X137). This work is also funded by RFBR according to the research project no. 19-52-80003
Предметные рубрики: RANDOM FOREST
CRYSTAL-STRUCTURE
TIN BROMIDE
CLASSIFICATION
Аннотация: The dependence of photoluminescence quantum yield (PLQY) on the crystal structure of existing zero-dimensional ns2 metal halides is analyzed with the help of principal component analysis and random forest methods. The primary role of the distance between metal ions in different compounds is revealed, and the influence of other structural features such as metal-halogen distance and the distortion of metal-halogen polyhedrons are quantified. Accordingly, the two previously unknown Sb3+-based zero-dimensional metal halides were synthesized to verify the obtained model. Experimental studies of the two compounds demonstrated good agreement with the predictions, and the PLQY of (C10H16N)2SbCl5 is found to be 96.5%. Via machine learning analysis, we demonstrate that concentration quenching is the main factor that determines PLQY for all s2 ion metal halides, which will accelerate the discovery of new luminescence metal halides.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Li, Mingze, Li, Yawen, Molokeev M. S., Zhao, Jing, Na, Guangren, Zhang, Lijun, Xia, Zhiguo
Заглавие : Halogen substitution in zero-dimensional mixed metal halides toward photoluminescence modulation and enhanced quantum yield
Место публикации : Adv. Opt. Mater. - 2020. - Vol. 8, Is. 16. - Ст.2000418. - ISSN 2195-1071, DOI 10.1002/adom.202000418
Примечания : Cited References: 34. - M.L., Y.L. contributed equaly to this work. This work was supported by the National Natural Science Foundation of China (51961145101, 51972118, and 51722202), Fundamental Research Funds for the Central Universities (FRFTP-18-002C1), the Guangdong Provincial Science &Technology Project (2018A050506004), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01 x 137). This work was also funded by RFBR according to the research project No. 19-52-80003. The work at Jilin University is supported by the National Natural Science Foundation of China (Grant No. 61722403 and 11674121) and Jilin Province Science and Technology Development Program (Grant No. 20190201016JC). Calculations were performed in part at the high performance computing center of Jilin University.
Предметные рубрики: WHITE-LIGHT EMISSION
PEROVSKITES
EXCITONS
Аннотация: Zero‐dimensional (0D) organic−inorganic hybrid metal halides haveunprecedented degrees of freedom for structural tunability and photoluminescence modulation. Here, the 0D isomorphic hybrid metal mixed halides (C9NH20)9Pb3Zn2Br19(1−x )Cl19x (x = 0–1) with continuous halogen contents control, exhibiting tunable emission and enhancement of photoluminescence quantum yield (PLQY) are reported. The competitive bromine to chlorine substitution process in (C9NH20)9Pb3Zn2Br19(1−x )Cl19x occurs first in [ZnBr4−x Clx ]2− tetrahedron before the [Pb3Br11−x Clx ]5− trimer. The increasing Cl content in samples from x = 0 to 1 results in an expected blue shift of emission peak from 565 to 516 nm, and meanwhile a strikingly room temperature PL quantum yield increase from 8% to 91%. Combined experimental characterizations and theoretical calculations indicate that the blue shift of interband transition energy is responsible for the emission peak shift. Moreover, with the increasing Cl content, the enhanced electron−phonon interaction and the weakened thermal‐assisted nonradiative recombination result in more efficient radiative transition channels and ultimately enhanced PLQY. The impact of halogen substitution on electronic structures and optical properties in 0D hybrid metal halides is emphasized in this work as a new strategy to promote the future development of new luminescent materials.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhou, Jun, Li, Mingze, Molokeev M. S., Sun, Jiayue, Xu, Denghui, Xia, Zhiguo
Заглавие : Tunable photoluminescence in Sb3+-doped zero-dimensional hybrid metal halides with intrinsic and extrinsic self-trapped excitons
Место публикации : J. Mater. Chem. C. - 2020. - Vol. 8, Is. 15. - P.5058-5063. - ISSN 2050-7526, DOI 10.1039/d0tc00391c. - ISSN 2050-7534(eISSN)
Примечания : Cited References: 33. - This work is supported by the National Natural Science Foundation of China (No. 51722202, 51961145101, 51972118, 21576002 and 61705003), Fundamental Research Funds for the Central Universities (D2190980), the Guangdong Provincial Science & Technology Project (2018A050506004), and Beijing Technology and Business University Research Team Construction Project (No. PXM2019_014213_000007). This work was also funded by RFBR according to the Research Project No. 19-52-80003.
Предметные рубрики: WHITE-LIGHT EMISSION
LUMINESCENCE
PEROVSKITES
CS2NASCCL6
CS2NAYCL6
Аннотация: Dopants in luminescent metal halides provide an alternative way for photoluminescence tuning towards versatile optical applications. Here we report a trivalent antimony (Sb3+)-doped single crystalline 0D metal halide with the composition of (C9NH20)9[Pb3Cl11](ZnCl4)2:Sb3+. This compound possessed the coexistence of two emission centers including intrinsic and extrinsic self-trapped excitons (STEs), which are ascribed to [Pb3Cl11]5− clusters and triplet STEs formed by the 3P1–1S0 transition of Sb3+. By regulating the Sb3+ concentration, the emission can be tuned from green to yellow and finally to orange, which would help to develop optically pumped white light-emitting diodes (WLEDs) with different photometric characteristics. Moreover, this dopant-induced extrinsic STE approach presents a new direction towards tuning the luminescence properties of 0D metal halides, and may find application in environmentally-friendly, high-performance metal halide light emitters.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Li, Mingze, Molokeev M. S., Zhao, Jing, Xia, Zhiguo
Заглавие : Optical functional units in zero-dimensional metal halides as a paradigm of tunable photoluminescence and multicomponent chromophores
Место публикации : Adv. Opt. Mater. - 2020. - Vol. 8, Is. 8. - Ст.1902114. - ISSN 2195-1071, DOI 10.1002/adom.201902114
Примечания : Cited References: 38. - This work was supported by the National Natural Science Foundation of China (Nos. 51961145101, 51722202, and 51972118), Fundamental Research Funds for the Central Universities (D2190980), the Guangdong Provincial Science & Technology Project (2018A050506004), and this work was also funded by RFBR according to the Research Project No. 19-52-80003
Предметные рубрики: PEROVSKITES
LUMINESCENCE
ABSORPTION
EMISSION
Аннотация: Zero-dimensional (0D) organic–inorganic hybrid luminescent metal halides have many promising optoelectronic applications; however, the single building unit in the 0D framework restricts their multimode optical control and photoluminescence tuning. Thus, it remains urgent but challenging to rationally design distinct anionic polyhedral with different optical functions and further expand this family by an equivalent cation substitution and halogen replacement. Herein, (C9NH20)9[Pb3X11](MX4)2 (X = Br and Cl, M = Mn, Fe, Co, Ni, Cu, and Zn) is successfully synthesized verifying the rationality of the design philosophy, and the optical characterizations demonstrate the effects of X‐position anions and M‐position cations on luminescence process. Intriguingly, both [Pb3X11]5− and [MX4]2− perform as inorganic building units in this 0D system and optically active centers, in which the former leads to high‐efficiency broad‐band yellow/green emission originating from self‐trapped excitons and the as‐observed multicomponent chromophores are derived from the absorption of the latter in the visible light region. The present work highlights the importance of different optical functional units showing synergistic effects on the physical properties and inspires future studies to explore multifunctional application of 0D luminescent metal halides.
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Su B., Song G., Molokeev M. S., Lin Z., Xia Z.
Заглавие : Synthesis, crystal structure and green luminescence in zero-dimensional tin halide (C8H14N2)2SnBr6
Место публикации : Inorg. Chem. - 2020. - Vol. 59, Is. 14. - P.9962–9968. - ISSN 00201669 (ISSN), DOI 10.1021/acs.inorgchem.0c01103
Примечания : Cited References: 33. - This work is supported by the National Natural Science Foundation of China (51961145101, 51722202, and 51972118), Fundamental Research Funds for the Central Universities (D2190980), Guangzhou Science & Technology Project (202007020005), and the Guangdong Provincial Science & Technology Project (No. 2018A050506004), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01X137). This work is also funded by RFBR according to Research Project No. 19-52-80003
Аннотация: Organic-inorganic hybrid metal halides with broad-band emission are currently receiving an increasing interest for their unique light emission properties. Here we report a novel lead-free zero-dimensional (0D) tin halide, (C8H14N2)2SnBr6, in which isolated [SnBr6]4- octahedrons are cocrystallized with organic cations, 1,3-bis(aminomethyl)benzene (C8H14N22+). Upon photoexcitation, the bulk crystals exhibit broad-band green emission peaking at 507 nm with a full width at half-maximum (fwhm) of 82 nm (0.395 eV), a Stokes shift of 157 nm (1.09 eV), and a photoluminescence quantum yield (PLQY) of 36 ± 4%. Combined structural analysis and density functional theory (DFT) calculations indicate that the excited state structural distortion of [SnBr6]4- octahedral units account for the formation of this green emission. The relatively small Stokes shift and narrow fwhm of the emission are hence caused by the reduced distortion of [SnBr6]4- octahedrons and rigid molecular structure. The discovery of lead-free (C8H14N2)2SnBr6 and insight into the mechanism of green emission provide an essential platform toward unveiling the relationship between structure and property for 0D metal halide perovskites.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Serebrennikov D. A., Bykov A. A., Trigub A. L., Kolyshkin N. A., Freydman A. L., Aborkin A. V., Tovpinets A. O., Clementyev E. S., Goikhman A. Y.
Заглавие : Near zero thermal expansion in metal matrix composites based on intermediate valence systems: Al/SmB6
Место публикации : Results Phys. - 2021. - Vol. 21. - Ст.103843. - ISSN 22113797 (ISSN), DOI 10.1016/j.rinp.2021.103843
Примечания : Cited References: 45. - This work was supported by the Russian Foundation for Basic Research , grant 18-32-00583 mol_a and by the State assignment of Russia , project FZWM-2020-0008. We are grateful to V.N. Leitsin for his support in the experimental studies
Аннотация: This work is focused on the fabrication and characterization of a new type of composite invar materials combining near-zero thermal expansion and functional properties that are important for applications. This is accomplished through the use of particles of SmB6, an intermediate valence system with negative thermal expansion, embedded in Al matrix. The composite based on SmB6-21 vol% was fabricated by hot pressing and was characterized by XRD, optical/electron microscopy, X-ray computed tomography and capacitive dilatometry. The study of thermal expansion revealed that the sample exhibits invar behaviour up to ~60 K with a zero value of the coefficient of thermal expansion near 45 K. In comparison to pure aluminum, the temperature range has increased by about 20 K. A quantitative analysis of dilatometric experimental data performed on the basis of widely used theoretical models showed that the thermal expansion of the Al/SmB6 composite was well reproduced within the Turner model.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liu, Youquan, Mei, Dajiang, Wang, Naizheng, Molokeev M. S., Jiang, Xingxing, Lin, Zheshuai
Заглавие : Intrinsic isotropic near-zero thermal expansion in Zn4B6O12X (X = O, S, Se)
Место публикации : ACS Appl. Mater. Interfaces. - 2020. - Vol. 12, Is. 34. - P.38435-38440. - ISSN 1944-8244, DOI 10.1021/acsami.0c12351. - ISSN 1944-8252(eISSN)
Примечания : Cited References: 43. - This work was supported by the National Scientific Foundations of China (Grants 51872297, 51702330, 11974360, 51972208, 51890864, and 51802321), Russian Foundation for Basic Research (Grant 17-52-53031), and Fujian Institute of Innovation (FJCXY18010201) in CAS. X.J. acknowledges the support from the Youth Innovation Promotion Association in CAS (Grant 2017035) and Youth Talent Promotion Project from China Association for Science and Technology
Предметные рубрики: CRYSTAL
Аннотация: Zero thermal expansion (ZTE) materials, keeping size constant as temperature varies, are valuable for resisting the deterioration of the performance from environmental temperature fluctuation, but they are rarely discovered due to the counterintuitive temperature-size effect. Herein, we demonstrate that a family of borates with sodalite cage structure, Zn4B6O12X (X = O, S, Se), exhibits intrinsic isotropic near-ZTE behaviors from 5 to 300 K. The very low thermal expansion is mainly owing to the coupling rotation of [BO4] rigid groups constrained by the bonds between Zn and cage-edged O atoms, while the central atoms in the cage have a negligible contribution. Our study has significant implications on the understanding of the ZTE mechanism and exploration of new ZTE materials.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhou, Guojun, Liu, Zhiyang, Huang, Jinglong, Molokeev M. S., Xiao, Zewen, Ma, Chonggeng, Xia, Zhiguo
Заглавие : Unraveling the near-unity narrow-band green emission in zero-dimensional Mn2+-based metal halides: a case study of (C10H16N)2Zn1–xMnxBr4 solid solutions
Место публикации : J. Phys. Chem. Lett. - 2020. - Vol. 11, Is. 15. - P.5956-5962. - ISSN 1948-7185, DOI 10.1021/acs.jpclett.0c01933
Примечания : Cited References: 32. - This work was supported by the National Natural Science Foundations of China (Grant No. 51972118, 51961145101, and 51722202), Fundamental Research Funds for the Central Universities (D2190980), Guangzhou Science & Technology Project (202007020005), the Guangdong Provincial Science & Technology Project (No. 2018A050506004), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (2017BT01X137). This work is also funded by RFBR according to the research project No. 19-5280003. C. Ma acknowledges the support from the Innovation and Entrepreneurship Programs for Returned Overseas Chinese Scholars offered by Chongqing Bureau of Human Resources and Social Security (CX2019055). Z. Xiao acknowledges the financial support from the Thousand Young Talents Program of China, the Startup Fund of Huazhong University of Science and Technology, and the Director Fund of Wuhan National Laboratory for Optoelectronics
Предметные рубрики: Organic-inorganic hybrid
Light emission
White
Br
Аннотация: Zero-dimensional (0D) Mn2+-based metal halides are potential candidates as narrow-band green emitters, and thus it is critical to provide a structural understanding of the photophysical process. Herein, we propose that a sufficiently long Mn–Mn distance in 0D metal halides enables all Mn2+ centers to emit spontaneously, thereby leading to near-unity photoluminescence quantum yield. Taking lead-free (C10H16N)2Zn1–xMnxBr4 (x = 0–1) solid solution as an example, the Zn/Mn alloying inhibits the concentration quenching that is caused by the energy transfer of Mn2+. (C10H16N)2MnBr4 exhibits highly thermal stable luminescence even up to 150 °C with a narrow-band green emission at 518 nm and a full width at half maximum of 46 nm. The fabricated white light-emitting diode device shows a high luminous efficacy of 120 lm/W and a wide color gamut of 104% National Television System Committee standard, suggesting its potential for liquid crystal displays backlighting. These results provide a guidance for designing new narrow-band green emitters in Mn2+-based metal halides.
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15.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Ignatchenko V.A., Polukhin D.S.
Заглавие : Magnetoelastic resonance in zero-mean magnetostrictive media
Коллективы : Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium, Уральское отделение РАН
Место публикации : IV Euro-Asian Symposium "Trends in MAGnetism" Nanospintronics (EASTMAG-2010). School for young scientist "Spintronics": June 28 - Lule 2, 2010"Book of abstracts. - Ekaterinburg, 2010. - P.331
РИНЦ
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Liu, Qin, Dang, Peipei, Zhang, Guodong, Molokeev M. S., Polyutov, Sergey, Lian, Hongzhou, Cheng, Ziyong, Li, Guogang, Lin, Jun
Заглавие : Achieving excellent thermostable red emission in singly Mn2+-doped near zero thermal expansion (NZTE) material Li2Zn3(P2O7)2
Колич.характеристики :10 с
Место публикации : J. Mater. Chem. C. - 2023. - Vol. 11, Is. 31. - P.10684-10693. - ISSN 20507526 (ISSN), DOI 10.1039/D3TC01683H. - ISSN 20507534 (eISSN)
Примечания : Cited References: 62. - This work wasfinancially supported by the National Science and Technology Major Project (2022YFB3503800), the Projects for Science and Technology Development Plan of Jilin Province (20210402046GH), the National Natural Science Foundation of China (NSFC No. 51932009, 51929201, 52072349, 52172166), the Natural Science Foundation of Zhejiang Province (LR22E020004), the Project funded by China Postdoctoral Science Foundation (2022TQ0365), and the Ministry of Science and High Education of Russian Federation (Project No. FSRZ2023-0006), M.S. Molokeev and S.P. Polyutov acknowledge the support by the Ministry of Science and High Education of Russian Federation (Project No. FSRZ-2023-0006)
Аннотация: The design of thermostable phosphor is still a pivotal challenge in pc-WLED applications. Herein, an efficient strategy is proposed to design excellent thermostable red emission in singly Mn2+-doped near zero thermal expansion (NZTE) material Li2Zn3(P2O7)2. Under the excitation of 412 nm wavelength, the emission could be tuned from 636 to 672 nm by increasing the Mn2+ doping level via synthetic effect among crystal field, the exchange coupling interaction in Mn-Mn dimers and energy transfer in different luminescence centers. The PL intensity of LZPO:Mn2+ maintains 97% at 150 °C and 94% at 200 °C of initial intensity at the room temperature. During the heat process, the LZPO presents near zero thermal expansion, which contributes to the nearly unaffected PL intensity. The traps assist energy transfer to luminescent center is also compensated for the emission loss. This work not only offers a perspective idea for elucidating the correlation between crystal structure and optical properties, but also opens a new way in line with that of designing excellent thermostable luminescent materials based on NZTE materials in self-reduction system.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shustin M. S., Aksenov S. V.
Заглавие : Effect of strong intersite Coulomb interaction on the topological properties of a superconducting nanowire
Место публикации : Phys. Solid State. - 2022. - Vol. 64, Is. 13. - P.2047-2053. - ISSN 10637834 (ISSN), DOI 10.21883/PSS.2022.13.53972.23s. - ISSN 10906460 (eISSN)
Примечания : Cited References: 55. - This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory and the Krasnoyarsk Regional Fund of Science, projects nos. 20-42-243001 and 20-42-243005. M.S.S. thanks the Foundation for the Advancement of Theoretical Physics and Mathematics ”BASIS“. S.V.A. is grateful to the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools, project No. MK-1641.2020.2
Аннотация: For superconducting nanowire with the pairing of extended s-type symmetry, Rashba spin-orbit interaction in a magnetic field, the influence of strong intersite charge correlations on single-particle Majorana excitations is analyzed. This problem is investigated on the basis of the density matrix renormalization group numerical method. It is shown that with an increase in the repulsion intensity of electrons located at the neighboring sites, two subbands emerge in the lower Hubbard band of the open system. Based on calculations of the Majorana polarization and degeneracy of the entanglement spectrum, it was found that a topologically nontrivial phase with one edge state survives at the edge of each of the subbands where the concentration of electrons or holes is minimal.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev, Nicolay N., Gerasimova, Marina A., Ostapenko, Ivan A., Zolotov, Andrey O., Molokeev M. S.
Заглавие : Two organic-inorganic manganese(II) halide hybrids containing protonated N,N’-dialkylthioureas with efficient green-emission
Место публикации : J. Mol. Struct. - 2023. - Vol. 1277. - Ст.134851. - ISSN 0022-2860 (ISSN), DOI 10.1016/j.molstruc.2022.134851
Примечания : Cited References: 42. - The reported study was funded by RFBR according to the research project № 19-52-80003. X-ray data from single crystals and powders were obtained with the analytical equipment of Krasnoyarsk Center of collective use of SB RAS
Аннотация: Luminescent (C5H13N2S)2[MnBr4] (1) and (C7H17N2S)2[MnBr4] (2) (C5H12N2S = N,N′-diethylthiourea, C7H16N2S = N,N′-diisopropylthiourea) were prepared via solvothermal method, and the structures of these compounds have been resolved using X-ray single crystal diffraction. The structures consist of electrostatically bound MnBr42− anions and organic C5H13N2S+ and C7H17N2S+ cations. The intermolecular N−H···Br and N−H···S hydrogen bonds additionally stabilize crystal structures of 1-2. Upon excitation over broadband covering the range 265 to 515 nm, these compounds show green emission peaking at 526 nm for 1 and 522 nm for 2, which is assigned to the 4T1→ 6A1 electronic transition of Mn2+ from isolated within the crystal structures MnBr42− tetrahedra. The photoluminescence quantum yield (PLQY) of powder 1 is 97 ± 7% for excitation at 440 nm and that of powder 2 is 83 ± 7% for excitation at 365 nm. The high PLQY indicates the absence of noticeable concentration quenching at shortest Mn···Mn distance of 8.11 and 8.73 Å between Mn2+ ions within the structures of 1 and 2. The high-performance photoluminescence of 0D (C5H13N2S)2[MnBr4] and (C7H17N2S)2[MnBr4] compounds demonstrated promising applications in photonics.
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19.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Popov M. A., Bolsunovskaya O. A., Petrakovskii G. A.
Заглавие : Peculiapities of properties of cooper metaborate in a zero magnetic field
Коллективы : Российская академия наук, Научный совет по физике конденсированных сред РАН, Научный совет РАН по физике низких температур, Сибирское отделение РАН, Красноярский научный центр Сибирского отделения РАН, Институт физики им. Л.В. Киренского Сибирского отделения РАН, Красноярский государственный университет, Красноярский государственный технический университет, Институт физики металлов Уральского отделения РАН, Euro-asian symposium "Trends in magnetism", "Trends in magnetism", Euro-Asian Symposium
Место публикации : EASTMAG-2004: abstract book/ org. com. K. S. Aleksandrov [et al.]. - Krasnoyarsk, 2004. - Sect.: Fundamental magnetic properties. - P.48
Примечания : Cited References: 1
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chen K., Gao P., Zhang Z., Ma Y., Luo Z., Molokeev M. S., Zhou Zh., Xia M.
Заглавие : Zero-thermal-quenching broadband yellow-emitting Bi3+-activated phosphors based on metal to metal charge transfer
Колич.характеристики :9 с
Место публикации : J. Alloys Compd. - 2024. - Vol. 986. - Ст.174112. - ISSN 09258388 (ISSN), DOI 10.1016/j.jallcom.2024.174112. - ISSN 18734669 (eISSN)
Примечания : Cited References: 52. - The authors would like to gratefully acknowledge funds from the National Natural Science Foundation of China (Grant No. 51974123), the Key R & D Projects in Hunan Province (2021SK2047 and 2022NK2044), the Wangcheng Science and Technology Plan (KJ221017) and the Science and Technology Innovation Program of Hunan Province (2022WZ1022). The work was supported by the Ministry of Science and Higher Education of the Russian Federation as part of World-class Research Center program: "Advanced Digital Technologies", contract no. 075-15-2020-935. Superior Youth Project of the Science Research Project of Hunan Provincial Department of Education (22B0211)
Аннотация: Bi3+-activated phosphors have been proven to have potential applications foreground in white light-emitting diodes (WLED), plant growth lamps and temperature sensing. Therefore, it is urgent to exploit high-efficiency Bi3+-activated phosphors. Herein, a novel broadband yellow-emitting phosphor Ba2GdGaO5:Bi3+ with high internal quantum efficiency (IQE = 77%) was obtained based on metal to metal charge transfer (MMCT) between Bi3+ ground state and Gd3+ excited states. The photoluminescence excitation (PLE) spectrum and photoluminescence (PL) spectrum range from 225 nm to 400 nm and 400 nm to 700 nm, respectively, which can avoid the reabsorption phenomenon efficiently. Besides, Ba2GdGaO5:Bi3+ has superior thermal stability and it shows zero-thermal-quenching at 150 °C. The K+ doping hardly changes the thermal stability and can improve the PL intensity to 133.1% when the K+ concentration is 2%. Finally, a phosphor-convert WLED (pc-WLED) was simply synthesized by Ba2GdGaO5:Bi3+ and BaMgAl10O17:Eu2+ (BAM:Eu2+) phosphors. The doping of Eu3+ can significantly enhance the color rendering index (CRI, from 88.1 to 91.5) and reduce the correlated color temperature (CCT, from 4911 K to 4014 K). The above experimental results demonstrated that the phosphor has great application prospect in WLED.
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