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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Altunin R. R., Moiseenko E. T., Zharkov S. M.
Заглавие : Effect of the structural properties on the electrical resistivity of the Al/Ag thin films during the solid-state reaction
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [18-13-00080]
Место публикации : Phys. Solid State. - 2020. - Vol. 62, Is. 4. - P.708-713. - ISSN 1063-7834, DOI 10.1134/S1063783420040034. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 43. - This study was supported by the Russian Science Foundation, project no. 18-13-00080.
Предметные рубрики: LIGHT-EMITTING-DIODES
PHASE-FORMATION
AG
AL
DIFFUSION
SUPPRESSION
INTERFACE
SURFACE
GROWTH
HEAT
Аннотация: Based on the results of in situ electron diffraction study of the solid-state reaction and electrical resistivity measurements on the Al/Ag thin films with an atomic ratio of Al : Ag = 1 : 3, the temperature of the reaction onset has been established and a model of the structural phase transitions has been proposed. The solid-state reaction begins at 70°C with the formation of the Al–Ag solid solution at the interface between the aluminum and silver nanolayers. It has been found that, in the course of the reaction, the intermetallic compounds γ-Ag2Al → μ-Ag3Al are successively formed. It is shown that the possibility of the formation of the μ‑Ag3Al phase during the solid-state reaction in the Al/Ag thin films depends on the aluminum-to-silver ratio, while the formation of the μ-Ag3Al phase begins only after all fcc aluminum has reacted.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Sadreev A. F.
Заглавие : Ab-initio investigation of thermoactivated directional transport of hydrogen molecules inside narrow carbon nanotubes
Место публикации : Phys. Status Solidi B. - 2009. - Vol. 246: 23rd Winterschool on Electronic Properties of Novel Materials (MAR 14, 2009, Kirchberg, GERMANY), Is. 11. - P.2598-2601. - ISSN 0370-1972, DOI 10.1002/pssb.200982285
Примечания : Cited References: 21. - A.S.Fedorov thanks the Institute of Computer Modeling (Krasnoyarsk, Russia) and the Joint Supercomputer Center (Moscow) for an assistence in quantum chemical calculations.
Предметные рубрики: DIFFUSION
ENERGY
Аннотация: Using the pseudopotential DFT and the empirical potential methods we calculate the potential acting to the hydrogen molecules in narrow single-wall carbon nanotubes (SWCNT) (6,0),(7,0) and (3,3). The potential forms a goffered potential surface and can be approximated as V(z, r, phi) approximate to V(0) sin(2 pi z/a) + V(r). We show that in these SWCNTs transport of molecules is given mainly by thermoactivated hoppings between minima of the periodic potential along the tube axis. Taking into account that hydrogen density distribution inside nanotube is stationary and assuming the temperature is changed linearly along the SWCNT length we show that the H(2) density is sufficiently variated, especially for the case of (6,0)SWCNT where the density on both SWCNT ends are different at similar to 30 times when the temperature is changed along the SWCNT from 300K to 1200K. Suppose that H2 molecules can penetrate in the both open SWCNT ends, the molecules would move in the direction of the temperature decreasing. This effect may be used potentially to build up a molecular pump driven by the temperature gradient along narrow nanotube. (C) 2009 WILEY-VCH Verlag GmbH & Co. KGaA, Weinheim
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Fedorov A. S., Sadreev A. F.
Заглавие : Thermoactivated transport of molecules H-2 in narrow single-wall carbon nanotubes
Коллективы : RFBR [0602-16132]
Разночтения заглавия :авие SCOPUS: Thermoactivated transport of molecules H 2 in narrow single-wall carbon nanotubes
Место публикации : Eur. Phys. J. B: SPRINGER, 2009. - Vol. 69, Is. 3. - P363-368. - ISSN 1434-6028, DOI 10.1140/epjb/e2009-00152-1
Примечания : Cited References: 40. - We are grateful to S. G. Ovchinnikov for discussions. This work has been supported by RFBR grant 0602-16132.
Предметные рубрики: DIFFUSION
NANOPORES
ENERGY
MOTION
FLUIDS
Ключевые слова (''Своб.индексиров.''): hydrogen molecule--inner potential--lennard-jones potential--periodic potentials--plane wave--potential surfaces--single-wall carbon nanotubes--thermal fluctuations--tube walls--carbon nanotubes--hydrogen--molecules--single-walled carbon nanotubes (swcn)
Аннотация: By use both of the plane wave DFT and the empirical exp-6 Lennard-Jones potential methods we calculate the inner potential in narrow single-wall carbon nanotubes (SWCNT) (6, 0), (7, 0) and (3, 3) which affects the hydrogen molecules. The inner potential forms a goffered potential surface and can be approximated as V(z,r,phi)a parts per thousand V(0)sin (2 pi z/a)+V(r). We show that in these SWCNTs transport of molecules is given mainly by thermoactivated hoppings between minima of the periodic potential along the tube axis. The rate hoppings is substantially depends on temperature because of thermal fluctuations of tube wall.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Zhigalov V. S., Matsynin A. A., Bykova L. E., Mikhlin Y. L., Bondarenko G. N., Patrin G. S., Yurkin G. Yu.
Заглавие : Formation of ferromagnetic germanides by solid-state reactions in 20Ge/80Mn films
Место публикации : Thin Solid Films: Elsevier Science, 2014. - Vol. 552. - P.86-91. - ISSN 0040-6090, DOI 10.1016/j.tsf.2013.12.029
Примечания : Cited References: 53
Предметные рубрики: PHASE-FORMATION
MAGNETIC-PROPERTIES
Mn5Ge3 FILMS
X-RAY
Ge(111)
TRANSFORMATIONS
DIFFUSION
SPECTRA
SYSTEM
LAYERS
Ключевые слова (''Своб.индексиров.''): manganite-germanium--solid state reaction--first phase--mn5ge3 alloy--carbon impurity--oxygen impurity--annealing--magnetic anisotropy
Аннотация: Solid state reactions between Ge and Mn films are systematically examined using X-ray diffraction, photoelectron spectroscopy, and magnetic and electrical measurements. The films have a nominal atomic ratio Ge:Mn = 20:80 and are investigated at temperatures from 50 to 500 °C. It is established that after annealing at ~ 120°C, the ferromagnetic Mn5Ge3 phase is the first phase to form at the 20Ge/80Mn interface. As the annealing temperature increases to 300°C, the weak magnetic Mn5Ge 2 + Mn3Ge phases simultaneously begin to grow and they become dominant at 400°C. Increasing the annealing temperature to 500°C leads to the formation of the ferromagnetic phase with a Curie temperature TC ~ 350-360 K and magnetization 14-25 kA/m at room temperature. The X-ray diffraction study of the samples shows the reflections from the Mn 5Ge3 phase, and the photoelectron spectra contain the oxygen and carbon peaks. The homogeneous distribution of oxygen and carbon over the sample thickness suggests that the increased Curie temperature and magnetization are related to the migration of C and O atoms into the Mn 5Ge3 lattice and the formation of the Nowotny phase Mn5Ge3CxOy. The initiation temperature (~ 120 C) is the same in the Mn5Ge3 phase with the solid-state reactions in the Ge/Mn films as well as in the phase separation in the GexMn1 - x diluted semiconductors. Thus, we conclude that the synthesis of the Mn5Ge3 phase is the moving force for the spinodal decomposition of the GexMn 1 - x diluted semiconductors.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Mikhlin Y. N., Bykova L. E., Mal'tsev V. K., Bondarenko G. N.
Заглавие : Long-Range Chemical Interaction in Solid-State Synthesis: The Formation of a CuAu Alloy in Au/beta-Co(001)/Cu(001) Epitaxial Film Structures
Коллективы : Russian Foundation for Basic Research [07-03-00190]; Ministry of Education and Science of the Russian Federation
Разночтения заглавия :авие SCOPUS: Long-range chemical interaction in solid-state synthesis: The formation of a CuAu alloy in Au/β-Co(001)/Cu(001) epitaxial film structures
Место публикации : JETP Letters. - 2009. - Vol. 90, Is. 2. - P.111-115. - ISSN 0021-3640, DOI 10.1134/S0021364009140069
Примечания : Cited References: 25. - This work was supported by Russian Foundation for Basic Research ( project no. 07-03-00190) and the Ministry of Education and Science of the Russian Federation ( program "Development of the Scientific Potential of Higher Education").
Предметные рубрики: THIN-FILMS
PHASE-TRANSITION
DIFFUSION
MICROSTRUCTURE
INTERLAYER
INTERFACE
COSI2
AU
Аннотация: The effect of an inert Co layer (0, 210, 480 nm) on the chemical interaction between Cu and Au in Au/beta-Co(001)/Cu(001) epitaxial films has been investigated by X-ray diffraction, nuclear magnetic resonance, photoelectron spectroscopy, and magnetic structure measurements. Mixing at interfaces in Cu/beta-Co(001) and Au/beta-Co(001) bilayer films has not been revealed up to a temperature of 600 C. The solid-state synthesis of ordered CuAu| and CuAu|| phases occurs through the Co inert buffer layer in Au/beta-Co(001)/Cu(001) trilayer film systems with an increase in the annealing temperature. The initiation temperatures of the CuAu| and CuAu|| phases increase only slightly with the thickness of the Co buffer layer. The assumption of the long range of the chemical interaction between Cu and Au through the chemically inert Co layer is justified using the performed investigations.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Bykova L. E., Bondarenko G. N., Bondarenko G. V.
Заглавие : Long-range chemical interaction in solid-state synthesis: The Kirkendall effect and solid-state reactions in Cu/beta-CuZn and Cu/Fe/beta-CuZn film systems
Коллективы :
Разночтения заглавия :авие SCOPUS: Long-range chemical interaction in solid-state synthesis: The Kirkendall effect and solid-state reactions in Cu/β-CuZn and Cu/Fe/β-CuZn film systems
Место публикации : JETP Letters. - 2010. - Vol. 91, Is. 12. - P.665-669. - ISSN 0021-3640, DOI 10.1134/S0021364010120106
Примечания : Cited References: 26. - We are grateful to Yu. L. Mikhlin for the measurements of the X-ray photoelectron spectra and for stimulating discussions. This work was supported by the Ministry of Education and Science of the Russian Federation (project no. 2.1.1/4399, program "Development of the Scientific Potential of Higher Education in 2009-2010").
Предметные рубрики: PHASE-FORMATION
DIFFUSION
Аннотация: The results of the experimental investigations of the solid-state reaction of Cu with beta brass, which is associated with the Kirkendall, in Cu/beta-CuZn and Cu/Fe/beta-CuZn film systems are reported. It has been shown that the initiation temperature of the solid-state synthesis of alpha brass at the Cu/beta-CuZn interface is about 200A degrees C. The chemically inert Fe barrier layers 420 and 850 nm in thickness between the Cu and beta-CuZn films do not suppress the solid-state synthesis of the alpha brass, but increase the initiation temperature to about 250A degrees C. This behavior indicates that the chemical interaction between the Cu and Zn atoms through the chemically inert Fe layer is long-range. The X-ray photoelectron investigations reveal the migration of Zn atoms from the beta-CuZn layer through the Fe barrier to the Cu layer. The results are interpreted under the assumption that the migration of Zn atoms in the Kirkendall is initiated by the strong chemical interaction between the Cu and Zn atoms in the Cu and beta-CuZn layers, which is due to the synthesis of alpha brass, rather than by the diffusion random walk, as is commonly accepted at present.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zobov V. E., Ivanov Y. N., Popov M. A., Livshits A. I.
Заглавие : Orientational dependence of the tails of dipole-broadened NMR spectra in crystals
Место публикации : J. Exp. Theor. Phys.: AMER INST PHYSICS, 1999. - Vol. 88, Is. 1. - P157-167. - ISSN 1063-7761, DOI 10.1134/1.558778
Примечания : Cited References: 36
Предметные рубрики: NUCLEAR-DOUBLE-RESONANCE
FLUCTUATION SPECTRUM
CROSS-RELAXATION
SOLIDS
DIFFUSION
MEMORY
SHAPE
Аннотация: This paper describes experimental and theoretical studies of the tails of the dipole-broadened nuclear magnetic resonance (NMR) absorption spectra of F-19 in isomorphic single crystals of BaF2 and CaF2 with the magnetic field directed along three crystallographic axes. The results obtained by directly measuring the derivative of the tail of the NMR absorption spectrum and the falloffs of the Engelsberg-Lowe free precession after Fourier transformation qualitatively agree. It is shown that the shape of the tail is well described by an exponential function in which the orientational dependence of the exponent does not reduce to variation of the second moment. The observed shape of the tail and the orientational dependence of its parameters are explained on the basis of a self-consistent fluctuating-local-field theory. Nonlinear integral equations are derived for the correlation functions, taking into account the changes of the actual number of nearest neighbors caused by the anisotropy of the dipole-dipole interaction and the contribution of lattice sums with loops. The equations are solved numerically. Good agreement is obtained for the computed dropoffs of the free precession, the NMR spectra, and the cross-polarization rates with the experimental results. (C) 1999 American Institute of Physics. [S1063-7761(99)02401-4].
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