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1.
Low-temperature magnetic behavior
of the rare-earth cobaltites GdCoO3 and SmCoO3 / N. B. Ivanova [et al.]> // Phys. Solid State. - 2007. -
Vol. 49
,
Is. 11
. - P. 2126-2131,
DOI
10.1134/S1063783407110182. - Cited References: 32. - This study was supported by the Branch of General Physics and Astronomy of the Russian Academy of Sciences within the framework of the program “Strong Electron Correlations” and the Russian Science Support Foundation . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
METAL-INSULATOR-TRANSITION
RCOO3 R
SPIN-STATE
OXIDE
SM
ND
PEROVSKITE
GLASSES
PR
EU
Аннотация:
The temperature and magnetic field dependences of the static magnetization of the polycrystalline rare-earth cobaltites GdCoO3 and SmCoO3 have been measured. It is shown that, below room temperature, the magnetization of both compounds derives primarily from the rare-earth ion paramagnetism. The GdCoO3 and SmCoO3 compounds have been found to differ substantially in magnetic behavior, which can be traced to differences in their electronic shell structures. The magnetic behavior of GdCoO3 is close to that of an array of free Gd3+ ions, whereas in SmCoO3 the deviation from the free-ion properties is very large because of the Sm3+ ground state being crystal-field split. Van Vleck magnetic susceptibility measurements of SmCoO3 suggest that the splitting is similar to 10 K.
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Публикация на русском языке
Сравнение одноэлектронного и многоэлектронного механизмов концентрационной зависимости зонной структуры ВТСП-купратов [Текст] / В. А. Гавричков [и др.] // Физ. тверд. тела. - 2007. - Т. 49 Вып. 11. - С. 1958-1963
Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Univ Guadalajara, Dept Fis, CUCEI, Guadalajara 44430, Jalisco, Mexico
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation
Departamento de Fisica, C.U.C.E.I., Universidad de Guadalajara, Guadalajara, Jalisco 44430, Mexico
Доп.точки доступа:
Ivanova, N. B.; Иванова, Наталья Борисовна; Kazak, N. V.; Казак, Наталья Валерьевна; Michel, C. R.; Balaev, A. D.; Балаев, Александр Дмитриевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
}
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2.
Effect of strontium
and barium doping on the magnetic state and electrical conductivity of GdCoO3 / N. B. Ivanova [et al.]> // Phys. Solid State. - 2007. -
Vol. 49
,
Is. 8
. - P. 1498-1506,
DOI
10.1134/S1063783407080161. - Cited References: 36 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
PEROVSKITE
ORDER
OXIDE
BEHAVIOR
GLASSES
LACOO3
PR
GD
SM
ND
Аннотация:
A coordinated investigation of the magnetic and electrical properties of polycrystalline cobalt oxide compounds CdCoO3, Gd0.9Ba0.1CoO3, and Gd0.9Sr0.1CoO3 is carried out. Undoped GdCoO3 reveals a low conductivity; a magnetic moment of 7.4 mu(B) per molecule, which is less than the theoretical value for the Gd3+ ion; and an asymptotic Curie temperature of -6 K. Doping GdCoO3 with barium and strontium to substitution of 10 at. % Gd brings about an increase in the conductivity and magnetic transitions at T = 300 K for Gd0.9Ba0.1CoO3 and T = 170 K for Gd0.9Sr0.1CoO3. The magnetization anomalies imply the formation of magnetic clusters. The behavior of the electrical conductivity at high temperatures suggests a variable activation energy. At low temperatures, Mott hopping conduction sets in.
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Влияние допирования стронцием и барием на магнитное состояние и электропроводность GdCoO[3] [Текст] / Н. Б. Иванова [и др.] // Физ. тверд. тела. - 2007. - Т. 49 Вып. 8. - С. 1427-1435
Держатели документа:
Russian Acad Sci, Siberian Div, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Univ Guadalajara, CUCEI, Dept Fis, Guadalajara 44430, Jalisco, Mexico
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation
Departmento de Fisica, C.U.C.E.I., Universidade de Guadalajara, Guadalajara, Jalisco 44430, Mexico
Доп.точки доступа:
Ivanova, N. B.; Иванова, Наталья Борисовна; Kazak, N. V.; Казак, Наталья Валерьевна; Michel, C. R.; Balaev, A. D.; Балаев, Александр Дмитриевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Vasil'ev, A. D.; Васильев, Александр Дмитриевич; Bulina, N. V.; Булина, Наталья Васильевна; Panchenko, E. B.
}
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3.
Polarized absorption spectra
and spectroscopic parameters of Tm3+ in the TmAl3(BO3)(4) single crystal / A. V. Malakhovskii [et al.]> // Phys. Solid State. - 2008. -
Vol. 50
,
Is. 7
. - P. 1287-1293,
DOI
10.1134/S1063783408070159. - Cited References: 36 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
RARE-EARTH IONS
ELECTRONIC ENERGY LEVELS
DIODE-PUMPED LASER
OPTICAL-ABSORPTION
ALUMINUM GARNET
MU-M
INTENSITIES
FLUORESCENCE
GLASSES
OXIDE
Аннотация:
High-optical-quality single crystals of the TmAl3(BO3)(4) compound were synthesized from a solution in the melt. The absorption spectra in the sigma and pi polarizations for the H-3(6) - F-3(4), H-3(6) - H-3(5), H-3(6) - H-3(4), H-3(6) - F-3(3), H-3(6) - F-3(2), H-3(6) - (1)G(4), and H-3(6) - D-1(2) transitions in the Tm3+ ion were recorded at room temperature. The transition intensities were analyzed in the framework of the Judd-Ofelt theory generalized to the case of anisotropic crystals, and the following parameters of the theory were obtained: Omega(2) = 6.14 x 10(-20) cm(2), Omega(4) = 3.09 x 10(-20) cm(2), and Omega(6) = 2.04 x 10(-20) cm(2). The lifetimes and the branching ratios were determined for all possible transitions.
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Держатели документа:
[Malakhovskii, A. V.
Sokolov, A. E.
Temerov, V. L.
Bezmaternykh, L. N.
Sukhachev, A. L.
Seredkin, V. A.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Gnatchenko, S. L.
Kachur, I. S.
Piryatinskaya, V. G.] Natl Acad Sci Ukraine, Verkin Inst Low Temp Phys & Engn, UA-61103 Kharkov, Ukraine
ИФ СО РАН
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Verkin Institute for Low Temperature Physics and Engineering, National Academy of Sciences of Ukraine, pr. Lenina 47, Kharkov 61103, Ukraine
Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sokolov, A. E.; Соколов, Алексей Эдуардович; Temerov, V. L.; Темеров, Владислав Леонидович; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Sukhachev, A. L.; Сухачев, Александр Леонидович; Seredkin, V. A.; Середкин, Виталий Александрович; Gnatchenko, S. L.; Kachur, I. S.; Piryatinskaya, V. G.
}
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4.
Spectroscopic properties of
HoAl3(BO3)4 single crystal / D. A. Ikonnikov [et al.]> // Opt. Mater. - 2014. -
Vol. 37
. - P. 257–261,
DOI
10.1016/j.optmat.2014.05.036. - Cited References: 30. - The work was supported by Grant of the Ministry of Education and Science of the Russian Federation for Siberian Federal University, the Russian Foundation for Basic Research Grants 12-02-00026, 14-02-00219 and 13-02-00825, by the Russian President Grant SS-2886.2014.2, and by SB RAS Project No. 43. . - ISSN 0925. - ISSN 1873-1252
Перевод заглавия:
Спектроскопические свойства монокристалла HoAl3(BO3)4
РУБ
Materials Science, Multidisciplinary + Optics
Рубрики:
RARE-EARTH IONS
OPTICAL-PROPERTIES
Ho3+ IONS
ABSORPTION
INTENSITIES
EMISSION
GLASSES
SPECTRA
LUMINESCENCE
PARAMETERS
Кл.слова (ненормированные):
Absorption
--
Luminescence
--
Holmium
--
Huntite
--
Judd-Ofelt
Аннотация:
The Judd–Ofelt theory has been applied to analyze absorption spectra of Ho3+ ion in HoAl3(BO3)4 measured in spectral range 300–700 nm at room temperature. The Judd–Ofelt spectroscopic parameters have been determined as: Ω2 = 18.87 x 10 -20 cm2, Ω4 = 17.04 x 10 -20 cm2, Ω6 = 9.21 x 10 -20 cm2. These parameters have been used to calculate radiative lifetimes and branching ratios of the luminescence manifolds. Three luminescent bands were found in the spectral range 450–700 nm ascribed to transitions from the 5F5, (5F4, 5S2) and 3K8 states to the ground state 5I8. Experimental intensities of these luminescence transitions were compared with those calculated by using Judd–Ofelt theory and the system of kinetic equations for populations of starting luminescing states. Probabilities of radiativeless transitions were evaluated from this comparison.
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Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Ikonnikov, D. A.; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Temerov, V. L.; Темеров, Владислав Леонидович; Krylov, A. S.; Крылов, Александр Сергеевич; Bovina, A. F.; Бовина, Ася Федоровна; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Ministry of Education and Science of the Russian Federation for Siberian Federal University; Russian Foundation for Basic Research Grants [12-02-00026, 14-02-00219, 13-02-00825]; Russian President Grant [SS-2886.2014.2]; SB RAS Project [43]
}
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5.
Preparation, structure, and
up-conversion luminescence of Yb3+/Er3+ codoped SrIn2O4 phosphors / M. Guan [et al.]> // J. Am. Ceram. Soc. - 2015. -
Vol. 98
,
Is. 4
. - P. 1182-1187,
DOI
10.1111/jace.13415. - Cited References:26. - This present work was supported by the National Natural Science Foundations of China (grant no. 51202226), the Fundamental Research Funds for the Central Universities (grant nos. 292014125,2652013128, 2652013043), and the Research Fund for the Doctoral Program of Higher Education of China (grant no. 20130022110006). . - ISSN 0002. - ISSN 1551-2916
Перевод заглавия:
Синтез, структура и ап-конверсионная люминесценция SrIn2O4 допированного Yb3+/Er3+
РУБ
Materials Science, Ceramics
Рубрики:
CORE-SHELL NANOPARTICLES
DOPED CaIn2O4
GREEN
Er3+
EMISSION
GLASSES
Аннотация:
SrIn2O4, which shows lower phonon energy than CaIn2O4, is not only a good photocatalyst but also can be an excellent up-conversion (UC) host to exhibits UC luminescence. In this work, Yb3+ and/or Er3+ doped SrIn2O4 phosphors were synthesized, and their UC luminescence properties were studied and compared with those in the CaIn2O4 host. The structure of SrIn2O4: 0.01Er3+ and SrIn2O4: 0.1Yb3+/0.01Er3+ samples were refined by the Rietveld method and found to that SrIn2O4: 0.1Yb3+/0.01Er3+ showed increasing unit cell parameters and cell volume, indicating In3+ sites were substituted successfully by Yb3+ and/or Er3+ ions. From the UC luminescence spectra and diffuse reflection spectra, Er3+-doped SrIn2O4 showed very weak luminescence due to ground state absorption of Er3+; Yb3+/Er3+ codoped SrIn2O4 presented strong green (550 nm) and red (663 nm) UC emissions which were assigned to energy transfer from Yb3+ transition 2F7/2→2F5/2 to the Er3+ transition 4S3/2 → 4I15/2 and 4F9/2 → 4I15/2. Comparing with CaIn2O4, Yb3+/Er3+ codoped SrIn2O4 showed obvious advantages with higher UC luminescent intensity. The pumping powers study showed that UC emissions in Yb3+/Er3+ codoped SrIn2O4 were attributed to energy transfer of Yb3+→Er3+ with a two-photon process. The possible UC luminescent mechanism of Yb3+/Er3+-doped SrIn2O4 was discussed.
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Держатели документа:
China Univ Geosci, Sch Mat Sci & Technol, Beijing Key Lab Mat Utilizat Nonmetall Minerals &, Natl Lab Mineral Mat, Beijing 100083, Peoples R China
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia
Univ Auckland, Dept Chem & Mat Engn, Auckland 1142, New Zealand
Доп.точки доступа:
Guan, Ming; Zheng, Hong; Mei, Lefu; Molokeev, M. S.; Молокеев, Максим Сергеевич; Xie, Jing; Yang, Tao; Wu, Xiaowen; Huang, Saifang; Huang, Zhaohui
}
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