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Каталог книг и брошюр библиотеки ИФ СО РАН

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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Isaenko L. I., Kesler V. G., Kang L., Lin Z. S., Molokeev M. S., Yelisseyev A. P., Zhurkov S. A.
Заглавие : Structural, spectroscopic, and electronic properties of cubic G0-Rb2KTiOF5 oxyfluoride
Место публикации : J. Phys. Chem. C: American Chemical Society, 2013. - Vol. 117, Is. 14. - P.7269-7278. - ISSN 1932-7447, DOI 10.1021/jp401391y
Примечания : Cited References: 80. - This study was supported by SB RAS (Grant 28.13), the National Natural Science Foundation of China under Grants 11174297 and 91022036, and the National Basic Research Project of China (Nos. 2010CB630701 and 2011CB922204).
Предметные рубрики: RAY PHOTOELECTRON-SPECTROSCOPY
SURFACE CHEMICAL-STABILITY
EFFECTIVE IONIC-RADII
PHASE-TRANSITIONS
CRYSTAL-GROWTH
HEAT-CAPACITY
CORE LEVELS
RB2KTIOF5
FLUORIDES
OXIDES
Аннотация: The G0-Rb2KTiOF5 single crystals with dimensions up to nearly a centimeter in size have been prepared by slow solidification method. The elpasolite-related crystal structure of G0-Rb2KTiOF5 has been refined by Rietveld method at T = 298 K (space group Fm (3) over barm, Z = 4, a = 8.880(1) angstrom, V = 700.16(2) angstrom(3); R-B = 2.66%). The wide optical transparency range of 0.25-9 mu m and forbidden band gap of E-g = 3.87 eV have been obtained for the G0-Rb2KTiOF5 crystal. Dominating photoluminescence bands at 3.36 and 2.33 eV are related to free and self-trapped excitons, respectively. The electronic structure of G0-Rb2KTiOF5 has been evaluated by X-ray photoelectron spectroscopy and calculated with the first-principles methods. A good agreement between theoretical and experimental results has been achieved. Chemical bonding effects have been discussed for all metal ions using binding energy difference parameters and a wide comparison with related oxides and fluorides. The competition between O2- and F- ions for metal valence electrons has been found.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrov K. S., Bartolome J., Gorev M. V., Flerov I. N.
Заглавие : Hydrostatic pressure effect on phase transitions in perovskites with ammonium cations
Место публикации : Phys. Status Solidi B. - 2000. - Vol. 217, Is. 2. - P.785-791. - ISSN 0370-1972, DOI 10.1002/(SICI)1521-3951(200002)217:2785::AID-PSSB7853.0.CO;2-Y
Примечания : Cited References: 36
Предметные рубрики: XMF3 CUBIC PEROVSKITES
THERMAL-PROPERTIES
HEAT-CAPACITY
TEMPERATURE DEPENDENCE
DIELECTRIC PROPERTIES
X-RAY
NH4ZNF3
NH4MNCL3
NH4COF3
NH4CDF3
Аннотация: The pressure dependence of the structural phase transition temperature has been measured for the powder samples of NH4MgF3, NH4ZnF3, NH4MnF3, NH4CoF3, NH4CdF3, and NH4MnCl3 perovskites in the pressure range 0 to 600 MPa. It was found that the values of dT(0)/dP are negative for the Mg, Zn. Co. Mn trifluorides and positive for NH4CdF3 and NH4MnCl3. Comparison with the known data for other halide and oxide perovskites allowed to conclude that the sign of dT(0)/dP is correlated with the value of the Goldschmidt tolerance factor of the perovskite, and its value is closely related to the temperature and mechanism of the transition.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Flerov I. N., Kartashev A. V., Gorev M. V., Bogdanov E. V., Mel'nikova S. V., Molokeev M. S., Pogoreltsev E. I., Laptash N. M.
Заглавие : Thermal, structural, optical, dielectric and barocaloric properties at ferroelastic phase transition in trigonal (NH4)2SnF6: A new look at the old compound
Место публикации : J. Fluor. Chem.: Elsevier, 2016. - Vol. 183. - P.1-9. - ISSN 00221139 (ISSN), DOI 10.1016/j.jfluchem.2015.12.010
Примечания : Cited References: 25. - The reported study was partially supported by RFBR, research project No. 15-02-02009a.
Предметные рубрики: Heat-capacity
Ammonium
(NH4)3TiF7
Pressure
Ключевые слова (''Своб.индексиров.''): fluorides--structural disorder--phase transitions--entropy--barocaloric effect
Аннотация: Structural phase transition P-3m1 → P-1 of the first order and nonferroelectric nature was found in (NH4)2SnF6 at about 110 K in the process of thermal, optical, dielectric and X-ray studies. Order-disorder transformation is accompanied by large changes of entropy (ΔS0 = 16.4 J/mol K) and volume (ΔV0/V ≈ 1%). The structural model associated with three orientations of NH4 tetrahedra in P-3m1 phase and their complete ordering in P-1 phase was suggested with the entropy change (ΔS0 = 18.3 J/mol K) close to the experimental value. A good agreement between baric coefficients measured in a direct way (dT0/dp = -157 K/GPa) and evaluated using entropy and volume changes at phase transition (-170 K/GPa) was found. Barocaloric effects in (NH4)2SnF6 are comparable with those of known solid state refrigerants and are characterised by a low-pressure need for realising their maximum values. © 2015 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kartashev A. V., Gorev M. V., Bogdanov E. V., Flerov I. N., Laptash N. M.
Заглавие : Thermal properties and phase transition in the fluoride, (NH4)3SnF7
Место публикации : J. Solid State Chem. - 2016. - Vol. 237. - P.269-273. - ISSN 00224596 (ISSN), DOI 10.1016/j.jssc.2016.02.027
Примечания : Cited References: 18. - This study was partially supported by the Russian Foundation for Basic Research (RFBR), research Project no. 15-02-02009a.
Предметные рубрики: Heat-capacity
Chemistry
Ключевые слова (''Своб.индексиров.''): phase transition--fluorides--heat capacity--entropy--thermal expansion--high pressure
Аннотация: Calorimetric, dilatometric and differential thermal analysis studies were performed on (NH4)3SnF7 for a wide range of temperatures and pressures. Large entropy (δS0=22 J/mol K) and elastic deformation (δ(ΔV/V)0=0.89%) jumps have proven that the Pa-3虠Pm-3m phase transition is a strong first order structural transformation. A total entropy change of ΔS0=32.5 J/mol K is characteristic for the order-disorder phase transition, and is equal to the sum of entropy changes in the related material, (NH4)3TiF7, undergoing transformation between the two cubic phases through the intermediate phases. Hydrostatic pressure decreases the stability of the high temperature Pm-3m phase in (NH4)3SnF7, contrary to (NH4)3TiF7, characterised by a negative baric coefficient. The effect of experimental conditions on the chemical stability of (NH4)3SnF7 was observed. © 2016 Elsevier Inc.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Pogorel'tsev E. I., Bogdanov E. V., Molokeev M. S., Voronov V. N., Isaenko L. I., Zhurkov S. A., Laptash N. M., Gorev M. V., Flerov I. N.
Заглавие : Thermodynamic Properties and Structure of Oxyfluorides Rb(2)KMoO(3)F(3) and K(2)NaMoO(3)F(3)
Разночтения заглавия :авие SCOPUS: Thermodynamic properties and structure of oxyfluorides Rb2KMoO3F3 and K2NaMoO3F3
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2011. - Vol. 53, Is. 6. - P1202-1211. - ISSN 1063-7834, DOI 10.1134/S1063783411060266
Примечания : Cited References: 24. - This study was supported by the Siberian Branch of the Russian Academy of Sciences within the framework of the Interdisciplinary Integration project no. 34 SO RAN and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools of the Russian Federation (project no. NSh-4645-2010.2).
Предметные рубрики: T PHASE-DIAGRAM
HEAT-CAPACITY
TRANSITIONS
(NH4)(3)MOO3F3
(NH4)(3)TIOF5
(NH4)(3)WO3F3
RB2KTIOF5
CRYSTALS
CRYOLITE
DISORDER
Аннотация: According to the results of calorimetric and structural studies, the Fm (3) over barm phase in K(2)NaMoO(3)F(3) remains stable at least to 100 K. No ferroelectric transformation assumed earlier has been revealed in a series of Rb(2)KMoO(3)F(3) samples prepared using various technologies. Only a phase transition of nonferroelectric origin has been observed near 195 K, and its thermodynamic characteristics have been determined. An analysis of the stability of the cubic structure of molybdenum fluorine-oxygen elpasolites-cryolites has been performed in the framework of the hypothesis on strengths of interatomic bonds. The barocaloric effect in Rb(2)KMoO(3)F(3) has been estimated.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gorev M. V., Flerov I. N., Bogdanov E. V., Voronov V. N., Laptash N. M.
Заглавие : Barocaloric effect near the structural phase transition in the Rb2KTiOF5 oxyfluoride
Коллективы :
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 2. - P377-383. - ISSN 1063-7834, DOI 10.1134/S1063783410020253
Примечания : Cited References: 21. - This study was supported by the Siberian Branch of the Russian Academy of Sciences (Interdisciplinary Integration Project no. 34), the Russian Foundation for Basic Research and the Krasnoyarsk Regional Scientific Foundation within the framework of the "Sibir'" Project (project no. 09-02-98001), and the Council on Grants from the President of the Russian Federation for Support of the Leading Scientific Schools of the Russian Federation (grant no. NSh-1011.2008.2).
Предметные рубрики: HEAT-CAPACITY
PRESSURE
Аннотация: The barocaloric effect (BCE) in the oxyfluoride Rb2KTiOF5 has been studied in the vicinity of the structural phase transition at a temperature of 215 K in the pressure range 0-0.6 GPa. It has been established that the extensive and intensive barocaloric effects are Delta S-BCE similar to -46 J/kg K and Delta T (AD) similar to 18 K, respectively, over a wide temperature range 215-280 K. The studies performed have shown that the external hydrostatic pressure is a very effective tool for changing the entropy and temperature of the crystals which undergo structural phase transitions accompanied by a large change in the entropy.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Gorev M. V., Bondarev V. S., Flerov I. N., Maglione M., Simon A., Sciau P., Boulos M., Guillemet-Fritsch S.
Заглавие : Thermal expansion, polarization and phase diagrams of Ba1-yBi2y/3Ti1-xZrxO3 and Ba1-yLayTi1-y/4O3 compounds
Коллективы : Russian Foundation for Basic Research [07-02-00069]; Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools [NSh-1011.2008.2]
Разночтения заглавия :авие SCOPUS: Thermal expansion, polarization and phase diagrams of Ba 1-yBi2y/3Ti1-xZrxO3 and Ba1-yLayTi1-y/4O3 compounds
Место публикации : J. Phys.: Condens. Matter: IOP PUBLISHING LTD, 2009. - Vol. 21, Is. 7. - Ст.75902. - С. P. - ISSN 0953-8984, DOI 10.1088/0953-8984/21/7/075902
Примечания : Cited References: 28. - This work was supported by the Russian Foundation for Basic Research ( project no. 07-02-00069) and the Council on Grants from the President of the Russian Federation for Support of Leading Scientific Schools ( project no. NSh-1011.2008.2).
Предметные рубрики: HEAT-CAPACITY
CERAMICS
BA(TI1-XZRX)O-3
FERROELECTRICS
BEHAVIOR
BATIO3
BATI0.65ZR0.35O3
CONDUCTIVITY
PEROVSKITES
CHEMISTRY
Ключевые слова (''Своб.индексиров.''): barium--dielectric properties--lanthanum--phase diagrams--polarization--thermal stress--zirconium--ceramic compositions--root mean squares--temperature ranges--temperature-dependent measurements--thermal expansion co-efficient--thermal-expansion properties--thermal expansion
Аннотация: The thermal expansion properties of the ceramic compositions Ba1-yLayTi1-y/4O3 (y = 0.0, 0.026, 0.036, 0.054) and Ba1-yBi2y/3Ti1-xZrxO3 (y = 0.10; x = 0.0, 0.04, 0.05, 0.10, 0.15) were determined in the temperature range 120-700 K. We report the temperature- dependent measurements of the strain, thermal expansion coefficient and the magnitude of root mean square polarization. The results obtained are discussed together with the data on the structure and dielectric properties.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kartashev A. V., Bondarev V. S., Flerov I. N., Gorev M. V., Pogorel'tsev E. I., Shabanov A. V., Molokeev M. S., Guillemet-Fritsch S., Raevskii I. P.
Заглавие : Study of the Physical Properties and Electrocaloric Effect in the BaTiO3 Nano- and Microceramics
Место публикации : Phys. Solid State. - 2019. - Vol. 61, Is. 6. - P.1052-1061. - ISSN 1063-7834, DOI 10.1134/S1063783419060088. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 38
Предметные рубрики: HEAT-CAPACITY
DIELECTRIC-PROPERTIES
THERMAL-EXPANSION
THIN-FILMS
Аннотация: The specific heat, thermal expansion, permittivity, and electrocaloric effect in bulk of BaTiO3 (BT) samples in the form of nano- (nBT-500 nm) and micro- (mBT-1200 nm) ceramics fabricated using spark plasma sintering and solid-state plasma techniques have been investigated. The size effect has been reflected, to a great extent, in the suppression of the specific heat and thermal expansion anomalies and in the changes in the temperatures and entropies of phase transitions and permittivity, and a decrease in the maximum intensive electrocaloric effect: ΔTmaxAD = 29 mK (E = 2.0 kV/cm) for nBT and ΔTmaxAD = 70 mK (E = 2.5 kV/cm) for mBT. The conductivity growth at temperatures above 360 K leads to the significant irreversible heating of the samples due to the Joule heat release in the applied electric field, which dominates over the electrocaloric effect.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Kargin, Yu F., Gerasimov V. P., Krylov A. S., Aleksandrovskii A. S., Chumilina L. G., Denisov V. M., Vasil'ev G. V.
Заглавие : Synthesis, crystal structure, and physicochemical properties of Bi4-xPrxTi3O12 (x=0.4, 0.8, 1.2, 1.6) solid solutions
Место публикации : Inorg. Mater. - 2021. - Vol. 57, Is. 9. - P.919-928. - ISSN 0020-1685, DOI 10.1134/S002016852109003X. - ISSN 1608-3172(eISSN)
Примечания : Cited References: 40
Предметные рубрики: BI4-XRXTI3O12 R-X
HEAT-CAPACITY
AURIVILLIUS PHASES
PR
ND
BI4TI3O12
Аннотация: Bi4–xPrxTi3O12 (x = 0.4, 0.8, 1.2, 1.6) solid solutions have been prepared by solid-state reactions, via multistep firing of stoichiometric mixtures of their constituent oxides in air at temperatures from 1003 to 1323 K. Their crystal structure has been determined using X-ray diffraction, and their luminescence spectra have been measured at room temperature. High-temperature heat capacity of polycrystalline substituted bismuth titanate samples has been determined by differential scanning calorimetry. The Cp(T) curves of the solid solutions with x = 0.4 and 0.8 have extrema related to phase transitions. Experimental data have been used to calculate the main thermodynamic functions of the solid solutions.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisova L. T., Molokeev M. S., Galiakhmetova N. A., Denisov V. M., Vasil'ev G. V.
Заглавие : Synthesis, crystal structure, and thermal properties of substituted titanates Bi2Pr2Ti3O12 and Bi2Nd2Ti3O12
Коллективы : [FSRZ-2020-0013]
Место публикации : Phys. Solid State. - 2021. - Vol. 63. Is. 8. - P.1159-1164. - ISSN 1063-7834, DOI 10.1134/S1063783421080084. - ISSN 1090-6460(eISSN)
Примечания : Cited References: 39. - This study was carried out in part within the state assignment for the Siberian Federal University, project no. FSRZ-2020-0013
Предметные рубрики: BI4-XRXTI3O12 R-X
PHASE-EQUILIBRIA
HEAT-CAPACITY
ND
BI4TI3O12
PR
Аннотация: Titanates Bi2Pr2Ti3O12 and Bi2Nd2Ti3O12 have been obtained by the solid-phase synthesis using sequential annealing of the Bi2O3, Nd2O3, Pr6O11, and TiO2 stoichiometric mixtures in air at temperatures of 1003–1323 K. Their crystal structure has been established by X-ray diffractometry and the high-temperature heat capacity has been determined by differential scanning calorimetry. Based on the experimental Cp = f(T) data, the main thermodynamic functions have been calculated.
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