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Synthesis, structure, and properties of EuLnCuSe3 (Ln = Nd, Sm, Gd, Er) / O. V. Andreev, V. V. Atuchin, A. S. Aleksandrovsky [et al.] // Crystals. - 2022. - Vol. 12, Is. 1. - Ст. 17, DOI 10.3390/cryst12010017. - Cited References: 60. - The study was funded by the Ministry of Science and Higher Education of the Russian Ferderation (Projects AAAA-A21-121011390011-4 and AAAA-A19-119031890025-9), as well as the Government of the Tyumen Region (grant to non-profit organizations No. 2. 89-don, dated 7 December 2020) . - ISSN 2073-4352

РУБ Crystallography + Materials Science, Multidisciplinary
Рубрики:
RARE-EARTH
   CRYSTAL-STRUCTURE
   MAGNETIC-PROPERTIES
   CHALCOGENIDES
Кл.слова (ненормированные):
rare earth elements -- complex sulfides -- chalcogenides -- crystal structure -- magnetic properties
Аннотация: EuLnCuSe3 (Ln = Nd, Sm, Gd, Er), due to their complex composition, should be considered new materials with the ability to purposefully change the properties. Samples of the EuLnCuSe3 were prepared using Cu, rare earth metal, Se (99.99%) by the ampoule method. The samples were obtained by the crystallization from a melt and annealed at temperatures 1073 and 1273 K. The EuErCuSe3 crystal structure was established using the single-crystal particle. EuErCuSe3 crystallizes in the orthorhombic system, space group Cmcm, KCuZrS3 structure type, with cell parameters a = 4.0555 (3), b = 13.3570 (9), and c = 10.4602 (7) Å, V = 566.62 (6) Å3. In structure EuErCuSe3, erbium ions are coordinated by selenium ions in the octahedral polyhedron, copper ions are in the tetrahedral coordination, europium ions are between copper and erbium polyhedra layers and are coordinated by selenium ions as two-cap trigonal prisms. The optical band gap is 1.79 eV. At 4.7 K, a transition from the ferrimagnetic state to the paramagnetic state was detected in EuErCuSe3. At 85 and 293 K, the compound is in a paramagnetic state. According to XRPD data, EuLnCuSe3 (Ln = Nd, Sm, Gd) compounds have a Pnma orthorhombic space group of the Eu2CuS3 structure type. For EuSmCuSe3, a = 10.75704 (15) Å, b = 4.11120 (5) Å, c = 13.37778 (22) Å. In the series of EuLnCuSe3 compounds, the optical band gap increases 1.58 eV (Nd), 1.58 eV (Sm), 1.72 eV (Gd), 1.79 eV (Er), the microhardness of the 205 (Nd), 210 (Sm), 225 (Gd) 235 ± 4 HV (Er) phases increases, and the thermal stability of the phases increases significantly. According to the measurement data of differential scanning calorimetry, the EuNdCuSe3 decomposes, according to the solid-phase reaction T = 1296 K, ΔH = 8.2 ± 0.8 kJ/mol. EuSmCuSe3 melts incongruently T = 1449 K, ΔH = 18.8 ± 1.9 kJ/mol. For the EuGdCuSe3, two (Tα↔β = 1494 K, ΔHα↔β = 14.8 kJ/mol, Tβ↔γ = 1530 K, ΔHβ↔γ = 4.8 kJ/mol) and for EuErCuSe3 three polymorphic transitions (Tα↔β = 1561 K, ΔHα↔β = 30.3 kJ/mol, Tβ↔γ = 1579 K, ΔHβ↔γ = 4.4 kJ/mol, and Tγ↔δ = 1600 K, ΔHγ↔δ = 10.1 kJ/mol). The compounds melt incongruently at the temperature of 1588 K, ΔHmelt = 17.9 ± 1.8 kJ/mol and 1664 K, ΔHmelt = 25.6 ± 2.5 kJ/mol, respectively. Incongruent melting of the phases proceeds with the formation of a solid solution of EuSe and a liquid phase.

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Держатели документа:
Univ Tyumen, Inst Chem, Tyumen 625003, Russia.
RAS, Inst Semicond Phys, Lab Opt Mat & Struct, SB, Novosibirsk 630090, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
Novosibirsk State Tech Univ, Dept Ind Machinery Design, Novosibirsk 630073, Russia.
RAS, KSC, Fed Res Ctr, Kirensky Inst Phys,SB, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660036, Russia.
Ind Univ Tyumen, Dept Gen & Special Chem, Tyumen 625000, Russia.
RAS, Boreskov Inst Catalysis, SB, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Lab Mol Design & Ecol Safe Technol, Novosibirsk 630090, Russia.
RAS, Inst Solid State Chem, UB, Ekaterinburg 620990, Russia.

Доп.точки доступа:
Andreev, O. V.; Atuchin, V. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Denisenko, Y. G.; Zakharov, B. A.; Tyutyunnik, A. P.; Habibullayev, N. N.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Ulybin, D. A.; Shpindyuk, D. D.; Ministry of Science and Higher Education of the Russian Ferderation [AAAA-A21-121011390011-4, AAAA-A19-119031890025-9]; Government of the Tyumen Region [2. 89-don]
}
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Tailoring the microwave properties of thin permalloy films using a periodically grooved substrate / A. V. Izotov, B. A. Belyaev, N. M. Boev [et al.] // Physica B. - 2022. - Vol. 629. - Ст. 413654, DOI 10.1016/j.physb.2021.413654. - Cited References: 50. - This work was supported by the Ministry of Science and Higher Education of the Russian Federation, agreement number 075-11-2019054 dated November 22, 2019 . - ISSN 0921-4526. - ISSN 1873-2135

РУБ Physics, Condensed Matter
Рубрики:
FERROMAGNETIC-RESONANCE
   MAGNETIC-PROPERTIES
   ANISOTROPY
   FREQUENCY
Кл.слова (ненормированные):
Patterned film -- Topography-induced anisotropy -- Netzelmann approach -- Ferromagnetic resonance -- Damping parameter
Аннотация: Thin magnetic films with periodic surface topography are of special interest for microwave applications as their static and dynamic magnetic characteristics can be readily adjusted. In this paper, we explore the capabilities of a simple method for producing large-area periodically patterned films by creating regularly spaced grooves on a substrate using a diamond cutter. For 110-nm-thick films, it was found that the substrate-topography-induced magnetic anisotropy was inversely proportional to the pattern period, which in experimental samples varied from 5 to 20 mu m. Based on the Netzelmann theory, analytical expressions for demagnetization tensor components were obtained, which accord well with the experimental data. The measurements of the natural ferromagnetic resonance spectra demonstrated that the increase of the topography-induced magnetic anisotropy with the decrease of the pattern period led to the increase of the resonance frequency from 0.65 to 1.86 GHz, and to a decrease of the linewidth and effective damping parameter.

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Держатели документа:
Siberian Fed Univ, 79 Svobodny Pr, Krasnoyarsk 660041, Russia.
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, 50-38 Akademgorodok, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Izotov, A. V.; Изотов, Андрей Викторович; Belyaev, B. A.; Беляев, Борис Афанасьевич; Boev, N. M.; Боев, Никита Михайлович; Burmitskikh, A. V.; Бурмитских, Антон Владимирович; Leksikov, An. A.; Лексиков, Андрей Александрович; Skomorokhov, G. V.; Скоморохов, Георгий Витальевич; Solovev, P. N.; Соловьев, Платон Николаевич; Ministry of Science and Higher Education of the Russian Federation [075-11-2019054]
}
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Biogenic ferrihydrite nanoparticles produced by Klebsiella oxytoca: Characterization, physicochemical properties and bovine serum albumin interactions / N. Cazacu, C. G. Chilom, S. Iftimie [et al.] // Nanomaterials. - 2022. - Vol. 12, Is. 2. - Ст. 249, DOI 10.3390/nano12020249. - Cited References: 59. - This research was funded by JINR Themes 02-1-1107-2011/2021, 04-5-1131-2017/2021 and 04-4-1133-2018/2023 and with the financial support of the RO-JINR Projects Nos. 366/11.05.2021 (items 7, 86, 97) and 365/11.05.2021 (items 8, 87 and 98). This work also benefited from the use of the SasView application, originally developed under NSF Award DMR-0520547. SasView also contains the code developed with funding from the EU Horizon 2020 program under the SINE2020 project Grant No 654000. The APC was funded by JINR Theme 02-1-1107-2011/2021, Project No. 366/11.05.2021, item 7. This study used the infrastructure of the Applied Genetics Resource Facility of MIPT (Suport Grant 075-15-2021-684) . - ISSN 2079-4991

РУБ Chemistry, Multidisciplinary + Nanoscience & Nanotechnology + Materials Science, Multidisciplinary + Physics, Applied
Рубрики:
MAGNETIC-PROPERTIES
   REDUCTION
   MOSSBAUER
   FERRITIN
   DOCKING
   BINDING
Кл.слова (ненормированные):
biogenic ferrihydrite nanoparticles -- the binding mechanism -- energy transfer -- protein stability -- molecular docking
Аннотация: The synthesis of nanoparticles inside microorganisms is an economical alternative to chemical and physical methods of nanoparticle synthesis. In this study, ferrihydrite nanoparticles synthesized by Klebsiella oxytoca bacterium in special conditions were characterized by scanning electron microscopy (SEM), energy-dispersive X-ray analysis (EDS), small-angle X-ray (SAXS), UV-Vis spectroscopy, fluorescence, fluorescence resonance energy transfer (FRET), and molecular docking. The morphology and the structure of the particles were characterized by means of SEM and SAXS. The elemental content was determined by means of the EDS method. The absorption properties of the ferrihydrite nanoparticles were investigated by UV-Vis spectroscopy. The binding mechanism of the biogenic ferrihydrite nanoparticles to Bovine Serum Albumin (BSA) protein, studied by fluorescence, showed a static and weak process, combined with FRET. Protein denaturation by temperature and urea in the presence of the ferrihydrite nanoparticles demonstrated their influence on the unfolding process. The AutoDock Vina and UCSF Chimera programs were used to predict the optimal binding site of the ferrihydrite to BSA and to find the location of the hydrophobic cavities in the sub-domain IIA of the BSA structure.

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Держатели документа:
Univ Bucharest, Fac Phys, Dept Elect Solid State & Biophys, RO-077125 Magurele, Romania.
Horia Hulubei Natl Inst Phys & Nucl Engn, Dept Nucl Phys, RO-077125 Magurele, Romania.
Joint Inst Nucl Res, Dubna 141980, Russia.
Moscow Inst Phys & Technol, Dolgoprudnyi 141701, Russia.
Russian Acad Sci, Siberian Branch, Fed Res Ctr KSC, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Sch Engn Phys & Radio Elect, Phys Dept, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Cazacu, Nicoleta; Chilom, Claudia G.; Iftimie, Sorina; Balasoiu, Maria; Ladygina, Valentina P.; Stolyar, S. V.; Столяр, Сергей Викторович; Orelovich, Oleg L.; Kovalev, Yuriy S.; Rogachev, Andrey V.
}
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    Quaternary selenides EuLnCuSe3: Synthesis, structures, properties and in silico studies / M. V. Grigoriev, L. A. Solovyov, A. V. Ruseikina [et al.] // Int. J. Mol. Sci. - 2022. - Vol. 23, Is. 3. - Ст. 1503, DOI 10.3390/ijms23031503. - Cited References: 90 . - ISSN 1422-0067
   Перевод заглавия: Четвертичные селениды EuLnCuSe3: синтез, структура, свойства и компьютерное моделирование

РУБ Biochemistry & Molecular Biology + Chemistry, Multidisciplinary
Рубрики:
RARE-EARTH
   CRYSTAL-STRUCTURES
   MAGNETIC-PROPERTIES
   THERMOELECTRIC PERFORMANCE
Кл.слова (ненормированные):
inorganic materials -- ab initio calculations -- magnetic measurements -- lattice dynamics -- vibrational spectroscopy -- optical spectroscopy -- negative magnetization
Аннотация: In this work, we report on the synthesis, in-depth crystal structure studies as well as optical and magnetic properties of newly synthesized heterometallic quaternary selenides of the Eu+2Ln+3Cu+1Se3 composition. Crystal structures of the obtained compounds were refined by the derivative difference minimization (DDM) method from the powder X-ray diffraction data. The structures are found to belong to orthorhombic space groups Pnma (structure type Ba2MnS3 for EuLaCuSe3 and structure type Eu2CuS3 for EuLnCuSe3, where Ln = Sm, Gd, Tb, Dy, Ho and Y) and Cmcm (structure type KZrCuS3 for EuLnCuSe3, where Ln = Tm, Yb and Lu). Space groups Pnma and Cmcm were delimited based on the tolerance factor t’, and vibrational spectroscopy additionally confirmed the formation of three structural types. With a decrease in the ionic radius of Ln3+ in the reported structures, the distortion of the (LnCuSe3) layers decreases, and a gradual formation of the more symmetric structure occurs in the sequence Ba2MnS3 → Eu2CuS3 → KZrCuS3. According to magnetic studies, compounds EuLnCuSe3 (Ln = Tb, Dy, Ho and Tm) each exhibit ferrimagnetic properties with transition temperatures ranging from 4.7 to 6.3 K. A negative magnetization effect is observed for compound EuHoCuSe3 at temperatures below 4.8 K. The magnetic properties of the discussed selenides and isostructural sulfides were compared. The direct optical band gaps for EuLnCuSe3, subtracted from the corresponding diffuse reflectance spectra, were found to be 1.87–2.09 eV. Deviation between experimental and calculated band gaps is ascribed to lower d states of Eu2+ in the crystal field of EuLnCuSe3, while anomalous narrowing of the band gap of EuYbCuSe3 is explained by the low-lying charge-transfer state. Ab initio calculations of the crystal structures, elastic properties and phonon spectra of the reported compounds were performed.

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Держатели документа:
Univ Tyumen, Lab Theory & Optimizat Chem & Technol Processes, Tyumen 625003, Russia.
SB RAS, Inst Chem & Chem Technol, Fed Res Ctr KSC, Krasnoyarsk 660036, Russia.
Univ Tyumen, Inst Chem, Tyumen 625003, Russia.
Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660079, Russia.
RAS, SB, Fed Res Ctr KSC, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Ural Fed Univ, Inst Nat Sci & Math, Mira Str 19, Ekaterinburg 620002, Russia.
Univ Tyumen, Inst Phys & Technol, Tyumen 625003, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
Siberian Fed Univ, Inst Engn Phys & Radioelect, Krasnoyarsk 660079, Russia.
Siberian Fed Univ, Sch Engn & Construct, Krasnoyarsk 660041, Russia.
Univ Tyumen, Engn Ctr Composite Mat Based Wolfram Cpds & Rare, Tyumen 625003, Russia.
Univ Stuttgart, Inst Inorgan Chem, D-70569 Stuttgart, Germany.
Kurgan State Univ, Adv Mat Ind & Biomed Lab, Sovetskaya Str 63-4, Kurgan 640020, Russia.
Ural Fed Univ, Innovat Ctr Chem & Pharmaceut Technol, Mira Str 19, Ekaterinburg 620002, Russia.

Доп.точки доступа:
Grigoriev, Maxim V.; Solovyov, Leonid A.; Ruseikina, Anna V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Chernyshev, Vladimir A.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Garmonov, Alexander A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Shestakov, N. P.; Шестаков, Николай Петрович; Matigorov, Alexey V.; Volkova, Svetlana S.; Ostapchuk, Evgeniy A.; Kertman, Alexander V.; Schleid, Thomas; Safin, Damir A.
}
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Structure and thermodynamic properties of the DyGaTi2O7 and EuGaTi2O7 titanates / L. T. Denisova, M. S. Molokeev, Y. F. Kargin [et al.] // Inorg. Mater. - 2021. - Vol. 57, Is. 7. - P. 733-740, DOI 10.1134/S0020168521070050. - Cited References: 26. - This work was supported by the Russian Federation Ministry of Science and Higher Education as part of the state research target for the Siberian Federal University federal state autonomous educational institution of higher education, project no. FSRZ-2020-0013 . - ISSN 0020-1685. - ISSN 1608-3172

РУБ Materials Science, Multidisciplinary
Рубрики:
CRYSTAL-STRUCTURE
MAGNETIC-PROPERTIES
STATE
Кл.слова (ненормированные):
solid-state synthesis -- rare-earth titanates -- crystal structure -- high-temperature heat capacity -- thermodynamic properties
Аннотация: The DyGaTi2O7 and EuGaTi2O7 titanates have been prepared by solid-state reactions in a starting mixture of Dy2O3 (Eu2O3), Ga2O3, and TiO2 via firing in air at temperatures of 1273 and 1573 K, and their crystal structure has been studied by X-ray diffraction. Their high-temperature heat capacity (350-1000 K) has been determined by differential scanning calorimetry. The Cp(T) experimental data have been used to calculate the thermodynamic functions of the titanates.

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Публикация на русском языке Структура и термодинамические свойства титанатов DyGaTi2O7 и EuGaTi2O7 [Текст] / Л. Т. Денисова, М. С. Молокеев, Ю. Ф. Каргин [и др.] // Неорган. матер. - 2021. - Т. 57 № 7. - С. 768-775

Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Fed Res Ctr, Siberian Branch, Kirensky Inst Phys,Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Baikov Inst Met & Mat Sci, Moscow 119991, Russia.
Russian Acad Sci, Inst Met, Ural Branch, Ekaterinburg 620016, Russia.

Доп.точки доступа:
Denisova, L. T.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Kargin, Yu F.; Ryabov, V. V.; Chumilina, L. G.; Belousova, N., V; Denisov, V. M.; Russian Federation Ministry of Science and Higher Education [FSRZ-2020-0013]
}
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    Study of flux crystal growth peculiarities, structure and Raman spectra of double (Mn,Ni)3BO5 and triple (Mn,Ni,Cu)3BO5 oxyborates with ludwigite structure / E. Moshkina, A. Bovina, M. Molokeev [et al.] // CrystEngComm. - 2021. - Vol. 23, Is. 33. - P. 5624-5635, DOI 10.1039/d1ce00750e. - Cited References: 32. - This work was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Krai, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 20-42-240011. X-ray and EDX data were obtained with the use of the analytical equipment of the Krasnoyarsk Regional Center of Research Equipment of Federal Research Center "Krasnoyarsk Science Center SB RAS" . - ISSN 1466-8033
   Перевод заглавия: Исследование особенностей роста, структуры и рамановских спектров двойных (Mn,Ni)3BO5 и тройных (Mn,Ni,Cu)3BO5 оксиборатов со структурой людвигита

РУБ Chemistry, Multidisciplinary + Crystallography
Рубрики:
MAGNETIC-PROPERTIES
SINGLE-CRYSTAL
Аннотация: Crystallization of heterovalent double (Mn,Ni)3BO5 and triple (Mn,Ni,Cu)3BO5 oxyborates with the ludwigite structure is studied in fluxes based on Bi2Mo3O12 diluted with Na2CO3 or Li2CO3 carbonates. Single crystals of five (Mn,Ni)3BO5 and three (Mn,Ni,Cu)3BO5 compounds with different cation ratios are obtained. The ion concentration is determined from the analysis of the lattice parameters by powder and single crystal XRD. The comparative analysis of the polarized Raman spectra of double and triple ludwigites is presented. The actual high nickel and small copper concentrations in the crystals are discussed. The hierarchy of chemical bonds in the fluxes used in addition to the approach involving stabilization of the manganese valence state using solvent components is estimated.

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Держатели документа:
Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
Russian Acad Sci, Fed Res Ctr, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk 660036, Russia.
Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia.

Доп.точки доступа:
Moshkina, E. M.; Мошкина, Евгения Михайловна; Bovina, A. F.; Бовина, Ася Федоровна; Molokeev, M. S.; Молокеев, Максим Сергеевич; Krylov, A. S.; Крылов, Александр Сергеевич; Shabanov, A. V.; Шабанов, Александр Васильевич; Chernyshov, A. V.; Чернышов, Артем Валерьевич; Sofronova, S. N.; Софронова, Светлана Николаевна; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Government of the Krasnoyarsk Krai; Krasnoyarsk Territorial Foundation for Support of Scientific and RD Activities [20-42-240011]
}
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Romanova, O. B.
Effect of electron and hole doping on the transport characteristics of chalcogenide systems / O. B. Romanova, S. S. Aplesnin, L. V. Udod // Phys. Solid State. - 2021. - Vol. 63, Is. 5. - P. 754-757, DOI 10.1134/S1063783421050152. - Cited References: 21. - This study was supported by the Russian Foundation for Basic Research and the Belarusian Republican Foundation for Basic Research, project no. 20-52-00005 . - ISSN 1063-7834. - ISSN 1090-6460

РУБ Physics, Condensed Matter
Рубрики:
MAGNETIC-PROPERTIES
TRANSITION
Кл.слова (ненормированные):
semiconductors -- conductivity -- Hall constant -- mobility
Аннотация: The electrical properties of the Ag0.01Mn0.99S and Tm0.01Mn0.99S semiconductor compounds and the Hall effect in them have been investigated in the temperature range of 80-400 K in a magnetic field of 12 kOe. Using the I-V characteristics, the conductivity mechanism depending on the doping type and concentration has been established. Upon substitution of silver for manganese, the Mott-type conductivity has been found, while substitution of thulium causes the ohmic conductivity. The mobility and type of carriers have been determined from the Hall constant data.

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Публикация на русском языке Романова, Оксана Борисовна. Влияние электронного и дырочного допирования на транспортные характеристики халькогенидных систем [Текст] / О. Б. Романова, С. С. Аплеснин, Л. В. Удод // Физ. тверд. тела. - 2021. - Т. 63 Вып. 5. - С. 606-609

Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Siberian State Univ Sci & Technol, Krasnoyarsk 660014, Russia.

Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Udod, L. V.; Удод, Любовь Викторовна; Романова, Оксана Борисовна; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Belarusian Republican Foundation for Basic Research [20-52-00005]
}
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    Iron-cobalt coatings produced using an eco-friendly route / E. A. Denisova, L. A. Chekanova, S. V. Komogortsev [et al.] // J. Supercond. Nov. Magn. - 2021. - Vol. 34, Is. 10. - P. 2681-2688, DOI 10.1007/s10948-021-05964-1. - Cited References: 35. - This work was funded by the Russian Foundation for Basic Research, Krasnoyarsk Territory, and Krasnoyarsk Regional Fund of Science, project number 20-43-240003 . - ISSN 1557-1939. - ISSN 1557-1947
   Перевод заглавия: Железо-кобальтовые покрытия, полученные экологически чистым путем

РУБ Physics, Applied + Physics, Condensed Matter
Рубрики:
MAGNETIC-PROPERTIES
   FECO FILMS
   THIN-FILMS
   CO-FE
   ELECTRODEPOSITION
Кл.слова (ненормированные):
High-induction Fe-Co coating -- Electroless deposition -- Structure -- Magnetic properties -- Eco-friendly synthesis
Аннотация: A facile, low-cost, and green route for synthesis of high-induction Fe-Co coatings was developed. Within this approach, three natural reducing agents have been used for deposition of the metal coatings by electroless plating on dielectric and metallic substrates: arabinogalactan, starch, and sucrose. The Fe-Co alloy coatings with Co content from 0 to 94 at.% are nanocrystalline bcc solid solution with carbon additive no more than 2 at%, and pure Co coatings are of hcp structure. The magnetic properties of bcc-based iron-cobalt alloys have been investigated as a function of the atomic composition. A high-saturation magnetization of about 240 emu/g was obtained for Fe70Co30 alloy films deposited onto copper substrate. The local magnetic anisotropy of FeCo alloys increases with a decrease in iron content for all reducing agents. High magnetization close to those in the bulk Fe-Co alloys implies the prospective applications of synthesized Fe-Co coatings as magnetic shield and magnetic sensors.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Res Ctr KSC SB RAS, Sci Ctr, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Denisova, E. A.; Денисова, Елена Александровна; Chekanova, L. A.; Чеканова, Лидия Александровна; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Nemtsev, I. V.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Dolgopolova, M. V.
}
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Dynamic remagnetisation of CoFe2O4 nanoparticles: thermal fluctuational thawing of anisotropy / D. A. Balaev, I. S. Poperechny, A. A. Krasikov [et al.] // J. Phys. D. - 2021. - Vol. 54, Is. 27. - Ст. 275003, DOI 10.1088/1361-6463/abf371. - Cited References: 63. - Experimental measurements were supported by Project No. AAAA-A17-117103050081-1. I S P and Yu L R acknowledge the support of ICMM in the framework of topical task AAAAA20-120020690030-5. The numerical calculations were performed on the Uran supercomputer (Ural Branch, Russian Academy of Sciences, Ekaterinburg) . - ISSN 0022-3727. - ISSN 1361-6463

РУБ Physics, Applied
Рубрики:
COBALT-FERRITE NANOPARTICLES
   MAGNETIC-PROPERTIES
   SIZE
   COERCIVITY
Кл.слова (ненормированные):
nanoparticles -- cobalt ferrite -- magnetodynamics -- superparamagnetism -- effective anisotropy
Аннотация: We report a study of the magnetodynamics of cobalt ferrite (CoFe2O4) nanoparticles with an average diameter of ~6 nm. Hysteresis loops were measured under quasi-static conditions and in pulse fields with amplitudes H0 of up to 130 kOe and for durations τP of 8 and 16 ms. The growth of coercivity Hc observed with an increase in the magnetic field variation rate dH/dt (determined by the values of H0 and τP) and the reduction of Hc with temperature is ascribed to the superparamagnetic effect. The proposed theoretical model explains the observed dependences fairly well. Notably, the effective magnetic anisotropy constant obtained exceeds the value for bulk crystals and might be indicative of the contribution of surface magnetic anisotropy.

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Держатели документа:
Russian Acad Sci, Inst Phys, Siberian Branch, Krasnoyarsk 660000, Russia.
Russian Acad Sci, Inst Continuous Media Mech, Ural Branch, Perm 614068, Russia.
Perm State Natl Res Univ, Dept Phase Transit Phys, Perm 614990, Russia.
Russian Acad Sci, Boreskov Inst Catalysis, Siberian Branch, Novosibirsk 630090, Russia.

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Poperechny, I. S.; Krasikov, A. A.; Красиков, Александр Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Popkov, S. I.; Попков, Сергей Иванович; Knyazev, Yu. V.; Князев, Юрий Владимирович; Kirillov, V. L.; Yakushkin, S. S.; Martyanov, O. N.; Raikher, Y. L.; [AAAA-A17-117103050081-1]; [AAAAA20-120020690030-5]
}
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10.

Magnetotransport effects and electronic phase separation in manganese sulfides with electron-hole doping / O. B. Romanova, S. S. Aplesnin, M. N. Sitnikov, L. V. Udod // J. Exp. Theor. Phys. - 2021. - Vol. 132, Is. 5. - P. 831-842, DOI 10.1134/S106377612103016X. - Cited References: 38. - This study was supported by the Russian Foundation for Basic Research and the Belarussian Republic Foundation for Basic Research (project no. 20-52-00005) . - ISSN 1063-7761. - ISSN 1090-6509

РУБ Physics, Multidisciplinary
Рубрики:
MAGNETIC-PROPERTIES
TRANSITION
MAGNETORESISTANCE
Аннотация: We analyze the effect of electron and hole doping with a low substituent concentration (x = 0.01) on the magnetic and electron subsystems in disordered semiconductors MexMn1-xS (Me = Ag and Tm) in a wide range of temperatures (77–1000 K) and magnetic fields up to 12 kOe. Using magnetic measurements, we have established the domains of ferron (polaron) formation in the vicinity of the magnetic phase transition. We have detected the magnetoimpedance and magnetoresistance, the magnitude and sign of which depend on the electric field, temperature, and the type of the substituent element. We have determined the temperatures of thermopower peaks associated with deformation of the crystalline structure. We have established the phonon and magnon contributions to charge carrier relaxation using the method of impedance spectroscopy and the Jahn–Teller mode of oscillations from the IR spectra for the system containing silver. We have determined the diffusion contribution to the conductivity from the impedance hodograph in TmxMn1-xS semiconductors. The experimental results are described using the models of supermagnetic clusters, ferroelectric domains, and the Debye model.

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Публикация на русском языке Магнитотранспортные эффекты и электронное фазовое расслоение в сульфидах марганца с электронно-дырочным допированием [Текст] / О. Б. Романова, С. С. Аплеснин, М. Н. Ситников, Л. В. Удод // Журн. эксперим. и теор. физ. - 2021. - Т. 159 Вып. 5. - С. 938-951

Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Reshetnev Siberian State Univ Sci & Technol, Krasnoyarsk 660037, Russia.

Доп.точки доступа:
Romanova, O. B.; Романова, Оксана Борисовна; Aplesnin, S. S.; Аплеснин, Сергей Степанович; Sitnikov, M. N.; Udod, L. V.; Удод, Любовь Викторовна; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR); Belarussian Republic Foundation for Basic Research [20-52-00005]
}
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11.

Spin Wave Resonance in the [(Co0.88Fe0.12)/Cu]N Synthetic Antiferromagnet / I. G. Vazhenina, R. S. Iskhakov, M. A. Milyaev [et al.] // Tech. Phys. Lett. - 2020. - Vol. 46, Is. 11. - P. 1076-1079, DOI 10.1134/S1063785020110140. - Cited References: 19. - This study was carried out under a state order of the Ministry of Science and Higher Education of the Russian Federation (theme "Spin" no. AAAA-A18-118020290104-2) and supported in part by the Russian Foundation for Basic Research (project no. 20-42-660018) . - ISSN 1063-7850. - ISSN 1090-6533

РУБ Physics, Applied
Рубрики:
MAGNETIC-PROPERTIES
   MAGNETORESISTANCE
   SPECTRUM
   FILMS
Кл.слова (ненормированные):
spin wave resonance -- synthetic antiferromagnet -- exchange coupling constant
Аннотация: The [(Co0.88Fe0.12)/Cu]N synthetic antiferromagnet has been investigated by the spin wave resonance method over the entire range of angles of an external dc magnetic field to the film surface normal. The investigations have shown that the superlattice under study consists of two exchange-coupled magnetic subsystems, each manifested in the recorded spectra as a series of spin-wave modes. The dependence of the linear region of propagation of a standing spin-wave mode on the sample orientation in an external magnetic field has been established.

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Публикация на русском языке Спин-волновой резонанс в синтетическом антиферромагнетике [(Co0.88Fe0.12)/Cu]N [Текст] / И. Г. Важенина, Р. С. Исхаков, М. А. Миляев [и др.] // Письма в Журн. техн. физ. - 2020. - T. 46 Вып. 21. - С. 28-31

Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Ural Branch, MN Mikheev Inst Met Phys, Ekaterinburg 620108, Russia.

Доп.точки доступа:
Vazhenina, I. G.; Важенина, Ирина Георгиевна; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Milyaev, M. A.; Naumova, L. I.; Rautskii, M. V.; Рауцкий, Михаил Владимирович; Ministry of Science and Higher Education of the Russian Federation [AAAA-A18-118020290104-2]; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [20-42-660018]
}
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12.

    Ferromagnetic resonance study of biogenic ferrihydrite nanoparticles: spin-glass state of surface spins / S. V. Stolyar, D. A. Balaev, V. P. Ladygina [et al.] // JETP Letters. - 2020. - Vol. 111, Is. 3. - P. 183-187, DOI 10.1134/S0021364020030145. - Cited References: 41. - This work was supported by the Russian Foundation for Basic Research, project no. 18-02-40137.This work was supported by the Russian Foundation for Basic Research, by the Government of Krasnoyarsk krai, by the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 19-42-240012 r_a “Magnetic Resonance in Ferrihydrite Nanoparticles: Effects Associated with the Core-Shell Structure”), and by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3). . - ISSN 0021-3640. - ISSN 1090-6487
Рубрики:
MAGNETIC-PROPERTIES
   NIO NANOPARTICLES
   TRANSITION
   ANISOTROPY
Аннотация: Ferrihydrite nanoparticles (2–3 nm in size), which are products of the vital activity of microorganisms, are studied by the ferromagnetic resonance method. The “core” of ferrihydrite particles is ordered antiferromagnetically, and the presence of defects leads to the appearance of an uncompensated magnetic moment in nanoparticles and the characteristic superparamagnetic behavior. It is established from the ferromagnetic resonance data that the field dependence of the frequency is described by the expression 2πν/γ = HR + H A(T=0) (1 − T/T*), where γ is the gyromagnetic ratio, HR is the resonance field, HA ≈ 7 kOe, and T* ≈ 50 K. The induced anisotropy HA is due to the spin-glass state of the near-surface regions.

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Публикация на русском языке Исследование наночастиц биогенного ферригидрита методом ферромагнитного резонанса: спин-стекольное состояние поверхностных спинов [Текст] / С. В. Столяр, Д. А. Балаев, В. П. Ладыгина [и др.] // Письма в ЖЭТФ. - 2020. - Т. 111 Вып. 3. - С. 197-202

Держатели документа:
Russian Acad Sci, Fed Res Ctr KSC, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Fed Res Ctr KSC, Siberian Branch, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Balaev, D. A.; Балаев, Дмитрий Александрович; Ladygina, V. P.; Pankrats, A. I.; Панкрац, Анатолий Иванович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович
}
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13.

External electric field effect on electronic properties and charge transfer in CoI2/NiI2 spinterface / I. Melchakova [et al.] // Int. J. Quantum Chem. - 2020. - Vol. 120, Is. 3. - Ст. e26092, DOI 10.1002/qua.26092. - Cited References: 27. - Ministry of Education and Science of the Russian Federation, Grant/Award Number: 16.1455.2017/PCh; National Research Foundation of Korea, Grant/Award Number: NRF-2017R1A2B4004440; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, Grant/Award Number: 18-43-243011 . - ISSN 0020-7608. - ISSN 1097-461X

РУБ Chemistry, Physical + Mathematics, Interdisciplinary Applications + Quantum Science & Technology + Physics, Atomic, Molecular & Chemical
Рубрики:
MAGNETIC-PROPERTIES
METAL
EDGE
Кл.слова (ненормированные):
DFT -- electric field -- Hubbard correction -- spintronics -- transition metal dihalides
Аннотация: Electronic structure and spin-related properties of CoI2/NiI2 heterostructure were studied by means of density functional theory. It was shown that the electronic structure at the Fermi level can be characterized by a band gap. The effect of the external electric field on charge transfer and electronic properties of the CoI2/NiI2 interface was investigated, and it was found that band gap width depends on the strength of the applied electric field, switching its nature from semiconducting to a half-metallic one. An easy control of the electronic properties and promising spin-polarized nature of the CoI2/NiI2 spinterface allows the heterostructure to be used in spin-related applications.

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Держатели документа:
Siberian Fed Univ, Krasnoyarsk, Russia.
Kirensky Inst Phys, Krasnoyarsk, Russia.
Kyungpook Natl Univ, Dept Chem, 80 Daehak Ro, Daegu 41566, South Korea.

Доп.точки доступа:
Melchakova, I.; Мельчакова, Юлия; Kovaleva, E. A.; Ковалева, Евгения Андреевна; Mikhaleva, Natalia S.; Tomilin, F. N.; Томилин, Феликс Николаевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Kuzubov, A. A.; Кузубов, Александр Александрович; Avramov, P. V.; Аврамов, Павел Вениаминович; Ministry of Education and Science of the Russian FederationMinistry of Education and Science, Russian Federation [16.1455.2017/PCh]; National Research Foundation of KoreaNational Research Foundation of Korea [NRF-2017R1A2B4004440]; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-43-243011]
}
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14.

Thermoelectric properties of the SmCoO3 and NdCoO3 cobalt oxides / V. A. Dudnikov, A. S. Fedorov, Y. S. Orlov [et al.] // Ceram. Int. - 2020. - Vol. 46, Is. 11. - P. 17987-17991, DOI 10.1016/j.ceramint.2020.04.113. - Cited References: 41. - This study was supported by the Russian Science Foundation, project no. 16-13-00060. . - ISSN 0272-8842. - ISSN 1873-3956

РУБ Materials Science, Ceramics
Рубрики:
MAGNETIC-PROPERTIES
   SPIN
   CONDUCTIVITY
   TRANSITIONS
   LACOO3
   SITE
Кл.слова (ненормированные):
Perovskite -- Thermoelectric oxide materials
Аннотация: The thermoelectric properties of the NdCoO3 and SmCoO3 rare-earth cobalt oxides with a perovskite structure have been investigated in a wide temperature range. It is shown that, in the low-temperature region, the thermal conductivity of the compounds has a sharp maximum and the electrical conductivity of the samples increases with temperature, whereas the Seebeck coefficient behaves nonmonotonically with increasing temperature. The SmCoO3 oxide is characterized by the positive thermopower over the entire investigated range with a sharp growth in the low-temperature region, attaining the maximum value (S ≈ 1000 μV/K) near room temperature, and a further decrease. It has been established that, in the NdCoO3 oxide, the Seebeck coefficient changes its sign, which was rarely observed in the La-based compounds and is atypical of the undoped rare-earth cobalt oxides. The thermopower maximum obtained at a temperature of 450 K is 400 μV/K. The regions of the fastest growth of the thermoelectric power factor correspond to the anomalies caused by the spin transition of Со3+ ions and the dielectric–metal transition.

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Держатели документа:
Russian Acad Sci, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Krasnoyarsk Sci Ctr, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Lebedev Phys Inst, Moscow 119991, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Ioffe Inst, St Petersburg 194021, Russia.

Доп.точки доступа:
Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Fedorov, A. S.; Федоров, Александр Семенович; Orlov, Yu. S.; Орлов, Юрий Сергеевич; Solovyov, L. A.; Vereshchagin, S. N.; Gavrilkin, S. Yu; Tsvetkov, A. Yu; Gorev, M. V.; Горев, Михаил Васильевич; Novikov, S., V; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Science FoundationRussian Science Foundation (RSF) [16-13-00060]
}
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15.

Transition of metastable pyrrhotites to a stable phase state / V. V. Onufrienok, A. V. Chzhan, G. V. Bondarenko, G. Y. Yurkin // Inorg. Mater. - 2020. - Vol. 56, Is. 9. - P. 898-902, DOI 10.1134/S0020168520090137. - Cited References: 23 . - ISSN 0020-1685. - ISSN 1608-3172

РУБ Materials Science, Multidisciplinary
Рубрики:
MAGNETIC-PROPERTIES
TEMPERATURE
CHEMISTRY
Кл.слова (ненормированные):
mineral -- pyrite -- troilite -- impurity centers -- magnetization
Аннотация: Equilibrium phase relations of synthetic minerals prepared by annealing metastable iron sulfides, followed by prolonged isothermal storage in the Earth atmosphere, have been studied by X-ray diffraction. The results demonstrate that prolonged storage of synthetic pyrrhotites annealed at different temperatures makes it possible to identify metastable and stable phases of Fe and S compounds.

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Публикация на русском языке Переход метастабильных пирротинов в стабильное фазовое состояние [Текст] / В. В. Онуфриенок, А. В. Чжан, Г. В. Бондаренко, Г. Ю. Юркин // Неорган. матер. - 2020. - Т. 56 № 9. - С. 948-952

Держатели документа:
Krasnoyarsk State Agr Univ, Krasnoyarsk 660049, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Onufrienok, V. V.; Chzhan, A. V.; Bondarenko, G. V.; Yurkin, G. Yu.; Юркин, Глеб Юрьевич
}
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16.

Size effects in the formation of an uncompensated ferromagnetic moment in NiO nanoparticles / S. I. Popkov [et al.] // J. Appl. Phys. - 2019. - Vol. 126, Is. 10. - Ст. 103904, DOI 10.1063/1.5109054. - Cited References: 54. - This study was supported by the Ministry of Science and Higher Education of the Russian Federation and by the Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory, and Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project: "Magnetic Reversal of Magnetic Nanoparticles in Strong Pulsed Magnetic Fields-A New Approach to the Study of Dynamic Effects Associated with the Magnetization of Magnetic Nanoparticles," Project No. 18-42-240012. . - ISSN 0021-8979. - ISSN 1089-7550

РУБ Physics, Applied
Рубрики:
MAGNETIC-PROPERTIES
   TEMPERATURE
   SUSCEPTIBILITY
   NANOFERRIHYDRITE
Аннотация: The magnetic properties of samples of NiO nanoparticles with average sizes of 23, 8.5, and 4.5 nm were investigated. Using the magnetization curves measured in strong (up to 250 kOe) pulsed magnetic fields, the contributions of the free spin and ferromagnetic subsystems were extracted. It has been found that the ferromagnetic contribution increases with a decrease in the nanoparticle size and is proportional to the fraction of uncompensated exchange-coupled spins. It is demonstrated that the uncompensated spins form in the antiferromagnetic NiO oxide due to an increase in the fraction of surface atoms in the nanoparticles with decreasing particle size and defects in the bulk of particles.

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk Sci Ctr,Siberian Branch, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia.

Доп.точки доступа:
Popkov, S. I.; Попков, Сергей Иванович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Volochaev, M. N.; Волочаев, Михаил Николаевич; Kirillov, V. L.; Martyanov, O. N.; Balaev, A. D.; Балаев, Александр Дмитриевич; Ministry of Science and Higher Education of the Russian Federation; Russian Foundation for Basic Research, Government of the Krasnoyarsk Territory [18-42-240012]; Krasnoyarsk Territorial Foundation [18-42-240012]
}
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17.

Magnetoresistance, magnetoimpedance, magnetothermopower, and photoconductivity in silver-doped manganese sulfides / O. B. Romanova [et al.] // J. Appl. Phys. - 2019. - Vol. 125, Is. 17. - Ст. 175706, DOI 10.1063/1.5085701. - Cited References: 29. - This study was supported by the Russian Foundation for Basic Research (Project No. 18-52-00009 Bel_a). The reported study was funded by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (Project No. 18-42-240001 r_a), to the research project: "Inversion of the Sign of the Components of the Magnetoelectric Tensor on the Temperature in Films of Bismuth Garnet Ferrite Replaced by Neodymium." This study was carried out in the framework of the state task No. 3.5743.2017/6.7. . - ISSN 0021-8979. - ISSN 1089-7550

РУБ Physics, Applied
Рубрики:
MAGNETIC-PROPERTIES
RESISTIVITY
Аннотация: New multifunction materials in the AgXMn1‒XS (Х = 0.05) system have been synthesized and investigated in the temperature range of 77‒500 K in magnetic fields up to 12 kOe. Near the temperature of the magnetic transition (ТN = 176 K), the anomalous behavior of the temperature dependence of magnetization has been observed and has been attributed to the formation of ferrons. An analysis of the infrared spectroscopy data and I‒V characteristics has revealed the spin-polaron subband splitting. Several conductivity channels have been found from the impedance spectra. The temperature and magnetic field dependences of the carrier relaxation time have been obtained. The magnetoresistance (−21%), magnetoimpedance (−65%), magnetothermopower (−40%), and photoconductivity effects have been detected. The majority carrier type, density, and mobility have been determined from the Hall-effect measurement data. The observed effects have been explained using a ferron model.
Синтезированы и исследованы новые многофункциональные материалы системы AgXMn1-XS (Х=0.05) в интервале температур 77-500К в магнитных полях до 12 кЭ. В близи температуры магнитного перехода (ТN=176К) наблюдается аномальное поведение температурной зависимости намагниченности, вызванное образованием ферронов. Найдено расщепление спин-поляронной подзоны из ИК спектроскопии и вольт-амперных характеристик. Установлено несколько каналов проводимости из спектров импеданса, отличающихся частоте. Определена зависимость времени релаксации носителей заряда от температуры и магнитного поля. Обнаружено четыре эффекта: магнитосопротивление (-21%), магнитоимпеданс (-65%), магнитотермоЭДС (-40%) и фотопроводимость. Найдены: тип, концентрация и подвижность основных носителей заряда из холловских измерений. Обнаруженные эффекты объясняются в модели ферронов.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.
Siberian State Univ Sci & Technol, Dept Phys, Krasnoyarsk 660014, Russia.
Sci Pract Mat Res Ctr NAS, Minsk 220072, BELARUS.

Доп.точки доступа:
Romanova, O. B.; Романова, Оксана Борисовна; Aplesnin, S. S.; Аплеснин, Сергей Степанович; Udod, L. V.; Удод, Любовь Викторовна; Sitnikov, M. N.; Kretinin, V. V.; Yanushkevich, K. I.; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Russian Foundation for Basic Research [18-52-00009 Bel_a]; Government of Krasnoyarsk Territory; Krasnoyarsk Regional Fund of Science [18-42-240001 r_a]
}
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18.

Magnetodielectric effect in a metamaterial consisting of xerogel with embedded ε-Fe2O3 iron oxide nanoparticles / A. A. Dubrovskiy [et al.] // Solid State Commun. - 2019. - Vol. 289. - P. 27-29, DOI 10.1016/j.ssc.2018.11.020. - Cited References: 30. - This work was supported by the Russian Science Foundation, project no. 17-12-01111. . - ISSN 0038-1098. - ISSN 1879-2766

РУБ Physics, Condensed Matter
Рубрики:
MAGNETIC-PROPERTIES
   HIGH-TEMPERATURE
   PHASE
   RAMAN
Аннотация: The ε-Fe2O3 iron oxide is a fairly rare polymorphic modification, which only exists in the form of nanoparticles embedded, as a rule, into a silica gel matrix. This magnetically ordered iron oxide, which exhibits a significant room-temperature coercivity, is a ferroelectric; therefore, the magnetoelectric and magnetodielectric properties of this material evoke keen interest. In this work, we investigate the magnetodielectric (MD) effect in a metamaterial consisting of xerogel SiO2 with embedded ε-Fe2O3 nanoparticles 9 nm in size on average in a concentration of 20 mass.%. This bulk material exhibits the MD effect in a wide temperature range. The temperature behavior of the permittivity is related to the magnetic state of the ε-Fe2O3 oxide, which undergoes the magnetic transition from the magnetically hard to magnetically soft phase in the temperature range of 80–150 K, indicating the interplay of the ε-Fe2O3 magnetic and charge subsystems.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Kiresnky Inst Phys, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia.

Доп.точки доступа:
Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Yakushhkin, S. S.; Kirillov, V. L.; Martyanov, O. N.; Russian Science Foundation [17-12-01111]
}
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19.

Study of mixed-valence Mn2BO4 using XRD, XPS and XAFS spectroscopies / N. V. Kazak [et al.] // Physica B. - 2019. - Vol. 560. - P. 228-235, DOI 10.1016/j.physb.2019.02.019. - Cited References: 39. - This work has been financed by Russian Foundation for Basic Research (17-02-00826 and 16-32-60049 grant numbers). . - ISSN 0921-4526. - ISSN 1873-2135

РУБ Physics, Condensed Matter
Рубрики:
SPIN-GLASS BEHAVIOR
MAGNETIC-PROPERTIES
PROFILE REFINEMENT
Кл.слова (ненормированные):
Charge-ordering -- Mixed-valence -- XAS -- XRD -- XPS
Аннотация: The valence states and local structure around Mn atoms in mixed-valence Mn2BO4 have been studied by temperature dependent X-ray powder diffraction (XRPD), X-ray photoelectron (XPS) and Mn K-edge X-ray absorption (XAFS) spectroscopies measurements. X-ray absorption near-edge structure (XANES) and XPS have been used to measure the average oxidation state of Mn in bulk and near-surface of the material. The edge position, peak shapes and pre-edge features of Mn K-edge XANES spectra have been discussed. The pronounced temperature dependence of the Debye-Waller (DW) factor corresponding to the MnO coordination shell has been found from the extended x-ray absorption fine structure (EXAFS) analysis and has been associated with variations in the local distortions in MnO6 octahedra and emergence of short-range magnetic correlations at low temperatures. The XRPD measurements have been carried out at 298, 523 and 773 K. The monoclinic symmetry (P21/n) was found to persist up to highest temperature measured. The BVS calculations have revealed large valence difference between two manganese sites that strongly supports the presence of charge ordering up to high temperatures.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Fed Res Ctr KSC SB RAS, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.
Natl Res Ctr, Kurchatov Inst, Moscow 123182, Russia.

Доп.точки доступа:
Kazak, N. V.; Казак, Наталья Валерьевна; Platunov, M. S.; Платунов, Михаил Сергеевич; Knyazev, Yu. V.; Князев, Юрий Владимирович; Moshkina, E. M.; Мошкина, Евгения Михайловна; Solovyov, L. A.; Vereshchagin, S. N.; Mikhlin, Yu. L.; Veligzhanin, A. A.; Trigub, A. L.; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Foundation for Basic Research [17-02-00826, 16-32-60049]
}
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20.

Growth of Textured Au-Fe/Fe Hybrid Nanocrystals on Oxidized Silicon Surface / I. A. Tarasov [et al.] // Semiconductors. - 2018. - Vol. 52, Is. 16. - P. 2073-2077, DOI 10.1134/S1063782618160364. - Cited References: 19. - The reported research was funded by Russian Foundation for Basic Research and the government of the region of the Russian Federation, grant no. 18-42-243013, the Program of the President of the Russian Federation for the support of young scientist (C Pi-2796.2018.1). We also thank L.A. Solovyov for his asistance in XRD analysis. . - ISSN 1063-7826. - ISSN 1090-6479

РУБ Physics, Condensed Matter
Рубрики:
INTERMETALLIC AU3FE1-X
MAGNETIC-PROPERTIES
FECU NANOPARTICLES
Аннотация: We present in this report the route to produce highly-textured Au3Fe(111)/Fe(110) hybrid nanocrystals on an amorphous surface of SiO2/Si by molecular beam epitaxy. By controlling the quantity of Au atoms deposited onto the SiO2/Si it is possible to tune the average lateral size of resultant Au-Fe hybrid nanocrystals from 10-20 nm up to 100-150 nm at the same Fe nominal thickness deposited. This process is sensitive to the initial density and size of Au islands. Examination of Au-Fe hybrid nanocrystals obtained was carried out using X-ray diffraction, transmission and scanning electron microscopy, reflection high energy electron diffraction, and Kerr effect methods.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Krasnoyarsk State Agr Univ, Achinsk Branch, Achinsk 662150, Russia.
Russian Acad Sci, Fed Res Ctr KSC, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Tarasov, I. A.; Тарасов, Иван Анатольевич; Smolyarova, T. E.; Смолярова, Татьяна Евгеньевна; Yakovlev, I. A.; Яковлев, Иван Александрович; Kosyrev, N. N.; Косырев, Николай Николаевич; Komarov, V. A.; Комаров, Василий Андреевич; Nemtsev, I. V.; Varnakov, S. N.; Варнаков, Сергей Николаевич; Patrin, G. S.; Патрин, Геннадий Семёнович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Russian Foundation for Basic Research; government of the region of the Russian Federation [18-42-243013]; Russian Federation [CPi-2796.2018.1]; International Symposium "Nanostructures: Physics and Technology"(26th ; June 18-22, 2018 ; Minsk, Belarus)
}
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