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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Isakova V. G., Osipova I. V., Dudnik A. I., Cherepakhin A. V., Zharikova N. V., Nemtsev I. V., Volochaev M. N.
Заглавие : Decoration of carbon nanomaterial powders with dispersed platinum metal particles
Коллективы : Center for Shared Use of the Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences
Место публикации : Russ. J. Appl. Chem. - 2018. - Vol. 91, Is. 7. - P.1209-1216. - ISSN 1070-4272, DOI 10.1134/S1070427218070212. - ISSN 1608-3296(eISSN)
Примечания : Cited References: 22. - The study was performed with the support and equipment of the Center for Shared Use of the Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences.
Предметные рубрики: NANOPARTICLES
PALLADIUM
FULLERENE
ELECTRODE
NANOTUBES
OXIDATION
Ключевые слова (''Своб.индексиров.''): carbon nanomaterials--platinum metal nanoparticles--in situ one-step method
Аннотация: Carbon nanomaterials (fullerite, detonation nanodiamonds, Taunit, fullerenol, fullerene-containing black) were decorated with platinum group metal nanoparticles in situ in one step by low-temperature combustion (~250–270°С) of a powdered mixture of platinum metal acetylacetonate [Pt-M(асас)n, Pt-М = Pt(II), Pd(II), Rh(III), Ir(III), acac = CH3COCHCOCH3, n is the oxidation state of Pt-М] with carbon nanomaterials in air. As shown by thermal analysis, the process is based on thermal oxidative degradation of the organometallic complex, catalyzed by carbon nanomaterials, with oxidation (combustion) of the organic moiety and release of the metal into the condensed phase. The thermal process in an open system occurs in the glowing mode (210–250°С); the size of the nanoparticles formed is 7–30 nm. Under the conditions restricting the air access to the reaction mixture and free outflow of gaseous products formed by oxidation of acac ligands, the nanoparticle size decreases to 3–10 nm. The particle size depends on the metal amount in the initial powder mixture and on the support morphology.
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2.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Smolyarova T. E., Lukyanenko A. V., Tarasov A. S., Sokolov A. Е.
Заглавие : Dip-Pen Nanolithography method for fabrication of biofunctionalized magnetic nanodiscs applied in medicine
Коллективы : International Symposium on Nanostructures - Physics and Technology , Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [17-42-240080, 16-42-243046, 16-42-242036]; Russian Federation [NSh-7559.2016.2]
Место публикации : Semiconductors. - 2018. - Vol. 52: 25th International Symposium on Nanostructures - Physics and Technology (Jun 26-30, 2017, Saint Petersburg, Russia), Is. 5. - P.675-677. - ISSN 1063-7826, DOI 10.1134/S1063782618050305. - ISSN 1090-6479(eISSN)
Примечания : Cited References:22. - The study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research project nos. 17-42-240080, 16-42-243046, 16-42-242036 and the Grant of the President of the Russian Federation no. NSh-7559.2016.2.
Предметные рубрики: DRUG-DELIVERY
FORCE MICROSCOPY
NANOPARTICLES
HYPERTHERMIA
THERAPY
Аннотация: The magnetic properties of ferromagnetic nanodiscs coated with gold, manufactured using the Dip-Pen Nanolithography method, and were studied by atomic-force and magnetic force microscopy methods. The magnetic discs (dots) are represented as nanoagents (nanorobots) applied in medicine for the cancer cell destruction. The motivation of this work stem from the necessity of the understanding of the magnetization distribution in ferromagnetic discs that is crucial for their application in biomedicine. We have performed the theoretical calculations in order to compare the theoretical image contrast to experimental results. Herein, we report about the fabrication and analysis of biocompatible ferromagnetic nanodiscs with the homogenous magnetized state.
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Poperechny I. S., Krasikov A. A., Shaikhutdinov K. A., Dubrovskiy A. A., Popkov S. I., Balaev A. D., Yakushkin S. S., Bukhtiyarova G. A., Martyanov O. N., Raikher, Yu. L.
Заглавие : Dynamic magnetization of ε-Fe2O3 in pulse field: Evidence of surface effect
Место публикации : J. Appl. Phys.: American Institute of Physics, 2015. - Vol. 117, Is. 6. - Ст.063908. - ISSN 0021, DOI 10.1063/1.4907586. - ISSN 10897550(eISSN)
Примечания : Cited References:30. - The work was supported by RFBR Grant Nos. 14-02-96002 and 12-02-00897, and project MIG S26/617 from the Ministry of Education and Science of Perm Region.
Предметные рубрики: FERROMAGNETIC-RESONANCE
COERCIVE FIELD
NANOPARTICLES
ANISOTROPY
Аннотация: The magnetization dynamics of ε-Fe2O3 nanoparticles with an average size of about 9 nm is investigated. From comparison of the hysteresis loops obtained in quasi-static conditions and under pulse fields with amplitudes up to 200 kOe and pulse lengths 8–32 ms, it follows that the effective coercivity increases considerably with the variation rate of the imposed magnetic field. A theoretical explanation of this behavior is proposed. The model takes into account the superparamagnetic effects as well as the fact that magnetic anisotropy of the nanoparticles, along with the bulk term, includes a surface contribution. The latter, being of minor importance for the observed magnetic behavior of 25–100 nm particles, becomes essential when the particle size is below 10 nm. From the experimental data, a reference value of the surface anisotropy of nanodisperse ε-Fe2O3 is established, and evidence is presented to the effect that below 300 K this contribution does not significantly depend on temperature.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Moseenkov S. I., Kuznetsov V. L., Zavorin A. V., Golubtsov G. V., Korovin, E. Yu., Suslyaev V. I., Ishchenko A. V., Serkova A. N., Sergeenko D. I., Velikanov D. A.
Заглавие : Electrophysical properties of composites based on polyethylene modified with multi-walled carbon nanotubes with high content of Fe-Co-catalyst
Коллективы : Russian Science FoundationRussian Science Foundation (RSF) [17-73-20293]
Место публикации : Russ. J. Appl. Chem. - 2020. - Vol. 93, Is. 4. - P.586-594. - ISSN 1070-4272, DOI 10.1134/S107042722004014X. - ISSN 1608-3296(eISSN)
Примечания : Cited References: 30. - This work was financially supported by the Russian Science Foundation, project no. 17-73-20293.
Предметные рубрики: POLYMER COMPOSITES
NANOPARTICLES
ACTIVATION
NANOCOMPOSITES
Аннотация: The effect of the residual catalyst for the synthesis of multi-walled carbon nanotubes (MWCNTs) on the electrophysical properties of MWCNT-polyethylene composites produced by melt mechanical mixing was studied. The residual catalyst content was varied by changing the MWCNTs synthesis time. The nanotubes used in the work were characterized using transmission and scanning electron microscopy, atomic emission analysis, X-ray phase analysis, and magnetic permeability measurements. The structure of the synthesized composites was studied using optical and scanning electron microscopy. The dependences of the specific magnetization on the applied magnetic field, bulk electrical conductivity on the volumetric content of the filler in the composite, and the frequency dependences of the reflection, transmission, and absorption of electromagnetic radiation in the range 0.01-18 GHz were obtained. It was established that the obtained composites are characterized by a uniform distribution of nanotubes in the polymer matrix, and the dependence of the bulk electrical conductivity on the content of MWCNTs in the composite has a percolation character. Variation in the synthesis time of nanotubes allows producing MWCNTs with a high content of ferromagnetic particles, which are an alloy close in stoichiometry to the composition of the active component of the catalyst. It was shown that the use of composites modified with MWCNTs with a high content of residual catalyst is more effective for absorbing electromagnetic radiation due to an increase in their magnetic losses.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova O. S., Ivantsov R. D., Edelman I. S., Petrakovskaja E. A., Velikanov D. A., Zubavichus Y. V., Zaikovskii V .I., Stepanov S. A.
Заглавие : Identification of ε-Fe2O3 nano-phase in borate glasses doped with Fe and Gd
Место публикации : J. Magn. Magn. Mater.: Elsevier, 2016. - Vol. 401. - P.880-889. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2015.10.126
Примечания : Cited References: 40. - This work was supported partly by the Russian Foundation for Basic Research, Grants No 14-02-01211-a and by the President of Russia Grant No. NSh-2886.2014.2. Authors are grateful to G.A. Bukhtiyarova and U.N. Martyanov for the assistance in the ε-Fe2O3 nanoparticles prepared by a wet chemical pore filling impregnation method and for the discussion of the obtained results
Предметные рубрики: MAGNETIC-PROPERTIES
IRON-OXIDE
NANOPARTICLES
CERAMICS
CRYSTAL
PARTICLES
SURFACE
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--ε-fe2o3--magnetic circular dichroism--electron magnetic resonance
Аннотация: A new type of magnetic nanoparticles was revealed in borate glasses co-doped with low contents of iron and gadolinium. Structure and magnetic properties of the particles differ essentially from that of the α-Fe2O3, γ-Fe2O3, or Fe3O4 nanoparticles which were detected earlier in similar glass matrices. Transmission electron microscopy including STEM-HAADF and EDX, synchrotron radiation-based XRD, static magnetic measurements, magnetic circular dichroism, and electron magnetic resonance studies allow referring the nanoparticles to the iron oxide phase-ε-Fe2O3. Analysis of the data set has shown that it is Gd atoms that govern the process of nanoparticles' nucleation and its incorporation into the particles in different proportions can be used to adjust their magnetic and magneto-optical characteristics. © 2015 Elsevier B.V.
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6.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Bulgakov E. N., Maksimov D. N.
Заглавие : Light guiding above the light line in arrays of dielectric nanospheres
Место публикации : Opt. Lett.: Optical Society of America, 2016. - Vol. 41, Is. 16. - P.3888-3891. - ISSN 01469592 (ISSN), DOI 10.1364/OL.41.003888
Примечания : Cited References: 46. - Russian Foundation for Basic Research (RFBR) (16-02-00314).
Предметные рубрики: SUBWAVELENGTH WAVE-GUIDES
OPTICAL MODES
NANOPARTICLES
CHAINS
RESONANCES
PARTICLES
SPHERES
Аннотация: We consider light propagation above the light line in arrays of spherical dielectric nanoparticles. It is demonstrated numerically that quasi-bound leaky modes of the array can propagate both stationary waves and light pulses to a distance of 60 wavelengths at the frequencies close to the bound states in the radiation continuum. A semi-analytical estimate for decay rates of the guided waves is found to match the numerical data to a good accuracy. © 2016 Optical Society of America.
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7.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Komogortsev S. V., Iskhakov R. S., Zimin A. A., Filatov E. Y., Korenev S. V., Shubin Y. V., Chizhik N. A., Yurkin G.Yu., Eremin E. V.
Заглавие : Magnetic anisotropy and order parameter in nanostructured CoPt particles
Коллективы : RFBR [11-03-00168-a, 12-02-00943-a]; Interdisciplinary integration of fundamental research of SB RAS [64]; Russian Federation [MK-1934.2013.3]
Место публикации : Appl. Phys. Lett.: American Institute of Physics, 2013. - Vol. 103, Is. 15. - Ст.152404. - P. - ISSN 0003-6951, DOI 10.1063/1.4824973
Примечания : Cited References: 36. - The authors are grateful to Dr. A. V. Zadesenets for synthesis of CoPt complex precursor and Dr. A. S. Bogomyakov for assistance in magnetic measurements. The work was supported by RFBR (Grant Nos. 11-03-00168-a and 12-02-00943-a), Interdisciplinary integration of fundamental research of SB RAS (2012-2014) project No. 64, and grant of the President of the Russian Federation (No. MK-1934.2013.3).
Предметные рубрики: FEPT THIN-FILMS
REMANENT MAGNETIZATION
UNIAXIAL ANISOTROPIES
FINE PARTICLES
NANOPARTICLES
FERROMAGNETS
PHASE
Аннотация: The correlation of magnetic anisotropy energy with order parameter in the crystallites of CoPt nanostructured particles prepared by thermal decomposition and further annealing has been studied by investigation of the approach magnetization to saturation curves and x-ray powder diffraction pattern profiles. It is shown that magnetic anisotropy energy value in partially ordered CoPt crystallite could be described as an intermediate case between two extremes, corresponding to either single or several c-domains of L1(0) phase in crystallite. (C) 2013 AIP Publishing LLC.
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8.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Raikher Y. L., Stepanov V. I., Stolyar S. V., Ladygina V. P., Balaev D. A., Ishchenko L. A., Balasoiu M.
Заглавие : Magnetic properties of biomineral particles produced by bacteria Klebsiella oxytoca
Коллективы :
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 2. - P298-305. - ISSN 1063-7834, DOI 10.1134/S1063783410020125
Примечания : Cited References: 29. - This study was supported by the Russian Foundation for Basic Research (project nos. 07-02-96026, 07- 02-96017, and 08-02-00802) and performed within the framework of the Federal Target Program "Research and Research-Pedagogical Personnel of Innovation Russia for 2009-2013."
Предметные рубрики: FERRITIN
NANOPARTICLES
IRON
SUSCEPTIBILITY
FERRIHYDRITE
BEHAVIOR
FINS
Аннотация: Ferrihydrite nanoparticles (2-5 nm in size) produced by bacteria Klebsiella oxytoca in the course of biomineralization of iron salt solutions from a natural medium exhibit unique magnetic properties: they are characterized by both the antiferromagnetic order inherent in a bulk ferrihydrite and the spontaneous magnetic moment due to the decompensation of spins in sublattices of a nanoparticle. The magnetic susceptibility enhanced by the superantiferromagnetism effect and the magnetic moment independent of the magnetic field provide the possibility of magnetically controlling these natural objects. This has opened up the possibilities for their use in nanomedicine and bioengineering. The results obtained from measurements of the magnetic properties of the ferrihydrite produced by Klebsiella oxytoca in its two main crystalline modifications are reported, and the data obtained are analyzed theoretically. This has made it possible to determine numerical values of the magnetic parameters of real biomineral nanoparticles.
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Belyaev B. A., Izotov A. V., Leksikov An. A.
Заглавие : Micromagnetic calculation of the equilibrium distribution of magnetic moments in thin films
Коллективы :
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2010. - Vol. 52, Is. 8. - P1664-1672. - ISSN 1063-7834, DOI 10.1134/S1063783410080160
Примечания : Cited References: 17. - This study was supported by the Council on Grants from the President of the Russian Federation (grant no. 3818.2008.3), the Siberian Branch of the Russian Academy of Sciences (integration project no. 5), the Presidium of the Russian Academy of Sciences (project no. 27.1), and the Ministry of Education and Science of the Russian federation (state contract nos. 02.740.11.0220 and 02.740.11.0568.
Предметные рубрики: SIMULATIONS
ANISOTROPY
NANOPARTICLES
MODES
Аннотация: A new approach has been proposed for determining an equilibrium configuration of magnetic moments in condensed matter in terms of its discrete model. The solution to this problem is reduced to a system of linear inhomogeneous equations with undetermined Lagrange multipliers. The possibility of numerically solving these systems has been shown using a modified power method. The efficiency of the method has been demonstrated for the model of a thin magnetic film with a nonuniform distribution of the uniaxial magnetic anisotropy over the area. The dependence of the coercive force on the uniaxial anisotropy of nanocrystallites, their exchange interaction, and other parameters of samples has been investigated.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shaykhutdinov K. A., Balaev D. A., Semenov S. V., Popkov S. I., Dubrovskiy A. A., Sapronova N. V., Volkov N. V.
Заглавие : Relaxation of low-temperature magnetoresistance and magnetization of polycrystalline (La0.5Eu0.5)(0.7)Pb0.3MnO3
Разночтения заглавия :авие SCOPUS: Relaxation of low-temperature magnetoresistance and magnetization of polycrystalline (La 0.5Eu 0.5) 0.7Pb 0.3MnO 3
Место публикации : J. Phys. D. - 2011. - Vol. 44, Is. 25. - Ст.255001. - ISSN 0022-3727, DOI 10.1088/0022-3727/44/25/255001
Примечания : Cited References: 34. - This work was partially supported by the Lavrentyev Competition of the Young Scientist's Projects of the Siberian Branch of the Russian Academy of Sciences, Project No 12. The authors are grateful to A D Balaev and V M Sosnin for useful discussions on the results.
Предметные рубрики: INSULATOR-METAL TRANSITION
GRANULAR FILMS
NANOPARTICLES
PR0.7CA0.3MNO3
PERCOLATION
MANGANITES
Ключевые слова (''Своб.индексиров.''): antiferromagnetic boundaries--characteristic value--ferromagnetic domains--ferromagnetic metal--lanthanum manganites--logarithmic law--low temperatures--magneto-resistive effect--polycrystalline--relative orientation--relaxation of magnetization--temperature fluctuation--time evolutions--time interval--tunnel magnetoresistance--antiferromagnetism--electric resistance--europium--ferromagnetic materials--ferromagnetism--grain boundaries--grain size and shape--lanthanum compounds--lead--magnetic domains--magnetic moments--magnetoelectronics--magnetoresistance--manganese oxide--magnetization
Аннотация: Hysteresis and relaxation of magnetoresistance and magnetization of substituted (La0.5Eu0.5)(0.7)Pb0.3MnO3 lanthanum manganite in a low-temperature region ( 40 K) are investigated. It is shown that at these temperature features of the magnetoresistive effect are determined mainly by spin-dependent tunnelling of carriers via insulating grain boundaries. As was demonstrated previously, the grain boundaries may be antiferromagnetically ordered. Therefore, relaxation of magnetization and resistance is determined by the processes of relative orientation of the magnetic moments of ferromagnetic domains neighbouring the antiferromagnetic boundary of ferromagnetic domains under the action of temperature fluctuations. It is shown that relaxation follows the logarithmic law within the time interval t similar to 10(2)-3x10(3) s. A comparison between time evolutions of the magnetic moment and resistance shows that magnetoresistance and magnetization are related as delta R
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