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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zamkova N. G., Zinenko V. I.
Заглавие : Lattice dynamics of ionic crystals in a model of "breathing" and polarizable ions
Место публикации : Phys. Solid State: AMER INST PHYSICS, 1998. - Vol. 40, Is. 2. - P320-324. - ISSN 1063-7834, DOI 10.1134/1.1130302
Примечания : Cited References: 14
Предметные рубрики: OXIDE
Аннотация: An expression is written down for the dynamic matrix of ionic crystals in terms of a microscopic, parameterless model of "breathing" and polarizable ions. Results from a calculation of the complete spectrum of the lattice vibrations of ionic crystals having an NaCl structure are presented as an illustration. (C) 1998 American Institute of Physics.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova N. B., Kazak N. V., Michel C. R., Balaev A. D., Ovchinnikov S. G.
Заглавие : Low-temperature magnetic behavior of the rare-earth cobaltites GdCoO3 and SmCoO3
Разночтения заглавия :авие SCOPUS: Low-temperature magnetic behavior of the rare-earth cobaltites GdCoO 3 and SmCoO3
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 11. - P2126-2131. - ISSN 1063-7834, DOI 10.1134/S1063783407110182
Примечания : Cited References: 32. - This study was supported by the Branch of General Physics and Astronomy of the Russian Academy of Sciences within the framework of the program “Strong Electron Correlations” and the Russian Science Support Foundation
Предметные рубрики: METAL-INSULATOR-TRANSITION
RCOO3 R
SPIN-STATE
OXIDE
SM
ND
PEROVSKITE
GLASSES
PR
EU
Аннотация: The temperature and magnetic field dependences of the static magnetization of the polycrystalline rare-earth cobaltites GdCoO3 and SmCoO3 have been measured. It is shown that, below room temperature, the magnetization of both compounds derives primarily from the rare-earth ion paramagnetism. The GdCoO3 and SmCoO3 compounds have been found to differ substantially in magnetic behavior, which can be traced to differences in their electronic shell structures. The magnetic behavior of GdCoO3 is close to that of an array of free Gd3+ ions, whereas in SmCoO3 the deviation from the free-ion properties is very large because of the Sm3+ ground state being crystal-field split. Van Vleck magnetic susceptibility measurements of SmCoO3 suggest that the splitting is similar to 10 K.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova N. B., Kazak N. V., Michel C. R., Balaev A. D., Ovchinnikov S. G., Vasil'ev A. D., Bulina N. V., Panchenko E. B.
Заглавие : Effect of strontium and barium doping on the magnetic state and electrical conductivity of GdCoO3
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 8. - P1498-1506. - ISSN 1063-7834, DOI 10.1134/S1063783407080161
Примечания : Cited References: 36
Предметные рубрики: PEROVSKITE
ORDER
OXIDE
BEHAVIOR
GLASSES
LACOO3
PR
GD
SM
ND
Аннотация: A coordinated investigation of the magnetic and electrical properties of polycrystalline cobalt oxide compounds CdCoO3, Gd0.9Ba0.1CoO3, and Gd0.9Sr0.1CoO3 is carried out. Undoped GdCoO3 reveals a low conductivity; a magnetic moment of 7.4 mu(B) per molecule, which is less than the theoretical value for the Gd3+ ion; and an asymptotic Curie temperature of -6 K. Doping GdCoO3 with barium and strontium to substitution of 10 at. % Gd brings about an increase in the conductivity and magnetic transitions at T = 300 K for Gd0.9Ba0.1CoO3 and T = 170 K for Gd0.9Sr0.1CoO3. The magnetization anomalies imply the formation of magnetic clusters. The behavior of the electrical conductivity at high temperatures suggests a variable activation energy. At low temperatures, Mott hopping conduction sets in.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Malakhovskii A. V., Sokolov A. E., Temerov V. L., Bezmaternykh L. N., Sukhachev A. L., Seredkin V. A., Gnatchenko S. L., Kachur I. S., Piryatinskaya V. G.
Заглавие : Polarized absorption spectra and spectroscopic parameters of Tm3+ in the TmAl3(BO3)(4) single crystal
Разночтения заглавия :авие SCOPUS: Polarized absorption spectra and spectroscopic parameters of Tm 3+ in the TmAl3(BO3)4 single crystal
Место публикации : Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2008. - Vol. 50, Is. 7. - P1287-1293. - ISSN 1063-7834, DOI 10.1134/S1063783408070159
Примечания : Cited References: 36
Предметные рубрики: RARE-EARTH IONS
ELECTRONIC ENERGY LEVELS
DIODE-PUMPED LASER
OPTICAL-ABSORPTION
ALUMINUM GARNET
MU-M
INTENSITIES
FLUORESCENCE
GLASSES
OXIDE
Аннотация: High-optical-quality single crystals of the TmAl3(BO3)(4) compound were synthesized from a solution in the melt. The absorption spectra in the sigma and pi polarizations for the H-3(6) - F-3(4), H-3(6) - H-3(5), H-3(6) - H-3(4), H-3(6) - F-3(3), H-3(6) - F-3(2), H-3(6) - (1)G(4), and H-3(6) - D-1(2) transitions in the Tm3+ ion were recorded at room temperature. The transition intensities were analyzed in the framework of the Judd-Ofelt theory generalized to the case of anisotropic crystals, and the following parameters of the theory were obtained: Omega(2) = 6.14 x 10(-20) cm(2), Omega(4) = 3.09 x 10(-20) cm(2), and Omega(6) = 2.04 x 10(-20) cm(2). The lifetimes and the branching ratios were determined for all possible transitions.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Yakushkin S. S., Dubrovskiy A. A., Balaev A. D., Shaykhutdinov K. A., Bukhtiyarova G. A., Martyanov O. N.
Заглавие : Magnetic properties of few nanometers ɛ-Fe2O3 nanoparticles supported on the silica
Место публикации : J. Appl. Phys.: American Institute of Physics, 2012. - Vol. 111, Is. 4. - Ст.44312. - ISSN 0021-8979, DOI 10.1063/1.3686647
Примечания : Cited References: 27. - authors thank A. D. Balaev and N. V. Volkov for fruitful discussions and comments. This work was supported by Program of RAS No. 27.46.
Предметные рубрики: HIGH-TEMPERATURE
IRON
STABILIZATION
OXIDE
GEL
Аннотация: Magnetic properties of ɛ-Fe2O3nanoparticles supported on silica with the average size of few nanometers, narrow size distribution and no admixture of any other iron oxide polymorphs are investigated. The investigation of the temperature behavior of magnetization within the temperature range from 4.2 to 1000 K revealed the presence of several magnetic subsystems in the species under study. The temperatures’ behavior of the magnetic moment value indicates ferrimagnetic ordering in the ɛ-Fe2O3nanoparticles with a Curie temperature of about 800 K and points to the existence of a significant paramagnetic contribution becoming apparent at low temperatures. According to the electron spin resonance data, the particles possess superparamagnetic behavior at temperature higher ∼120 K. The model of the magnetic structure of monophase system of few nanometers ɛ-Fe2O3nanoparticles supported on silica is proposed.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Balaev D. A., Bulavchenko O. A., Dubrovskii A. A., Tsybulya S. V., Cherepanova S. V., Gerasimov E. Y., Shaikhutdinov K. A.
Заглавие : Features of the structure, microstructure, and magnetic properties of manganese-aluminum spinels obtained in various thermal treatment conditions
Место публикации : Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2013. - Vol. 55, Is. 7. - P.1401-1406. - ISSN 1063-7834, DOI 10.1134/S1063783413070056
Примечания : Cited References: 18. - This study was supported by the Russian Foundation for Basic Research (project no. 12-03-90839-mol_rf_nr) and the Ministry of Education and Science of the Russian Federation (agreement no. 8429).
Предметные рубрики: A-SITE SPINELS
CATALYSTS
OXIDE
MN3O4
Аннотация: The structural, microstructural, and magnetic properties of aluminum-manganese oxide in the ratio Mn: Al = 1: 1 in the well-crystallized and nanoheterogeneous states have been investigated. This oxide is obtained under various thermal treatment conditions and at different partial pressures of oxygen. The composition and cation distribution of the manganese and aluminum ions in spinel sites are determined. It is shown that the studied compound is a ferrimagnet with the Curie point T (C) a parts per thousand 26 K.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Tambasov I. A., Bayukov O. A., Zhigalov V. S., Bykova L. E., Mikhlin Yu. L., Volochaev M. N., Bondarenko G. N.
Заглавие : Solid state synthesis and characterization of ferromagnetic nanocomposite Fe-In2O3 thin films
Место публикации : J. Alloys Compd.: Elsevier Science, 2014. - Vol. 612. - P.189-194. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2014.05.176. - ISSN 1873-4669
Примечания : Cited References: 56
Предметные рубрики: HIGH-TEMPERATURE FERROMAGNETISM
PHASE-FORMATION
In2O
OXIDE
NANOPARTICLES
CO
SEMICONDUCTORS
NANOCRYSTALS
COMBUSTION
SYSTEMS
Ключевые слова (''Своб.индексиров.''): thermite reactions--reactive films--ferromagnetic nanocomposite films--transparent conducting oxides
Аннотация: We have successfully synthesized ferromagnetic Fe-In2O 3 nanocomposite thin films for the first time using the thermite reaction Fe2O3 + In = In2O3 + Fe. The initial In/Fe2O3 bilayers were obtained by the deposition of In layers on α-Fe2O3 films. The reaction occurs in a self-propagating mode in a homogeneous thermal film plane field at heating rates above 20 K/s and at temperatures above initiation temperature T[[d]]in[[/d]] ~ 180 °C. At heating rates lower than 20 K/s the mixing of the In and Fe2O3 layers occurs across the whole In/Fe2O3 interface and the synthesis of the ferromagnetic α-Fe phase starts above the initiation temperature T[[d]]in[[/d]] = 180 °C. X-ray diffraction, X-ray photoelectron spectroscopy, Mossbauer spectroscopy, transmission electron microscopy and magnetic measurements were used for phase identification and microstructure observation of the synthesized Fe-In2O3 samples. The reaction products contain (1 1 0) textured α-Fe nanocrystals with a diameter around 100 nm and surrounded by an In2O3 matrix. These results enable new efficient low-temperature methods for synthesizing ferromagnetic nanocomposite films containing ferromagnetic nanoclusters embedded in transparent conducting oxides. © 2014 Elsevier B.V. All rights reserved.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Smirnov M. B., Roginskii E. M., Kazimirov V. Y., Smirnov K. S., Baddour-Hadjean R., Pereira-Ramos J. P., Zhandun V. S.
Заглавие : Spectroscopic and computational study of structural changes in γ-LiV2O5 cathodic material induced by lithium intercalation
Место публикации : J. Phys. Chem. C: American Chemical Society, 2015. - Vol. 119, Is. 36. - P.20801-20809. - ISSN 1932-7447, DOI 10.1021/acs.jpcc.5b05540
Примечания : Cited References: 36. - This work was supported by the international collaboration program between the Centre National de la Recherche Scientifique (CNRS) of France and the Russian Foundation for Basic Research (RFBR), LIBASTRAM CNRS Project 6094, and RFBR Grant 13-03-91052.
Предметные рубрики: AUGMENTED-WAVE METHOD
LIXV2O5 SYSTEM
AB-INITIO
VANADIUM PENTOXIDE
RAMAN-SPECTROSCOPY
LI INTERCALATION
OXIDE
V2O5
TRANSITION
TRANSITION
Аннотация: Structure, electronic states, and vibrational dynamics of γ-LiV2O5 were studied by combined use of quantum-chemical calculations and Raman spectroscopy. The spin-polarized DFT+U calculations correctly mimic the structural changes induced by the Li intercalation into the V2O5 framework. The analysis of the density of electronic states shows that the electrons of Li atoms are transferred to the Vb atoms and are aligned in ferromagnetic order. The charge distribution in the system reflects the change of valence state of the Vb atoms from 5+ to 4+, and it is in line with changes of Vb–O bond lengths. The calculated Raman spectrum of the γ-LiV2O5 structure is in line with the experimental Raman spectra that allows a reliable assignment of all prominent Raman peaks. Comparison of the spectra of γ-LiV2O5 and γ'-V2O5 indicates spectral signatures of structural changes induced by the Li insertion into the γ'-V2O5 lattice. Results of the study present the opportunity of using Raman spectroscopy for characterization of structural modifications of the vanadate framework upon intercalation of guest species.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Anshits A. G., Bayukov O. A., Kondratenko E. V., Anshits N. N., Pletnev O. N., Rabchevskii E. V., Solovyov L. A.
Заглавие : Catalytic properties and nature of active centers of ferrospheres in oxidative coupling of methane
Коллективы : Russian Science Foundation [14-13-00289]
Место публикации : Appl. Catal. A-Gen.: Elsevier Science, 2016. - Vol. 524. - P.192-199. - ISSN 0926-860X, DOI 10.1016/j.apcata.2016.06.032. - ISSN 1873-3875(eISSN)
Примечания : Cited References:47. - This study was supported by the Russian Science Foundation (project no. 14-13-00289).
Предметные рубрики: GLASS CRYSTAL CATALYSTS
MAGNETIC-PROPERTIES
PROFILE REFINEMENT
FLY-ASH
MOSSBAUER
MICROSPHERES
PERFORMANCE
CONVERSION
ETHYLENE
OXIDE
Ключевые слова (''Своб.индексиров.''): methane coupling--active center--ferrospinel--mossbauer spectroscopy
Аннотация: Ferrospheres with the Fe2O3 content in the range from 76 to 97 wt% were applied as catalysts for the oxidative coupling of methane (OCM). To identify their phase composition and distribution of iron sites, the ferrospheres were characterized by X-ray powder diffraction and Mossbauer spectroscopy before and after the OCM reaction. Magnetite-based ferrite spinel, hematite and aluminosilicate glasses were established to be the main phases. The ferrospinel of all ferrospheres partially oxidized to hematite after the OCM reaction. It was established that the yield of C-2-hydrocarbons sharply increased at the ferrospheres with Fe2O3 content higher than 89 wt% The spinel phase of these ferrospheres includes Fevv3+(B) sites with a Ca2+ tetrahedral cation and an octahedral cation vacancy among the nearest neighbors. A linear correlation between the yield of C-2-hydrocarbons (ethane and ethylene) and the content of such sites was established, thus indicating that their electrophilic oxygen species participate in selective CH4 conversion to C2H6. (C) 2016 Elsevier B.V. All rights reserved.
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Myagkov V. G., Zhigalov V. S., Bykova L. E., Zharkov S. M., Matsynin A. A., Volochaev M. N., Tambasov I. A., Bondarenko G. N.
Заглавие : Thermite synthesis and characterization of Co-ZrO2 ferromagnetic nanocomposite thin films
Место публикации : J. Alloys Compd.: Elsevier, 2016. - Vol. 665. - P.197-203. - ISSN 09258388 (ISSN), DOI 10.1016/j.jallcom.2015.12.257
Примечания : Cited References: 56. - This study was partially supported by the Russian Foundation for Basic Research (grants ##15-02-00948, 14-03-00515), by the Council for Grants of the President of the Russian Federation (SP-317.2015.1), and by the program of the Foundation for Assistance to Small Innovative Enterprises in Science and Technology (“UMNIK” program). The TEM studies were carried out using the facilities of Electron Microscopy Laboratory of Siberian Federal University and the Performance Service at Krasnoyarsk Scientific Center.
Предметные рубрики: SOLID-STATE SYNTHESIS
PHASE-FORMATION
ZrO2
NANOPARTICLES
TRANSPORT
OXIDE
MICROSTRUCTURE
NANOTHERMITE
FABRICATION
PARTICLES
Ключевые слова (''Своб.индексиров.''): thermite reactions--reactive films--ferromagnetic nanocomposite films--zro2
Аннотация: Co-ZrO2 ferromagnetic nanocomposite thin films were successfully synthesized using a new thermite reaction between Zr and Co3O4 in layer geometry. The initial Zr/Co3O4 bilayers were obtained by the deposition of Zr layers onto Co3O4 films at room temperature. The process of mixing at the Zr/Co3O4 interface and synthesis of fine-crystalline Co and amorphous ZrO2 phases started at a temperature above the initiation temperature Tin ∼250 °C which did not depend on the bilayer thickness. For the bilayer thickness more than 300 nm high-temperature fcc-Co and cubic c-ZrO2 (or tetragonal t-ZrO2) phases were formed. For the bilayer thickness less than ∼50 nm stable low-temperature hexagonal hcp-Co and monoclinic m-ZrO2 phases were also present in the reaction product. A partial transformation from Co3O4 to CoO occurred after annealing at 300 °C. The secondary reaction between CoO and Zr started soon after Co3O4 had been converted to the CoO phase. After annealing at 500 °C more than 80% of Co was reduced and the final product contained Co nanoparticles above and below the superparamagnetic critical size embedded into a dielectric ZrO2 matrix. The synthesized Co-ZrO2 nanocomposite films possessed soft magnetic behavior, high magnetization and good chemical stability.
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