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1.
Вид документа
: Статья из журнала
Шифр издания
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Автор(ы)
: Drokina T. V., Petrakovskii G. A., Velikanov D. A., Molokeev M. S.
Заглавие
: Specific features of magnetic ordering in the SmFeGe2O7 compound
Место публикации
: Phys. Solid State: MAIK Nauka-Interperiodica / Springer, 2014. - Vol. 56, Is. 6. - P.1131-1136. - ISSN 1063-7834,
DOI
10.1134/S1063783414060122. - ISSN 1090-6460
Примечания
: Cited References: 10
Предметные рубрики:
NEUTRON-DIFFRACTION
PR
FERGE2O7
R=LA
Аннотация:
The results of the experimental investigation of the magnetic properties of the SmFeGe2O7 compound have been presented. It has been found that the temperature dependence of the susceptibility exhibits two features that coincide with the anomalies in the temperature dependence of the specific heat and indicate magnetic phase transitions in SmFeGe2O7. The external magnetic field induces a magnetic transition, the critical field of which depends on the temperature.
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2.
Вид документа
: Статья из журнала
Шифр издания
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Автор(ы)
: Petrov M. I., Balaev D. A., Gokhfel'd Yu. S., Dubrovskii A. A., Shaikhutdinov K. A.
Заглавие
: Effect of heterovalent substitution of rare-earth elements on the magnetic and transport properties of YBa2Cu3O7
Место публикации
: Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 11. - P2047-2051. - ISSN 1063-7834,
DOI
10.1134/S1063783407110054
Примечания
: Cited References: 18
Предметные рубрики:
PR
SUPERCONDUCTIVITY
CE
ND
TRANSITION
SYSTEM
LA
Аннотация:
The Y(1-x) Ce (x) Ba2Cu3O7 system with low cerium concentrations has been synthesized. The cerium solubility limit measured using x-ray powder diffraction analysis is about 2.4 at. %. The temperature dependences of the magnetization M(T) are measured for samples cooled in a magnetic field (FC) and in a zero field (ZFC). The difference between the magnetizations M-ZFC-M-FC at 77.4 K, which is proportional to the pinning potential, passes through a maximum at x = 0.0156. This concentration corresponds to the average distance (equal to eight lattice constants) between the impurity ions in the plane of the rare-earth elements, which is comparable to the diameter of Abrikosov vortices in YBa2Cu3O7.
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3.
Вид документа
: Статья из журнала
Шифр издания
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Автор(ы)
: Ivanova N. B., Kazak N. V., Michel C. R., Balaev A. D., Ovchinnikov S. G.
Заглавие
: Low-temperature magnetic behavior of the rare-earth cobaltites GdCoO3 and SmCoO3
Разночтения заглавия
:авие SCOPUS: Low-temperature magnetic behavior of the rare-earth cobaltites GdCoO 3 and SmCoO3
Место публикации
: Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 11. - P2126-2131. - ISSN 1063-7834,
DOI
10.1134/S1063783407110182
Примечания
: Cited References: 32. - This study was supported by the Branch of General Physics and Astronomy of the Russian Academy of Sciences within the framework of the program “Strong Electron Correlations” and the Russian Science Support Foundation
Предметные рубрики:
METAL-INSULATOR-TRANSITION
RCOO3 R
SPIN-STATE
OXIDE
SM
ND
PEROVSKITE
GLASSES
PR
EU
Аннотация:
The temperature and magnetic field dependences of the static magnetization of the polycrystalline rare-earth cobaltites GdCoO3 and SmCoO3 have been measured. It is shown that, below room temperature, the magnetization of both compounds derives primarily from the rare-earth ion paramagnetism. The GdCoO3 and SmCoO3 compounds have been found to differ substantially in magnetic behavior, which can be traced to differences in their electronic shell structures. The magnetic behavior of GdCoO3 is close to that of an array of free Gd3+ ions, whereas in SmCoO3 the deviation from the free-ion properties is very large because of the Sm3+ ground state being crystal-field split. Van Vleck magnetic susceptibility measurements of SmCoO3 suggest that the splitting is similar to 10 K.
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4.
Вид документа
: Статья из журнала
Шифр издания
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Автор(ы)
: Ivanova N. B., Kazak N. V., Michel C. R., Balaev A. D., Ovchinnikov S. G., Vasil'ev A. D., Bulina N. V., Panchenko E. B.
Заглавие
: Effect of strontium and barium doping on the magnetic state and electrical conductivity of GdCoO3
Место публикации
: Phys. Solid State: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2007. - Vol. 49, Is. 8. - P1498-1506. - ISSN 1063-7834,
DOI
10.1134/S1063783407080161
Примечания
: Cited References: 36
Предметные рубрики:
PEROVSKITE
ORDER
OXIDE
BEHAVIOR
GLASSES
LACOO3
PR
GD
SM
ND
Аннотация:
A coordinated investigation of the magnetic and electrical properties of polycrystalline cobalt oxide compounds CdCoO3, Gd0.9Ba0.1CoO3, and Gd0.9Sr0.1CoO3 is carried out. Undoped GdCoO3 reveals a low conductivity; a magnetic moment of 7.4 mu(B) per molecule, which is less than the theoretical value for the Gd3+ ion; and an asymptotic Curie temperature of -6 K. Doping GdCoO3 with barium and strontium to substitution of 10 at. % Gd brings about an increase in the conductivity and magnetic transitions at T = 300 K for Gd0.9Ba0.1CoO3 and T = 170 K for Gd0.9Sr0.1CoO3. The magnetization anomalies imply the formation of magnetic clusters. The behavior of the electrical conductivity at high temperatures suggests a variable activation energy. At low temperatures, Mott hopping conduction sets in.
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5.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Yen F., Lorenz B., Sun Y. Y., Chu C. W., Bezmaternykh L. N., Vasiliev A. N.
Заглавие
: Magnetic field effect and dielectric anomalies at the spin reorientation phase transition of GdFe3(BO3)(4)
Разночтения заглавия
:авие SCOPUS: Magnetic field effect and dielectric anomalies at the spin reorientation phase transition of GdFe3 (BO3) 4
Место публикации
: Phys. Rev. B: AMERICAN PHYSICAL SOC, 2006. - Vol. 73, Is. 5. - Ст.54435. - ISSN 1098-0121,
DOI
10.1103/PhysRevB.73.054435
Примечания
: Cited References: 21
Предметные рубрики:
IRON BORATE GDFE3(BO3)(4)
HOMNO3
ANISOTROPY
PR
SM
Аннотация:
GdFe3(BO3)(4) exhibits a structural phase transition at 156 K, antiferromagnetic order of the Fe3+ moments at 36 K, followed by a spin reorientation phase transition at 9 K. The reorientation phase transition is studied through dielectric, magnetic, and heat capacity measurements under the application of external magnetic fields of up to 7 kOe. The dielectric constant indicates the existence of two distinct anomalies at T-SR=9 K that separate in temperature under external magnetic fields. The spin rotation phase transition is proven to be of the first-order nature through the magnetic analog of the Clausius-Clapeyron equation. Magnetodielectric effect of up to 1% is observed at 8 K and 7 kOe. The uniaxial magnetocaloric effect along the c axis is observed below the spin reorientation phase transition of 9 K.
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6.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Irtyugo L. A., Denisova L. T., Molokeev M. S., Denisov V. M., Aleksandrovsky A. S., Beletskii V. V., Sivkova, E. Yu
Заглавие
: Synthesis, crystal structure, and the optical and thermodynamic properties of PrAlGe2O7
Место публикации
: Russ. J. Phys. Chem. A. - 2021. - Vol. 95, Is. 8. - P.1546-1550. - ISSN 0036-0244,
DOI
10.1134/S0036024421080124. - ISSN 1531-863X(eISSN)
Примечания
: Cited References: 23
Предметные рубрики:
TEMPERATURE HEAT-CAPACITY
GERMANATES
SMFEGE2O7
PR
Аннотация:
Germanate PrAlGe2O7 is obtained from initial oxides Pr2O3, Al2O3, and GeO2 via solid-phase synthesis. The crystal structure of the investigated germanate is determined via X-ray diffraction. The luminescence spectra are been determined at room temperature. The effect temperature has on the heat capacity is determined via differential scanning calorimetry. The thermodynamic properties of the complex oxide compound are calculated using the experimental data on Cp = f(T) in the temperature range of 350‒1000 K.
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7.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Denisova L. T., Molokeev M. S., Kargin, Yu F., Gerasimov V. P., Krylov A. S., Aleksandrovskii A. S., Chumilina L. G., Denisov V. M., Vasil'ev G. V.
Заглавие
: Synthesis, crystal structure, and physicochemical properties of Bi4-xPrxTi3O12 (x=0.4, 0.8, 1.2, 1.6) solid solutions
Место публикации
: Inorg. Mater. - 2021. - Vol. 57, Is. 9. - P.919-928. - ISSN 0020-1685,
DOI
10.1134/S002016852109003X. - ISSN 1608-3172(eISSN)
Примечания
: Cited References: 40
Предметные рубрики:
BI4-XRXTI3O12 R-X
HEAT-CAPACITY
AURIVILLIUS PHASES
PR
ND
BI4TI3O12
Аннотация:
Bi4–xPrxTi3O12 (x = 0.4, 0.8, 1.2, 1.6) solid solutions have been prepared by solid-state reactions, via multistep firing of stoichiometric mixtures of their constituent oxides in air at temperatures from 1003 to 1323 K. Their crystal structure has been determined using X-ray diffraction, and their luminescence spectra have been measured at room temperature. High-temperature heat capacity of polycrystalline substituted bismuth titanate samples has been determined by differential scanning calorimetry. The Cp(T) curves of the solid solutions with x = 0.4 and 0.8 have extrema related to phase transitions. Experimental data have been used to calculate the main thermodynamic functions of the solid solutions.
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8.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Denisova L. T., Molokeev M. S., Galiakhmetova N. A., Denisov V. M., Vasil'ev G. V.
Заглавие
: Synthesis, crystal structure, and thermal properties of substituted titanates Bi2Pr2Ti3O12 and Bi2Nd2Ti3O12
Коллективы
: [FSRZ-2020-0013]
Место публикации
: Phys. Solid State. - 2021. - Vol. 63. Is. 8. - P.1159-1164. - ISSN 1063-7834,
DOI
10.1134/S1063783421080084. - ISSN 1090-6460(eISSN)
Примечания
: Cited References: 39. - This study was carried out in part within the state assignment for the Siberian Federal University, project no. FSRZ-2020-0013
Предметные рубрики:
BI4-XRXTI3O12 R-X
PHASE-EQUILIBRIA
HEAT-CAPACITY
ND
BI4TI3O12
PR
Аннотация:
Titanates Bi2Pr2Ti3O12 and Bi2Nd2Ti3O12 have been obtained by the solid-phase synthesis using sequential annealing of the Bi2O3, Nd2O3, Pr6O11, and TiO2 stoichiometric mixtures in air at temperatures of 1003–1323 K. Their crystal structure has been established by X-ray diffractometry and the high-temperature heat capacity has been determined by differential scanning calorimetry. Based on the experimental Cp = f(T) data, the main thermodynamic functions have been calculated.
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9.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Kazak N. V., Ovchinnikov S. G., Balaev A. D., Ivanova N.B., Pashkevich, Yu. G., Michel C.R., Bondarenko G. V.
Заглавие
: Magnetic and transport properties of Gd(0.9)A(0.1)CoO(3-delta) (A = Ba, Sr)
Место публикации
: J. Magn. Magn. Mater. - 2009. - Vol. 321, Is. 9. - P.1266-1271. - ISSN 0304-8853,
DOI
10.1016/j.jmmm.2008.11.087
Примечания
: Cited Reference Count: 31. - Гранты: This study was supported by the Rosnauka (Project no. MK-4278.2008.2), Russian Foundation for Basic Research (Project no. 08-02-90708 mob_st) and "Strongly correlated electrons'' program of the Department of Physical Sciences of RAS.Финансирующая организация: Rosnauka [MK-4278.2008.2]; Russian Foundation for Basic Research [08-02-90708 mob_st]; "Strongly correlated electrons'' program of the Department of Physical Sciences of RAS
Предметные рубрики:
PEROVSKITE
PR
LA
EU
ND
LN
TRANSITION
SPIN
GD
SM
Ключевые слова
(''Своб.индексиров.''): perovskite structure--doped cobaltite--magnetic susceptibility--metal-insulator transition--doped cobaltite--magnetic susceptibility--metal-insulator transition--perovskite structure--antiferromagnetism--barium--cobalt compounds--electric conductivity--ferromagnetic materials--ferromagnetism--gadolinium--magnetic susceptibility--metal insulator boundaries--oxide minerals--paramagnetic materials--perovskite--phase separation--semiconductor insulator boundaries--transport properties--antiferromagnetic--doped cobaltite--doped samples--electrical conductivity measurements--ferromagnetic transitions--insulator-metal transitions--magnetic and transport properties--magnetic behaviors--perovskite structure--temperature ranges--transport datum--x- ray diffractions--metal insulator transition
Аннотация:
The X-ray diffraction, magnetization and electrical conductivity measurements for Gd(0.9)A(0.1)CoO(3-delta) (A = Ba, Sr) have been made. The complicated magnetic behavior, including the paramagnetic-ferromagnetic-antiferromagnetic and paramagnetic-ferromagnetic transitions, was found for Ba- and Sr-doped samples. The gradual insulator-metal transitions were observed in a wide temperature range T = 600-800 K. The complex magnetic and transport data could be explained on the basis of the structural phase separation. (C) 2009 Elsevier B.V. All rights reserved.
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