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1.
Exploration of the
electronic structure of monoclinic α-Eu2(MoO4)3: DFT-based study and X-ray photoelectron spectroscopy / A. H. Reshak [et al.]> // J. Phys. Chem. C. - 2016. -
Vol. 120
,
Is. 19
. - P. 10559-10568,
DOI
10.1021/acs.jpcc.6b01489. - Cited References:85. - This work was partly supported by the Russian Foundation for Basic Research (Grants 15-32-50586 and 15-52-53080). V.V.A. gratefully acknowledges the Ministry of Education and Science of the Russian Federation for the financial support. A.H.R. would like to acknowledge the CENTEM project, reg. no. CZ.1.05/2.1.00/03.0088, cofunded by the ERDF as part of the Ministry of Education, Youth and Sports OP RDI program and, in the follow-up sustainability stage, supported through CENTEM PLUS (LO1402) by financial means from the Ministry of Education, Youth and Sports under the "National Sustainability Programme I". Computational resources were provided by MetaCentrum (LM2010005) and CERIT-SC (CZ.1.05/3.2.00/08.0144) infrastructures. . - ISSN 1932-7447
Перевод заглавия:
Исследование электронной структуры моноклинного альфа-Eu2(MoO4)3: ТФП исследования и рентгеновская фотоэлектронная спектроскопия
РУБ
Chemistry,
Physical
+ Nanoscience & Nanotechnology + Materials Science, Multidisciplinary
Рубрики:
Density-functional theory
Solid-solution phosphors
Luminescence
properties
Optical-
properties
Cleaved surface
Core levels
Vibrational
properties
Physical
-
properties
Crystal-structure
Single-crystals
Аннотация:
The powder α-Eu2(MoO4)3 sample was prepared by the solid-state reaction method. The phase purity of the final powder product was verified by X-ray diffraction analysis. The constituent element core levels and valence band are measured by X-ray photoelectron spectroscopy as a function of Ar+ ion (2.5 keV, 7-8 μA/cm2) bombardment time. The formation of Mo5+ and Mo4+ states at high bombardment times was detected. The Eu-O and Mo-O bonding was considered in comparison with other Eu3+- and Mo6+-containing oxides using binding energy difference parameters. The transparency range obtained for the pure α-Eu2(MoO4)3 tablet is λ = 0.41-0.97 μm, as estimated at the transmission level of 5%. The short-wavelength cut edge in α-Eu2(MoO4)3 is governed by the direct allowed optical transitions within the band gap of Eg = 3.74 eV (300 K). The band structure of α-Eu2(MoO4)3 was calculated by ab initio methods and strongly different results were obtained for the spin up/down configurations. The Eu-4f states are located around 2.2 eV and -4.0 eV for spin up (↑) and the structures situated at around 6.5 and 5.5 eV for spin down (↓) configuration. The calculated spin magnetic moments are in excellent relation to the Slater-Pauling rule and within the Eu sphere the magnetic moment of 4f electrons is ∼5.99 μB. © 2016 American Chemical Society.
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Держатели документа:
Univ W Bohemia, New Technol Res Ctr, Univ 8, Plzen 30614, Czech Republic.
Univ Malaysia Perlis, Sch Mat Engn, Ctr Excellence Geopolymer & Green Technol, Kangar 01007, Perlis, Malaysia.
King Saud Univ, Coll Sci, Dept Phys & Astron, Riyadh 11451, Saudi Arabia.
Czech Tech Univ, Fac Mech Engn, Dept Instrumentat & Control Engn, Tech 4, Prague 16607 6, Czech Republic.
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia.
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia.
Novosibirsk State Univ, Lab Semicond & Dielectr Mat, Novosibirsk 630090, Russia.
SB RAS, Baikal Inst Nat Management, Lab Oxide Syst, Ulan Ude 670047, Russia.
Buryat State Univ, Dept Chem, Ulan Ude 670000, Russia.
SB RAS, Kirensky Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036, Russia.
Far Eastern State Transport Univ, Dept Phys, Khabarovsk 680021, Russia.
SB RAS, Boreskov Inst Catalysis, Novosibirsk 630090, Russia.
SB RAS, Inst Geol & Mineral, Lab High Pressure Minerals & Diamond Deposits, Novosibirsk 630090, Russia.
Доп.точки доступа:
Reshak, Ali H.; Alahmed, Z. A.; Bila, J.; Atuchin, V. V.; Bazarov, B. G.; Chimitova, O. D.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Prosvirin, Igor P.; Yelisseyev, Alexander P.; Russian Foundation for Basic Research [15-32-50586, 15-52-53080]; Ministry of Education and Science of the Russian Federation; CENTEM project - ERDF as part of the Ministry of Education, Youth and Sports OP RDI program [CZ.1.05/2.1.00/03.0088]; CENTEM PLUS - Ministry of Education, Youth and Sports [LO1402]
}
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2.
High-temperature heat capacity
of Y2.93Ho0.07Fe5O12 / V. M. Denisov [et al.]> // Phys. Solid State. - 2012. -
Vol. 54
,
Is. 11
. - P. 2205-2207,
DOI
10.1134/S1063783412110078. - Cited References: 28 . - ISSN 1063-7834
РУБ
Physics, Condensed Matter
Рубрики:
PHYSICAL
-
PROPERTIES
SYSTEM
OXIDES
Аннотация:
This paper presents data on the heat capacity of Y2.93Ho0.07Fe5O12 obtained in the temperature range 343-1000 K. A correlation between the composition of the Fe2O3-Y2O3 pseudobinary system and the specific heat capacity of oxide compounds is pointed out.
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Публикация на русском языке
Высокотемпературная теплоемкость Y2.93Ho0.07Fe5O12 // Физика твердого тела : Издательство "Наука", 2012. - Т. 54, N 11. - С. 2073-2075. - ISSN 0367-3294
Держатели документа:
Denisov, V. M.
Denisova, L. T.
Irtyugo, L. A.
Chumilina, L. G.] Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660025, Russia
Patrin, G. S.
Volkov, N. V.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Доп.точки доступа:
Denisov, V. M.; Denisova, L. T.; Irtyugo, L. A.; Patrin, G. S.; Патрин, Геннадий Семёнович; Volkov, N. V.; Волков, Никита Валентинович; Chumilina, L. G.
}
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3.
Electron spin resonance
in CuCrS(2) chrome-copper disulphides synthesized by different methods / G. . Abramova [et al.]> // J. Appl. Phys. - 2010. -
Vol. 107
,
Is. 9
. - Ст. 93914,
DOI
10.1063/1.3374679. - Cited References: 13 . - ISSN 0021-8979
РУБ
Physics, Applied
Рубрики:
COLOSSAL MAGNETORESISTANCE
PHYSICAL
-
PROPERTIES
TRANSITION
Кл.слова (ненормированные):
Chemical vapor transport
--
Electron spin resonance
--
Ferromagnets
--
G-values
--
Magnetic transitions
--
Polycrystalline
--
Synthesis method
--
Temperature range
--
Astatine
--
Paramagnetism
--
Resonance
--
Single crystals
--
Spin dynamics
--
Crystal impurities
Аннотация:
The electron spin resonance (ESR) in CuCrS(2) disulphides is found to be strongly dependent on a synthesis method used. At a temperature of 300 K, a polycrystalline CuCrS(2) sample is paramagnetic with a g-value of 1.95 at 40 K, it undergoes the magnetic transition. In the temperature range 4.2-290 K, a single-crystal sample prepared by a chemical vapor transport method exhibits the ESR features typical of a ferromagnet. It is shown that these features are related to the presence of a small amount of the single-crystal CuCr(2)S(4) impurity in the CuCrS(2) single crystal. (C) 2010 American Institute of Physics. [doi:10.1063/1.3374679]
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Держатели документа:
[Abramova, Galina
Pankrats, Anatolii
Petrakovskii, German
Vorotynov, Aleksandr
Tugarinov, Vasilii
Bovina, Asya
Vasil'ev, Viktor] Russian Acad Sci, LV Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
[Rasch, Julia C. E.
Boehm, Martin] Inst Max Von Laue Paul Langevin, F-38042 Grenoble 9, France
[Szumszak, Rita] Polish Acad Sci, Inst Phys, PL-02668 Warsaw, Poland
ИФ СО РАН
L.V. Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Akademgorodok 50, bld. 38, Krasnoyarsk 660036, Russian Federation
Institute Max von Laue-Paul Langevin, Grenoble, Cedex 9, France
Institute of Physics, Polish Academy of Sciences, 02-668 Warsaw, Poland
Доп.точки доступа:
Abramova, G. M.; Абрамова, Галина Михайловна; Pankrats, A. I.; Панкрац, Анатолий Иванович; Petrakovskii, G. A.; Петраковский, Герман Антонович; Rasch, JCE; Boehm, M.; Vorotynov, A. M.; Воротынов, Александр Михайлович; Tugarinov, V. I.; Тугаринов, Василий Иванович; Szumszak, R.; Bovina, A. F.; Бовина, Ася Федоровна; Vasil'ev, V.
}
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