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1.


   
    Electronic structure of α-SrB[[d]]4[[/d]]O[[d]]7[[/d]]: experiment and theory / V. V. Atuchin [et al.] // J. Phys.: Condens. Matter. - 2013. - Vol. 25, no. 8. - Ст. 085503DOI 10.1088/0953-8984/25/8/085503
   Перевод заглавия: Электронная структура α-SrB4O7: эксперимент и теория
Аннотация: The investigation of valence band structure and electronic parameters of constituent element core levels of α-SrB4O7 has been carried out with x-ray photoemission spectroscopy. Optical-quality crystal α-SrB4O7 has been grown by the Czochralski method. Detailed photoemission spectra of the element core levels have been recorded from the powder sample under excitation by nonmonochromatic Al Kα radiation (1486.6 eV). The band structure of α-SrB4O7 has been calculated by ab initio methods and compared to XPS measurements. It has been found that the band structure of α-SrB4O7 is weakly dependent on the Sr-related states.

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Держатели документа:
SB RAS, Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090 90, Russia
SB RAS, Inst Semicond Phys, Lab Phys Bases Integrated Microelect, Novosibirsk 630090 90, Russia
SB RAS, Inst Phys, Lab Crystal Phys, Krasnoyarsk 660036 36, Russia
Siberian Fed Univ, Krasnoyarsk 660041 41, Russia
SB RAS, Inst Phys, Lab Coherent Opt, Krasnoyarsk 660036 36, Russia

Доп.точки доступа:
Atuchin, V. V.; Zaitsev, A. I.; Зайцев, Александр Иванович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Kuzubov, A. A.; Кузубов, Александр Александрович; Ignatova, N. Y.; Kesler, V. G.
}
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2.


   
    Electronic structure of α-SrB4O7: Experiment and theory / A. S. Aleksandrovsky [et al.] // The 7th Russian-French workshop on Nanosciences and Nanotechnologies : Program and abstract book / ed. A. V. Okotrub. - Novosibirsk, 2013. - P. 47 . - ISBN 978-5-901688-29-8
   Перевод заглавия: Электронная структура α-SrB4O7: эксперимент и теория

Материалы конференции

Доп.точки доступа:
Okotrub, A.V. \ed.\; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Atuchin, V. V.; Kesler, V. G.; Zaitsev, A. I.; Зайцев, Александр Иванович; Molokeev, M. S.; Молокеев, Максим Сергеевич; Kuzubov, A. A.; Кузубов, Александр Александрович; Ignatova, N. Y.; Russian-French workshop on Nanosciences and Nanotechnologies(7 ; 2013 ; Jun. ; 3-6 ; Новосибирск); Российская академия наук; Сибирское отделение РАН; Институт неорганической химии им. А.В. Николаева Сибирского отделения РАН; Институт катализа им. Г.К. Борескова Сибирского отделения РАН; Институт физики полупроводников им. А.В. Ржанова Сибирского отделения РАН
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3.


   
    Structural properties and high temperature spin and electronic transitions in GdCoO[[d]]3[[/d]]: experiment and theory [Текст] / Yu. S. Orlov [и др.] // V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism : abstracts. - Vladivostok : FEFU, 2013. - P200 . - ISBN 978-5-7444-3124-2


Доп.точки доступа:
Orlov, Yu.S.; Орлов, Юрий Сергеевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Fedorov, A. S.; Федоров, Александр Семенович; Kuzubov, A. A.; Кузубов, Александр Александрович; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; Sept. ; 15-21 ; Vladivostok)
}
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4.


   
    Structural properties and high-temperature spin and electronic transitions in GdCoO3: Experiment and theory / Yu. S. Orlov [et al.] // Phys. Rev. B. - 2013. - Vol. 88, Is. 23. - Ст. 235105. - P. , DOI 10.1103/PhysRevB.88.235105 . - ISSN 1098-0121
   Перевод заглавия: Структурные свойства и высокотемпературные спиновые и электронные переходы в GdCoO3: эксперимент и теория
Аннотация: We have investigated the x-ray diffraction (XRD) structure, magnetic susceptibility, and heat capacity of GdCoO3 in a wide temperature range. A model of phase separation of the low-spin (LS) and high-spin (HS) states has been proposed based on the analysis of XRD peak shape anomalies in the temperature range 200-800 K. From magnetic measurements we separated the HS Co3+ contribution and fitted it with the temperature-dependent spin gap. We found a smooth LS-HS crossover at T=800 K. The possible contribution of the intermediate spin (IS) state to the thermodynamics is excluded by the calculation IS-LS excitation energy within the modified crystal-field approach. In the two-phase model, with HS/LS probabilities calculated from the found spin gap and the LS and HS volumes calculated by the DFT-GGA method, we were able to reproduce the temperature dependence of the unit-cell volume and thermal expansion. Thus, we conclude that in GdCoO3 the main mechanism of the lattice expansion is not the conventional lattice anharmonicity, but the HS/LS fluctuations. The electronic structure has been calculated by the LDA+GTB method. At zero temperature, we have obtained the charge-transfer insulator with the charge gap Eg=0.5 eV. The thermal population of the HS term results in the in-gap band formation inside the insulator gap and smooth insulator-metal transition at TIMT=780 K. Heat-capacity measurements revealed a smooth maximum near the TIMT. © 2013 American Physical Society.

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Держатели документа:
Russian Acad Sci, LV Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660049, Russia
Moscow MV Lomonosov State Univ, Fac Phys, Moscow 119991, Russia
Natl Acad Sci Ukraine, OO Galkin Donetsk Inst Phys & Engn, UA-83114 Donetsk, Ukraine
MF Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia;

Доп.точки доступа:
Orlov, Yu.S.; Орлов, Юрий Сергеевич; Solovyov, L. A.; Соловьев, Леонид Александрович; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Fedorov, A. S.; Федоров, Александр Семенович; Kuzubov, A. A.; Кузубов, Александр Александрович; Kazak, N. V.; Казак, Наталья Валерьевна; Voronov, V. N.; Воронов, Владимир Николаевич; Vereshchagin, S. N.; Shishkina, N. N.; Perov, N. S.; Lamonova, K. V.; Babkin, R.Yu.; Pashkevich, Yu.G.; Anshits, A. G.; Аншиц, Александр Георгиевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич
}
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5.


   
    The role of rocks saturated with metallic iron in the formation of ferric carbonate-silicate melts: experimental modeling under PT-conditions of lithospheric mantle / Y. V. Bataleva [et al.] // Russ. Geol. Geophys. - 2015. - Vol. 56, Is. 1-2. - P. 143-154, DOI 10.1016/j.rgg.2015.01.008. - Cited References:68. - This work was supported by Integration project 31 from the Siberian Branch of the Russian Academy of Sciences and by grant 12-05-00740 from the Russian Foundation for Basic Research. . - ISSN 1068. - ISSN 1878-030X. -
РУБ Geosciences, Multidisciplinary
Рубрики:
OXYGEN FUGACITY
   DIAMOND FORMATION

   OXIDATION-STATE

   EARTHS MANTLE

Кл.слова (ненормированные):
carbonate-silicate melt -- graphite -- CO2 fluid -- iron carbide -- garnet -- redox gradient -- high-pressure experiment
Аннотация: Experimental modeling of the processes of formation of ferric carbonate-silicate melts through the carbonate-oxide-metal interaction is performed in the (Mg,Ca)CO3-SiO2-Al2O3-Fe0 system at 6.3 and 7.5 GPa and within 1150-1650 °C, using a multianvil high-pressure apparatus of “split-sphere” type (BARS). Two parallel reactions run in the subsolidus region (1150-1450 °C): decarbonation, producing pyrope-almandine (Fe# = 0.40-0.75) and CO2 fluid, and redox interaction between carbonate and Fe0, resulting in the crystallization of iron carbide in assemblage with magnesiowustite (Fe# = 0.75-0.85). It is shown that the reduction of carbonate or CO2 fluid by iron carbide and parallel redox interaction of magnesiowustite with CO2 produce graphite in assemblage with Fe3 + -containing magnesiowustite. In the temperature range of 1450-1650 °C, generation of carbonate-silicate melts coexisting with pyrope-almandine, magnesiowustite, magnetite, ferrospinel, and graphite takes place. The composition of the produced melts is as follows: SiO2 - 10-15 wt.%, X(FeO + Fe2O3) = 36-43 wt.%, and Fe3+/XFe - 0.18-0.23. These Fe3 + -enriched carbonate-silicate melts/fluids are saturated with carbon and are the medium of graphite crystallization. Oxide and silicate phases (almandine, ferrospinel, and magnetite) coexisting with graphite are also characterized by high Fe3+/XFe values. It has been established that Fe3 + -enriched carbonate-silicate melts can result from the interaction of Fe0-containing rocks with carbonated rocks. In the reduced mantle (with the presence of iron carbides or oxides), melts of this composition can be the source of carbon and the medium of graphite crystallization at once. After separation and ascent, these ferric carbonate-silicate melts can favor oxidizing metasomatism in the lithospheric mantle.

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Публикация на русском языке Роль пород, содержащих самородное железо, в образовании железистых карбонатно-силикатных расплавов: экспериментальное моделирование при P-T-параметрах литосферной мантии [Текст] / Ю. В. Баталева [и др.] // Геол. и геофиз. - Новосибирск : Изд-во СО РАН, 2015. - Т. 56 № 1-2. - С. 188-203

Держатели документа:
Russian Acad Sci, Siberian Branch, VS Sobolev Inst Geol & Mineral, Novosibirsk 630090, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Novosibirsk State Univ, Novosibirsk 630090, Russia.

Доп.точки доступа:
Bataleva, Yu. V.; Palyanov, Yu. N.; Sokol, A. G.; Borzdov, Yu. M.; Bayukov, O. A.; Баюков, Олег Артемьевич; Siberian Branch of the Russian Academy of Sciences [31]; Russian Foundation for Basic Research [12-05-00740]
}
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6.


   
    Wüstite stability in the presence of a CO2-fluid and a carbonate-silicate melt: Implications for the graphite/diamond formation and generation of Fe-rich mantle metasomatic agents / Y. V. Bataleva [et al.] // Lithos. - 2016. - Vol. 244. - P. 20-29, DOI 10.1016/j.lithos.2015.12.001. - Cited References: 68. - This work was supported by the Russian Science Foundation under grant no. 14-27-00054. The authors thank A. Moskalev for his assistance in the work preparation, A. Khokhryakov for useful suggestions throughout the study, and S. Ovchinnikov for his assistance in implementation of Mössbauer spectroscopy measurements. The authors thank editor M. Scambelluri, and two anonymous reviewers for their useful comments, which helped to profoundly improve the manuscript. . - ISSN 0024-4937
РУБ Geochemistry & Geophysics + Mineralogy
Рубрики:
EARTHS LOWER MANTLE
   FERRIC IRON CONTENT

   DIAMOND FORMATION

   MINERAL INCLUSIONS

   NATURAL DIAMOND

   OXIDATION-STATE

   DEEP MANTLECRUST

   LITHOSPHERIC MANTLE

   OXYGEN FUGACITY

   OCEANIC-CRUST

Кл.слова (ненормированные):
Wustite -- CO2-fluid -- Carbonate-silicate melt -- Decarbonation -- Graphite formation -- HPHT experiment
Аннотация: Experimental simulation of the interaction of wüstite with a CO2-rich fluid and a carbonate-silicate melt was performed using a multianvil high-pressure split-sphere apparatus in the FeO-MgO-CaO-SiO2-Al2O3-CO2 system at a pressure of 6.3GPa and temperatures in the range of 1150°C-1650°C and with run time of 20h. At relatively low temperatures, decarbonation reactions occur in the system to form iron-rich garnet (Alm75Prp17Grs8), magnesiowüstite (Mg#≤0.13), and CO2-rich fluid. Under these conditions, magnesiowüstite was found to be capable of partial reducing CO2 to C0 that leads to the formation of Fe3+-bearing magnesiowüstite, crystallization of magnetite and metastable graphite, and initial growth of diamond seeds. At T≥1450°C, an iron-rich carbonate-silicate melt (FeO~56wt.%, SiO2~12wt.%) forms in the system. Interaction between (Fe,Mg)O, SiO2, fluid and melt leads to oxidation of magnesiowüstite and crystallization of fayalite-magnetite spinel solid solution (1450°C) as well as to complete dissolution of magnesiowüstite in the carbonate-silicate melt (1550°C-1650°C). In the presence of both carbonate-silicate melt and CO2-rich fluid, dissolution (oxidation) of diamond and metastable graphite was found to occur. The study results demonstrate that under pressures of the lithospheric mantle in the presence of a CO2-rich fluid, wüstite/magnesiowüstite is stable only at relatively low temperatures when it is in the absolute excess relative to CO2-rich fluid. In this case, the redox reactions, which produce metastable graphite and diamond with concomitant partial oxidation of wüstite to magnetite, occur. Wüstite is unstable under high concentrations of a CO2-rich fluid as well as in the presence of a carbonate-silicate melt: it is either completely oxidized or dissolves in the melt or fluid phase, leading to the formation of Fe2+- and Fe3+-enriched carbonate-silicate melts, which are potential metasomatic agents in the lithospheric mantle. © 2015 Elsevier B.V.

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Держатели документа:
Sobolev Institute of Geology and Mineralogy, Siberian Branch of Russian Academy of Sciences, Koptyug ave 3, Novosibirsk, Russian Federation
Novosibirsk State University, Pirogova str 2, Novosibirsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch of Russian Academy of Sciences, Akademgorodok 50, bld. 38, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Bataleva, Yu. V.; Palyanov, Y .N.; Sokol, A. G.; Borzdov, Y. M.; Bayukov, O. A.; Баюков, Олег Артемьевич
}
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7.


   
    Conditions for diamond and graphite formation from iron carbide at the P-T parameters of lithospheric mantle / Y. V. Bataleva [et al.] // Russ. Geol. Geophys. - 2016. - Vol. 57, Is. 1 : Tectonics, geodynamics, and petrology of earth’s lithosphere and mantle (to the 80th birthday of Academician Nikolai Leontievich Dobretsov). - P. 176-189, DOI 10.1016/j.rgg.2016.01.012. - Cited References:55. - This work was supported by the Russian Science Foundation under Grant No. 14-27-00054. . - ISSN 1068-7971. - ISSN 1878-030X
РУБ Geosciences, Multidisciplinary
Рубрики:
DEEP CARBON-CYCLE
   EARTHS MANTLE

   MINERAL INCLUSIONS

   HIGH-PRESSURE

   KOKCHETAV MASSI

   SUBDUCTION ZONES

   REDOX BUDGET

   FERRIC IRON

   MOSSBAUER

   METAL

Кл.слова (ненормированные):
iron carbide -- wusite -- graphite -- diamond -- oxides -- olivine -- subduction -- redox interaction -- lithospheric mantle -- high-pressure experiment
Аннотация: To estimate conditions for the stability of iron carbide under oxidation conditions and to assess the possibility of formation of elemental carbon by interaction between iron carbide and oxides, experimental modeling of redox interaction in the systems Fe3C-Fe2O3 and Fe3C-Fe2O3-MgO-SiO2 was carried out on a split-sphere high-pressure multianvil apparatus at 6.3 GPa and 900-1600 degrees C for 18-20 h. During carbide-oxide interaction in the system Fe3C-Fe2O3, graphite crystallizes in assemblage with Fe3+-containing wusite. Graphite forms from carbide carbon mainly by cohenite oxidation: Fe3C + 3Fe(2)O(3) -> 9FeO + C-0 and FeO + Fe3C -> (Fe2+, Fe3+)O + C-0. At above-solidus temperatures (>= 1400 degrees C), when metal-carbon melt is oxidized by wusite, graphite and diamond crystallize by the redox mechanism and form the Fe3+-containing wstite + graphite/diamond assemblage. Interaction in the system Fe3C-Fe2O3-MgO-SiO2 results in the formation of Fe3+-containing mannesiowusite-olivine-graphite assemblage. At >= 1500 degrees C, two melts with contrasting f(O2) values are generated: metal-carbon and silicate-oxide; their redox interaction leads to graphite crystallization and diamond growth. Under oxidation conditions, iron carbide is unstable in the presence of iron, silicon, and magnesium oxides, even at low temperatures. Iron carbide-oxide interaction at the mantle temperatures and pressures leads to the formation of elemental carbon; graphite is produced from carbide carbon mainly by redox reactions of cohenite (or metal-carbon melt) with Fe2O3 and FeO as well as by interaction between metal-carbon and silicate-oxide melts. The results obtained suggest that cohenite can be a potential source of carbon during graphite (diamond) formation in the lithospheric mantle and the interaction of iron carbide with iron, silicon, and magnesium oxides, during which carbon is extracted can be regarded as a process of the global carbon cycle. (C) 2016, V.S. Sobolev IGM, Siberian Branch of the RAS. Published by Elsevier B.V. All rights reserved.

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Публикация на русском языке Условия образования графита и алмаза из карбида железа при Р, Т-параметрах литосферной мантии [Текст] / Ю. В. Баталева [и др.] // Геол. и геофиз. - 2016. - Т. 57 № 1. - С. 225-240

Держатели документа:
Russian Acad Sci, Siberian Branch, VS Sobolev Inst Geol & Mineral, Pr Akad Koptyuga 3, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Ul Pirogova 2, Novosibirsk 630090, Russia.
Russian Acad Sci, Siberian Branch, LV Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Bataleva, Yu. V.; Palyanov, Yu. N.; Borzdov, Yu. M.; Bayukov, O. A.; Баюков, Олег Артемьевич; Sobolev, N. V.; Russian Science Foundation [14-27-00054]
}
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8.


   
    Magnetization and specific heat of TbFe3(BO3)(4): Experiment and crystal-field calculations / E. A. Popova [et al.] // Phys. Rev. B. - 2007. - Vol. 75, Is. 22. - Ст. 224413, DOI 10.1103/PhysRevB.75.224413. - Cited References: 22 . - ISSN 1098-0121
РУБ Physics, Condensed Matter
Рубрики:
GDFE3(BO3)(4)
   MAGNETOSTRICTION

Аннотация: We have studied the thermodynamic properties of single-crystalline TbFe3(BO3)(4). Magnetization measurements have been carried out as a function of magnetic field (up to 50 T) and temperature up to 350 K with the magnetic field both parallel and perpendicular to the trigonal c axis of the crystal. The specific heat has been measured in the temperature range 2-300 K with a magnetic field up to 9 T applied parallel to the c axis. The data indicate a structural phase transition at 192 K and antiferromagnetic spin ordering at T-N approximate to 40 K. A Schottky anomaly is present in the specific-heat data around 20 K, arising due to two low-lying energy levels of the Tb3+ ions being split by f-d coupling. Below T-N, magnetic fields parallel to the c axis drive a spin-flop phase transition, which is associated with a large magnetization jump. The highly anisotropic character of the magnetic susceptibility is ascribed mainly to the Ising-like behavior of the Tb3+ ions in the trigonal crystal field. We describe our results in the framework of a unified approach which is based on mean-field approximation and crystal-field calculations.

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Держатели документа:
Moscow MV Lomonosov State Univ, Fac Phys, Low Temp Phys Dept, Moscow 119992, Russia
Bryansk State Tech Univ, Bryansk 241035, Russia
RAS, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
IFW Dresden, Leibniz Inst Solid State & Mat Res, D-01171 Dresden, Germany
ИФ СО РАН
Low Temperature Physics Department, Physics Faculty, Moscow State University, 119992 Moscow, Russian Federation
Bryansk State Technical University, 241035 Bryansk, Russian Federation
L.V. Kirensky Institute of Physics, Siberian Branch of RAS, 660036 Krasnoyarsk, Russian Federation
Leibniz-Institute for Solid State and Materials Research, IFW Dresden, 01171 Dresden, Germany

Доп.точки доступа:
Popova, E. A.; Volkov, D. V.; Vasiliev, A. N.; Demidov, A. A.; Kolmakova, N. P.; Gudim, I. A.; Гудим, Ирина Анатольевна; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Tristan, N.; Skourski, Y.; Buchner, B.; Hess, C.; Klingeler, R.
}
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9.


   
    Characteristics of the magnetic microstructure of amorphous and nanocrystalline ferromagnets with a random anisotropy: Theoretical estimates and experiment / R. S. Iskhakov [et al.] // JETP Letters. - 2000. - Vol. 72, Is. 12. - P. 603-607, DOI 10.1134/1.1351199. - Cited References: 22 . - ISSN 0021-3640
РУБ Physics, Multidisciplinary
Рубрики:
ALLOYS
Аннотация: An experimental determination (both direct and indirect) of the characteristics of the magnetic microstructure, namely, the ferromagnetic correlation radius R-f and the rms fluctuation of the mean anisotropy D-1/2H-a, is performed for amorphous and nanocrystalline ferromagnets with a random anisotropy characterized by the quantities R-c and (DHa)-H-1/2, respectively. The magnetization curves of amorphous and nanocrystalline ferromagnets are found to exhibit a dependence on H that is caused by the alignment of the magnetizations of individual magnetic blocks with the field. (C) 2000 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, Siberian Div, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Siberian Univ Routes Commun, Krasnoyarsk Branch, Krasnoyarsk 660028, Russia
Moscow MV Lomonosov State Univ, Moscow 119899, Russia
ИФ СО РАН

Доп.точки доступа:
Iskhakov, R. S.; Исхаков, Рауф Садыкович; Komogortsev, S. V.; Комогорцев, Сергей Викторович; Moroz, Z. M.; Shalygina, E. E.
}
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10.


    AIZENBERG, L. A.
    CALCULATION EXPERIMENT ON THE HIGH-RESOLUTION OF PHYSICAL DEVICES BY THE EXTRAPOLATION OF THE FOURIER SPECTRUM OF UNIDIMENSIONAL FINITE SIGNALS / L. A. AIZENBERG, B. A. KRAVTSOV // Pisma Zhurnal Tek. Fiz. - 1987. - Vol. 13, Is. 19. - P. 1193-1197. - Cited References: 6 . - ISSN 0320-0116
РУБ Physics, Applied


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Доп.точки доступа:
KRAVTSOV, B. A.
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