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1.


   
    Optical properties of polymer dispersed liquid crystal films with inhomogeneous anchoring on the droplet surface / V. A. Loiko [et al.] // Актуальные проблемы физики твердого тела (ФТТ-2013) : сб. докл. в 3 т. - Минск : Ковчег, 2013. - Т. 2. - P222-224 . - ISBN ISBN 978-985-7055-81-4

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Доп.точки доступа:
Loiko, V. A.; Лойко В. А.; Konkolovich, A. V.; Конколович А. В. ; Miskevich, A. A.; Мискевич А. А.; Maschke, U.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Национальная Академия наук Беларуси; Научно-практический центр по материаловедению НАН Беларуси (Институт физики твердого тела и полупроводников); Актуальные проблемы физики твердого тела, международная научная конференция(2013 ; 15-18 окт. ; Минск, Беларусь)
}
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2.


   
    Experimental results and theoretical model to describe angular dependence of light scattering by monolayer of nematic droplets / V. A. Loiko [et al.] // J. Quant. Spectrosc. Radiat. Transf. - 2016. - Vol. 178: Electromagnetic and light scattering by nonspherical particles XV: Celebrating 150 years of Maxwell's electromagnetics. - P. 263-268, DOI 10.1016/j.jqsrt.2015.10.024. - Cited References:25 . - ISSN 0022-4073. - ISSN 1879-1352
   Перевод заглавия: Экспериментальные результаты и теоретическая модель, описывающая угловую зависимость рассеяния света монослоем капель нематика
РУБ Optics + Spectroscopy
Рубрики:
Dispersed liquid-crystals
   Inhomogeneous boundary-conditions

   Films

   Transmittance

   Radiation

Кл.слова (ненормированные):
Polymer-dispersed liquid crystal film -- Liquid crystal droplet -- Director -- configuration -- Light scattering -- Monolayer of droplets
Аннотация: Light scattering by a monolayer of bipolar nematic droplets encapsulated in polymer film is examined both experimentally and theoretically. A method for the simulation of the angular distribution of scattered light is based on the anomalous diffraction and interference approximations taking into account the director configuration within liquid crystal droplets and their bipolar axes orientation. The director configuration in nematic droplets is calculated using the relaxation method of the free energy minimization. The characteristics of the sample, including distribution of droplet sizes and shape anisometry, are measured in details. The experimental results and theoretical data agree closely with each other. (C) 2015 Elsevier Ltd. All rights reserved.

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Доп.точки доступа:
Loiko, V. A.; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Konkolovich, A. V.; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Miskevich, A. A.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Conference on Electromagnetic and Light Scattering(15 ; June 21-26, 2015 ; Leipzig, Germany)
}
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3.


   
    Small-Angle Light Scattering from Polymer-Dispersed Liquid-Crystal Films / V. A. Loiko [et al.] // J. Exp. Theor. Phys. - 2008. - Vol. 107, Is. 4. - P. 692-698, DOI 10.1134/S1063776108100178. - Cited References: 20 . - ISSN 1063-7761
РУБ Physics, Multidisciplinary
Рубрики:
NEMATIC DROPLETS
Кл.слова (ненормированные):
ABS resins -- Angular distribution -- Drop formation -- Drops -- Light -- Light scattering -- Phase transitions -- Plastic films -- Polymer films -- Polymers -- Polynomial approximation -- Powders -- Angle light scatterings -- Anomalous diffractions -- Crystal films -- Cylindrical symmetries -- Droplet sizes -- Induced phase transitions -- Optical wavelengths -- PDLC films -- Scattered lights -- Scattering approximations -- Single layers -- Liquid crystal polymers
Аннотация: A method is developed for modeling and computing the angular distribution of light scattered forward from a single-layer polymer-dispersed liquid-crystal (PDLC) film. The method is based on effective-medium approximation, anomalous diffraction approximation, and far-field single-scattering approximation. The angular distribution of forward-scattered light is analyzed for PDLC films with droplet size larger than the optical wavelength. The method can be used to study field- and temperature-induced phase transitions in LC droplets with cylindrical symmetry by measuring polarized scattered light intensity.

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Держатели документа:
[Loiko, V. A.
Konkolovich, A. V.
Misckevich, A. A.] Natl Acad Sci Belarus, BI Stepanov Phys Inst, Minsk 220072, Byelarus
[Maschke, U.] Univ Sci & Technol Lille, Lab Chim Macromol, F-59655 Villeneuve Dascq, France
[Zyryanov, V. Ya.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Stepanov Institute of Physics, National Academy of Sciences of Belarus, Minsk 220072, Belarus
Laboratoire de Chimie Macromoleculaire, Universite des Sciences et Technologies de Lille, Villeneuve d'Ascq Cedex F-59655, France
Kirenskii Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Loiko, V. A.; Maschke, U.; Zyryanov, V. Y.; Зырянов, Виктор Яковлевич; Konkolovich, A. V.; Misckevich, A. A.
}
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4.


   
    Director configurations in nematic droplets with tilted surface anchoring / M. N. Krakhalev [et al.] // Liq. Cryst. - 2017. - Vol. 44, Is. 2. - P. 355-363, DOI 10.1080/02678292.2016.1205225. - Cited References:32. - This work was supported by Russian Foundation for Basic Research (RFBR) under Grants 15-02-06924 and 16-32-00164 and Siberian Branch of the Russian Academy of Sciences (SB RAS) under Complex Program [II.2P 0358-2015-0010], and V.S.S. acknowledges financial support from RFBR [16-32-60036]. . - ISSN 0267-8292. - ISSN 1366-5855
РУБ Chemistry, Multidisciplinary + Crystallography + Materials Science, Multidisciplinary
Рубрики:
DISPERSED LIQUID-CRYSTALS
   RIGIDLY FIXED POLES

   ELECTRIC-FIELD

   POLYMER

Кл.слова (ненормированные):
Polymer dispersed liquid crystal -- nematic droplet -- director -- configuration -- boundary conditions -- surface anchoring strength -- optical -- texture
Аннотация: The polymer dispersed nematic liquid crystal (LC) with the tilted surface anchoring has been studied. The droplet orientational structures with two point surface defects – boojums and the surface ring defect – are formed within the films. The director tilt angle α = 40° ± 4° at the droplet interface and LC surface anchoring strength Ws ~ 10–6 (J m−2) have been estimated. The bipolar axes within the studied droplets of oblate ellipsoidal form can be randomly oriented are oriented randomly relatively to the ellipsoid axes as opposed to the droplets with homeotropic and tangential anchoring.

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Держатели документа:
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Krasnoyarsk, Russia.
Siberian Fed Univ, Krasnoyarsk, Russia.

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Sutormin, V. S.; Сутормин, Виталий Сергеевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Russian Foundation for Basic Research (RFBR) [15-02-06924, 16-32-00164]; Siberian Branch of the Russian Academy of Sciences (SB RAS) [II.2P 0358-2015-0010]; RFBR [16-32-60036]
}
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5.


   
    Anionic-cationic surfactant mixture providing the electrically controlled homeotropic surface anchoring of liquid crystals / M. N. Krakhalev [et al.] // J. Mol. Liq. - 2019. - Vol. 282: Suzdal Conference (2018, Suzdal, RUSSIA). - P. 57-62, DOI 10.1016/j.molliq.2019.02.132. - Cited References: 30. - The reported study was supported by the Belarusian Republican Foundation for Fundamental Research (project No X16P-110) and Russian Foundation for Basic Research (RFBR) (project No 16-53-00073). Mikhail N. Krakhalev and Vitaly S. Sutormin acknowledge financial support from RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science (project No 18-42-243006). . - ISSN 0167-7322. - ISSN 1873-3166
   Перевод заглавия: Смесь анионного и катионного сурфактантов, обеспечивающая электроуправляемое гомеотропное поверхностное сцепление в жидких кристаллах
РУБ Chemistry, Physical + Physics, Atomic, Molecular & Chemical
Рубрики:
IONIC MODIFICATION
   TRANSITION

   DROPLETS

   CONFIGURATION

   LAYER

Кл.слова (ненормированные):
Polymer dispersed liquid crystal -- Nematic droplet -- Ionic surfactant -- Anchoring transition -- Director configuration -- Optical texture
Аннотация: In search of a substance able to function as an anionic surfactant applied for the electrically-induced anchoring transitions in liquid crystals, the compound 4-heptyloxybenzoate benzyl dodecyldimethylammonium (HOBBDDA) has been synthesized. Its orienting influence on nematic liquid crystal 4-pentyl-4'-cyanobiphenyl (5CB) has been tested. HOBBDDA dissolved up to 1.4%in 50 droplets dispersed in polymer film does not change the tangential surface anchoring inherent to polyvinyl alcohol matrix used. Homeotropic surface anchoring is realized if the HOBBDDA content exceeds 1.7%. The molecules of the surfactant in 5CB dissociate into anions and cations. The anions modify the surface anchoring under the action of DC electric field both in the normal and inverse mode. The mixture of HOBBDDA and cetyltrimethylammonium bromide can function as a binary ionic cationic surfactant which significantly expands the prospects for using the ionic-surfactant method to control liquid crystal materials. (C) 2019 Elsevier B.V. All rights reserved.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.
Belarusian State Technol Univ, Minsk 220006, BELARUS.

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Sutormin, V. S.; Сутормин, Виталий Сергеевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Kuz'menok, N. M.; Mikhalyonok, S. G.; Bezborodov, V. S.; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Belarusian Republican Foundation for Fundamental Research [X16P-110]; Russian Foundation for Basic Research (RFBR) [16-53-00073]; RFBR, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science [18-42-243006]; International conference on Hole Burning, Single Molecule, and Related Spectroscopies: Science and Applications - 2018(XIII ; August 6-12, 2018 ; Suzdal - Moscow, Russia)
}
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6.


   
    Model to describe light scattering by polymer film containing droplets with inhomogeneous anchoring of liquid crystal molecules at the polymer-droplet interface: asymmetry effect in the angular distribution of light / A. V. Konkolovich [et al.] // Liq. Cryst. - 2019. - Vol. 46, Is. 9. - P. 1415-1427, DOI 10.1080/02678292.2019.1573331. - Cited References: 67. - The work was performed in the framework of an agreement on inter-academic cooperation between the National Academy of Sciences of Belarus and the SB RAS. It is supported by the Belarusian Republican Foundation for Fundamental Research (Project No. F18RA-003). MN Krakhalev thanks the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory and the Krasnoyarsk Regional Science Foundation (grant No. 18-42-243006). . - ISSN 0267-8292. - ISSN 1366-5855
РУБ Chemistry, Multidisciplinary + Crystallography + Materials Science, Multidisciplinary
Рубрики:
IONIC MODIFICATION
   NEMATIC DROPLETS

   COHERENT TRANSMITTANCE

Кл.слова (ненормированные):
Polymer-dispersed liquid crystal film -- liquid crystal droplets -- light transmission -- angular distribution of scattered light
Аннотация: A model to describe light scattering by polymer film containing of monolayer of liquid crystal droplets with inhomogeneous anchoring of liquid crystal molecules at the polymer-droplet interface is developed. It is based on the interference approximation of the wave scattering theory. The director field distribution in the droplet volume is determined by solving the free energy density minimization problem using the relaxation method. The spatial distribution of droplets in the layer is described by the hard disks model. The amplitude scattering matrices of individual droplets are found in the anomalous diffraction approximation. The algorithm for numerical analysis of the characteristics of light scattered in a polymer film containing droplets at homogeneous and inhomogeneous surface anchoring is described in terms of the partial filling factors of the monolayer film. Electrically controllable symmetry breaking effect of angular distribution of light scattered by films containing droplets with inhomogeneous anchoring at the polymer-droplet interface is described and experimentally confirmed.

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Держатели документа:
Natl Acad Sci Belarus, Stepanov Inst Phys, Minsk, BELARUS.
Russian Acad Sci, Fed Res Ctr, Krasnoyarsk Sci Ctr, Siberian Branch,Kirensky Inst Phys, Krasnoyarsk, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk, Russia.

Доп.точки доступа:
Konkolovich, A. V.; Miskevich, A. A.; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Shabanov, A. V.; Шабанов, Александр Васильевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Loiko, V. A.; Belarusian Republican Foundation for Fundamental Research [F18RA-003]; Krasnoyarsk Regional Science Foundation [18-42-243006]
}
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7.


   
    Polarization, transmission, and small-angle scattering of light by a polymer film with elongated droplets of nematic liquid crystal / V. A. Loiko [et al.] // J. Quant. Spectrosc. Radiat. Transf. - 2019. - Vol. 229. - P. 130-144, DOI 10.1016/j.jqsrt.2019.03.006. - Cited References: 29. - The work was performed in the framework of an agreement on inter-academic cooperation between the National Academy of Sciences of Belarus and the Siberian Branch of the Russian Academy of Sciences and supported by the Belarusian Republican Foundation for Fundamental Research (project no. F18RA-003 ). M.N. Krakhalev thanks the Russian Foundation for Basic Research and Government of Krasnoyarsk Territory , Krasnoyarsk Regional Fund of Science, grant no. 18-42-243006. . - ISSN 0022-4073
   Перевод заглавия: Поляризация, пропускание и малоугловое рассеяние света полимерной пленкой с вытянутыми каплями нематического жидкого кристалла
Кл.слова (ненормированные):
Polarization -- Polymer-dispersed liquid crystal -- Uniaxially stretched film -- Liquid crystal droplet -- Light transmittance -- Light scattering anisotropy
Аннотация: An optical-mechanical model has been developed to describe the transmittance, polarization and small-angle distribution of light scattered by an uniaxially-stretched polymer film containing the elongated ellipsoidal droplets of nematic liquid crystal. It is based on the approximations of Foldy-Twersky, anomalous diffraction, and single scattering. The spectral dependences of transmittances and polarizing abilities of the polymer dispersed liquid crystal films have been analyzed as well as the small-angle intensity distribution and the polarization degree of scattered light depending on the film thicknesses, refractive index of polymer matrix, sizes of droplets, their anisometry parameters, concentration, polydispersity, and optical axes orientation. The optical characteristics of films with homogeneous and inhomogeneous interfacial anchoring at the surface of liquid crystal droplets have been considered. The transmittance and polarizing ability of the films have been studied as functions of the angular aperture of the system recording scattered light. © 2019 Elsevier Ltd

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Держатели документа:
Stepanov Institute of Physics, National Academy of Sciences of Belarus, Niezalezhnastsi avenue 68-2, Minsk, 220072, Belarus
Kirensky Institute of Physics, Federal Research Center “Krasnoyarsk Scientific Center”, Siberian Branch, Russian Academy of Sciences, Academgorodok 50(38), Krasnoyarsk, 660036, Russian Federation
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Loiko, V. A.; Konkolovich, A. V.; Miskevich, A. A.; Prishchepa, O. O.; Прищепа, Оксана Олеговна; Shabanov, A. V.; Шабанов, Александр Васильевич; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич
}
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8.


    Parshin, A. M.
    Structural stability of nematic liquid crystal droplets in the light of the catastrophe theory / A. M. Parshin // Mod. Phys. Lett. B. - 2019. - Vol. 33, Is. 34. - Ст. 1950434, DOI 10.1142/S0217984919504347. - Cited References: 25. - The work was supported in part by the Siberian Branch of the Russian Academy of Sciences, integration Project No. 356-2018-0058. . - ISSN 0217-9849. - ISSN 1793-6640
   Перевод заглавия: Структурная устойчивость нематических жидкокристаллических капель в свете теории катастроф
Кл.слова (ненормированные):
Liquid crystal droplet -- polymer -- anchoring energy -- cups catastrophe -- control parameters -- structural transition
Аннотация: Dynamical systems and defects in liquid crystals (LCs) are described using topological methods. Meanwhile, the director field distribution in LC droplets is affected by many bulk and surface factors that are difficult to take into account in the topological analysis. Therefore, the structural instability of a LC droplet formed in a magnetic field has been investigated by us in the framework of the catastrophe theory. The effect of temperature on the control parameters of the cusp catastrophe, which leads to the transition from a bipolar structure with extended poles to the homogeneous or radial configuration, has been estimated. It has been established from the potential curves that the transition is induced by the variation in the LC director orientation between the potential minima related to the LC polymer anchoring energy and magnetic field. The interplay of the cusp catastrophe control parameters and anchoring parameters has been elucidated.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Akademgorodok 50, Krasnoyarsk, 660036 Russia
Siberian Federal University, pr. Svobodny 79, Krasnoyarsk 660041 Russia

Доп.точки доступа:
Паршин, Александр Михайлович
}
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9.


    Gardymova, Anna P..
    Optical textures and orientational structures in cholesteric droplets with conical boundary conditions / A. P. Gardymova, M. N. Krakhalev, V. Y. Zyryanov // Molecules. - 2020. - Vol. 25, Is. 7. - Ст. 1740, DOI 10.3390/molecules25071740. - Cited References: 53. - The authors are grateful for the financial support by the Russian Science Foundation (grant No. 18-72-10036). . - ISSN 1420-3049
РУБ Biochemistry & Molecular Biology + Chemistry, Multidisciplinary
Рубрики:
DISPERSED LIQUID-CRYSTALS
   CHIRAL NEMATIC DROPLETS

   IONIC MODIFICATION

Кл.слова (ненормированные):
cholesteric liquid crystal -- droplet -- optical texture -- orientational structure -- conical surface anchoring -- topological defect
Аннотация: Cholesteric droplets dispersed in polymer with conical boundary conditions have been studied. The director configurations are identified by the polarising microscopy technique. The axisymmetric twisted axial-bipolar configuration with the surface circular defect at the droplet’s equator is formed at the relative chirality parameter N0≤2.9 . The intermediate director configuration with the deformed circular defect is realised at 2.9
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Держатели документа:
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.
RAS, Fed Res Ctr KSC SB, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Krakhalev, M. N.; Крахалев, Михаил Николаевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Russian Science FoundationRussian Science Foundation (RSF) [18-72-10036]
}
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10.


   
    Polymer dispersed cholesteric liquid crystals with a toroidal director configuration under an electric field / A. P. Gardymova, M. N. Krakhalev, V. Ya. Zyryanov [et al.] // Polymers. - 2021. - Vol. 13, Is. 5. - Ст. 732. - P. 1-11, DOI 10.3390/polym13050732. - Cited References: 49. - This research was funded by Russian Science Foundation, Grant No. 20-72-10038 . - ISSN 2073-4360
Кл.слова (ненормированные):
cholesteric droplet -- orientational structure -- electric field -- polymer dispersted liquid crystal -- dichroic dye
Аннотация: The electro-optical properties of polymer dispersed liquid crystal (PDLC) films are highly dependent on the features of the contained liquid crystal (LC) droplets. Cholesteric LC droplets with homeotropic boundaries can form several topologically different orientational structures, including ones with single and more point defects, layer-like, and axisymmetric twisted toroidal structures. These structures are very sensitive to an applied electric field. In this work, we have demonstrated experimentally and by computer simulations that twisted toroidal droplets reveal strong structural response to the electric field. In turn, this leads to vivid changes in the optical texture in crossed polarizers. The response of droplets of different sizes were found to be equivalent in terms of dimensionless parameters. In addition, the explanation of this phenomenon showed a comparison of theoretical and experimental structural response curves aids to determine the shape of the droplet. Finally, we demonstrated that the addition of a dichroic dye allows such films to be used as optical filters with adjustable color even without polarizers.

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Держатели документа:
Institute of Engineering Physics and Radio Electronics, Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Faculty of Physics, Lomonosov Moscow State University, Moscow, 119991, Russian Federation

Доп.точки доступа:
Gardymova, A. P.; Krakhalev, M. N.; Крахалев, Михаил Николаевич; Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Gruzdenko, A. A.; Alekseev, A. A.; Rudyak, V. Yu.
}
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