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Ion exchange equilibria in simultaneous extraction of platinum(II, IV) and rhodium(III) from hydrochloric solutions / A. M. Mel'nikov [et al.] // Russ. J. Phys. Chem. A. - 2012. - Vol. 86, Is. 6. - P. 1018-1024, DOI 10.1134/S0036024412060192. - Cited References: 24 . - ISSN 0036-0244

РУБ Chemistry, Physical

Кл.слова (ненормированные):
platinum -- rhodium -- ionites -- ion exchange equilibria -- hydrochloric acid solutions -- sorption
Аннотация: Regularities of sorption extraction of platinum(II, IV) and rhodium(III) by anion exchangers of various physical and chemical structure in the presence of hydrochloric media were studied. It is established that AM-2B, Purolite A 500, and Purolite S 985 ionites adsorb complex anions of platinum metals employing mixed mechanism. A high affinity of the studied anionites for the studied complex anions of platinum and rhodium is established.

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Публикация на русском языке Ионообменные равновесия при совместном извлечении платины (II, IV) и родия (III) из солянокислых растворов [Текст] / А. М. Мельникова [и др.] // Журн. физ. химии. - 2012. - Т. 86 № 6. - С. 1129-1135

Держатели документа:
[Mel'nikov, A. M.] Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660041, Russia
[Kononova, O. N.
Pavlenko, N. I.] Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660049, Russia
[Krylov, A. S.] Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Mel'nikov, A. M.; Kononova, O. N.; Pavlenko, N. I.; Krylov, A. S.; Крылов, Александр Сергеевич
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Luminescent oxide materials obtained by the extraction pyrolytic method / T. N. Patrusheva [et al.] // Theor. Found. Chem. Eng. - 2012. - Vol. 46, Is. 4. - P. 379-383, DOI 10.1134/S0040579512040069. - Cited References: 13. - The work was supported by the Russian Foundation for Basic Research project (no. 10-03-00188a). . - ISSN 0040-5795

РУБ Engineering, Chemical

Кл.слова (ненормированные):
extraction pyrolytic method -- luminescent films -- X-ray diffraction -- luminescence spectra
Аннотация: Luminescent Y1.74Eu0.16Bi0.1O3 films have been obtained by extraction pyrolytic method. The formation of a crystalline structure in the film upon isothermal annealing in air at 600–650°C was established by X-ray diffraction. Single-phase Y1.74Eu0.16Bi0.1O3 films begin to exhibit luminescent properties after pyrolysis at 500°C; the intensity of luminescence increases with increasing temperature. The films annealed at 800°C consists of defect-free homogeneous crystallites with sizes of about 0.7 μm and demonstrats high luminescence intensity.

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Публикация на русском языке Оксидные люминисцентные материалы, полученные экстракционно-пиролитическим методом [Текст] / Т. Н. Патрушева [и др.] // Хим. технол. : ООО "Наука и технологии", 2010. - № 4. - С. 198-203

Держатели документа:
[Patrusheva, T. N.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Inst Phys, Krasnoyarsk 660036, Akademgorodok, Russia
Russian Acad Sci, NS Kurnakov Gen & Inorgan Chem Inst, Moscow 119991, Russia

Доп.точки доступа:
Patrusheva, T. N.; Патрушева, Тамара Николаевна; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Khval'ko, A. A.; Kolovskii, Yu.V.; Polyushkevich, A. V.; Khol'kin, A. I.
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Ion-exchange extraction of platinum(II,IV) from chloride solutions in the presence of iron(III) / O. N. Kononova [et al.] // Russ. J. Phys. Chem. A. - 2015. - Vol. 89, Is. 8. - P. 1464-1470, DOI 10.1134/S0036024415080166. - Cited References: 28 . - ISSN 0036-0244. - ISSN 1531-863X

РУБ Chemistry, Physical
Рубрики:
RHODIUM
Кл.слова (ненормированные):
platinum -- iron -- ionites -- sorption -- hydrochloric solutions -- sorption
Аннотация: The sorption concentration of platinum(II,IV) in the presence of iron(III) is studied on new samples of domestically produced ionites of the CYBBER brand. In comparing the sorption and kinetic properties of the new ionites to those of sorbents of the Purolite brand studied earlier, the higher effectiveness of the former is demonstrated via the extraction of platinum(II,IV) ions from strongly and weakly acidic chloride solutions. It is found that the sorbed platinum ions can be completely separated from iron(III) ions through separate elution using 0.01-0.001 M HCl (iron ions) and a thiourea solution (80 g/L) in 0.3 M H2SO4 (platinum ions).

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Публикация на русском языке Ионообменное извлечение платины (II, IV) в присутствии железа (III) из хлоридных растворов [Текст] / О. Н. Кононова [и др.] // Журн. физ. химии : Наука, 2015. - Т. 83 № 8. - С. 1305-1312

Держатели документа:
Institute of Nonferrous Metals and Materials Science, Siberian Federal University, Krasnoyarsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Kononova, O. N.; Duba, E. V.; Karplyakova, N. S.; Krylov, A. S.; Крылов, Александр Сергеевич
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Transparent conductive ITO coatings obtained by pyrolysis of metal extracts / T. N. Patrusheva [et al.] // J. Appl. Chem. Sci. Int. - 2015. - Vol. 3, Is. 1. - P. 21-28 . - ISSN 2395-3705
Кл.слова (ненормированные):
Indium-tin oxide -- thin films -- extraction-pyrolysis technique -- liquid precursors -- nanocrystalline structure
Аннотация: Thin films of indium-tin oxide (ITO) have been prepared by pyrolysis of liquid organic-extracts of indium and tin. The films were deposited on glass substrate in the atmospheric condition. Extraction-pyrolytic method adopted here uses cheap starting materials and provides the required stoichiometric ratio by mixing the stable liquid precursors in appropriate concentration. Thermal decomposition processes are induced in the narrow temperature range of 350–400°C. The zirconium-yttrium oxide (ZYO) sublayer was deposited on glass substrate in advance to provide homo epitaxial growth. This would induce reduction in intrinsic stress of the films due to matching in thermal expansion coefficient with ITO film. XPS studies showed the absence of impurity elements in these extraction-pyrolytic technique derived ITO films and the spectra is quite similar to that for ITO films deposited in vacuum environment. ITO film has a nanocrystalline structure with grain size of about 6 nm.

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Доп.точки доступа:
Patrusheva, T. N.; Патрушева, Тамара Николаевна; Snezhko, N. Yu.; Belousov, A. L.; Rizhenkov, A. V.; Mikhlin, Y. L.; Михлин, Юрий Леонидович; Kirik, S. D.; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Zharkov, S. M.; Жарков, Сергей Михайлович; Romanov, A. A.
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Features of the magnetic properties of La0.7Sr0.3MnO3 manganite films obtained by an extraction-pyrolysis method / G. S. Patrin [et al.] // Tech. Phys. Lett. - 2007. - Vol. 33, Is. 4. - P. 330-332, DOI 10.1134/S1063785007040177. - Cited References: 12 . - ISSN 1063-7850

РУБ Physics, Applied
Рубрики:
PHASE-SEPARATION
MAGNETORESISTANCE
Аннотация: We have experimentally studied the magnetic properties of manganite films obtained for first time using an extraction-pyrolysis technique. It is established that the characteristics of samples significantly depend on the conditions of final annealing. The annealing at temperatures T-a 970 K is accompanied by strong thermomagmetic effects. and the resulting films possess properties similar to those of spin glasses. When the annealig temperature is increased to T-a = 1020 K, the films exhibit magnetic properties typical of ferromagnetic systems.

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Держатели документа:
Russian Acad Sci, Siberian Div, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Krasnoyarsk State Univ, Krasnoyarsk 660041, Russia
Krasnoyarsk State Polytech Univ, Krasnoyarsk 660062, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Patrin, G. S.; Патрин, Геннадий Семёнович; Polyakova, K. P.; Полякова, Клавдия Павловна; Patrusheva, T. N.; Патрушева, Тамара Николаевна; Velikanov, D. A.; Великанов, Дмитрий Анатольевич
}
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Parameters of the effective singlet-triplet model for band structure of high-T-c cuprates by alternative approaches / M. M. Korshunov [et al.] // J. Exp. Theor. Phys. - 2004. - Vol. 99, Is. 3. - P. 559-565, DOI 10.1134/1.1809685. - Cited References: 48 . - ISSN 1063-7761

РУБ Physics, Multidisciplinary
Рубрики:
DENSITY-FUNCTIONAL CALCULATION
   TIGHT-BINDING METHOD
   COPPER OXIDES
   ENERGY-BANDS
   SUPERCONDUCTORS
   HOLE
   LA2-XSRXCUO4
   PLANE
   SR2CUO2CL2
   INSULATORS
Кл.слова (ненормированные):
Band structure -- Carbon dioxide lasers -- Copper oxides -- Doping (additives) -- Parameter estimation -- Electron systems -- Generalized tight binding (GTB) -- Parameters extraction -- Singlet triplet model -- Technetium compounds
Аннотация: We consider the problem of determining the parameters for high-T-c superconducting copper oxides. Alternative approaches, the ab initio LDA and LDA + U calculations and the generalized tight-binding (GTB) method for strongly correlated electron systems, are used to calculate hopping and exchange parameters of the effective singlet-triplet model for the CuO2 layer. The resulting parameters are in remarkably good agreement with each other and with parameters extracted from experiment. This set of parameters is proposed for proper quantitative description of the physics of hole-doped high-T-c cuprates in the framework of effective models. (C) 2004 MAIK "Nauka / Interperiodica".

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Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Div, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Met Phys, Ural Div, Ekaterinburg 620219, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Institute of Metal Physics, Ural Division, Russian Academy of Sciences, Ekaterinburg, 620219, Russian Federation

Доп.точки доступа:
Korshunov, M. M.; Коршунов, Максим Михайлович; Gavrichkov, V. A.; Гавричков, Владимир Александрович; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Pchelkina, Z. V.; Nekrasov, I. A.; Korotin, M. A.; Anisimov, V. I.
}
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Yttrium-containing endohedral metallofullerenes: Synthesis and extraction / G. N. Churilov [et al.] // Phys. Solid State. - 2017. - Vol. 59, Is. 8. - P. 1662-1665, DOI 10.1134/S1063783417080054. - Cited References:11. - This study was supported by the Ministry of Education and Science of the Russian Federation, Russian/Japanese Project, agreement no. 14.613.21.0010, ID RFMEFl61314X0010. . - ISSN 1063-7834. - ISSN 1090-6460

РУБ Physics, Condensed Matter
Рубрики:
FULLERENES
PRESSURE
PLASMA
Аннотация: Yttrium-containing endohedral metallofullerenes are synthesized in an RF arc discharge in the helium flow with embedded Y2O3. It is shown that the formation of the metallofullerenes depends on the helium pressure in a chamber; however, this dependence cannot be explained using the model of formation of conventional fullerenes without a guest atom in a molecule. The results of extraction of Y@C-82 by pyridine and carbon disulfide are reported. The pressure corresponding to the maximum yttrium-containing endohedral metallofullerene content is shown to be 60 kPa; under this pressure, extraction by carbon disulfide allows obtaining 27.1 wt % of the endohedral metallofullerene, while extraction by pyridine yields its amount of 17.3 wt %.

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Публикация на русском языке Эндоэдральные металлофуллерены с иттрием: синтез и выделение [Текст] / Г. Н. Чурилов [и др.] // Физ. тверд. тела. - 2017. - Т. 59 Вып. 8. - С. 1638-1641

Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
Fed Res Ctr KSC SB RAS, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Churilov, G. N.; Чурилов, Григорий Николаевич; Vnukova, N. G.; Внукова, Наталья Григорьевна; Tomashevich, E. V.; Dudnik, A. I.; Дудник, Александр Иванович; Glushchenko, G. A.; Глущенко, Гарий Анатольевич; Dubinina, I. A.; Дубинина, Ирина Александровна; Gulyaeva, U. E.; Гуляева, Ульяна Евгеньевна; Mel'nikova, E. I.; Ministry of Education and Science of the Russian Federation, Russian/Japanese Project [14.613.21.0010, RFMEFl61314X0010]
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Ion-exchange sorption of palladium(II) from hydrochloric acid solutions in the presence of silver(I) / O. N. Kononova [et al.] // Russ. J. Phys. Chem. A. - 2018. - Vol. 92, Is. 10. - P. 2053-2059, DOI 10.1134/S0036024418100138. - Cited References: 36 . - ISSN 0036-0244. - ISSN 1531-863X

РУБ Chemistry, Physical
Рубрики:
PLATINUM-GROUP METALS
   RECOVERY
   COMPLEXES
   CHLORIDE
   PD(II)
Кл.слова (ненормированные):
palladium -- silver -- hydrochloric acid solutions -- sorption -- sorptive extraction
Аннотация: The sorptive extraction of palladium(II) chloride complexes in the presence of silver(I) chloride complexes from 2 and 4 M aqueous solutions of HCl with a series of Purolite anionites with different functional groups is studied. An anion exchange mechanism of sorption is identified from Raman spectroscopy data. Kinetic properties that are inherent to the investigated ionites and allow the elution of palladium(II) and silver(I) after their extraction in a dynamic mode are revealed.

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Публикация на русском языке Ионообменная сорбция палладия (II) в присутствии серебра (I) из солянокислых растворов [Текст] / О. Н. Кононова [и др.] // Журн. физ. химии. - 2018. - Т. 92 № 10. - С. 1641-1647

Держатели документа:
Siberian Fed Univ, Inst Nonferrous Met & Mat Sci, Krasnoyarsk 660025, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Kononova, O. N.; Duba, E. V.; Medovikov, D. V.; Krylov, A. S.; Крылов, Александр Сергеевич
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    Ultrafast method of fullerenes extraction from carbon condensate / G. N. Churilov [et al.] // Fuller. Nanotub. Carbon Nanostruct. - 2019. - Vol. 27, Is. 3. - P. 225-232, DOI 10.1080/1536383X.2018.1543277. - Cited References: 46. - The authors are grateful to Alexey Popov (Leibniz Institute for Solid State and Materials Research, Dresden, German) for his contribution in conducting mass spectrometer studies. . - ISSN 1536-383X
   Перевод заглавия: Сверхбыстрый метод выделения фуллеренов из углеродного конденсата
Кл.слова (ненормированные):
solution extraction -- mechanical extraction -- fullerenes -- Soxhlet
Аннотация: The Soxhlet extraction method (SE) only used in the extraction of fullerenes from carbon condensate (CC) obtained in the fullerene production facility, which in the literature is often referred to as carbon black, does not provide complete extraction. Fullerenes can also be extracted from the CC suspension and the solvent by the mechanical extraction method (ME) and show higher degree of extraction efficiency. This method combined with filtration process takes only a few minutes and allows a significant reduction in solvent consumption. Extraction via the ME method application makes it possible to carry out extraction of fullerenes twenty times faster than by the SE method. It can be used as an independent method, bypassing the extraction by the SE method, and also as an additional one. Application of the ME method allows additional extraction of fullerenes weight percentage from the CC, after extracting fullerenes from it applying the SE method. In this instance the higher fullerenes prevail in the essences extracted by the ME method with their content reaching as high as 39.50 wt%. The obtained samples of fullerene mixtures (FM) are characterized by the methods of high-performance liquid chromatography and mass spectrometry. Analysis of the results shows that the composition of the FM, isolated by the ME method, differs from the compositions extracted via the ME method.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center "Krasnoyarsk Science Center SB RAS", Krasnoyarsk, Russia
Siberian Federal University, Av. Svobodny 79, 660041 Krasnoyarsk, Russia

Доп.точки доступа:
Churilov, G. N.; Чурилов, Григорий Николаевич; Elesina, V. I.; Елесина, Виктория Игоревна; Dudnik, A. I.; Дудник, Александр Иванович; Vnukova, N. G.; Внукова, Наталья Григорьевна
}
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10.

    Spin-dependent electrical hole extraction from low doped p-Si via the interface states in a Fe3Si/p-Si structure / A. S. Tarasov [et al.] // Semicond. Sci. Technol. - 2019. - Vol. 34, Is. 3. - Ст. 035024, DOI 10.1088/1361-6641/ab0327. - Cited References: 56. - The reported study was funded by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund by project. 18-42-243022 and supported in part by the Russian Foundation for Basic Research by project no. 18-32-00035. The work was partially supported by the Ministry of Education and Science of the Russian Federation and by Siberian Branch of the Russian Academy of Sciences (Project II.8.70) and Fundamental research program of the Presidium of the RAS no. 32 "Nanostructures: physics, chemistry, biology, basics of technologies" . - ISSN 0268-1242. - ISSN 1361-6641
   Перевод заглавия: Спин-зависимая электрическая экстракция дырок из низколегированного p-Si через интерфейсные состояния в структуре Fe3Si/p-Si

РУБ Engineering, Electrical & Electronic + Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
ALLOYS
Кл.слова (ненормированные):
spin accumulation -- interface states -- hybrid structures -- Hanle effect -- iron silicide
Аннотация: Spin accumulation effect in Fe3Si/p-Si structure with low boron doped silicon substrate was found. Calculated spin lifetimes are comparable with results reported earlier but for structures with highly doped semiconductors (SC) with or without a tunnel barrier introduced between the SC and ferromagnet (FM). Electrical characterization of a prepared Fe3Si/p-Si diode allowed the determination of possible reasons for the pronounced spin signal. Analysis of the forward bias I-V curve revealed a Schottky barrier at the Fe3Si/p-Si interface with a height of φBp = 0.57 eV. Then, using impedance spectroscopy, we observed interface states localized in the band gap of silicon with energy of E LS = 40 meV. Such states most probably cause the observed spin signal. We believe that in our experiment, spin-dependent hole extraction was performed via the interface states resulting in the minority spin accumulation in the silicon valence band. The observed effect paves the way to the development of different spintronic devices based on FM/SC structures without dielectric tunneling barriers.

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Держатели документа:
Fed Res Ctr KSC SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Engn Phys & Radio Elect, Krasnoyarsk 660041, Russia.

Доп.точки доступа:
Tarasov, A. S.; Тарасов, Антон Сергеевич; Lukyanenko, A. V.; Лукьяненко, Анна Витальевна; Rautskii, M. V.; Рауцкий, Михаил Владимирович; Bondarev, I. A.; Бондарев, Илья Александрович; Smolyakov, D. A.; Смоляков, Дмитрий Александрович; Tarasov, I. A.; Тарасов, Иван Анатольевич; Yakovlev, I. A.; Яковлев, Иван Александрович; Varnakov, S. N.; Варнаков, Сергей Николаевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Baron, F. A.; Барон, Филипп Алексеевич; Volkov, N. V.; Волков, Никита Валентинович; Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund [18-42-243022]; Russian Foundation for Basic Research [18-32-00035]; Ministry of Education and Science of the Russian Federation; Siberian Branch of the Russian Academy of Sciences [II.8.70]; Fundamental research program of the Presidium of the RAS [32]
}
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