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1.


    Ryzhkov, I. I.
    Convective stability of multicomponent fluids in the thermogravitational column / I. I. Ryzhkov, V. M. Shevtsova // Phys. Rev. E. - 2009. - Vol. 79, Is. 2. - Ст. 26308, DOI 10.1103/PhysRevE.79.026308. - Cited References: 26 . - ISSN 1539-3755
РУБ Physics, Fluids & Plasmas + Physics, Mathematical
Рубрики:
THERMAL-DIFFUSION
   SORET COEFFICIENT

   MIXTURES

   SEPARATION

   LIQUID

Кл.слова (ненормированные):
convection -- density -- flow instability -- Galerkin method -- heat transfer -- mass transfer -- thermal diffusion -- Binary mixtures -- Fluids -- Galerkin methods -- Linear stability analysis -- Ternary systems -- Thermal diffusion -- Planes -- Binary fluids -- Convective stabilities -- Cross-diffusion effects -- Density stratifications -- Individual components -- Linear stabilities -- Longitudinal instabilities -- Longitudinal waves -- Multi-component fluids -- Separation ratios -- Soret effects -- Stability problems -- Temperature gradients -- Ternary fluids -- Ternary mixtures -- Thermal diffusion coefficients -- Transversal waves -- Vertical axis -- Vertical directions -- System stability
Аннотация: A comprehensive linear stability analysis of convection in the thermogravitational column is first performed for multicomponent fluids. Two types of perturbations are investigated: Longitudinal waves propagating in vertical direction of the column and transversal waves propagating perpendicular to the vertical axis and temperature gradient. The stability problems are reduced to those without cross-diffusion effect by a special transformation. The calculations are performed for binary and ternary mixtures by the Galerkin method. It is found that in binary fluids, the onset of longitudinal instability can be monotonic or oscillatory depending on the separation ratio, which characterizes the Soret effect. The difference between stability characteristics of binary and ternary fluids is associated with different diffusion times of components in a ternary system. It is shown that the mechanism of transversal instability is related to the unstable density stratification in the column (in total or due to individual components). The unstable stratification can only be realized in fluids with negative Soret effect. The analogue of exchange of stabilities principle for a plane column with a multicomponent fluid is proved. The obtained results indicate that the thermogravitational column can be used for measuring diffusion and thermal diffusion coefficients in ternary and higher mixtures with one or several components having negative Soret effect.

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Держатели документа:
[Ryzhkov, Ilya I.
Shevtsova, Valentina M.] Univ Libre Bruxelles, Dept Chem Phys, MRC, B-1050 Brussels, Belgium
[Ryzhkov, Ilya I.] Inst Computat Modelling SB RAS, Krasnoyarsk 660036, Russia
ИВМ СО РАН
MRC, Department of Chemical Physics, Universite Libre de Bruxelles, av. F.D. Roosevelt 50, B-1050 Brussels, Belgium
Institute of Computational Modelling, SB, RAS, 660036 Krasnoyarsk, Russian Federation

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Shevtsova, V. M.
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2.


   
    Growth of carbon nanotubes inside porous anodic alumina membranes: Simulation and experiment / I. I. Ryzhkov, I. A. Kharchenko, E. V. Mikhlina [et al.] // Int. J. Heat Mass Transf. - 2021. - Vol. 176. - Ст. 121414, DOI 10.1016/j.ijheatmasstransfer.2021.121414. - Cited References: 57. - This work is supported by the Russian Foundation for Basic Research, Project 18-29-19078 . - ISSN 0017-9310
   Перевод заглавия: Рост углеродных нанотрубок внутри пористых анодных мембран из оксида алюминия: моделирование и эксперимент
Кл.слова (ненормированные):
Porous anodic alumina -- Ethanol pyrolysis -- Chemical vapour deposition -- Carbon nanotubes -- Mathematical modelling
Аннотация: Porous anodic alumina (PAA) membranes represent a widely used and extensively studied template for production of carbon nanotubes (CNT). The PAA–CNT membranes possess a number of unique properties, such as controllable nanotube geometry, size– and chemically–based selectivity as well as high water permeability. In this work, we first propose a combination of gas phase and surface reaction models to quantitatively describe the growth of carbon nanotubes in PAA membranes in a commercial CVD reactor. A complimentary experimental study of CNT formation from ethanol precursor with argon as a carrier gas is performed. A new method for characterizing carbon nanotubes geometry by SEM and TEM image processing of membrane cross–sections is proposed. The simulations show that the carbon growth rate (in nm/min) averaged over the membrane remains constant during the deposition process until the pore diameter becomes relatively small, and rapidly falls to zero after that. The carbon nanotube thickness near the membrane surface is slightly higher than that in the membrane center. The carbon growth rate increases with synthesis temperature and pressure, while it decreases with the argon flow rate. The dependence of carbon growth rate on the ethanol/water flow rate reaches maximum at some intermediate value. These results are supported by the experimental data obtained from SEM/TEM image processing. It is found that the SEM data provide overestimated values of nanotube diameter and thickness in comparison with the TEM data. The obtained results provide new insights into the CNT growth kinetics in nanoporous media, and develop quantitative guidelines for synthesis of CNT–PAA membranes with precisely controlled nanopore geometry. It also validates the combined homogenous / heterogeneous reaction model by comparison with carbon deposition kinetics on a nanometer scale.

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Держатели документа:
Institute of Computational Modelling SB RAS Akademgorodok 50–44, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodny 79, Krasnoyarsk, 660041, Russian Federation
Federal Research Center KSC SB RAS, Akademgorodok 50–38, Krasnoyarsk, 660036, Russian Federation
Reshetnev Siberian State University of Science and Technology, Krasnoyarsk, 660037, Russian Federation

Доп.точки доступа:
Ryzhkov, I. I.; Kharchenko, I. A.; Mikhlina, E. V.; Minakov, A. V.; Guzei, D. V.; Nemtsev, I. V.; Немцев, Иван Васильевич; Volochaev, M. N.; Волочаев, Михаил Николаевич; Korobko, A. V.; Simunin, M. M.
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3.


   
    Broadband Tamm plasmons in chirped photonic crystals for light-induced water splitting / M. V. Pyatnov, R. G. Bikbaev, I. V. Timofeev [et al.] // Nanomaterials. - 2022. - Vol. 12, Is. 6. - Ст. 928, DOI 10.3390/nano12060928. - Cited References: 41 . - ISSN 2079-4991
Кл.слова (ненормированные):
water splitting -- plasmon catalysis -- solar-to-hydrogen efficiency -- photocurrent
Аннотация: An electrode of a light-induced cell for water splitting based on a broadband Tamm plasmon polariton localized at the interface between a thin TiN layer and a chirped photonic crystal has been developed. To facilitate the injection of hot electrons from the metal layer by decreasing the Schottky barrier, a thin n-Si film is embedded between the metal layer and multilayer mirror. The chipping of a multilayer mirror provides a large band gap and, as a result, leads to an increase in the integral absorption from 52 to 60 percent in the wavelength range from 700 to 1400 nm. It was shown that the photoresponsivity of the device is 32.1 mA/W, and solar to hydrogen efficiency is 3.95%.

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Держатели документа:
Kirensky Institute of Physics, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Institute of Computer Modelling, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Pyatnov, M. V.; Пятнов, Максим Владимирович; Bikbaev, R. G.; Бикбаев, Рашид Гельмединович; Timofeev, I. V.; Тимофеев, Иван Владимирович; Ryzhkov, I. I.; Vetrov, S. Ya.; Ветров, Степан Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович
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4.


   
    The effect of copper and iron adsorption on the catalytic performance of alumina nanofiber / nanodiamond composite in sensing applications / N. O. Ronzhin, E. D. Posokhina, E. V. Mikhlina [et al.] // J. Phys. Chem. Solids. - 2022. - Vol. 167. - Ст. 110785, DOI 10.1016/j.jpcs.2022.110785. - Cited References: 68. - This work is supported by the Russian Foundation for Basic Research, Project 18–29–19078. The authors would like to express their special thanks to Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» for providing the equipment to ensure the accomplishment of this project . - ISSN 0022-3697
Кл.слова (ненормированные):
Nanodiamonds -- Alumina nanofibers -- Indicator system -- Copper ions -- Iron ions -- Phenol detection
Аннотация: Phenolic compounds are common environmental pollutants, which are used in many industries and contaminate water environment due to industrial wastewater discharge. Presently, there is an increasing demand for the development and improvement of inexpensive, easy-to-use analytical tools for in-situ detection of phenolic compounds. In this work, we investigate the effect of adsorption of Cu2+ and Fe2+ ions on the catalytic activity of a composite material based on alumina nanofibers (ANF) and detonation nanodiamonds (DND) in the co-oxidation of phenols with 4-aminoantipyrine in the presence of hydrogen peroxide. We have found more than two-fold increase of the catalytic activity for ANF + DND + Cu composite, while the activity of ANF + DND + Fe composite is found to decrease by several times in comparison with the original ANF + DND material. The results of FTIR analysis indicate that the adsorption of iron ions occurs with the formation of hydroxide surface groups and hydrogen bonds, which apparently block their catalytic activity in the Fenton redox cycle. The higher catalytic performance of AND + DND composite functionalized with copper ions makes it possible to detect two times lower concentrations of analytes (phenol and 4-chlorophenol) in comparison with the original composite. It is shown that the AND + DND + Cu composite provides a linear yield of the co-oxidation reaction product in a wide range of analyte concentrations (0.25–100 μM for phenol and 0.5–25 μM for 4-chlorophenol). Model experiments demonstrate the applicability of copper-functionalized composite as a reusable sensor for the determination of phenol in aqueous samples.

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Держатели документа:
Institute of Biophysics SB RAS, Akademgorodok 50/50, Krasnoyarsk, 660036, Russian Federation
Institute of Computational Modelling SB RAS, Akademgorodok 50/44, Krasnoyarsk, 660036, Russian Federation
Kirensky Institute of Physics SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Federal Research Center KSC SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodny 79, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Ronzhin, N. O.; Posokhina, E. D.; Mikhlina, E. V.; Shestakov, N. P.; Шестаков, Николай Петрович; Nemtsev, I. V.; Немцев, Иван Васильевич; Bondar, V. S.; Ryzhkov, I. I.
}
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5.


   
    High strength ceramic substrates based on perlite and foam silicates for filtration membranes / N. P. Fadeeva, M. V. Pavlov, I. A. Kharchenko [et al.] // Membr. Membr. Technol. - 2022. - Vol. 4, Is. 3. - P. 170-176, DOI 10.1134/S2517751622030040. - Cited References: 32. - The work was performed using the equipment of the Krasnoyarsk Regional Center for Collective Use of the Federal Research Center, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences. This work was partially supported by the Russian Foundation for Basic Research, grant no. 18-29-19078 . - ISSN 2517-7516
Кл.слова (ненормированные):
perlite -- foam silicate -- ceramic membranes -- substrates -- water permeability
Аннотация: Samples of two-layer ceramics based on polydisperse powder of the pearlite mineral and foam silicates possessing high compressive strength up to 50 MPa, thermal stability up to 1150°C, and water permeability of 272 m3/h m2 bar have been obtained. According to the X-ray powder diffraction analysis, the supporting substrate material is X-ray amorphous. The average pore size of the supporting substrate is 40 µm, while the average pore size of the modifying layer is 17 µm according to the bubble method and electron microscopy. The obtained materials are promising for use as substrates of microfiltration, ultrafiltration, and nanofiltration membranes.

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Публикация на русском языке Высокопрочные керамические подложки на основе перлита и пеносиликатов для фильтрационных мембран [Текст] / Н. П. Фадеева, М. В. Павлов, И. А. Харченко [и др.] // Мембраны и мембран. технол. - 2022. - Т. 12 № 3. - С. 192-199

Держатели документа:
Institute of Computational Modeling, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Specialized Design and Technological Bureau “Nauka” FRC KSC SB RAS, 50/45 Akademgorodok, Krasnoyarsk, 660036, Russian Federation
Federal Research Center, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Fadeeva, N. P.; Pavlov, M. V.; Kharchenko, I. A.; Харченко, Иван Александрович; Simunin, M. M.; Shabanova, K. A.; Шабанова, К. А.; Pavlov, V. F.; Ryzhkov, I. I.
}
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6.


   
    Ceramic substrates for filtration membranes based on fine fly ash microspheres / E. V. Fomenko, G. V. Akimochkina, A. G. Anshits [et al.] // Membr. Membr. Technol. - 2024. - Vol. 6, Is. 2. - P. 71-83, DOI 10.1134/S2517751624020033. - Cited References: 58. - The work was carried out with the support of the Russian Science Foundation, project no. 23-19-00269, using the equipment of the Krasnoyarsk Regional Center for Collective Use at the Krasnoyarsk Federal Research Center of the Siberian Branch of the Russian Academy of Sciences . - ISSN 2517-7516. - ISSN 2517-7524
Кл.слова (ненормированные):
fine microspheres -- fly ash -- ceramic materials -- filtration membranes
Аннотация: A procedure has been proposed for producing ceramic substrates for filtration membranes based on a narrow fraction of fine fly ash microspheres using cold uniaxial pressing followed by high-temperature firing. It has been shown that increasing the sintering temperature from 1000 to 1150°C leads to a decrease in open porosity from 40 to 24%, a decrease in the average pore size from 1.60 to 0.34 μm, and an increase in the compressive strength from 9.5 to 159 MPa. The resulting substrates are characterized by water permeability values of 1210, 310, 240, 170 L m−2 h−1 bar−1 at sintering temperatures of 1000, 1050, 1100 and 1150°C, respectively. Experiments on filtration of aqueous suspensions of fine microspheres (dav = 2.5 µm) and microsilica (dav = 1.9 μm) through a substrate produced at a sintering temperature of 1150°C have shown the rejection close to 100%. The proposed methodology for using ash waste in the production of membrane materials promotes the development of technologies for the integrated processing of thermal energy waste.

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Держатели документа:
Institute of Chemistry and Chemical Technology, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia
Institute of Computational Modelling, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia
Siberian Federal University, 660041, Krasnoyarsk, Russia
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, 660036, Krasnoyarsk, Russia

Доп.точки доступа:
Fomenko, E. V.; Akimochkina, G. V.; Anshits, A. G.; Fadeeva, N. P.; Kharchenko, I. A.; Elsuf’ev, E. V.; Shabanova, K. A.; Шабанова, Ксения Александровна; Maksimova, A. A.; Ryzhkov, I. I.
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