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1.


   
    Magneto-optical activity of crude oil and its heavy fractions / A. E. Sokolov [et al.] // Opt. Spectrosc. - 2012. - Vol. 112, Is. 5. - P. 755-762, DOI 10.1134/S0030400X12050165. - Cited References: 18. - This work was performed under Interdisciplinary Integration Project no. 118 of the Siberian Branch of the Russian Academy of Sciences (2009-2011). . - ISSN 0030-400X
РУБ Optics + Spectroscopy
Рубрики:
MAGNETIC CIRCULAR-DICHROISM
   SINGLE-CRYSTALS

   SPECTROSCOPY

   EPR

   ABSORBENCY

   PORPHYRIN

   SYSTEMS

Аннотация: We have experimentally studied optical and magneto-optical spectra of solutions of crude oils of different origin and their heavy fractions in the visible spectral range. Magnetic circular dichroism of oil in the wavelength range similar to 550 nm has been revealed. We show that the shape of the spectra of this dichroism depends on the origin of crude oil, with the magnetic dichroism magnitude being proportional to the concentration of the oil in the solution. A comparison of the data of magneto-optical spectroscopy with electron paramagnetic resonance spectra and chemical composition of samples has allowed us to conclude that the observed magneto-optical activity is determined by the occurrence of VO2+ complexes in the oil samples. The revealed magneto-optical activity of crude oil can form the basis of a unique method of analysis of the composition and properties of oils of different origin and heavy fractions thereof.

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Публикация на русском языке Магнитооптическая активность природной нефти и ее тяжелых фракций [Текст] / А. Э. Соколов [и др.] // Оптика и спектроскопия : Наука, 2012. - Т. 112 № 5. - С. 820-827

Держатели документа:
[Sokolov, A. E.
Edelman, I. S.
Zabluda, V. N.
Petrakovskaya, E. A.
Aleksandrovskii, A. S.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Shubin, A. A.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Trukhan, S. N.
Mart'yanov, O. N.] Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia

Доп.точки доступа:
Sokolov, A. E.; Соколов, Алексей Эдуардович; Edelman, I. S.; Эдельман, Ирина Самсоновна; Zabluda, V. N.; Заблуда, Владимир Николаевич; Petrakovskaya, E. A.; Петраковская, Элеонора Анатольевна; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Shubin, A. A.; Trukhan, S. N.; Mart'yanov, O. N.
}
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2.


   
    Magnetic circular dichroism analysis of crude oil / I. S. Edelman [et al.] // J. Struct. Chem. - 2016. - Vol. 57, Is. 2. - P. 382-389, DOI 10.1134/S0022476616020207. - Cited References:33. - The work was carried out with the partial support of the grant of the President of the Russian Federation (NSh-2886.2014.2), and in the frameworks of the base budget financing of Kirensky Institute of Physics and Boreskov Institute of Catalysis (Siberian Branch, Russian Academy of Sciences) (V.44.1.15.). . - ISSN 0022-4766. - ISSN 1573-8779
РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
Near-UV/visible spectroscopy
   Electron-spin-resonance

   Asphaltene dispersions

   Single-crystals

   Absorption

   VO2+

   EPR

   FLuorescence

   Aggregation

   Absorbency

Кл.слова (ненормированные):
magnetic circular dichroism (MCD) -- MCD spectroscopy -- absorption spectroscopy of oil
Аннотация: Optical and magneto-optical properties of solutions of crude oil of different origin (i.e., taken from different fields) are studied in the visible and near-UV region of optical emission. Magnetic circular dichroism (MCD) spectra of oil are obtained in the vicinity of wavelengths of ~410 nm, 533 nm, and 576 nm. It is demonstrated that the intensity of the MCD signal depends on the origin of crude oil, and it is proportional to the oil concentration in the solution. The comparison of the magneto-optical spectroscopy data with the chemical composition of samples allows us to conclude that the observed magneto-optical activity is determined by the presence of VO2+ complexes in the oil samples studied. The revealed magneto-optical activity of conventional oil can form a basis of a new method for the analysis of the composition and properties of oil of different origin.

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Публикация на русском языке Исследование природной нефти с помощью спектроскопии магнитного кругового дихроизма [Текст] / И. С. Эдельман [и др.] // Журн. структ. химии. - 2016. - Т. 57 № 2. - С. 394-401

Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk, Russia.
Siberian Fed Univ, Krasnoyarsk, Russia.
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk, Russia.

Доп.точки доступа:
Edelman, I. S.; Эдельман, Ирина Самсоновна; Sokolov, A. E.; Соколов, Алексей Эдуардович; Zabluda, V. N.; Заблуда, Владимир Николаевич; Shubin, A. A.; Martyanov, O. N.; Russian Federation [NSh-2886.2014.2]; Kirensky Institute of Physics (Siberian Branch, Russian Academy of Sciences) [V.44.1.15]; Boreskov Institute of Catalysis (Siberian Branch, Russian Academy of Sciences) [V.44.1.15]
}
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3.


   
    Two-phase paramagnetic-ferromagnetic state of La0.7Pb0.3MnO3 single-crystal lanthanum manganite / N. V. Volkov [et al.] // Phys. Solid State. - 2002. - Vol. 44, Is. 7. - P. 1350-1354, DOI 10.1134/1.1494635. - Cited References: 17 . - ISSN 1063-7834
РУБ Physics, Condensed Matter
Рубрики:
COLOSSAL MAGNETORESISTANCE
   MAGNETIC-RESONANCE

   DOPED MANGANITES

   LA1-XCAXMNO3

   SEPARATION

   TRANSITION

   RELAXATION

   EPR

Аннотация: Two phases, paramagnetic and ferromagnetic, were shown by the magnetic resonance method to coexist below the temperature T-C in La0.7Pb0.3MnO3 single crystals exhibiting colossal magnetoresistance. The magnetic resonance spectra were studied in the frequency range 10-78 GHz. The specific features in the behavior of the spectral parameters were observed to be the strongest at the temperatures corresponding to the maximum magnetoresistance in the crystals. The concentration ratios of the paramagnetic and ferromagnetic phases in the samples were found to be sensitive to variations in temperature and external magnetic field. This behavior suggests realization of the electronic phase separation mechanism in the system under study. (C) 2002 MAIK "Nauka/Interperiodica".

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Div, Krasnoyarsk 660036, Russia
ИФ СО РАН
Kirensky Institute of Physics, Siberian Division, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Volkov, N. V.; Волков, Никита Валентинович; Petrakovskii, G. A.; Петраковский, Герман Антонович; Vasil'ev, V. N.; Sablina, K. A.; Саблина, Клара Александровна
}
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4.


    Ovchinnikov, S. G.
    Weak Ferromagnetism along the Triad Axis and the Basal Anisotropy Caused by the Dzyaloshinskii-Moriya Interaction and the Cubic Electric Field of the FeBO3 Crystal / S. G. Ovchinnikov, V. V. Rudenko, A. M. Vorotynov // J. Exp. Theor. Phys. - 2019. - Vol. 128, Is. 3. - P. 443-449, DOI 10.1134/S1063776119020110. - Cited References: 18 . - ISSN 1063-7761. - ISSN 1090-6509
Рубрики:
MN2+
   EPR

Аннотация: Based on the spin Hamiltonian and taking into account the cubic invariant of the crystal field and the Dzyaloshinskii-Moriya interaction, the weak ferromagnetic moment along the triad axis and the basal anisotropy of FeBO3 crystals are calculated in the approximation of second-order perturbation theory.

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Публикация на русском языке Овчинников, Сергей Геннадьевич. Слабый ферромагнетизм вдоль оси третьего порядка и базисная анизотропия, вызванные взаимодействием Дзялошинского-Мория и кубическим электрическим полем кристаллов FeBO3 [Текст] / С. Г. Овчинников, В. В. Руденко, А. М. Воротынов // Журн. эксперим. и теор. физ. - 2019. - Т. 155 Вып. 3. - С. 514-521

Держатели документа:
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Rudenko, V. V.; Руденко, Валерий Васильевич; Vorotynov, A. M.; Воротынов, Александр Михайлович; Овчинников, Сергей Геннадьевич
}
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5.


   
    Competitive site occupation toward improved quantum efficiency of SrLaScO4:Eu red phosphors for warm white LEDs / Z. Y. Yang, G. C. Liu, Y. F. Zhao [et al.] // Adv. Opt. Mater. - 2022. - Vol. 10. Is. 6. - Ст. 2102373, DOI 10.1002/adom.202102373. - Cited References: 42. - This research was supported by the International Cooperation Project of National Key Research and Development Program of China (Program No. 2021YFE0105700), National Natural Science Foundation of China (Grant Nos. 51972118 and 51961145101), Guangzhou Science & Technology Project (Project No. 202007020005), the State Key Laboratory of Luminescent Materials and Devices (Grant No. Skllmd-2021-09), China Postdoctoral Science Foundation (Grant No. 2021M691053), and the Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program (Program No. 2017BT01X137). This work was also funded by RFBR according to the research Project No. 19-52-80003 and the NRF International: SA/China Joint Research Programme 2021 - CHIN2002265 06921 UID 132785 . - ISSN 2195-1071
   Перевод заглавия: Конкурентное заселение позиций для повышения квантовой эффективности красных люминофоров SrLaScO4:Eu для тепло-белых светодиодов
РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
LUMINESCENCE
   EUROPIUM

   BLUE

   EU2+

   STABILIZATION

   EPR

Кл.слова (ненормированные):
light-emitting diodes -- photoluminescence -- red emission
Аннотация: The discovery of Eu2+-doped high-efficiency red phosphors remains a vital challenge for white light-emitting diode (WLED) applications. It is therefore urgent to find effective strategies managing the oxidation state to help reduce Eu3+ to Eu2+ and accordingly increase the photoluminescence quantum yield (PLQY). Herein, a new red-emitting SrLaScO4:Eu phosphor is designed, and the PLQY is enhanced from 13% to 67% under 450 nm excitation by employing (NH4)2SO4-assisted sintering. Combined structural analysis, optical spectroscopy, and theoretical calculation reveal that predominant Eu2+ prefers to occupy the Sr2+ sites in the SrLaScO4 enabling red emission, and a competitive site occupation of Eu3+ in La3+ can be restrained, and the reduction mechanism of Eu3+ to Eu2+ originating from the (NH4)2SO4 addition is analyzed. The fabricated WLED device using red-emitting SrLaScO4:Eu and yellow-emitting Y3(Al,Ga)5O12:Ce3+ exhibits a high color-rendering index of 86.7 at a low correlated color temperature of 4005 K. This work provides a feasible reduction strategy for guiding the development of high-efficiency Eu2+-doped red phosphor for WLED applications.

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Держатели документа:
South China Univ Technol, State Key Lab Luminescent Mat & Devices, Guangdong Prov Key Lab Fiber Laser Mat & Appl Tec, Sch Mat Sci & Engn, Guangzhou 510641, Peoples R China.
City Univ Hong Kong, Dept Chem, Kowloon, Hong Kong 999077, Peoples R China.
KSC SB RAS, Lab Crystal Phys, Kirensky Inst Phys, Fed Res Ctr, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Engn Phys & Radioelect, Krasnoyarsk 660041, Russia.
Kemerovo State Univ, Res & Dev Dept, Kemerovo 650000, Russia.
Univ Free State, Dept Phys, POB 339, ZA-9300 Bloemfontein, South Africa.
South China Univ Technol, Sch Phys & Optoelect, Guangzhou 510641, Peoples R China.

Доп.точки доступа:
Yang, Zhiyu; Liu, Gaochao; Zhao, Yifei; Zhou, Yayun; Qiao, Jianwei; Molokeev, M. S.; Молокеев, Максим Сергеевич; Swart, Hendrik C.; Xia, Zhiguo; International Cooperation Project of National Key Research and Development Program of China [2021YFE0105700]; National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [51972118, 51961145101]; Guangzhou Science & Technology Project [202007020005]; State Key Laboratory of Luminescent Materials and Devices [Skllmd-2021-09]; China Postdoctoral Science FoundationChina Postdoctoral Science Foundation [2021M691053]; Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BT01X137]; RFBRRussian Foundation for Basic Research (RFBR) [19-52-80003]; NRF International: SA/China Joint Research Programme 2021 [CHIN2002265 06921 UID 132785]
}
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