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Structural investigation of biogenic ferrihydrite nanoparticles dispersion / M. . Balasoiu [et al.] // Optoelectron. Adv. Mater.-Rapid Commun. - 2010. - Vol. 4, Is. 12. - P. 2136-2139. - Cited References: 21. - The financial support from the Grants No.224 it.7 and No.56 it.5 of the Romanian Governmental Plenipotentiary at JINR and the support from the JINR theme No. 04-4-1069-2009/2011 are acknowledged. S.S. Abramchyuk (Advanced Technologies Center, Moscow) for the HRTEM images is acknowledged. . - ISSN 1842-6573

РУБ Materials Science, Multidisciplinary + Optics
Рубрики:
S-LAYER PROTEINS
   METAL NANOPARTICLES
   BIOLOGICAL SYNTHESIS
   BIOSYNTHESIS
   MICROORGANISMS
   FUNGI
Кл.слова (ненормированные):
Bacterial nanoparticles -- Ferrihydrite -- Small angle X-ray scattering -- High-resolution electron microscopy
Аннотация: Structural properties of biogenic ferrihydrite nanoparticles produced by bacteria Klebsiella oxytoca are investigated. Investigations of morphology and size of particles dispersed in water by means of high-resolution transmission electron microscopy and small angle X-ray scattering measurements were performed. By model calculations followed by fitting procedure the structural parameters of a cylinder of radius R = 4.87 +/- 0.02 nm and height L = 2.12 +/- 0.04 nm are obtained.

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Держатели документа:
[Balasoiu, M.
Kuklin, A. I.
Soloviov, D. V.
Arzumanian, G. M.] Joint Inst Nucl Res, Dubna 141980, Russia
[Ischenko, L. A.
Stolyar, S. V.
Iskhakov, R. S.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Raikher, Y. L.] RAS, Ural Branch, Inst Continuum Media Mech, Perm 614013, Russia
[Kurkin, T. S.] RAS, Inst Synthet Polymer Mat, Moscow 117393, Russia
[Balasoiu, M.
Aranghel, D.] Natl Inst Phys & Nucl Engn, Bucharest, Romania
[Stolyar, S. V.
Iskhakov, R. S.] RAS, Siberian Branch, Inst Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Balasoiu, M.; Ischenko, L. A.; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Raikher, Y. L.; Kuklin, A. I.; Soloviov, D. V.; Kurkin, T. S.; Aranghel, D.; Arzumanian, G. M.
}
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Механизм формирования нескомпенсированного магнитного момента в наночастицах ферригидрита бактериального происхождения / Д. А. Балаев [и др.] // Письма в Журн. эксперим. и теор. физ. - 2013. - Т. 98, Вып. 3. - С. 160-164DOI 10.7868/S0370274X13150046
Аннотация: Исследованы магнитные свойства антиферромагнитных (AF) наночастиц ферригидрита FeOOH• nH2O размером 3-7 нм, являющихся продуктом жизнедеятельности бактерий Klebsiella oxitoca. Частицы демонстрируют суперпарамагнитное поведение. Характерная температура блокировки составляет 23 K. Анализ кривых намагничивания показал, что механизмом формирования нескомпенсированного магнитного момента частиц является случайная раскомпенсация магнитных моментов ионов Fe3+ как на поверхности, так и в объеме AF-частицы. При этом реализуется обменная связь между нескомпенсированным магнитным моментом частицы и ее AF "ядром". Установлено, что температурная зависимость нескомпенсированного магнитного момента подчиняется закону {\sim} (1-\text{const}T. ).

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Переводная версия Mechanism of the formation of an uncompensated magnetic moment in bacterial ferrihydrite nanoparticles. - [Б. м. : б. и.]

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Балаев, Дмитрий Александрович; Balaev, D. A.; Дубровский, Андрей Александрович; Dubrovskii, A. A.; Красиков, Александр Александрович; Столяр, Сергей Викторович; Stolyar S.V.; Исхаков, Рауф Садыкович; Iskhakov, R. S.; Ладыгина, Валентина Петровна; Хилажева, Е. Д.
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Mechanism of the formation of an uncompensated magnetic moment in bacterial ferrihydrite nanoparticles / D. A. Balaev [et al.] // JETP Letters. - 2013. - Vol. 98, Is. 3. - P. 139-142DOI 10.1134/S0021364013160029
Аннотация: The magnetic properties of antiferromagnetic nanoparticles of FeOOH · nH2O with sizes of 3–7 nm, which are products of vital functions of Klebsiella oxytoca bacteria, have been studied. Particles exhibit a superparamagnetic behavior. The characteristic blocking temperature is 23 K. Analysis of the magnetization curves shows that the mechanism of the formation of the uncompensated magnetic moment of particles is the random decompensation of magnetic moments of Fe3+ ions both on the surface and in the bulk of the antiferromagnetic particle. In this mechanism, the exchange coupling between the uncompensated magnetic moment of the particle and its antiferromagnetic “core” is implemented. It has been found that the temperature dependence of the uncompensated magnetic moment has the form 1 — constT 2.

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Публикация на русском языке Механизм формирования нескомпенсированного магнитного момента в наночастицах ферригидрита бактериального происхождения. - [S. l. : s. n.]

Держатели документа:
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Int Res Ctr Studies Extreme States Organism, Presidium Krasnoyarsk Res Ctr, Krasnoyarsk 660036, Russia;

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Krasikov, A. A.; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Khilazheva, E. D.
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Biogenic ferrihydrite nanoparticles doped with gadolinium [Текст] / S. V. Stolyar [и др.] // V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism : abstracts. - Vladivostok : FEFU, 2013. - P232 . - ISBN 978-5-7444-3124-2

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, V. P.; Ладыгина, Валентина Петровна; Ishchenko, L. A.; Ищенко Л. А.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; Sept. ; 15-21 ; Vladivostok)
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Magnetic properties of biogenic ferrihydrite nanoparticles [Текст] / D. A. Balaev [и др.] // V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism : abstracts. - Vladivostok : FEFU, 2013. - P235 . - ISBN 978-5-7444-3124-2

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Popkov, S. I.; Попков, Сергей Иванович; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Ладыгина, Валентина Петровна; Khilazheva, E. D.; Хилажева Е.Д.; Krasikov, A. A.; Красиков, Александр Александрович; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; Sept. ; 15-21 ; Vladivostok)
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    Structure and magnetic properties of biogenic ferrihydrite nanoparticles doped with gadolinium / S. V. Stolyar [et al.] // J. Sib. Fed. Univ. Math. Phys. - 2013. - Vol. 6, Is. 3. - P. 358-365 ; Журн. СФУ. Сер. "Математика и физика" . - ISSN 1997-1397
   Перевод заглавия: Структура и магнитные свойства биогенных наночастиц ферригидрита, легированных гадолинием
Кл.слова (ненормированные):
ferrihydrite nanoparticle -- bacterial culture Klebsiela oxytoca -- Mössbauer spectroscopy -- gadolinium doping
Аннотация: Bacterial culture Klebsiella oxytoca was grown in a Lovley medium at various concentrations of gadolinium salt. Biogenic magnetic nanoparticles of ferrihydrite were investigated by Mossbauer spectroscopy and magnetization curves were obtained. The results of structural studies showed that iron Fe(5) takes new position when cultivating is carried out in medium with high concentrations of gadolinium. It was found that gadolinium is fit into the crystal structure of ferrihydrite. These results are consistent with the analysis of the magnetization curves.

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Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, V. P.; Ischenko, L. A.; Iskhakov, R. S.; Исхаков, Рауф Садыкович

}
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Gurevich, Y. L.
Self-assembly of superparamagnetic ferrihydrite nanoparticles / Y. L. Gurevich, Yu. I. Mankov, R. G. Khlebopros // Dokl. Phys. - 2013. - Vol. 58, Is. 11. - P. 478-481, DOI 10.1134/S1028335813110104. - Cited References: 15. - This work was supported by the Russian Foundation for Basic Research, project nos. 08-08-00427_a and 10-08-00278_a, and by the Siberian Branch, Russian Academy of Sciences, Integration project no. 21. . - ISSN 1028-3358

РУБ Mechanics + Physics, Multidisciplinary
Рубрики:
CHAINS
CLUSTERS
Аннотация: A study was conducted to estimate the possibility of formation of chains of superparamagnetic nanoparticles of iron oxyhydroxides synthesized in a bacteria culture. The self-assembly of biogenic nanoparticles distinguished by low values of magnetization and small sizes is assumed to proceed due to the forces of magnetic dipole dipole interaction as an initial mechanism of aggregation and exchange-interaction forces, which provide the stability of chains. The microphotographs demonstrate the self-assembly of anisotropic cobalt-doped ferrihydrite nanoparticles in aggregates of ellipsoidal shape with sizes of about 550 × 300 nm and a platelike shape of 50-100 nm thick. The aggregates, in turn, are combined from blocks, which include a restricted number of nanoparticles of about 5 nm in diameter and have the shape of rods of 50-100 × 12 nm in size. The energy of degaussing fields of chains is reasonably high, which forces them to form two and three dimensional structures in which the compensation of such fields is provided.

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Публикация на русском языке Самосборка суперпарамагнитных наночастиц ферригидрита. - [S. l. : s. n.]

Держатели документа:
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia
Russian Acad Sci, Kirenskii Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia;

Доп.точки доступа:
Mankov, Yu.I.; Маньков, Юрий Иннокентьевич; Khlebopros, R. G.; Хлебопрос, Рэм Григорьевич; Russian Foundation for Basic Research [08-08-00427_a, 10-08-00278_a]; Siberian Branch, Russian Academy of Sciences, Integration project [21]
}
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Гуревич, Юрий Леонидович.
Самосборка суперпарамагнитных наночастиц ферригидрита / Ю. Л. Гуревич, Ю. И. Маньков, Р. Г. Хлебопрос // Доклады Академии наук. - 2013. - Т. 453, № 3. - С. 268-271DOI 10.7868/S0869565213330098

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Переводная версия Self-assembly of superparamagnetic ferrihydrite nanoparticles. - [Б. м. : б. и.]

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Маньков, Юрий Иннокентьевич; Man'kov, Yu.I.; Хлебопрос, Рэм Григорьевич; Khlebopros, R. G.
}
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Magnetic properties and the mechanism of formation of the uncompensated magnetic moment of antiferromagnetic ferrihydrite nanoparticles of a bacterial origin / D. A. Balaev [et al.] // J. Exp. Theor. Phys. - 2014. - Vol. 119, Is. 3. - P. 479-487, DOI 10.1134/S1063776114080044. - Cited References: 42. - This work was supported by the Ministry of Education and Science of the Russian Federation (state contract in 2014-2016) and a program of the Siberian Branch of the Russian Academy of Sciences. . - ISSN 1063-7761. - ISSN 1090-6509

РУБ Physics, Multidisciplinary
Рубрики:
NIO NANOPARTICLES
   EXCHANGE BIAS
   HYSTERESIS ANOMALIES
   FERRITIN
   SURFACE
   MOSSBAUER
   ORDER
   SIZE
Аннотация: The magnetic properties of the superparamagnetic ferrihydrite nanoparticles that form as a result of the vital activity of Klebsiella oxytoca bacteria are studied. Both an initial powder with an average number of iron atoms N Fe ∼ 2000–2500 in a particle and this powder after annealing at 140°C for 3 h in air are investigated. The following substantial modifications of the magnetic properties of the ferrihydrite nanoparticles are detected after annealing: the superparamagnetic blocking temperature increases from 23 to 49.5 K, and the average magnetic moment of a particle increases (as follows from the results of processing of magnetization curves). The particles have antiferromagnetic ordering, and the magnetic moment resulting in the superparamagnetism of the system appears due to random spin decompensation inside the particle. For this mechanism, the number of uncompensated spins is proportional to the number of magnetically active atoms raised to the one-half power, and this relation holds true for the samples under study at a good accuracy. The possible causes of the detected shift of magnetic hysteresis loops at low temperatures upon field cooling are discussed.

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Публикация на русском языке Магнитные свойства и механизм формирования нескомпенсированного магнитного момента антиферромагнитных наночастиц ферригидрита бактериального происхождения [Текст] / Д. А. Балаев [и др.] // Журн. эксперим. и теор. физ. : Наука, 2014. - Т. 146 Вып. 3. - С. 546–556

Держатели документа:
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660041, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Int Sci Ctr Extreme States Organisms, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Ладыгина, Валентина Петровна; Ishchenko, L. A.; Ищенко, Л. А.; Ministry of Education and Science of the Russian Federation; Siberian Branch of the Russian Academy of Sciences
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10.

Magnetic properties of ferrihydrite nanoparticles of bacterial origin / D. A. Balaev [et al.] // Moscow Int. Symp. on Magnet. (MISM-2014) : 29 June - 3 July 2014 : вook of abstracts. - 2014. - Ст. 330PO-J2-8. - P. 225 . - ISBN 978-5-91978-025-0

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Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Bayukov, O. A.; Баюков, Олег Артемьевич; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Ishchenko, L. A.; Ищенко Л. А.; Moscow International Symposium on Magnetism(6 ; 2014 ; June-July ; Moscow)
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11.

The effect of low-temperature heat treatment on the magnetic properties of biogenic ferrihydrite nanoparticles / D. A. Balaev [et al.] // Tech. Phys. Lett. - 2015. - Vol. 41, Is. 7. - P. 705-709, DOI 10.1134/S1063785015070172. - Cited References: 12. - This study was supported in part by the Ministry of Education and Science of the Russian Federation in the framework of a federal program for 2014-2016. . - ISSN 1063-7850

РУБ Physics, Applied
Рубрики:
BACTERIAL FERRIHYDRITE
MOSSBAUER
Аннотация: We have studied the influence of low-temperature heat treatment (annealing) on the magnetic properties of superparamagnetic nanoparticles of biogenic ferrihydrite. It is established that the proposed treatment leads to an increase in the blocking temperature and magnetic susceptibility of samples. After subsequent exposure in aqueous medium, the magnetic properties of annealed sol remain constant. The character of changes in the magnetic properties of samples studied shows that low-temperature heat treatment allows nanoparticle dimensions to be increased in a controlled way. © 2015, Pleiades Publishing, Ltd.

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Публикация на русском языке Влияние низкотемпературной термообработки на магнитные свойства наночастиц ферригидрита биогенного происхождения [Текст] / Д. А. Балаев [и др.] // Письма в Журн. техн. физ. : Санкт-Петербургская издательская фирма "Наука" РАН, 2015. - Т. 41 Вып. 14. - С. 88-96

Держатели документа:
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Dubrovskii, A. A.; Дубровский, Андрей Александрович; Bayukov, O. A.; Баюков, Олег Артемьевич; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Ладыгина, Валентина Петровна; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Ministry of Education and Science of the Russian Federation
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12.

Production and magnetic properties of biogenic ferrihydrite nanoparticles / S. V. Stolyar [et al.] // J. Optoelectron. Adv. Mater. - 2015. - Vol. 17, Is. 7-8. - P. 968-972. - Cited References:14. - Support by project No3072 of the basic part of the state task of Ministry of Education and Science of Russian Federation is acknowledged. . - ISSN 1454. - ISSN 1841-7132. -

РУБ Materials Science, Multidisciplinary + Optics + Physics, Applied
Рубрики:
FERRITIN
Кл.слова (ненормированные):
Magnetic nanoparticles -- Biosynthesis -- Ferrihydrite -- superparamagnetics
Аннотация: In present work the magnetic properties of biomineral ferrihydrite nanoparticles (biomass), produced by Klebsiella oxytoca strain and the nanoparticles obtained by drying the sol (so!), made on the basis of biomineral ferrihydrite nanoparticles have been studied. Ferrihydrite nanoparticles are formed on the surface of the bacterial cell.

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Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia.
SB RAS, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
SB RAS, Int Sci Ctr Organism Extreme States Res Attached, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Balaev, D. A.; Балаев, Дмитрий Александрович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ishchenko, L. A.; Ищенко, Л. А.; Ladygina, V. P.; Yaroslavtsev, R. N.; Ministry of Education and Science of Russian Federation [3072]
}
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13.

Ferrihydrite nanoparticles produced by chemical and biological methods / R. N. Yaroslavtsev [и др.] // International Baltic Conference on Magnetism (IBCM-2015) : book of abstracts. - 2015. - P. 96

Доп.точки доступа:
Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Stolyar, S. V.; Столяр, Сергей Викторович; Balaev, D. A.; Балаев, Дмитрий Александрович; Ladygina, V. P.; Bayukov, O. A.; Баюков, Олег Артемьевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; International Baltic Conference on Magnetism: Focus on Biomedical Aspects (2015 ; 30 Aug.-3 Sept. ; Svetlogorsk); Балтийский федеральный университет им. И. Канта
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14.

Specific features of magnetic properties of ferrihydrite nanoparticles of bacterial origin: A shift of the hysteresis loop / D. A. Balaev [et al.] // Phys. Solid State. - 2016. - Vol. 58, Is. 2. - P. 287-292, DOI 10.1134/S1063783416020050. - Cited References: 23. - This study was supported by the Ministry of Education and Science of the Russian Federation within the state contract for 2014-2016. . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
Exchange bias
NiO nanoparticles
Anomalies
Аннотация: The results of the experimental investigation into the magnetic hysteresis of systems of superparamagnetic ferrihydrite nanoparticles of bacterial origin have been presented. The hysteresis properties of these objects are determined by the presence of an uncompensated magnetic moment in antiferromagnetic nanoparticles. It has been revealed that, under the conditions of cooling in an external magnetic field, there is a shift of the hysteresis loop with respect to the origin of the coordinates. These features are associated with the exchange coupling of the uncompensated magnetic moment and the antiferromagnetic “core” of the particles, as well as with processes similar to those responsible for the behavior of minor hysteresis loops due to strong local anisotropy fields of the ferrihydrite nanoparticles. © 2016, Pleiades Publishing, Ltd.

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Публикация на русском языке Особенности магнитных свойств наночастиц ферригидрита бактериального происхождения: смещение петли гистерезиса [Текст] / Д. А. Балаев [и др.] // Физ. тверд. тела : Физико-технический институт им. А. Ф. Иоффе РАН, 2016. - Т. 58 Вып. 2. - С. 280-284

Держатели документа:
Kirensky Institute of Physics, Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50/38, Krasnoyarsk, Russian Federation
Siberian Federal University, Svobodny pr. 79, Krasnoyarsk, Russian Federation
International Laboratory of High Magnetic Fields and Low Temperatures, ul. Gajowicka 95, Wroclaw, Poland
International Scientific Centre for Organism Extreme States Research, Presidium of the Krasnoyarsk Scientific Centre of the Siberian Branch of the Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Popkov, S. I.; Попков, Сергей Иванович; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Yaroslavtsev, R. N.
}
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15.

Magnetic properties of heat treated bacterial ferrihydrite nanoparticles / D. A. Balaev [et al.] // J. Magn. Magn. Mater. - 2016. - Vol. 410. - P. 171-180, DOI 10.1016/j.jmmm.2016.02.059. - Cited References: 66. - TEM studies were performed on facility of Resource Sharing Center of Krasnoyarsk Scientific Center of Siberian Branch of Russian Academy of Sciences. Authors acknowledge to M.N. Volochaev for the TEM measurements. . - ISSN 0304-8853

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
Hematite nanoparticles
   NiO nanoparticles
   Porous-glass
   Ferritin
   Particles
   Temperature
   Hysteresis
   Transition
   Anomalies
   Mossbauer
Кл.слова (ненормированные):
Ferrihydrite -- Nanoparticles -- Superparamagnetism
Аннотация: The magnetic properties of ferrihydrite nanoparticles, which are products of vital functions of Klebsiella oxitoca bacteria, have been studied. The initial powder containing the nanoparticles in an organic shell was subjected to low-temperature (T=160 °C) heat treatment for up to 240 h. The bacterial ferrihydrite particles exhibit a superparamagnetic behavior. Their characteristic blocking temperature increases from 26 to 80 K with the heat treatment. Analysis of the magnetization curves with regard to the magnetic moment distribution function and antiferromagnetic contribution shows that the low-temperature heat treatment enhances the average magnetic moment of a particle; i.e., the nanoparticles coarsen, probably due to their partial agglomeration during heat treatment. It was established that the blocking temperature nonlinearly depends on the particle volume. Therefore, a model was proposed that takes into account both the bulk and surface magnetic anisotropy. Using this model, the bulk and surface magnetic anisotropy constants KV≈1.7×105 erg/cm3 and KS≈0.055 erg/cm2 have been determined. The effect of the surface magnetic anisotropy of ferrihydrite nanoparticles on the observed magnetic hysteresis loops is discussed.

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Держатели документа:
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation
Siberian Federal University, Krasnoyarsk, Russian Federation
Presidium of Krasnoyarsk Scientific Center, Russian Academy of Sciences, Siberian Branch, Krasnoyarsk, Russian Federation
International Laboratory of High Magnetic Fields and Low Temperatures, Gajowicka 95, Wroclaw, Poland

Доп.точки доступа:
Balaev, D. A.; Балаев, Дмитрий Александрович; Krasikov, A. A.; Красиков, Александр Александрович; Dubrovskiy, A. A.; Дубровский, Андрей Александрович; Popkov, S. I.; Попков, Сергей Иванович; Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ladygina, V. P.; Yaroslavtsev, R. N.
}
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16.

Mossbauer Investigation of Temperature Transformations in Bacterial Ferrihydrite / S. V. Stolyar [et al.] // Phys. Solid State. - 2011. - Vol. 53, Is. 1. - P. 100-104, DOI 10.1134/S1063783411010306. - Cited References: 10. - This study was supported by the Federal Agency for Science and Innovation of the Russian Federation within the framework of the Russian Federal Target Program "Scientific and Scientific-Pedagogical Personnel of the Innovative Russia" for 2009-2013 and the Russian Foundation for Basic Research (project no. 09-04-98038-r_sibir'_a). . - ISSN 1063-7834

РУБ Physics, Condensed Matter

Аннотация: Ferrihydrite nanoparticles formed as a result of the microorganism activity have been studied using Mossbauer spectroscopy, X-ray powder diffraction analysis, and X-ray fluorescence analysis. Three positions of trivalent iron with nonoverlapping ranges of quadrupole splittings have been revealed in bacterial ferrihydrite: QS{Fe(3+)(1)} = 0.49-0.83 mm/s, QS{Fe(3+)(2)} = 0.84-1.10 mm/s, and QS{Fe(3+)(3)} = 1.25-1.73 mm/s. It has been experimentally demonstrated that the Fe(3+)(3) positions are the centers of nucleation of the hematite phase in the course of heat treatment.

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Держатели документа:
[Stolyar, S. V.
Bayukov, O. A.
Iskhakov, R. S.
Ishchenko, L. A.
Yakovchuk, V. Yu.
Piksina, O. E.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Stolyar, S. V.
Bayukov, O. A.
Iskhakov, R. S.
Ishchenko, L. A.
Yakovchuk, V. Yu.
Pozdnyakov, A. I.] Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
[Ladygina, V. P.] Russian Acad Sci, Siberian Branch, Presidium Krasnoyarsk Sci Ctr, Int Res Ctr Extreme States Organism, Krasnoyarsk 660036, Russia
[Dobretsov, K. G.] Joint Stock Co Russian Railways RZhD, Railway Clin Hosp Krasnoyarsk Stn, Krasnoyarsk 660021, Russia
ИФ СО РАН
КНЦ СО РАН
Siberian Federal University, Svobodnyi pr. 79, Krasnoyarsk 660041, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
International Research Center for Extreme States of the Organism, Presidium of Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
Railway Clinical Hospital at the Krasnoyarsk station, Joint Stock Company Russian Railways (RZhD), pr. Mira 154, Krasnoyarsk 660021, Russian Federation

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, V. P.; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ishchenko, L. A.; Yakovchuk, V. Y.; Dobretsov, K. G.; Pozdnyakov, A. I.; Piksina, O. E.
}
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17.

State of iron in nanoparticles prepared by impregnation of silica gel and aluminum oxide with FeSO4 solutions / G. A. Bukhtiyarova [et al.] // Phys. Solid State. - 2010. - Vol. 52, Is. 4. - P. 826-837, DOI 10.1134/S1063783410040268. - Cited References: 27. - This study was supported by the Presidium of the Russian Academy of Sciences within the framework of the Program no. 27 "Principles of Basic Research of Nanotechnologies and Nanomaterials," Project no. 46 "Magnetically Ordered Nanoparticles in Catalytic Systems: Synthesis, Evolution, and Physicochemical Properties." . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
THERMAL-DECOMPOSITION
   BETA-FEOOH
   MOSSBAUER
   FERRIHYDRITE
   EPSILON-FE2O3
   FE-2(SO4)(3)
   SULFATE
   FE-57
Аннотация: The state of iron in nanoparticles prepared by impregnating silica gel and aluminum oxide with iron(II) sulfate solutions has been investigated using Mossbauer spectroscopy. It has been revealed that the state of iron depends on the nature of the support. Iron(III) hydroxysulfate and iron(III) oxysulfate nanoparticles are formed on the surface of silica gel, and iron oxide nanoparticles are formed on the surface of aluminum oxide. An increase in the concentration of iron ions or in the size of iron-containing particles leads to hydration of the nanoparticle surface. The calcination of the samples results in the formation of E -Fe2O3 oxide in a strongly disordered or amorphous state in iron-containing particles on the surface of silica gel.

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Держатели документа:
[Bukhtiyarova, G. A.
Mart'yanov, O. N.
Yakushkin, S. S.
Shuvaeva, M. A.] Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[Bayukov, O. A.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
ИФ СО РАН
Boreskov Institute of Catalysis, Siberian Branch, Russian Academy of Sciences, pr. Akademika Lavrent'eva 5, Novosibirsk 630090, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation

Доп.точки доступа:
Bukhtiyarova, G. A.; Mart'yanov, O. N.; Yakushkin, S. S.; Shuvaeva, M. A.; Bayukov, O. A.; Баюков, Олег Артемьевич
}
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18.

Magnetic properties of biomineral particles produced by bacteria Klebsiella oxytoca / Y. L. Raikher [et al.] // Phys. Solid State. - 2010. - Vol. 52, Is. 2. - P. 298-305, DOI 10.1134/S1063783410020125. - Cited References: 29. - This study was supported by the Russian Foundation for Basic Research (project nos. 07-02-96026, 07- 02-96017, and 08-02-00802) and performed within the framework of the Federal Target Program "Research and Research-Pedagogical Personnel of Innovation Russia for 2009-2013." . - ISSN 1063-7834

РУБ Physics, Condensed Matter
Рубрики:
FERRITIN
   NANOPARTICLES
   IRON
   SUSCEPTIBILITY
   FERRIHYDRITE
   BEHAVIOR
   FINS
Аннотация: Ferrihydrite nanoparticles (2-5 nm in size) produced by bacteria Klebsiella oxytoca in the course of biomineralization of iron salt solutions from a natural medium exhibit unique magnetic properties: they are characterized by both the antiferromagnetic order inherent in a bulk ferrihydrite and the spontaneous magnetic moment due to the decompensation of spins in sublattices of a nanoparticle. The magnetic susceptibility enhanced by the superantiferromagnetism effect and the magnetic moment independent of the magnetic field provide the possibility of magnetically controlling these natural objects. This has opened up the possibilities for their use in nanomedicine and bioengineering. The results obtained from measurements of the magnetic properties of the ferrihydrite produced by Klebsiella oxytoca in its two main crystalline modifications are reported, and the data obtained are analyzed theoretically. This has made it possible to determine numerical values of the magnetic parameters of real biomineral nanoparticles.

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Держатели документа:
[Raikher, Yu. L.
Stepanov, V. I.] Russian Acad Sci, Ural Div, Inst Continuum Media Mech, Perm 614013, Russia
[Stolyar, S. V.
Balaev, D. A.] Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk 660036, Russia
[Stolyar, S. V.
Balaev, D. A.
Ishchenko, L. A.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Ladygina, V. P.] Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Int Sci Ctr Res Organism Extreme Condit, Krasnoyarsk 660036, Russia
[Balasoiu, M.] Joint Inst Nucl Res, Dubna 141980, Moscow Oblast, Russia
ИФ СО РАН
Institute of Continuum Media Mechanics, Ural Division, Russian Academy of Sciences, ul. Akademika Koroleva 1, Perm 614013, Russian Federation
Kirensky Institute of Physics, Siberian Branch, Russian Academy of Sciences, Akademgorodok 50, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, pr. Svobody 79, Krasnoyarsk 660041, Russian Federation
International Scientific Center for Research of Organism under Extreme Conditions, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences, Akademgorodok, Krasnoyarsk 660036, Russian Federation
Joint Institute for Nuclear Research, ul. Joliot-Curie 6, Dubna, Moscow oblast 141980, Russian Federation

Доп.точки доступа:
Raikher, Y. L.; Stepanov, V. I.; Stolyar, S. V.; Столяр, Сергей Викторович; Ladygina, V. P.; Balaev, D. A.; Балаев, Дмитрий Александрович; Ishchenko, L. A.; Balasoiu, M.
}
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19.

Hierarchical structure investigations of biogenic ferrihydrite samples / M. Balasoiu [et al.] // Rom. J. Phys. - 2010. - Vol. 55, Is. 7-8. - P. 782-789. - Cited References: 21. - The work was accomplished with the financial support of Grant 224/11.04.2008 of Romanian Governmental Plenipotentiary at JINR. . - ISSN 1221-146X

РУБ Physics, Multidisciplinary
Рубрики:
ELECTRON NANODIFFRACTION
   6-LINE FERRIHYDRITE
   SYNTHETIC 2-LINE
   FERROFLUIDS
Кл.слова (ненормированные):
ferrihydrite nanoparticles -- Klebsiella oxytoca bacteria -- optical microscopy -- SEM -- SAXS
Аннотация: Results of observation and preliminary analysis on morphology and structure of ferrihydrite particles produced in vivo by Klebsiella oxytoca bacteria are presented. In particular, optical microscopy, scanning electron microscopy and small angle X-ray scattering in accordance with one another point out the fractal structure of the biomineral particle surface. The effect of the bacteria age (the duration of growth) on the fractal dimension is established and characterized.

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Держатели документа:
[Balasoiu, M.] Horia Hulubei Natl Inst Phys & Nucl Engn, Bucharest, Romania
[Stolyar, S. V.
Iskhakov, R. S.
Ishchenko, L. A.] Siberian Fed Univ, Krasnoyarsk 660041, Russia
[Raikher, Yu. L.] RAS, Ural Branch, Inst Continuum Media Mech, Perm 614013, Russia
[Balasoiu, M.
Kuklin, A. I.
Orelovich, O. L.
Kovalev, Yu. S.
Arzumanian, G. M.] Joint Inst Nucl Res, Dubna 141980, Russia
[Kurkin, T. S.] RAS, Inst Synthet Polymer Mat, Moscow 117393, Russia
[Stolyar, S. V.
Iskhakov, R. S.] RAS, Siberian Branch, Inst Phys, Krasnoyarsk 660036, Russia
ИФ СО РАН

Доп.точки доступа:
Balasoiu, M.; Stolyar, S. V.; Столяр, Сергей Викторович; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Ishchenko, L. A.; Raikher, Y. L.; Kuklin, A. I.; Orelovich, O. L.; Kovalev, Y. S.; Kurkin, T. S.; Arzumanian, G. M.
}
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20.

Ultrasonic treatment of suspensions of magnetic ferrihydrite nanoparticles / S. V. Stolyar [et al.] // VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. P9.14. - P. 400. - References: 1. - This work was supported by the Special Program for Siberian Federal University of the Ministry of Education and Science of the Russian Federation . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
ferrihydrite -- magnetic nanoparticles

Доп.точки доступа:
Stolyar, S. V.; Столяр, Сергей Викторович; Bayukov, O. A.; Баюков, Олег Артемьевич; Ladygina, V. P.; Ладыгина, Валентина Петровна; Iskhakov, R. S.; Исхаков, Рауф Садыкович; Yaroslavtsev, R. N.; Ярославцев, Роман Николаевич; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН

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