Библиотека института физики им. Л.В. Киренского СО РАН

Главная

Базы данных

Труды сотрудников ИФ СО РАН - результаты поиска

Вид поиска

Каталог книг и брошюр библиотеки ИФ СО РАН

Каталог журналов библиотеки ИФ СО РАН

Труды сотрудников ИФ СО РАН

Область поиска

в найденном

Найдено в других БД:

Каталог книг и брошюр библиотеки ИФ СО РАН (3)

Формат представления найденных документов:
полный	информационный	краткий

Отсортировать найденные документы по:
автору	заглавию	году издания	типу документа

Поисковый запрос: (<.>K=Oxidation<.>)

Общее количество найденных документов : 41
Показаны документы с 1 по 20

    Crystal structure and magnetic properties of Mn substituted ludwigite Co3O2BO3 / Yu. V. Knyazev [et al.] // J. Magn. Magn. Mater. - 2012. - Vol. 324, Is. 6. - P. 923-927, DOI 10.1016/j.jmmm.2011.07.044. - Cited References: 15. - The study was supported by the Russian Foundation for Basic Research (Project no. 09-02-00171-a), the Federal Agency for Science and Innovation (Rosnauka) (Project no. MK-5632.2010.2), the Physical Division of the Russian Academy of Science, the program "Strongly Correlated Electrons", Project 2.3.1. . - ISSN 0304-8853
   Перевод заглавия: Кристаллическая структура и магнитные свойства Mn-замещенного людвигита Co3O2BO3

РУБ Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
BOND VALENT SUMS
   COORDINATION CHEMISTRY
   OXIDATION -STATE
   O BONDS
   COMPLEXES
   MANGANESE
   COBALT
Кл.слова (ненормированные):
Transition metal oxyborate -- Distinct crystallographic position -- Spin glass magnetic ordering
Аннотация: The needle shape single crystals Co3−x MnxO2BO3 with ludwigite structure have been prepared. According to the X-ray diffraction data the preferable character of distinct crystallographic positions occupation by Mn ions is established. Magnetization field and temperature dependencies are measured. Paramagnetic Curie temperature value Θ=−100 K points out the predominance of antiferromagnetic interactions. Spin-glass magnetic ordering takes the onset at TN=41 K. The crystallographic and magnetic properties of Co3O2BO3:Mn are compared with the same for the isostructural analogs Co3O2BO3 and CoO2BO3:Fe.

Смотреть статью,
Scopus,
WoS,
Читать в сети ИФ

Доп.точки доступа:
Knyazev, Yu.V.; Князев, Юрий Владимирович; Ivanova, N. B.; Иванова, Наталья Борисовна; Kazak, N. V.; Казак, Наталья Валерьевна; Platunov, M. S.; Платунов, Михаил Сергеевич; Bezmaternykh, L. N.; Безматерных, Леонард Николаевич; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Vasiliev, A. D.; Васильев, Александр Дмитриевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Yurkin, G. Yu.; Юркин, Глеб Юрьевич
}
Найти похожие

Структурные и оптические свойства тонких пленок In2O3, полученных автоволновым окислением / И. А. Тамбасов [и др.] // Физ. и техника полупроводников. - 2013. - Т. 47, Вып. 4. - С. 546-550
Аннотация: Пленки кубической фазы In2O3 получены автоволновой реакцией окисления. Электронно-микроскопические исследования и фотоэлектронная спектроскопия профилей распределения показали, что образцы однородны по всей площади и толщине, характерный размер зерна 20--40 нм. Проведены исследования оптических и электрических свойств пленок In2O3, полученных при различном давлении в вакуумной камере. В диапазоне длины волн 400--1100 нм пленки имели прозрачность более 85% и удельное сопротивление 1.8· 10-2 Ом·см.

Смотреть статью,
Читать в сети ИФ

Переводная версия Structural and optical properties of thin In2O3 films produced by autowave oxidation. - [Б. м. : б. и.]

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Тамбасов, Игорь Анатольевич; Tambasov I.A.; Мягков, Виктор Григорьевич; Myagkov V.G.; Иваненко, Александр Анатольевич; Ivanenko, A. A.; Немцев, Иван Васильевич; Nemtsev I.V.; Быкова, Людмила Евгеньевна; Bykova L.E.; Бондаренко, Галина Николаевна; Bondarenko, G. N.; Mikhlin, Y. L.; Михлин, Юрий Леонидович; Максимов, И. А.; Иванов, В. В.; Балашов, С. В.; Карпенко, Д. С.
}
Найти похожие

Structural and optical properties of thin In2O3 films produced by autowave oxidation / I. A. Tambasov [et al.] // Semiconductors. - 2013. - Vol. 47, Is. 4. - P. 569-573DOI 10.1134/S1063782613040210
Аннотация: Cubic-phase In2O3 films are produced by the autowave oxidation reaction. Electron microscopy and photoelectron spectroscopy of the atomic profiles show that the samples are homogeneous over the entire area and throughout the thickness, with the typical grain size being 20–40 nm. The optical and electrical properties are studied for In2O3 films fabricated at different pressures in the vacuum chamber. In the wave-length range from 400 to 1100 nm, the transparency of the films was higher than 85%; the resistivity of the films was 1.8 × 10–2Ω cm.

Смотреть статью,
WOS,
Читать в сети ИФ

Публикация на русском языке Структурные и оптические свойства тонких пленок In2O3, полученных автоволновым окислением // Физика и техника полупроводников. - 2013. - Т. 47, Вып. 4. - С. 546-550

Держатели документа:
Russian Acad Sci, Kirenskii Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660049, Russia
Joint Stock Co Academician MF Reshetnev Informat, Zheleznogorsk 662972, Russia

Доп.точки доступа:
Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Myagkov, V. G.; Ivanenko, A. A.; Иваненко, Александр Анатольевич; Nemtsev, I. V.; Немцев, Иван Васильевич; Bykova, L. E.; Быкова, Людмила Евгеньевна; Bondarenko, G. N.; Бондаренко, Галина Николаевна; Mihlin, J. L.; Михлин, Юрий Леонидович; Maksimov, I. A.; Максимов И. А.; Ivanov, V. V.; Иванов В. В.; Balashov, S. V.; Балашов С. В.; Karpenko, D. S.; Карпенко Д. С.
}
Найти похожие

    Влияние фотонной обработки и температуры на проводимость In2O3 пленок, полученных автоволновым окислением / И. А. Тамбасов [и др.] // Вестник СибГАУ. - 2013. - № 3. - С. 103-106. - Работа выполнена частично при финансовой поддержке ФЦП «Исследования и разработки по приоритетным направлениям развития научно-технологичного комплекса России на 2007-2013 годы» (госконтракт № 14.513.11.0023), а также Министерства образования и науки Российской Федерации (договор № 02.G25.31.0043) . - ISSN 1816-9724
   Перевод заглавия: The impact of the photon processing and temperature on the conductivity of In2O3 films produed with autowave oxidation
Кл.слова (ненормированные):
ТОНКИЕ ПЛЕНКИ -- ОКСИД ИНДИЯ -- АВТОВОЛНОВОЕ ОКИСЛЕНИЕ -- УЛЬТРАФИОЛЕТОВОЕ ОБЛУЧЕНИЕ -- THIN FILMS -- INDIUM OXIDE -- AUTO-WAVE OXIDATION -- ULTRAVIOLET IRRADIATION
Аннотация: Пленки оксида индия были синтезированы автоволновой реакцией окисления на покровном стекле, кварце и монокристалле MgO. Толщина пленки измерялась с помощью режима «cross-section» сканирующего электронного микроскопа и составляла ~300 нм. Оптическая ширина запрещенной зоны оксида индия была ~3.5 эВ. Исследования сопротивления In2O3 пленки от температуры в теневых условиях показали, что при нагревании до 100 0С сопротивление увеличивается на ~10 %. Показано, что при фотооблучении происходит резкое уменьшение электрического сопротивления пленок, максимальное изменение которого составило 52 % при комнатной температуре. Определены две скорости релаксации сопротивления пленок после прекращения облучения 15 Ом/сек первые 30 сек и 7 Ом/сек в остальное время. Сделано предположение, что фотовосстановление является доминирующим механизмом, ответственным за изменения проводимости пленок.
Indium oxide films were synthesized by auto-wave oxidation reaction on the cover glass, quartz and single crystal MgO. The film thickness was measured with a mode «cross-section» scanning electron microscope and was ~ 300 nm. Optical band gap of indium oxide was ~3.5 eV. The study of In2O3 film resistance versus temperature in the dark conditions showed that when heated to 100 °C the resistance increases by about 10 %. It is shown that the_ films electric resistance decreases sharply under photo radiation and the maximum change was 52 % at room temperature. The two film resistance relaxation rates after irradiation have been determined to be 15 Ohm/s the first 30 seconds and 7 Оhm/s f for the rest, respectively. On the basis of the above stated the authors suggest that the photo reduction is the dominant mechanism responsible for the changes in conductivity of In 2O 3 films.

Смотреть статью,
Читать в сети ИФ
Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Тамбасов, Игорь Анатольевич; Tambasov, I.A.; Немцев, Иван Васильевич; Nemtsev, I.V.; Савранский, Д. С.; Мацынин, Алексей Александрович; Matsynin, A.A.; Ежикова, Е. В.
}
Найти похожие

Effect of exposure to optical radiation and temperature on the electrical and optical properties of In2O3 films produced by autowave oxidation / I. A. Tambasov [et al.] // Semiconductors. - 2014. - Vol. 48, Is. 2. - P. 207-211, DOI 10.1134/S1063782614020286. - Cited References: 42. - This study was supported by the Ministry of Education and Science of the Russian Federation, Federal Targeted Program "Research and Development in Priority Fields of Development of the Science and Technology Complex of Russia for 2007-2013", state contract no. 14.513.11.0023. . - ISSN 1063-7826. - ISSN 1090-6479

РУБ Physics, Condensed Matter
Рубрики:
GAS SENSOR RESPONSE
   INDIUM OXIDE-FILMS
   THIN-FILMS
   HIGH-PERFORMANCE
   TIN OXIDE
   TRANSPARENT CONDUCTORS
   SUBSTRATE-TEMPERATURE
   ROOM-TEMPERATURE
   TRANSISTORS
   PHOTOREDUCTION
Аннотация: Indium-oxide films are synthesized by the autowave-oxidation reaction. It is shown that, upon exposure to optical radiation, the resistance of the films sharply decreases and the maximal relative change in the resistance is 52% at room temperature. Two resistance relaxation rates after termination of the irradiation, 15 Omega s(-1) during the first 30 s and 7 Omega s(-1) over the remaining time, are determined. The data of infrared spectroscopy of the films show that exposure to optical radiation induces a 2.4% decrease in the transmittance at a wavelength of 6.3 mu m. It is found that, after termination of the irradiation, the transmittance gradually increases with a rate of 0.006% s(-1). It is suggested that photoreduction is the dominant mechanism responsible for changes in the electrical and optical properties of the In2O3 films.

Смотреть статью,
Scopus,
WoS,
Читать в сети ИФ

Публикация на русском языке Влияние фотооблучения и температуры на электрические и оптические свойства пленок In2O3, полученных автоволновым окислением [Текст] / И. А. Тамбасов [и др.] // Физ. и техника полупроводников : Санкт-Петербургская издательская фирма "Наука" РАН, 2014. - Т. 48 Вып. 2. - С. 220-224

Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Siberian State Aerosp Univ, Krasnoyarsk 660037, Russia
Joint Stock Co Academician MF Reshetnev Informat, Zheleznogorsk 662972, Russia

Доп.точки доступа:
Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Myagkov, V. G.; Мягков, Виктор Григорьевич; Ivanenko, A. A.; Иваненко, Александр Анатольевич; Bykova, L. E.; Быкова, Людмила Евгеньевна; Yozhikova, E. V.; Maksimov, I. A.; Ivanov, V. V.; Ministry of Education and Science of the Russian Federation [14.513.11.0023]
}
Найти похожие

Size control in the formation of magnetite nanoparticles in the presence of citrate ions / V. L. Kirillov [et al.] // Mater. Chem. Phys. - 2014. - Vol. 145, Is. 1-2. - P. 75-81, DOI 10.1016/j.matchemphys.2014.01.036. - Cited References: 46. - This work was supported by the Interdisciplinary Integration Project no. 45 of the Siberian Branch of the Russian Academy of Sciences for 2012-2014. . - ISSN 0254-0584. - ISSN 1879-3312

РУБ Materials Science, Multidisciplinary
Рубрики:
OLEIC-ACID
   CATALYST
   HYPERTHERMIA
   PARTICLES
   OXIDATION
   REMOVAL
   CO
Кл.слова (ненормированные):
Magnetic materials -- Magnetic properties -- Precipitation -- Electron paramagnetic resonance
Аннотация: A one-pot synthesis method for the controllable growth of magnetite nanoparticles directly during the process of co-precipitation using citrate ions was developed. The effects of the concentration of citrate ions and the solution pH on the characteristics of magnetite particles with sizes in the range of 4-10 nm synthesized by the method of co-precipitation were studied. The results showed that the specified concentration of citrate ions allowed the preparation of magnetite particles with a definite size that exhibited superparamagnetic behaviour in a particular temperature range. As the concentration ratio of citrate to iron ions was increased from 0 to 0.11, the average size of the prepared magnetite particles decreased from 10.5 to 4.4 nm. As a result, the superparamagnetic blocking temperature decreased from 300 to 20 K, the saturation magnetisation decreased from 50 to 20 emu g(-1), and the average magnetic moment decreased from 8000 mu(B) to 340 mu(B) (at T = 300 K). The obtained experimental data proved that the size effects of the magnetite nanoparticles can be attributed to the capping of the magnetite surface by adsorbed citrate ions. Thus, the suggested approach allows magnetite nanoparticles to be prepared with an optimum particle size around superparamagnetic threshold that prevents their irreversible agglomeration and simultaneously allows them to be removed from a solution at an acceptable rate. (C) 2014 Elsevier B.V. All rights reserved.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Kirillov, V. L.; Balaev, D. A.; Балаев, Дмитрий Александрович; Semenov, S. V.; Семёнов, Сергей Васильевич; Shaikhutdinov, K. A.; Шайхутдинов, Кирилл Александрович; Martyanov, O. N.; Siberian Branch of the Russian Academy of Sciences
}
Найти похожие

    Oxidation of Ag nanoparticles in aqueous media: Effect of particle size and capping / Y. L. Mikhlin [et al.] // Appl. Surf. Sci. - 2014. - Vol. 297. - P. 75-83, DOI 10.1016/j.apsusc.2014.01.081. - Cited References: 58. - This work was partially financially supported by the Ministry of Education and Science of RF (Grant 8580) and RFBR (12-03-31178). . - ISSN 0169-4332. - ISSN 1873-5584
   Перевод заглавия: Окисление наночастиц Ag в водной среде: Влияние размера частиц и оболочки.

РУБ Chemistry, Physical + Materials Science, Coatings & Films + Physics, Applied + Physics, Condensed Matter
Рубрики:
EX-SITU XPS
   POLYCRYSTALLINE SILVER ELECTRODES
   RAY PHOTOELECTRON-SPECTROSCOPY
   METAL NANOPARTICLES
   ELECTROCHEMICAL OXIDATION
   ABSORPTION SPECTROSCOPY
   PYROLYTIC-GRAPHITE
   OXYGEN-ADSORPTION
   TRANSFORMATIONS
   DISSOLUTION
Кл.слова (ненормированные):
Silver nanoparticles -- Oxidation -- Resistive switching effect -- X-ray photoelectron spectroscopy
Аннотация: Many applications and environmental impact of silver-bearing nanomaterials critically depend upon their specific reactivity, which is still poorly understood. Here, silver nanoparticles (Ag NPs) of about 3-5 nm and 10-12 nm in diameter, uncapped and capped with l-glucose or citrate, were prepared, characterized using UV-vis absorption spectroscopy, SAXS, TEM, and their (electro) chemical oxidation was examined in comparison with each other and bulk metal applying scanning tunneling microscopy and spectroscopy, cyclic voltammetry, and XPS. A resistive switching effect was found in the tunneling spectra measured in air at the smaller uncapped Ag NPs deposited on HOPG and was interpreted in terms of Ag transfer between the particle and the probe. The anodic oxidation of these Ag NPs in 1 M NaOH yielded 3D Ag2O, while only a layer of "primary"Ag(I) oxide emerged on larger uncapped nanoparticles during the potential sweep. The formation of AgO at higher potentials proceeded readily at the "primary"oxide but was retarded at the smaller NPs. The citrate- and glucose-capping substantially impeded the formation both of Ag2O and AgO. The findings highlighted, particularly, a non-trivial effect of particle size and transient mobilization of Ag species on the reactions of silver nanoparticles. (c) 2014 Elsevier B.V. All rights reserved.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Boreskov Inst Catalysis, Novosibirsk 630090, Russia
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Mikhlin, Y. L.; Vishnyakova, E. A.; Romanchenko, A. S.; Saikova, S. V.; Сайкова, С. В.; Likhatski, M. N.; Larichev, Y. V.; Tuzikov, F. V.; Zaikovskii, V. I.; Zharkov, S. M.; Жарков, Сергей Михайлович
}
Найти похожие

Reversible UV induced metal-semiconductor transition in In2O3 thin films prepared by autowave oxidation / I. A. Tambasov [et al.] // Semicond. Sci. Technol. - 2014. - Vol. 29, Is. 8. - Ст. 82001, DOI 10.1088/0268-1242/29/8/082001. - Cited References: 56. - This work was supported by the Federal Target Program through Contract No 14.513.11.0023; the Russian Foundation for Basic Research, Project No. 14-02-31156. . - ISSN 0268-1242. - ISSN 1361-6641

РУБ Engineering, Electrical & Electronic + Materials Science, Multidisciplinary + Physics, Condensed Matter
Рубрики:
TRANSPARENT CONDUCTING OXIDES
   Ga-DOPED ZnO
   LOW-TEMPERATURE
   HIGH-PERFORMANCE
   SUBSTRATE-TEMPERATURE
   INSULATOR-TRANSITION
   ROOM-TEMPERATURE
   TRANSISTORS
   COMBUSTION
   PHOTOREDUCTION
Кл.слова (ненормированные):
indium oxide thin films -- autowave oxidation -- metal-semiconductor transition -- UV irradiation -- photoreduction
Аннотация: We have prepared thin indium oxide films by the autowave oxidation reaction. Measurements of temperature dependence of resistivity, Hall carrier concentration and Hall mobility have been conducted in the temperature range 5-272 K. Before ultraviolet (UV) irradiation, the indium oxide film had a semiconductor-like temperature dependence of resistivity. and the ratio of rho (5 K)/rho(272 K) was very limited (similar to 1.2). It was found that after UV irradiation of the In2O3 film, the metal-semiconductor transition (MST) was observed at similar to 100 K. To show that this MST is reversible and repeatable, two full cycles of 'absence of MST-presence of MST' have been done using UV irradiation (photoreduction) as the induced mechanism and exposure to an oxygen environment as the reversible mechanism, respectively. MST in transparent conducting oxide (TCO) is possibly associated with the undoped structure of metal oxide, which has some disorder of oxygen vacancies. It was suggested that reversible UV induced metal-semiconductor transition would occur in other TCOs.

Смотреть статью,
Scopus,
WoS,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, Siberian Branch, LV Kirensky Phys Inst, Krasnoyarsk 660036, Russia
Reshetnev Siberian State Aerosp Univ, Krasnoyarsk 660014, Russia
Russian Acad Sci, Siberian Branch, Krasnoyarsk Sci Ctr, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Tambasov, I. A.; Тамбасов, Игорь Анатольевич; Myagkov, V. G.; Мягков, Виктор Григорьевич; Tarasov, A. S.; Тарасов, Антон Сергеевич; Ivanenko, A. A.; Иваненко, Александр Анатольевич; Bykova, L. E.; Быкова, Людмила Евгеньевна; Nemtsev, I. V.; Немцев, Иван Васильевич; Eremin, E. V.; Еремин, Евгений Владимирович; Yozhikova, E. V.; Federal Target Program [14.513.11.0023]; Russian Foundation for Basic Research [14-02-31156]
}
Найти похожие

Methane oxidation over A-site ordered and disordered Sr0.8Gd0.2CoO3−δ perovskites / S. N. Vereshchagin [et al.] // Chem. Commun. - 2014. - Vol. 50, Is. 46. - P. 6112-6115, DOI 10.1039/c4cc00913d. - Cited References: 20. - The authors acknowledge the financial support from SB RAS project N 38 (2012) and RFBR grant 13-02-00358. . - ISSN 1359-7345. - ISSN 1364-548X

РУБ Chemistry, Multidisciplinary
Рубрики:
MEMBRANE REACTORS
   OXYGEN
   OXIDES
   PERFORMANCE
   COMBUSTION
   FEATURES
   PHASES
Аннотация: A tetragonal phase Sr0.8Gd0.2CoO3−δ with ordered Gd3+/Sr2+ ions and oxygen vacancy sites is found to be about five times less active in the reaction of methane combustion than a quenched cubic perovskite phase with randomly distributed (disordered) Gd3+/Sr2+ ions over the A-sites of the crystal lattice.

Смотреть статью,
Scopus,
WoS,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Krasnoyarsk 660036, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Branch, Krasnoyarsk, Russia
Siberian Fed Univ, Krasnoyarsk 660041, Russia

Доп.точки доступа:
Vereshchagin, S. N.; Solovyov, L. A.; Соловьев, Леонид Александрович; Rabchevskii, E. V.; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Anshits, A. G.; Аншиц, Александр Георгиевич; SB RAS project [38]; RFBR [13-02-00358]
}
Найти похожие

10.

Oxatrane is a parent compound of a new atrane family: Crystal and molecular structure of triethanolamine N-oxide / M. G. Voronkov [et al.] // Dokl. Chem. - 2014. - Vol. 458. - P. 172-175, DOI 10.1134/S0012500814090031. - This work was supported by the Council for Grants of the President of the Russian Federation for Support of Leading Scientific Schools (grant no. NSh-3649.2014.3). . - ISSN 0012-5008. - ISSN 1608-3113

РУБ Chemistry, Multidisciplinary
Рубрики:
TERTIARY-AMINES
   DIETHANOLAMINE
   SILATRANES
   OXIDATION

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ

Публикация на русском языке Оксатран - родоначальник нового семейства атранов. Кристаллическая и молекулярная структура N-оксида триэтаноламина. [Текст] / М. Г. Воронков [и др.] // Докл. Акад. наук. - 2014. - Т. 458 № 3. - С. 287-290

Держатели документа:
Russian Acad Sci, Favorskii Inst Chem, Siberian Branch, Irkutsk 664033, Russia
East Siberian State Acad Educ, Irkutsk 664011, Russia
Russian Acad Sci, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia
Siberian Fed Univ, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Voronkov, M. G.; Zel'bst, E. A.; Vasil'ev, A. D.; Васильев, Александр Дмитриевич; Molokeev, M. S.; Молокеев, Максим Сергеевич; Kuznetsova, G. A.; Council for Grants of the President of the Russian Federation for Support of Leading Scientific Schools [NSh-3649.2014.3]
}
Найти похожие

11.

The role of rocks saturated with metallic iron in the formation of ferric carbonate-silicate melts: experimental modeling under PT-conditions of lithospheric mantle / Y. V. Bataleva [et al.] // Russ. Geol. Geophys. - 2015. - Vol. 56, Is. 1-2. - P. 143-154, DOI 10.1016/j.rgg.2015.01.008. - Cited References:68. - This work was supported by Integration project 31 from the Siberian Branch of the Russian Academy of Sciences and by grant 12-05-00740 from the Russian Foundation for Basic Research. . - ISSN 1068. - ISSN 1878-030X. -

РУБ Geosciences, Multidisciplinary
Рубрики:
OXYGEN FUGACITY
   DIAMOND FORMATION
   OXIDATION-STATE
   EARTHS MANTLE
Кл.слова (ненормированные):
carbonate-silicate melt -- graphite -- CO2 fluid -- iron carbide -- garnet -- redox gradient -- high-pressure experiment
Аннотация: Experimental modeling of the processes of formation of ferric carbonate-silicate melts through the carbonate-oxide-metal interaction is performed in the (Mg,Ca)CO3-SiO2-Al2O3-Fe0 system at 6.3 and 7.5 GPa and within 1150-1650 °C, using a multianvil high-pressure apparatus of “split-sphere” type (BARS). Two parallel reactions run in the subsolidus region (1150-1450 °C): decarbonation, producing pyrope-almandine (Fe# = 0.40-0.75) and CO2 fluid, and redox interaction between carbonate and Fe0, resulting in the crystallization of iron carbide in assemblage with magnesiowustite (Fe# = 0.75-0.85). It is shown that the reduction of carbonate or CO2 fluid by iron carbide and parallel redox interaction of magnesiowustite with CO2 produce graphite in assemblage with Fe3 + -containing magnesiowustite. In the temperature range of 1450-1650 °C, generation of carbonate-silicate melts coexisting with pyrope-almandine, magnesiowustite, magnetite, ferrospinel, and graphite takes place. The composition of the produced melts is as follows: SiO2 - 10-15 wt.%, X(FeO + Fe2O3) = 36-43 wt.%, and Fe3+/XFe - 0.18-0.23. These Fe3 + -enriched carbonate-silicate melts/fluids are saturated with carbon and are the medium of graphite crystallization. Oxide and silicate phases (almandine, ferrospinel, and magnetite) coexisting with graphite are also characterized by high Fe3+/XFe values. It has been established that Fe3 + -enriched carbonate-silicate melts can result from the interaction of Fe0-containing rocks with carbonated rocks. In the reduced mantle (with the presence of iron carbides or oxides), melts of this composition can be the source of carbon and the medium of graphite crystallization at once. After separation and ascent, these ferric carbonate-silicate melts can favor oxidizing metasomatism in the lithospheric mantle.

Смотреть статью,
Scopus,
WOS

Публикация на русском языке Роль пород, содержащих самородное железо, в образовании железистых карбонатно-силикатных расплавов: экспериментальное моделирование при P-T-параметрах литосферной мантии [Текст] / Ю. В. Баталева [и др.] // Геол. и геофиз. - Новосибирск : Изд-во СО РАН, 2015. - Т. 56 № 1-2. - С. 188-203

Держатели документа:
Russian Acad Sci, Siberian Branch, VS Sobolev Inst Geol & Mineral, Novosibirsk 630090, Russia.
Russian Acad Sci, Kirensky Inst Phys, Siberian Branch, Krasnoyarsk 660036, Russia.
Novosibirsk State Univ, Novosibirsk 630090, Russia.

Доп.точки доступа:
Bataleva, Yu. V.; Palyanov, Yu. N.; Sokol, A. G.; Borzdov, Yu. M.; Bayukov, O. A.; Баюков, Олег Артемьевич; Siberian Branch of the Russian Academy of Sciences [31]; Russian Foundation for Basic Research [12-05-00740]
}
Найти похожие

12.

    Synthesis, structural and spectroscopic properties of acentric triple molybdate Cs2NaBi(MoO4)3 / A. A. Savina [et al.] // J. Solid State Chem. - 2015. - Vol. 225. - P. 53–58, DOI 10.1016/j.jssc.2014.11.023. - Cited References: 66. - The authors are grateful to Dr. K.M. Khal'baeva and Dr. Irina A. Gudkova for their assistance in preparing the compound and taking X-ray single-crystal diffraction data. This study is partly supported by the Russian Foundation for Basic Research (Grants 13-03-01020 and 14-03-00298). V.V.A., A.S.K. and A.S.O. gratefully acknowledge the Ministry of Education and Science of the Russian Federation for a partial financial support. . - ISSN 0022-4596. - ISSN 1095-726X
   Перевод заглавия: Синтез, структурные и спектроскопические свойства ацентричного тройного молибдата Cs2NaBi(MoO4)3

РУБ Chemistry, Inorganic & Nuclear + Chemistry, Physical
Рубрики:
CRYSTAL-STRUCTURE
   SINGLE-CRYSTALS
   VIBRATIONAL PROPERTIES
   RAMAN-SPECTROSCOPY
   HYDROTHERMAL SYNTHESIS
   DIELECTRIC-PROPERTIES
   SELECTIVE OXIDATION;
   BISMUTH MOLYBDATES
   IONIC-CONDUCTIVITY
   OPTICAL-PROPERTIES
Кл.слова (ненормированные):
Triple molybdate -- Sodium -- Cesium -- Bismuth -- Crystal structure -- Raman spectroscopy -- CRYSTAL-STRUCTURE -- SINGLE-CRYSTALS -- VIBRATIONAL PROPERTIES -- RAMAN-SPECTROSCOPY -- HYDROTHERMAL SYNTHESIS -- DIELECTRIC-PROPERTIES -- SELECTIVE OXIDATION; -- BISMUTH MOLYBDATES -- IONIC-CONDUCTIVITY -- OPTICAL-PROPERTIES
Аннотация: New ternary molybdate Cs2NaBi(MoO4)3 is synthesized in the system Na2MoO4–Cs2MoO4–Bi2(MoO4)3. The structure of Cs2NaBi(MoO4)3 of a new type is determined in noncentrosymmetric space group R3c, a=10.6435(2), c=40.9524(7) Å, V=4017.71(13) Å3, Z=12 in anisotropic approximation for all atoms taking into account racemic twinning. The structure is completely ordered, Mo atoms are tetrahedrally coordinated, Bi(1) and Bi(2) atoms are in octahedra, and Na(1) and Na(2) atoms have a distorted trigonal prismatic coordination. The Cs(1) and Cs(2) atoms are in the framework cavities with coordination numbers 12 and 10, respectively. No phase transitions were found in Cs2NaBi(MoO4)3 up to the melting point at 826 K. The compound shows an SHG signal, I2w/I2w(SiO2)=5 estimated by the powder method. The vibrational properties are evaluated by Raman spectroscopy, and 26 narrow lines are measured.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
SB RAS, Baikal Inst Nat Management, Lab Oxide Syst, Ulan Ude 670047, Russia.
Buryat State Univ, Dept Chem, Ulan Ude 670000, Russia.
SB RAS, Rzhanov Inst Semicond Phys, Lab Opt Mat & Struct, Novosibirsk 630090, Russia.
Tomsk State Univ, Funct Elect Lab, Tomsk 634050, Russia.
Novosibirsk State Univ, Lab Semicond & Dielect Mat, Novosibirsk 630090, Russia.
SB RAS, Nikolaev Inst Inorgan Chem, Lab Crystal Chem, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia.
SB RAS, Kirensky Inst Phys, Lab Mol Spectroscopy, Krasnoyarsk 660036, Russia.
SB RAS, Nikolaev Inst Inorgan Chem, Lab Epitaxial Layers, Novosibirsk 630090, Russia.
Novosibirsk State Univ, Lab Res Methods Composit & Struct Funct Mat, Novosibirsk 630090, Russia.
SB RAS, Kirensky Inst Phys, Lab Crystal Struct, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Dept Photon & Laser Technol, Krasnoyarsk 660079, Russia.
SB RAS, Inst Automat & Elect, Lab Condenced Matter Spectroscopy, Novosibirsk 630090, Russia.

Доп.точки доступа:
Savina, A. A.; Atuchin, V. V.; Solodovnikov, S. F.; Solodovnikova, Z. A.; Krylov, A. S.; Крылов, Александр Сергеевич; Maximovsky, E. A.; Molokeev, M. S.; Молокеев, Максим Сергеевич; Oreshonkov, A. S.; Орешонков, Александр Сергеевич; Pugachev, A. M.; Khaikina, E. G.; Russian Foundation for Basic Research [4828.2012.2, 12-02-31205]; Federal Special Program "Scientific and scientific-pedagogical staff of innovative Russia" [8379]
}
Найти похожие

13.

New method for regulating the activity of ABO3 perovskite catalysts / S. N. Vereshchagin [et al.] // Kinet. Catal. - 2015. - Vol. 56, Is. 5. - P. 640-645, DOI 10.1134/S0023158415040199. - Cited References:23. - This work was supported in part by the Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools (grant no. NSh-2886.2014.2). . - ISSN 0023. - ISSN 1608-3210. -

РУБ Chemistry, Physical
Рубрики:
MEMBRANE REACTORS
   METHANE COMBUSTION
   OXIDATION
   OXIDES
   OXYGEN
   PERFORMANCE
   FEATURES
   PHASES
   CO
Кл.слова (ненормированные):
perovskite -- cobalt -- methane -- deep oxidation -- oxidative condensation
Аннотация: A new possibility of changing the activity and selectivity of perovskite catalysts in the oxidative conversion of methane was demonstrated using the Sr x Gd1–x CoO3–δ (0.5 < x < 0.9) compounds as an example. It was established that, at the same chemical composition, the disordering of Sr2+/Gd3+ ions over the A positions of the crystal structure led to a significant increase in activity in the deep oxidation reaction of CH4, as compared with the samples with an ordered distribution of cations.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ

Публикация на русском языке Новый способ регулирования активности катализаторов АВО3 со структурой перовскита [Текст] / С. Н. Верещагин [и др.] // Кинетика и катализ. - М. : Наука, 2015. - Т. 56 № 5. - С. 649-664

Держатели документа:
Russian Acad Sci, Siberian Branch, Inst Chem & Chem Technol, Krasnoyarsk 660036, Russia.
Russian Acad Sci, Siberian Branch, Kirenskii Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Vereshchagin, S. N.; Solov'ev, L. A.; Соловьев, Леонид Александрович; Rabchevskii, E. V.; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Ovchinnikov, S. G.; Овчинников, Сергей Геннадьевич; Anshits, A. G.; Аншиц, Александр Георгиевич; Council of the President of the Russian Federation for Support of Young Scientists and Leading Scientific Schools [NSh-2886.2014.2]
}
Найти похожие

14.

    Магнитотранспортные свойства тонких пленок оксида индия при низких температурах / И. А. Тамбасов [и др.] // Решетневские чтения : материалы XIX Междунар. науч. конф. : в 2-х ч. - Красноярск : Сибирский государственный аэрокосмический университет им. акад. М. Ф. Решетнева, 2015. - Ч. 1. - С. 546-547. - Библиогр.: 5. - Исследование было поддержано Российским фондом фундаментальных исследований (грант 15-02-00948-A,), Советом по грантам Президента Российской Федерации (СП-317.2015.1) и программой Фонда содействия развитию малых форм предприятий в научно-технической сфере ("У.М.Н.И.К."). . - ISBN 1990-7702
   Перевод заглавия: Magnetotransport properties of indium oxide thin films at low temperatures
Кл.слова (ненормированные):
оксид индия -- тонкие пленки -- автоволновое окисление -- indium oxide -- thin films -- autowave oxidation
Аннотация: Представлено исследование магнитотранспортных свойств пленок оксида индия в температурном диапазоне от 4,2 до 80 K. Полученные экспериментальные данные могут быть полезны для специалистов аэрокосмической отрасли.
This paper presents a study of magnetotransport properties of indium oxide films in the temperature range from 4.2 to 80 K. The experimental data can be useful for aerospace specialists.

Материалы конференции,
РИНЦ,
Читать в сети ИФ
Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Тамбасов, Игорь Анатольевич; Tambasov, I. A.; Тарасов, Антон Сергеевич; Tarasov, A. S.; Рауцкий, Михаил Владимирович; Rautskii, M. V.; Мягков, Виктор Григорьевич; Myagkov, V. G.; Тамбасова, Е. Г.; Tambasova E. V.; "Решетневские чтения", международная научно-практическая конференция(19 ; 2015 ; нояб. ; 10-14 ; Красноярск)
}
Найти похожие

15.

Wüstite stability in the presence of a CO2-fluid and a carbonate-silicate melt: Implications for the graphite/diamond formation and generation of Fe-rich mantle metasomatic agents / Y. V. Bataleva [et al.] // Lithos. - 2016. - Vol. 244. - P. 20-29, DOI 10.1016/j.lithos.2015.12.001. - Cited References: 68. - This work was supported by the Russian Science Foundation under grant no. 14-27-00054. The authors thank A. Moskalev for his assistance in the work preparation, A. Khokhryakov for useful suggestions throughout the study, and S. Ovchinnikov for his assistance in implementation of Mössbauer spectroscopy measurements. The authors thank editor M. Scambelluri, and two anonymous reviewers for their useful comments, which helped to profoundly improve the manuscript. . - ISSN 0024-4937

РУБ Geochemistry & Geophysics + Mineralogy
Рубрики:
EARTHS LOWER MANTLE
   FERRIC IRON CONTENT
   DIAMOND FORMATION
   MINERAL INCLUSIONS
   NATURAL DIAMOND
   OXIDATION-STATE
   DEEP MANTLECRUST
   LITHOSPHERIC MANTLE
   OXYGEN FUGACITY
   OCEANIC-CRUST
Кл.слова (ненормированные):
Wustite -- CO2-fluid -- Carbonate-silicate melt -- Decarbonation -- Graphite formation -- HPHT experiment
Аннотация: Experimental simulation of the interaction of wüstite with a CO2-rich fluid and a carbonate-silicate melt was performed using a multianvil high-pressure split-sphere apparatus in the FeO-MgO-CaO-SiO2-Al2O3-CO2 system at a pressure of 6.3GPa and temperatures in the range of 1150°C-1650°C and with run time of 20h. At relatively low temperatures, decarbonation reactions occur in the system to form iron-rich garnet (Alm75Prp17Grs8), magnesiowüstite (Mg#≤0.13), and CO2-rich fluid. Under these conditions, magnesiowüstite was found to be capable of partial reducing CO2 to C0 that leads to the formation of Fe3+-bearing magnesiowüstite, crystallization of magnetite and metastable graphite, and initial growth of diamond seeds. At T≥1450°C, an iron-rich carbonate-silicate melt (FeO~56wt.%, SiO2~12wt.%) forms in the system. Interaction between (Fe,Mg)O, SiO2, fluid and melt leads to oxidation of magnesiowüstite and crystallization of fayalite-magnetite spinel solid solution (1450°C) as well as to complete dissolution of magnesiowüstite in the carbonate-silicate melt (1550°C-1650°C). In the presence of both carbonate-silicate melt and CO2-rich fluid, dissolution (oxidation) of diamond and metastable graphite was found to occur. The study results demonstrate that under pressures of the lithospheric mantle in the presence of a CO2-rich fluid, wüstite/magnesiowüstite is stable only at relatively low temperatures when it is in the absolute excess relative to CO2-rich fluid. In this case, the redox reactions, which produce metastable graphite and diamond with concomitant partial oxidation of wüstite to magnetite, occur. Wüstite is unstable under high concentrations of a CO2-rich fluid as well as in the presence of a carbonate-silicate melt: it is either completely oxidized or dissolves in the melt or fluid phase, leading to the formation of Fe2+- and Fe3+-enriched carbonate-silicate melts, which are potential metasomatic agents in the lithospheric mantle. © 2015 Elsevier B.V.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Sobolev Institute of Geology and Mineralogy, Siberian Branch of Russian Academy of Sciences, Koptyug ave 3, Novosibirsk, Russian Federation
Novosibirsk State University, Pirogova str 2, Novosibirsk, Russian Federation
Kirensky Institute of Physics, Siberian Branch of Russian Academy of Sciences, Akademgorodok 50, bld. 38, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Bataleva, Yu. V.; Palyanov, Y .N.; Sokol, A. G.; Borzdov, Y. M.; Bayukov, O. A.; Баюков, Олег Артемьевич
}
Найти похожие

16.

Oxidative conversion of methane over Gd-Sr-Co-perovskites: structure-activity relationship / S. N. Vereshchagin [et al.] // 12th Eur. Congress on Catalysis (EuropaCat-XII) : [proceedings]. - 2015. - Библиогр.: 4
Кл.слова (ненормированные):
methane -- oxidation -- OCM -- perovskite -- crystal structure

Материалы конгресса

Доп.точки доступа:
Vereshchagin, S. N.; Solovyov, L. A.; Соловьев, Леонид Александрович; Shishkina, N. N.; Шишкина, Нина Николаевна; Dudnikov, V. A.; Дудников, Вячеслав Анатольевич; Anshits, A. G.; Аншиц, Александр Георгиевич; European Congress on Catalysis "Catalysis: Balancing the use of fossil and renewable resources”(12 ; 30 Aug. - 4 Sept., 2015 ; Kazan, Russia)
}
Найти похожие

17.

High performance hybrid rGO/ Ag quasi-periodic mesh transparent electrodes for flexible electrochromic devices / A. S. Voronin [et al.] // Appl. Surf. Sci. - 2016. - Vol. 364. - P. 931–937, DOI 10.1016/j.apsusc.2015.12.182. - Cited References: 31 . - ISSN 0169-4332. - ISSN 1873-5584

РУБ Chemistry, Physical + Materials Science, Coatings & Films + Physics, Applied + Physics, Condensed Matter
Рубрики:
NANOWIRE NETWORKS
   GRAPHENE FILMS
   OXIDE
   OXIDATION
   HEATERS
Кл.слова (ненормированные):
Quasi-periodic mesh transparent electrode self-organized template -- Reduced graphene oxide (rGO) -- Flexible electrochromic device
Аннотация: A possibility of creating a stable hybrid coating based on the hybrid of a reduced graphene oxide (rGO)/ Ag quasi-periodic mesh (q-mesh) coating has been demonstrated. The main advantages of the suggested method are the low cost of the processes and the technology scalability. The Ag q-mesh coating is formed by means of the magnetron sputtering of silver on the original template obtained as a result of quasi-periodic cracking of a silica film. The protective rGO film is formed by low temperature reduction of a graphene oxide (GO) film, applied by the spray-deposition in the solution of NaBH4. The coatings have low sheet resistance (12.3 Ω/sq) and high optical transparency (82.2%). The hybrid coating are characterized by high chemical stability, as well as they show high stability to deformation impacts. High performance of the hybrid coatings as electrodes in the sandwich-system «electrode – electrochromic composition – electrode» has been demonstrated. The hybrid electrodes allow the electrochromic sandwich to function without any visible degradation for a long time, while an unprotected mesh electrode does not allow performing even a single switching cycle.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ

Доп.точки доступа:
Voronin, A. S.; Ivanchenko, F. S.; Simunin, M. M.; Shiverskiy, A. V.; Aleksandrovsky, A. S.; Александровский, Александр Сергеевич; Nemtsev, I. V.; Fadeev, Y. V.; Karpova, D. V.; Khartov, S. V.
}
Найти похожие

18.

Bi2(Sn0.95Cr0.05)2O7: Structure, IR spectra, and dielectric properties / S. S. Aplesnin [et al.] // Ceram. Int. - 2016. - Vol. 42, Is. 4. - P. 5177-5183, DOI 10.1016/j.ceramint.2015.12.040. - Cited References: 45. - This work was supported by the Russian Foundation for Basic Research Projects no. 15-42-04099 r_siberia_a, Siberian Branch of Science and NAS of Belarus “Electronic and magnetic phase transitions in materials with magnetoelectric affect” and government work no. 114090470016. . - ISSN 0272-8842

РУБ Materials Science, Ceramics
Рубрики:
BISMUTH PYROSTANNATE
   PYROCHLORE STRUCTURE
   MAGNETIC-PROPERTIES
   PARTIAL OXIDATION
   HIGH-TEMPERATURE
   X-RAY
   Bi2Sn2O7
   SUBSTITUTION
   CATALYSTS
   DIFFRACTION
Кл.слова (ненормированные):
Bismuth pyrostannate -- Infrared absorption spectra -- Structural transition -- Permittivity -- Debye model
Аннотация: Infrared absorption spectra of the bismuth pyrostannate Bi2(Sn0.95Cr0.05)2O7 were investigated in the frequency range 350-1100 cm-1 at temperatures of 110-525 K. Four frequency regions with split absorption lines are distinguished. Softening of frequencies at the structural transitions was observed. The maxima of permittivity measured in the frequency range 1-200 kHz at temperatures 100-400 K were determined. It was found that the magnetic susceptibility changes its sign in the low-temperature region. The correlation between anomalies in the magnetic susceptibility, permittivity, and absorption line intensity was established. Softening of frequencies is explained by the variation in the coefficient of thermal expansion of the lattice. The temperature behavior of permittivity is described using the Debye model. © 2015 Elsevier Ltd and Techna Group S.r.l.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Kirensky Institute of Physics, Russian Academy of Sciences, Siberian Branch, Akademgorodok 50, Krasnoyarsk, Russian Federation
Siberian State Aerospace University, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Aplesnin, S. S.; Аплеснин, Сергей Степанович; Udod, L. V.; Удод, Любовь Викторовна; Sitnikov, M. N.; Shestakov, N. P.; Шестаков, Николай Петрович
}
Найти похожие

19.

    Preparation and characterization of colloidal copper xanthate nanoparticles / Y. Mikhlin [et al.] // New J. Chem. - 2016. - Vol. 40, Is. 4. - P. 3059-3065, DOI 10.1039/c6nj00098c. - Cited References:50. - This research was supported by the Russian Science Foundation grant 14-17-00280. We thank Dr Roberto Felix Duarte (HZB) and bilateral program "German-Russian laboratory at BESSY II" for assistance with the X-ray absorption experiments. . - ISSN 1144-0546. - ISSN 1369-9261
   Перевод заглавия: Получение и исследование коллоидных наночастиц ксантогената меди

РУБ Chemistry, Multidisciplinary
Рубрики:
X-ray-absorption
   Self-assembled monolayers
   Sulfide nanoparticles
   Electronic-structure
   Waste-water
   Complexes
   Flotation
   Spectroscopy
   Adsorption
   Oxidation
Аннотация: Despite the important role of metal xanthates in a number of industrial processes and emerging applications, no attempts have been made to prepare the metal xanthate nanoparticles and to study colloidal solutions of insoluble heavy metal xanthates. Here, we examined the formation of colloidal copper xanthate particles during the reactions of aqueous solutions of cupric sulfate and various potassium xanthates, which occur in flotation and water treatment slurries and can be used to manufacture nanoparticles for materials science (e.g., as precursors for copper sulfide nanoparticles and biomedicine). The products were characterized using UV-vis absorption, dynamic light scattering, zeta potential measurements, transmission electron microscopy (TEM), electron diffraction, Fourier transform infrared spectroscopy, thermogravimetry, X-ray photoelectron spectroscopy, and X-ray absorption spectroscopy (XANES). Colloidal copper xanthates with compositions of ROCSSCu (R = ethyl, isopropyl, butyl, isobutyl, and amyl groups), disordered structures and average diameters of 20–80 nm easily formed and aggregated and were stable for at least several hours, especially if excessive xanthate was used. The hydrodynamic diameters of the nanoparticles were smaller at lower temperatures. Dixanthogens, which were produced in the reactions along with ROCSSCu, seemed to promote nanoparticle aggregation and precipitated with the copper xanthate, affecting their thermal decomposition. The TEM micrographs and S K- and Cu K-edge XANES spectra revealed core/shell particle morphologies, likely with Cu(I) bonded to four S atoms in the core and reduced copper coordination in the shell.

Смотреть статью,
Scopus,
WOS,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, Inst Chem & Chem Technol, Siberian Branch, Akad 50-24, Krasnoyarsk 6600036, Russia.
Siberian Fed Univ, Svobodny Pr 79, Krasnoyarsk 660041, Russia.
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Akad 50-38, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Mikhlin, Y. L.; Михлин, Юрий Леонидович; Vorobyev, S.; Saikova, S. V.; Сайкова, С. В.; Tomashevich, Y.; Fetisova, O.; Kozlova, S.; Zharkov, S. M.; Жарков, Сергей Михайлович; Russian Science Foundation [14-17-00280]
}
Найти похожие

20.

Chiganov, A. S.
Selective inhibition of the oxidation of nanodiamonds for their cleaning / A. S. Chiganov // Phys. Solid State. - 2004. - Vol. 46, Is. 4. - P. 620-621, DOI 10.1134/1.1711436. - Cited References: 6 . - ISSN 1063-7834

РУБ Physics, Condensed Matter

Аннотация: The effect of selective inhibition of nanodiamond oxidation upon heating of detonation carbon in air is used to extract nanodiamonds from the detonation products. The methods for cleaning nanodiamonds from nondiamond carbon modifications are described depending on the synthesis conditions. (C) 2004 MAIK "Nauka / Interperiodica".

WOS,
Scopus,
Читать в сети ИФ
Держатели документа:
Russian Acad Sci, Siberian Div, Krasnoyarsk Sci Ctr, Dept Phys Nanophase Mat, Krasnoyarsk 660036, Russia
КНЦ СО РАН, ОФНМ
Dept. of the Phys. of Nanophase Mat., Krasnoyarsk Scientific Center, Russian Academy of Sciences, Krasnoyarsk, 660036, Russian Federation
}
Найти похожие