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Sokolov, V. V.
Comparative study of magnetic circular dichroism of f-f transitions in ErAl3(BO3)4 and ErFe3(BO3)4 / V. V. Sokolov, A. V. Malakhovskii, I. A. Gudim // XVII International Feofilov Symposium on spectroscopy of crystals doped with rare earth and transition metal ions (IFS'XVII) : book of abstracts. - 2018. - P. 207-208

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Malakhovskii, A. V.; Малаховский, Александр Валентинович; Gudim, I. A.; Гудим, Ирина Анатольевна; Соколов, Валерий Владимирович; International Feofilov Symposium on spectroscopy of crystals doped with rare earth and transition metal ions(17 ; 2018 ; Sept. ; 23-28 ; Ekaterinburg, Russia)
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Malakhovskii, A. V.
Influence of the low local symmetry of Er3+ ions on magnetic circular dichroism and absorption spectra of f-f transitions in ErFe3(BO3)4 single crystal / A. V. Malakhovskii, V. V. Sokolov, I. A. Gudim // J. Magn. Magn. Mater. - 2018. - Vol. 465. - P. 700-708, DOI 10.1016/j.jmmm.2018.06.057. - Cited References: 29. - The work was supported by the Russian Foundation for Basic Researches grant 16-02-00273 and by the Project of Russian Academy of Science No. 0356-2017-0030. . - ISSN 0304-8853
Кл.слова (ненормированные):
Er3+ ion -- f-f transitions -- Magnetic circular dichroism -- Rare earth ferroborates
Аннотация: Linearly polarized absorption spectra and magnetic circular dichroism (MCD) spectra of ErFe3(BO3)4 single crystal were measured in the range of 9000–23000 cm−1 at 90 K. The absorption spectra of f-f transitions were decomposed into the Lorentz shape components and intensities of the components were found. MCD spectra permitted us to measure the Zeeman splitting of some transitions and so to determine changes of the Landé factor along the C3 axis of the crystal during these transitions. Optical and magneto-optical properties of f-f transitions in the ErFe3(BO3)4 crystal were compared with those in the ErAl3(BO3)4 crystal. Substantial difference of the properties connected with the difference of the Er3+ ions local symmetry in two crystals was revealed. Large splitting of one of the f-f transitions without magnetic field, which is not possible for the Kramers doublets, was observed. It was explained by appearance of two absorbing centers due to the local decrease of symmetry in the excited state. Appreciable difference of the local vibrations energy in some excited states was revealed.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Малаховский, Александр Валентинович
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Magnetic circular dichroism and absorption of a HoAl3(BO3)4 crystal in the region of 5I8 → 5I3 and 5F2 transitions / V. V. Sokolov, A. V. Malakhovskii, A. L. Sukhachev, I. A. Gudim // VIII Euro-Asian symposium "Trends in magnetism" (EASTMAG-2022) : Book of abstracts / program com. S. G. Ovchinnikov [et al.]. - 2022. - Vol. 1, Sect. : Magnetotransport, magnetooptics and magnetophotonics. - Ст. D.P16. - P. 470-471. - Cited References: 4 . - ISBN 978-5-94469-051-7

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia

Доп.точки доступа:
Ovchinnikov, S. G. \program com.\; Овчинников, Сергей Геннадьевич; Sokolov, V. V.; Соколов, Валерий Владимирович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; Российская академия наук; Физико-технический институт им. Е.К. Завойского ФИЦ Казанского научного центра РАН; Казанский (Приволжский) федеральный университет; Euro-Asian Symposium "Trends in MAGnetism"(8 ; 2022 ; Aug. ; 22-26 ; Kazan); "Trends in MAGnetism", Euro-Asian Symposium(8 ; 2022 ; Aug. ; 22-26 ; Kazan)
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Magnetic circular dichroism and absorption spectra of 5I8 → 5F5 transition in HoAl3(BO3)4 and HoFe3(BO3)4 single crystals / A. V. Malakhovskii [et al.] // Phys. Lett. A. - 2019. - Vol. 383, Is. 16. - P. 1960-1966, DOI 10.1016/j.physleta.2019.03.016. - Cited References: 34. - The work was supported by the Russian Foundation for Basic Researches grant 19-02-00034. . - ISSN 0375-9601
Кл.слова (ненормированные):
Ho3+ ion -- f-f transitions -- Magnetic circular dichroism -- Electron structure
Аннотация: Comparative study of magnetic circular dichroism (MCD) and absorption spectra of HoAl3(BO3)4 and HoFe3(BO3)4 single crystals in the region of 5I8 → 5F5 transition of the Ho3+ ion was carried out. Absorption spectra were decomposed into the Lorentz shape components and intensities of transitions were obtained. Unusually strong vibronic transitions were observed in HoAl3(BO3)4, but were not observed in HoFe3(BO3)4 that testified to the strong non diagonal vibronic interaction in HoAl3(BO3)4. The MCD spectra were analyzed in approximation of the ∣J,± MJ≻ of the wave functions of the free atom and using concept of the crystal quantum number. Peculiarity of application of this concept to ions with integer moments was revealed and modification of the concept was suggested. With the help of the MCD spectra, the Zeeman splitting of some transitions was found. In particular, the Landé factor gC ≈2 of the ground state of the Ho3+ ion in HoAl3(BO3)4 in the trigonal axis direction was determined. It appeared to be five times less than that in HoFe3(BO3)4 also found with the help of the MCD.

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Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Rautskii, M. V.; Рауцкий, Михаил Владимирович
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Malakhovskii, A. V.
Magnetic circular dichroism and absorption spectra of f–f transitions 5I8 → 5F2 and 5F3 in the HoFe3(BO3)4 single crystal / A. V. Malakhovskii, V. V. Sokolov, I. A. Gudim // Low Temp. Phys. - 2020. - Vol. 46, Is. 7. - P. 734-739, DOI 10.1063/10.0001371. - Cited References: 16. - The study was supported by the Russian Foundation for Basic Research, grant No. 19-02-00034, and also by the Krasnoyarsk Krai Russian Foundation for Basic Research and the Krasnoyarsk Krai Regional Fund of Science as part of project No. 19-42-240003 on "The influence of the local environment on the magneto-optical properties of f-f transitions in rare-earth aluminoborates and ferroborates" . - ISSN 1063-777X. - ISSN 1090-6517

РУБ Physics, Applied
Рубрики:
MAGNETOOPTICAL ACTIVITY
ELECTRON-STRUCTURE
ERFE3(BO3)4
Кл.слова (ненормированные):
magnetic circular dichroism -- f-ftransitions -- rare earth ferroborates
Аннотация: Magnetic circular dichroism (MCD) and absorption spectra of multiferroic HoFe3(BO3)4 of 5I8 → 5F2 and 5F3 f–f transitions are measured at T = 90 K. The absorption spectra are expanded into Lorentzian components, and the transition intensities are obtained. The Zeeman splitting of some transitions is determined using the MCD and absorption spectra. The MCD spectra and Zeeman splitting are theoretically analyzed in the free-atom |J, ±MJ〉wave function approximation by using the concept of a crystalline quantum number. An inconsistency is revealed when this concept is applied to ions with an integer moment, and a modification of the concept is proposed. Anomalously intense vibronic repetitions of electronic transitions from excited sublevels of the ground multiplet are found.

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Публикация на русском языке Малаховский, Александр Валентинович. Магнитный круговой дихроизм и поглощение кристалла HoFe3(BO3)4 в области f–f переходов 5I8 → 5F2 и 5F3 [Текст] / А. В. Малаховский, В. В. Соколов, И. А. Гудим // Физ. низких температур. - 2020. - Т. 46 № 7. - С. 869-876

Держатели документа:
Russian Acad Sci, Siberian Branch, Fed Res Ctr Krasnoyarsk Sci Ctr, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Малаховский, Александр Валентинович; Russian Foundation for Basic ResearchRussian Foundation for Basic Research (RFBR) [19-02-00034]; Krasnoyarsk Krai Russian Foundation for Basic Research; Krasnoyarsk Krai Regional Fund of Science [19-42-240003]
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Magnetic circular dichroism of 5 I8 5F5 transition in HoAl3(BO3)4 and HoFe3(BO3)4 crystals / V. V. Sokolov [et al.] // Euro-asian symposium "Trends in magnetism" (EASTMAG-2019) : Book of abstracts / чл. конс. ком.: S. G. Ovchinnikov, N. V. Volkov [et al.] ; чл. прогр. ком. D. M. Dzebisashvili [et al.]. - 2019. - Vol. 1. - Ст. E.P2. - P. 423-424. - Cited References: 4. - Support by the Russian Foundation for Basic Researches grant 19-02-00034 is acknowledged . - ISBN 978-5-9500855-7-4

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russia

Доп.точки доступа:
Ovchinnikov, S. G. \чл. конс. ком.\; Овчинников, Сергей Геннадьевич; Volkov, N. V. \чл. конс. ком.\; Волков, Никита Валентинович; Dzebisashvili, D. M. \чл. прогр. ком.\; Дзебисашвили, Дмитрий Михайлович; Sokolov, V. V.; Соколов, Валерий Владимирович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Gudim, I. A.; Гудим, Ирина Анатольевна; Rautskii, M. V.; Рауцкий, Михаил Владимирович; Российская академия наук; Уральское отделение РАН; Институт физики металлов им. М. Н. Михеева Уральского отделения РАН; Уральский федеральный университет им. первого Президента России Б.Н. Ельцина; Российский фонд фундаментальных исследований; Euro-Asian Symposium "Trends in MAGnetism"(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg); "Trends in MAGnetism", Euro-Asian Symposium(7 ; 2019 ; Sept. ; 8-13 ; Ekaterinburg)
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Malakhovskii, A. V.
Magnetic circular dichroism of 5I8→ 5F3, 5F2 and 3K8 transitions in Na0.4Ho0.6F2.2 single crystal / A. V. Malakhovskii, V. V. Sokolov, D. N. Karimov // Opt. Mater. - 2021. - Vol. 114. - Ст. 110953, DOI 10.1016/j.optmat.2021.110953. - Cited References: 23. - A.V. Malakhovskii and V.V. Sokolov acknowledge the financing of the reported study by the Russian Foundation for Basic Researches grant 19-02-00034 and by the Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, to the research project: number 19-42-240003 “Influence of the local environment on magneto-optical properties of f-f transitions in rare-earth aluminum and iron borates.” D.N. Karimov acknowledges the financing support by the Ministry of Science and Higher Education of Russia within the State assignment FSRC «Crystallography and Photonics» of Russian Academy of Sciences . - ISSN 0925-3467
Кл.слова (ненормированные):
Magnetic circular dichroism -- f-f transitions -- Fluoride crystals Ho3+ ions
Аннотация: We measured optical absorption and magnetic circular dichroism spectra of Na0.4Ho0.6F2.2 single crystal in the region of 5I8→ 5F3, 5F2 and 3K8 transitions in Ho3+ ion at 90 K and room temperature. Paramagnetic magneto-optical activities (MOA) of the transitions were found for these two temperatures and compared with the theory based on the nature of f-f transitions allowance. It was shown that nature of allowance of three considered transitions is different. The MCD spectra were also analyzed in approximation of the |J, ±MJ› wave functions of the free atom and using concept of the crystal quantum number. Using this concept and experimental paramagnetic MOA, we found that MJeff = 2.1 for the initial state of the 5I8→ 5F3 transition.

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Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Federal Scientific Research Centre «Crystallography and Photonics» of Russian Academy of Sciences, Leninskiy Prospekt 59, Moscow, 119333, Russian Federation

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Karimov, D. N.; Малаховский, Александр Валентинович
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Magnetic circular dichroism of f-f transitions in multiferroic antiferromagnet Ho0.75Nd0.25Fe3(BO3)4 / A. V. Malakhovskii, V. V. Sokolov, A. L. Sukhachev, I. A. Gudim // International conference "Functional materials" : book of abstracts / ed. V. N. Berzhansky ; org. com. S. G. Ovchinnikov [et al.]. - Simferopol, 2023. - P. 100-101. - Cited References: 2

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Держатели документа:
Kirensky Institute of Physics, FRC KSC SB RAS,

Доп.точки доступа:
Berzhansky, V. N. \ed.\; Бержанский, Владимир Наумович; Ovchinnikov, S. G. \org. com.\; Овчинников, Сергей Геннадьевич; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sokolov, V. V.; Соколов, Валерий Владимирович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; "Functional materials", International conference(2023 ; Oct. 2-6 ; Crimea, Foros); Крымский федеральный университет имени В.И. Вернадского
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    Sokolov, V. V.
    Magnetic circular dichroism spectra and electron structure of ErAl3(BO3)4 single crystal / V. V. Sokolov, A. V. Malakhovskii, I. A. Gudim // Moscow Int. Symp. on Magnet. (MISM-2017) : 1-7 July 2017 : book of abstracts / чл. междунар. конс. комитета С. Г. Овчинников ; чл. нац. конс. комитета Н. В. Волков. - 2017. - Ст. 32PO-12-5. - P. 588. - Cited References: 1
   Перевод заглавия: Московский международный симпозиум по магнетизму

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Доп.точки доступа:
Овчинников, Сергей Геннадьевич \чл. междунар. конс. комитета\; Ovchinnikov, S. G.; Волков, Никита Валентинович \чл. нац. конс. комитета\; Volkov, N. V.; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Gudim, I. A.; Гудим, Ирина Анатольевна; Соколов, Валерий Владимирович; Moscow International Symposium on Magnetism(7 ; 2017 ; Jul. ; Moscow); Московский государственный университет им. М.В. Ломоносова; Российский фонд фундаментальных исследований
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10.

    Magneto-optical activity of F-F transitions in Nd[[d]]0.5[[/d]]Gd[[d]]0.5[[/d]]Fe[[d]]3[[/d]](BO[[d]]3[[/d]])[[d]]4[[/d]] and ErFe[[d]]3[[/d]](BO[[d]]3[[/d]])[[d]]4[[/d]] single crystal [Текст] / A. L. Sukhachev [и др.] // V Euro-Asian simposium "Trend in MAGnetism": Nanomagnetism : abstracts. - Vladivostok : FEFU, 2013. - P. 287 . - ISBN 978-5-7444-3124-2
   Перевод заглавия: Магнитооптическая активность f-f переходов в монокристаллах Nd0,5Gd0,5Fe3(BO3)4 и ErFe3(BO3)4
Аннотация: Изучены спектры поглощения и магнитного кругового дихроизма и магнитооптическая активность f-f переходов в кристаллах Nd0.5Gd0.5Fe3(BO3)4 и ErFe3(BO3)4 в функции от температуры. Проведено сравнение экспериментальных результатов с теорией.

Доп.точки доступа:
Sukhachev, A. L.; Сухачев, Александр Леонидович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sokolov, V. V.; Соколов, Валерий Владимирович; Temerov, V. L.; Темеров, Владислав Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна; Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism(5 ; 2013 ; Sept. ; 15-21 ; Vladivostok)
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11.

    Magneto-optical properties of ErFe3(BO3)4 and ErAl3(BO3)4 single crystals / A. V. Malakhovskii [et al.] // Spin Waves 2015, Int. Symp. : abstracts. - СПб., 2015. - P. 156
   Перевод заглавия: Магнито-оптические свойства монокристаллов ErFe3(BO3)4 и ErAl3(BO3)4

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Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Sokolov, V. V.; Соколов, Валерий Владимирович; Kutsak, T. V.; Куцак, Т. В.; Gudim, I. A.; Гудим, Ирина Анатольевна; "Spin Waves", International Simposium(2015 ; Jun. ; 7-13 ; Saint Petersburg); Физико-технический институт им. А.Ф. Иоффе РАН
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12.

Magnetooptical properties of amorphous Co–P thin films / V. V. Sokolov [et al.] // VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016) : abstracts / ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk : KIP RAS SB, 2016. - Ст. P6.4. - P. 312 . - ISBN 978-5-904603-06-9
Кл.слова (ненормированные):
Co-P thin films -- magnetic circular dichroism -- Faraday rotation

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Tabakaeva, K. V.; Табакаева К. В.; Burkova, L. V.; Буркова, Людмила Викторовна; Chzhan, A.V.; Чжан, Анатолий Владимирович; Patrin, G. S.; Патрин, Геннадий Семёнович; Euro-Asian Symposium "Trends in MAGnetism"(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); "Trends in MAGnetism", Euro-Asian Symposium(6 ; 2016 ; Aug. ; 15-19 ; Krasnoyarsk); Институт физики им. Л.В. Киренского Сибирского отделения РАН

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13.

Malakhovskii, A. V.
Natural optical activity of f-f transitions in ErAl3(BO3)4 single crystal / A. V. Malakhovskii, V. V. Sokolov, I. A. Gudim // Chem. Phys. - 2017. - Vol. 493. - P. 102-110, DOI 10.1016/j.chemphys.2017.06.011. - Cited References: 50. - The work was supported by the Russian Foundation for Basic Researches grant 16-02-00273 and by the President of Russia grant No Nsh-7559.2016.2. . - ISSN 0301-0104
Кл.слова (ненормированные):
f-f transitions -- Natural circular dichroism -- Er3+ ion
Аннотация: Absorption and natural circular dichroism (NCD) spectra of ErAl3(BO3)4 single crystal were measured at 90 K in the range of 10,000–28,200 cm−1. The spectra were decomposed on the Lorentz shape components and the natural optical activities (NOA) of f-f transitions between Stark components of the ground and excited multiplets were found. The NCD spectra permitted us to find out existence of two non equivalent positions of Er3+ ion in one of its excited states, which are due to the local decrease of the crystal symmetry in this state. Very large NOA of a vibronic line was revealed. This phenomenon was accounted for basing on the new quantum mechanical formula for the NOA of electron transitions. The principle difference of the NOA properties of electric dipole allowed and parity forbidden transitions is discussed.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, Russian Federation

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Малаховский, Александр Валентинович
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14.

Malakhovskii, A. V.
Nature of magnetic circular dichroism and absorption spectra of f-f transitions in Na0.4Ho0.6F2.2 single crystal / A. V. Malakhovskii, V. V. Sokolov, D. N. Karimov // Chem. Phys. - 2024. - Vol. 581. - Ст. 112257, DOI 10.1016/j.chemphys.2024.112257. - Cited References: 25 . - ISSN 0301-0104. - ISSN 1873-4421
Кл.слова (ненормированные):
Magnetic circular dichroism -- f-f transitions -- Fluoride crystals -- Ho ions
Аннотация: We present first study of magnetic circular dichroism (MCD) spectra of Ho3+ ion in C4v local symmetry, which it has in fluorite Na0.4Ho0.6F2.2. Optical absorption and MCD spectra were studied in this single crystal in the region of 5I8> 5F3, 5F2, 3K8 and 5G5 transitions in the temperature range 3.6–––90 K. It was revealed, that number of transitions observed in the MCD and absorption spectra coincides with the number of transitions only from the doublet E state to singlet excited states. The E-E type transitions are not active in MCD, but they are not observed in the absorption spectra either. Paramagnetic magneto-optical activities (MOA) of the absorption bands and their temperature dependences were measured and interpreted with the help of the theory based on the nature of f-f transitions allowance. The MCD spectra were also analyzed in approximation of the J,±MJ wave functions of the free atom. It was shown in particular, that the lowest initial state of the transitions observed at T ˃ 10 K had MJ = 7, but this is not the lowest state of the holmium ion in the crystal. A little lower there is a quasi-doublet with MJ = 8 and, accordingly, with a higher magneto-optical activity of transitions from it. However, the intensity of transitions from this state is low.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, 660036 Krasnoyarsk, Russian Federation
Federal Scientific Research Centre «Crystallography and Photonics» of Russian Academy of Sciences, Leninskiy Prospekt 59, 119333 Moscow, Russia

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Karimov, D.N.; Малаховский, Александр Валентинович
}
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15.

Neutron diffraction measurements of the FexMn1-xS solid solutions [Text] / G. A. Abramova, M. Boehm, B. Roessli [et al.] // 4th European conference on neutron scattering : Lund, Sweden, 25-29 June 2007 : [сб. тезисов]. - p. 128

Доп.точки доступа:
Abramova, G. A.; Boehm, M.; Roessli, B.; Raseh, J.; Petrakovskiy, G. A.; Петраковский, Герман Антонович; Velikanov, D. A.; Великанов, Дмитрий Анатольевич; Vorotynov, A. M.; Воротынов, Александр Михайлович; Bovina, A. F.; Бовина, Ася Федоровна; Sokolov, V. V.; Соколов, Валерий Владимирович; European conference on neutron scattering(4 ; 2007 ; June ; Lund, Sweden)
}
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16.

Malakhovskii, A. V.
Optical and magneto-optical spectra and electron structure of ErAl3(BO3)4 single crystal / A. V. Malakhovskii, V. V. Sokolov, I. A. Gudim // J. Alloys Compd. - 2017. - Vol. 698. - P. 364-374, DOI 10.1016/j.jallcom.2016.12.200. - Cited References: 32. - The work was supported by the Russian Foundation for Basic Researches grant 16-02-00273 and by the President of Russia grant No Nsh-7559.2016.2. . - ISSN 0925-8388
Кл.слова (ненормированные):
Electron structure -- Er3+ ion -- f-f transitions -- Magnetic circular dichroism
Аннотация: Linearly polarized absorption spectra and magnetic circular dichroism (MCD) spectra of ErAl3(BO3)4 single crystal were measured in the range of 10000–27000 cm−1 at 90 K. The Stark components of the ground and excited multiplets of Er3+ ion were identified in terms of the irreducible representations, basing on the linearly polarized absorption spectra. MCD spectra permitted us to measure the Zeeman splitting of some transitions and so to determine changes of the Landé factors along the C3 axis during these transitions. Additionally, the MCD spectra permitted us to identify some states in the |J,±MJ〉function approximation. In particular, it was shown that the ground state of the Er3+ ion in this approximation has MJ = ± 13/2 that corresponds to magnetic moment m = ±7.8 μB. Very intensive f-f vibronic transitions, corresponding to electron transitions from the upper components of the ground multiplet, were revealed. Energies of the local vibrations in a number of the excited states were found.

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Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Малаховский, Александр Валентинович
}
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17.

Paramagnetic magneto-optical activity of f-f transitions in HoFe3(BO3)4 and HoAl3(BO3)4 single crystals / V. V. Sokolov [et al.] // Opt Mater. - 2019. - Vol. 94. - P. 35-40, DOI 10.1016/j.optmat.2019.05.024. - Cited References: 38. - The work was supported by the Russian Foundation for Basic Researches grant 19-02-00034. . - ISSN 0925-3467
Кл.слова (ненормированные):
Magnetic circular dichroism -- f-f transitions -- Rare earth ferroborates -- Rare earth alumoborates
Аннотация: Absorption and magnetic circular dichroism (MCD) spectra of HoFe3(BO3)4 and HoAl3(BO3)4 single crystals were measured as a function of temperature in the range of 90–293 K. Based on integrals of f-f absorption and МСD bands, temperature dependences of the paramagnetic magneto-optical activity (MOA) of f-f transitions were obtained for the first time. It was revealed that MOA of the same f-f transitions in the studied crystals were substantially different and their temperature dependences did not follow the Curie-Weiss law in contrast to the properties of allowed transitions. The observed phenomena were accounted for as a consequence of the nature of f-f transitions allowance. In temperature dependences of the MOA of two transitions the singularities were revealed, which indicated to some local structural distortions in the corresponding excited states.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Sokolov, V. V.; Соколов, Валерий Владимирович; Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Gudim, I. A.; Гудим, Ирина Анатольевна
}
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18.

Transformation of 5I8→5F5 Ho absorption band in Ho0.75Nd0.25Fe3(BO3)4 crystal during spin-reorientation transition / A. V. Malakhovskii, A. L. Sukhachev, V. V. Sokolov [et al.] // Phys. B: Condens. Matter. - 2023. - Vol. 654. - Ст. 414706, DOI 10.1016/j.physb.2023.414706. - Cited References: 17 . - ISSN 0921-4526. - ISSN 1873-2135
Кл.слова (ненормированные):
Optical f-f transitions -- Magnetic reorientation transition -- Local properties in the optically excited states
Аннотация: Polarized absorption spectra of crystal Ho0.75Nd0.25Fe3(BO3)4 in the region of the 5I8→5F5 absorption band of Ho ions were investigated depending on temperature in the range of 5–20 K. Absorption spectra are decomposed into components of the Lorentz form. The spin-reorientation phase transition was detected at 6.9 K. The observed line position shifts during the reorientation transition were different for different lines, which indicated different local magnetic anisotropy of the Ho ion in its excited states. Significant changes in absorption line intensities as a function of temperature were observed during the reorientation transition and above. These were explained as a consequence of the change in even components of the local crystal field in excited states. These components mix the closely spaced 4f states. Distortion of local symmetry in the ground state was detected at one of the electron transitions.

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Держатели документа:
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Malakhovskii, A. V.; Малаховский, Александр Валентинович; Sukhachev, A. L.; Сухачев, Александр Леонидович; Sokolov, V. V.; Соколов, Валерий Владимирович; Gudim, I. A.; Гудим, Ирина Анатольевна; Kuchesheva-Titova, V. R.; Кучешева-Титова, Вероника Романовна
}
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19.

Малаховский, Александр Валентинович.
Естественный круговой дихроизм ʄ-ʄ переходов в кристалле ErAl3(BO3)4 / А. В. Малаховский, В. В. Соколов, И. А. Гудим // Физика диэлектриков (Диэлектрики-2017) : материалы XIV Междунар. конф. - СПб., 2017. - Т. 2. - С. 114-116

Материалы конференции
Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Соколов, Валерий Владимирович; Гудим, Ирина Анатольевна; Gudim, Irina A.; Malakhovskii, A. V.; "Физика диэлектриков", международная конференция(14 ; 2017 ; 29 мая-2 июня ; Санкт-Петербург); Физико-технический институт им. А.Ф. Иоффе РАН; Санкт-Петербургский политехнический университет им. Петра Великого; Российский государственный педагогический университет им. А. И. Герцена
}
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20.

Магнитные свойства твердых растворов CuMXCr1-XS2, M=V, Fe / Абрамова Г.М.Петраковский Г.А. [и др.] // XI Междисциплинарный международный симпозиум "Фазовые превращения в твердых растворах и сплавах". OMA-11 : сборник трудов : 10-15 сентября 2008, п. Лоо, Сочи. - Т. 1. - С. 10-14

Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Абрамова, Галина Михайловна; Abramova, G. M.; Петраковский, Герман Антонович; Petrakovskii, G. A.; Великанов, Дмитрий Анатольевич; Velikanov D. A.; Раш, Ю.; Келлер, Л.; Шимчак, Р.; Баюков, Олег Артемьевич; Bayukov, O. A.; Воротынов, Александр Михайлович; Vorotynov; Васильева, И. Г.; Мазалов, Л. Н.; Соколов, Валерий Владимирович; Sokolov V. V.; Васильев, В. В.; "Фазовые превращения в твердых растворах и сплавах", Международный междисциплинарный симпозиум(11 ; 2008 ; сент. ; Ростов на Дону, пос. Лоо)
}
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