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    Паршин, Александр Михайлович.
    Конфигурации директора в структурах нематика, адсорбированного на поверхности полимера / А. М. Паршин, В. Я. Зырянов, В. Ф. Шабанов // Жидк. кристаллы и их практич. использ. - 2015. - Т. 15, Вып. 1. - С. 56-65 ; Liquid Crystals and their Application. - Библиогр.: 20. - Работа выполнена частично при финансовой поддержке программ Президиума РАН и РФФИ (грант № 15-02-06924). . - ISSN 1991-3966
   Перевод заглавия: Director configurations in the structures of the nematic adsorbed on a polymer surface
Кл.слова (ненормированные):
нематический жидкий кристалл -- полимер -- адсорбция -- дисклинация -- конфигурация директора -- nematic liquid crystal -- polymer -- adsorption -- disclination -- director configuration
Аннотация: Исследованы ориентационные структуры нематических жидких кристаллов, возникающие на поверхности полимера в результате адсорбции, и их устойчивость относительно шлирен-текстуры. Изучены особенности точечных и линейных сингулярностей в исследуемых структурах. Рассмотрены конфигурации директора в слое нематика, определяемые комбинацией двух ориентирующих факторов: воздействием линейной дисклинации, фактора, стремящегося задать однородное планарное упорядочение, а также влиянием точечного дефекта, задающего радиальную структуру директора. С использованием расчетного метода проведен сравнительный анализ энергии упругих искажений поля директора для различных видов конфигураций: радиально-планарной, радиально-гомеотропной и радиально-радиальной в зависимости от толщины слоя нематика.
The orientational structures of nematic liquid crystals that form at the polymer surface due to adsorption and their stability with respect to the schlieren texture are investigated. Features of point and linear singularities in these structures are studied. The director configurations in nematic layer as a result of the combination of two aligning factors, which are the linear disclination that tends to impose uniform planar ordering and point defect that imparts the radial structure to the director are considered. The analysis of the elastic distortions energies of the director configurations for the radial-planar, radial-homeotropic and radial-radial structures, depending on the nematic layer thickness was performed using the calculation method.

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Держатели документа:
Институт физики им. Л.В. Киренского СО РАН

Доп.точки доступа:
Зырянов, Виктор Яковлевич; Zyryanov, V. Ya.; Шабанов, Василий Филиппович; Shabanov, V. F.; Parshin, A. M.

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    Влияние ионного сурфактанта на энергию сцепления жидкого кристалла с поверхностью, исследованное с использованием магнитных пороговых полей перехода Фредерикса / А. М. Паршин [и др.] // Жидк. кристаллы и их практич. использ. - 2018. - Т. 18, № 3. - С. 59-66 ; Liq. Cryst. Appl., DOI 10.18083/LCAppl.2018.3.59. - Библиогр.: 25. - В. С. Сутормин благодарен РФФИ за поддержку исследований по гранту № 16-32-60036 мол_а_дк. . - ISSN 1991-3966. - ISSN 2499-9644
   Перевод заглавия: Influence of ionic surfactant on the anchoring energy of liquid crystal with a surface investigated using magnetic threshold fields of Freedericksz transition

РУБ Crystallography
Рубрики:
WALL INTERFACE
   TEMPERATURE-DEPENDENCE
   NEMATIC DROPLETS
   ADSORPTION
Кл.слова (ненормированные):
нематический жидкий кристалл -- ионный сурфактант -- энергия сцепления -- магнитное поле -- переход Фредерикса -- nematic liquid crystal -- ionic surfactant -- anchoring energy -- magnetic field -- Freedericksz transition
Аннотация: Исследовано сцепление нематического жидкого кристалла 5ЦБ и 5ЦБ, допированного ионным сурфактантом ЦТАБ, в ячейках с плоскопараллельными ограничивающими поверхностями. Получены зависимости интенсивности проходящего лазерного излучения от величины магнитного поля для ячеек с различными толщинами слоя нематика при различных температурах. Из пороговых полей перехода Фредерикса определены значения полярной энергии сцепления жидкого кристалла с поверхностью. Изучено влияние ионного сурфактанта на энергию сцепления, установлено, что добавление в объем жидкого кристалла ионного сурфактанта ведет к ее ослаблению. Проведен анализ точности определения энергии сцепления на основе выражения, следующего из соотношения Рапини – Популара. Показано, что лучшее экспериментальное разрешение энергии сцепления достигается при использовании тонких слоев нематика, более сильных магнитных полей, а также слабого сцепления молекул жидкого кристалла с поверхностью.
The coupling of nematic liquid crystal 5CB and 5CB doped with ionic surfactant CTAB in the cells with plane parallel interfaces was studied. For the cells with the varied nematic layer thickness at different temperatures, the dependencies of the passed laser radiation intensity on the magnetic field were obtained. From the threshold fields of Freedericksz transition, the polar anchoring energy of the liquid crystal to the surface was determined. The effect of the ionic surfactant on the anchoring energy was studied and it was found that the addition of the ionic surfactant to liquid crystal weakens the anchoring energy. The analysis of the accuracy of the anchoring energy determination based on the expression following from the Rapini - Popular relation was carried out. It was shown that the best experimental resolution of the anchoring energy is achieved when the thin nematic layers, stronger magnetic fields and weak anchoring of the liquid crystal molecules with the surface are used.

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Держатели документа:
Институт физики им. Л. В. Киренского, Федеральный исследовательский центр «Красноярский научный центр Сибирского отделения Российской академии наук», Академгородок, 50, 660036 Красноярск, Россия
Сибирский Федеральный университет, пр. Свободный, 79, 660041 Красноярск, Россия

Доп.точки доступа:
Паршин, Александр Михайлович; Parshin, A. M.; Сутормин, Виталий Сергеевич; Sutormin, V. S.; Зырянов, Виктор Яковлевич; Zyryanov, V. Ya.; Шабанов, Василий Филиппович; Shabanov, V. F.

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Theoretical investigation of the adsorption and diffusion of hydrogen on the surface and in the bulk of the intermetallic compound Mg2Ni / A. A. Kuzubov [et al.] // Phys. Solid State. - 2014. - Vol. 56, Is. 10. - P. 2035-2042, DOI 10.1134/S1063783414100187. - Cited References: 30 . - ISSN 1063-7834. - ISSN 1090-6460

РУБ Physics, Condensed Matter
Рубрики:
STORAGE MATERIAL Mg2NiH4
   INITIO MOLECULAR-DYNAMICS
   AUGMENTED-WAVE METHOD
   MINIMUM ENERGY PATHS
   ELASTIC BAND METHOD
   TEMPERATURE STRUCTURE
   SADDLE-POINTS
   ALLOYS
   TRANSITION
   MAGNESIUM
Аннотация: The intermetallic compound Mg2Ni as a potential material for hydrogen storage has been investigated theoretically. The sorption and diffusion of a hydrogen atom in the bulk and on the surface of this material, as well as the step-by-step process of dissociative chemisorption of a H-2 molecule on the surface, have been considered. The dependence of the sorption energy of atomic hydrogen on the structural characteristics of the intermetallic compound Mg2Ni has been analyzed.

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Публикация на русском языке Теоретическое изучение сорбции и диффузии водорода на поверхности и в объеме интерметаллида Mg2Ni [Текст] / А. А. Кузубов [и др.] // Физ. тверд. тела. - 2014. - T. 56 Вып. 10. - С. 1970-1977

Держатели документа:
Siberian Fed Univ, Krasnoyarsk 660041, Russia
Russian Acad Sci, Siberian Branch, Kirensky Inst Phys, Krasnoyarsk 660036, Russia
Siberian State Technol Univ, Krasnoyarsk 660049, Russia

Доп.точки доступа:
Kuzubov, A. A.; Кузубов, Александр Александрович; Eliseeva, N. S.; Krasnov, P. O.; Краснов, Павел Олегович; Kuklin, A. V.; Куклин, Артем Валентинович; Kovaleva, E. A.; Kholtobina, A. S.
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The effect of copper and iron adsorption on the catalytic performance of alumina nanofiber / nanodiamond composite in sensing applications / N. O. Ronzhin, E. D. Posokhina, E. V. Mikhlina [et al.] // J. Phys. Chem. Solids. - 2022. - Vol. 167. - Ст. 110785, DOI 10.1016/j.jpcs.2022.110785. - Cited References: 68. - This work is supported by the Russian Foundation for Basic Research, Project 18–29–19078. The authors would like to express their special thanks to Krasnoyarsk Regional Center of Research Equipment of Federal Research Center «Krasnoyarsk Science Center SB RAS» for providing the equipment to ensure the accomplishment of this project . - ISSN 0022-3697
Кл.слова (ненормированные):
Nanodiamonds -- Alumina nanofibers -- Indicator system -- Copper ions -- Iron ions -- Phenol detection
Аннотация: Phenolic compounds are common environmental pollutants, which are used in many industries and contaminate water environment due to industrial wastewater discharge. Presently, there is an increasing demand for the development and improvement of inexpensive, easy-to-use analytical tools for in-situ detection of phenolic compounds. In this work, we investigate the effect of adsorption of Cu2+ and Fe2+ ions on the catalytic activity of a composite material based on alumina nanofibers (ANF) and detonation nanodiamonds (DND) in the co-oxidation of phenols with 4-aminoantipyrine in the presence of hydrogen peroxide. We have found more than two-fold increase of the catalytic activity for ANF + DND + Cu composite, while the activity of ANF + DND + Fe composite is found to decrease by several times in comparison with the original ANF + DND material. The results of FTIR analysis indicate that the adsorption of iron ions occurs with the formation of hydroxide surface groups and hydrogen bonds, which apparently block their catalytic activity in the Fenton redox cycle. The higher catalytic performance of AND + DND composite functionalized with copper ions makes it possible to detect two times lower concentrations of analytes (phenol and 4-chlorophenol) in comparison with the original composite. It is shown that the AND + DND + Cu composite provides a linear yield of the co-oxidation reaction product in a wide range of analyte concentrations (0.25–100 μM for phenol and 0.5–25 μM for 4-chlorophenol). Model experiments demonstrate the applicability of copper-functionalized composite as a reusable sensor for the determination of phenol in aqueous samples.

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Держатели документа:
Institute of Biophysics SB RAS, Akademgorodok 50/50, Krasnoyarsk, 660036, Russian Federation
Institute of Computational Modelling SB RAS, Akademgorodok 50/44, Krasnoyarsk, 660036, Russian Federation
Kirensky Institute of Physics SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Federal Research Center KSC SB RAS, Akademgorodok 50/38, Krasnoyarsk, 660036, Russian Federation
Siberian Federal University, Svobodny 79, Krasnoyarsk, 660041, Russian Federation

Доп.точки доступа:
Ronzhin, N. O.; Posokhina, E. D.; Mikhlina, E. V.; Shestakov, N. P.; Шестаков, Николай Петрович; Nemtsev, I. V.; Немцев, Иван Васильевич; Bondar, V. S.; Ryzhkov, I. I.
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    Parshin, A. M.
    The director field distribution with the strongly pinned alignment in nematic structures at the polymer surface / A. M. Parshin, V. Y. Zyryanov, V. F. Shabanov // Liq. Cryst. - 2015. - Vol. 42, Is. 1. - P. 57-64, DOI 10.1080/02678292.2014.960904. - Cited References:18. - This work was partially supported by the Russian Foundation for BasicResearch [project No. 12-03-00816] and by the Siberian Branch of theRussian Academy of Sciences (SB RAS) [grants nos. 30, 24.29, 24.32] andby SB RAS through a Taiwan-SB RAS joint project. . - ISSN 0267. - ISSN 1366-5855
   Перевод заглавия: Распределение поля директора с сильно фиксированным упорядочением в нематических структурах на поверхности полимера

РУБ Chemistry, Multidisciplinary + Crystallography + Materials Science,
Рубрики:
LIQUID-CRYSTALS
DISCLINATION LINES
DEFECTS
Кл.слова (ненормированные):
orientational order -- disclination -- adsorption -- nematic -- polymer surface -- director configuration
Аннотация: We investigate orientational nematic liquid crystal structures that form at the polymer surface due to adsorption, their stability against the schlieren texture and features of point and linear singularities in them. We demonstrate that surface disclination lines, which also occur due to molecular adsorption, can lead to azimuthal anchoring of a bulk layer and make the singularities with the charge m=+/- 1 stable. We consider the director field distribution in a nematic layer as a result of the combination of two aligning factors, which are the linear disclination that tend to impose uniform planar ordering and point defects that impart the radial configuration to the director. With the use of the calculation, we analyse the energies of elastic distortions of the director field for the radial-planar, radial-homeotropic and radial-radial configurations, depending on the nematic layer thickness.

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Держатели документа:
Russian Acad Sci, LV Kirensky Phys Inst, Krasnoyarsk Sci Ctr, Siberian Branch, Krasnoyarsk, Russia.
Siberian Fed Univ, Dept Energy, Krasnoyarsk, Russia.

Доп.точки доступа:
Zyryanov, V. Ya.; Зырянов, Виктор Яковлевич; Shabanov, V. F.; Шабанов, Василий Филиппович; Паршин, Александр Михайлович; Russian Foundation for Basic Research [12-03-00816]; Siberian Branch ofthe Russian Academy of Sciences (SB RAS) [30, 24.29, 24.32]; SB RASthrough a Taiwan-SB RAS joint project
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Template synthesis of CMK-3 nanostructured carbon material and study of its properties / I. V. Ponomarenko [et al.] // Glass Phys. Chem. - 2014. - Vol. 40, Is. 1. - P. 79-87, DOI 10.1134/S1087659614010180 . - ISSN 1087-6596
Кл.слова (ненормированные):
adsorption of N2 -- CMK-3 mesostructured carbon -- mesoporous mesostructured silicates -- SBA-15 -- template synthesis -- transmission electron microscopy -- X-ray diffraction
Аннотация: Mesostructured carbon has been obtained by template synthesis. SBA-15 mesostructured silicate has been used as a template. The effect of the properties of a template on the ordering of a replica has been studied. It has been shown with the use of X-ray diffraction, gas adsorption, and electron microscopy that there are evident correlations of the conditions of synthesis of a template with the ordering of a carbon replica, which can be guided by the synthesis of materials. The ordering of a replica significantly depends on the mesopore volume of the initial template and thickness of the pore wall. One should use templates with the highest possible mesopore volume and minimal wall thickness to obtain highly ordered replicas. These templates can be prepared during the treatment of synthesized materials at temperatures close to 100 C. It has been determined that, when there is SBA-15, the presence of micropores is a necessary condition for the preparation of carbon replicas that retain the structure of the template. © 2014 Pleiades Publishing, Ltd.

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Держатели документа:
Institute of Chemistry and Chemical Engineering, Russian Academy of Sciences, Siberian Branch, Akademgorodok 50/24, Krasnoyarsk 660036, Russian Federation
Siberian Federal University, pr. Svobodnyi 79, Krasnoyarsk 660049, Russian Federation

Доп.точки доступа:
Ponomarenko, I. V.; Parfenov, V. A.; Zaitseva, Y. N.; Zharkov, S. M.; Жарков, Сергей Михайлович; Kirik, S. D.
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Temperature dependent elastic repulsion of colloidal nanoparticles with a polymer adsorption layer / A. P. Gavrilyuk [et al.] // Colloid Polym. Sci. - 2018. - Vol. 296, Is. 10. - P. 1689-1697, DOI 10.1007/s00396-018-4383-y. - Cited References: 49. - The reported research was funded by the Russian Foundation for Basic Research, the government of the Krasnoyarsk territory and Krasnoyarsk Regional Fund of Science, grant 18-42-243023, the RF Ministry of Science and Education, the State contract with Siberian Federal University for scientific research in 2017-2019, and SB RAS Program No II.2P (0358-2015-0010). . - ISSN 0303-402X. - ISSN 1435-1536

РУБ Chemistry, Physical + Polymer Science
Рубрики:
STERICALLY-STABILIZED PARTICLES
DEPLETION FLOCCULATION
AGGREGATION
Кл.слова (ненормированные):
Nanoparticle -- Adsorption layer -- Elastic deformation -- Coagulation -- kinetics -- Elasticity modulus
Аннотация: The model of pairwise elastic repulsion of contacting colloidal nanoparticles with a rigid core and deformable shell is discussed. A simple analytical equation is applied for the energy of elastic repulsion of nanoparticles with arbitrary sizes and the elasticity moduli of self-healing polymer adsorption layers. The model is based on the representation of the absorption layer as a continuous medium that is elastically deformed upon the contact of nanoparticles. The major characteristic of this medium is the elasticity modulus. The magnitude of the elasticity modulus is determined from the condition of balance of the van der Waals attractive forces of nanoparticles and the elastic repulsion of their adsorption layers in the contact area, taking into account the temperature variations. We employed the kinetic approach to describe the dependence of the elasticity modulus on both the temperature and the rate of its change.

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Держатели документа:
RAS, SB, Inst Computat Modeling, Krasnoyarsk 660036, Russia.
Siberian Fed Univ, Inst Math & Comp Sci, Krasnoyarsk 660041, Russia.
Siberian Fed Univ, Lab Nanotechnol Spect & Quantum Chem, Krasnoyarsk 660041, Russia.
RAS, SB, Fed Res Ctr KSC, Kirensky Inst Phys, Krasnoyarsk 660036, Russia.
Siberian State Univ Sci & Technol, Krasnoyarsk 660014, Russia.

Доп.точки доступа:
Gavrilyuk, A. P.; Gerasimov, V. S.; Герасимов, Валерий Сергеевич; Ershov, A. E.; Ершов, Александр Евгеньевич; Karpov, S. V.; Карпов, Сергей Васильевич; Russian Foundation for Basic Research; government of the Krasnoyarsk territory and Krasnoyarsk Regional Fund of Science [18-42-243023]; RF Ministry of Science and Education,; State contract with Siberian Federal University for scientific research in 2017-2019; SB RAS Program [II.2P (0358-2015-0010)]
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Tailoring adsorption induced switchability of a pillared layer MOF by crystal size engineering / L. Abylgazina, I. Senkovska, S. Ehrling [et al.] // CrystEngComm. - 2021. - Vol. 23, Is. 3. - P. 538-549, DOI 10.1039/d0ce01497d. - Cited References: 71. - The authors thank the DFG (FOR 2433 MOF Switches, Project No. 279409724) for financial support. P.P. and J. D. E. thank Center for Information Services and High Performance Computing (ZIH) at TU Dresden for providing high-performance computing facilities. Authors acknowledge Helmholtz-Zentrum Berlin für Materialien und Energie for allocated beamtime at KMC-2 and MX14.2 beamlines. J. D. E. acknowledges the support of the Alexander von Humboldt foundation and HPC platforms provided by a GENCI grant (A0070807069) . - ISSN 1466-8033
Кл.слова (ненормированные):
Adsorption -- Crystals -- Dichloromethane -- Hinges -- Nickel metallography -- Particle size -- Zinc metallography
Аннотация: The pillared layer framework DUT-8(Zn) (Zn2(2,6-ndc)2(dabco), 2,6-ndc = 2,6-naphthalenedicarboxylate, dabco = 1,4-diazabicyclo-[2.2.2]-octane, DUT = Dresden University of Technology) is a prototypical switchable MOF, showing characteristic adsorption and desorption induced open phase (op) to closed phase (cp) transformation associated with huge changes in cell volume. We demonstrate switchability strongly depends on a framework-specific critical particle size (dcrit). Superposed, the solvent removal process (pore desolvation stress contracting the framework) significantly controls the cp/op ratio after desolvation and, subsequently, the adsorption induced switchability characteristics of the system. After desolvation, the dense cp phase of DUT-8(Zn) shows no adsorption-induced reopening and therefore is non-porous for N2 at 77 K and CO2 at 195 K. However, polar molecules with a higher adsorption enthalpy, such as chloromethane at 249 K and dichloromethane (DCM) at 298 K can reopen the macro-sized crystals upon adsorption. For macro-sized particles, the outer surface energy is negligible and only the type of metal (Zn, Co, Ni) controls the DCM-induced gate opening pressure. The node hinge stiffness increases from Zn to Ni as confirmed by DFT calculations, X-ray crystal structural analysis, and low frequency Raman spectroscopy. This softer Zn-based node hinges and overall increased stabilization of cp vs. op phase shift the critical particle size at which switchability starts to become suppressed to even lower values (dcrit ‹ 200 nm) as compared to the Ni-based system (dcrit ≈ 500 nm). Hence, the three factors affecting switchability (energetics of the empty host, (Eop–Ecp) (I), particle size (II), and desolvation stress (III)) appear to be of the same order of magnitude and should be considered collectively, not individually.

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Department of Inorganic Chemistry i, Technische Universitat Dresden, Bergstrasse 66, Dresden, 01069, Germany
Faculty of Chemistry and Pharmacy, University of Sofia, Sofia, 1126, Bulgaria
Kirensky Institute of Physics, Federal Research Center KSC SB RAS, Krasnoyarsk, 660036, Russian Federation

Доп.точки доступа:
Abylgazina, L.; Senkovska, I.; Ehrling, S.; Bon, V.; St. Petkov, P.; Evans, J. D.; Krylova, S. N.; Крылова, Светлана Николаевна; Krylov, A. S.; Крылов, Александр Сергеевич; Kaskel, S.
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Study of interaction between transition metal atoms and bigraphene monovacancy by means of quantum chemistry / A. A. Kuzubov [et al.] // Comput. Mater. Sci. - 2016. - Vol. 112, Part A. - P. 269-275, DOI 10.1016/j.commatsci.2015.11.002. - Cited References: 39. - The authors would like to thank Siberian Supercomputer Center (SSCC) of SB RAS, Novosibirsk; and L.V. Kirensky Institute of Physics of SB RAS, Krasnoyarsk, for providing the access to their supercomputers. This work was supported by the government contract of the Ministry of Education and Science of the Russian Federation to Siberian Federal University (Grant No. 16.1500.2014/K). . - ISSN 0927-0256

РУБ Materials Science, Multidisciplinary
Рубрики:
INITIO MOLECULAR-DYNAMICS
   MASSLESS DIRAC FERMIONS
   GRAPHENE
   VACANCIES
   POINTS
   GAS
Кл.слова (ненормированные):
Bigraphene -- Spintronics -- Transition metal -- Adsorption -- Migration
Аннотация: First-row transition metal atoms adsorption on bigraphene monovacancy was studied within the framework of DFT in periodic boundary conditions. Electronic and magnetic properties of composites were analyzed and their potential utilization in spintronics was discussed. Barriers of metal atoms migration from bigraphene surface to the interlayer space through the vacancy were estimated in order to consider both thermodynamic and kinetic aspects of composites experimental preparation. Formation of metal atoms inner-sorbed on bigraphene was found to demand harsh synthesis conditions; whereas outer-sorbed composites demonstrate significantly higher degree of spin polarization which makes them perspective for usage in spintronic devices. © 2015 Elsevier B.V.

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Держатели документа:
Siberian Federal University, 79 Svobodny pr., Krasnoyarsk, Russian Federation
L.V. Kirensky Institute of Physics, 50 Akademgorodok, Krasnoyarsk, Russian Federation
Kyungpook National University, 80 Daehakro, Bukgu, Daegu, South Korea

Доп.точки доступа:
Kuzubov, A. A.; Кузубов, Александр Александрович; Avramov, P. V.; Аврамов, Павел Вениаминович; Nikolaeva, K. M.; Mikhaleva, N. S.; Kovaleva, E. A.; Kuklin, A. V.; Куклин, Артем Валентинович; Fedorov, A. S.; Федоров, Александр Семенович
}
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10.

    Simultaneous ion exchange recovery of platinum and rhodium from chloride solutions / O. N. Kononova [et al.] // Hydrometallurgy. - 2011. - Vol. 105, Is. 3-4. - P. 341-349, DOI 10.1016/j.hydromet.2010.11.009. - Cited Reference Count: 46 . - JAN. - ISSN 0304-386X
Рубрики:
GROUP-METALS PGM
   SEPARATION
   CATALYST
   ANION
   ADSORPTION
   EXTRACTION
   CHEMISTRY
   RESIN
Кл.слова (ненормированные):
platinum -- rhodium -- sorption -- anion exchangers -- chloride solutions -- anion exchangers -- chloride solutions -- platinum -- rhodium -- sorption -- ammonium thiocyanate -- anion exchangers -- basic parameters -- chemical structure -- chloride solutions -- diffusion coefficients -- distribution coefficient -- exchange capacities -- kinetic properties -- noble metals -- purolite -- rhodium chloride -- separation factors -- sorption ability -- work focus -- ammonium compounds -- chlorine compounds -- desorption -- hydrochloric acid -- ion exchange -- ion exchange resins -- ions -- platinum -- platinum compounds -- potassium hydroxide -- precious metals -- recovery -- rhodium -- sulfuric acid -- thioureas -- urea -- rhodium compounds
Аннотация: This work focuses on the sorption recovery of platinum (II, IV) and rhodium (III) simultaneously present in chloride solutions, freshly prepared and stored over 3 months, on commercial anion exchangers with different physical and chemical structure. The sorption was carried out from solutions with 0.001-4.0 mol/L HCl. The initial platinum and rhodium concentrations in contacting solutions were 0.25-2.5 mmol/L Sorption and kinetic properties of the chosen anion exchangers were investigated and the basic parameters of exchange capacity, recovery, distribution coefficients, separation factors, process rate, diffusion coefficients and half-exchange times were calculated. It is shown that anion exchangers investigated possess high sorption ability to platinum and rhodium chloride complexes, which does not deteriorate in case of stored solutions. Desorption of platinum and rhodium from the resins investigated was carried out with hydrochloric acid (2 mol/L), thiourea (1 mol/L) in sulfuric acid (2 mol/L) or in potassium hydroxide (2 mol/L) as well as by ammonium thiocyanate (2 mol/L). It was shown that complete separation of platinum and rhodium can be carried out with 2 mol/L HCl on anion exchanger Purolite S 985, whereas 2 mol/L NH(4)SCN as an elution agent leads to complete separation of noble metals on anion exchangers Purolite S 985, Purolite A 500 and AM-2B. (C) 2010 Elsevier B.V. All rights reserved.

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Держатели документа:
Siberian Fed Univ, Dept Chem, Krasnoyarsk 660041, Russia
Russian Acad Sci, LV Kirensky Phys Inst, Siberian Dept, Krasnoyarsk 660036, Russia

Доп.точки доступа:
Kononova, O.N.; Melnikov, A.M.; Borisova, T.V.; Krylov, A. S.; Крылов, Александр Сергеевич
}
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