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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Krylov A. S., Potseluyko A. M., Seredkin V. A., Zaitsev A. I., Zamkov A. V.
Заглавие : Pulsed laser deposition of europium borate glass films and their optical and magneto-optical properties
Коллективы : International Conference on Lasers, Applications, and Technologies
Место публикации : Laser-Assisted Micro- and Nanotechnologies. Proceedings of SPIE: [11-15 May 2005]/ ed. V. I. Konov [et al.]: SPIE-Int. Soc. Optical Engineering, 2006. - P.61610A
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Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Zhiguo, Xia, Molokeev M. S., Atuchin V. V.
Заглавие : Crystal structure and photoluminescence properties of europium doped Ca7La3(PO4)3(SiO4)3F2
Коллективы : Институт нанотехнологий микроэлектроники РАН, Ульяновский государственный университет, Российский фонд фундаментальных исследований, Академия наук Татарстана, "Opto-, nanoelectronics, nanotechnology, and microsystems", International Conference (2013 ; Jul. ; 26-30; Ulyanovsk, Russia), "Опто-, наноэлектроника, нанотехнологии и микросистемы", международная конференция (2013 ; июль.; 26-30; Ульяновск)
Место публикации : XVI Международная конференция "Опто-, наноэлектроника, нанотехнологии и микросистемы": Труды. - Ульяновск, 2013. - P.156
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Boldyrev K. N., Stanislavchuk T. N., Klimin S. A., Popova M. N., Bezmaternykh L. N.
Заглавие : Terahertz spectroscopy of multiferroic EuFe3(BO3)4
Место публикации : Phys. Lett. A: Elsevier Science BV, 2012. - Vol. 376, Is. 37. - P.2562-2564. - ISSN 0375-9601, DOI 10.1016/j.physleta.2012.06.028
Примечания : Cited References: 19. - This work was partially supported by the Russian Foundation for Basic Research under Grants No. 10-02-01071-a and No. 09-02-00171-a, by the Ministry of Education and Science under Grant HIII-4828.2012.2, and by the Russian Academy of Sciences under the programs for basic research.
Предметные рубрики: SINGLE-CRYSTAL
GDFE3(BO3)4
Ключевые слова (''Своб.индексиров.''): terahertz spectroscopy--multiferroics--europium iron borate
Аннотация: The terahertz spectra of a rare-earth iron borate with the huntite structure are obtained for the first time. We study the low-temperature (4.0–90 K) α-polarized transmittance spectra of the EuFe3(BO3)4 single crystal in the region 0.9–6.0 THz. Pronounced shifts of phonon frequencies and appearance of new phonon modes at the temperature T S = 58 K of the R 32 → P 3 1 21 structural phase transition are observed. Additional shifts of phonon frequencies occur at the temperature T N = 34 K of the magnetic ordering of the Fe subsystem, thus evidencing the spin–phonon coupling in this multiferroic material.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ruseikina A. V., Solovyov L. A., Molokeev M. S., Andreev O. V.
Заглавие : Crystal structures of EuLnCuS3 (Ln = Nd and Sm)
Место публикации : Russ. J. Inorg. Chem.: MAIK Nauka-Interperiodica / Springer, 2012. - Vol. 57, Is. 1. - P.79-83. - ISSN 0036-0236, DOI 10.1134/S0036023612010172
Примечания : This work was supported by the Federal Target Program "Scientific and Pedagogical Personnel of Innovative Russia" for 2009-2013 (grant nos. 6K/143-09 (P 646) and NK-409/5 (P2263)) and the President of the Russian Federation (Support Program for Leading Scientific Schools of the Russian Federation, grant NSh-4645.2010.2).The results of this study have been presented at the X International Scientific Conference “Solid-State Chemistry: Nanomaterials, Nanotechnologies” (Stavropol, October 17–22, 2010) and the All-Russia Scientific Conference “Challenges of Modern Chemistry. Theory and Practice” (Ufa, October 21–23, 2010).
Предметные рубрики: RARE-EARTH
MAGNETIC-PROPERTIES
COPPER SULFIDE
CHALCOGENIDES
EUROPIUM
EU2CUS3
Аннотация: The compound sulfides EuLnCuS3 (Ln = Nd and Sm) were obtained for the first time. Their crystal structures were determined from X-ray powder diffraction data. The crystals of both compounds are orthorhombic (space group Pnma). The compound EuNdCuS3 is isostructural with BaLaCuS3; the unit cell parameters are a = 11.0438(2) Å, b = 4.0660(1) Å, c = 11.4149(4) Å. The compound EuSmCuS3 is isostructural with Eu2CuS3; the unit cell parameters are a = 10.4202(2) Å, b = 3.9701(1) Å, c = 12.8022(2) Å.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Aleksandrovsky A. S., Chimitova O. D., Gavrilova T. A., Krylov A. S., Molokeev M. S., Oreshonkov A. S., Bazarov B. G., Bazarova J. G.
Заглавие : Synthesis and spectroscopic properties of monoclinic α-Eu2(MoO4)3
Коллективы : Ministry of Education and Science of the Russian Federation
Место публикации : J. Phys. Chem. C: American Chemical Society, 2014. - Vol. 118, Is. 28. - P.15404-15411. - ISSN 1932-7447, DOI 10.1021/jp5040739
Примечания : Cited References: 63. - This study is partly supported by the Ministry of Education and Science of the Russian Federation.
Предметные рубрики: RARE-EARTH MOLYBDATES
VIBRATIONAL PROPERTIES
LUMINESCENCE PROPERTIES
CRYSTAL-STRUCTURE
PHASE-TRANSITIONS
TRIPLE MOLYBDATE
SINGLE-CRYSTAL
X-RAY
PHOSPHORS
EUROPIUM
Аннотация: The microcrystals of monoclinic europium molybdate, alpha-Eu-2(MoO4)(3), have been fabricated by solid-state synthesis at T = 753-1273 K for 300 h. The crystal structure of alpha-Eu-2(MoO4)(3) has been refined by the Rietveld method and was found to belong to the space group C2/c with unit cell parameters a = 7.5576(1), b = 11.4709(2), c = 11.5158(2) angstrom, and beta = 109.278(1)degrees (R-B = 3.39%). About 40 narrow Raman lines have been observed in the Raman spectrum of the alpha-Eu-2(MoO4)(3) powder sample. The luminescence spectra of alpha-Eu-2(MoO4)(3) under excitation at 355 and 457.9 nm reveal domination of induced electric dipole transition D-5(0) - F-7(2) and the presence of ultranarrow lines at D-5(0) - F-7(0) and D-5(1) - F-7(0) transitions.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ji H. P., Huang Z. H., Xia Z. G., Molokeev M. S., Atuchin V. V., Fang M. H., Huang S. F.
Заглавие : New yellow-emitting whitlockite-type structure Sr1.75Ca 1.25(PO4)2:Eu2+ phosphor for near-UV pumped white light-emitting devices
Место публикации : Inorg. Chem.: American Chemical Society, 2014. - Vol. 53, Is. 10. - P.5129-5135. - ISSN 0020-1669, DOI 10.1021/ic500230v. - ISSN 1520-510X
Примечания : Cited References: 31. - This work was supported by the National Natural Science Foundations of China (Grant Nos. 51032007, 51002146, 51272242), the Research Fund for the Doctoral Program of Higher Education of China (Grant No. 20130022110006), and the Program for New Century Excellent Talents in University of Ministry of Education of China (NCET-12-0950). V.V.A. gratefully acknowledges the Ministry of Education and Science of the Russian Federation for the financial support. S.H. would like to acknowledge the China Scholarship Council (CSC) for providing a doctoral scholarship for his Ph.D. study at the University of Auckland.
Предметные рубрики: LUMINESCENCE PROPERTIES
CRYSTAL-STRUCTURE
RED PHOSPHOR
DIODES
LEDS
SR
CA
ORTHOPHOSPHATE
CA-3(PO4)2
EUROPIUM
Аннотация: New compound discovery is of interest in the field of inorganic solid-state chemistry. In this work, a whitlockite-type structure Sr1.75Ca1.25(PO4)2 newly found by composition design in the Sr3(PO4)2–Ca3(PO4)2 join was reported. Crystal structure and luminescence properties of Sr1.75Ca1.25(PO4)2:Eu2+ were investigated, and the yellow-emitting phosphor was further employed in fabricating near-ultraviolet-pumped white light-emitting diodes (w-LEDs). The structure and crystallographic site occupancy of Eu2+ in the host were identified via X-ray powder diffraction refinement using Rietveld method. The Sr1.75Ca1.25(PO4)2:Eu2+ phosphors absorb in the UV–vis spectral region of 250–430 nm and exhibit an intense asymmetric broadband emission peaking at 518 nm under λex = 365 nm which is ascribed to the 5d–4f allowed transition of Eu2+. The luminescence properties and mechanism are also investigated as a function of Eu2+ concentration. A white LED device which is obtained by combining a 370 nm UV chip with commercial blue phosphor and the present yellow phosphor has been fabricated and exhibit good application properties.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Golovnev N. N., Molokeev M. S., Vereshchagin S. N.
Заглавие : Crystal structure and some properties of europium(III) Catena-{tris(1,3-diethyl-2-thiobarbiturate)}
Место публикации : J. Struct. Chem.: MAIK Nauka-Interperiodica / Springer, 2016. - Vol. 57, Is. 1. - P.167-174. - ISSN 00224766 (ISSN), DOI 10.1134/S0022476616010200
Примечания : Cited References: 25. - The work was supported within the State Contract of the Ministry of Education and Science of the Russian Federation for research in the Siberian Federal University in 2015.
Предметные рубрики: 1,3-diethyl-2-thiobarbituric acid
Hydrogen-bond
Diffraction
Series
Ключевые слова (''Своб.индексиров.''): crystal structure--complex--europium(iii)--1,3-diethyl-2-thiobarbituric acid--thermal analysis--ir spectroscopy--photoluminescence
Аннотация: The [Eu(HDTBA)3] n complex (I), HDTBA is 1,3-diethyl-2-thiobarbituric acid (C8H12N2O2S) is synthesized and its structure is determined by X-ray crystallography. The crystals of I are triclinic: a = 11.0205(2) Å, b = 11.8811(3) Å, c = 12.7312(2) Å, α = 100.933(1)°, β = 109.704(1)°, γ = 101.161(1)°, V = 1479.88(5) Å3, space group P-1, Z = 2. Each of three independent DETBA- ions is a bridging μ2-O,O′-coordinated ligand. The coordination polyhedron of Eu(III) is a distorted octahedron. Bridging DETBA- organize the octahedra into an infinite two-dimensional layer. The structure contains intramolecular hydrogen bonds but intermolecular hydrogen bonds and the π-π interaction are absent. The results of IR spectroscopy and photoluminescence agree with the single crystal X-ray diffraction data. The main product of the thermal decomposition of I at 900°C is oxysulfate Eu2O2SO4. © 2016 Pleiades Publishing, Ltd.
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Kuz'menko A. M., Mukhin A. A., Ivanov V. Y., Kadomtseva A. M., Lebedev S. P., Bezmaternykh L. N.
Заглавие : Antiferromagnetic Resonance and Dielectric Properties of Rare-earth Ferroborates in the Submillimeter Frequency Range
Место публикации : J. Exp. Theor. Phys.: MAIK NAUKA/INTERPERIODICA/SPRINGER, 2011. - Vol. 113, Is. 1. - P113-120. - ISSN 1063-7761, DOI 10.1134/S106377611105013X
Примечания : Cited References: 27. - This work was supported by the Russian Foundation for Basic Research, project no. 10-02-00846.
Предметные рубрики: GDFE3(BO3)(4)
SPECTROSCOPY
CRYSTAL
Ключевые слова (''Своб.индексиров.''): antiferromagnetic resonance--basic parameters--effective anisotropy constant--ferroborates--ferroics--ferromagnetic orderings--frequency ranges--magnetic interactions--magnetoresonance--millimeter frequency range--rare earth ions--submillimeters--antiferromagnetic materials--crystallography--erbium--europium--ferromagnetic resonance--ion exchange--magnetic anisotropy--magnetic devices--magnetic structure--permittivity--resonance--antiferromagnetism
Аннотация: The magnetoresonance and dielectric properties of a number of crystals of a new family of multiferroics, namely, rare-earth ferroborates RFe(3)(BO(3))(4) (R = Y, Eu, Pr, Tb, Tb(0.25)Er(0.75)), are studied in the submillimeter frequency range (nu = 3-20 cm(-1)). Ferroborates with R = Y, Tb, and Eu exhibit permittivity jumps at temperatures of 375, 198, and 58 K, respectively, which are caused by the R32 - P3(1)2(1) phase transition. Antiferromagnetic resonance (AFMR) modes in the subsystem of Fe(3+) ions are detected in the range of antiferromagnetic ordering (T T(N)
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Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shaykhutdinov K. A., Balaev D. A., Semenov S. V., Popkov S. I., Dubrovskiy A. A., Sapronova N. V., Volkov N. V.
Заглавие : Relaxation of low-temperature magnetoresistance and magnetization of polycrystalline (La0.5Eu0.5)(0.7)Pb0.3MnO3
Разночтения заглавия :авие SCOPUS: Relaxation of low-temperature magnetoresistance and magnetization of polycrystalline (La 0.5Eu 0.5) 0.7Pb 0.3MnO 3
Место публикации : J. Phys. D. - 2011. - Vol. 44, Is. 25. - Ст.255001. - ISSN 0022-3727, DOI 10.1088/0022-3727/44/25/255001
Примечания : Cited References: 34. - This work was partially supported by the Lavrentyev Competition of the Young Scientist's Projects of the Siberian Branch of the Russian Academy of Sciences, Project No 12. The authors are grateful to A D Balaev and V M Sosnin for useful discussions on the results.
Предметные рубрики: INSULATOR-METAL TRANSITION
GRANULAR FILMS
NANOPARTICLES
PR0.7CA0.3MNO3
PERCOLATION
MANGANITES
Ключевые слова (''Своб.индексиров.''): antiferromagnetic boundaries--characteristic value--ferromagnetic domains--ferromagnetic metal--lanthanum manganites--logarithmic law--low temperatures--magneto-resistive effect--polycrystalline--relative orientation--relaxation of magnetization--temperature fluctuation--time evolutions--time interval--tunnel magnetoresistance--antiferromagnetism--electric resistance--europium--ferromagnetic materials--ferromagnetism--grain boundaries--grain size and shape--lanthanum compounds--lead--magnetic domains--magnetic moments--magnetoelectronics--magnetoresistance--manganese oxide--magnetization
Аннотация: Hysteresis and relaxation of magnetoresistance and magnetization of substituted (La0.5Eu0.5)(0.7)Pb0.3MnO3 lanthanum manganite in a low-temperature region ( 40 K) are investigated. It is shown that at these temperature features of the magnetoresistive effect are determined mainly by spin-dependent tunnelling of carriers via insulating grain boundaries. As was demonstrated previously, the grain boundaries may be antiferromagnetically ordered. Therefore, relaxation of magnetization and resistance is determined by the processes of relative orientation of the magnetic moments of ferromagnetic domains neighbouring the antiferromagnetic boundary of ferromagnetic domains under the action of temperature fluctuations. It is shown that relaxation follows the logarithmic law within the time interval t similar to 10(2)-3x10(3) s. A comparison between time evolutions of the magnetic moment and resistance shows that magnetoresistance and magnetization are related as delta R
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10.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shaykhutdinov K. A., Popkov S. I., Semenov S. V., Balaev D. A., Dubrovskiy A. A., Sablina K. A., Sapronova N. V., Volkov N. V.
Заглавие : Low-temperature resistance and magnetoresistance hysteresis in polycrystalline (La0.5Eu0.5)(0.7)Pb0.3MnO3
Разночтения заглавия :авие SCOPUS: Low-temperature resistance and magnetoresistance hysteresis in polycrystalline (La0.5Eu0.5)0.7Pb 0.3MnO3
Место публикации : J. Appl. Phys.: AMER INST PHYSICS, 2011. - Vol. 109, Is. 5. - Ст.53711. - ISSN 0021-8979, DOI 10.1063/1.3559303
Примечания : Cited References: 20. - This study was partially supported by the Russian Foundation for Basic Research, Project No. 08-02-00259a and the Lavrentyev Competition of the Young Scientists' Projects of the Siberian Branch of the Russian Academy of Sciences, Project No. 12.
Предметные рубрики: RESISTIVITY MINIMUM
MANGANITES
FILMS
Ключевые слова (''Своб.индексиров.''): antiferromagnets--electrical resistances--ferromagnets--field dependence--inter-grain--lanthanum manganites--low temperatures--low-temperature resistance--polycrystalline--temperature dependence--tunnel contacts--antiferromagnetic materials--europium--ferromagnetic materials--ferromagnetism--hysteresis--lead--magnetic field effects--magnetoelectronics--magnetoresistance--magnets--manganese oxide--paramagnetism--superconducting materials--electric resistance
Аннотация: The behavior of temperature dependences of electrical resistance and magnetoresistance of polycrystalline substituted lanthanum manganite (La0.5Eu0.5)(0.7)Pb0.3MnO3 at low temperatures was thoroughly studied. A broad hysteresis was found in the field dependences of electrical resistance in the low-temperature region. Above 40 K, no hysteresis feature was observed. The temperature T = 40 K corresponds to the temperature of minimum electrical resistance and the temperature T-N to the antiferromagnet-paramagnet phase transition of the material of the intergrain boundaries. In this work we propose a model which explains the observed features of the rho(T) and rho(H) curves at temperatures below T-N by the formation of a network of ferromagnet-antiferromagnet-ferromagnet tunnel contacts. (C) 2011 American Institute of Physics. [doi:10.1063/1.3559303]
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shaykhutdinov K. A., Popkov S. I., Balaev D. A., Semenov S. V., Bykov A. A., Dubrovskiy A. A., Sapronova N. V., Volkov N. V.
Заглавие : Non-linear current-voltage characteristics of (La0.5Eu0.5)(0.7)Pb0.3MnO3 single crystals: Possible manifestation of the internal heating of charge carriers
Коллективы :
Разночтения заглавия :авие SCOPUS: Non-linear currentvoltage characteristics of (La0.5Eu 0.5)0.7Pb0.3MnO3 single crystals: Possible manifestation of the internal heating of chargecarriers
Место публикации : Physica B: ELSEVIER SCIENCE BV, 2010. - Vol. 405, Is. 24. - P4961-4965. - ISSN 0921-4526, DOI 10.1016/j.physb.2010.09.043
Примечания : Cited References: 19. - The authors are grateful to A.N. Lavrov for useful discussions on the results. This study was partially supported by the Russian Foundation for Basic Research, Project no. 08-02-00259a and the Lavrent'ev Young Scientists' Competition of the Siberian Branch of the Russian Academy of Sciences. Project no. 12.
Предметные рубрики: INSULATOR-METAL TRANSITION
PR0.7CA0.3MNO3
MANGANITES
Ключевые слова (''Своб.индексиров.''): manganites--negative differential resistance--cvc--cvc--manganites--negative differential resistance--applied electric field--charge ordering--current switching--cvc--dielectric regions--experimental data--internal heating--lanthanum manganites--metal-dielectric transition--negative differential resistances--non equilibrium--non-linear--sample heating--temperature evolution--transport currents--electric fields--electron gas--europium--heating--lanthanum--lead--manganites--negative resistance--phase separation--single crystals--thermal conductivity--manganese oxide
Аннотация: Temperature evolution of the current-voltage characteristics (CVCs) of a single-crystal lanthanum manganite (La0.5Eu0.5)(0.7)Pb0.3MnO3 is investigated in a wide (up to 1 A) range of instrumental currents. Effects of a transport current and an applied electric field on the resistance of the material are studied in view of possible implementation of the charge ordering break in dielectric regions occurring due to phase separation in manganites. A negative differential resistance portion observed in the CVCs suggests the presence of a current switching effect. Below the temperature of the metal-dielectric transition in (La0.5Eu0.5)(0.7)Pb0.3MnO3, the hysteresis is observed in the CVC. The detailed analysis of the internal sample heating on the basis of experimental data on thermal conductivity showed, however, that these CVC features can be explained within the concept of non-equilibrium heating of electron gas. (C) 2010 Elsevier B.V. All rights reserved.
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12.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Dyakonov V. P., Szymczak R., Prokhorov A. D., Zubov E., Prokhorov A. A., Petrakovskii G. A., Bezmaternykh L. N., Berkowski M., Varyukhin V., Szymczak H.
Заглавие : Magnetic and EPR studies of the EuFe3(BO3)(4) single crystal
Коллективы :
Разночтения заглавия :авие SCOPUS: Magnetic and EPR studies of the EuFe 3(BO 3) 4 single crystal
Место публикации : Eur. Phys. J. B: SPRINGER, 2010. - Vol. 78, Is. 3. - P291-298. - ISSN 1434-6028, DOI 10.1140/epjb/e2010-10059-3
Примечания : Cited References: 23. - A.A. Prokhorov is grateful to Mianowski Fund for financial support.
Предметные рубрики: EARTH
GDFE3(BO3)(4)
MULTIFERROICS
Ключевые слова (''Своб.индексиров.''): absorption lines--antiferromagnetic orderings--applied magnetic fields--basal planes--easy direction of magnetizations--electron paramagnetic resonance--epr measurements--epr spectra--epr studies--europium ions--exchange fields--g factors--lorentz--magnetic measurements--magnetic subsystems--orientation dependence--sub-lattices--temperature dependence--temperature range--trigonal symmetry--zeeman effect--antiferromagnetism--crystal orientation--europium--magnetic fields--magnetic moments--magnetic variables measurement--magnetization--paramagnetic resonance--paramagnetism--single crystals--spectroscopy--electron spin resonance spectroscopy
Аннотация: Magnetic and electron paramagnetic resonance (EPR) properties of EuFe3(BO3)(4) single crystals have been studied over the temperature range of 300-4.2 K and in a magnetic field up to 5 T. The temperature, field and orientation dependences of susceptibility, magnetization and EPR spectra are presented. An antiferromagnetic ordering of the Fe subsystem occurs at about 37 K. The easy direction of magnetization perpendicular to the c axis is determined by magnetic measurements. Below 10 K, we observe an increase of susceptibility connected with the polarization of the Eu sublattice by an effective exchange field of the ordered Fe magnetic subsystem. In a magnetic field perpendicular to the c axis, we have observed an increase of magnetization at T 10 K in the applied magnetic field, which can be attributed to the appearance of the magnetic moment induced by the magnetic field applied in the basal plane. According to EPR measurements, the distance between the maximum and minimum of derivative of absorption line of the Lorentz type is equal to 319 Gs. The anisotropy of g-factor and linewidth is due to the influence of crystalline field of trigonal symmetry. The peculiarities of temperature dependence of both intensity and linewidth are caused by the influence of excited states of europium ion (Eu3+). It is supposed that the difference between the g-factors from EPR and the magnetic measurements is caused by exchange interaction between rare earth and Fe subsystems via anomalous Zeeman effect.
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Aleksandrovsky A. S., Arkhipkin V. G., Bezmaternykh L. N., Gudim I. A., Krylov A. S., Vagizov F.
Заглавие : Origin of color centers in the flux-grown europium gallium garnet
Место публикации : J. Appl. Phys.: AMER INST PHYSICS, 2008. - Vol. 103, Is. 8. - Ст.83102. - ISSN 0021-8979, DOI 10.1063/1.2902365
Примечания : Cited References: 7
Предметные рубрики: SPECTRA
IONS
Ключевые слова (''Своб.индексиров.''): absorption--europium alloys--garnets--ultraviolet radiation--calcium-free flux--flux-grown europium gallium garnet--color centers
Аннотация: Europium gallium garnet (EuGG) single crystals were grown from fluxes with various contents. Optical absorption spectra of EuGG grown from a flux containing calcium show an additional band in the ultraviolet and blue regions of the spectra as compared to the case of a calcium-free flux. Mossbauer spectra of the samples grown from the fluxes with different additives show no signs of other valence states of the europium ions except for 3+. However, they indicate changes in the crystal field due to the entrance of additive ions. The nature of the additional absorption must be the same as that for calcium-doped gadolinium gallium garnet, i.e., anion vacancies. Mossbauer isotope shifts and quadrupole splitting for EuGG are determined. (C) 2008 American Institute of Physics.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Volkov N. V., Petrakovskii G. A., Vasiliev V. N., Velikanov D. A., Sablina K. A., Patrin K. G.
Заглавие : Observation of mixed two-phase state in Eu0.7Pb0.3MnO3 single crystal by magnetic resonance method
Место публикации : Physica B. - 2002. - Vol. 324, Is. 1-4. - P.254-260. - ISSN 0921-4526, DOI 10.1016/S0921-4526(02)01397-2
Примечания : Cited References: 19
Предметные рубрики: OPTIMALLY DOPED MANGANITES
COLOSSAL MAGNETORESISTANCE
PARAMAGNETIC ANOMALIES
CURIE-TEMPERATURE
LA1-XCAXMNO3
RELAXATION
SEPARATION
Ключевые слова (''Своб.индексиров.''): manganites--cmr--magnetic resonance--phase separation--cmr--magnetic resonance--manganites--phase separation--europium compounds--ferromagnetic materials--paramagnetic resonance--phase separation--phase transitions--manganites--single crystals
Аннотация: The magnetic resonance measurements show that the mixed two-phase state takes place in the Eu0.7Pb0.3MnO3 single crystal. The coexistence of the magnetic phases is observed in vicinity of the magnetic phase transition, where the sample exhibits the effect of the CMR. The frequency-field dependencies of the spectra allow to conclude that these phases are paramagnetic and ferromagnetic ones. Moreover, the study of the frequency dependencies shows the sensitivity of the mixed-phase state to the external magnetic field. This suggests that the scenario of the phase separation is realized in this case and the mixed two-phase state is not related to simple chemical inhomogeneity. (C) 2002 Elsevier Science B.V. All rights reserved.
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15.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhang M., Xia Z., Molokeev M. S., Shi L., Liu Q.
Заглавие : New insight into the crystal structure of Sr4Ca(PO4)2SiO4 and the photoluminescence tuning of Sr4Ca(PO4)2SiO4:Ce3+,Na+,Eu2+ phosphors
Место публикации : J. Mater. Chem. C: Royal Society of Chemistry, 2016. - Vol. 4, Is. 38. - P.9078-9084. - ISSN 20507534 (ISSN), DOI 10.1039/c6tc03373c
Примечания : Cited References: 31
Ключевые слова (''Своб.индексиров.''): calcium--energy transfer--europium--light emission--light emitting diodes--luminescence--phosphate minerals--phosphors--photoluminescence--positive ions--rietveld refinement--tuning--chemical compositions--energy transfer mechanisms--green component--hexagonal cells--luminescence properties--single phase--solid state method--white lightemitting diodes (wleds)--crystal structure
Аннотация: A new single phase based on the substitution of a Sr cation by a Ca cation in the apatite-type Sr5(PO4)2(SiO4) has been fabricated with the nominal chemical composition of Sr4Ca(PO4)2(SiO4), which appears as a definite compound rather than a solid solution between (Sr,Ca)3(PO4)2 and (Sr,Ca)2SiO4. The crystal structure of Sr4Ca(PO4)2(SiO4) has been firstly analysed by the difference electron map, and further resolved by the Rietveld refinement, and the final composition has been determined as Sr4Ca(PO4)(2+x)(SiO4)(1-x)(OH)x (x = 0.64) with a hexagonal cell (P63/m). The Ce3+/Eu2+ codoped Sr4Ca(PO4)2SiO4 phosphors have been designed and prepared by the solid state method, and the photoluminescence tuning from blue to green upon 365 nm ultraviolet (UV) radiation can be realized, which is ascribed to the energy transfer from Ce3+ to Eu2+ ions. The luminescence properties and the energy transfer mechanism in Ce3+/Eu2+ codoped Sr4Ca(PO4)2SiO4 phosphors have been discussed, which might act as potential candidates for blue-green components in UV-pumped white light emitting diodes (WLEDs). © 2016 The Royal Society of Chemistry.
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16.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Shinkorenko A. S., Pavlovskii M. S., Zinenko V. I.
Заглавие : Calculation of the electronic structure, lattice dynamics, and optical and magnetic properties of europium tetraborate EuB4O7
Место публикации : Phys. Solid State: Maik Nauka-Interperiodica Publishing, 2016. - Vol. 58, Is. 11. - P.2300-2306. - ISSN 10637834 (ISSN), DOI 10.1134/S1063783416110329
Примечания : Cited References: 20
Аннотация: The electronic band structure, lattice vibration frequencies, and optical and magnetic properties of EuB4O7 crystal with α-SrB4O7-type structure are calculated within the density functional method. It is found that this compound is a dielectric with a band gap of the order of 4 eV. It is found that the ground state of this crystal is the state with ferromagnetic ordering of Eu2+ spins. Exchange interaction constants are calculated; the ferromagnetic ordering temperature is estimated within the molecular field approximation (Tc ≈ 1 K). The EuB4O7 compound is a magnetic pyroelectric and, hence, can exhibit magnetoelectric properties. The calculated polarization change during ferromagnetic ordering of this crystal is 3973 μC/m2. © 2016, Pleiades Publishing, Ltd.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chen M., Xia Z., Molokeev M. S., Wang T., Liu Q.
Заглавие : Tuning of photoluminescence and local structures of substituted cations in xSr2Ca(PO4)2-(1 - x)Ca10Li(PO4)7:Eu2+ phosphors
Место публикации : Chem. Mater.: American Chemical Society, 2017. - Vol. 29, Is. 3. - P.1430-1438. - ISSN 08974756 (ISSN), DOI 10.1021/acs.chemmater.7b00006
Примечания : Cited References: 37. - The present work was supported by the National Natural Science Foundation of China (Grants 91622125 and 51572023), Natural Science Foundations of Beijing (2172036), and Fundamental Research Funds for the Central Universities (FRF-TP-15-003A2).
Ключевые слова (''Своб.индексиров.''): calcium--energy transfer--europium--light emission--lithium--luminescence--phosphors--photoionization--photoluminescence--single crystals--composition ranges--crystal-field splitting--luminescence measurements--non-linear variation--photoionization process--polyhedra distortion--rare earth doped solids--temperature dependent--solid solutions
Аннотация: Local structure modification in solid solution is an essential part of photoluminescence tuning of rare earth doped solid state phosphors. Herein we report a new solid solution phosphor of Eu2+-doped xSr2Ca(PO4)2-(1 - x)Ca10Li(PO4)7 (0 ≤ x ≤ 1), which share the same β-Ca3(PO4)2 type structure in the full composition range. Depending on the x parameter variation in xSr2Ca(PO4)2-(1 - x)Ca10Li(PO4)7:Eu2+, the vacancies generated in the M(4) site enable the nonlinear variation of cell parameters and volume, and this increases the magnitude of M(4)O6 polyhedra distortion. The local structure modulation around the Eu2+ ions causes different luminescent behaviors of the two-peak emission and induces the photoluminescence tuning. The shift of the emission peaks in the solid solution phosphors with different compositions has been discussed. It remains invariable at x ≤ 0.5, but the red-shift is observed at x 0.5 which is attributed to combined effect of the crystal field splitting, Stokes shift, and energy transfer between Eu2+ ions. The temperature-dependent luminescence measurements are also performed, and it is shown that the photoionization process is responsible for the quenching effect.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Zhao M., Xia Z., Molokeev M. S., Ning L., Liu Q.
Заглавие : Temperature and Eu2+-doping induced phase selection in NaAlSiO4 polymorphs and the controlled yellow/blue emission
Место публикации : Chem. Mater.: American Chemical Society, 2017. - Vol. 29, Is. 15. - P.6552-6559. - ISSN 08974756 (ISSN), DOI 10.1021/acs.chemmater.7b02548
Примечания : Cited References: 48. - The present work was supported by the National Natural Science Foundation of China (Grants 91622125 and 51572023 and 11574003), Natural Science Foundations of Beijing (2172036), and Fundamental Research Funds for the Central Universities (FRF-TP-16-002A3). L.N. acknowledges the support from the Special and Excellent Research Fund of Anhui Normal University.
Ключевые слова (''Своб.индексиров.''): chemical modification--coordination reactions--europium--light emitting diodes--photoluminescence--functional properties--high color rendering index--local coordination structures--near ultraviolet excitations--structural transformation--synthesis temperatures--temperature dependent--white light emitting diodes--density functional theory
Аннотация: The union of temperature-dependent phase transition and relating structural transformation via modification of chemical compositions is of fundamental importance for the discovery of new materials or their functional properties optimization. Herein, the synthesis temperature and Eu2+-doping content induced phase selection and variations of the local structures in nepheline, low-carnegieite and high-carnegieite types of NaAlSiO4 polymorphs were studied in detail. The luminescence of Eu2+ in low-carnegieite and nepheline phases shows blue (460 nm) and yellow (540 nm) broad-band emissions, respectively, under near-ultraviolet excitation. The photoluminescence evolution can be triggered by the different synthesis temperatures in relation to the Eu2+-doping concentration, as corroborated by density functional theory calculations on the local coordination structures and corresponding mechanical stabilities in terms of the Debye temperature. The fabricated white light-emitting diode device with high color rendering index demonstrates that the multicolor phosphors from one system provides a new gateway for the photoluminescence tuning. © 2017 American Chemical Society.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Chen M., Xia Z., Molokeev M. S., Lin C. C., Su C., Chuang Y. -C., Liu Q.
Заглавие : Probing Eu2+ luminescence from different crystallographic sites in Ca10M(PO4)7:Eu2+ (M = Li, Na, and K) with β-Ca3(PO4)2-type structure
Место публикации : Chem. Mater.: American Chemical Society, 2017. - Vol. 29, Is. 17. - P.7563-7570. - ISSN 08974756 (ISSN), DOI 10.1021/acs.chemmater.7b02724
Примечания : Cited References: 34. - The present work was supported by the National Natural Science Foundation of China (Grants 51722202, 91622125, and 51572023), Natural Science Foundations of Beijing (2172036), and Fundamental Research Funds for the Central Universities (FRF-TP-16-002A3). C.C.L. and C.C.S. acknowledge the financial support from the Ministry of Science and Technology of Taiwan (Contract No. MOST 104-2113-M-027-007-MY3), and M. Molokeev acknowledges support of the Russian Foundation for Basic Research (17-52-53031).
Ключевые слова (''Своб.индексиров.''): calcium--doping (additives)--excited states--light emission--lithium--luminescence--phosphors--photoluminescence--positive ions--rietveld refinement--single crystals--color tuning--crystallographic sites--different distributions--emission bands--local environments--long wavelength bands--luminescent centers--power diffraction data--europium
Аннотация: Eu2+ local environments in various crystallographic sites enable the different distributions of the emission and excitation energies and then realize the photoluminescence tuning of the Eu2+ doped solid state phosphors. Herein we report the Eu2+-doped Ca10M(PO4)7 (M = Li, Na, and K) phosphors with β-Ca3(PO4)2-type structure, in which there are five cation crystallographic sites, and the phosphors show a color tuning from bluish-violet to blue and yellow with the variation of M ions. The difference in decay rate monitored at selected wavelengths is related to multiple luminescent centers in Ca10M(PO4)7:Eu2+, and the occupied rates of Eu2+ in Ca(1), Ca(2), Ca(3), Na(4), and Ca(5) sites from Rietveld refinements using synchrotron power diffraction data confirm that Eu2+ enters into four cation sites except for Ca(5). Since the average bond lengths d(Ca-O) remain invariable in the Ca10M(PO4)7:Eu2+, the drastic changes of bond lengths d(M-O) and Eu2+ emission depending on the variation from Li to Na and K can provide insight into the distribution of Eu2+ ions. It is found that the emission band at 410 nm is ascribed to the occupation of Eu2+ in the Ca(1), Ca(2), and Ca(3) sites with similar local environments, while the long-wavelength band (466 or 511 nm) is attributed to Eu2+ at the M(4) site (M = Na and K). We show that the crystal-site engineering approach discussed herein can be applied to probe the luminescence of the dopants and provide a new method for photoluminescence tuning.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Denisenko Y. G., Aleksandrovsky A. S., Atuchin V. V., Krylov A. S., Molokeev M. S., Oreshonkov A. S., Shestakov N. P., Andreev O. V.
Заглавие : Exploration of structural, thermal and spectroscopic properties of self-activated sulfate Eu2(SO4)3 with isolated SO4 groups
Место публикации : J. Ind. Eng. Chem. - 2018. - Vol. 68. - P.109-116. - ISSN 1226086X (ISSN), DOI 10.1016/j.jiec.2018.07.034
Примечания : Cited References: 83. - This work was supported by the Russian Foundation for Basic Research ( 16-52-48010 , 17-52-53031 ). The equipments of the Collective Use Center — Kirensky Institute of Physics, Federal Research Center KSC Siberian Branch Russian Academy of Sciences [ http://ccu.kirensky.ru/ ] was used.
Ключевые слова (''Своб.индексиров.''): europium sulfate--synthesis--structure--thermal analysis--photoluminescence
Аннотация: Eu2(SO4)3 was synthesized by chemical precipitation method and the crystal structure was determined by Rietveld analysis. The compound crystallizes in monoclinic space group С2/с. In the air environment, Eu2(SO4)3 is stable up to 670 °C. The sample of Eu2(SO4)3 was examined by Raman, Fourier-transform infrared absorption and luminescence spectroscopy methods. The low site symmetry of SO4 tetrahedra results in the appearance of the IR inactive ν1 mode around 1000 cm−1 and ν2 modes below 500 cm−1. The band intensities redistribution in the luminescent spectra of Eu3+ ions is analyzed in terms of the peculiarities of its local environment.
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