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1.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Иванова, Оксана Станиславовна, Иванцов, Руслан Дмитриевич, Эдельман, Ирина Самсоновна
Заглавие : Магнитооптические боратные и германатные стекла
Примечания : Библиогр.: 1 назв. - Работа поддержана грантом РФФИ 14-02-01211_a :
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2.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Kliava J., Edelman I. S., Ivanova O. S., Ivantsov R. D., Bayukov O. A., Petrakovskaja E. A., Zaikovskiy V. I.
Заглавие : Nanostructures based on glasses simultaneously doped with Fe and Mn
Место публикации : Abstracts of Nano South West European Conference, Bordeaux, France, 2008, р. 137
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3.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Mikhaleva E. A., Gorev M. V., Bondarev V. S., Molokeev M. S., Zaitsev A. I., Nemtsev I. V., Fokin A. V., Flerov I. N.
Заглавие : Heat capacity and thermal expansion of nanosized ferroelectric (NH4)2SO4 embedded in borosilicate glasses
Место публикации : J. Non-Cryst. Solids. - 2022. - Vol. 597. - Ст.121935. - ISSN 00223093 (ISSN), DOI 10.1016/j.jnoncrysol.2022.121935
Примечания : Cited References: 29. - The authors are grateful to Dr. Ewa Rysiakiewicz-Pasek (Wroclaw University of Science and Technology, Poland) for the preparation and characterization of borosilicate glasses. X-ray and dilatometric data were obtained using the equipment of Krasnoyarsk Regional Center of Research Equipment of Federal Research Center “Krasnoyarsk Science Center SB RAS”
Аннотация: The thermal properties of nanocomposites obtained by incorporating a ferroelectric (NH4)2SO4 (AS) into porous glasses (PG) was studied for the first time. X-ray diffraction studies showed a strong increase in the ratio of the size of nanocrystallites grown in glass matrices to pore size, dcryst/ dpore = 0.47→1.50→5.00, with a decrease in dpore = 320→46→7 nm. Calorimetric and dilatometric measurements showed a change from a first-order phase transition in AS single crystal to a second-order transformation in AS nanocrystallites. A restricted geometry also led to a significant decrease in the anomalous entropy in AS+PG samples compared to AS (J/mol∙K): 17.7 (AS)→12.4 (AS+PG320)→10.4 (AS+PG46)→8.1 (AS+PG7). A discussion of the nontrivial behavior of the phase transition temperature in embedded AS was carried out using the degree of PG filling, the ratio dcryst/dpore, texture, and the volumetric and linear baric coefficients for the bulk AS.
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4.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Korotkov L. N., Stekleneva L. S., Flerov I. N., Mikhaleva E. A., Rysiakiewicz-Pasek E., Molokeev M. S., Bondarev I. A., Gorev M. V., Sysoev O. I.
Заглавие : X-Ray, Dielectric, and Thermophysical Studies of Rubidium Tetrachlorozincate inside Porous Glasses
Место публикации : Bull. Russ. Acad. Sci. Phys. - 2019. - Vol. 83, Is. 9. - P.1072-1076. - ISSN 10628738 (ISSN), DOI 10.3103/S1062873819090132
Примечания : Cited References: 17
Аннотация: Results are presented from studying the X-ray diffraction, heat capacities, dielectric permittivities, and coefficients of the volumetric thermal expansion of composite materials obtained by embedding of Rb2ZnCl4 salt into the porous matrices of borosilicate glass with average pore diameters of 46 and 320 nm in the temperature range of 120–350 K. The temperatures of transitions to the incommensurate and ferroelectric phases are determined, along with the freezing temperature of the mobility of domain boundaries in Rb2ZnCl4 particles. A substantial increase in their Curie temperature is observed.
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5.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Kliava J., Ivanova O. S., Ivantsov R. D., Velikanov D. A., Zaikovskii V., Petrakovskaja E. A., Zubavichus Y., Stepanov S.
Заглавие : Effect of gadolinium on magnetic circular dichroism and electron magnetic resonance of ε-Fe2O3 nanoparticles formed in borate glasses
Место публикации : J. Non-Cryst. Solids. - 2019. - Vol. 506. - P.68-79. - ISSN 00223093 (ISSN) , DOI 10.1016/j.jnoncrysol.2018.12.006
Примечания : Cited References: 81. - The work is supported by Russian Academy of Sciences in the frame of the Project № 0356-2017-0030.
Ключевые слова (''Своб.индексиров.''): iron oxides--ε-fe2o3--borate glasses--nanoparticles--magnetic circular dichroism--electron magnetic resonance
Аннотация: A remarkable characteristic of borate glasses is the ability of forming magnetic nanoparticles at low doping with transition element oxides. We have studied structure and magnetic properties of iron oxide nanoparticles formed in borate glasses, in particular, concentration and temperature dependences of magnetic circular dichroism (MCD) and electron magnetic resonance (EMR) spectra. A series of glasses of molar composition 22.5K2O-22.5Al2O3–55B2O3 doped with 1.5 mass % of Fe2O3 and different contents of Gd2O3 from 0.1 to 1.0 mass % was prepared using a conventional melt quenching technique and subjected to an additional thermal treatment. The whole set of results allows to identify the predominant magnetic phase in these glasses as ε-Fe2O3 nanoparticles, with a considerable part of iron ions substituted by gadolinium. Analysis and computer simulations of the EMR spectra allow separating the contribution of electron paramagnetic resonance of diluted iron ions and together with the temperature dependences of magnetization demonstrate a superparamagnetic character of the nanoparticle magnetism.
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6.

Вид документа : Статья из сборника (выпуск продолж. издания)
Шифр издания :
Автор(ы) : Ivanova O. S., Kliava J., Edelman I. S., Ivantsov R. D., Petrakovskaja E. A.
Заглавие : Microwave and magneto-optic properties of ϵ-Fe2O3 nanoparticles arising in borate glasses doped with Fe and Gd
Коллективы : Moscow International Symposium on Magnetism, Московский государственный университет им. М.В. Ломоносова, Российский фонд фундаментальных исследований
Место публикации : EPJ Web Conf.: 1-7 July 2017 : book of abstracts. - 2018. - Vol. 185. - Ст.03011. - DOI 10.1051/epjconf/201818503011
Примечания : Cited References: 15
Аннотация: The ϵ-Fe2O3 nanoparticles in borate glasses co-doped with low concentrations of Fe2O3 and Gd2O3 were investigated with two experimental techniques-visible magnetic circular dichroism (MCD) and electron spin resonance (ESR). The most prominent features of the MCD spectra are: non-linear dependence of the spectral maxima intensities on the Gd concentration and strong increase with the temperature decrease. The ESR spectra of these glasses exhibit two features with g = 4.3 due to the diluted Fe3+ ions and 2.0 associated both with Fe3+ ions and with nanoparticles. The integrated spectra intensities do not follow the T-1 Curie law suggesting a considerable contribution from the magnetically ordered nanoparticles to ESR. Analysis of the MCD and ESR concentration dependences allow suggestion on the Gd ions incorporation into nanoparticles.
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7.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Иванова, Оксана Станиславовна, Эдельман, Ирина Самсоновна
Заглавие : Прозрачные магнитные стеклокерамики на основе боратных и германатных стекол с наночастицами ферритов
Коллективы : "Новые материалы и перспективные технологии", междисциплинарный научный форум с международным участием, Российская академия наук, Совет молодых ученых Российской академии наук, Российское химическое общество им. Д.И. Менделеева, Институт металлургии и материаловедения им. А. А. Байкова РАН
Место публикации : Четвертый междисциплинарный научный форум с международным участием “Новые материалы и перспективные технологии”: сборник материалов. - 2018. - Т. 1. - С. 215-220
Примечания : Библиогр.: 5
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8.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Mikhaleva E. A., Flerov I. N., Kartashev A. V., Gorev M. V., Bogdanov E. V., Bondarev V. S., Kogotkov L. N., Rysiakiewicz-Pasek E.
Заглавие : Effect of interaction of components on thermal properties of ferroelectric nanocomposites
Коллективы : "Porous Glasses-Special Glasses", Seminar, Wroclaw University of Science and Technology
Место публикации : Eleventh Seminar Porous Glasses-Special Glasses (PGL'2018): Abstracts and program. - 2018. - Ст.18. - P.23
Примечания : Библиогр.: 2
,
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9.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Drokina T. V., Petrakovskii G. A., Bayukov O. A., Molokeev M. S., Bartolome J., Arauzo A.
Заглавие : Role of Fe magnetic subsystems to form a magnetic spin glass state in RFeTi2O7
Коллективы : Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium, Институт физики им. Л.В. Киренского Сибирского отделения РАН , project MECOM [MAT2014-53921-R]; project DGA [IMANA E34]
Место публикации : J. Magn. Magn. Mater.: Elsevier Science, 2017. - Vol. 440. - P.41-43. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2016.12.088. - ISSN 1873-4766(eISSN)
Примечания : Cited References:6. - This work has been partially financed by projects MECOM (MAT2014-53921-R) and DGA (IMANA E34)
Предметные рубрики: COMPOUND
Ключевые слова (''Своб.индексиров.''): oxide materials--solid state reaction--cation substitution--spin glasses
Аннотация: The experimental studies on R3+Fe3+Ti2O7 (R=Sm, Gd, Tb, Tm, Dy) magnetic properties evidence the low temperature spin glass state in all compounds. The possibility of rare-earth cation substitution allows the investigation of the role of magnetic iron Fe3+ ions and rare earth R3+ ions subsystems in a ground state formation in these oxide compounds.
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10.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Ivanova O. S., Kliava J., Edelman I. S., Ivantsov R. D., Petrakovskaja E. A.
Заглавие : Microwave and magneto-optic properties OF ε-FE2O3 nanoparticles arising in borate glasses doped with FE and GD
Коллективы : Moscow International Symposium on Magnetism, Московский государственный университет им. М.В. Ломоносова, Российский фонд фундаментальных исследований
Место публикации : Moscow International Symposium on Magnetism (MISM-2017): 1-7 July 2017 : book of abstracts. - 2017. - Ст.4OR-C-15. - P.726 (Шифр 29916280)
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11.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova O. S., Ivantsov R. D., Edelman I. S., Petrakovskaja E. A.
Заглавие : A comparative study of γ-Fe2O3 and ε-Fe2O3 nanoparticles arising in borate glasses doped with Fe and Gd
Место публикации : J. Sib. Fed. Univ. Math. Phys. - 2016. - Vol. 9, Is. 4. - P.459–462. - ISSN 1997-1397, DOI 10.17516/1997-1397-2016-9-4-459-462; Журн. СФУ. Сер. "Математика и физика"
Примечания : Cited References: 6. - The work was supported partly by the RFBR, 14-02-01211-a, and by the President of Russia Grant NSh-7559.2016.2.
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--magnetic circular dichroism--magnetic measurements--магнитные наночастицы--магнитный круговой дихроизм--магнитные измерения
Аннотация: Formation and properties of the iron oxides γ -Fe2O3 and ϵ-Fe2O3 nanoparticles arising in glasses of basic compositions Ge2O-K2O-Al2O3-B2O3 and K2O-Al2O3-B2O3 doped with different concentrations of Fe2O3 and Gd2O3 and subjected to the additional thermal treatment are studied. The X-ray diffraction, TEM microscopy, magnetooptical effects, and electron spin resonance study allow elucidating the matrix and Gd role in determining the nanoparticle properties.Изучены свойства наночастиц γ-Fe2O3 и ϵ-Fe2O3, формирующихся в стеклах основного состава Ge2O-K2O-Al2O3-B2O3 и K2O-Al2O3-B2O3, допированных Fe2O3 и Gd2O3 и подвергнутых дополни- тельной термической обработке. Результаты исследования рентгеновской дифракции, электрон- ной микроскопии, магнитооптических эффектов и электронного спинового резонанса позволили объяснить роль матрицы и гадолиния в определении свойств наночастиц.
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12.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Ivanova O. S., Ivantsov R. D., Edelman I. S., Petrakovskaja E. A.
Заглавие : A comparative study of γ-Fe2O3 and ε-Fe2O3 nanoparticles arising in borate glasses doped with Fe and Gd
Коллективы : Euro-Asian Symposium "Trends in MAGnetism", "Trends in MAGnetism", Euro-Asian Symposium, Институт физики им. Л.В. Киренского Сибирского отделения РАН
Место публикации : VI Euro-Asian Symposium "Trends in MAGnetism" (EASTMAG-2016): abstracts/ ed.: O. A. Maksimova, R. D. Ivantsov. - Krasnoyarsk: KIP RAS SB, 2016. - Ст.P9.11. - P.397. - ISBN 978-5-904603-06-9 (Шифр -478014040)
Примечания : References: 1. - The work was supported partly by the RFBR grant No. 14-02-01211
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--magnetic circular dichroism--magnetic measurements
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13.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova O. S., Ivantsov R. D., Edelman I. S., Petrakovskaja E. A., Velikanov D. A., Zubavichus Y. V., Zaikovskii V .I., Stepanov S. A.
Заглавие : Identification of ε-Fe2O3 nano-phase in borate glasses doped with Fe and Gd
Место публикации : J. Magn. Magn. Mater.: Elsevier, 2016. - Vol. 401. - P.880-889. - ISSN 0304-8853, DOI 10.1016/j.jmmm.2015.10.126
Примечания : Cited References: 40. - This work was supported partly by the Russian Foundation for Basic Research, Grants No 14-02-01211-a and by the President of Russia Grant No. NSh-2886.2014.2. Authors are grateful to G.A. Bukhtiyarova and U.N. Martyanov for the assistance in the ε-Fe2O3 nanoparticles prepared by a wet chemical pore filling impregnation method and for the discussion of the obtained results
Предметные рубрики: MAGNETIC-PROPERTIES
IRON-OXIDE
NANOPARTICLES
CERAMICS
CRYSTAL
PARTICLES
SURFACE
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--ε-fe2o3--magnetic circular dichroism--electron magnetic resonance
Аннотация: A new type of magnetic nanoparticles was revealed in borate glasses co-doped with low contents of iron and gadolinium. Structure and magnetic properties of the particles differ essentially from that of the α-Fe2O3, γ-Fe2O3, or Fe3O4 nanoparticles which were detected earlier in similar glass matrices. Transmission electron microscopy including STEM-HAADF and EDX, synchrotron radiation-based XRD, static magnetic measurements, magnetic circular dichroism, and electron magnetic resonance studies allow referring the nanoparticles to the iron oxide phase-ε-Fe2O3. Analysis of the data set has shown that it is Gd atoms that govern the process of nanoparticles' nucleation and its incorporation into the particles in different proportions can be used to adjust their magnetic and magneto-optical characteristics. © 2015 Elsevier B.V.
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14.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Edelman I. S., Ivanova O. S., Petrakovskaja E. A., Velikanov D. A., Tarasov I. A., Zubavichus Y. V., Trofimova N. N., Zaikovskii V. I.
Заглавие : Formation, characterization and magnetic properties of maghemite γ-Fe2O3 nanoparticles in borate glasses
Коллективы : Russian Foundation for Basic Research - Russia [14-02-01211-a]; President of Russia [NSh-2886.2014.2]; Russian Ministry of Science and Education [RFMEFI61914X0002]
Место публикации : J. Alloys Compd.: Elsevier Science, 2015. - Vol. 624. - P.60-67. - ISSN 0925-8388, DOI 10.1016/j.jallcom.2014.11.059
Примечания : Cited References: 25. - This work was supported partly by the Russian Foundation for Basic Research - Russia, Grant No. 14-02-01211-a and by the President of Russia Grant No. NSh-2886.2014.2. This work was performed using the equipment of Unique Scientific Facility "Kurchatov Synchrotron Radiation Source'' supported by the Russian Ministry of Science and Education (project code RFMEFI61914X0002).
Предметные рубрики: SUPERPARAMAGNETIC RESONANCE
HYSTERESIS LOOPS
EXCHANGE BIAS
IONS
MATRIX
Ключевые слова (''Своб.индексиров.''): nanostructures--crystal structure and symmetry--magnetic measurements
Аннотация: A new type of nanocomposite materials based on maghemite, γ-Fe2O3, nanoparticles dispersed in borate glasses co-doped with low contents of iron together with the larger radius element combinations: Y and Bi, or Sm and Pb, or Y and Pb is studied. Nanoparticles arise as a result of heat treatment of the glasses which gives them properties characteristic of magnetically ordered substances. Transmission electron microscopy and XRD show that only one magnetic phase, namely γ-Fe2O3 nanoparticles, occurs in glasses subjected to the thermal treatment at 540 °C during 24 h independently on the doping element nature. At the same time doping element and their concentrations ratio in every combination affect the particles average size and glass magnetic properties, such as magnetization temperature dependences, Faraday rotation value and electron magnetic resonance spectrum characteristics.
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15.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Ivantsov R. D., Ivanova O. S., Petrakovskaja E. A., Zubavichus Y. V., Mikhlin Y. L., Edelman I. S.
Заглавие : Magnetic nanoparticles origin in glasses co-doped with iron and gadolinium oxides
Коллективы : Asian School-Conference on Physics and Technology of Nanostructured Materials, Азиатская школа-конференция по физике и технологии наноструктурированных материалов
Место публикации : Third Asian school-conference on physics and technology of nanostructured materials (ASCO-NANOMAT 2015): proceedings. - Vladivostok: Dalnauka, 2015. - Ст.VI.21.06p. - ISBN 978-5-8044-1556-4
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16.

Вид документа : Статья из сборника (однотомник)
Шифр издания :
Автор(ы) : Mikhaleva E. A., Flerov I. N., Kartashev A. V., Gorev M. V., Bogdanov E. V., Korotkov L. N., Dotsenko I. I., Rysiakiewicz-Pasek E.
Заглавие : Properties of NH4HSO4 ferroelectric embedded in nanoporous glasses
Коллективы : International Workshop on Phase Transitions and Inhomogeneous States in Oxides, "Фазовые переходы и неоднородные состояния в оксидах", международный семинар
Место публикации : Int. Workshop on Phase Transit. and Inhomogeneous States in Oxides: book of abstracts. - Kazan, 2015. - Р.64
Примечания : Библиогр.: 4 назв.
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17.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Guan, Ming, Zheng, Hong, Mei, Lefu, Molokeev M. S., Xie, Jing, Yang, Tao, Wu, Xiaowen, Huang, Saifang, Huang, Zhaohui
Заглавие : Preparation, structure, and up-conversion luminescence of Yb3+/Er3+ codoped SrIn2O4 phosphors
Место публикации : J. Am. Ceram. Soc.: Wiley-Blackwell, 2015. - Vol. 98, Is. 4. - P.1182-1187. - ISSN 0002, DOI 10.1111/jace.13415. - ISSN 15512916(eISSN)
Примечания : Cited References:26. - This present work was supported by the National Natural Science Foundations of China (grant no. 51202226), the Fundamental Research Funds for the Central Universities (grant nos. 292014125,2652013128, 2652013043), and the Research Fund for the Doctoral Program of Higher Education of China (grant no. 20130022110006).
Предметные рубрики: CORE-SHELL NANOPARTICLES
DOPED CaIn2O4
GREEN
Er3+
EMISSION
GLASSES
Аннотация: SrIn2O4, which shows lower phonon energy than CaIn2O4, is not only a good photocatalyst but also can be an excellent up-conversion (UC) host to exhibits UC luminescence. In this work, Yb3+ and/or Er3+ doped SrIn2O4 phosphors were synthesized, and their UC luminescence properties were studied and compared with those in the CaIn2O4 host. The structure of SrIn2O4: 0.01Er3+ and SrIn2O4: 0.1Yb3+/0.01Er3+ samples were refined by the Rietveld method and found to that SrIn2O4: 0.1Yb3+/0.01Er3+ showed increasing unit cell parameters and cell volume, indicating In3+ sites were substituted successfully by Yb3+ and/or Er3+ ions. From the UC luminescence spectra and diffuse reflection spectra, Er3+-doped SrIn2O4 showed very weak luminescence due to ground state absorption of Er3+; Yb3+/Er3+ codoped SrIn2O4 presented strong green (550 nm) and red (663 nm) UC emissions which were assigned to energy transfer from Yb3+ transition 2F7/2→2F5/2 to the Er3+ transition 4S3/2 → 4I15/2 and 4F9/2 → 4I15/2. Comparing with CaIn2O4, Yb3+/Er3+ codoped SrIn2O4 showed obvious advantages with higher UC luminescent intensity. The pumping powers study showed that UC emissions in Yb3+/Er3+ codoped SrIn2O4 were attributed to energy transfer of Yb3+→Er3+ with a two-photon process. The possible UC luminescent mechanism of Yb3+/Er3+-doped SrIn2O4 was discussed.
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18.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ivanova O. S., Edelman I. S., Ivantsov R. D., Petrakovskaja E. A., Velikanov D. A., Trofimova N. N., Zubavichus Y. V.
Заглавие : Ensembles of γ-Fe2O3 nanoparticles formed during devitrification of borate glasses
Коллективы : Euro-Asian Symposium "Trends in MAGnetism": Nanomagnetism
Место публикации : Solid State Phenom.: Selected, peer reviewed papers/ ed.: S. G. Ovchinnikov, A. Samardak: Trans Tech Publications, 2014. - Vol. 215: Trends in Magnetism: Nanomagnetism (EASTMAG-2013). - P.173-178. - ISSN 978-303835054-5, DOI 10.4028/www.scientific.net/SSP.215.173. - ISSN 1662-9779
Примечания : Cited References: 16
Ключевые слова (''Своб.индексиров.''): magnetic nanoparticles--magneto-optical properties
Аннотация: Structural, magnetic and magneto-optical properties of borate glasses co-doped with Fe and the lager radius ions are presented. Maghemite, ?-Fe2O3, nanoparticles arise in the glasses as a result of their thermal treatment in different regimes. Magnetization FC and ZFC temperature dependences demonstrate the superparamagnetic behavior of the particles with the blocking temperature below the room temperature. The EMR spectra measurements revealed a significant anisotropy with a large contribution of the nanoparticles' surface anisotropy. The FR maximum centered near 700 nm is a characteristic feature of the investigated glasses. © (2014) Trans Tech Publications, Switzerland.
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19.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Atuchin V. V., Yelisseyev A. P., Galashov E. N., Molokeev M. S.
Заглавие : Synthesis and luminescence properties of Li2O–Y2O3–TeO2:Eu3+ tellurite glass
Коллективы : Ministry of Education and Science of the Russian Federation
Место публикации : Mater. Chem. Phys.: Elsevier Science, 2014. - Vol. 147, Is. 3. - P.1191-1194. - ISSN 0254-0584, DOI 10.1016/j.matchemphys.2014.07.003. - ISSN 1879-3312
Примечания : Cited References: 26. - This study is partly supported by the Ministry of Education and Science of the Russian Federation.
Предметные рубрики: LIGHT-EMITTING-DIODES
SPECTROSCOPIC PROPERTIES
OPTICAL-PROPERTIES
ENERGY-TRANSFER
CERAMICS
Eu3+
PHOTOLUMINESCENCE
TEMPERATURE
EMISSION
PHOSPHOR
Ключевые слова (''Своб.индексиров.''): glasses--heat treatment--photoluminescence spectroscopy--optical properties
Аннотация: The Eu3+-doped red-orange emitting phosphor of tellurite glass 0.25Li2O–0.20Y2O3–0.5TeO2–0.05Eu2O3 has been synthesized by the melt quenching method. The amorphous nature of the glass has been verified by XRD measurements. The photoluminescence excitation and emission spectra, the luminescence decay curves have been investigated for the composition. The phosphor can be efficiently excited by the near UV light to realize the intense narrow red emission line (611 nm) corresponding to forced electric dipole transition 5D0 → 7F2 of Eu3+ ions. The Li2O–Y2O3–TeO2:Eu3+glass phosphor is a potential red-orange emitting candidate for the application in WLEDs.
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20.

Вид документа : Статья из журнала
Шифр издания :
Автор(ы) : Ikonnikov D. A., Malakhovskii A. V., Sukhachev A. L., Temerov V. L., Krylov A. S., Bovina A. F., Aleksandrovsky A. S.
Заглавие : Spectroscopic properties of HoAl3(BO3)4 single crystal
Коллективы : Ministry of Education and Science of the Russian Federation for Siberian Federal University; Russian Foundation for Basic Research Grants [12-02-00026, 14-02-00219, 13-02-00825]; Russian President Grant [SS-2886.2014.2]; SB RAS Project [43]
Место публикации : Opt. Mater.: Elsevier Science, 2014. - Vol. 37. - P.257–261. - ISSN 0925, DOI 10.1016/j.optmat.2014.05.036. - ISSN 18731252 (eISSN)
Примечания : Cited References: 30. - The work was supported by Grant of the Ministry of Education and Science of the Russian Federation for Siberian Federal University, the Russian Foundation for Basic Research Grants 12-02-00026, 14-02-00219 and 13-02-00825, by the Russian President Grant SS-2886.2014.2, and by SB RAS Project No. 43.
Предметные рубрики: RARE-EARTH IONS
OPTICAL-PROPERTIES
Ho3+ IONS
ABSORPTION
INTENSITIES
EMISSION
GLASSES
SPECTRA
LUMINESCENCE
PARAMETERS
Ключевые слова (''Своб.индексиров.''): absorption--luminescence--holmium--huntite--judd-ofelt
Аннотация: The Judd–Ofelt theory has been applied to analyze absorption spectra of Ho3+ ion in HoAl3(BO3)4 measured in spectral range 300–700 nm at room temperature. The Judd–Ofelt spectroscopic parameters have been determined as: Ω2 = 18.87 x 10 -20 cm2, Ω4 = 17.04 x 10 -20 cm2, Ω6 = 9.21 x 10 -20 cm2. These parameters have been used to calculate radiative lifetimes and branching ratios of the luminescence manifolds. Three luminescent bands were found in the spectral range 450–700 nm ascribed to transitions from the 5F5, (5F4, 5S2) and 3K8 states to the ground state 5I8. Experimental intensities of these luminescence transitions were compared with those calculated by using Judd–Ofelt theory and the system of kinetic equations for populations of starting luminescing states. Probabilities of radiativeless transitions were evaluated from this comparison.
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