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Библиотека института физики им. Л.В. Киренского СО РАН
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1.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Sorensen L. K., Utyushev A. D., Zakomirnyi V. I., Gerasimov V. S., Ershov A. E., Polyutov S. P., Karpov S. V., Agren H.
Заглавие
: Plasmonic enhancement of local fields in ultrafine metal
nanoparticles
Место публикации
: J. Phys. Chem. C. - 2021. - Vol. 125, Is. 5. - P.13900-13908. - ISSN 19327447 (ISSN),
DOI
10.1021/acs.jpcc.1c01424
Примечания
: Cited References: 65. - The work was supported by the Russian Science Foundation (project no. 18-13-00363). L.K.S acknowledges the support of Carl Tryggers Stifetelse, project CTS 18-441
Аннотация:
We present an analysis of ultrafine metallic
nanoparticles
(1-15 nm) with respect to electromagnetic field generation by plasmonic excitations. A number of structures with different symmetries and geometries are studied in order to analyze the distributions of plasmonically generated near-electric fields and the concentration of hot and cold spots around the particles. The study is made possible by the recent development of an extended discrete interaction model (Ex-DIM) where the explicit dependency of the plasmonic spectra on the structure and composition of particles in the range of 1-15 nm is accounted for. With the Ex-DIM, the optical response of the internal crystal structure of the nanoscale particles can be visualized, thereby making it possible to predict the dependence of the generated local fields with respect to the position of the particles relative to the external field polarization. The results indicate rather surprising concentrations of the plasmon fields in very confined hot spots also in cases when the particles retain a high symmetry. The consequence of the findings of this study when using small symmetric
nanoparticles
for near-field imaging is briefly discussed.
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2.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Kostyukov A. S., Ershov A. E., Bikbaev R. G., Gerasimov V. S., Rasskazov I. L., Karpov S. V., Polyutov S. P.
Заглавие
: Substrate-mediated lattice Kerker effect in Al metasurfaces
Место публикации
: J. Opt. Soc. Am. B. - 2021. - Vol. 38, Is. 9. - P.C78-C83. - ISSN 07403224 (ISSN),
DOI
10.1364/JOSAB.427939
Примечания
: Cited References: 62. - Funding. Russian Foundation for Basic Research, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science (20-42-240003); Ministry of Science and Higher Education of the Russian Federation (FSRZ-2020-0008)
Аннотация:
Surface lattice resonances (SLRs) emerging in regular arrays of plasmonic
nanoparticles
(NPs) are known to be exceptionally sensitive to the homogeneity of the environment. It is considered necessary to have a homogeneous environment for engineering narrowband SLRs, while in a half-space environment, SLRs rapidly vanish as the contrast between the refractive indices of the substrate and superstrate increases. From this conventional wisdom, it is apparent that the delicate lattice Kerker effect emerging from SLRs and resonances on constituent NPs should be difficult to achieve in a non-homogeneous environment. Using a rigorous theoretical treatment with multipolar decomposition, we surprisingly find and explain a narrowband substrate-mediated lattice Kerker effect in two-dimensional arrays of Al nanocylinders in a half-space geometry. We propose to use this effect for sensing applications and demonstrate its broad tunability across the UV/Vis wavelength range.
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3.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Petrov D. A., Ivanova O. S., Sokolov A. Е., Герасимова М. А., Edelman I. S., Ying Zhen Chen, Spivakov A. A., Yaw-Teng Tseng, Chun-Rong Lin
Заглавие
: Surface modification of Fe3O4@SiO2
nanoparticles
Коллективы
: "Новое в магнетизме и магнитных материалах", международная конференция, Научный совет по физике конденсированных сред РАН, МИРЭА - Российский технологический университет, Московский государственный университет им. М.В. Ломоносова, Магнитное общество России
Место публикации
: Новое в магнетизме и магнитных материалах: сборник трудов XXIV международной конференции/ прогр. ком.: Р. С. Исхаков, С. Г. Овчинников [и др.]. - 2021. - Секция 10: Малые магнитные частицы. - Ст.10-24-27
Примечания
: Библиогр.: 9
Аннотация:
Работа направлена на разработку технологии амино-функциональных наночастиц Fe3O4@SiO2. Изучены морфология и особенности магнитных и магнитооптических свойств полученных гибридных наночастиц. Рассмотрены некоторые примеры применения таких гибридных наноструктур.The work is aimed to the development of the technology of the amino-functionalized Fe3O4@SiO2
nanoparticles
. The morphology and features of the magnetic and magneto-optical properties of the obtained hybrid
nanoparticles
are studied. Some examples of applications of such hybrid nanostructures are considered.
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4.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Fedorov A. S., Kovaleva E. A., Sokolov A. Е., Visotin M. A., Lin C. R., Ovchinnikov S. G.
Заглавие
: Trimetallic magnetite-Ti-Au nanoparticle formation: A theoretical approach
Место публикации
: Mater. Chem. Phys. - 2021. - Vol. 271. - Ст.124847. - ISSN 02540584 (ISSN),
DOI
10.1016/j.matchemphys.2021.124847
Примечания
: Cited References: 46. - The reported study was funded by Joint Research Project of Russian Foundation for Basic Research # 19-52-52002 and Ministry of Science and Technology, Taiwan MOST # 109-2112-M-153-003 and # 108-2923-M-153-001-MY3
Аннотация:
Geometric, electronic and magnetic structure of planar slabs consisting of magnetite Fe3O4, titanium and gold layers are investigated by DFT-GGA calculations. It is assumed that these slabs can be used to simulate the upper layers of magnetite
nanoparticles
covered with an intermediate layer of titanium and a gold layer on the surface. Specific energies and spreading parameters (wettability) of the magnetite-gold, magnetite-titanium and titanium-gold interfaces are calculated. The specific energy and spreading parameter of the magnetite-gold interface is found to be negative, while these values of the magnetite-titanium (for thin Ti layer) and magnetite-titan-gold interfaces are significantly positive. This allows us to hope that the intermediate thin layer of titanium at the boundary between the surface of the magnetite nanoparticle and the gold layer stabilizes this three-layer structure and allows obtaining magnetite
nanoparticles
covered with continuous gold coating.
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5.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Saikova S., Pavlikov A., Trofimova T., Mikhlin Y., Karpov D., Asanova A., Grigoriev Y., Volochaev M. N., Samoilo A., Zharkov S. M., Velikanov D. A.
Заглавие
: Hybrid
nanoparticles
based on cobalt ferrite and gold: Preparation and characterization
Место публикации
: Metals. - 2021. - Vol. 11, Is. 5. - Ст.705. - ISSN 20754701 (ISSN),
DOI
10.3390/met11050705
Примечания
: Cited References: 74
Аннотация:
During the past few decades, hybrid
nanoparticles
(HNPs) based on a magnetic material and gold have attracted interest for applications in catalysis, diagnostics and nanomedicine. In this paper, magnetic CoFe2O4/Au HNPs with an average particle size of 20 nm, decorated with 2 nm gold clusters, were prepared using methionine as a reducer and an anchor between CoFe2O4 and gold. The methionine was used to grow the Au clusters to a solid gold shell (up to 10 gold deposition cycles). The obtained
nanoparticles
(NPs) were studied by X-Ray diffraction (XRD), transmis-sion electron microscopy (TEM), Fourier-transform infrared (FT-IR) spectroscopy, X-Ray photoelectron spectroscopy (XPS) and UV-vis spectroscopy techniques. The TEM images of the obtained HNPs showed that the surface of cobalt ferrite was covered with gold nanoclusters, the size of which slightly increased with an increase in the number of gold deposition cycles (from 2.12 ± 0.15 nm after 1 cycle to 2.46 ± 0.13 nm after 10 cycles). The density of the Au clusters on the cobalt ferrite surface insignificantly decreased during repeated stages of gold deposition: 21.4 ± 2.7 Au NPs/CoFe2O4 NP after 1 cycle, 19.0 ± 1.2 after 6 cycles and 18.0 ± 1.4 after 10 cycles. The magnetic measurements showed that the obtained HNPs possessed typical ferrimagnetic behavior, which corresponds to that of CoFe2O4
nanoparticles
. The toxicity evaluation of the synthesized HNPs on Chlorella vulgaris indicated that they can be applied to biomedical applications such as magnetic hyperthermia, photothermal therapy, drug delivery, bioimaging and biosensing.
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6.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Balaev D. A., Poperechny I. S., Krasikov A. A., Semenov S. V., Popkov S. I., Knyazev Yu. V., Kirillov V. L., Yakushkin S. S., Martyanov O. N., Raikher Y. L.
Заглавие
: Dynamic remagnetisation of CoFe2O4
nanoparticles
: thermal fluctuational thawing of anisotropy
Коллективы
: [AAAA-A17-117103050081-1]; [AAAAA20-120020690030-5]
Место публикации
: J. Phys. D. - 2021. - Vol. 54, Is. 27. - Ст.275003. - ISSN 0022-3727,
DOI
10.1088/1361-6463/abf371. - ISSN 1361-6463(eISSN)
Примечания
: Cited References: 63. - Experimental measurements were supported by Project No. AAAA-A17-117103050081-1. I S P and Yu L R acknowledge the support of ICMM in the framework of topical task AAAAA20-120020690030-5. The numerical calculations were performed on the Uran supercomputer (Ural Branch, Russian Academy of Sciences, Ekaterinburg)
Предметные рубрики:
COBALT-FERRITE
NANOPARTICLES
MAGNETIC-PROPERTIES
SIZE
COERCIVITY
Аннотация:
We report a study of the magnetodynamics of cobalt ferrite (CoFe2O4)
nanoparticles
with an average diameter of ~6 nm. Hysteresis loops were measured under quasi-static conditions and in pulse fields with amplitudes H0 of up to 130 kOe and for durations τP of 8 and 16 ms. The growth of coercivity Hc observed with an increase in the magnetic field variation rate dH/dt (determined by the values of H0 and τP) and the reduction of Hc with temperature is ascribed to the superparamagnetic effect. The proposed theoretical model explains the observed dependences fairly well. Notably, the effective magnetic anisotropy constant obtained exceeds the value for bulk crystals and might be indicative of the contribution of surface magnetic anisotropy.
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7.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Vorob’ev S. A., Burdakova E. A., Sarycheva A. A., Volochaev M. N., Karacharov A. A., Likhatskii M. N., Mikhlin Y. L.
Заглавие
: Analysis of function of copper sulfide
nanoparticles
as sphalerite flotation activator
Место публикации
: J. Min. Sci. - 2021. - Vol. 57, Is. 1. - P.144-153. - ISSN 10627391 (ISSN),
DOI
10.1134/S1062739121010154
Примечания
: Cited References: 22. - This study was supported by the Russian Science Foundation, project no. 18-17-00135
Аннотация:
The authors compare the effect exerted by copper ions and sulphide copper
nanoparticles
on flotation of Gorevka deposit sphalerite using potassium n-butyl xanthate and in reagent-less regime. Covelline-like colloid particles 4–8 nm in size, obtained in interaction of copper (II) and sulfide ions in aqueous solutions, are characterized using the methods of dynamic light scattering, electron microscopy and diffraction. Sphalerite surface after reaction with copper ions and CuS dispersoid solutions are described by zeta-potential measurements and X-ray photoelectron spectroscopy. It is found that sphalerite flotation after activation with
nanoparticles
is lower than with copper ion solutions of the same concentrations, and improves with increasing duration of activation and flotation processes. The mechanism of CuS
nanoparticles
consists in creation of active centers for the collector to attach to, which intensifies the hydrophobic behavior and adsorption of the collector. Moreover, CuS
nanoparticles
promote formation of a special microrelief of the solid–liquid interface, which ensures rupture of liquid film and attachment of sphalerite particles to air bubbles when they collide.
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8.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Sokolov A. Е., Ivanova O. S., Svetlitsky E. S., Petrov D. A., Chen Ying-Zhen, Spivakov A. A., Lin En-Szu, Jhang Cheng-Jhih, Tseng Yaw Teng, Lin Chun-Rong
Заглавие
: Magnetic
nanoparticles
FE3O4@C: synthesis, morphology, magnetic properties and application
Коллективы
: "Новое в магнетизме и магнитных материалах", международная конференция, Научный совет по физике конденсированных сред РАН, МИРЭА - Российский технологический университет, Московский государственный университет им. М.В. Ломоносова, Магнитное общество России
Место публикации
: Новое в магнетизме и магнитных материалах: сборник трудов XXIV международной конференции/ прогр. ком.: Р. С. Исхаков, С. Г. Овчинников [и др.]. - 2021. - Секция 10: Малые магнитные частицы. - Ст.10-35-38
Примечания
: Библиогр.: 8
Аннотация:
Работа посвящена исследованию магнитных наночастиц Fe3O4@C, синтезированных методом термического разложения с использованием трех различных маршрутов синтеза: (1) двухстадийный процесс, когда предварительно синтезированные наночастицы Fe3O4 покрываются углеродом, (2) наночастицы в одностадийном процессе получения покрываются углеродом, и (3) эти наночастицы ядро-оболочка покрывались дополнительной углеродной оболочкой. Изучены морфология и особенности магнитных и магнитооптических свойств полученных гибридных наночастиц. Исследованы адсорбционные свойства наночастиц по удалению катионных и анионных красителей из водных растворов.The work is devoted to the study of the Fe3O4@C magnetic
nanoparticles
synthesized with the thermal decomposition method using three different synthesis routes: (1) two stage process when preliminary synthesized Fe3O4
nanoparticles
were covered by carbon, (2) core-shell
nanoparticles
were prepared in the one stage process, and (3) these core-shell
nanoparticles
were covered with the additional carbon shell. The morphology and features of the magnetic and magneto-optical properties of the obtained hybrid
nanoparticles
were studied. The sorption properties of NPs for the removal of dyes have been studied.
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9.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Sokolov A. Е., Ivanova O. S., Svetlitsky E. S., Petrov D. A., Edelman I. S., Spivakov A. A., Lin C. R.
Заглавие
: Surface modification of Magnetite
nanoparticles
for their applications
Коллективы
: International Baltic Conference on Magnetism: focus on nanobiomedicine and smart materials, Балтийский федеральный университет им. И. Канта
Место публикации
: 4th International Baltic Conference on Magnetism (IBCM 2021): Book of abstracts. - 2021. - P.197
Примечания
: Cited References: 2. - The reported study was funded by RFBR, project number The reported study was funded by Joint Research Project of Russian Foundation for Basic Research # 19-52-52002 and Ministry of Science and Technology, Taiwan MOST # 109-2112-M-153-003 and # 108-2923-M-153-001-MY3.
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10.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Tyumentseva A. V., Tyutrina E. S., Stolyar S. V., Yaroslavtsev R. N., Velikanov D. A.
Заглавие
: Aminated magnetic
nanoparticles
for epithelial cell separation
Коллективы
: International Baltic Conference on Magnetism: focus on nanobiomedicine and smart materials, Балтийский федеральный университет им. И. Канта
Место публикации
: 4th International Baltic Conference on Magnetism (IBCM 2021): Book of abstracts. - 2021. - P.208
Примечания
: This work was supported by Russian Foundation for Basic Research, Government of Krasnoyarsk Territory, Krasnoyarsk Region Science and Technology Support Fund to the research projects No. 20-42-242902 and by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3). We are grateful to the Center of collective use of FRC KSC SB RAS for the provided equipment.
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11.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Tyumentseva, Anna, V, Yaroslavtsev R. N., Stolyar S. V., Saitova, Alina T., Tyutrina, Ekaterina S., Gorbenko, Alexey S., Stolyar, Marina A., Olkhovskiy, Igor A.
Заглавие
: Silica-coated iron oxide
nanoparticles
for DNA isolation for molecular genetic studies in hematology
Место публикации
: Genet. Test. Mol. Biomark. - 2021. - Vol. 25, Is. 9. - P.611-614. - ISSN 1945-0265,
DOI
10.1089/gtmb.2021.0067. - ISSN 1945-0257(eISSN)
Примечания
: Cited References: 16
Предметные рубрики:
OXIDATIVE STRESS
MUTATION
DAMAGE
Аннотация:
Aim: To develop magnetic
nanoparticles
(MNPs) based on iron oxide for DNA isolation from blood cells for quantitative molecular genetic analyses of the V617F mutation in the Januskinase 2 (JAK2) gene. Materials and Methods: MNPs were synthesized by the coprecipitation method and coated with tetraethyl orthosilicate (TEOS). The size and shape of the complexes were estimated using transmission electron microscopy. Twenty blood samples from patients with myeloproliferative disorders were used for DNA isolation with the MNPs. DNA quality and compatibility for molecular genetic studies of the JAK2 V617F mutation were investigated by gel electrophoresis and real-time polymerase chain reaction (RT-PCR). Results: The average amount of DNA isolated from 150 μL of whole blood was 75.2 ng when MNPs were used and 72.5 ng when standard silica sorbent was used. There was no DNA damage observed after interaction with MNPs. RT-PCR demonstrated similar values for the JAK2 V617F mutant DNA ratios in the samples after DNA isolation with MNPs and by standard sorption on silica. Conclusions: MNPs with silicate capsules of sufficient thickness were obtained and the undesirable damaging effect of iron oxides on nucleic acids during isolation from cells were eliminated. Designed MNPs allow obtaining intact DNA for molecular genetic studies using the example of the JAK2 V617F for study.
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12.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Balaev D. A., Poperechny I. S., Krasikov A. A., Semenov S. V., Popkov S. I., Knyazev Yu. V., Kirillov V. L., Yakushkin S. S., Martyanov O., Raikher Y. L.
Заглавие
: Superparamagnetic effect on the dynamic remagnetization of CoFe2O4
nanoparticles
in a pulse field
Коллективы
: International Baltic Conference on Magnetism: focus on nanobiomedicine and smart materials, Балтийский федеральный университет им. И. Канта
Место публикации
: 4th International Baltic Conference on Magnetism (IBCM 2021): Book of abstracts. - 2021. - P.104
Примечания
: Cited References: 7
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13.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Balaev D. A., Krasikov A. A., Popkov S. I., Semenov S. V., Volochaev M. N., Velikanov D. A., Kirillov V. L., Martyanov O. N.
Заглавие
: Uncompensated magnetic moment and surface and size effects in few-nanometer antiferromagnetic NiO particles
Место публикации
: J. Magn. Magn. Mater. - 2021. - Vol. 539. - Ст.168343. - ISSN 03048853 (ISSN),
DOI
10.1016/j.jmmm.2021.168343
Примечания
: Cited References: 98. - The TEM study was carried out on the equipment of the Krasnoyarsk Territorial Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences
Аннотация:
The analysis of the M(H) magnetization curves of antiferromagnetic
nanoparticles
yields information about magnetic subsystems formed in these objects, which are characterized by a large fraction of surface atoms. However, in the conventionally investigated experimental magnetic field range of up to 60–90 kOe, this analysis often faces the ambiguity of distinguishing the Langevin function-simulated contribution of uncompensated magnetic moments μun of particles against the background of a linear-in-field dependence (the antiferromagnetic susceptibility and other contributions). Here, this problem has been solved using a pulsed technique, which makes it possible to significantly broaden the range of external fields in which the μun contribution approaches the saturation.
Nanoparticles
of a typical NiO antiferromagnet with an average size of d ~ 4.5 nm have been investigated. Based on the thorough examination of the M(H) magnetization curves measured in pulsed fields of up to 250 kOe, a model of the magnetic state of NiO
nanoparticles
of such a small size has been proposed. The average moment is ~130 μB (μB is the Bohr magneton) per particle, which corresponds to 60–70 decompensated spins of nickel atoms localized, according to the Néel hypothesis (μun ~ d3/2), both on the surface and in the bulk of a particle. A part of the surface spins unrelated to the antiferromagnetic core form another subsystem, which behaves as free paramagnetic atoms. Along with the antiferromagnetic core, an additional linear-in-field contribution has been detected, which is apparently related to superantiferromagnetism, i.e., the size effect inherent to small antiferromagnetic particles.
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14.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Knyazev Yu. V., Balaev D. A., Stolyar S. V., Krasikov A. A., Bayukov O. A., Volochaev M. N., Yaroslavtsev R. N., Ladygina V. P., Velikanov D. A., Iskhakov R. S.
Заглавие
: Interparticle magnetic interactions in synthetic ferrihydrite: Mossbauer spectroscopy and magnetometry study of the dynamic and static manifestations
Место публикации
: J. Alloys Compd. - 2022. - Vol. 889. - Ст.161623. - ISSN 09258388 (ISSN),
DOI
10.1016/j.jallcom.2021.161623
Примечания
: Cited References: 84. - This study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk Territory, and the Krasnoyarsk Territorial Foundation for Support of Scientific and R&D Activities, project no. 19–42–240012 R-A “Magnetic Resonance in Ferrihydrite
Nanoparticles
: Effects Related to the Core-Shell Structure”
Аннотация:
Samples of synthetic ferrihydrite with an average nanoparticle size of 2.7 nm have been examined by magnetometry and Mossbauer spectroscopy. Ferrihydrite is characterized by the antiferromagnetic interactions between the magnetic moments of iron atoms. In ferrihydrite
nanoparticles
, as in any other antiferromagnetic ones, structural defects induce the formation of an uncompensated magnetic moment, which determines the magnetic properties typical of single-domain ferro- and ferrimagnetic particles. The manifestation of the magnetic interactions between ferrihydrite
nanoparticles
in the magnetic properties of the material and in the temperature evolution of Mossbauer spectra has been in focus. The results obtained on synthetic ferrihydrite have been compared with the data for the biogenic ferrihydrite sample with a similar average size of particles surrounded by a polysaccharide shell, which weakens and screens the interparticle magnetic interactions. A clear manifestation of the effect of the interparticle magnetic interactions on the transition to the blocked state is the presence of a significant contribution of the relaxation component in the Mossbauer spectra at temperatures of the transition from the superparamagnetic to blocked state. The temperature dependence of the particle relaxation time obtained from the Mossbauer spectra points out the collective effect of freezing of the magnetic moments of particles due to the magnetic interactions between them.
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15.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Lin C. -R., Ivanova O. S., Petrov D. A., Sokolov A. Е., Chen Y. -Z., Gerasimova M. A., Zharkov S. M., Tseng Y. -T., Shestakov N. P., Edelman I. S.
Заглавие
: Amino-functionalized Fe3O4@SiO2 core-shell magnetic
nanoparticles
for dye adsorption
Место публикации
: Nanomaterials. - 2021. - Vol. 11, Is. 9. - Ст.2371. - ISSN 20794991 (ISSN),
DOI
10.3390/nano11092371
Примечания
: Cited References: 35. - The authors are thankful for the financial support the Russian Foundation for Basic Research, Grant № 19-52-52002, Ministry of Science and Technology of Taiwan, Grants MOST № 108-2923-M-153-001-MY3 and № 109-2112-M-153-003-, the Russian Foundation for Basic Research with Government of Krasnoyarsk Territory, Krasnoyarsk Regional Fund of Science, the research project number 19-42-240005: “Features of the electronic structure, magnetic properties and optical excitations in nanocrystals of the multifunctional magnetic chalcogenides Fe3S4 and FeSe”. We thank also the SFU Joint Scientific Center supported by the State assignment (#FSRZ-2020-0011) of the Ministry of Science and Higher Education of the Russian Federation, where the Transmission Electron Microscopy studies were carried out
Аннотация:
Fe3O4@SiO2 core-shell
nanoparticles
(NPs) were synthesized with the co-precipitation method and functionalized with NH2 amino-groups. The
nanoparticles
were characterized by X-ray, FT-IR spectroscopy, transmission electron microscopy, selected area electron diffraction, and vibrating sample magnetometry. The magnetic core of all the
nanoparticles
was shown to be nanocrystalline with the crystal parameters corresponding only to the Fe3O4 phase covered with a homogeneous amorphous silica (SiO2) shell of about 6 nm in thickness. The FT-IR spectra confirmed the appearance of chemical bonds at amino functionalization. The magnetic measurements revealed unusually high saturation magnetization of the initial Fe3O4
nanoparticles
, which was presumably associated with the deviations in the Fe ion distribution between the tetrahedral and octahedral positions in the nanocrystals as compared to the bulk stoichiometric magnetite. The fluorescent spectrum of eosin Y-doped NPs dispersed in water solution was obtained and a red shift and line broadening (in comparison with the dye molecules being free in water) were revealed and explained. Most attention was paid to the adsorption properties of the
nanoparticles
with respect to three dyes: methylene blue, Congo red, and eosin Y. The kinetic data showed that the adsorption processes were associated with the pseudo-second order mechanism for all three dyes. The equilibrium data were more compatible with the Langmuir isotherm and the maximum adsorption capacity was reached for Congo red.
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16.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Sokolov A. Е., Kurilova A. V., Sherepa A. V., Volochaev M. N., Velikanov D. A., Goncharova D. A., Shabalina A. V., Svetlichnyi V.
Заглавие
: Magneto-optical properties of the iron oxide
nanoparticles
obtained by laser ablation
Коллективы
: Pulsed Lasers and Laser Applications, International Conference
Место публикации
: Pulsed lasers and laser applications (AMPL-2019): abstracts of XIV Int. conf. - 2019. - Ст.B-12. - P.61-62. - ISBN 978-5-93629-634-5
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17.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Stolyar S. V., Kryukova O. V., Yaroslavtsev R. N., Bayukov O. A., Knyazev Yu. V., Gerasimova Yu. V., Pyankov V. F., Latyshev N. V., Shestakov N. P.
Заглавие
: Influence of magnetic
nanoparticles
on cells of Ehrlich ascites carcinoma
Место публикации
: AIP Adv. - 2021. - Vol. 11, Is. 1. - Ст.015019. - ISSN 21583226 (ISSN),
DOI
10.1063/9.0000165
Примечания
: Cited References: 22. - The electron microscopy and magnetic resonance study was carried out on the equipment of the Krasnoyarsk Territorial Center for Collective Use, Krasnoyarsk Scientific Center, Siberian Branch, Russian Academy of Sciences. This work was supported by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3). The research was funded by RFBR, Krasnoyarsk Territory and Krasnoyarsk Regional Fund of Science, project number 20-42-242902
Аннотация:
The effect of magnetic
nanoparticles
coated with arabinogalactan on the viability of Ehrlich ascites carcinoma (EAC) cells was studied. The
nanoparticles
were studied by transmission electron microscopy, Mossbauer spectroscopy, IR spectroscopy, and ferromagnetic resonance. A correlation between the proportion of dead EAC cells in suspension and the intensity of the EPR signal of dinitrosyl iron complexes was found. This result may be due to the presence of NO molecules.
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18.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Komogortsev S. V., Balaev D. A., Krasikov A. A., Stolyar S. V., Yaroslavtsev R. N., Ladygina V. P., Iskhakov R. S.
Заглавие
: Magnetic hysteresis of blocked ferrihydrite
nanoparticles
Место публикации
: AIP Adv. - 2021. - Vol. 11, Is. 1. - Ст.015329. - ISSN 21583226 (ISSN),
DOI
10.1063/9.0000111
Примечания
: Cited References: 23. - The magnetic measurements were partially carried out on the equipment of the Krasnoyarsk Regional Center for Collective Use, Krasnoyarsk Science Center, Siberian Branch, Russian Academy of Sciences. This study was supported by the Council of the President of the Russian Federation for State Support of Young Scientists and Leading Scientific Schools (project no. MK-1263.2020.3)
Аннотация:
Using minor hysteresis loops in the Stoner-Wohlfarth model allows describing the experimental behavior of the coercive force of minor hysteresis loops in ferrihydrite
nanoparticles
with a change in the field amplitude. The description allows estimating the parameters of the distribution of the magnetic anisotropy field in
nanoparticles
. The best agreement of the anisotropy fields estimated by different approaches is achieved for the assumption of uniaxial anisotropy in ferrihydrite
nanoparticles
.
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19.
Вид документа
: Статья из сборника (однотомник)
Шифр издания
:
Автор(ы)
: Kurilova A. V., Sokolov A. Е., Sherepa A. V., Volochaev M. N., Velikanov D. A., Goncharova D. A., Shabalina A. V., Svetlichnyi V.
Заглавие
: Magnetic and optical properties of
nanoparticles
of iron and nickel decorated with gold and the possibility of their medical use
Коллективы
: Pulsed Lasers and Laser Applications, International Conference
Место публикации
: Pulsed Lasers and Laser Applications, International Conference (14 ; 2019 ; 15-20 Sept. ; Tomsk). Pulsed lasers and laser applications (AMPL-2019): abstracts of XIV Int. conf. - 2019. - Ст.Y-30. - P.30. - ISBN 978-5-93629-634-5
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20.
Вид документа
: Статья из журнала
Шифр издания
:
Автор(ы)
: Stolyar S. V., Ladygina V. P., Boldyreva A. V., Kolenchukova O. A., Vorotynov A. M., Bairmani M. S., Yaroslavtsev R. N., Iskhakov R. S.
Заглавие
: Synthesis, Properties, and in vivo Testing of Biogenic Ferrihydrite
Nanoparticles
Место публикации
: Bull. Russ. Acad. Sci. Phys. - 2020. - Vol. 84, Is. 11. - P.1366-1369. - ISSN 10628738 (ISSN),
DOI
10.3103/S106287382011026X
Примечания
: Cited References: 12. - The study was supported by the Russian Foundation for Basic Research, the Government of the Krasnoyarsk krai, the Krasnoyarsk Regional Fund for the Support of Scientific and Technical Activities (project no. 19-42-240012 r_a “Magnetic Resonance in Ferrihydrite
Nanoparticles
: Effects Associated with the Core–Shell Structure”), and the grant of the President of the Russian Federation for state support of young Russian scientists—Candidates of sciences no. MK-1263.2020.3
Аннотация:
A sol containing biogenic ferrihydrite
nanoparticles
is obtained by cultivating Klebsiella oxytoca microorganisms. Data on the physical properties of the biogenic ferrihydrite and its effect on the organism of laboratory animals are obtained using a model of experimental hemolytic anemia, according to indicators of the functional activity of erythrocytes and morphological descriptions of organs.
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